CN220311158U - Device for nondestructively cleaning bronze ware - Google Patents

Device for nondestructively cleaning bronze ware Download PDF

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Publication number
CN220311158U
CN220311158U CN202321490709.5U CN202321490709U CN220311158U CN 220311158 U CN220311158 U CN 220311158U CN 202321490709 U CN202321490709 U CN 202321490709U CN 220311158 U CN220311158 U CN 220311158U
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gas
cleaning
micro
communicated
liquid
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宋艳
李继香
谢振斌
蒋如潇
王冲
王雯娟
刘建成
赵延琴
李婷竹
姜标
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Sichuan Institute Of Cultural Relics And Archaeology
Shanghai Advanced Research Institute of CAS
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Sichuan Institute Of Cultural Relics And Archaeology
Shanghai Advanced Research Institute of CAS
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Abstract

The utility model discloses a device for nondestructively cleaning a bronze ware, which comprises a liquid storage tank, a gas conveying pipeline, a micro-nano bubble generating system, a gas-liquid mixing pump, an ultrasonic cleaning water tank and a flow dividing assembly, wherein the liquid storage tank is connected with the gas conveying pipeline; wherein, the liquid outlet of the liquid storage tank is communicated with the feed inlet of the gas-liquid mixing pump; the gas outlet of the gas conveying pipeline is communicated with the feed inlet of the gas-liquid mixing pump; the discharge port of the gas-liquid mixing pump is communicated with the feed port of the micro-nano bubble generation system, and the discharge port of the micro-nano bubble generation system is communicated with the flow dividing assembly; the flow dividing assembly is arranged in the ultrasonic cleaning water tank; compared with the prior art, the utility model mixes the gas with the mixed cleaning solution prepared by water and the cleaning agent to form micro-nano bubbles, and then efficiently and nondestructively cleans the bronze ware in an ultrasonic cleaning water tank in a mode of combining ultrasonic cleaning, micro-nano bubble cleaning and chemical cleaning.

Description

Device for nondestructively cleaning bronze ware
Technical Field
The utility model relates to the technical field of bronze ware cleaning, in particular to a device for cleaning bronze ware in a nondestructive mode.
Background
The relics are remains and remains left in the historic development process of human beings, and have important archaeological values. However, these precious relics are inevitably damaged to varying degrees after thousands of years of both natural weathering, including natural factors such as rain and snow, sand, dust, smoke, soluble salts, organisms and microorganisms, and also including artifacts such as smearing, scoring, soot, acid rain, improper retooling and reinforcement, and the like, leaving a wide variety of contaminants and blots.
Cleaning is an important link of cultural relic restoration, and aims to remove various pollutants and marks, reduce and preserve the historical value of the cultural relic as much as possible. At present, physical cleaning, chemical cleaning, ultrasonic cleaning, laser cleaning, dry ice cleaning and other methods are mainly adopted for cleaning cultural relics. The chemical cleaning mainly uses acid materials such as oxalic acid, citric acid, acetic acid and the like, complexing materials such as sodium hexametaphosphate, EDTA disodium salt and the like, alkaline materials such as sodium carbonate and the like, oxidizing materials such as 84 disinfectant and hydrogen peroxide and the like, and the chemical substances tend to irreversibly corrode the surface of the cultural relics while cleaning, so that the cultural relics are damaged. The physical cleaning mainly adopts a mechanical means to physically erase, and uses a dust collector, a brush, a flap, sticky, wiping and the like to directly remove dirt or adopts a mechanical electric tool to remove hard pollutants, so that the defect is that the pollutants on the surface of the cultural relics are difficult to thoroughly clean, and the electric tool can possibly damage the cultural relics. The cleaning methods such as laser and dry ice have respective defects, for example, laser cleaning irradiates the surface of an object by using high-frequency high-energy laser pulse, the instantaneously focused laser energy causes instantaneous evaporation or stripping of pollutants on the surface, the substrates of cultural relics can be possibly damaged, the dry ice cleaning needs a high-pressure cleaning machine, the equipment requirement is high, and the application range is small.
Ultrasonic cleaning is to utilize cavitation, acceleration and direct flow of ultrasonic wave in liquid to directly and indirectly act on liquid and dirt to disperse, emulsify and strip dirt layer for cleaning. Cavitation and direct flow are more commonly used in all ultrasonic cleaners. The ultrasonic wave has high frequency and short wavelength, so that the propagation directivity is good and the penetrating power is strong, which is why the ultrasonic cleaner is designed and manufactured. Ultrasonic cleaning belongs to physical cleaning, is green cleaning per se, belongs to combined cleaning if proper cleaning agents are added into cleaning fluid, has obvious cleaning effect, and is very suitable for cleaning the surfaces of some cultural relics.
Bronze is an alloy with copper, tin and lead as main components, and is subjected to long-time oxidation effect both in the prior art and the earth, so that various corrosion coatings with different colors are naturally formed, and harmful rust is extremely damaged on the bronze, so that the bronze rust removal repair is very important. The aim of cleaning and rust removal of the copper relics is mainly to better read historical information such as textures, inscriptions and various casting marks left by the copper relics, remove corrosive substances such as unstable harmful rust on the surfaces of the copper relics, restore the surfaces and the processed original appearance of the copper relics, show the historical originality of the copper relics, and provide the truest and most reliable information for the research of the current social politics, economy and culture of the relevant staff such as Wen Bo. The cleaning and rust removal of copper cultural relics can be divided into two types, namely physical rust removal and chemical rust removal. The physical rust removing method mainly adopts a surgical knife, a miniature dental drill and ultrasonic vibration to remove scaling and rust matters on metal cultural relics. The chemical method for removing rust is to use chemical medicines such as citric acid, glycolic acid, ethylenediamine tetraacetic acid, sodium nitrite, ethanol, acetone, sodium dithionate solution, citric acid-thiourea compound solution, trisodium bicarbonate solution and the like, wherein the temperature is about 35 ℃ and the pH is controlled between 6 and 7, so that the purposes of removing scaling and harmful rust on the surface of the copper cultural relics are achieved. The disadvantage of this method is that it may cause excessive cleaning or residue effects, and the control of the amount of the drug at the time of use is a difficult problem.
In summary, there is no system for cleaning bronze-type relics that is relatively thorough and friendly.
Disclosure of Invention
Aiming at the defects existing in the prior art, the utility model aims to provide a device for cleaning bronze wares without damage, which solves the problem that no system is available for cleaning bronze cultural relics thoroughly and friendly in the prior art.
In order to achieve the above purpose, the present utility model adopts the following technical scheme: a device for nondestructively cleaning a bronze ware comprises a liquid storage tank, a gas conveying pipeline, a micro-nano bubble generation system, a gas-liquid mixing pump, an ultrasonic cleaning water tank and a flow dividing assembly;
wherein, the liquid outlet of the liquid storage tank is communicated with the feed inlet of the gas-liquid mixing pump;
the gas outlet of the gas conveying pipeline is communicated with the feed inlet of the gas-liquid mixing pump;
the discharge port of the gas-liquid mixing pump is communicated with the feed port of the micro-nano bubble generation system, and the discharge port of the micro-nano bubble generation system is communicated with the flow dividing assembly;
the flow dividing assembly is arranged in the ultrasonic cleaning water tank.
Working principle:
the liquid storage tank is internally provided with a mixed cleaning solution prepared from water and cleaning agent, a gas conveying pipeline is used for introducing gas, the mixed cleaning solution and the gas are pumped into a micro-nano bubble generation system after being mixed in a gas-liquid mixing pump, the micro-nano bubble generation system generates micro-nano bubbles to be uniformly distributed into an ultrasonic cleaning water tank through a flow dividing assembly, and the cleaning agent, the micro-nano bubbles and ultrasonic waves in the ultrasonic cleaning water tank jointly act to clean the bronze ware.
Further, the flow splitting assembly includes:
the gas distribution pipe rack is horizontally arranged at the bottom in the ultrasonic cleaning water tank, and a feed inlet of the gas distribution pipe rack is communicated with a discharge outlet of the micro-nano bubble generation system;
the cloth nozzles are communicated with the cloth air pipe frame, and the cloth nozzles are uniformly distributed at the top of the cloth air pipe frame.
Further, the cloth gas pipe frame includes:
the first guide pipes are arranged at intervals, and any one of the first guide pipes is connected with a water inlet pipe which is used for being connected with a discharge port of the micro-nano bubble generation system;
the second guide pipes are multiple and distributed at intervals, the multiple second guide pipes are communicated between the two first guide pipes, and the multiple distribution nozzles are distributed on the multiple second guide pipes.
Further, the micro-nano bubble generation system can be in a dissolved air tank form, a spiral form or a honeycomb form.
Further, a liquid outlet of the liquid storage tank is communicated with a feed inlet of the gas-liquid mixing pump through a first connecting pipe, and a liquid flow control valve is arranged on the first connecting pipe.
Further, a pressure gauge is arranged at the discharge port of the micro-nano bubble generation system in a matched mode.
Further, the discharge port of the micro-nano bubble generation system is communicated with the feed port of the gas distribution pipe frame through a liquid guide pipe, the pressure gauge is arranged on the liquid guide pipe, and the liquid guide pipe is further provided with a pressure control valve.
Compared with the prior art, the utility model has the following beneficial effects:
1. the device for cleaning the bronze ware in a nondestructive mode mainly comprises a liquid storage tank, a gas conveying pipeline, a micro-nano bubble generation system, a gas-liquid mixing pump, an ultrasonic cleaning water tank and a flow dividing assembly, wherein gas and a mixed cleaning solution prepared by water and a cleaning agent are mixed to form micro-nano bubbles, and then the bronze ware is cleaned in the ultrasonic cleaning water tank in an efficient and nondestructive mode in a matching mode of ultrasonic cleaning, micro-nano bubble cleaning and chemical cleaning.
Drawings
FIG. 1 is a process flow diagram of an embodiment of the present utility model;
fig. 2 is a schematic structural view of the flow dividing assembly in fig. 1.
Reference numerals in the drawings of the specification include: the device comprises a liquid storage tank 1, a liquid flow control valve 2, a gas conveying pipeline 3, a micro-nano bubble generation system 4, a gas-liquid mixing pump 5, a pressure gauge 6, an ultrasonic cleaning water tank 7, a flow dividing assembly 8, a first guide pipe 81, a second guide pipe 82 and a distribution nozzle 83.
Detailed Description
The utility model is described in further detail below by way of specific embodiments:
as shown in fig. 1, the embodiment of the utility model provides a device for nondestructively cleaning a bronze ware, which comprises a liquid storage tank 1, a gas conveying pipeline 3, a micro-nano bubble generating system 4, a gas-liquid mixing pump 5, an ultrasonic cleaning water tank 7 and a shunt assembly 8;
wherein, the liquid outlet of the liquid storage tank 1 is communicated with the feed inlet of the gas-liquid mixing pump 5;
the air outlet of the air conveying pipeline 3 is communicated with the feed inlet of the air-liquid mixing pump 5;
the discharge port of the gas-liquid mixing pump 5 is communicated with the feed port of the micro-nano bubble generation system 4, and the discharge port of the micro-nano bubble generation system 4 is communicated with the flow dividing assembly 8;
the flow dividing assembly 8 is arranged in the ultrasonic cleaning water tank 7.
When in use, the utility model is characterized in that:
the liquid storage tank 1 stores mixed cleaning solution prepared by water and cleaning agent, the gas is introduced into the gas conveying pipeline 3, the mixed cleaning solution and the gas are pumped into the micro-nano bubble generation system 4 after being mixed in the gas-liquid mixing pump 5, the micro-nano bubble generation system 4 generates micro-nano bubbles to be uniformly distributed into the ultrasonic cleaning water tank 7 through the flow dividing component 8, the bronze ware is cleaned under the combined action of the cleaning agent, the micro-nano bubbles and the ultrasonic waves in the ultrasonic cleaning water tank 7, and the cleaning time in the ultrasonic cleaning water tank 7 is 0.1-10 hours, preferably 1-2 hours.
The cleaning agent can be citric acid, glycolic acid, ethylenediamine tetraacetic acid, sodium nitrite, ethanol, acetone, sodium dithionate, citric acid-thiourea compound liquid, trisodium bicarbonate, sodium carbonate, hydrogen peroxide, sodium tripolyphosphate, sodium hexametaphosphate, sodium hydroxide-sodium dithionite, acetonitrile, sodium tartrate, dimethyl sulfoxide or cysteine, and the molar concentration of the mixed cleaning solution is 2% -3%, so that harmful rust on the surface of a cultural relic can be effectively cleaned.
The gas introduced into the gas delivery line 3 may be air or the like.
The device for cleaning the bronze ware without damage mainly comprises a liquid storage tank 1, a gas conveying pipeline 3, a micro-nano bubble generation system 4, a gas-liquid mixing pump 5, an ultrasonic cleaning water tank 7 and a flow dividing component 8, wherein gas and a mixed cleaning solution prepared from water and a cleaning agent are mixed to form micro-nano bubbles, and then the bronze ware is efficiently and nondestructively cleaned in the ultrasonic cleaning water tank 7 in a mode of matching ultrasonic cleaning, micro-nano bubble cleaning and chemical cleaning.
As shown in fig. 2, according to another embodiment of the present utility model, the apparatus for non-destructive cleaning of bronze ware, wherein the diverter assembly 8 comprises a gas distribution pipe rack and a distribution nozzle 83;
wherein the gas distribution pipe frame is horizontally arranged at the bottom of the ultrasonic cleaning water tank 7, and the feed inlet of the gas distribution pipe frame is communicated with the discharge outlet of the micro-nano bubble generation system 4;
the cloth nozzles 83 are several and all communicated with the cloth gas frame, and the cloth nozzles 83 are uniformly distributed at the top of the cloth gas frame.
The following are given here: micro-nano bubbles generated by the micro-nano bubble generation system 4 are guided into a gas distribution pipe rack and then are evenly sprayed into the ultrasonic cleaning water tank 7 through a plurality of distribution nozzles 83 to clean the bronze ware.
Based on the scheme:
the gas distribution pipe frame specifically adopted comprises a first conduit 81 and a second conduit 82;
wherein, the first guide pipes 81 are arranged at intervals, and any one of the first guide pipes 81 is connected with a water inlet pipe which is used for being connected with a discharge hole of the micro-nano bubble generation system 4;
the second ducts 82 are multiple and spaced apart, the multiple second ducts 82 are communicated between the two first ducts 81, and the multiple distribution nozzles 83 are distributed on the multiple second ducts 82.
The number of the second ducts 82 may be 10, and the number of the distribution nozzles 83 on each second duct 82 may be 1-20, which are reasonably arranged according to the requirement. In this embodiment, two first ducts 81 are arranged in parallel at intervals, the water inlet pipe is arranged outside the two first ducts 81 in a direction perpendicular to the first ducts 81, the number of second ducts 82 is four and arranged in parallel at intervals, and the number of distribution nozzles 83 arranged on each second duct 82 is 5.
The first conduit 81 and the second conduit 82 are arranged in such a way that the introduced micro-nano bubbles are distributed uniformly in the gas distribution pipe frame, so that the pressure of the micro-nano bubbles sprayed out from the gas distribution nozzle 83 is uniform, and the micro-nano bubbles distributed in the ultrasonic cleaning water tank 7 are uniform, thereby being beneficial to cleaning bronze relics.
As shown in fig. 1, according to another embodiment of the present utility model, the liquid outlet of the liquid storage tank 1 is communicated with the feed inlet of the gas-liquid mixing pump 5 through a first connecting pipe, and the first connecting pipe is provided with a liquid flow control valve 2.
Here: the on-off and flow rate of the introduced mixed cleaning solution are controlled through the liquid flow control valve 2, so that the gas-liquid ratio mixed in the gas-liquid mixing pump 5 can be adjusted, the gas-liquid ratio is generally 1:3-1:50, the gas-liquid ratio is preferably 1:10-1:20, and the gas-liquid ratio is more preferably 1:10-1:15 in the use process; after the gas-liquid ratio is adjusted to 1:10-1:15, the cleaning effect on bronze relics is better and the chemical agent residue is less.
As shown in fig. 1, according to another embodiment of the present utility model, the discharging hole of the micro-nano bubble generating system 4 is cooperatively provided with a pressure gauge 6 for observing the water outlet pressure of the micro-nano bubble generating system 4, wherein the water outlet pressure is controlled to be 0.1-1.0MPa, the water outlet pressure is preferably 0.3-0.8MPa, and the water outlet pressure is more preferably 0.4-0.6MPa; wherein, the pressure gauge 6 is matched with a pressure control valve; specifically, the discharge port of the micro-nano bubble generation system 4 is communicated with the feed port of the gas distribution pipe frame through a liquid guide pipe, the pressure gauge 6 and the pressure control valve are both arranged on the liquid guide pipe, and the water outlet pressure of the micro-nano bubble generation system 4 can be regulated through the pressure control valve.
The pressure of micro-nano bubbles entering the ultrasonic cleaning water tank 7 can be controlled by the design of the water outlet pressure of the micro-nano bubble generating system 4, so that the pressure of the micro-nano bubbles in the ultrasonic cleaning water tank 7 is more reasonable, and the cultural relics can be cleaned efficiently without damage.
As shown in fig. 1, according to another embodiment of the present utility model, the apparatus for non-destructive cleaning of a bronze ware, wherein the micro-nano bubble generating system 4 may be in the form of a dissolved air tank, a spiral form or a honeycomb form.
The micro-nano bubble generation system 4 in the form of a dissolved air tank can refer to a micro-nano bubble generator disclosed in application number CN201810073331.6, the micro-nano bubble generation system 4 in the form of a spiral can refer to a nano-scale fluid magnetization mixed bubble generator disclosed in application number CN202111127538.5, the micro-nano bubble generation system 4 in the form of a honeycomb can refer to a micro-nano bubble generation system 4 disclosed in application number CN202122265713.9, and the micro-nano bubble generation system has the function of stabilizing the size of micro-nano bubbles and can enable the size of micro-nano bubbles to be stabilized within the range of 0-50 mu m.
Notably, are:
the micro-nano bubble cleaning cultural relics mainly depend on strong energy generated when bubbles break down in a dynamic state, and a part of dirt layers on the surface of the cultural relics are peeled off, dispersed, emulsified and shed under the action of shock waves.
In the present application: adding a proper amount of cleaning agent into the micro-nano bubble water, and combining ultrasonic waves under the dynamic disturbance state of the water body to clean harmful rust on the surface of the cultural relics. In the process, micro-nano bubbles are formed, grown and closed, high pressure is generated at the moment of cracking, and the instant high pressure is continuously generated by continuous cracking like a series of small 'explosion' to continuously impact the surface of the cultural relics, so that dirt on the surface of the cultural relics and in gaps is rapidly peeled off, and the aim of purifying the surface of the cultural relics is fulfilled. On one hand, the adsorption of dirt and the surface of a cleaning piece is destroyed, on the other hand, fatigue damage of a dirt layer can be caused to be refuted, the solid surface is scrubbed by vibration of gas type bubbles, once the dirt layer is slotted and drillable, the bubbles can enter the vibration to enable the dirt layer to fall off. The gaps and gaps between the dirt layer and the surface layer formed by impact are permeated, and the small bubbles are repeatedly acted on the dirt layer due to expansion and contraction, so that the dirt layer is peeled layer by layer, and bubbles continue to permeate inwards until the dirt layer is completely peeled. Meanwhile, the dissolution process of dirt can be enhanced by adding disturbance and a proper amount of cleaning agent, and the chemical force and the physical force are combined, so that the cleaning process is accelerated. Wherein the chemical action of the cleaning medium can accelerate the ultrasonic wave and micro-nano bubble cleaning effect.
The bronze cultural relics are sufficiently and thoroughly cleaned by combining micro-nano bubbles, ultrasonic waves and chemical reagents.
The lower the ultrasonic frequency is, the easier cavitation is generated in the liquid, the larger the generated force is, the stronger the effect is, the ultrasonic cleaning device is suitable for coarse, dirty and primary cleaning of workpieces, the higher the frequency is, the stronger the ultrasonic directivity is, and the ultrasonic cleaning device is more suitable for cleaning fine objects.
In the present application: two or more than three transducers with different frequencies are arranged in the ultrasonic cleaning water tank 7, and the transducers with the respective frequencies are respectively pushed by a plurality of generators. When the operating frequency of the ultrasonic cleaning tank 7 is high, the cavitation density is high when the liquid cavitation intensity is low, and the opposite is true when the operating frequency is low. The low-frequency ultrasonic wave has high intensity, is beneficial to cleaning the surface of an object, has high cavitation density, and can penetrate through the fine structures such as grooves, slits, deep holes and the like. Meanwhile, the ultrasonic cleaning water tank 7 has ultrasonic waves with various frequencies, and the problem of uneven cleaning caused by a single-frequency cleaning standing wave field is also solved. In addition, the sweep frequency and the frequency hopping cleaning can be selected to improve the sound field structure in the ultrasonic cleaning water tank 7. The sweep frequency solves the uneven standing wave field in the ultrasonic cleaning water tank 7, so that the cleaning is uniform. The frequency hopping and the multi-frequency are both carried out on high and low frequency cleaning, except that the frequency hopping is carried out by an ultrasonic transducer and an ultrasonic generator, the ultrasonic transducer has two resonant frequencies, continuous frequency change is carried out in the bandwidth of a first resonant point, then the frequency hopping is carried out in the other bandwidth, and the frequency sweeping cleaning is carried out alternately on high and low frequencies.
Finally, it is noted that the above embodiments are only for illustrating the technical solution of the present utility model and not for limiting the same, and although the present utility model has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications and equivalents may be made thereto without departing from the spirit and scope of the technical solution of the present utility model, which is intended to be covered by the scope of the claims of the present utility model.

Claims (7)

1. The device for nondestructively cleaning the bronze ware is characterized by comprising a liquid storage tank, a gas conveying pipeline, a micro-nano bubble generating system, a gas-liquid mixing pump, an ultrasonic cleaning water tank and a shunt assembly;
wherein, the liquid outlet of the liquid storage tank is communicated with the feed inlet of the gas-liquid mixing pump;
the gas outlet of the gas conveying pipeline is communicated with the feed inlet of the gas-liquid mixing pump;
the discharge port of the gas-liquid mixing pump is communicated with the feed port of the micro-nano bubble generation system, and the discharge port of the micro-nano bubble generation system is communicated with the flow dividing assembly;
the flow dividing assembly is arranged in the ultrasonic cleaning water tank.
2. A device for non-destructive cleaning of a bronze according to claim 1, wherein: the flow splitting assembly includes:
the gas distribution pipe rack is horizontally arranged at the bottom in the ultrasonic cleaning water tank, and a feed inlet of the gas distribution pipe rack is communicated with a discharge outlet of the micro-nano bubble generation system;
the cloth nozzles are communicated with the cloth air pipe frame, and the cloth nozzles are uniformly distributed at the top of the cloth air pipe frame.
3. A device for non-destructive cleaning of a bronze according to claim 2, wherein: the cloth gas pipe frame includes:
the first guide pipes are arranged at intervals, and any one of the first guide pipes is connected with a water inlet pipe which is used for being connected with a discharge port of the micro-nano bubble generation system;
the second guide pipes are multiple and distributed at intervals, the multiple second guide pipes are communicated between the two first guide pipes, and the multiple distribution nozzles are distributed on the multiple second guide pipes.
4. A device for non-destructive cleaning of a bronze according to claim 1, wherein: the micro-nano bubble generation system can be in a dissolved air tank form, a spiral form or a honeycomb form.
5. A device for non-destructive cleaning of a bronze according to claim 1, wherein: the liquid outlet of the liquid storage tank is communicated with the feed inlet of the gas-liquid mixing pump through a first connecting pipe, and a liquid flow control valve is arranged on the first connecting pipe.
6. A device for non-destructive cleaning of a bronze according to claim 1, wherein: and a pressure gauge is arranged at the discharge hole of the micro-nano bubble generation system in a matched mode.
7. The apparatus for non-destructive cleaning of a bronze according to claim 6, wherein: the discharge port of the micro-nano bubble generation system is communicated with the feed port of the gas distribution pipe frame through a liquid guide pipe, the pressure gauge is arranged on the liquid guide pipe, and the liquid guide pipe is further provided with a pressure control valve.
CN202321490709.5U 2023-06-12 2023-06-12 Device for nondestructively cleaning bronze ware Active CN220311158U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202321490709.5U CN220311158U (en) 2023-06-12 2023-06-12 Device for nondestructively cleaning bronze ware

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321490709.5U CN220311158U (en) 2023-06-12 2023-06-12 Device for nondestructively cleaning bronze ware

Publications (1)

Publication Number Publication Date
CN220311158U true CN220311158U (en) 2024-01-09

Family

ID=89425317

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202321490709.5U Active CN220311158U (en) 2023-06-12 2023-06-12 Device for nondestructively cleaning bronze ware

Country Status (1)

Country Link
CN (1) CN220311158U (en)

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