CN220012396U - High-organic matter high-salt-content industrial wastewater treatment system - Google Patents

High-organic matter high-salt-content industrial wastewater treatment system Download PDF

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CN220012396U
CN220012396U CN202321375773.9U CN202321375773U CN220012396U CN 220012396 U CN220012396 U CN 220012396U CN 202321375773 U CN202321375773 U CN 202321375773U CN 220012396 U CN220012396 U CN 220012396U
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tank
water
industrial wastewater
organic matter
enters
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裴元虎
李梦坤
李江涛
王洁琳
黄艳霞
刘浩冉
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Qingshuiyuan Shanghai Environmental Technology Co ltd
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Qingshuiyuan Shanghai Environmental Technology Co ltd
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Abstract

The utility model relates to a high organic matter and high salt content industrial wastewater treatment system which comprises a regulating tank, a coagulating sedimentation tank, a hydrolysis acidification tank, a QSYB tank, a middle water tank, an ion exchange system, a nanofiltration system, a collecting tank, a double-effect evaporation tank, a recycling water tank, a centrifuge, a collecting tank, a drying system and a recycling water tank which are connected in sequence. Compared with the prior art, the method has the advantages of simple process, high recycling utilization rate, low energy consumption and zero emission.

Description

High-organic matter high-salt-content industrial wastewater treatment system
Technical Field
The utility model relates to the field of industrial wastewater treatment, in particular to a high-organic-content high-salt industrial wastewater treatment system.
Background
Certain high-organic matter and high-salt wastewater is often generated in the modern industrial production process, and is directly discharged to the outside without treatment, so that water resources are seriously damaged, and a lot of potential resources are wasted.
Along with the continuous update of modern industrial production technology, the components of industrial wastewater are more complex and various, and the problems of low purity of crystalline salt, high energy consumption, high cost and the like exist in the practical engineering application by utilizing the traditional high-salt wastewater zero discharge technology.
Therefore, the development of a processing system with simple process, high resource utilization rate, low energy consumption and zero emission is particularly important.
Disclosure of Invention
The utility model aims to overcome the defects of the prior art and provide the high-organic matter and high-salt industrial wastewater treatment system with simple process, high recycling utilization rate, low energy consumption and zero emission.
The aim of the utility model can be achieved by the following technical scheme:
the utility model provides a high-organic matter high-salt-content industrial wastewater treatment system, which comprises a regulating tank, a coagulating sedimentation tank, a hydrolysis acidification tank, a QSYB tank, a middle water tank, an ion exchange system, a nanofiltration system, a first collecting tank and a double-effect evaporation tank which are sequentially connected, and also comprises a centrifuge, a second collecting tank, a drying system and a second recycling water tank which are sequentially connected;
the drying system utilizes a low-temperature evaporation crystallization technology to finally and completely solidify sodium sulfate salt in incoming water, and the produced water enters a second reuse water tank to be used as factory production water;
the sludge from the coagulating sedimentation tank to the sludge hopper and the residual sludge from the hydrolytic acidification tank and the QSYB tank are discharged to a sludge tank, and are conveyed to a plate-and-frame filter press through a feed pump to be dewatered, and filtered liquid is conveyed to an adjusting tank again.
Preferably, the regulating tank is used for balancing the water quality and the water quantity of the high-organic-content high-salt chemical wastewater, and the high-organic-content high-salt chemical wastewater is lifted to the coagulating sedimentation tank through the water pump.
Preferably, the coagulating sedimentation tank comprises a hardness removal reaction zone, a coagulating zone, a flocculation zone, an inclined plate sedimentation zone and a neutralization zone which are connected in sequence.
Preferably, a strain for improving the biodegradability of the industrial wastewater is put into the hydrolysis acidification tank, and the strain is used for converting the macromolecular substances difficult to biodegrade into the micromolecular substances easy to biodegrade by hydrolyzing insoluble organic substances in the industrial wastewater into soluble organic substances.
Preferably, the bacterial species include hydrolytic bacteria and acidifying bacteria.
Preferably, the QSYB pool removes organic pollutants in water by using a clean water source biological strengthening technology, and the effluent enters a middle pool, is lifted to an ion exchange system for further softening and then enters a nanofiltration system.
Preferably, the outlet water of the nanofiltration system enters a recycling water tank, the concentrated water enters a first collecting tank, and the concentrated water is lifted to a double-effect evaporation tank through a water pump.
Preferably, the effluent of the double-effect evaporation pond enters a first recycling pond, concentrated solution enters a centrifugal machine, sodium sulfate salt is crystallized after repeated reflux evaporation treatment, and final mother solution enters a second collection pond and then enters a drying system through a lifting pump.
Compared with the prior art, the utility model has the following advantages:
according to the utility model, the efficient selective ion separation nanofiltration membrane is organically combined with the double-effect evaporation and concentration drying technology, and the sodium sulfate salt in the wastewater is finally and completely solidified and is recycled as industrial salt, so that the obtained condensate is reused for factory production water, zero emission is realized, and the method has the advantages of simple process, simplicity in operation, low energy consumption and zero emission, high recycling utilization rate, low overall operation cost, stable treatment effect, better water outlet index and the like.
Drawings
FIG. 1 is a schematic diagram of a system architecture of the present utility model;
reference numerals: 1-adjusting tank, 2-coagulating sedimentation tank, 3-hydrolytic acidification tank, 4-QSYB tank, 5-middle water tank, 6-ion exchange system, 7-nanofiltration system, 8-reuse water tank, 9-first collecting tank, 10-double effect evaporation tank, 11-first reuse water tank, 12-centrifuge, 13-second collecting tank, 14-drying system, 15-second reuse water tank, 16-sludge tank and 17-plate-and-frame filter press.
Detailed Description
The following description of the embodiments of the present utility model will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are some, but not all embodiments of the utility model. All other embodiments, which can be made by those skilled in the art based on the embodiments of the present utility model without making any inventive effort, shall fall within the scope of the present utility model.
Examples
The embodiment provides a high organic matter high salt industrial wastewater treatment system, which comprises a regulating tank 1, a coagulating sedimentation tank 2, a hydrolysis acidification tank 3, a QSYB tank 4, a middle water tank 5, an ion exchange system 6, a nanofiltration system 7, a first collecting tank 9, a double-effect evaporation tank 10 and a first recycling water tank 11 which are sequentially connected, and further comprises a centrifugal machine 12, a second collecting tank 13, a drying system 14 and a second recycling water tank 15 which are sequentially connected.
The regulating tank 1 is used for balancing the water quality and the water quantity of the high-organic-content high-salt chemical wastewater, and the high-organic-content high-salt chemical wastewater is lifted to the coagulating sedimentation tank 2 through a water pump.
The coagulating sedimentation tank 2 comprises a hard removing reaction zone, a coagulating zone, a flocculating zone, an inclined plate sedimentation zone and a neutralization zone which are connected in sequence.
Strains (such as hydrolytic bacteria and acidizing bacteria) for improving the biodegradability of the industrial wastewater are put into the hydrolytic acidification tank 3, and are used for converting the macromolecular substances which are difficult to biodegrade into the micromolecular substances which are easy to biodegrade by hydrolyzing insoluble organic substances in the industrial wastewater into soluble organic substances.
The QSYB pool 4 removes organic pollutants in water by using a clean water source biological strengthening technology, and the water enters the middle pool 5, is lifted to the ion exchange system 6 to be further softened, and then enters the nanofiltration system 7.
The effluent of the nanofiltration system 7 enters a recycling water tank 8, the concentrated water enters a first collecting tank 9, and the concentrated water is lifted to a double-effect evaporation tank 10 by a water pump.
The effluent of the double-effect evaporation pond 10 enters a first recycling pond 11, concentrated solution enters a centrifugal machine 12, sodium sulfate salt is crystallized after repeated reflux evaporation treatment, and final mother solution enters a second collection pond 13 and then enters a drying system 14 through a lifting pump.
The drying system 14 utilizes a low-temperature evaporation crystallization technology to finally completely solidify sodium sulfate salt in the incoming water, and the produced water enters the second reuse water tank 15 to be used as factory production water.
The sludge settled in the coagulating sedimentation tank 2 to the sludge hopper and the residual sludge in the hydrolytic acidification tank 3 and the QSYB tank 4 are discharged to a sludge tank 16, and are conveyed to a plate-and-frame filter press 17 through a feed pump to dewater the sludge, and the filtered liquid is conveyed to the regulating tank 1 again.
In the embodiment, industrial wastewater of a certain chemical plant is used as a treatment object, wherein the COD content is 1000mg/L, the calcium sulfate content is 3000mg/L, and the specific treatment process is as follows:
1) The content of calcium sulfate in the industrial wastewater is 3000mg/L, and the industrial wastewater is lifted to a coagulating sedimentation tank through a water pump after being collected and balanced by an adjusting tank.
2) Adding sodium carbonate into a hard removing reaction area of a coagulating sedimentation tank, stirring by using a stirrer, wherein the rotating speed is 80rpm, the reaction time is 15min, calcium ions generate calcium carbonate sediment, the calcium carbonate sediment further flows into a coagulating area, adding a coagulant PAC, stirring by using the stirrer, the rotating speed is 80rpm, the reaction time is 15min, suspended matters in water and the coagulant are fully contacted and reacted to form alum flowers, the alum flowers further flow into a flocculation area, adding a flocculating agent PAM to assist the flocculation, stirring by using the stirrer, the rotating speed is 40rpm, the reaction time is 30min, the flocculation of the alum flowers is increased through net capturing, the formed large floccules flow through an inclined plate sedimentation area to complete solid-liquid separation, the precipitated sludge is discharged into a mud bucket, the total hardness in supernatant is reduced to 200mg/L, the COD is reduced to 720mg/L, the pH value is adjusted back to 7-9 by adding sulfuric acid, and then conveying the sulfuric acid to a hydrolysis acidification tank by using a lifting pump.
3) After the biodegradability is improved by the hydrolysis acidification tank, wastewater automatically flows into a QSYB tank for biochemical treatment, and the COD of the effluent is reduced to 150mg/L.
4) The effluent of the QSYB pool automatically flows into an intermediate pool, then is lifted to an ion exchange system by a water pump to further soften the water quality, weak acid cation exchange resin is adopted, the operating pressure of a resin tank is 0.6MPa, the operating filtering speed is 25m/h, the backwashing flow rate is 15m/h, and the conductivity of the effluent is 5000 mu S/cm.
5) The effluent of the resin tank enters the nanofiltration system through a nanofiltration water supply pump, and the forced circulation technology of concentrated water is adopted, so that the water inlet stability and recovery rate of the system are fully ensured. The nanofiltration system adopts a primary three-stage treatment process, the conductivity of the inflow water is 5000 mu S/cm, the water yield and the conductivity of the produced water are reduced to 1000 mu S/cm after the treatment of the first two sections of membranes, and the conductivity of the concentrated water is 30000 mu S/cm; concentrated water of the second section nanofiltration device enters a third section to be continuously concentrated, the water conductivity of the third section is 2000 mu S/cm, and the concentrated water conductivity is 45000 mu S/cm. The overall recovery rate of the nanofiltration system is up to 87.62 percent, and the nanofiltration system is directly recycled for production.
6) And the final concentrated solution of the nanofiltration system is conveyed to a double-effect evaporation system through a lifting water pump, and the steam supply amount is 600kg/h of low-pressure saturated steam. Each effect concentrated solution adopts a forced circulation process, sodium sulfate is crystallized through repeated reflux evaporation treatment, the water content is less than or equal to 20%, and the final mother solution enters a drying system for further evaporation; the TDS of the double-effect condensate is less than 1000mg/L and is reused as the production water.
7) The drying system adopts a low-temperature evaporation crystallization technology, deslagging is carried out for 10-15min, feeding is carried out for 2-4min, evaporation is carried out for 60-80min, the pressure of compressed air is above 0.4Mpa, the working vacuum degree is about-90 to-96 kpa, the evaporation temperature is about 37 ℃, and the system is fully-automatic to operate. The low-temperature evaporation drying system effectively separates the salt in the concentrated solution, and finally the salt in the wastewater is completely solidified, so that the moisture content is less than or equal to 10%, and the packaging, transportation and recycling are facilitated. The TDS of condensate of the drying system is less than 1000mg/L, and the condensate is reused for production water, thereby realizing zero emission.
8) The method comprises the steps of setting sludge in a coagulating sedimentation tank to a sludge hopper, discharging residual sludge in a hydrolytic acidification tank and a QSYB tank to a sludge tank, conveying the residual sludge to a plate-and-frame filter press through a feed pump, dehydrating the sludge, arranging a pressure transmitter at a liquid inlet pipeline of the filter press to judge the full state of the inner volume of a filter plate of the filter press through pressure parameters, determining the stop of a filter press pump, and improving the automation degree, wherein the water content of the dehydrated sludge is less than 40%. The filtered liquid is returned to the regulating tank for further treatment.
While the utility model has been described with reference to certain preferred embodiments, it will be understood by those skilled in the art that various changes and substitutions of equivalents may be made and equivalents will be apparent to those skilled in the art without departing from the scope of the utility model. Therefore, the protection scope of the utility model is subject to the protection scope of the claims.

Claims (7)

1. The high-organic matter high-salt-content industrial wastewater treatment system is characterized by comprising an adjusting tank (1), a coagulating sedimentation tank (2), a hydrolysis acidification tank (3), a QSYB tank (4), an intermediate water tank (5), an ion exchange system (6), a nanofiltration system (7), a first collecting tank (9), a double-effect evaporation tank (10) and a first recycling water tank (11) which are connected in sequence, and further comprising a centrifuge (12), a second collecting tank (13), a drying system (14) and a second recycling water tank (15) which are connected in sequence;
the water discharged from the nanofiltration system (7) enters a recycling water tank (8) arranged, the concentrated water enters a first collecting tank (9), and the concentrated water is lifted to a double-effect evaporation tank (10) through a water pump;
the effluent of the double-effect evaporation pond (10) enters a first recycling pond (11), concentrated solution enters a centrifugal machine (12), sodium sulfate salt is crystallized after repeated reflux evaporation treatment, final mother solution enters a second collection pond (13), and then enters a drying system (14) through a lifting pump.
2. The high organic matter high salt content industrial wastewater treatment system according to claim 1, wherein the regulating tank (1) is used for balancing the water quality and the water quantity of the high organic matter high salt content chemical wastewater, and the high organic matter high salt content chemical wastewater is lifted to the coagulating sedimentation tank (2) through a water pump.
3. The high organic matter high salt content industrial wastewater treatment system according to claim 1, wherein the coagulating sedimentation tank (2) comprises a hardness removal reaction zone, a coagulating zone, a flocculation zone, an inclined plate sedimentation zone and a neutralization zone which are connected in sequence.
4. The high-organic matter high-salt-content industrial wastewater treatment system according to claim 1, wherein a strain for improving the biodegradability of the industrial wastewater is put into the hydrolysis acidification tank (3) and is used for converting a large molecular substance difficult to biodegrade into a small molecular substance easy to biodegrade by hydrolyzing insoluble organic matters in the industrial wastewater into soluble organic matters.
5. The high organic matter and high salt content industrial wastewater treatment system according to claim 1, wherein the QSYB tank (4) removes organic pollutants in water by using a clean water source biological strengthening technology, and the effluent enters an intermediate water tank (5) and then enters a nanofiltration system (7) after being lifted to an ion exchange system (6) for further softening.
6. The high-organic matter high-salt-content industrial wastewater treatment system according to claim 1, wherein the drying system (14) utilizes a low-temperature evaporation crystallization technology to completely solidify sodium sulfate salt in incoming water, and the produced water enters a second reuse water tank (15) as factory production water.
7. The high organic matter and high salt content industrial wastewater treatment system according to claim 1, wherein the sludge settled to the sludge hopper in the coagulating sedimentation tank (2) and the residual sludge in the hydrolysis acidification tank (3) and the QSYB tank (4) are discharged to a sludge tank (16) which is arranged, and are conveyed to a plate-and-frame filter press (17) which is arranged through a feed pump to carry out sludge dewatering, and filtered liquid is conveyed to the regulating tank (1) again.
CN202321375773.9U 2023-05-31 2023-05-31 High-organic matter high-salt-content industrial wastewater treatment system Active CN220012396U (en)

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Application Number Priority Date Filing Date Title
CN202321375773.9U CN220012396U (en) 2023-05-31 2023-05-31 High-organic matter high-salt-content industrial wastewater treatment system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321375773.9U CN220012396U (en) 2023-05-31 2023-05-31 High-organic matter high-salt-content industrial wastewater treatment system

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CN220012396U true CN220012396U (en) 2023-11-14

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