CN219099044U - Multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material - Google Patents

Multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material Download PDF

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CN219099044U
CN219099044U CN202223517700.7U CN202223517700U CN219099044U CN 219099044 U CN219099044 U CN 219099044U CN 202223517700 U CN202223517700 U CN 202223517700U CN 219099044 U CN219099044 U CN 219099044U
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layer
adhesive
self
thermoplastic polyolefin
multilayer
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马双
郑宪明
张奉勇
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Dayu Waterproof Building Materials Group Co ltd
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Liaoning Dayu Waterproof Technology Development Co ltd
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Abstract

The utility model provides a multilayer co-extrusion thermoplastic polyolefin self-adhesion composite waterproof coiled material, which comprises a central shaft, wherein a coiled material main body is wound on the outer wall of the central shaft, the coiled material main body comprises a co-extrusion layer, a self-adhesion layer and a separation film layer which are sequentially connected, and the co-extrusion layer comprises a thermoplastic polyolefin layer, a first adhesion layer, a barrier layer and a second adhesion layer which are sequentially connected. The second bonding layer plays a role of a bonding medium between the blocking layer and the self-adhesive layer, increases the adhesive force between the main material and the self-adhesive layer, further increases the integrity of the coiled material, obviously reduces the detachment phenomenon between the material and the base material, improves the interlayer composite effect when the material is exposed and used, and enhances the overall waterproof effect of the material; the second adhesive layer is a substance with high cohesive force, and even if the plasticizer in the adhesive layer migrates into the material adhesive layer, the cohesive force of the second adhesive layer is not obviously reduced, so that the waterproof and adhesive effects of the material can be ensured, and the integrity of the material is ensured.

Description

Multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material
Technical Field
The utility model relates to the technical field of waterproof coiled materials, in particular to a multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material.
Background
Thermoplastic Polyolefin (TPO) waterproof coiled materials have good physical properties and excellent ageing resistance. The joint edges can be welded into a whole through hot air, so that the waterproof material has good integrity and is a novel high polymer waterproof material. There are generally homogeneous, backing and in-fabric reinforcement. With the development of the waterproof industry in recent years, more composite waterproof solutions are developed, and some of the waterproof solutions are compounded with asphalt-based self-adhesive coiled materials, some of the waterproof solutions are compounded with non-asphalt-based high-polymer hot-melt pressure-sensitive adhesives, and some of the waterproof solutions are compounded with butyl adhesives. The composite waterproof solutions can effectively improve the bonding capability between materials and other waterproof coiled materials or between the materials and a base surface, and can enhance the waterproof effect. A portion of Thermoplastic Polyolefin (TPO) waterproof rolls are also compounded with a coating (one-component polyurethane SPU or polymer cement JS waterproof coating) to form a roll composite waterproof system.
Whether asphalt-based hot melt adhesive, non-asphalt-based high polymer hot melt pressure-sensitive adhesive or butyl hot melt pressure-sensitive adhesive, a small amount of small molecular plasticizer is needed in the formula composition. Most of Thermoplastic Polyolefin (TPO) waterproof coiled materials are amorphous high molecular polymers, and most of molecular chain structures are amorphous and amorphous, if the waterproof coiled materials are not treated by proper technical measures, small molecular substances (oil or plasticizer) in a composite adhesive layer can easily enter a TPO layer through diffusion, so that the physical and mechanical properties of the TPO layer are reduced. The loss of small molecules can also change the components in the adhesive layer, so that the pressure sensitivity of the adhesive layer is reduced, and even the adhesive layer is lost. As can be seen, migration of small molecule oil is a very troublesome problem in composite waterproof rolls or waterproof systems.
Disclosure of Invention
Aiming at the defects of the prior art, the utility model provides a multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material, which solves the problems in the background art.
In order to achieve the above purpose, the utility model is realized by the following technical scheme:
the utility model provides a multilayer is crowded thermoplastic polyolefin self-adhesion composite waterproof coiled material altogether, includes the center pin, and the outer wall winding of center pin has the coiled material main part, and the coiled material main part is including the crowded layer of altogether, self-adhesion glue film, the barrier film layer that connect gradually, and the crowded layer of altogether is including the thermoplastic polyolefin layer, first adhesive linkage, barrier layer and the second adhesive linkage that connect gradually.
Further, the thermoplastic polyolefin layer has a thickness of 0.1 to 2.5mm.
Further, the thickness of the first bonding layer and the second bonding layer is 0.005-0.1mm.
Further, the thickness of the first adhesive layer is greater than the thickness of the second adhesive layer.
Further, the thickness of the barrier layer is 0.01-0.1mm.
Further, the thickness of the self-adhesive layer is 0.2-3mm.
Further, the rotating grooves are formed in the two ends of the central shaft, the assembly joints are embedded in the rotating grooves in a rotating mode, and each assembly joint is used for being connected with lifting equipment.
Further, the assembly joint comprises a first plate body, a second plate body and a hanging ring, the side section of the rotating groove is in a convex shape, the second plate body is concentrically arranged on the side surface of the first plate body, the first plate body and the second plate body are rotationally embedded in the rotating groove, and the hanging ring is vertically arranged on the outer wall of the second plate body.
The utility model provides a multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material. Compared with the prior art, the method has the following beneficial effects:
1. the second adhesive layer plays a role of an adhesive medium of the barrier layer and the self-adhesive layer, increases the adhesive force between the main material and the self-adhesive layer, further increases the integrity of the coiled material, remarkably reduces the separation phenomenon between the material and the base material, improves the composite effect of the material when the material is exposed and used, and enhances the overall waterproof effect of the material.
2. The second adhesive layer is a substance with high cohesive force, and even if the plasticizer in the adhesive layer migrates into the material adhesive layer, the cohesive force of the second adhesive layer is not obviously reduced, so that the waterproof and adhesive effects of the material can be ensured, and the integrity of the material is ensured.
Drawings
In order to more clearly illustrate the embodiments of the utility model or the technical solutions in the prior art, the drawings that are required in the embodiments or the description of the prior art will be briefly described, it being obvious that the drawings in the following description are only some embodiments of the utility model, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
Fig. 1 shows a schematic structural view of a multilayer co-extrusion self-adhesive composite waterproof roll of the utility model;
fig. 2 shows a schematic cross-sectional structure of the waterproof roll of the present utility model;
fig. 3 is a schematic view showing the connection structure of the central shaft and the waterproof roll of the present utility model;
FIG. 4 shows a schematic view of the fitting construction of the present utility model;
the figure shows: 1. a central shaft; 11. a rotary groove; 2. a coil body; 21. a thermoplastic polyolefin layer; 22. a first adhesive layer; 23. a barrier layer; 24. a second adhesive layer; 25. a self-adhesive layer; 251. a carcass layer; 252. a third adhesive layer; 26. an isolation film layer; 3. assembling a joint; 31. a first plate body; 32. a second plate body; 33. hanging rings.
Detailed Description
For the purpose of making the objects, technical solutions and advantages of the embodiments of the present utility model more clear, the technical solutions in the embodiments of the present utility model are clearly and completely described, and it is obvious that the described embodiments are some embodiments of the present utility model, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the utility model without making any inventive effort, are intended to be within the scope of the utility model.
Example 1
In order to solve the technical problems in the background technology, the following multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material is provided:
referring to fig. 1-4, the multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material provided by the utility model comprises a central shaft 1, wherein a coiled material main body 2 is wound on the outer wall of the central shaft 1, the coiled material main body 2 comprises a co-extrusion layer, a self-adhesive layer 25 and a separation film layer 26 which are sequentially arranged, and the co-extrusion layer is formed by compounding and co-extrusion of a thermoplastic polyolefin layer 21, a first adhesive layer 22, a separation layer 23 and a second adhesive layer 24; the adhesive layers include a carcass layer 251 and a third adhesive layer 252, the carcass layer 251 being connected to the second adhesive layer 24, the third adhesive layer 252 being connected to the barrier film layer 26.
In the embodiment, the co-extrusion layer and the self-adhesive layer are formed by roll extrusion;
in this embodiment, the thermoplastic polyolefin layer 21 is made by blending one or more of thermoplastic resin, polypropylene, polyethylene octene co-elastomer, thermoplastic polyolefin elastomer, olefin block copolymer, triblock copolymer material, polystyrene and terpolymer, and the thickness of the thermoplastic polyolefin layer 21 is 0.1mm;
in the present embodiment, the thickness of the first adhesive layer 22 is 0.1mm, and the thickness of the second adhesive layer 24 is 0.05mm; the first adhesive layer 22 and the second adhesive layer 24 are selected from one or a mixture of several of maleic anhydride grafted PE, maleic anhydride grafted PP, maleic anhydride grafted POE, maleic anhydride grafted SEBS, maleic anhydride grafted SEPS or maleic anhydride grafted EPDM.
In this embodiment, the barrier layer 23 is one or a blend of several of thermoplastic resin, polypropylene, polyamide (nylon PA), olefin plastic, polyvinylidene chloride, polyvinylidene fluoride, ethylene and vinyl alcohol copolymer (EVOH), and the thickness of the barrier layer 23 is 0.1mm.
In this embodiment, the self-adhesive layer 25 is one of asphalt-based self-adhesive, non-asphalt-based self-adhesive, and butyl adhesive, and has a thickness of 0.2mm.
Example two
As shown in fig. 1 to 3, on the basis of the above embodiment, the present embodiment further provides the following:
in the embodiment, the co-extrusion layer and the self-adhesive layer are formed by roll extrusion;
in this embodiment, the thermoplastic polyolefin layer 21 is made by blending one or more of thermoplastic resin, polypropylene, polyethylene octene co-elastomer, thermoplastic polyolefin elastomer, olefin block copolymer, triblock copolymer material, polystyrene and terpolymer, and the thickness of the thermoplastic polyolefin layer 21 is 2.5mm;
in the present embodiment, the thickness of the first adhesive layer 22 is 0.1mm, and the thickness of the second adhesive layer 24 is 0.05mm; the first adhesive layer 22 and the second adhesive layer 24 are selected from one or a mixture of several of maleic anhydride grafted PE, maleic anhydride grafted PP, maleic anhydride grafted POE, maleic anhydride grafted SEBS, maleic anhydride grafted SEPS or maleic anhydride grafted EPDM.
In this embodiment, the thickness of the barrier layer 23 is 0.01mm by using one or a blend of several of thermoplastic resin, polypropylene, polyamide (nylon PA), olefin plastic, polyvinylidene chloride, polyvinylidene fluoride, ethylene and vinyl alcohol copolymer (EVOH).
In this embodiment, the self-adhesive layer 25 is one of asphalt-based self-adhesive, non-asphalt-based self-adhesive, and butyl adhesive, and has a thickness of 3.00mm.
Example III
As shown in fig. 1 to 3, on the basis of the above embodiment, the present embodiment further provides the following:
in the embodiment, the co-extrusion layer and the self-adhesive layer are formed by blade coating;
in this embodiment, the thermoplastic polyolefin layer 21 is made by blending one or more of thermoplastic resin, polypropylene, polyethylene octene co-elastomer, thermoplastic polyolefin elastomer, olefin block copolymer, triblock copolymer material, polystyrene and terpolymer, and the thickness of the thermoplastic polyolefin layer 21 is 2mm;
in the present embodiment, the thickness of the first adhesive layer 22 is 0.1mm, and the thickness of the second adhesive layer 24 is 0.05mm; the first adhesive layer 22 and the second adhesive layer 24 are selected from one or a mixture of several of maleic anhydride grafted PE, maleic anhydride grafted PP, maleic anhydride grafted POE, maleic anhydride grafted SEBS, maleic anhydride grafted SEPS or maleic anhydride grafted EPDM.
In this embodiment, the barrier layer 23 is one or a blend of several of thermoplastic resin, polypropylene, polyamide (nylon PA), olefin plastic, polyvinylidene chloride, polyvinylidene fluoride, ethylene and vinyl alcohol copolymer (EVOH), and the thickness of the barrier layer 23 is 0.05mm.
In this embodiment, the self-adhesive layer 25 is one of asphalt-based self-adhesive, non-asphalt-based self-adhesive, and butyl adhesive, and has a thickness of 3.00mm.
Example IV
As shown in fig. 4, on the basis of the above embodiment, the present embodiment further gives the following:
the two ends of the central shaft 1 are provided with rotating grooves 11, the inside of each rotating groove 11 is rotationally embedded with an assembly joint 3, and each assembly joint 3 is used for connecting hoisting equipment; the assembly joint 3 comprises a first plate body 31, a second plate body 32 and a hanging ring 33, the side section of the rotary groove 11 is in a convex shape, the second plate body 32 is concentrically arranged on the side surface of the first plate body 31, the first plate body 31 and the second plate body 32 are rotationally embedded in the rotary groove 11, and the hanging ring 33 is vertically arranged on the outer wall of the second plate body 32.
Through the rotatable assembly structure of design to multi-angle and lifting hook equipment, dismantlement, the operation is more simple and convenient.
It is noted that relational terms such as first and second, and the like are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Moreover, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising one … …" does not exclude the presence of other like elements in a process, method, article, or apparatus that comprises the element.
The above embodiments are only for illustrating the technical solution of the present utility model, and are not limiting; although the utility model has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical scheme described in the foregoing embodiments can be modified or some technical features thereof can be replaced by equivalents; such modifications and substitutions do not depart from the spirit and scope of the technical solutions of the embodiments of the present utility model.

Claims (8)

1. The multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material is characterized in that: including center pin (1), the outer wall winding of center pin (1) has coiled material main part (2), coiled material main part (2) including the crowded layer altogether that connects gradually, self-adhesion glue film (25), barrier film layer (26), crowded layer altogether including thermoplastic polyolefin layer (21), first adhesive linkage (22), barrier layer (23) and second adhesive linkage (24) that connect gradually.
2. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 1, wherein: the thermoplastic polyolefin layer (21) has a thickness of 0.1-2.5mm.
3. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 2, wherein: the thickness of the first adhesive layer (22) and the second adhesive layer (24) is 0.005-0.1mm.
4. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 3, wherein: the thickness of the first adhesive layer (22) is greater than the thickness of the second adhesive layer (24).
5. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 1, wherein: the thickness of the barrier layer (23) is 0.01-0.1mm.
6. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 1, wherein: the thickness of the self-adhesive layer (25) is 0.2-3mm.
7. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 1, wherein: the two ends of the central shaft (1) are provided with rotating grooves (11), the inside of each rotating groove (11) is embedded with an assembly joint (3) in a rotating mode, and each assembly joint (3) is used for being connected with lifting equipment.
8. The multilayer co-extruded thermoplastic polyolefin self-adhesive composite waterproof roll according to claim 7, wherein: the assembly joint (3) comprises a first plate body (31), a second plate body (32) and a hanging ring (33), the side section of the rotating groove (11) is in a convex shape, the second plate body (32) is concentrically arranged on the side surface of the first plate body (31), the first plate body (31) and the second plate body (32) are rotationally embedded in the rotating groove (11), and the hanging ring (33) is vertically arranged on the outer wall of the second plate body (32).
CN202223517700.7U 2022-12-28 2022-12-28 Multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material Active CN219099044U (en)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202223517700.7U CN219099044U (en) 2022-12-28 2022-12-28 Multilayer co-extrusion thermoplastic polyolefin self-adhesive composite waterproof coiled material

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CN219099044U true CN219099044U (en) 2023-05-30

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CP01 Change in the name or title of a patent holder

Address after: 124000 Panjin new waterproof material industrial base, Panjin City, Liaoning Province (Chenjia, Panshan county)

Patentee after: Dayu Waterproof Building Materials Group Co.,Ltd.

Address before: 124000 Panjin new waterproof material industrial base, Panjin City, Liaoning Province (Chenjia, Panshan county)

Patentee before: LIAONING DAYU WATERPROOF TECHNOLOGY DEVELOPMENT Co.,Ltd.

CP01 Change in the name or title of a patent holder