CN211376862U - Liquid battery efficiency detection device - Google Patents

Liquid battery efficiency detection device Download PDF

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Publication number
CN211376862U
CN211376862U CN201921822637.3U CN201921822637U CN211376862U CN 211376862 U CN211376862 U CN 211376862U CN 201921822637 U CN201921822637 U CN 201921822637U CN 211376862 U CN211376862 U CN 211376862U
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frame
battery
negative electrode
negative
cell
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王学华
卢苗苗
王浩
王强
申楷赟
白志城
张宗永
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Wuhan Institute of Technology
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Wuhan Institute of Technology
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    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02E60/10Energy storage using batteries

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Abstract

The utility model provides a liquid battery efficiency detection device, which comprises a negative electrode frame, a single battery frame and a positive electrode frame which are connected in sequence; a negative plate is arranged on one side, adjacent to the single-cell frame, of the negative frame, and the negative frame is provided with a negative lead-out screw rod in contact with the negative plate; after the negative electrode frame and the single battery frame are overlapped, the negative electrode frame and the single battery frame form a sealed electrolyte chamber; the monocell frame is provided with a liquid injection hole communicated with the sealed electrolyte cabin; one side of the positive electrode frame, which is adjacent to the single battery frame, is provided with a bipolar plate, and the positive electrode frame is provided with a positive electrode lead-out screw rod which is in contact with the bipolar plate. The utility model discloses a liquid battery efficiency detection device can directly detect the charge-discharge efficiency of liquid battery electrolyte, can be used to quick aassessment and the judgement of battery electrolyte performance and battery polar plate performance, just the utility model discloses a liquid battery efficiency detection device is simple, can dismantle fast and wash to the change of the electrolyte of being convenient for and polar plate has improved detection efficiency greatly.

Description

Liquid battery efficiency detection device
Technical Field
The utility model relates to an electrochemistry energy storage technical field, in particular to liquid battery efficiency detection device.
Background
The existing electrochemical energy storage technology mainly comprises a sodium-sulfur battery, a flow battery, a lead-acid battery, a lithium ion battery and the like. Achieving rapid verification of cell efficiency is an important step in cell development efforts.
Chinese utility model patent with publication number CN 101662040a discloses a method for measuring the first coulomb efficiency of lithium batteries, which mainly comprises manufacturing lithium ion batteries with different specifications, connecting the batteries after liquid injection and aging to a testing device, and recording the charge and discharge efficiency, wherein the device involved in the method needs to use a vacuum-pumping device to vacuumize the interior of the batteries in practical application.
Chinese utility model patent with publication number CN108134141A discloses a static zinc-bromine battery without diaphragm, which adopts top-down sandwich stack structure, and expects to realize the self-discharge effect of reducing the battery, but when the number of stacked layers is too much in actual use, the pressure-bearing capacity of the polar plate is not enough, resulting in the risk of leakage of the battery.
Chinese utility model patent with publication number CN105680082A discloses a structure of a long-life zinc bromine flow battery, which adopts a diaphragm and a circulating pump, resulting in a complicated structure of the battery system, which is not beneficial to miniaturization, and can not truly reflect the theoretical efficiency of the battery system due to the influence of the circulating system.
In addition, for the efficiency or capacity detection of sodium-sulfur batteries, lead-acid batteries and lithium ion batteries, the batteries are generally made into dry battery finished products, and then the efficiency or capacity detection is carried out on the dry battery finished products. In the process of verifying the battery capacity, the formula and the structure of the battery need to be repeatedly redesigned, then the battery is made into a dry battery finished product, a corresponding testing device needs to be designed, the whole process period is long, and the device is complicated. Because flow batteries cannot be made into dry cell batteries, the prior art test devices are not suitable for detecting flow battery efficiency/capacity.
SUMMERY OF THE UTILITY MODEL
In view of this, the present invention is directed to a liquid battery efficiency testing apparatus to solve the problem that the existing testing apparatus cannot detect the efficiency/capacity of the liquid battery.
In order to achieve the above purpose, the technical scheme of the utility model is realized like this:
a liquid battery efficiency detection device comprises a negative electrode frame, a single battery frame and a positive electrode frame which are connected in sequence; a negative plate is arranged on one side, adjacent to the single-cell frame, of the negative frame, and the negative frame is provided with a negative lead-out screw rod in contact with the negative plate; after the negative electrode frame and the single battery frame are overlapped, the negative electrode frame and the single battery frame form a sealed electrolyte chamber; the monocell frame is provided with a liquid injection hole communicated with the sealed electrolyte cabin; and a bipolar plate is arranged on one side of the positive electrode frame, which is adjacent to the single cell frame, and a positive electrode lead-out screw rod which is in contact with the bipolar plate is arranged on the positive electrode frame.
Optionally, the number of the single battery frames is multiple; the rest single cell frames except the single cell frame closest to the negative electrode frame in the plurality of single cell frames are provided with bipolar plates; the bipolar plate is arranged on one side of the residual single cell frame adjacent to the negative electrode frame; after the two adjacent single battery frames are overlapped, the two adjacent single battery frames form a sealed electrolyte cabin, and each single battery frame is provided with a liquid injection hole communicated with the corresponding sealed electrolyte cabin.
Optionally, an upper sealing ring is arranged on one side of the single battery frame adjacent to the negative electrode frame, and a lower sealing ring is arranged on one side of the single battery frame adjacent to the positive electrode frame; the bipolar plate is embedded into the lower sealing ring.
Optionally, a groove is formed on one side of the single cell frame adjacent to the negative electrode frame, and the negative electrode plate is placed in the groove.
Optionally, the negative electrode frame, the single cell frame and the positive electrode frame are provided with assembling holes; the negative electrode frame, the single-cell frame and the positive electrode frame are sequentially connected in parallel through the compression bolts matched with the assembling holes.
Optionally, the negative electrode frame, the single-cell frame and the positive electrode frame are all rectangular frames made of organic glass.
Optionally, the height of the sealed electrolyte compartment is 5-8 mm.
Optionally, the bipolar plate is formed by bonding a metal plate with an anticorrosive conductive coating and a graphite felt by using a conductive sizing material; the negative plate is composed of a metal plate with an anti-corrosion conductive coating.
Optionally, the metal plate is one of an aluminum alloy plate, a copper plate, a titanium plate and a steel plate; the anticorrosion conductive coating is TiN coating, TiC coating, SiC coating and C3N4One of a coating, a boron-doped diamond coating; the conductive adhesive material is one of high polymer resin materials doped with graphite, silver powder and aluminum powder.
Compared with the prior art, liquid battery efficiency detection device have following advantage:
1. the utility model discloses a liquid battery efficiency detection device can directly detect the charge-discharge efficiency of liquid battery electrolyte, can be used to quick aassessment and the judgement of battery electrolyte performance and battery polar plate performance, just the utility model discloses a liquid battery efficiency detection device is simple, can dismantle fast and wash to the change of the electrolyte of being convenient for and polar plate has improved detection efficiency greatly.
2. The utility model discloses a liquid battery efficiency detection device can assemble the battery of different specifications wantonly, convenient and fast's the inspection of the different specification batteries of realization.
Drawings
The accompanying drawings, which form a part hereof, are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention without undue limitation. In the drawings:
fig. 1 is a schematic view of an exploded structure of the three-section liquid battery efficiency detection device of the present invention;
fig. 2 is an exploded front view of the three-section liquid battery efficiency detection device of the present invention;
fig. 3 is an assembled front sectional view of the three-section liquid battery efficiency detection device of the present invention;
fig. 4 is an assembled side sectional view of the three-section liquid battery efficiency detection device of the present invention;
fig. 5 is a graph showing the charging and discharging efficiency of the liquid battery efficiency detecting device for detecting 100 times of the single battery according to the present invention;
fig. 6 is a graph showing that the liquid battery efficiency detecting device of the present invention detects 100 times of charging and discharging efficiency of the double batteries;
fig. 7 is the utility model discloses liquid battery efficiency detection device detects three section battery 100 times charge-discharge efficiency curve chart.
Reference numerals:
1-compression nut, 2-negative electrode frame, 3-negative electrode lead-out screw, 4-single cell frame, 5-compression screw, 6-positive electrode lead-out screw, 7-bipolar plate, 8-liquid injection hole plug, 9-negative electrode plate, 10-upper sealing ring, 11-lower sealing ring, 12-sealed electrolyte cabin and 13-positive electrode frame.
Detailed Description
It should be noted that, in the present invention, the embodiments and features of the embodiments may be combined with each other without conflict.
The present invention will be described in detail with reference to examples.
Example 1
Referring to fig. 1-4, a liquid battery efficiency detection device includes a negative electrode frame 2, a single battery frame 4, and a positive electrode frame 13 connected in sequence; a negative plate 9 is arranged on one side of the negative frame 2, which is adjacent to the single-cell frame 4, and the negative frame 2 is provided with a negative lead-out screw 3 which is in contact with the negative plate 9; after the negative electrode frame 2 and the single battery frame 4 are overlapped, the negative electrode frame 2 and the single battery frame 4 form a sealed electrolyte chamber 12, and at the moment, the negative electrode plate 9 is arranged between the negative electrode frame 2 and the single battery frame 4; the single cell frame 4 is provided with a liquid injection hole communicated with the sealed electrolyte chamber 12; the side of the positive frame 13 adjacent to the cell frame 4 is provided with a bipolar plate 7, and the positive frame 13 is provided with a positive lead screw 6 in contact with the bipolar plate 7.
In this embodiment, through connecting negative pole frame 2, monocell frame 4, positive frame 13 coincide in proper order, in the coincide connection process, make negative pole frame 2 that has negative plate 9 and monocell frame 4 form the sealed electrolyte cabin 12 that can pour into the electrolyte into, and set up bipolar plate 7 in one side that positive frame 13 is close to monocell frame 4, and adopt negative pole extraction screw 3 and anodal extraction screw 6 to be connected with negative plate 9 and bipolar plate 7 contact respectively, realize being connected of this embodiment liquid battery efficiency detection device and battery tester, thereby realize the detection to liquid electrode efficiency, whole device is simple, can dismantle fast and wash, and be convenient for the change of electrolyte and polar plate, detection efficiency has been improved greatly.
Also, in the present embodiment, in order to improve the efficiency of assembly, a groove is provided on the side of the cell frame 4 adjacent to the negative electrode frame 2, and the negative electrode plate 9 is placed in the groove.
The liquid battery efficiency detection device is assembled by the following method:
inserting the compression screw 5 into the assembling hole of the positive electrode frame 13;
embedding the bipolar plate 7 into one side of the positive electrode frame 13, which is adjacent to the single cell frame 4, and in order to improve the sealing performance of the sealed electrolyte chamber 12 in the whole device, arranging an upper sealing ring 10 at one side of the single cell frame 4, which is adjacent to the negative electrode frame 2, and arranging a lower sealing ring 11 at one side of the single cell frame 4, which is adjacent to the positive electrode frame 13, and then, penetrating the compression screw 5 through an assembly hole of the single cell frame 4 to be spliced with the positive electrode frame 13, wherein the bipolar plate 7 is positioned between the positive electrode frame 13 and the single cell frame 4;
placing a negative plate 9 in a groove on one side of a single cell frame 4 adjacent to a negative electrode frame 2, then, penetrating a compression screw 5 through an assembly hole of the negative electrode frame 2, superposing the negative electrode frame 2 and the single cell frame 4 to form a sealed electrolyte cabin 12 with the height of 5mm, arranging an electrolyte injection hole communicated with the sealed electrolyte cabin 12 on the single cell frame 4, and injecting electrolyte to be tested into the sealed electrolyte cabin 12 through the electrolyte injection hole and blocking the electrolyte injection hole by an electrolyte injection hole plug 8 when the battery efficiency test is required;
after a compression screw 5 penetrates through an assembly hole of a negative electrode frame 2, a compression nut 1 is sleeved on the compression screw 5 and screwed to form a single cell, and then a positive electrode lead-out screw 6 and a negative electrode lead-out screw 3 are respectively screwed into a positive electrode frame 13 and the negative electrode frame 2, wherein the positive electrode lead-out screw 6 is in contact with a bipolar plate 7, and the negative electrode lead-out screw 3 is in contact with a negative electrode plate 9.
The assembly of the liquid battery efficiency detection device of this embodiment can be completed according to the above steps, and after the liquid battery efficiency detection device of this embodiment is assembled, the positive electrode frame 13, the bipolar plate 7, the lower seal ring 11, the first cell frame 4 (the cell frame closest to the positive electrode frame 13), the upper seal ring 10, the negative electrode plate 9, and the negative electrode frame 2 are arranged in sequence from bottom to top according to the directions shown in fig. 1 to 4.
The liquid battery efficiency detection device adopting the embodiment is used for detecting the coulomb efficiency of the battery, and specifically comprises the following steps:
injecting the liquid battery electrolyte into the sealed electrolyte chamber 12, and plugging the electrolyte injection hole by the electrolyte injection hole plug 8;
the positive pole of the battery is led out of the screw 6 and is connected with the positive pole of the battery tester by a lead;
connecting the negative lead-out screw rod 3 with the negative pole of the battery tester by using a lead, connecting the positive pole of the battery tester with the positive pole of the battery tester, connecting the negative pole of the battery tester with the negative pole of the battery tester, and testing the coulomb efficiency of the battery;
during testing, recording the charging and discharging parameters of the battery under each charging and discharging period by adopting the testing software of the battery testing instrument, and calculating the coulomb efficiency of the battery according to the following formula:
coulombic efficiency (output amp hour/input amp hour) x 100%.
Example 2
As shown in fig. 1 to 4, the present embodiment is different from embodiment 1 in that: the liquid battery efficiency detecting apparatus of the present embodiment has two cell frames 4, wherein one cell frame 4 is closest to the positive electrode frame 13 (the first cell frame), one cell frame 4 is closest to the negative electrode frame 2 (the second cell frame), a bipolar plate is disposed on a side of the positive electrode frame 13 adjacent to the first cell frame, a bipolar plate is also disposed on a side of the first cell frame adjacent to the negative electrode frame 2, a groove for placing the negative electrode plate 9 on the negative electrode frame 2 is disposed on a side of the second cell frame adjacent to the negative electrode frame 2, when the cell frame 4 closest to the negative electrode frame 2 is overlapped on the cell frame 4 closest to the positive electrode frame 13, the bipolar plate 7 on the cell frame 4 closest to the negative electrode frame 2 and the cell frame 4 closest to the positive electrode frame 13 form a first sealed electrolyte chamber 12, and when the negative electrode frame 2 is overlapped on the cell frame 4 closest to the negative electrode frame 2, the negative frame 2 forms a second sealed electrolyte chamber 12 with the cell frame 4 nearest the negative frame 2, that is, when the second cell frame is stacked on the first cell frame, the negative electrode frame 2 is stacked on the second cell frame, the second cell frame forms a first sealed electrolyte compartment 12 with the first cell frame, the negative electrode frame 2 forms a second sealed electrolyte compartment 12 with the second cell frame, in order to conveniently inject electrolyte to be tested into the two sealed electrolyte cabins 12, the two single cell frames 4 are respectively provided with an injection hole communicated with the corresponding sealed electrolyte cabins 12, that is, the cell frame 4 (first cell frame) nearest to the positive electrode frame 13 is provided with a liquid injection hole communicating with the first sealed electrolyte chamber 12, and the cell frame 4 (second cell frame) nearest to the negative electrode frame 2 is provided with a liquid injection hole communicating with the second sealed electrolyte chamber 12. In order to improve the sealing performance of the two sealed electrolyte compartments 12, an upper sealing ring 10 is arranged on one side of each of the two cell frames 4 adjacent to the negative electrode frame 2, a lower sealing ring 11 is arranged on one side of each of the two cell frames 4 adjacent to the positive electrode frame 13, the bipolar plate 7 on the positive electrode frame 13 is embedded into the lower sealing ring 11 of the first cell frame 4, and the bipolar plate 7 on the first cell frame 4 is embedded into the lower sealing ring 11 of the second cell frame.
In the present embodiment, the two cell frames 4 are assembled by the following method:
after connecting the cell frame 4 (first cell frame) having the bipolar plate 7 and nearest to the positive electrode frame 13 with the positive electrode frame 13 having the bipolar plate 7 by the pressing screw 5, the cell frame 4 (second cell frame) nearest to the negative electrode frame 2 is stacked on the cell frame 4 (first cell frame) having the bipolar plate 7 and nearest to the positive electrode frame 13 to form a first sealed electrolyte chamber 12 having a height of 5mm, and then the negative electrode frame 2 having the negative electrode plate 9 is stacked on the cell frame 4 (second cell frame) nearest to the negative electrode frame 2 to form a second sealed electrolyte chamber 12 having a height of 5mm, and the two-cell battery pack is assembled by tightening the pressing nut 1, wherein the assembly steps of other members in the liquid battery efficiency detecting device are the same as those in embodiment 1, that is, after the liquid battery efficiency detecting device of this embodiment is assembled, according to the direction shown in fig. 1-4, the components are arranged in the order of a positive electrode frame 13, a bipolar plate 7, a lower seal ring 11, a single cell frame 4 (first single cell frame) nearest to the positive electrode frame 13, an upper seal ring 10, the bipolar plate 7, the lower seal ring 11, the single cell frame 4 (second single cell frame) nearest to the negative electrode frame 2, the upper seal ring 10, a negative electrode plate 9, and the negative electrode frame 2 from bottom to top.
The liquid battery efficiency detection device adopting the embodiment is used for detecting the coulomb efficiency of the battery, and specifically comprises the following steps:
injecting the liquid battery electrolyte into the first sealed electrolyte chamber 12 and the second sealed electrolyte chamber 12, and blocking the electrolyte injection hole by the electrolyte injection hole plug 8;
the positive pole of the battery is led out of the positive pole leading screw 6 by a lead and is connected with the positive pole of the battery tester;
connecting the negative lead-out screw rod 3 with the negative pole of the battery tester by using a lead, connecting the positive pole of the battery tester with the positive pole of the battery tester, connecting the negative pole of the battery tester with the negative pole of the battery tester, and testing the coulomb efficiency of the battery;
during testing, recording the charging and discharging parameters of the battery under each charging and discharging period by adopting the testing software of the battery testing instrument, and calculating the coulomb efficiency of the battery according to the following formula:
coulombic efficiency (output amp hour/input amp hour) x 100%.
Example 3
As shown in fig. 1 to 4, the present embodiment is different from embodiment 1 in that: the number of the cell frames 4 in this embodiment is three, wherein one cell frame 4 is closest to the positive electrode frame 13 (the first cell frame), one cell frame 4 is closest to the negative electrode frame 2 (the third cell frame), one cell frame 4 is located between the two cell frames 4 (the second cell frame is located between the first cell frame and the third cell frame), that is, the three cell frames 4 are sequentially stacked from bottom to top in the direction shown in fig. 1 to 4, a bipolar plate is disposed on the side of the positive electrode frame 13 adjacent to the first cell frame, bipolar plates are disposed on the sides of the first cell frame and the second cell frame adjacent to the negative electrode frame 2, a groove for placing the negative electrode plate 9 on the negative electrode frame 2 is disposed on the side of the third cell frame adjacent to the negative electrode frame 2, when the middle cell frame 4 is stacked on the cell frame 4 closest to the positive electrode frame 13, the middle cell frame 4 and the cell frame 4 adjacent to the positive electrode frame 13 form a first sealed electrolyte compartment 12, the cell frame 4 closest to the negative electrode frame 2 and the middle cell frame 4 form a second sealed electrolyte compartment 12 when the cell frame 4 closest to the negative electrode frame 2 is superimposed on the middle cell frame 4, and the negative electrode frame 2 and the cell frame 4 closest to the negative electrode frame 2 form a third sealed electrolyte compartment 12 when the negative electrode frame 2 is superimposed on the cell frame 4 closest to the negative electrode frame 2, i.e. the second cell frame and the first cell frame form a first sealed electrolyte compartment 12 when the second cell frame is superimposed on the first cell frame and the third cell frame is superimposed on the second cell frame and the negative electrode frame 2 is superimposed on the third cell frame, the third cell frame and the second cell frame form a second sealed electrolyte compartment 12, the negative electrode frame 2 and the third single cell frame form a second sealed electrolyte chamber 12, and in order to facilitate the injection of the electrolyte to be measured into the three sealed electrolyte chambers 12, the three single cell frames 4 are each provided with an injection hole communicated with the corresponding sealed electrolyte chamber 12, that is, the single cell frame 4 (the first single cell frame) nearest to the positive electrode frame 13 is provided with an injection hole communicated with the first sealed electrolyte chamber 12, the middle single cell frame 4 (the second single cell frame) is provided with an injection hole communicated with the second sealed electrolyte chamber 12, and the single cell frame 4 (the third single cell frame) nearest to the negative electrode frame 2 is provided with an injection hole communicated with the third sealed electrolyte chamber 12. In order to improve the sealing performance of the three sealed electrolyte compartments 12, upper sealing rings 10 are respectively arranged on the sides of the three single cell frames 4 adjacent to the negative electrode frame 2, lower sealing rings 11 are respectively arranged on the sides of the three single cell frames 4 adjacent to the positive electrode frame 13, the bipolar plate 7 on the positive electrode frame 13 is embedded into the lower sealing ring 11 of the first single cell frame 4, the bipolar plate 7 on the first single cell frame 4 is embedded into the lower sealing ring 11 of the second single cell frame, and the bipolar plate 7 on the second single cell frame is embedded into the lower sealing ring 11 of the third single cell frame.
In the present embodiment, three single cell frames 4 are assembled by the following method:
after connecting the cell frame 4 (first cell frame) with the bipolar plate 7 and nearest to the positive electrode frame 13 with the compression screw 5, the middle cell frame 4 (second cell frame) with the bipolar plate 7 is overlapped on the cell frame 4 (first cell frame) nearest to the positive electrode frame 13 to form a first sealed electrolyte chamber 12 with a height of 5mm, then the cell frame 4 (third cell frame) nearest to the negative electrode frame 2 is overlapped on the middle cell frame 4 (second cell frame) to form a second sealed electrolyte chamber 12 with a height of 5mm, then the negative electrode frame 2 with the negative electrode plate 9 is overlapped on the cell frame 4 (third cell frame) nearest to the negative electrode frame 2 to form a third sealed electrolyte chamber 12 with a height of 5mm, and the assembled three-cell battery is tightened with the compression nut 1, the steps of assembling the other components in the liquid battery efficiency detection apparatus are the same as those in embodiment 1, that is, after the liquid battery efficiency detection apparatus of this embodiment is assembled, the positive electrode frame 13, the bipolar plate 7, the lower seal ring 11, the cell frame 4 (first cell frame) closest to the positive electrode frame 13, the upper seal ring 10, the bipolar plate 7, the lower seal ring 11, the middle cell frame 4 (second cell frame), the upper seal ring 10, the bipolar plate 7, the lower seal ring 11, the cell frame 4 (third cell frame) closest to the negative electrode frame 2, the upper seal ring 10, the negative electrode plate 9, and the negative electrode frame 2 are arranged in this order from bottom to top in the direction shown in fig. 1 to 4.
The liquid battery efficiency detection device adopting the embodiment is used for detecting the coulomb efficiency of the battery, and specifically comprises the following steps:
injecting the liquid battery electrolyte into a first sealed electrolyte chamber 12, a second sealed electrolyte chamber 12 and a third sealed electrolyte chamber 12, and blocking the electrolyte injection hole by an electrolyte injection hole plug 8;
the positive pole of the battery is led out of the positive pole leading screw 6 by a lead and is connected with the positive pole of the battery tester;
connecting the negative lead-out screw rod 3 with the negative pole of the battery tester by using a lead, connecting the positive pole of the battery tester with the positive pole of the battery tester, connecting the negative pole of the battery tester with the negative pole of the battery tester, and testing the coulomb efficiency of the battery;
during testing, recording the charging and discharging parameters of the battery under each charging and discharging period by adopting the testing software of the battery testing instrument, and calculating the coulomb efficiency of the battery according to the following formula:
coulombic efficiency (output amp hour/input amp hour) x 100%.
It should be noted that, in order to improve the detection accuracy, the utility model discloses in, through with negative pole frame 2, each single cell frame 4, the last pilot hole assorted clamp bolt of positive pole frame 13 between negative pole frame 2, each single cell frame 4, the positive pole frame 13 parallel connection in proper order. The negative electrode frame 2, each single-cell frame 4 and the positive electrode frame 13 are all cuboid frames made of organic glass, but the shape of the negative electrode frame is not limited to the cuboid frame, and the negative electrode frame can also be other shapes, such as a square frame, a round frame and the like; the material is not limited to organic glass, but may be other materials, such as Polytetrafluoroethylene (PTFE), High Density Polyethylene (HDPE), Polycarbonate (PC), Polyoxymethylene (POM), and the like.
Furthermore, in the utility model, the bipolar plate 7 is formed by bonding the metal plate with the anti-corrosion conductive coating and the conductive rubber material for the graphite felt, and the negative plate 9 is formed by the metal plate with the anti-corrosion conductive coatingWherein, the metal plate is preferably one of an aluminum alloy plate, a copper plate, a titanium plate and a steel plate; the anticorrosive conductive coating is preferably TiN coating, TiC coating, SiC coating and C3N4One of a coating, a boron-doped diamond coating; the conductive sizing material is preferably one of high polymer resin materials doped with graphite, silver powder and aluminum powder.
Adopt the utility model discloses liquid battery efficiency detection device of embodiment 1-3 detects battery coulomb efficiency, and the testing result is shown as figure 5-7 and table 1 respectively.
As can be seen from figures 5-7 and table 1, the utility model discloses the charge-discharge efficiency that realizes arbitrary festival liquid battery that embodiment 1 ~ 3's liquid battery efficiency detection device can be quick simple and convenient detects, has greatly reduced the preparation cycle of battery sample, has reduced the preparation degree of difficulty, detects for liquid battery's efficiency and provides a reliable way.
TABLE 1
Figure BDA0002250333160000121
The above description is only a preferred embodiment of the present invention, and should not be taken as limiting the invention, and any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (8)

1. The liquid battery efficiency detection device is characterized by comprising a negative electrode frame, a single battery frame and a positive electrode frame which are sequentially connected; a negative plate is arranged on one side, adjacent to the single-cell frame, of the negative frame, and the negative frame is provided with a negative lead-out screw rod in contact with the negative plate; after the negative electrode frame and the single battery frame are overlapped, the negative electrode frame and the single battery frame form a sealed electrolyte chamber; the monocell frame is provided with a liquid injection hole communicated with the sealed electrolyte cabin; and a bipolar plate is arranged on one side of the positive electrode frame, which is adjacent to the single cell frame, and a positive electrode lead-out screw rod which is in contact with the bipolar plate is arranged on the positive electrode frame.
2. The liquid cell efficiency detection apparatus according to claim 1, wherein the single cell frame is plural; the rest single cell frames except the single cell frame closest to the negative electrode frame in the plurality of single cell frames are provided with bipolar plates; the bipolar plate is arranged on one side of the residual single cell frame adjacent to the negative electrode frame; after the two adjacent single battery frames are overlapped, the two adjacent single battery frames form a sealed electrolyte cabin, and each single battery frame is provided with a liquid injection hole communicated with the corresponding sealed electrolyte cabin.
3. The liquid battery efficiency detection apparatus according to claim 1 or 2, wherein an upper seal ring is provided on a side of the cell frame adjacent to the negative electrode frame, and a lower seal ring is provided on a side of the cell frame adjacent to the positive electrode frame; the bipolar plate is embedded into the lower sealing ring.
4. The liquid cell efficiency detection apparatus according to claim 1, wherein a side of the single cell frame adjacent to the negative electrode frame is provided with a groove, and the negative electrode plate is placed in the groove.
5. The liquid battery efficiency detection apparatus according to claim 1, wherein the negative electrode frame, the single battery frame, and the positive electrode frame are each provided with an assembly hole; the negative electrode frame, the single-cell frame and the positive electrode frame are sequentially connected in parallel through the compression bolts matched with the assembling holes.
6. The liquid cell efficiency detection device according to claim 1 or 5, wherein the negative electrode frame, the single cell frame, and the positive electrode frame are rectangular parallelepiped frames made of organic glass.
7. The liquid battery efficiency detection apparatus according to claim 1 or 2, wherein the height of the sealed electrolyte compartment is 5 to 8 mm.
8. The liquid battery efficiency detection device according to claim 1, wherein the bipolar plate is formed by bonding a metal plate with an anticorrosive conductive coating and a graphite felt by using a conductive adhesive; the negative plate is composed of a metal plate with an anti-corrosion conductive coating.
CN201921822637.3U 2019-10-28 2019-10-28 Liquid battery efficiency detection device Active CN211376862U (en)

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