CN220351896U - Nickel-tungsten-containing electroplating wastewater treatment device - Google Patents

Nickel-tungsten-containing electroplating wastewater treatment device Download PDF

Info

Publication number
CN220351896U
CN220351896U CN202320467543.9U CN202320467543U CN220351896U CN 220351896 U CN220351896 U CN 220351896U CN 202320467543 U CN202320467543 U CN 202320467543U CN 220351896 U CN220351896 U CN 220351896U
Authority
CN
China
Prior art keywords
kettle
sedimentation
stirring treatment
pipe
stirring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202320467543.9U
Other languages
Chinese (zh)
Inventor
易秉智
陈剑峰
彭金鑫
胡湘钧
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Teli Renewable Resources Co ltd
Original Assignee
Zhejiang Teli Renewable Resources Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Teli Renewable Resources Co ltd filed Critical Zhejiang Teli Renewable Resources Co ltd
Priority to CN202320467543.9U priority Critical patent/CN220351896U/en
Application granted granted Critical
Publication of CN220351896U publication Critical patent/CN220351896U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Manufacture And Refinement Of Metals (AREA)

Abstract

The utility model provides a nickel-tungsten-containing electroplating wastewater treatment device, which comprises a two-stage supporting frame, a stirring treatment kettle, a raw material input port, a communicating cutoff pipe, a precipitation kettle and a suspension extraction pipe, wherein: the stirring treatment kettle is fixed at the upper end of the two-stage support frame through a bolt, the raw material input port is welded at the outer side of the stirring treatment kettle, and the communicating cut-off pipe is fixed at the bottom end of the stirring treatment kettle through external threads; the top of sedimentation kettle is fixed in the one end that the intercommunication cut off the pipe through the screw thread, and sedimentation kettle passes through the lower extreme of bolt fastening at two-stage support frame, and this liquid is taken out the pipe and is inlayed on the top of sedimentation kettle. The stirring treatment kettle and the stirring treatment kettle are arranged, so that the wastewater and additives in the stirring treatment kettle can be sufficiently stirred, and precipitation can be performed in a special area.

Description

Nickel-tungsten-containing electroplating wastewater treatment device
Technical Field
The utility model relates to the technical field of electroplating wastewater, in particular to a nickel-tungsten-containing electroplating wastewater treatment device.
Background
The surfaces of metal and non-metal materials often need surface treatment modification, such as electroplating, electrophoresis, etching, pickling, dephosphorization, etc., which can produce various waste liquids and waste waters, such as electroplating waste water generated in the electroplating process, pickling waste water generated in the pickling process, etc., and nickel and tungsten can be present in these waste waters. However, the conventional electroplating wastewater still has a problem that the wastewater and additives in the wastewater cannot be sufficiently stirred and the precipitation cannot be performed in a specific area.
Therefore, it is very necessary to invent a nickel-tungsten-containing electroplating wastewater treatment device.
Disclosure of Invention
In order to solve the technical problems, the utility model provides a nickel-tungsten-containing electroplating wastewater treatment device, which solves the problems that the existing electroplating wastewater still cannot sufficiently stir the wastewater and additives in the electroplating wastewater and cannot cause precipitation in a special area. The utility model provides a nickel-tungsten electroplating wastewater treatment device, includes two-stage support frame, stirring treatment cauldron, raw materials input port, intercommunication cut-off pipe, sedimentation kettle and suspension extraction pipe, wherein: the stirring treatment kettle is fixed at the upper end of the two-stage support frame through a bolt, the raw material input port is welded at the outer side of the stirring treatment kettle, and the communicating cut-off pipe is fixed at the bottom end of the stirring treatment kettle through external threads; the top of sedimentation kettle is fixed in the one end that the intercommunication cut off the pipe through the screw thread, and sedimentation kettle passes through the lower extreme of bolt fastening at two-stage support frame, and this liquid is taken out the pipe and is inlayed on the top of sedimentation kettle.
The sedimentation kettle comprises a sedimentation area, a stable bottom plate, a temperature control plate, a disassembly sealing cover and a liquid outlet, wherein the sedimentation area is fixed at the lower end of the two-stage support frame through bolts by the stable bottom plate, and the temperature control plate surrounds the outer side of the sedimentation area and is fixed on the surface of the stable bottom plate through bolts; the disassembly sealing cover is arranged above the sedimentation area through bolts, and the liquid outlet is arranged above the disassembly sealing cover through bolts.
The stirring treatment kettle adopts a group of stainless steel metal kettles, stirring blades are arranged in the stirring treatment kettle, and the stirring blades in the stirring treatment kettle are driven by an outer motor to rotate in the horizontal direction; the surface of the stirring treatment kettle is provided with three groups of raw material input ports which are arranged on the surface of the stirring treatment kettle in a mode of two from top to bottom; the space inside the stirring treatment kettle is communicated with or cut off from the precipitation kettle through the communicating cut-off pipe, and is used for mixing and stirring tungsten precipitation tail liquid, lime slurry and sodium hypochlorite in the precipitation kettle, after stirring, the tungsten precipitation tail liquid, the lime slurry and the sodium hypochlorite can be immediately guided into the precipitation kettle through the communicating cut-off pipe, and the stirring treatment kettle can not stay in the precipitation kettle for a long time, so that all precipitation processes are carried out in the precipitation kettle.
The precipitation kettle adopts a stainless steel metal kettle with the specification consistent with that of the stirring treatment kettle, a disassembly sealing cover in the precipitation kettle can be disassembled in the opposite direction, and a plurality of pieces of temperature control plates are adopted; the inside of the temperature control plate is embedded with a plurality of heating wires for dry combustion, the temperature control plate wraps the temperature control plate, a liquid outlet is positioned at the top end of the precipitation kettle, and an electromagnetic valve is arranged in the liquid outlet; the liquid outlet can be used for the suspension liquid extraction pipe to stretch and retract in the suspension liquid extraction pipe for precipitating substances in the suspension liquid extraction pipe, so that the temperature of the substances in the suspension liquid extraction pipe can be always kept between 30 ℃ and 40 ℃, the substances in the suspension liquid extraction pipe can be always kept at a temperature suitable for precipitation, and the precipitation is not convenient to take out outwards.
Compared with the prior art, the utility model has the following beneficial effects:
1. the stirring treatment kettle is used for mixing and stirring the tungsten-precipitation tail liquid, the lime slurry and the sodium hypochlorite in the stirring treatment kettle, and can be immediately guided into the precipitation kettle through the communicated cutoff pipe after the stirring is completed, so that the tungsten-precipitation tail liquid, the lime slurry and the sodium hypochlorite can not stay in the stirring treatment kettle for a long time, and all the precipitation processes are carried out in the precipitation kettle.
2. The setting of the sedimentation kettle is used for sedimentation of substances in the sedimentation kettle, so that the temperature of the substances in the sedimentation kettle can be always kept between 30 ℃ and 40 ℃, the substances in the sedimentation kettle can be always kept at a temperature suitable for sedimentation, and the sedimentation is not convenient to take out.
Drawings
Fig. 1 is a schematic structural view of the present utility model.
FIG. 2 is a schematic structural view of the precipitation tank of the present utility model.
Fig. 3 is a schematic of the workflow of the present utility model.
In the figure:
the device comprises a two-stage supporting frame 1, a stirring treatment kettle 2, a raw material input port 3, a communicating cutoff pipe 4, a precipitation kettle 5, the two-stage supporting frame 1, the stirring treatment kettle 2, the raw material input port 3, the communicating cutoff pipe 4, the precipitation kettle 5, a suspension extraction pipe 6 and a suspension extraction pipe 6.
Detailed Description
In order that those skilled in the art will better understand the present utility model, a technical solution of the embodiments of the present utility model will be clearly and completely described below, and it is apparent that the described embodiments are only some embodiments of the present utility model, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the present utility model without making any inventive effort, shall fall within the scope of the present utility model.
As shown in fig. 1 to 3.
The utility model provides a nickel-tungsten-containing electroplating wastewater treatment device, which comprises a two-stage support frame 1, a stirring treatment kettle 2, a raw material input port 3, a communicating cutoff pipe 4, a precipitation kettle 5 and a suspension extraction pipe 6, wherein: the stirring treatment kettle 2 is fixed at the upper end of the two-stage support frame 1 through bolts, the raw material input port 3 is welded at the outer side of the stirring treatment kettle 2, and the communicating cut-off pipe 4 is fixed at the bottom end of the stirring treatment kettle 2 through external threads; the top of sedimentation kettle 5 is fixed in the one end that the intercommunication cut-off pipe 4 through the screw thread, and sedimentation kettle 5 passes through the lower extreme of bolt fastening at two-stage support frame 1, and this liquid is taken out pipe 6 and is inlayed on the top of sedimentation kettle 5.
The sedimentation kettle 5 comprises a sedimentation area 51, a stable bottom plate 52, a temperature control plate 53, a disassembly sealing cover 54 and a liquid outlet 55, wherein the sedimentation area 51 is fixed at the lower end of the two-stage support frame 1 through bolts by the stable bottom plate 52, and the temperature control plate 53 surrounds the outer side of the sedimentation area 51 and is fixed on the surface of the stable bottom plate 52 through bolts; the detachable cover 54 is mounted above the sedimentation zone 51 by bolts, and the liquid outlet 55 is mounted above the detachable cover 54 by bolts.
The two-stage support frame 1 is used for forming two high supports, so that the height difference exists between the stirring treatment kettle 2 and the precipitation kettle 5, and the substances in the stirring treatment kettle are convenient to convey; the stirring treatment kettle 2 adopts a group of stainless steel metal kettles, stirring blades are arranged in the stirring treatment kettle 2, and the stirring blades in the stirring treatment kettle 2 are driven by an outer motor to rotate in the horizontal direction; the surface of the stirring treatment kettle 2 is provided with three groups of raw material input ports 3 which are arranged on the surface of the stirring treatment kettle 2 in a mode of two from top to bottom; the space inside the stirring treatment kettle 2 is communicated with or cut off from the precipitation kettle 5 through the communicating cut-off pipe 4, and is used for mixing and stirring tungsten-precipitation tail liquid, lime slurry and sodium hypochlorite in the precipitation kettle 5, after stirring, the tungsten-precipitation tail liquid, the lime slurry and the sodium hypochlorite can be immediately guided into the precipitation kettle 5 through the communicating cut-off pipe 4, and the tungsten-precipitation tail liquid, the lime slurry and the sodium hypochlorite can not stay in the precipitation kettle 2 for a long time, so that all precipitation processes are carried out in the precipitation kettle 5; the raw material input port 3 is used for inputting tungsten precipitation tail liquid, lime slurry and sodium hypochlorite into the stirring treatment kettle 2; the communicating cutoff pipe 4 is used for communicating the stirring treatment kettle 2 and the precipitation kettle 5; the sedimentation kettle 5 is a stainless steel metal kettle with the specification consistent with that of the stirring treatment kettle 2, a disassembly sealing cover 54 in the sedimentation kettle 5 can be disassembled in a direction, and a plurality of temperature control plates 53 are adopted; a plurality of heating wires for dry combustion are embedded in the temperature control plate 53, the temperature control plate 53 wraps the temperature control plate 53, a liquid outlet 55 is positioned at the top end of the precipitation kettle 5, and an electromagnetic valve is arranged in the liquid outlet 55; the liquid outlet 55 can be used for the suspension liquid extraction pipe 6 to stretch and retract in the suspension liquid extraction pipe for precipitating substances in the suspension liquid extraction pipe, so that the temperature of the substances in the suspension liquid extraction pipe can be kept between 30 ℃ and 40 ℃ all the time, the substances in the suspension liquid extraction pipe can be kept in a temperature suitable for precipitation all the time, and the precipitation is not convenient to take out outwards; the suspension extraction pipe 6 is used to extract the suspension produced after precipitation outwards.
Example 2
The existing treatment process comprises the following steps: as shown in figure 3, hydrochloric acid is used for converting tungsten element in nickel-tungsten-containing electroplating wastewater into tungstic acid to precipitate, and crude tungstic acid can be purified. The ammonia nitrogen and COD content in the tungsten-sinking tail liquid is higher, and the tungsten-sinking tail liquid can be discharged after reaching the standard through treatment; the nickel element can be removed in the ammonia nitrogen removal process.
The nickel-tungsten-containing electroplating wastewater to be treated is acidic, the nickel and tungsten contents are above 20g/L, the ammonia nitrogen content is 10-20 g/L, and the COD is as high as 40g/L.
(1) Precipitated tungstic acid
Due to the different chemical properties of nickel and tungsten, the nickel and tungsten cannot be treated under the same conditions; the tungsten element is generally present in solution in the form of anions (WO 42-) and the tungstic acid is present in precipitated form under acidic conditions (in the absence of hydrofluoric acid). The nickel-tungsten-containing electroplating wastewater is acidified by hydrochloric acid, so that the hydrochloric acid is excessive to obtain tungstic acid precipitate, and the tungsten content in the tail liquid is lower than 2g/L.
(2) Breaking ammonia nitrogen
The pH of the tail liquid after the tungstic acid precipitation is regulated to be strong alkaline by lime slurry, ammonia gas is generated, and then sodium hypochlorite is added to accelerate ammonia nitrogen decomposition, so that the sodium hypochlorite has a certain effect on reducing COD. The nickel ions and the residual tungstate radical can be disposed of in the step, and the nickel ions are precipitated in the form of nickel hydroxide under the strong alkaline condition; the sodium tungstate in the solution reacts with calcium hydroxide to generate calcium tungstate precipitate, metal ions in the tail liquid after filter pressing can reach the emission standard, and the nickel-containing precipitate can be smelted and recycled later.
(3) Fenton reaction to remove COD
The technology for removing COD in the disposal process is Fenton oxidation, which has extremely high capability of removing organic pollutants difficult to degrade, and utilizes the strong redox property of ferrous sulfate and hydrogen peroxide to generate hydroxyl free radicals with strong oxidizing property, and the hydroxyl free radicals are generated with the organic matters difficult to degrade, and finally the organic pollutants difficult to degrade are effectively oxidized and decomposed. And (3) carrying out Fenton reaction for 1-2 times on the solution with the metal ions and ammonia nitrogen reaching the standards, wherein COD can reach the emission standard, and the produced iron-containing sludge can be smelted and recovered.
By utilizing the technical scheme of the utility model or under the inspired by the technical scheme of the utility model, a similar technical scheme is designed by a person skilled in the art, so that the technical effects are achieved, and the technical scheme falls into the protection scope of the utility model.

Claims (4)

1. Nickel-tungsten-containing electroplating wastewater treatment device is characterized in that: including two-stage support frame (1), stirring treatment cauldron (2), raw materials input port (3), intercommunication cut-off pipe (4), sedimentation kettle (5) and suspension extraction pipe (6), wherein: the stirring treatment kettle (2) is fixed at the upper end of the two-stage supporting frame (1) through a bolt, the raw material input port (3) is welded at the outer side of the stirring treatment kettle (2), and the communicating cut-off pipe (4) is fixed at the bottom end of the stirring treatment kettle (2) through external threads; the top of sedimentation kettle (5) is fixed in the one end of intercommunication cut-off pipe (4) through the screw thread, and sedimentation kettle (5) pass through the lower extreme of bolt fastening at two-stage support frame (1), and this liquid is taken out pipe (6) and is inlayed on the top of sedimentation kettle (5).
2. The nickel-tungsten-containing electroplating wastewater treatment device according to claim 1, wherein: the sedimentation kettle (5) comprises a sedimentation zone (51), a stabilizing bottom plate (52), a temperature control plate (53), a disassembly sealing cover (54) and a liquid outlet (55), wherein the sedimentation zone (51) is fixed at the lower end of the two-stage support frame (1) through bolts by the stabilizing bottom plate (52), and the temperature control plate (53) surrounds the outer side of the sedimentation zone (51) and is fixed on the surface of the stabilizing bottom plate (52) through bolts; the disassembly sealing cover (54) is arranged above the sedimentation zone (51) through bolts, and the liquid outlet (55) is arranged above the disassembly sealing cover (54) through bolts.
3. The nickel-tungsten-containing electroplating wastewater treatment device according to claim 1, wherein: the stirring treatment kettle (2) is a group of stainless steel metal kettles, stirring blades are arranged in the stirring treatment kettle (2), and the stirring blades in the stirring treatment kettle (2) are driven by an outer motor to rotate in the horizontal direction; the surface of the stirring treatment kettle (2) is provided with three groups of raw material input ports (3) which are arranged on the surface of the stirring treatment kettle (2) in a two-over-two mode; the space inside the stirring treatment kettle (2) is communicated with or cut off by a communicating cut-off pipe (4) through the communicating cut-off pipe (4).
4. The nickel-tungsten-containing electroplating wastewater treatment device according to claim 2, wherein: the sedimentation kettle (5) is a stainless steel metal kettle with the specification consistent with that of the stirring treatment kettle (2), a disassembly sealing cover (54) in the sedimentation kettle (5) can be disassembled in the opposite direction, and the temperature control plate (53) is a plurality of pieces; a plurality of heating wires for dry heating are embedded in the temperature control plate (53), the temperature control plate (53) wraps the temperature control plate (53),
the liquid outlet (55) is positioned at the top end of the sedimentation kettle (5), and an electromagnetic valve is arranged in the liquid outlet (55);
the liquid outlet (55) can be used for the suspension liquid extraction pipe (6) to stretch and retract in the suspension liquid extraction pipe.
CN202320467543.9U 2023-03-13 2023-03-13 Nickel-tungsten-containing electroplating wastewater treatment device Active CN220351896U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202320467543.9U CN220351896U (en) 2023-03-13 2023-03-13 Nickel-tungsten-containing electroplating wastewater treatment device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202320467543.9U CN220351896U (en) 2023-03-13 2023-03-13 Nickel-tungsten-containing electroplating wastewater treatment device

Publications (1)

Publication Number Publication Date
CN220351896U true CN220351896U (en) 2024-01-16

Family

ID=89477714

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202320467543.9U Active CN220351896U (en) 2023-03-13 2023-03-13 Nickel-tungsten-containing electroplating wastewater treatment device

Country Status (1)

Country Link
CN (1) CN220351896U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117884452A (en) * 2024-03-15 2024-04-16 崇义章源钨业股份有限公司 Method for treating ammonia-containing tungsten-containing slag

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117884452A (en) * 2024-03-15 2024-04-16 崇义章源钨业股份有限公司 Method for treating ammonia-containing tungsten-containing slag
CN117884452B (en) * 2024-03-15 2024-06-11 崇义章源钨业股份有限公司 Method for treating ammonia-containing tungsten-containing slag

Similar Documents

Publication Publication Date Title
CN100494098C (en) Fenton and air-float integral water treating method
US20130168314A1 (en) Method for Treating Wastewater Containing Copper Complex
CN104261622A (en) Fenton sewage treatment process and equipment thereof
CN220351896U (en) Nickel-tungsten-containing electroplating wastewater treatment device
CN106746031A (en) A kind of processing method of Ni-containing Plating Wastewater
CN106830467B (en) Fenton method sewage treatment integrated device based on iron mud recycling and method thereof
CN104193058B (en) A kind of gold mine cyanide wastewater comprehensive processing method
CN101172725A (en) Method for processing waste alkali liquid in butyl octanol production
CN109721195B (en) Internal circulation catalytic oxidation method for waste water
CN111170582A (en) Treatment process for standard-reaching discharge and recovery of electroplating wastewater
CN107188265A (en) It is a kind of that the method that heavy metal is complexed waste water is handled based on UV/ chlorine high-level oxidation technology
CN213623721U (en) Hydrogen peroxide solution waste water processing system
CN109809652A (en) A kind of chemical nickel Wastewater by Electric treatment by catalytic oxidation and system
CN102757141A (en) Method for processing heavy metal nickel in stainless steel pickling mixed waste acid
CN112047566A (en) Full-quantitative treatment system and method for landfill leachate
CN108675418A (en) A kind of polysilicate aluminium ferric flocculant and preparation method thereof
CN212425687U (en) Electroplating effluent and PCB waste water's high-efficient pretreatment systems
CN211111439U (en) Treatment device for high-concentration cyanide-containing wastewater
CN210559900U (en) Chemical nickel waste water electrocatalytic oxidation treatment system
CN100591630C (en) Monocrystalline silicon or carbon-base monocrystalline silicon electrode electrolysis oxidation treatment method for organic chemical sewage
CN206553372U (en) Fenton sludge treatment device with cyclic utilization of iron salt
CN215102472U (en) System for treating deplating waste bath solution containing sodium metanitrate basic sulfonate
CN203820520U (en) Calcium carbonate wastewater treatment system
CN219839613U (en) Biochemical sludge regeneration recovery system
CN210065495U (en) Processing system for recycling iron-containing sludge generated by advanced oxidation process

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant