CN217033731U - Lithium ion battery electrode material and electrolyte performance testing device - Google Patents

Lithium ion battery electrode material and electrolyte performance testing device Download PDF

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Publication number
CN217033731U
CN217033731U CN202122602172.4U CN202122602172U CN217033731U CN 217033731 U CN217033731 U CN 217033731U CN 202122602172 U CN202122602172 U CN 202122602172U CN 217033731 U CN217033731 U CN 217033731U
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electrolyte
end cover
reference electrode
bin
lithium ion
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韩广帅
余卓平
叶际平
郑丹
赵健
郭阳阳
李文昌
卢朝迪
乔冬冬
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Shanghai Intelligent New Energy Vehicle Technology Innovation Platform Co ltd
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Shanghai Intelligent New Energy Vehicle Technology Innovation Platform Co ltd
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Abstract

The utility model relates to a lithium ion battery electrode material and electrolyte performance testing device, which comprises an electrolyte bin and testing equipment, wherein two ends of the electrolyte bin are sealed by a first end cover and a second end cover, and the first end cover and the second end cover are provided with polar columns; the first end cover and the second end cover are cover plates made of conductive materials, one surfaces of the first end cover and the second end cover, which are contacted with the electrolyte bin, are used for placing electrode plates, and a diaphragm is arranged between the two electrode plates; the electrolyte bin is a container made of insulating materials and used for containing electrolyte, a conducting ring made of conducting materials is arranged in the electrolyte bin, a reference electrode access port used for connecting a reference electrode is formed in the electrolyte bin and matched with the conducting ring, and the reference electrode is connected with the conducting ring after being inserted into the reference electrode access port. Compared with the prior art, the utility model has the advantages of simple structure, low production cost, easy assembly, shortened evaluation time, repeated use and reduced evaluation cost.

Description

Lithium ion battery electrode material and electrolyte performance testing device
Technical Field
The utility model relates to the technical field of lithium ion battery testing, in particular to a lithium ion battery electrode material and electrolyte performance testing device.
Background
Lithium ion batteries have been increasingly widely used in various electronic products and new energy automobile industries due to their advantages of small size, high energy density, no environmental pollution, etc. Particularly, with the development of new energy automobiles, lithium ion batteries are growing explosively. The lithium ion battery generally comprises a positive electrode material, a negative electrode material, a diaphragm, electrolyte and a shell, and the production process generally comprises the steps of slurry stirring, coating and baking, rolling, slitting, winding or laminating, shell filling, liquid injection, packaging, formation and capacity grading. For evaluating a novel anode and cathode material or electrolyte, there are currently 2 mature methods:
1. for the anode and cathode materials, button cells can be manufactured, and the capacity, multiplying power or cycle performance of the electrode material can be tested by taking a lithium sheet as a reference electrode. The method is convenient and simple to operate, but only can evaluate a single electrode material, and cannot simultaneously evaluate the performance of the anode material and the cathode material and the material matching property.
2. The two-electrode battery is generally manufactured by using the anode and cathode materials or the electrolyte, and the production process is as described above. The battery manufactured by the method can only reflect the performance of the whole battery, can not monitor the potential changes of the positive electrode and the negative electrode in different electrolyte systems in real time, and has long consumed time and higher production cost investment.
SUMMERY OF THE UTILITY MODEL
The utility model aims to overcome the defects in the prior art and provide a lithium ion battery electrode material and an electrolyte performance testing device.
The purpose of the utility model can be realized by the following technical scheme:
a lithium ion battery electrode material and electrolyte performance testing device comprises an electrolyte bin and testing equipment, wherein two ends of the electrolyte bin are sealed by a first end cover and a second end cover, the first end cover and the second end cover are provided with pole posts, and the testing equipment is connected with the pole posts;
the first end cover and the second end cover are cover plates made of conductive materials, one surfaces of the first end cover and the second end cover, which are contacted with the electrolyte bin, are used for placing electrode plates, and a diaphragm is arranged between the two electrode plates;
the electrolyte bin is a container made of insulating materials and used for containing electrolyte, a conducting ring made of conducting materials is arranged in the electrolyte bin, a reference electrode access port used for connecting a reference electrode is formed in the electrolyte bin and matched with the conducting ring, the reference electrode is inserted into the reference electrode access port and then conducted with the conducting ring, and the testing equipment is connected with the reference electrode.
Preferably, a groove is formed in the inner wall of the electrolyte bin, the conducting ring is placed in the groove, and the reference electrode access port is communicated with the groove.
Preferably, the electrolyte storage device further comprises an insulating connecting piece, a first connecting hole is formed in the first end cover, a second connecting hole is formed in the second end cover, the insulating connecting piece is connected with the first end cover and the second end cover through the first connecting hole and the second connecting hole, and the electrolyte bin is clamped between the first end cover and the second end cover.
Preferably, the insulating connecting piece comprises a fastener and an insulating washer made of insulating materials, and the insulating washer is a convex washer and matched with the first connecting hole and the second connecting hole.
Preferably, the insulating connecting member includes a fastener and an insulating washer made of an insulating material, and the insulating washer is a convex washer and is matched with the first connecting hole or the second connecting hole.
Preferably, a first sealing washer is arranged at the joint of the first end cover and the electrolyte bin, and a second sealing washer is arranged at the joint of the second end cover and the electrolyte bin.
Preferably, one side of the first end cover, which is in contact with the electrolyte tank, is provided with a first seal ring groove, the first seal ring is installed in the first seal ring groove, one side of the second end cover, which is in contact with the electrolyte tank, is provided with a second seal ring groove, and the second seal ring is installed in the second seal ring groove.
Preferably, the reference electrode access port is a threaded hole, the reference electrode is provided with a matched thread, and the reference electrode is screwed into the reference electrode access port and seals the reference electrode access port.
Preferably, the electrolyte bin is further provided with an exhaust hole, and the exhaust hole is sealed by an air hole sealing element.
Preferably, the exhaust hole is a threaded hole, and the air hole sealing element is an air hole bolt.
Compared with the prior art, the utility model has the following beneficial effects:
(1) the main components are the electrolyte bin, the first end cover and the second end cover, the structure is simple, the production cost is low, the assembly is easy, and the evaluation time is shortened; the electrode plate to be tested is placed on the inner sides of the first end cover and the second end cover, and the electrolyte is poured into the electrolyte bin, so that the device is convenient to use, can be used for performing performance test on different combinations of anode and cathode materials and the electrolyte, can be repeatedly used for many times, and reduces the evaluation cost.
(2) The positive and negative electrode materials and the electrolyte can be combined at will, such as a brand new electrode material or electrolyte, the electrolyte is also suitable for matching the failed electrode plate with the brand new electrolyte, the application scenes are various, the performance and the matching performance of the positive and negative electrode materials and the electrolyte can be evaluated, the potential change can be monitored in real time through the testing equipment, and the evaluation time is shortened.
(3) And sealing rings are arranged between the electrolyte bin and the first end cover and between the electrolyte bin and the second end cover, so that good sealing performance is ensured.
Drawings
FIG. 1 is a schematic diagram of a half-section structure of a performance testing apparatus;
FIG. 2 is a front view of a performance testing apparatus;
FIG. 3 is an isometric view of the electrolyte tank;
FIG. 4 is a schematic view of a half-section structure of the electrolyte tank;
FIG. 5 is an isometric view of the first end cap;
FIG. 6 is a schematic view of a half-section of the first end cap;
FIG. 7 is an isometric view of the second end cap;
FIG. 8 is a schematic view of a half-section of the second endcap;
FIG. 9 is an isometric view of an insulating washer;
FIG. 10 is a schematic view of a half-section of an insulating washer;
FIG. 11 is a schematic view of the structure of an electrode plate and a separator;
reference numerals are as follows: 1. the electrolytic cell comprises an electrolyte bin 1-1, a reference electrode access port 1-2, a groove 2, a first end cover 2-1, a first connecting hole 2-2, a first sealing ring groove 3, a second end cover 3-1, a second connecting hole 3-2, a second sealing ring groove 4, a conducting ring 5 and an insulating gasket; 001. electrode plate, 002, separator.
Detailed Description
The utility model is described in detail below with reference to the figures and the specific embodiments. The present embodiment is implemented on the premise of the technical solution of the present invention, and a detailed implementation manner and a specific operation process are given, but the scope of the present invention is not limited to the following embodiments.
In the drawings, elements that are structurally identical are represented by like reference numerals, and elements that are structurally or functionally similar in each instance are represented by like reference numerals. The size and thickness of each component shown in the drawings are arbitrarily illustrated, and the present invention is not limited to the size and thickness of each component. In the drawings, components have been enlarged where appropriate to make the drawings clearer.
In the description of the embodiments of the present application, it should be understood that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, or the orientations or positional relationships that the product of the application will usually place when in use, or the orientations or positional relationships that a person skilled in the art will usually understand, are only used for convenience of describing the present application and simplifying the description, and do not indicate or imply that the device or element referred to must have a particular orientation, be constructed in a particular orientation, and operate, and therefore, should not be construed as limiting the present application.
Furthermore, the terms "first," "second," "third," and the like are used solely to distinguish one from another, and are not to be construed as indicating or implying relative importance.
In the description of the embodiments of the present application, it should also be noted that, unless otherwise explicitly stated or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present application can be understood in a specific case by those of ordinary skill in the art.
Example 1:
a lithium ion battery electrode material and electrolyte performance testing device comprises an electrolyte bin 1 and testing equipment, and is used for performing performance testing on an electrode plate 001 and electrolyte.
Two ends of the electrolyte bin 1 are sealed by a first end cover 2 and a second end cover 3, the first end cover 2 and the second end cover 3 are provided with polar columns, and test equipment is connected with the polar columns;
the electrolyte chamber 1 is a container made of insulating materials and used for containing electrolyte, a conducting ring 4 made of conducting materials is arranged in the electrolyte chamber 1, a reference electrode access 1-1 used for connecting a reference electrode is arranged on the electrolyte chamber 1, the reference electrode access 1-1 is matched with the conducting ring 4, the reference electrode is conducted with the conducting ring 4 after being inserted into the reference electrode access 1-1, and a test device is connected with the reference electrode; the test equipment is connected with the pole and the reference electrode to measure the potential and the like.
First end cover 2 and second end cover 3 are the apron that conducting material made, and the one side of first end cover 2 and second end cover 3 and electrolyte storehouse 1 contact is used for placing electrode board 001, is provided with diaphragm 002 between two electrode boards 001 that await measuring.
The electrolyte bin 1 is made of polytetrafluoroethylene materials or other insulating materials, and the first end cover 2, the second end cover 3, the conducting ring 4 and the pole are made of stainless steel or other conducting materials.
As shown in fig. 1, 2, 3 and 4, the electrolyte tank 1 of the present embodiment is a hollow cylinder, and as shown in fig. 1, 2, 5, 6, 7 and 8, the first end cap 2 and the second end cap 3 are disk-shaped cover plates, and one surface near the electrolyte tank 1 has a cylindrical protrusion, which is just matched with two ends of the electrolyte tank 1. In order to be matched with the electrolyte chamber 1, the conducting ring 4 is shaped like a circular ring and is arranged in the electrolyte chamber 1, and after the performance testing device is assembled, the conducting ring 4 is parallel to the first end cover 2 and the second end cover 3 and is positioned between the first end cover 2 and the second end cover 3. In other embodiments, the shapes of the electrolyte tank 1, the first end cap 2 and the second end cap may also be changed as desired.
When the electrode material and electrolyte performance test is carried out by using the utility model, electrode plates 001 and diaphragms 002 to be tested are manufactured according to the size of the electrode material and the electrolyte performance test device, the electrode plates 001 and the diaphragms 002 are shown in fig. 11, the conducting rings 4 are installed in the electrolyte chamber 1, the electrolyte chamber 1 is assembled with the first end cover 2 or the second end cover 3, the positive electrode plate 001 and the negative electrode plate 001 are installed on the first end cover 2 and the second end cover 3, the diaphragms 002 are inserted between the two electrode plates 001, the second end cover 3 or the first end cover 2 is assembled with the electrolyte chamber 1, the first end cover 2 and the second end cover 3 seal the electrolyte chamber 1, the electrolyte to be tested is injected into the electrolyte chamber 1, the conducting rings are inserted, the reference electrodes are conducted with the conducting rings 4, and the test device is connected with the pole columns and the reference electrodes to start measurement.
In order to install the conducting ring 4, a groove 1-2 is formed in the inner wall of the electrolyte bin 1, the conducting ring 4 is placed in the groove 1-2, the reference electrode access port 1-1 is communicated with the groove 1-2, and after the reference electrode is inserted into the electrolyte bin 1 along the reference electrode access port 1-1, the reference electrode is conducted with the conducting ring 4 in the groove 1-2. As shown in fig. 3 and 4, the opening of the groove in this embodiment is parallel to the first end cap 2 and the second end cap 3, so as to facilitate the assembly of the conductive ring 4, the first end cap 2 is in sealing fit with one end of the electrolyte chamber 1, and the second end cap 3 is in sealing fit with the other end of the electrolyte chamber 2.
In order to ensure the sealing performance, a first sealing washer is arranged at the joint of the first end cover 2 and the electrolyte chamber 1, and a second sealing washer is arranged at the joint of the second end cover 3 and the electrolyte chamber 1. In this embodiment, as shown in fig. 1, fig. 2, fig. 5, fig. 6, fig. 7 and fig. 8, a first seal ring groove 2-2 is formed in one surface of the first end cover 2, which is in contact with the electrolyte tank 1, the first seal ring is installed in the first seal ring groove 2-2, a second seal ring groove 3-2 is formed in one surface of the second end cover 3, which is in contact with the electrolyte tank 1, and the second seal ring is installed in the second seal ring groove 3-2. In other embodiments, it is also conceivable to provide a sealing gasket groove on the electrolyte tank 1 for the installation of a sealing gasket.
In this embodiment, considering that the positive electrode and the negative electrode in the battery should be in close contact but cannot be directly conducted, the electrolyte tank 1 is not connected with the first end cover 2 and the second end cover 3 through the connecting member, but the first end cover 2 and the second end cover 3 are connected through the insulating connecting member, the first end cover 2 is provided with a first connecting hole 2-1, the second end cover 3 is provided with a second connecting hole 3-1, the insulating connecting member is connected with the first end cover 2 and the second end cover 3 through the first connecting hole 2-1 and the second connecting hole 3-1, after the first end cover 2 and the second end cover 3 are connected and fixed, the electrolyte tank 1 is clamped between the first end cover 2 and the second end cover 3 and sealed by the first end cover 2 and the second end cover 3. In other embodiments, two connectors may be provided, one connector connecting and sealing the electrolyte tank 1 and the first end cap 2, and the other connector connecting and sealing the electrolyte tank 1 and the second end cap 3.
The insulating connecting piece comprises a fastening piece and an insulating washer 5 made of insulating materials, the fastening piece is a bolt and a nut, as shown in fig. 9 and 10, the insulating washer 5 is a convex washer, the first connecting hole 2-1 is an opening penetrating through the first end cover 2, the second connecting hole 3-1 is an opening penetrating through the second end cover 3, the opening can be a smooth through hole or can be provided with threads, and the bolt is locked by the nut after penetrating through the first connecting hole 2-1 and the second connecting hole 3-1. In order to ensure that the first end cap 2 and the second end cap 3 are not directly conducted, in the present embodiment, the insulating gasket 5 is fitted into the first connecting hole 2-1 and the second connecting hole 3-1, and the insulating gasket 5 is installed in both the first connecting hole 2-1 and the second connecting hole 3-1. In other embodiments, the insulating washer 5 may also be matched with the first connection hole 2-1 or the second connection hole 3-1, and one insulating washer 5 is disposed between a corresponding pair of the first connection hole 2-1 and the second connection hole 3-1, so that it is only necessary to ensure that the first end cap 2 and the second end cap 3 are not directly conducted.
In another embodiment, the fastening member is a stud and a nut, one of the first connection hole 2-1 and the second connection hole 3-1 is an internal threaded hole, and the other is an opening, which can be a smooth through hole or a thread, one end of the stud is screwed into the internal threaded hole, and the other end of the stud is locked by the nut after passing through the opening, as shown in fig. 9 and 10, the insulating washer 5 is a convex washer, and the insulating washer 5 is matched with the opening. In other embodiments, it is also contemplated that the first end cap 2 may be provided with an opening and a female screw hole, the second end cap 3 may be provided with a female screw hole and an opening, and the insulating washer 5 may be fitted into the opening.
In the embodiment, in order to fix the reference electrode, the reference electrode access port 1-1 is a threaded hole, the reference electrode is provided with a matched thread, and the reference electrode is screwed into the reference electrode access port 1-1 and seals the reference electrode access port 1-1.
In this embodiment, do not set up the electrolyte entry alone, electrolyte through reference electrode access mouth 1-1 get into electrolyte storehouse 1 can, also can set up the electrolyte entry alone in other embodiments to the design and electrolyte entry complex entry sealing member, electrolyte use the entry sealing member to seal the electrolyte entry after getting into electrolyte storehouse 1.
In this embodiment, do not set up the electrolyte entry alone, for the convenience of electrolyte gets into electrolyte storehouse 1, still is equipped with the exhaust hole on the electrolyte storehouse 1, and the exhaust hole is sealed by the pore sealing spare. In this embodiment, the exhaust hole is the screw hole, and the pore sealing piece is the pore bolt, and in other embodiments, also can set up the pore sealing piece as required, like the embolism etc. after electrolyte gets into electrolyte storehouse 1 and reference electrode inserts electrolyte storehouse 1, use the pore sealing piece to seal electrolyte storehouse 1.
The foregoing detailed description of the preferred embodiments of the utility model has been presented. It should be understood that numerous modifications and variations can be devised by those skilled in the art in light of the above teachings. Therefore, the technical solutions that can be obtained by a person skilled in the art through logical analysis, reasoning or limited experiments based on the prior art according to the concepts of the present invention should be within the scope of protection determined by the claims.

Claims (10)

1. A lithium ion battery electrode material and electrolyte performance testing device is characterized by comprising an electrolyte bin (1) and testing equipment, wherein two ends of the electrolyte bin (1) are sealed by a first end cover (2) and a second end cover (3), the first end cover (2) and the second end cover (3) are provided with polar columns, and the testing equipment is connected with the polar columns;
the first end cover (2) and the second end cover (3) are cover plates made of conductive materials, one surfaces of the first end cover (2) and the second end cover (3) which are in contact with the electrolyte bin (1) are used for placing electrode plates (001), and a diaphragm (002) is arranged between the two electrode plates (001);
the electrolyte bin (1) is a container made of insulating materials and used for containing electrolyte, a conducting ring (4) made of conducting materials is arranged in the electrolyte bin (1), a reference electrode access port (1-1) used for connecting a reference electrode is arranged on the electrolyte bin (1), the reference electrode access port (1-1) is matched with the conducting ring (4), the reference electrode is inserted into the reference electrode access port (1-1) and then conducted with the conducting ring (4), and the testing equipment is connected with the reference electrode.
2. The lithium ion battery electrode material and electrolyte performance testing device according to claim 1, wherein a groove (1-2) is formed in the inner wall of the electrolyte bin (1), the conductive ring (4) is placed in the groove (1-2), and the reference electrode access port (1-1) is communicated with the groove (1-2).
3. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 1, further comprising an insulating connecting member, wherein a first connecting hole (2-1) is formed in the first end cover (2), a second connecting hole (3-1) is formed in the second end cover (3), the insulating connecting member is connected with the first end cover (2) and the second end cover (3) through the first connecting hole (2-1) and the second connecting hole (3-1), and the electrolyte chamber (1) is clamped between the first end cover (2) and the second end cover (3).
4. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 3, wherein the insulating connecting piece comprises a fastener and an insulating washer (5) made of an insulating material, and the insulating washer (5) is a convex washer and is matched with the first connecting hole (2-1) and the second connecting hole (3-1).
5. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 3, wherein the insulating connecting piece comprises a fastener and an insulating washer (5) made of an insulating material, and the insulating washer (5) is a convex washer and is matched with the first connecting hole (2-1) or the second connecting hole (3-1).
6. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 1, wherein a first sealing washer is arranged at the joint of the first end cover (2) and the electrolyte chamber (1), and a second sealing washer is arranged at the joint of the second end cover (3) and the electrolyte chamber (1).
7. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 6, wherein a first sealing ring groove (2-2) is formed in one surface, which is in contact with the electrolyte bin (1), of the first end cover (2), the first sealing gasket is installed in the first sealing ring groove (2-2), a second sealing ring groove (3-2) is formed in one surface, which is in contact with the electrolyte bin (1), of the second end cover (3), and the second sealing gasket is installed in the second sealing ring groove (3-2).
8. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 1, wherein the reference electrode access port (1-1) is a threaded hole, a matching thread is arranged on the reference electrode, and the reference electrode is screwed into the reference electrode access port (1-1) and seals the reference electrode access port (1-1).
9. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 1, wherein the electrolyte bin (1) is further provided with an exhaust hole, and the exhaust hole is sealed by an air hole sealing element.
10. The device for testing the performance of the electrode material and the electrolyte of the lithium ion battery according to claim 9, wherein the vent hole is a threaded hole, and the vent hole sealing element is a vent bolt.
CN202122602172.4U 2021-10-28 2021-10-28 Lithium ion battery electrode material and electrolyte performance testing device Active CN217033731U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202122602172.4U CN217033731U (en) 2021-10-28 2021-10-28 Lithium ion battery electrode material and electrolyte performance testing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202122602172.4U CN217033731U (en) 2021-10-28 2021-10-28 Lithium ion battery electrode material and electrolyte performance testing device

Publications (1)

Publication Number Publication Date
CN217033731U true CN217033731U (en) 2022-07-22

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