CN220194014U - Glycol rectification waste heat recovery and utilization system - Google Patents

Glycol rectification waste heat recovery and utilization system Download PDF

Info

Publication number
CN220194014U
CN220194014U CN202321644587.0U CN202321644587U CN220194014U CN 220194014 U CN220194014 U CN 220194014U CN 202321644587 U CN202321644587 U CN 202321644587U CN 220194014 U CN220194014 U CN 220194014U
Authority
CN
China
Prior art keywords
waste heat
communicated
glycol
tower
recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202321644587.0U
Other languages
Chinese (zh)
Inventor
邱增明
张士祥
张胜利
张道祥
郭海滨
许祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Zhengdakai New Materials Co ltd
Original Assignee
Sichuan Zhengdakai New Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Zhengdakai New Materials Co ltd filed Critical Sichuan Zhengdakai New Materials Co ltd
Priority to CN202321644587.0U priority Critical patent/CN220194014U/en
Application granted granted Critical
Publication of CN220194014U publication Critical patent/CN220194014U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The utility model relates to the field of waste heat recovery and utilization, and particularly discloses a glycol rectification waste heat recovery and utilization system, which comprises a first waste heat boiler communicated with a butanediol removal tower top, a second waste heat boiler communicated with a glycol refining tower top, a third waste heat boiler communicated with a glycol recovery tower top and a recovery steam pipe network, wherein the first waste heat boiler, the second waste heat boiler and the third waste heat boiler are all communicated with a recovery low-pressure steam pipe network, and the recovery steam pipe network is communicated with a steam user; the steam user comprises a methanol removal tower A reboiler, a methanol removal tower B feeding heater, an ethanol light removal tower reboiler and an ethanol refining tower reboiler. By adopting the technical scheme provided by the utility model, the technical problem that the waste heat of the tower top material of the glycol rectifying device is not recycled, so that energy is wasted in the prior art can be solved.

Description

Glycol rectification waste heat recovery and utilization system
Technical Field
The utility model relates to the field of waste heat recovery and utilization, in particular to a glycol rectification waste heat recovery and utilization system.
Background
The production method of the ethylene glycol mainly comprises two major types of petroleum routes and non-petroleum routes, wherein the petroleum routes are mature in process and wide in application, but are influenced by raw material price and sources, and the production cost is high; but not the synthesis gas in the petroleum route, and the method gradually reflects the advantages of wide and low raw material sources, short process flow, high technical economy and the like, and becomes a research hot spot for the current industrialized preparation of ethylene glycol.
In the process of preparing ethylene glycol from synthesis gas, impurities such as lower carboxylic acid and esters thereof, propylene glycol, butanediol and the like are introduced, and the prepared crude ethylene glycol is required to be rectified to obtain a final ethylene glycol product. Because ethylene glycol is easy to generate dehydration condensation reaction at higher temperature to generate diethylene glycol and triethylene glycol, the temperature is required to be controlled to be lower than 180 ℃ in the rectification operation, and the purity requirement of ethylene glycol products is high (more than 99.9%), a rectification device with multiple towers is often adopted to finish the rectification of crude ethylene glycol through multiple times of decompression.
In the ethylene glycol rectifying device, the butanediol removing tower has the functions of removing butanediol and other trace esters in crude ethylene glycol, the butanediol obtained at the tower top is mixed with ethylene glycol, the ethylene glycol is sent to an ethylene glycol recovery tower to recover the ethylene glycol therein, and the crude ethylene glycol at the tower bottom is pumped to an ethylene glycol refining tower; the ethylene glycol refining tower has the function of further removing light components and heavy components (mainly alcohols such as diethylene glycol, triethylene glycol and the like) in the crude ethylene glycol; the ethylene glycol recovery tower has the function of recovering ethylene glycol, and the mixture containing butanediol obtained from the tower top is sent to a tank area as light dihydric alcohol.
Because the tower top and tower bottom temperatures of the butanediol removing, glycol refining and glycol recycling towers are smaller, namely the tower top materials of the butanediol removing, glycol refining and glycol recycling towers are higher in temperature, water coolers are arranged at the tower tops of the butanediol removing, glycol refining and glycol recycling towers at present in order to reduce the temperature of the partial materials, and the partial high-temperature materials are cooled by adopting circulating water, so that a large amount of circulating water is consumed, the glycol production cost is higher, waste heat loss of the partial materials can be caused, the waste heat is not fully recycled, and the energy waste is caused.
Therefore, there is a need for a glycol rectification waste heat recovery and utilization system to recover and utilize the waste heat of the overhead material in the glycol rectification process, so as to reduce energy waste and reduce the production cost of glycol.
Disclosure of Invention
The utility model aims to provide a glycol rectification waste heat recovery and utilization system, which solves the technical problem that the waste heat of the tower top material of a glycol rectification device is not recovered and utilized, so that energy is wasted in the prior art.
In order to achieve the above purpose, the utility model adopts the following technical scheme:
a glycol rectification waste heat recovery and utilization system comprises a first waste heat boiler communicated with a butylene glycol removal tower top, a second waste heat boiler communicated with a glycol refining tower top, a third waste heat boiler communicated with a glycol recovery tower top and a recovery steam pipe network, wherein the first waste heat boiler, the second waste heat boiler and the third waste heat boiler are all communicated with a recovery low-pressure steam pipe network, and the recovery steam pipe network is communicated with a steam user.
The principle and the advantages of the scheme are as follows:
in actual application, materials (butanediol mixed with ethylene glycol) at the top of the butanediol removing tower pass through a first waste heat boiler, and the waste heat of the materials is recycled by the first waste heat boiler to produce steam; materials (mainly alcohols such as diethylene glycol, triethylene glycol and the like) at the top of the ethylene glycol refining tower pass through a second waste heat boiler, and the waste heat of the materials is recycled by the second waste heat boiler to produce steam; the materials (mixture containing butanediol) at the top of the glycol recovery tower pass through a third waste heat boiler, and the third waste heat boiler recovers and utilizes the waste heat of the materials to produce steam; and the steam produced by the first waste heat boiler, the second waste heat boiler and the third waste heat boiler is fed into a recovery steam pipe network and is conveyed to a steam user by the recovery steam pipe network for use by the steam user.
According to the scheme, the waste heat of materials at the top of each tower is recovered through the first waste heat boiler, the second waste heat boiler and the third waste heat boiler which are communicated with the butylene glycol removal tower, the ethylene glycol refining tower and the ethylene glycol recovery tower, and steam is produced by utilizing the waste heat for a steam user, namely, on the basis of not changing the structure of an original ethylene glycol rectifying device, the waste heat boiler is additionally arranged at each tower top, so that the recycling of the waste heat of the materials at the top of each tower can be realized, and the waste of energy sources is effectively avoided.
Before using this scheme to recycle the residual heat of the material at the top of the glycol rectifying device, the inventors have tried the following scheme: the method comprises the steps of respectively connecting a first waste heat boiler, a second waste heat boiler and a third waste heat boiler at the tops of a butanediol removal tower, an ethylene glycol refining tower and an ethylene glycol recovery tower, and correspondingly connecting the first waste heat boiler, the second waste heat boiler and the third waste heat boiler with a steam user one by one, so that steam produced by recycling waste heat of materials at the tops of the first waste heat boiler, the second waste heat boiler and the third waste heat boiler is supplied to the steam user one by one. But the inventors found in testing the protocol that: the waste heat quantity which can be recycled by the waste heat boilers positioned at different tower tops is different, so that the steam quantity generated by each waste heat boiler is different, and the steam quantity is difficult to match with the steam demand of a steam user when the waste heat boilers are supplied to the steam user one by one; and along with the promotion of glycol rectification process, the waste heat of the tower top material can change, so that the steam quantity which can be produced by the corresponding waste heat boiler fluctuates, and the stability of the steam quantity supplied by a steam user is difficult to ensure.
By adopting the scheme, the recovery steam pipe network is additionally arranged, the steam produced by recycling the waste heat of the corresponding tower top materials of the first waste heat boiler, the second waste heat boiler and the third waste heat boiler is firstly introduced into the recovery steam pipe network, and after the steam produced by each waste heat boiler is collected in the recovery steam pipe network, the steam is respectively supplied to each steam user, so that the stability of the steam quantity supplied to each steam user can be ensured; and the steam produced by each waste heat boiler is collected in the recovery steam pipe network and then is supplied in the same way, so that the quality (pressure and temperature) of the steam used by a steam user can be improved to be more stable, and stable process operation at the steam user can be ensured.
Preferably, as an improvement, the steam user comprises a methanol removal tower A reboiler, and the methanol removal tower A reboiler is communicated with the methanol removal tower A of the ethylene glycol rectifying device.
By adopting the scheme, steam generated by recycling waste heat of tower top materials of a butanediol removal tower, a glycol refining tower and a glycol recovery tower in the glycol rectifying device enters a recovery steam pipe network, and is fed to a methanol removal tower A in the glycol rectifying device through the recovery steam pipe network for being used by a reboiler of the methanol removal tower A, and partial external steam can be replaced by steam generated by recycling the waste heat of the glycol rectification, so that the using amount of the external steam is reduced, the overall energy consumption of the glycol rectification is reduced, and the production cost of the glycol is saved.
Preferably, as an improvement, the steam user further comprises a methanol removal tower B feeding heater, and the methanol removal tower B feeding heater is communicated with a methanol removal tower B of the ethylene glycol rectifying device.
By adopting the scheme, steam generated by the recovery of waste heat of materials at the top of a butylene glycol removal tower, a ethylene glycol refining tower and an ethylene glycol recovery tower in the ethylene glycol rectifying device enters a recovery steam pipe network, and is fed to a methanol removal tower B in the ethylene glycol rectifying device through the recovery steam pipe network for a methanol removal tower B feeding heater to use, and steam generated by the recovery of waste heat of ethylene glycol feeding can replace part of external steam, so that the using amount of external steam is further reduced, the overall energy consumption of ethylene glycol rectification is further reduced, and the production cost of ethylene glycol is saved.
Preferably, as an improvement, the steam user further comprises an ethanol light-removal tower reboiler, and the ethanol light-removal tower reboiler is communicated with the ethanol light-removal tower of the ethylene glycol rectifying device.
By adopting the scheme, the steam generated by the recovery of the waste heat of the materials at the top of the butanediol removing tower, the ethylene glycol refining tower and the ethylene glycol recovery tower in the ethylene glycol rectifying device enters the recovery steam pipe network, and is fed to the ethanol light removal tower in the ethylene glycol rectifying device through the recovery steam pipe network for the reboiler of the ethanol light removal tower to use, and the steam generated by the recovery of the waste heat of the ethylene glycol feeding can replace part of external steam, so that the using amount of the external steam is further reduced, the overall energy consumption of the ethylene glycol rectifying is further reduced, and the production cost of the ethylene glycol is saved.
Preferably, as an improvement, the steam user further comprises an ethanol refining tower reboiler, and the ethanol refining tower reboiler is communicated with the ethanol refining tower of the ethylene glycol rectifying device.
By adopting the scheme, the steam generated by the recovery of the waste heat of the materials at the top of the butanediol removal tower, the ethylene glycol refining tower and the ethylene glycol recovery tower in the ethylene glycol rectifying device enters the recovery steam pipe network, and is fed to the ethanol refining tower in the ethylene glycol rectifying device through the recovery steam pipe network for the reboiler of the ethanol refining tower to use, and the steam generated by the recovery of the waste heat of the ethylene glycol feeding can replace part of external steam, so that the using amount of the external steam is further reduced, the overall energy consumption of the ethylene glycol rectification is further reduced, and the production cost of the ethylene glycol is saved.
Preferably, as an improvement, the first waste heat boiler, the second waste heat boiler and the third waste heat boiler all adopt sintering type high-flux heat exchange tubes.
By adopting the scheme, the first waste heat boiler, the second waste heat boiler and the third waste heat boiler all adopt the sintering type high-flux heat exchange tubes, compared with the common heat exchange tubes, the sintering type high-flux heat exchange tubes can improve the heat exchange coefficients of the first waste heat boiler, the second waste heat boiler and the third waste heat boiler, so that the heat exchange coefficients of the first waste heat boiler, the second waste heat boiler and the third waste heat boiler reach more than twice that of the common heat exchange tubes, the utilization rate of the material waste heat at the top of the ethylene glycol rectifying device is improved, the waste of energy sources is further reduced, more steam is produced for the recycling of the ethylene glycol rectifying device, and the production cost is further saved.
Preferably, as an improvement, the methanol removal tower A reboiler, the methanol removal tower B feed heater, the ethanol light removal tower reboiler and the ethanol refining tower reboiler are all communicated with a lithium bromide refrigerating unit, the lithium bromide refrigerating unit is communicated with a deaerator, the deaerator is communicated with a boiler water pipe network, and the boiler water pipe network is communicated with a first waste heat boiler, a second waste heat boiler and a third waste heat boiler.
By adopting the scheme, the lithium bromide refrigerating unit is communicated with the steam user methanol removal tower A reboiler, the methanol removal tower B feed heater, the ethanol light removal tower reboiler and the ethanol refining tower reboiler, the steam condensate after being used by the steam user is introduced into the lithium bromide refrigerating unit, the low temperature water is further cooled after being prepared to form condensed water, then oxygen and other gases in the condensed water are removed by the deaerator, the deoxidized water is obtained and is introduced into the boiler water pipe network, and the boiler water pipe network supplies the condensed water to the first waste heat boiler, the second waste heat boiler and the third waste heat boiler for use, so that the cyclic use of water resources is realized, the resource consumption is reduced, and the production cost of ethylene glycol is further saved. The lithium bromide refrigerating unit is used for cooling the steam condensate after the steam user uses, so that the water resource can be reused, the lithium bromide refrigerating unit can be used for preparing low-temperature water by utilizing the waste heat in the steam, and the waste of energy sources is further reduced.
Preferably, as an improvement, the recovery steam pipe network is communicated with an external steam pipe network, and the external steam pipe network is communicated with an external steam source.
By adopting the scheme, the external steam pipe network is communicated on the recovery steam pipe network, when the glycol rectifying device is in an on-off or fault state and the steam yield is unstable, the external steam pipe network is utilized to convey the steam of the external steam source into the recovery steam pipe network, the unstable steam quantity in the recovery steam pipe network is supplemented, the stability of the recovery steam pipe network for the steam user to supply the steam quantity can be ensured, and thus the stable process operation of the steam user is ensured.
Drawings
Fig. 1 is a schematic structural diagram of embodiment 1 of the present utility model.
Detailed Description
The following is a further detailed description of the embodiments:
reference numerals in the drawings of the specification include: 1 butanediol removing tower, 2 ethylene glycol refining tower, 3 ethylene glycol recovery tower, 4 first waste heat boiler, 5 second waste heat boiler, 6 third waste heat boiler, 7 recovery steam pipe network, 8 methanol removing tower A reboiler, 9 methanol removing tower B feeding heater, 10 ethanol light tower reboiler, 11 ethanol refining tower reboiler.
Example 1
A glycol rectification waste heat recovery and utilization system is shown in figure 1, and comprises a first waste heat boiler 4 communicated with the top of a butylene glycol removal tower 1 through a pipeline, a second waste heat boiler 5 communicated with the top of a glycol refining tower 2 through a pipeline, a third waste heat boiler 6 communicated with the top of a glycol recovery tower 3 through a pipeline and a recovery steam pipe network 7, wherein the first waste heat boiler 4, the second waste heat boiler 5 and the third waste heat boiler 6 are all communicated with a recovery low-pressure steam pipe network, and the recovery steam pipe network 7 is communicated with a steam user.
In this embodiment, the steam user includes a methanol removal tower a reboiler 8, a methanol removal tower B feed heater 9, an ethanol light removal tower reboiler 10, and an ethanol purification tower reboiler 11, wherein the methanol removal tower a reboiler 8 is communicated with a methanol removal tower a of the ethylene glycol rectification device, the methanol removal tower B feed heater 9 is communicated with a methanol removal tower B of the ethylene glycol rectification device, the ethanol light removal tower reboiler 10 is communicated with an ethanol light removal tower of the ethylene glycol rectification device, and the ethanol purification tower reboiler 11 is communicated with an ethanol purification tower of the ethylene glycol rectification device.
In this embodiment, the first waste heat boiler 4, the second waste heat boiler 5 and the third waste heat boiler 6 all adopt sintering type high flux heat exchange tubes, and compared with the common heat exchange tubes, the heat exchange efficiency can reach more than twice. The recovery steam pipe network 7 can be communicated with other steam users in the glycol rectification process and is used for supplying steam to the recovery steam pipe network, so that the glycol rectification energy consumption is further reduced, and the production cost is saved; the recovery steam pipe network 7 can be communicated with an external steam user even and is used for treating the steam which is not used up by the glycol rectifying device, so that energy waste is avoided.
The specific implementation process is as follows:
waste heat recovery and utilization: the material (butanediol mixed with ethylene glycol) at the top of the butanediol removal tower 1 passes through a first waste heat boiler 4, and the waste heat of the material is recycled by the first waste heat boiler 4 to produce steam; materials (mainly alcohols such as diethylene glycol, triethylene glycol and the like) at the top of the ethylene glycol refining tower 2 pass through a second waste heat boiler 5, and the waste heat of the materials is recycled by the second waste heat boiler 5 to produce steam; the materials (mixture containing butanediol) at the top of the glycol recovery tower 3 pass through a third waste heat boiler 6, and the third waste heat boiler 6 is used for producing steam by recycling the waste heat; the steam produced by the first waste heat boiler 4, the second waste heat boiler 5 and the third waste heat boiler 6 is all led into a recovery steam pipe network 7.
Steam feed use: the recovery steam pipe network 7 respectively supplies the steam collected from the first waste heat boiler 4, the second waste heat boiler 5 and the third waste heat boiler 6 to a methanol removal tower A reboiler 8, a methanol removal tower B feeding heater 9, an ethanol light removal tower reboiler 10 and an ethanol refining tower reboiler 11 in the ethylene glycol rectifying device for the steam users of the ethylene glycol rectifying device, and the steam produced by recycling the waste heat of the ethylene glycol rectification replaces part of external steam, so that the use amount of the external steam is reduced, the whole energy consumption of the ethylene glycol rectification can be reduced, and the ethylene glycol production cost is saved.
Example 2
The difference between the glycol rectification waste heat recovery and utilization system and the embodiment 1 is that: the recovery steam pipe network 7 is communicated with an external steam pipe network, and the external steam pipe network is communicated with an external steam source. Specifically, the external steam source may adopt a steam generator, a steam boiler, etc., which is the prior art, and this embodiment will not be described in detail.
According to the scheme, the external steam pipe network is communicated with the recovery steam pipe network 7, when the glycol rectifying device is in an on-off or fault state and the steam yield is unstable, the external steam pipe network is utilized to convey steam of an external steam source into the recovery steam pipe network 7, the unstable steam quantity in the recovery steam pipe network 7 is supplemented, the stability of the recovery steam pipe network 7 for supplying the steam quantity to a steam user can be guaranteed, and therefore stable process operation of the steam user is guaranteed.
Example 3
The difference between the glycol rectification waste heat recovery and utilization system and the embodiment 1 is that: the reboiler of the methanol removal tower A, the feed heater of the methanol removal tower B, the reboiler 10 of the ethanol removal tower and the reboiler 11 of the ethanol refining tower are all communicated with a lithium bromide refrigerating unit through pipelines, the lithium bromide refrigerating unit is communicated with a deaerator through pipelines, the deaerator is communicated with a boiler water pipe network, and the boiler water pipe network is communicated with the first waste heat boiler 4, the second waste heat boiler 5 and the third waste heat boiler 6.
In the scheme, the steam condensate after being used by a steam user is introduced into a lithium bromide refrigerating unit, the low-temperature water is prepared and then is further cooled to form condensate water, then oxygen and other gases in the condensate water are removed through a deaerator, the obtained deoxidized water is introduced into a boiler water pipe network, and the boiler water pipe network supplies the condensate water to a first waste heat boiler, a second waste heat boiler and a third waste heat boiler for use, so that the cyclic use of water resources is realized, the resource consumption is reduced, and the production cost of ethylene glycol is further saved. The lithium bromide refrigerating unit is used for cooling the steam condensate after the steam user uses, so that the water resource can be reused, the lithium bromide refrigerating unit can be used for preparing low-temperature water by utilizing the waste heat in the steam, and the waste of energy sources is further reduced.
The foregoing is merely exemplary of the present utility model, and specific technical solutions and/or features that are well known in the art have not been described in detail herein. It should be noted that, for those skilled in the art, several variations and modifications can be made without departing from the technical solution of the present utility model, and these should also be regarded as the protection scope of the present utility model, which does not affect the effect of the implementation of the present utility model and the practical applicability of the patent. The protection scope of the present application shall be subject to the content of the claims, and the description of the specific embodiments and the like in the specification can be used for explaining the content of the claims.

Claims (8)

1. A glycol rectification waste heat recovery and utilization system is characterized in that: the system comprises a first waste heat boiler communicated with the top of a butanediol removing tower, a second waste heat boiler communicated with the top of a glycol refining tower, a third waste heat boiler communicated with the top of a glycol recovery tower and a recovery steam pipe network, wherein the first waste heat boiler, the second waste heat boiler and the third waste heat boiler are all communicated with a recovery low-pressure steam pipe network, and the recovery steam pipe network is communicated with a steam user.
2. The glycol distillation waste heat recovery and utilization system according to claim 1, wherein: the steam user comprises a methanol removal tower A reboiler which is communicated with a methanol removal tower A of the glycol rectifying device.
3. The glycol distillation waste heat recovery and utilization system according to claim 2, wherein: the steam user also comprises a methanol removal tower B feeding heater which is communicated with the methanol removal tower B of the glycol rectifying device.
4. A glycol rectification waste heat recovery and utilization system according to claim 3, wherein: the steam user also comprises an ethanol light component removing tower reboiler which is communicated with the ethanol light component removing tower of the glycol rectifying device.
5. The glycol distillation waste heat recovery and utilization system according to claim 4, wherein: the steam user also comprises an ethanol refining tower reboiler which is communicated with the ethanol refining tower of the glycol rectifying device.
6. The glycol distillation waste heat recovery and utilization system according to claim 5, wherein: the first waste heat boiler, the second waste heat boiler and the third waste heat boiler all adopt sintering type high-flux heat exchange tubes.
7. The glycol distillation waste heat recovery and utilization system according to claim 6, wherein: the reboiler of the methanol removal tower A, the feed heater of the methanol removal tower B, the reboiler of the ethanol removal tower and the reboiler of the ethanol refining tower are all communicated with a lithium bromide refrigerating unit, the lithium bromide refrigerating unit is communicated with a deaerator, the deaerator is communicated with a boiler water pipe network, and the boiler water pipe network is communicated with a first waste heat boiler, a second waste heat boiler and a third waste heat boiler.
8. The glycol distillation waste heat recovery and utilization system according to any one of claims 1-7, wherein: the recovery steam pipe network is communicated with an external steam pipe network, and the external steam pipe network is communicated with an external steam source.
CN202321644587.0U 2023-06-26 2023-06-26 Glycol rectification waste heat recovery and utilization system Active CN220194014U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202321644587.0U CN220194014U (en) 2023-06-26 2023-06-26 Glycol rectification waste heat recovery and utilization system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321644587.0U CN220194014U (en) 2023-06-26 2023-06-26 Glycol rectification waste heat recovery and utilization system

Publications (1)

Publication Number Publication Date
CN220194014U true CN220194014U (en) 2023-12-19

Family

ID=89137562

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202321644587.0U Active CN220194014U (en) 2023-06-26 2023-06-26 Glycol rectification waste heat recovery and utilization system

Country Status (1)

Country Link
CN (1) CN220194014U (en)

Similar Documents

Publication Publication Date Title
CN102660340B (en) Process and equipment for converting carbon dioxide in flue gas into natural gas by using dump power energy
CN214496146U (en) New energy electrolytic hydrogen production and carbon capture combined methanol production system
CN111302896A (en) Renewable energy methanol synthesis system of thermal power plant
CN104086371B (en) The processing method that in the cyclohexene method preparing cyclohexanone production process, hexalin is separated
CN103467248B (en) A kind of energy-saving ester through hydrogenation technique
CN111592446A (en) Rectification system and process for preparing ethylene glycol by dimethyl oxalate hydrogenation
CN105693467A (en) Energy-saving production method of pentaerythritol
CN114669073A (en) 1,4-butanediol multi-effect rectification device system and multi-effect rectification process
CN110862839A (en) System and method for co-production of methanol from coal-based natural gas
CN220194014U (en) Glycol rectification waste heat recovery and utilization system
CN108083984A (en) For glyphosate solvent and the method for by-product recovery
CN104844414A (en) Equipment and process for recovering glyphosate solvent during production with glycine method
CN107089901A (en) A kind of 1,4 butynediols purification systems
CN113563148B (en) Coal-to-natural gas and methanol poly-generation system and method integrating waste heat refrigeration
CN116143078A (en) System and method for recycling hydrogen chloride in polycrystalline silicon tail gas
CN207451978U (en) A kind of device using carbon dioxide production n-propyl acetate
CN113546438A (en) Heat integration system and method for gas-steam combined cycle, methanol synthesis and five-tower rectification
CN211284557U (en) Production system for producing hydrogen and oxygen by using distilled water through electrolysis
CN212357095U (en) Renewable energy methanol synthesis system of thermal power plant
CN204111354U (en) A kind of sour water steam stripping at reduced pressure device
CN110090543B (en) Continuous CH separation by fluidized bed4/CO2Method (2)
CN111848401A (en) Device and process for refining dimethyl carbonate by energy coupling with partition wall tower
CN105037078A (en) Method for recovering dichloromethane in chlorone mother liquid
CN217511198U (en) Four-tower heat pump thermal coupling methanol rectification device
CN218608101U (en) Double-hot-trap five-tower countercurrent triple-effect methanol rectifying device

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant