CN218827247U - CCM transfer apparatus - Google Patents

CCM transfer apparatus Download PDF

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Publication number
CN218827247U
CN218827247U CN202222314682.6U CN202222314682U CN218827247U CN 218827247 U CN218827247 U CN 218827247U CN 202222314682 U CN202222314682 U CN 202222314682U CN 218827247 U CN218827247 U CN 218827247U
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transfer
roller
cathode
anode
ccm
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请求不公布姓名
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Jiangsu Hydrogen Guide Intelligent Equipment Co ltd
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Jiangsu Hydrogen Guide Intelligent Equipment Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

The utility model relates to a CCM transfer apparatus, including catalyst transfer means, proton membrane feedway, positive pole feedway and negative pole feedway. Under normal working conditions, the proton exchange membrane, the anode transfer printing membrane and the cathode transfer printing membrane in the transfer printing channel are rolled by the first working roller and the second working roller. Because the anode catalyst layer on the anode transfer film and the cathode catalyst layer on the cathode transfer film are coated intermittently, the anode catalyst layer and the cathode catalyst layer can be completely transferred to the proton exchange membrane. When the alignment of the anode catalyst layer and the cathode catalyst layer is deviated, the roll pressing of the proton exchange membrane, the anode transfer film and the cathode transfer film can be released by increasing the distance between the first working roll and the second working roll. At this time, the transport speeds of the cathode transfer film and the cathode transfer film are adjusted, so that the anode catalyst layer and the cathode catalyst layer can be aligned again. As can be seen, the CCM transfer apparatus described above can reduce material waste.

Description

CCM transfer apparatus
Technical Field
The utility model relates to a fuel cell technical field, in particular to CCM transfer apparatus.
Background
CCM (catalyst coated membrane, catalyst/proton exchange membrane assembly) is a core element of a fuel cell, and is composed of a proton exchange membrane and positive and negative catalyst layers attached to both sides of the proton exchange membrane. The preparation process of CCM is generally divided into two processes, one is to directly coat the catalyst slurry on two sides of the proton exchange membrane, and the other is to coat the catalyst on a transfer printing membrane, dry and transfer the catalyst to two sides of the proton exchange membrane by means of transfer printing. Because direct coating has problems such as swelling, which can affect precision, the CCM is generally prepared by transfer printing in the art.
In order to produce a CCM that is compatible with subsequent processing, the catalyst needs to be intermittently transferred during the transfer process, i.e., the catalyst layer on the surface of the proton exchange membrane is discontinuous after transfer. At present, the process for realizing intermittent transfer mainly comprises concave roller transfer and lifting roller transfer. The transfer printing of the concave roller is to make the local part of the transfer printing roller into a concave surface, and the transfer printing can not be realized due to no pressure at the concave surface, so that a gap is formed; when the transfer roller is lifted to the non-transfer area of the proton exchange membrane, the transfer roller is lifted so as not to transfer the non-transfer area to form a gap.
However, the catalyst coated in advance on the transfer film is continuous regardless of whether the transfer is the gravure transfer or the transfer is the gravure transfer. After transfer, only a portion of the catalyst is transferred to the surface of the proton exchange membrane, and more catalyst remains on the transfer membrane. Therefore, the existing transfer printing process can cause great waste of materials.
SUMMERY OF THE UTILITY MODEL
In view of this, there is a need to provide a CCM transfer apparatus capable of significantly reducing material waste in view of the above problems.
A CCM transfer apparatus comprising:
the catalyst transfer printing device comprises a first working roller and a second working roller, wherein the first working roller and the second working roller are arranged oppositely to form a transfer printing channel for a proton exchange membrane, an anode transfer printing film and a cathode transfer printing film to pass through, and the distance between the first working roller and the second working roller is adjustable;
proton membrane supply means for supplying said proton exchange membrane;
the anode feeding device is used for providing the anode transfer printing film, and the surface of the anode transfer printing film is intermittently coated with an anode catalyst layer; and
the cathode feeding device is used for providing the cathode transfer printing film, and the surface of the cathode transfer printing film is intermittently coated with a cathode catalyst layer;
the first working roll and the second working roll can roll the proton exchange membrane, the anode transfer film and the cathode transfer film in the transfer printing channel so as to transfer the anode catalyst layer and the cathode catalyst layer to two sides of the proton exchange membrane respectively and obtain a CCM material belt, and the cathode transfer film can independently move in the transfer printing channel along with the increase of the distance between the first working roll and the second working roll so as to adjust the relative position of the anode catalyst layer and the cathode catalyst layer.
In one embodiment, the catalyst transfer device further comprises a first support assembly and a second support assembly, the first support assembly abuts against the surface of the first working roller and can roll along the circumferential direction of the first working roller, and the first support assembly can apply a support force pointing to the second working roller to the first working roller; the second supporting assembly abuts against the surface of the second working roll and can roll along the circumferential direction of the second working roll, and the second supporting assembly can apply supporting force pointing to the first working roll to the second working roll.
In one embodiment, the first support assembly comprises a first support roller which is abutted against the first working roller, and the first support roller is parallel to the rotation axis of the first working roller and can be driven by the first working roller to rotate;
the second supporting assembly comprises a second supporting roller which is abutted against the second working roller, and the second supporting roller is parallel to the rotation axis of the second working roller and can rotate under the driving of the second working roller.
In one embodiment, the first supporting roller is provided with one, and the diameter of the first supporting roller is larger than that of the first working roller; the number of the second supporting rollers is one, and the diameter of the second supporting rollers is larger than that of the second working rollers.
In one embodiment, the rotation axes of the first support roller, the first working roller, the second working roller and the second support roller are located in the same plane.
In one embodiment, the catalyst transfer device further includes a nip roller abutting against the second working roller to press the cathode transfer film output from the transfer passage against a roller surface of the second working roller.
In one embodiment, the anode feed device comprises a first visual detection assembly positioned on the conveying path of the anode transfer film, wherein the first visual detection assembly can acquire the position information of the anode catalyst layer; the cathode feeding device comprises a second visual detection assembly positioned on the conveying path of the cathode transfer film, and the second visual detection assembly can acquire the position information of the cathode catalyst layer.
In one embodiment, the method further comprises the following steps:
the CCM winding device is used for winding the CCM material belt;
the anode rolling device is used for rolling the anode transfer printing film output from the transfer printing channel;
and the cathode rolling device is used for rolling the cathode transfer printing film output from the transfer printing channel.
In one embodiment, the device further comprises a composite device arranged on the upstream side of the catalyst transfer printing device, and the proton exchange membrane and the anode transfer printing membrane pass through the composite device before entering the transfer printing channel and are combined by the composite device.
In one embodiment, the CCM material belt structure further comprises a film covering device, wherein the film covering device is used for covering one side of the CCM material belt with a back film material belt.
According to the CCM transfer printing equipment, under the normal working condition, the proton exchange membrane, the anode transfer printing membrane and the cathode transfer printing membrane in the transfer printing channel are rolled by the first working roller and the second working roller. Because the anode catalyst layer on the anode transfer printing film and the cathode catalyst layer on the cathode transfer printing film are both coated intermittently and are of discontinuous structures, the anode catalyst layer and the cathode catalyst layer can be completely transferred to the proton exchange membrane, thereby forming discontinuous catalyst layers on the surface of the proton exchange membrane. When the alignment of the anode catalyst layer and the cathode catalyst layer is deviated, the height of the transfer printing channel can be increased by increasing the distance between the first working roller and the second working roller, so that the rolling of the proton exchange membrane, the anode transfer printing film and the cathode transfer printing film is eliminated. At this time, the transport speeds of the cathode transfer film and the cathode transfer film are adjusted, so that the anode catalyst layer and the cathode catalyst layer can be aligned again. As can be seen, the CCM transfer apparatus described above can reduce material waste.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present application, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a schematic view of a CCM transfer apparatus according to an embodiment of the present invention;
FIG. 2 is a schematic view showing the construction of a catalyst transfer device in the CCM transfer apparatus shown in FIG. 1;
FIG. 3 is a schematic view showing the arrangement of a proton membrane supplying device in the CCM transfer apparatus shown in FIG. 1;
FIG. 4 is a schematic view showing the construction of an anode feeding device in the CCM transfer apparatus shown in FIG. 1;
FIG. 5 is a schematic view showing the construction of a cathode feeding device in the CCM transfer apparatus shown in FIG. 1;
FIG. 6 is a schematic view showing the structure of a CCM take-up device in the CCM transfer apparatus shown in FIG. 1;
FIG. 7 is a schematic view showing the structure of an anode take-up device in the CCM transfer apparatus shown in FIG. 1;
FIG. 8 is a schematic view showing the structure of a cathode take-up device in the CCM transfer apparatus shown in FIG. 1;
FIG. 9 is a schematic view showing the structure of a film covering device in the CCM transfer apparatus shown in FIG. 1;
fig. 10 is a top view of an anode transfer film according to an embodiment of the invention;
fig. 11 is a top view of a cathode transfer film in an embodiment of the invention;
fig. 12 is a schematic view of a laminated structure of CCM material tapes according to an embodiment of the present invention.
Detailed Description
In order to make the above objects, features and advantages of the present invention more comprehensible, embodiments of the present invention are described in detail below with reference to the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. The invention may be embodied in many other forms different from those described herein and similar modifications may be made by those skilled in the art without departing from the spirit and scope of the invention and, therefore, the invention is not to be limited to the specific embodiments disclosed below.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", and the like, indicate the orientation or positional relationship based on the orientation or positional relationship shown in the drawings, and are only for convenience of description and simplicity of description, and do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore, should not be construed as limiting the present invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one of the feature. In the description of the present invention, "a plurality" means at least two, e.g., two, three, etc., unless explicitly defined otherwise.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," and "fixed" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally formed; can be mechanically or electrically connected; they may be directly connected or indirectly connected through intervening media, or they may be connected internally or in any other suitable relationship, unless expressly stated otherwise. The specific meaning of the above terms in the present invention can be understood according to specific situations by those skilled in the art.
In the present application, unless expressly stated or limited otherwise, the first feature may be directly on or directly under the second feature or indirectly via intermediate members. Also, a first feature "on," "above," and "over" a second feature may be directly on or obliquely above the second feature, or simply mean that the first feature is at a higher level than the second feature. A first feature being "under," "below," and "beneath" a second feature may be directly under or obliquely under the first feature, or may simply mean that the first feature is at a lesser elevation than the second feature.
It will be understood that when an element is referred to as being "secured to" or "disposed on" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. As used herein, the terms "vertical," "horizontal," "upper," "lower," "left," "right," and the like are for purposes of illustration only and do not denote a single embodiment.
Referring to fig. 1, a CCM transfer apparatus according to an embodiment of the present invention includes a catalyst transfer device 100, a proton membrane supplying device 200, an anode supplying device 300, and a cathode supplying device 400.
Proton membrane supply device 200 is used for providing proton exchange membrane 10, anode supply device 300 is used for providing anode transfer membrane 20, and cathode supply device 400 is used for providing cathode transfer membrane 30. As shown in fig. 10 and 11, the surface of the anode transfer film 20 is intermittently coated with an anode catalyst layer 21, and the surface of the cathode transfer film 30 is intermittently coated with a cathode catalyst layer 31. The anode catalyst layer 21 and the cathode catalyst layer 31 are both discontinuous structures and each include a plurality of block-shaped catalyst layer structures, and the plurality of block-shaped catalyst layer structures are arranged at intervals along the extending direction of the anode transfer film 20 or the cathode transfer film 30.
The anode transfer film 20 and the cathode transfer film 30 can enter the catalyst transfer device 100 together with the proton exchange membrane 10, and the anode transfer film 20 and the cathode transfer film 30 are respectively located on two sides of the proton exchange membrane 10. Specifically, as shown in fig. 1, the anode transfer film 20 is located on the left side of the proton exchange membrane 10, and the right side surface thereof is coated with an anode catalyst layer 21; the right side of the cathode transfer film 30 is located at the right side of the proton exchange membrane 10, and the left side surface thereof is coated with a cathode catalyst layer 31.
Under the pressing action of the catalyst transfer device 100, the anode catalyst layer 21 on the anode transfer film 20 and the cathode catalyst layer 31 on the cathode transfer film 30 are respectively transferred to both sides of the proton exchange membrane 10, so as to obtain the CCM carrier tape 40 having catalyst layers on both sides. As shown in fig. 12, the catalyst layer on the upper surface of the CCM carrier tape 40 is the anode catalyst layer 21 on the original anode transfer film 20, and the catalyst layer on the lower surface is the cathode catalyst layer 31 on the original cathode transfer film 30.
Referring also to fig. 2, the catalyst transfer apparatus 100 includes a first work roll 110 and a second work roll 120. The first working roll 110 and the second working roll 120 are disposed opposite to each other, and form a transfer passage (not shown) through which the anode transfer film 20, the cathode transfer film 30, and the proton exchange membrane 10 can pass.
Further, the distance between the first work roll 110 and the second work roll 120 is adjustable, thereby adjusting the height of the transfer path. The larger the distance between the first work roll 110 and the second work roll 120 is, the higher the height of the transfer path is, and the distance between the first work roll 110 and the second work roll 120 is the distance in the direction of the line connecting the axes, that is, the up-down direction shown in fig. 2. The height adjustment of the transfer path may be achieved by moving the position of the first work roll 110 and/or the second work roll 120. Specifically, in the present embodiment, the first work roll 110 is fixed in position, and the second work roll 120 located below is capable of moving back and forth in the up-down direction.
When the height of the transfer channel is small and smaller than the sum of the thicknesses of the anode transfer film 20, the cathode transfer film 30, and the proton exchange membrane 10, the first working roll 110 and the second working roll 120 can roll the anode transfer film 20, the cathode transfer film 30, and the proton exchange membrane 10 passing through the transfer channel. When the height of the transfer channel is increased and is greater than the sum of the thicknesses of the anode transfer film 20, the cathode transfer film 30 and the proton exchange membrane 10, the first working roll 110 and the second working roll 120 cannot press the cathode transfer film 30 and the cathode transfer film 30, so that the cathode transfer film 30 and the cathode transfer film 30 can independently move in the transfer channel without interfering with each other, thereby conveniently adjusting the relative positions of the anode catalyst layer 21 and the cathode catalyst layer 31.
Under normal operating conditions, the height of the transfer printing channel is small, so that the first working roll 110 and the second working roll 120 are matched to roll the proton exchange membrane 10, the anode transfer printing membrane 20 and the cathode transfer printing membrane 30, so as to transfer the anode catalyst layer 21 on the anode transfer printing membrane 20 and the cathode catalyst layer 31 on the cathode transfer printing membrane 30 to two sides of the proton exchange membrane 10 respectively. Since the anode catalyst layer 21 and the cathode catalyst layer 31 are both discontinuous structures, the anode catalyst layer 21 and the cathode catalyst layer 31 can be transferred to the proton exchange membrane 10, thereby forming discontinuous catalyst layers on the surface of the proton exchange membrane 10. After the transfer, there is no catalyst residue on the anode transfer film 20 and the cathode transfer film 30, so that the waste of materials can be significantly reduced.
Specifically, in the present embodiment, the first work roll 110 and the second work roll 120 are provided with heating elements (not shown) inside. The heating assembly can be an electromagnetic heating assembly, an electrical bar heating assembly and the like, and can heat the anode transfer film 20, the cathode transfer film 30 and the proton exchange membrane 10 in the transfer process, so that the transfer rate of the catalyst is improved, and the transfer effect is improved.
Because the anode catalyst layer 21 and the cathode catalyst layer 31 are both of a discontinuous structure, and errors and defects are present in the processing process, after long-time accumulation, the anode catalyst layer 21 and the cathode catalyst layer 31 may have a misalignment when entering the rolling channel, that is, the block-shaped catalyst layer structure in the anode catalyst layer 21 cannot be aligned with the block-shaped catalyst layer structure in the cathode catalyst layer 31. If the anode catalyst layer 21 and the cathode catalyst layer 31 with the misalignment are directly transferred to the two sides of the proton exchange membrane 10, the catalyst layers on the two sides of the CCM carrier tape 40 may not be aligned, and the CCM carrier tape 40 may be discarded.
Referring to fig. 4 and 5, in the present embodiment, the anode feeding device 300 includes a first visual inspection device 310 located on the conveying path of the anode transfer film 20, wherein the first visual inspection device 310 can acquire the position information of the anode catalyst layer 21; the cathode feeding apparatus 400 includes a second visual inspection assembly 410 on the conveying path of the cathode transfer sheet 30, and the second visual inspection assembly 410 can acquire positional information of the cathode catalyst layer 31.
The first visual inspection device 310 and the second visual inspection device 410 have the same structure and can be CCD cameras. After the first visual inspection unit 310 and the second visual inspection unit 410 respectively detect the position information of the anode catalyst layer 21 and the cathode catalyst layer 31, the alignment deviation between the anode catalyst layer 21 and the cathode catalyst layer 31 can be detected by comparison analysis.
When the misalignment of the anode catalyst layer 21 and the cathode catalyst layer 31 is detected, the height of the transfer channel can be increased by increasing the distance between the first working roll 110 and the second working roll 120, so as to release the roll pressure on the proton exchange membrane 10, the anode transfer membrane 20, and the cathode transfer membrane 30. At this time, the cathode transfer films 30 and 30 can be independently transported, and the transport speeds of the cathode transfer films 30 and 30 are adjusted, respectively, so that the anode catalyst layers 21 and the cathode catalyst layers 31 can be aligned again. After the alignment is completed, the height of the transfer printing channel is restored to the size of the normal working condition, and the cathode transfer printing film 30 are synchronized again, so that the transfer printing operation can be continuously performed.
In addition, compared with the traditional gravure roll transfer printing process, the adaptability of the CCM transfer printing device is higher, parts of the device do not need to be replaced when the CCM transfer printing device is used for processing products of other models, and only the anode transfer printing film 20 and the cathode transfer printing film 30 with corresponding specifications need to be replaced and can be used along with the proton exchange membrane 10. Moreover, since the pressure between the first working roll 110 and the second working roll 120 is relatively stable during the rolling process, the edge of the catalyst layer of the CCM material tape 40 can be prevented from being jagged.
Compared with the traditional transfer printing process by the lifting roller, the CCM transfer printing equipment does not need to frequently change the positions of the first working roller 110 and the second working roller 120 in the transfer printing process, so that the transfer printing efficiency is higher, and the production capacity is favorably improved. Similarly, the pressure between the first working roll 110 and the second working roll 120 is relatively stable during the rolling process, so that the edge of the catalyst layer of the CCM material tape 40 can be prevented from being jagged.
Referring to fig. 2 again, in the present embodiment, the catalyst transfer printing apparatus 100 further includes a first supporting assembly 130 and a second supporting assembly 140. The first supporting assembly 130 is supported against the surface of the first working roll 110 and can roll along the circumferential direction of the first working roll 110. Also, the first support assembly 130 can apply a supporting force directed toward the second work roll 120 to the first work roll 110.
The first supporting member 130 may be in point contact or line contact with the surface of the first working roll 110, and the acting force applied to the first working roll 110 by the first supporting member 130 may be one or more than one, as long as it is ensured that the direction of the resultant force of the acting forces is directed to the second working roll 120. Under the supporting effect of the first supporting assembly 130, the first working roll 110 is not easy to bend during the transfer process. Moreover, since the first support assembly is added to support the first work roll 110, the compressive strength of the first work roll 110 itself can be reduced properly, and the diameter of the first work roll 110 is smaller than that of the conventional work roll. In general, the work rolls in the conventional transfer apparatus each have a diameter of 200 mm or more, and the diameter of the first work roll 110 in the present embodiment may be set to 100 mm or less.
The second support element 140 is substantially identical in structure and function to the first support element 130. The second supporting assembly 140 abuts against the surface of the second working roll 120 and can roll along the circumferential direction of the second working roll 120, and the second supporting assembly 140 can apply a supporting force pointing to the first working roll 110 to the second working roll 120. Under the supporting action of the second supporting assembly 140, the second working roll 120 is also less prone to bending during the transfer process, and has a smaller diameter than a conventional working roll.
Therefore, on the premise of a certain pressure, the transfer pressure between the first working roll 110 and the second working roll 120 is increased, and the transfer rate of the catalyst is increased, so that the catalyst residue is reduced, and the transfer effect is improved. Moreover, the straightness of the edge of the catalyst layer in the width direction on the CCM carrier tape 40 can be ensured.
It should be noted that when the distance between the first work roll 110 and the second work roll 120 is adjusted, the first support assembly 130 and the second support assembly 140 move synchronously with the first work roll 110 and the second work roll 120.
Further, in this embodiment, the first supporting assembly 130 includes a first supporting roller 131 abutting against the first working roller 110, and the first supporting roller 131 is parallel to the rotation axis of the first working roller 110 and can be driven by the first working roller 110 to rotate. Moreover, the second supporting assembly 140 includes a second supporting roller 141 abutting against the second working roller 120, and the second supporting roller 141 is parallel to the rotation axis of the second working roller 120 and can be driven by the second working roller 120 to rotate.
At this time, the first supporting member 130 is in line contact with the first work roll 110, and the contact position extends in the axial direction of the first work roll 110. The second support member 140 is also in line contact with the second work roll 120, and the contact position extends in the axial direction of the second work roll 120. Therefore, the first supporting assembly 130 and the second supporting assembly 140 support the first working roll 110 and the second working roll 120 better.
Specifically, in the present embodiment, one first supporting roller 131 is provided, and the diameter of the first supporting roller 131 is larger than that of the first work roller 110. Also, one second support roller 141 is provided, and the diameter of the second support roller 141 is larger than that of the second work roller 120.
The first support roller 131 and the second support roller 141 having a large diameter have high support strength and can provide better support. In addition, since there is only one first support roller 131 and one second support roller 141, the structures of the first support unit 130 and the second support unit 140 can be simplified.
Further, in the present embodiment, the rotation axes of the first support roller 131, the first work roller 110, the second work roller 120, and the second support roller 141 are located in the same plane. As can be seen, the first supporting roller 131 and the second supporting roller 141 cooperate with each other to sandwich the first working roller 110 and the second working roller 120, so that the supporting effect is better.
It should be noted that, in other embodiments, the first supporting component 130 and the second supporting component 140 may have other structures. For example, at least two contact points may be formed between the first supporting member 130 and the first working roll 110 by rolling members such as balls and rollers, and the at least two contact points are spaced apart along the axial direction of the first working roll 110. Likewise, the second support assembly 140 may define at least two contact points with the second work roll 120, and the at least two contact points are spaced apart along the axial direction of the second work roll 120.
In addition, in the present embodiment, the catalyst transfer device 100 further includes a pressure roller 150, and the pressure roller 150 abuts against the second work roller 120 to press the cathode transfer film 30 output from the transfer passage against the roller surface of the second work roller 120.
The line connecting the center line of the nip roller 150 and the center line of the second work roller 120 is substantially perpendicular to the connection of the center line of the second work roller 120 and the center line of the first work roller 110. Under the action of the pressure roller 150, the cathode transfer film 30 can form a larger envelope angle on the roller surface of the second work roller 120, thereby being beneficial to improving the transfer effect. Further, the nip roller 150 can maintain the cathode transfer film 30 in good contact with the second work roll 120 when the second work roll 120 moves up and down.
Referring to fig. 3, in the present embodiment, the proton membrane supplying apparatus 200 includes a proton membrane unwinding assembly 210, a membrane peeling assembly 220, and a back membrane winding assembly 230.
The proton membrane unwinding assembly 210 may be an unwinding shaft, the proton exchange membrane 10 with the protective membrane 11 on one side is stored in the proton membrane unwinding assembly 210 in advance, and the proton membrane unwinding assembly 210 unwinds at a preset speed. When the proton exchange membrane 10 passes through the membrane peeling assembly 220, the protective membrane 11 is separated from the proton exchange membrane 10 under the traction of the back membrane rolling assembly 230, and the protective membrane 11 is rolled by the back membrane rolling assembly 230.
In addition, the proton membrane supplying apparatus 200 generally includes a roll diameter measuring assembly (not shown), a roller (not shown), a static removing assembly (not shown), and a belt connecting platform (not shown). In order to realize automatic unwinding and deviation correction, the proton membrane feeding device 200 further includes a deviation correction follower roll (not shown), a deviation correction sensor (not shown), a tension sensor (not shown), and the like on the belt traveling path of the proton exchange membrane 10.
Referring to fig. 4 again, in the present embodiment, the anode feeding device 300 further includes an anode transfer film unwinding assembly 320 and an anode preheating assembly 330.
The anode transfer film unwinding assembly 320 may be an unwinding shaft, and the pre-coated and dried anode transfer film 20 may be stored in the anode transfer film unwinding assembly 320 and may be unwound by the anode transfer film unwinding assembly 320 at a predetermined speed. The anode preheating assembly 330 can preheat the anode transfer film 20 in the tape transport process, thereby reducing the heat conduction time in the transfer process and improving the transfer quality and speed. Specifically, the anode preheating assembly 330 may be preheated by electromagnetic heating, infrared heating, or the like.
In addition, the anode feeding device 300 also includes a roll diameter measuring assembly (not shown), a roller (not shown), a static removing assembly (not shown), and a belt splicing platform (not shown). In order to realize automatic unwinding and deviation correction, the anode feeding device 300 further includes a deviation correction follower roller (not shown), a deviation correction sensor (not shown), a tension sensor (not shown), and the like on the tape running path of the anode transfer film 20.
It should be noted that in other embodiments, the anode feeding device 300 can also be used to prepare the anode transfer film 20 on-line in a real-time catalyst coating manner.
Referring to fig. 5 again, in the present embodiment, the cathode supply device 400 further includes a cathode transfer film unwinding assembly 420 and a cathode preheating assembly 430.
The cathode transfer film unwinding assembly 420 may also be an unwinding shaft, and the pre-coated and dried cathode transfer film 30 may be stored in the cathode transfer film unwinding assembly 420 and may be unwound by the cathode transfer film unwinding assembly 420 at a predetermined speed. The cathode preheating assembly 430 can preheat the cathode transfer film 30 during the tape running process, thereby reducing the heat conduction time during the transfer process and improving the transfer quality and speed. Specifically, the cathode preheating assembly 430 may be preheated by electromagnetic heating, infrared heating, or the like.
In addition, the cathode feeding device 400 also includes a roll diameter measuring assembly (not shown), a roller (not shown), a static removing assembly (not shown), and a belt connecting platform (not shown). In order to realize automatic unwinding and deviation correction, the cathode feeding device 400 further includes a deviation correction follower roller (not shown), a deviation correction sensor (not shown), a tension swing roller (not shown), and the like on the running path of the cathode transfer film 30.
It is noted that in other embodiments, the cathode feeding device 400 can also be used to on-line prepare the cathode transfer film 30 by coating the catalyst in real time.
Referring to fig. 1 again, in the present embodiment, the CCM transfer apparatus further includes a CCM winding device 500, an anode winding device 600, and a cathode winding device 700.
The CCM rolling device 500 is used for rolling the CCM material belt 400, and the rolled CCM material belt 400 can be stored in a material roll form. Moreover, the CCM winding device 500 is matched with the proton exchange membrane feeding device 200, so that the proton exchange membrane 10 can maintain stable tension during the transfer process.
Referring to fig. 6, in the embodiment, the CCM winding apparatus 500 includes a CCM winding shaft 510, a first surface inspection device 520, a second surface inspection device 530, and a marking device 520.
The first surface detection component 520 and the second surface detection component 530 can respectively detect the catalyst layers on the two sides of the CCM carrier tape 400 by adopting a visual detection method to check whether the transfer printing of the catalyst layers meets the process requirements. To the position that CCM material area 400 surface detection is unqualified, beat mark subassembly 520 can beat it to find and reject in the convenient follow-up use. After the detection and marking are completed, the CCM tape 400 is wound and wound by the CCM winding shaft 510.
In addition, the CCM winding device 500 also includes a roll diameter measuring assembly (not shown), a roller (not shown), a static electricity removing assembly (not shown), and a belt splicing platform (not shown). In order to realize automatic winding and deviation correction, the CCM winding device 500 further includes a deviation correction follower roller (not shown), a deviation correction sensor (not shown), a tension sensor (not shown), and a tension swing roller (not shown) on the running path of the CCM tape 40.
The anode rolling device 600 is used for rolling the anode transfer film 20 output from the transfer passage. Thus, the anode transfer film 20 after transfer printing can be prevented from scattering, and the anode transfer film 20 can be conveniently recycled. In addition, the anode take-up device 600 is coupled to the anode feeding device 300, so that the anode transfer film 20 can maintain stable tension during the transfer process.
Referring to fig. 7, in the embodiment, the anode rolling device 600 includes an anode transfer film rolling shaft 610, a separating assembly 620 and an anode defect detecting assembly 630.
Separation component 620 can be when CCM material area 40 route with the separation of one side of anode transfer film 20 from CCM material area 40 to make anode transfer film 20 can be rolled up by anode transfer film rolling shaft 610 smoothly. The anode defect detecting assembly 630 determines the transfer effect through visual inspection, and records the position of the transfer failure, so as to facilitate the marking assembly 520 to mark the corresponding position of the CCM material tape 40.
In addition, the anode take-up device 600 also includes a roll diameter measuring assembly (not shown), a roller (not shown), a static electricity removing assembly (not shown), and a tape splicing platform (not shown). In order to realize automatic winding and deviation correction, the anode winding device 600 further includes a deviation correction follower roller (not shown), a deviation correction sensor (not shown), a tension sensor (not shown), and the like on the tape running path of the anode transfer film 20.
The cathode rolling device 700 is used for rolling the cathode transfer film 30 output from the transfer passage. Similarly, the cathode transfer film 30 after transfer can be recycled by the cathode take-up device 700. In addition, the cathode rolling device 700 is matched with the cathode feeding device 400, so that the cathode transfer film 30 can maintain stable tension in the transfer process.
Referring to fig. 8, in the embodiment, a cathode rolling device 700 includes a cathode transfer film rolling shaft 710 and a cathode defect detecting assembly 720.
Cathode transfer film rolling axle 710 can carry out the rolling to cathode transfer film 30, and cathode defect detection subassembly 720 then judges the rendition effect through visual inspection to the unqualified position of will transferring to record, mark the subassembly 520 of making things convenient for and mark on the corresponding position of CCM material area 40.
In addition, the cathode winding device 700 also includes a roll diameter measuring assembly (not shown), a roller (not shown), a static removing assembly (not shown), and a tape splicing platform (not shown). In order to realize automatic winding and deviation correction, the cathode winding device 700 further includes a deviation correction follower roller (not shown), a deviation correction sensor (not shown), a tension sensor (not shown), and the like on the tape running path of the cathode transfer film 30.
Referring to fig. 1 again, in the present embodiment, the CCM transfer apparatus further includes a composite device 800 disposed on the upstream side of the catalyst transfer device 100, and the proton exchange membrane 10 and the anode transfer membrane 20 pass through the composite device 800 before entering the transfer channel, and are combined by the composite device 800.
That is, the pem 10 and the anode transfer film 20 can be combined into a strip by the combining device 800 before entering the transfer channel. It can be seen that the number of material strips entering the transfer channel is reduced compared to the case where the anode transfer film 20, the cathode transfer film 30 and the proton exchange membrane 10 enter the transfer channel separately. So, will conveniently make each material area align in the rendition passageway to guarantee the machining precision.
It should be noted that in other embodiments, the proton exchange membrane 10 and the cathode transfer membrane 30 may be combined into a single strip before entering the transfer channel.
Specifically, the compound device 800 generally includes two sets of counter rollers (not shown) disposed opposite to each other, and one of the sets of counter rollers is a driving roller. The proton exchange membrane 10 and the anode transfer membrane 20 can pass through between the two pairs of rollers, and are roll-combined. And the driving roller can also provide driving force for the compounded material belt so as to enable the compounded material belt to smoothly enter the transfer printing channel.
In addition, in the present embodiment, the CCM transfer apparatus further includes a film coating device 900, and the film coating device 900 is used for coating the back film tape 50 on one side of the CCM tape 40. The backing film material tape 50 may be a material tape made of PET, and has high wear resistance and toughness. The back film material belt 50 is covered on one side of the CCM material belt 40, so that a better protection effect can be achieved, and the CCM material belt 40 is prevented from damaging the catalyst layer on the surface in the storage and transportation processes.
Referring to fig. 9, in the embodiment, the film covering apparatus 900 includes a back film unwinding shaft 910 and a back film composite assembly 920.
The back film unreeling shaft 910 is used for storing and unreeling the back film material belt 50, the CCM material belt 40 output by the transfer printing channel can enter the back film composite assembly 920 together with the back film material belt 50 before being reeled, and the back film composite assembly 920 is used for covering the back film material belt 50 on one side of the CCM material belt 40. The back film composite assembly 920 generally comprises oppositely arranged press rollers, and the CCM material belt 40 and the back film material belt 50 can be continuously compounded through the rolling manner.
Moreover, the film covering device 900 generally includes a roll diameter measuring assembly (not shown), a roller (not shown), a static removing assembly (not shown), a belt splicing platform (not shown), a deviation correcting follower roller (not shown), a deviation correcting sensor (not shown), a tension sensor (not shown), and a tension swing roller (not shown).
In the CCM transfer apparatus, under normal operating conditions, the proton exchange membrane 10, the anode transfer film 20, and the cathode transfer film 30 in the transfer channel are rolled by the first working roll 110 and the second working roll 120. Since the anode catalyst layer 21 on the anode transfer film 20 and the cathode catalyst layer 31 on the cathode transfer film 30 are both intermittently coated and have a discontinuous structure, the anode catalyst layer 21 and the cathode catalyst layer 31 can be completely transferred to the proton exchange membrane 10, so that a discontinuous catalyst layer is formed on the surface of the proton exchange membrane 10. When the alignment of the anode catalyst layer 21 and the cathode catalyst layer 31 is deviated, the distance between the first working roll 110 and the second working roll 120 is increased to increase the height of the transfer channel, so as to release the roll pressing of the proton exchange membrane 10, the anode transfer film 20, and the cathode transfer film 30. At this time, the anode catalyst layer 21 and the cathode catalyst layer 31 can be aligned again by adjusting the transport speeds of the cathode transfer film 30 and the cathode transfer film 30, respectively. As can be seen, the CCM transfer apparatus described above can reduce material waste.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only represent some embodiments of the present invention, and the description thereof is specific and detailed, but not to be construed as limiting the scope of the present invention. It should be noted that, for those skilled in the art, without departing from the spirit of the present invention, several variations and modifications can be made, which are within the scope of the present invention. Therefore, the protection scope of the present invention should be subject to the appended claims.

Claims (10)

1. A CCM transfer apparatus, comprising:
the catalyst transfer printing device comprises a first working roller and a second working roller, wherein the first working roller and the second working roller are arranged oppositely to form a transfer printing channel for a proton exchange membrane, an anode transfer printing film and a cathode transfer printing film to pass through, and the distance between the first working roller and the second working roller is adjustable;
proton membrane supply means for supplying said proton exchange membrane;
the anode feeding device is used for providing the anode transfer printing film, and the surface of the anode transfer printing film is intermittently coated with an anode catalyst layer; and
the cathode feeding device is used for providing the cathode transfer printing film, and the surface of the cathode transfer printing film is intermittently coated with a cathode catalyst layer;
the first working roll and the second working roll can roll the proton exchange membrane, the anode transfer film and the cathode transfer film in the transfer printing channel so as to transfer the anode catalyst layer and the cathode catalyst layer to two sides of the proton exchange membrane respectively and obtain a CCM material belt, and the cathode transfer film can independently move in the transfer printing channel along with the increase of the distance between the first working roll and the second working roll so as to adjust the relative position of the anode catalyst layer and the cathode catalyst layer.
2. The CCM transfer apparatus according to claim 1, wherein the catalyst transfer device further comprises a first support member and a second support member, the first support member being supported against a roll surface of the first work roll and being capable of rolling in a circumferential direction of the first work roll, the first support member being capable of applying a supporting force to the first work roll directed to the second work roll; the second supporting assembly abuts against the surface of the second working roll and can roll along the circumferential direction of the second working roll, and the second supporting assembly can apply supporting force pointing to the first working roll to the second working roll.
3. The CCM transfer apparatus of claim 2, wherein the first support assembly comprises a first support roller that abuts against the first work roller, the first support roller being parallel to the rotation axis of the first work roller and being rotatable by the first work roller;
the second supporting assembly comprises a second supporting roller abutted against the second working roller, and the second supporting roller is parallel to the rotation axis of the second working roller and can be driven by the second working roller to rotate.
4. The CCM transfer apparatus of claim 3, wherein there is one first support roller and the diameter of the first support roller is larger than the diameter of the first work roller; the second supporting roller is provided with one, and the diameter of the second supporting roller is larger than that of the second working roller.
5. The CCM transfer apparatus of claim 4, wherein the axes of rotation of the first support roller, the first work roller, the second work roller, and the second support roller are in the same plane.
6. The CCM transfer apparatus of claim 1, wherein the catalyst transfer device further comprises a nip roller that abuts the second work roller to hold the cathode transfer film output from the transfer passage against a roller surface of the second work roller.
7. The CCM transfer apparatus of claim 1, wherein the anode feed device comprises a first visual inspection assembly positioned on the transport path of the anode transfer film, the first visual inspection assembly capable of obtaining positional information of the anode catalyst layer; the cathode feeding device comprises a second visual detection assembly positioned on the conveying path of the cathode transfer film, and the second visual detection assembly can acquire the position information of the cathode catalyst layer.
8. The CCM transfer apparatus of claim 1, further comprising:
the CCM winding device is used for winding the CCM material belt;
the anode rolling device is used for rolling the anode transfer printing film output from the transfer printing channel;
and the cathode rolling device is used for rolling the cathode transfer printing film output from the transfer printing channel.
9. The CCM transfer apparatus of claim 1, further comprising a compounding device disposed on an upstream side of the catalyst transfer device, the proton exchange membrane and the anode transfer film being routed through and compounded by the compounding device prior to entering the transfer channel.
10. The CCM transfer apparatus of claim 1, further comprising a film applicator for applying a backing film web to one side of said CCM web.
CN202222314682.6U 2022-08-31 2022-08-31 CCM transfer apparatus Active CN218827247U (en)

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Application Number Priority Date Filing Date Title
CN202222314682.6U CN218827247U (en) 2022-08-31 2022-08-31 CCM transfer apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202222314682.6U CN218827247U (en) 2022-08-31 2022-08-31 CCM transfer apparatus

Publications (1)

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Application Number Title Priority Date Filing Date
CN202222314682.6U Active CN218827247U (en) 2022-08-31 2022-08-31 CCM transfer apparatus

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116901603A (en) * 2023-09-12 2023-10-20 苏州擎动动力科技有限公司 Transfer printing method and transfer printing system for non-rectangular coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116901603A (en) * 2023-09-12 2023-10-20 苏州擎动动力科技有限公司 Transfer printing method and transfer printing system for non-rectangular coating
CN116901603B (en) * 2023-09-12 2023-12-01 苏州擎动动力科技有限公司 Transfer printing method and transfer printing system for non-rectangular coating

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