CN216404557U - A lead paste solid-phase electrolysis anode structure with adjustable discharge area - Google Patents
A lead paste solid-phase electrolysis anode structure with adjustable discharge area Download PDFInfo
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- CN216404557U CN216404557U CN202123196767.0U CN202123196767U CN216404557U CN 216404557 U CN216404557 U CN 216404557U CN 202123196767 U CN202123196767 U CN 202123196767U CN 216404557 U CN216404557 U CN 216404557U
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 19
- 239000007790 solid phase Substances 0.000 title claims abstract description 15
- 239000011505 plaster Substances 0.000 claims abstract 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 description 7
- 238000012545 processing Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
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Abstract
Description
技术领域technical field
本实用新型涉及铅膏固相电解技术领域,具体为一种放电面积可调的铅膏固相电解阳极结构。The utility model relates to the technical field of lead paste solid phase electrolysis, in particular to a lead paste solid phase electrolysis anode structure with adjustable discharge area.
背景技术Background technique
固相电解还原是一种新型的膏泥冶炼方法,该方法优点是金属铅回收率比传统火法高,是一种几乎没有污染的清洁生产方法。而目前固相电解成套规模化的成型装备研发还有待开发;主要存在以下问题:固相电解技术阳极结构放电的有效面积有限,阳极利用效率不高;在电解过程中阳极逐渐变薄,使得阳极导电面积与阴极框不适配,阳极泥层会增厚,使槽电压变高,过高的槽电压会导致电化序在铅以下的杂质金属溶解,并在阴极上析出,阴极异常结晶不仅影响它的品质,而且会导致电流效率下降,影响电解效率。因此,需要研制一种能根据阴极框导电率和铅膏处理量大小来调整阳极放电的有效面积,使阳极导电板导电面积与阴极框和处理量适配,提高阳极利用效率,使阳极导电率最大化,从而提高电解效率的放电面积可调的铅膏固相电解阳极结构。Solid-phase electrolytic reduction is a new type of paste-sludge smelting method. The advantage of this method is that the recovery rate of metal lead is higher than that of traditional fire method, and it is a clean production method with almost no pollution. At present, the research and development of large-scale forming equipment for solid-phase electrolysis still needs to be developed; there are mainly the following problems: the effective area of the anode structure for solid-phase electrolysis technology is limited, and the anode utilization efficiency is not high; the anode gradually becomes thinner during the electrolysis process, making the anode If the conductive area does not fit the cathode frame, the anode slime layer will thicken, making the cell voltage higher. Too high cell voltage will cause the impurity metals whose electrochemical sequence is lower than lead to dissolve and precipitate on the cathode. The abnormal crystallization of the cathode will not only affect the Its quality, and it will cause the current efficiency to drop, affecting the electrolysis efficiency. Therefore, it is necessary to develop a method that can adjust the effective area of anode discharge according to the conductivity of the cathode frame and the processing capacity of lead paste, so that the conductive area of the anode conductive plate can be adapted to the cathode frame and the processing capacity, so as to improve the utilization efficiency of the anode and make the anode conductivity The anode structure of lead paste solid-phase electrolysis with adjustable discharge area maximizes the discharge area, thereby improving the electrolysis efficiency.
实用新型内容Utility model content
本实用新型的目的在于提供一种能根据阴极框导电率和铅膏处理量大小来调整阳极放电的有效面积,使阳极导电板导电面积与阴极框和处理量适配,提高阳极利用效率,使阳极导电率最大化,从而提高电解效率的放电面积可调的铅膏固相电解阳极结构。The purpose of this utility model is to provide a method that can adjust the effective area of the anode discharge according to the conductivity of the cathode frame and the processing capacity of the lead paste, so that the conductive area of the anode conductive plate is adapted to the cathode frame and the processing capacity, so as to improve the utilization efficiency of the anode, so that the The anode structure of lead paste solid-phase electrolysis with adjustable discharge area maximizes anode conductivity, thereby improving electrolysis efficiency.
为实现上述目的,本实用新型提供如下技术方案,一种放电面积可调的铅膏固相电解阳极结构,包括纵向导电板,纵向导电板由下至上设置有数层导电盘,每层导电盘均包括前导电半环和后导电半环,前导电半环包括前内半环和前外半环,前内半环和前外半环内侧分别对应设置有卡槽,卡槽内设置有导电辐板,前内半环和前外半环的两端端部分别设置有第三连接板和第二连接板;后导电半环包括后内半环和后外半环,后内半环和后外半环内侧分别对应设置有卡槽,卡槽内设置有导电辐板,后内半环和后外半环的两端端部分别设置有第五连接板和第四连接板;纵向导电板的顶部与阳极导电板连接。In order to achieve the above purpose, the present utility model provides the following technical solutions, a lead paste solid-phase electrolytic anode structure with adjustable discharge area, comprising a longitudinal conductive plate, and the longitudinal conductive plate is provided with several layers of conductive plates from bottom to top, and each layer of conductive plates is It includes a front conductive half ring and a rear conductive half ring. The front conductive half ring includes a front inner half ring and a front outer half ring. The inner sides of the front inner half ring and the front outer half ring are respectively provided with a corresponding slot, and a conductive spoke is arranged in the slot. The two ends of the front inner half ring and the front outer half ring are respectively provided with a third connecting plate and a second connecting plate; the rear conductive half ring includes a rear inner half ring and a rear outer half ring, and the rear inner half ring and the rear The inner side of the outer half ring is respectively provided with a corresponding card slot, a conductive spoke plate is arranged in the card groove, and the two ends of the rear inner half ring and the rear outer half ring are respectively provided with a fifth connection plate and a fourth connection plate; the longitudinal conductive plate The top of it is connected to the anode conductive plate.
进一步地,每层导电盘均通过第一连接板螺栓连接纵向导电板。Further, each layer of conductive plates is bolted to the longitudinal conductive plates through the first connecting plate.
进一步地,前导电半环和后导电半环的内圈分别通过第三连接板和第五连接板螺栓连接,外圈分别通过第二连接板和第四连接板螺栓连接。Further, the inner rings of the front conductive half-ring and the rear conductive half-ring are respectively connected by bolts through the third connection plate and the fifth connection plate, and the outer rings are connected by bolts through the second connection plate and the fourth connection plate respectively.
进一步地,纵向导电板采用铜板外部包裹不锈钢制成,导电盘采用不锈钢制成。Further, the longitudinal conductive plate is made of stainless steel wrapped around the copper plate, and the conductive disc is made of stainless steel.
本实用新型的有益效果是:本实用新型通过在纵向导电板上设置数层导电盘,导电盘包括若干块导电辐板,可以调整导电盘的层数以及导电辐板的数量来调节阳极放电面积,使阳极导电面积与阴极框的导电率以及铅膏处理量适配,从而提高阳极利用效率,增大阳极导电率和电解效率。The beneficial effects of the utility model are: the utility model arranges several layers of conductive disks on the longitudinal conductive plate, and the conductive disk includes a plurality of conductive spokes, the number of layers of the conductive disk and the number of the conductive spokes can be adjusted to adjust the anode discharge area , so that the conductive area of the anode is adapted to the conductivity of the cathode frame and the processing capacity of the lead paste, thereby improving the utilization efficiency of the anode, increasing the conductivity of the anode and the electrolysis efficiency.
附图说明Description of drawings
图1为本实用新型的整体结构示意图;Fig. 1 is the overall structure schematic diagram of the present utility model;
图2为本实用新型中前导电半环的剖面结构示意图;2 is a schematic cross-sectional structure diagram of the front conductive half-ring in the utility model;
图中:1-纵向导电板,2-第一连接板,31-前内半环,32-前外半环,33-第二连接板,34-第三连接板,4-导电辐板,51-后内半环,52-后外半环,53-第四连接板,54-第五连接板,6-阳极导电板。In the figure: 1-longitudinal conductive plate, 2-first connecting plate, 31-front inner half ring, 32-front outer half ring, 33-second connecting plate, 34-third connecting plate, 4-conducting web, 51-rear inner half ring, 52-rear outer half ring, 53- fourth connecting plate, 54- fifth connecting plate, 6- anode conductive plate.
具体实施方式Detailed ways
下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present utility model will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present utility model. Obviously, the described embodiments are only a part of the embodiments of the present utility model, rather than all the implementations. example. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.
请参阅图1,本实用新型提供一种技术方案,一种放电面积可调的铅膏固相电解阳极结构,包括纵向导电板1,纵向导电板1由下至上设置有数层导电盘,每层导电盘均包括前导电半环和后导电半环,前导电半环包括前内半环31、前外半环32,前内半环31和前外半环32内侧分别对应设置有卡槽,卡槽内设置有导电辐板4,前内半环31和前外半环32的两端端部分别设置有第三连接板34和第二连接板33;后导电半环包括后内半环51和后外半环52,后内半环51和后外半环52内侧分别对应设置有卡槽,卡槽内设置有导电辐板4,后内半环51和后外半环52的两端端部分别设置有第五连接板54和第四连接板53;纵向导电板1的顶部与阳极导电板6连接。Please refer to FIG. 1, the present utility model provides a technical solution, a lead paste solid-phase electrolytic anode structure with adjustable discharge area, comprising a longitudinal
每层导电盘均通过第一连接板2螺栓连接纵向导电板1。Each layer of conductive plates is bolted to the longitudinal
前导电半环和后导电半环的内圈分别通过第三连接板34和第五连接板54螺栓连接,外圈分别通过第二连接板33和第四连接板53螺栓连接。The inner rings of the front conductive half-ring and the rear conductive half-ring are connected by bolts through the third connecting
纵向导电板1采用铜板外部包裹不锈钢制成,导电盘采用不锈钢制成。The longitudinal
本实用新型通过在纵向导电板1上设置数层导电盘,导电盘内设置有若干导电辐板4,使用时可以调整导电盘的层数以及导电辐板4的数量来调节阳极放电面积,使阳极导电面积与阴极框的导电率以及铅膏处理量适配,从而提高阳极利用效率,增大阳极导电率和电解效率。In the utility model, several layers of conductive plates are arranged on the longitudinal
尽管已经示出和描述了本实用新型的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本实用新型的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本实用新型的范围由所附权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes and modifications can be made to these embodiments without departing from the principles and spirit of the present invention , alternatives and modifications, the scope of the present invention is defined by the appended claims and their equivalents.
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