CN216155988U - Electrophoresis anolyte circulation system and electrophoresis coating system - Google Patents
Electrophoresis anolyte circulation system and electrophoresis coating system Download PDFInfo
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- CN216155988U CN216155988U CN202122264585.6U CN202122264585U CN216155988U CN 216155988 U CN216155988 U CN 216155988U CN 202122264585 U CN202122264585 U CN 202122264585U CN 216155988 U CN216155988 U CN 216155988U
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- 238000001962 electrophoresis Methods 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims description 10
- 239000011248 coating agent Substances 0.000 title claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 84
- 239000007788 liquid Substances 0.000 claims abstract description 51
- 238000007865 diluting Methods 0.000 claims abstract description 14
- 239000012895 dilution Substances 0.000 claims description 28
- 238000010790 dilution Methods 0.000 claims description 28
- 238000004070 electrodeposition Methods 0.000 claims description 5
- 238000005259 measurement Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 4
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- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000002035 prolonged effect Effects 0.000 description 5
- 238000012423 maintenance Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- -1 organic acid radical ions Chemical class 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
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- 229920005989 resin Polymers 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
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- 125000002091 cationic group Chemical group 0.000 description 1
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Abstract
The utility model discloses an electrophoresis anolyte circulating system, which comprises: the diluting box is internally provided with a liquid inlet area and a liquid outlet area, the liquid inlet area of the diluting box is provided with a pure water supply pipe and an anolyte inlet, the liquid outlet area of the diluting box is provided with an anolyte outlet and an overflow port, and a plurality of water retaining parts are arranged between the liquid inlet area and the liquid outlet area of the diluting box and form a circuitous water flow path through the water retaining parts; the anode assembly is connected with the anolyte outlet through a liquid inlet pipe and is connected with the anolyte inlet through a liquid return pipe to form a circulating pipeline; and the circulating pump is arranged on the circulating pipeline. The technical scheme can save water, ensure the production quality requirement and realize low carbon and environmental protection. Meanwhile, the whole system is simple in structure, and has the characteristics of strong practicability, high integrity, simplicity in processing, low manufacturing cost and convenience in popularization.
Description
Technical Field
The utility model is used in the field of automobile manufacturing, and particularly relates to an electrophoresis anolyte circulating system and an electrophoresis coating system.
Background
The cathode electrophoresis is a coating process generally adopted in the manufacture of automobile bodies, and is a main means for prolonging the service life (corrosion resistance) of the automobile bodies. The electrodeposition paint used in the cathodic electrodeposition is a cationic (positively charged) resin and a pigment, and the object to be coated (vehicle body) serves as a cathode.
In the process of cathode electrophoretic coating, when resin cations with positive charges are deposited on a workpiece, organic acid radical ions (acetate ions and formate ions which are derived from electrophoretic paint) are continuously generated in the bath solution and are correspondingly accumulated in the bath solution. When too much organic acid radical ion accumulates in the bath solution, it directly results in a decrease in the pH of the bath solution and an increase in conductivity. In order to ensure optimum coating results and stable paint liquids, these acid ions must be removed continuously during the coating process by means of an anodic circulation system. In the prior art, the anolyte is generally subjected to a renewal cycle to continuously remove the acid radical ions, and a large amount of pure water is required for dilution during the process, so that the water consumption is high, and the dilution efficiency is low.
SUMMERY OF THE UTILITY MODEL
The utility model aims to at least solve one of the technical problems in the prior art, and provides an electrophoresis anolyte circulating system and an electrophoresis coating system, which can save water, ensure the production quality requirement and achieve low carbon and environmental protection.
The technical scheme adopted by the utility model for solving the technical problems is as follows:
in a first aspect, an electrophoresis anolyte circulation system comprises:
the diluting box is internally provided with a liquid inlet area and a liquid outlet area, the liquid inlet area of the diluting box is provided with a pure water supply pipe and an anolyte inlet, the liquid outlet area of the diluting box is provided with an anolyte outlet and an overflow port, and a plurality of water retaining parts are arranged between the liquid inlet area and the liquid outlet area of the diluting box and form a circuitous water flow path through the water retaining parts;
the anode assembly is connected with the anolyte outlet through a liquid inlet pipe and is connected with the anolyte inlet through a liquid return pipe to form a circulating pipeline;
and the circulating pump is arranged on the circulating pipeline.
With reference to the first aspect, in certain implementations of the first aspect, the pure water supply pipe forms a water inlet at a bottom of the liquid inlet zone.
With reference to the first aspect and the foregoing implementation manners, in some implementation manners of the first aspect, the method further includes:
the conductivity meter is used for detecting the conductivity of the anolyte in the dilution tank;
the first control valve is arranged at the overflow port;
and the PLC is connected with the conductivity meter and the first control valve and controls the first control valve to be opened and closed according to the measurement result of the conductivity meter.
With reference to the first aspect and the foregoing implementations, in certain implementations of the first aspect, the conductivity meter is disposed in the liquid intake zone.
With reference to the first aspect and the foregoing implementation manners, in some implementation manners of the first aspect, the liquid return pipe is provided with a branch for directly discharging the anolyte, the liquid return pipe is provided with a second control valve downstream of a connection port of the branch, and the branch is provided with a third control valve.
With reference to the first aspect and the foregoing implementation manners, in certain implementation manners of the first aspect, the water baffle includes a water baffle extending downward from a top of the dilution tank and defining a passage port at a bottom through which the anolyte passes.
With reference to the first aspect and the foregoing implementation manners, in certain implementation manners of the first aspect, the circulation pump is disposed at the liquid inlet pipe.
With reference to the first aspect and the foregoing implementation manners, in certain implementation manners of the first aspect, the liquid inlet pipe is provided with a filter downstream of the circulation pump.
With reference to the first aspect and the implementations described above, in certain implementations of the first aspect, the dilution tank is provided with an agitation device in the liquid intake zone.
In a second aspect, an electrocoating system includes the electrophoretic anolyte circulation system described in any implementation manner of the first aspect.
One of the above technical solutions has at least one of the following advantages or beneficial effects: when the anolyte is renewed and circulated, the anolyte continuously renews and circulates the anolyte of the anode assembly under the action of the circulating pump, and during the renewal, the anolyte of the anode assembly is mixed with pure water in the dilution tank to realize dilution. The anolyte of the anode assembly backflow is mixed with the pure water flowing into the pure water supply pipe in the liquid inlet area, then flows through the circuitous water flow path formed by the water retaining part, the water flow path is prolonged, the mixing time is prolonged, and the anolyte is fully combined and then flows out of the overflow port or circulates through the anolyte outlet. This technical scheme is with pure water and anolyte intensive mixing in the dilution box, and the density of avoiding hesitation pure water is less than the anolyte, and layering, mixing are not abundant appears, and lead to the pure water extravagant. The technical scheme can save water, ensure the production quality requirement and realize low carbon and environmental protection. Meanwhile, the whole system is simple in structure, and has the characteristics of strong practicability, high integrity, simplicity in processing, low manufacturing cost and convenience in popularization.
Additional aspects and advantages of the utility model will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the utility model.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 is a schematic structural diagram of an embodiment of an electrophoresis anolyte circulation system according to the present invention.
Detailed Description
Reference will now be made in detail to the present preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout.
In the utility model, the meaning of "a plurality" is one or more, the meaning of "a plurality" is more than two, and the terms of "more than", "less than", "more than" and the like are understood to exclude the number; the terms "above", "below", "within" and the like are understood to include the instant numbers. In the description of the present invention, if there is description of "first" and "second" only for the purpose of distinguishing technical features, it is not to be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features or implicitly indicating the precedence of the indicated technical features.
In the present invention, unless otherwise specifically limited, the terms "disposed," "mounted," "connected," and the like are to be understood in a broad sense, and for example, may be directly connected or indirectly connected through an intermediate; can be fixedly connected, can also be detachably connected and can also be integrally formed; may be mechanically coupled, may be electrically coupled or may be capable of communicating with each other; either as communication within the two elements or as an interactive relationship of the two elements. The specific meaning of the above-mentioned words in the present invention can be reasonably determined by those skilled in the art in combination with the detailed contents of the technical solutions.
Referring to fig. 1, an embodiment of the present invention provides an electrophoresis anolyte circulation system including a dilution tank 1, an anode assembly 2, and a circulation pump 3.
Wherein, dilution box 1 is inside to form into liquid district 11 and play liquid district 12, and dilution box 1 is equipped with pure water supply pipe 13, anolyte import 14 in liquid district 11, and pure water supply pipe 13 is arranged in supplying pure water to dilution box 1 to dilute the anolyte in dilution box 1. The diluting box 1 is provided with an anolyte outlet 15 and an overflow port 16 in the liquid outlet area 12, part of the diluted anolyte flows into the anode assembly 2 again through the anolyte outlet 15 to realize circulation, and part of the diluted anolyte is discharged through the overflow port 16. In order to improve the mixing effect of pure water and anolyte, a plurality of water retaining parts are arranged between the liquid inlet area 11 and the liquid outlet area 12 in the dilution tank 1, and a circuitous water flow path is formed by the water retaining parts.
Referring to fig. 1, when the anolyte is renewed and circulated, the anolyte continuously renews and circulates the anolyte of the anode assembly 2 under the action of the circulation pump 3, and meanwhile, the anolyte of the anode assembly 2 is mixed with pure water in the dilution tank 1 to realize dilution. The anolyte flowing back from the anode assembly 2 is mixed with the pure water flowing in from the pure water supply pipe 13 in the liquid inlet area 11, and then flows through the circuitous water flow path formed by the water retaining part, so that the water flow path is prolonged, the mixing time is prolonged, and the anolyte is fully combined and then flows out from the overflow port 16 or circulates through the anolyte outlet 15. This technical scheme is with pure water and anolyte intensive mixing in dilution tank 1, and the density of avoiding hesitation pure water is less than the anolyte, and layering, mixing are not abundant appears, and lead to the pure water extravagant. The technical scheme can save water, ensure the production quality requirement and realize low carbon and environmental protection. Meanwhile, the whole system has simple structure, strong practicability, high integrity, simple processing and manufactureLow price and convenient popularization. In some practical examples, the pure water consumption of the electrophoresis anode is reduced by 2779.8m3The water-saving effect is obvious every year.
It is understood that the circulating pump 3 can be disposed in the liquid inlet pipe 21 or the liquid return pipe 22, for example, in the embodiment shown in fig. 1, the circulating pump 3 is disposed in the liquid inlet pipe 21, and further, the liquid inlet pipe 21 is disposed with the filter 5 downstream of the circulating pump 3, so as to prevent impurities in the anolyte from entering the anode assembly 2, and prolong the service life of the anode membrane.
Through the principle that the density of water is less than the anolyte, prolong the size of pure water supply pipe 13, pure water supply pipe 13 forms the water inlet in the bottom of liquid inlet district 11, for example in some embodiments, the water inlet of pure water supply pipe 13 is apart from the 10cm of dilution tank 1 bottom distance, adds water improvement at the anolyte surface originally and supplys pure water under water, makes pure water and anolyte combine more fully, further promotes the mixed effect of pure water and anolyte, practices thrift the pure water quantity.
In the prior art, since the density of pure water is lower than that of the anolyte, so that the insufficiently mixed pure water can be directly discharged through the overflow port 16, the utilization rate of the pure water is greatly influenced, and in some embodiments, referring to fig. 1, the electrophoresis anolyte circulation system further comprises a conductivity meter 6, a first control valve 71 and a PLC72, wherein the conductivity meter 6 is used for detecting the conductivity of the anolyte in the dilution tank 1, and the first control valve 71 is arranged at the overflow port 16 and is used for controlling the opening and closing of the overflow port 16. The PLC72 is connected to the conductivity meter 6 and the first control valve 71, and the PLC72 controls the first control valve 71 to open and close according to the measurement result of the conductivity meter 6. The embodiment can quantitatively monitor the preferential discharge of the liquid with higher concentration live, and realizes automatic discharge.
Wherein, in order to accurately know the mixing effect of the pure water and the anolyte, the conductivity meter 6 is arranged in the liquid inlet area 11.
It is understood that, in order to realize automatic water replenishment, a control valve may be provided in the pure water supply pipe 13, and the PLC72 controls the pure water supply pipe 13 to replenish water automatically according to the conductivity of the anode liquid in the dilution tank 1 detected by the conductivity meter 6.
In the prior art, when the anode assembly 2 is abnormal and needs to be maintained and replaced, the anode assembly 2 needs to be cleaned by continuously circulating the circulating pump 3, the dilution tank 1 is emptied and cleaned for multiple times, the working time and the long-term efficiency are low, and the pure water consumption is large. In view of this, in some embodiments, referring to fig. 1, the return pipe 22 is provided with a branch 8 for discharging anolyte directly, the return pipe 22 being provided with a second control valve 23 downstream of the junction of the branch 8, the branch 8 being provided with a third control valve 81. In this embodiment, when the anode assembly 2 is abnormal and needs to be repaired and replaced, the second control valve 23 is closed, and the third control valve 81 is opened, so that the anolyte for cleaning the anode assembly 2 can be directly discharged, the anolyte is prevented from entering the dilution tank 1, and the maintenance steps and the cycle number are reduced. The maintenance time is effectively reduced by 5.5h, and the reduction of the maintenance time also effectively reduces the use amount of pure water during maintenance.
Referring to fig. 1, in some embodiments the water stop comprises a water stop 17, the water stop 17 extending downwardly from the top of the dilution tank 1 and defining at the bottom a passage opening 18 for the passage of anolyte, the flow of water being forced from the water bottom through the water stop 17 passage opening. By changing the direction of the water flow, the water flow path is prolonged, and the mixing time is increased, so that the water flows out after being fully combined.
In some embodiments, the dilution tank 1 is provided with stirring means in the intake zone 11 in order to enhance the mixing effect of the pure water and the anolyte.
The embodiment of the utility model also provides an electrophoretic coating system which comprises the electrophoretic anolyte circulating system in any one of the embodiments.
In the description herein, references to the description of the term "example," "an embodiment," or "some embodiments," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the utility model. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The utility model is not limited to the above embodiments, and those skilled in the art can make equivalent modifications or substitutions without departing from the spirit of the utility model, and such equivalent modifications or substitutions are included in the scope of the claims of the present application.
Claims (10)
1. An electrophoresis anolyte circulation system comprising:
the diluting box is internally provided with a liquid inlet area and a liquid outlet area, the liquid inlet area of the diluting box is provided with a pure water supply pipe and an anolyte inlet, the liquid outlet area of the diluting box is provided with an anolyte outlet and an overflow port, and a plurality of water retaining parts are arranged between the liquid inlet area and the liquid outlet area of the diluting box and form a circuitous water flow path through the water retaining parts;
the anode assembly is connected with the anolyte outlet through a liquid inlet pipe and is connected with the anolyte inlet through a liquid return pipe to form a circulating pipeline;
and the circulating pump is arranged on the circulating pipeline.
2. An electrophoresis anolyte circulation system according to claim 1 characterized in that said pure water supply conduit forms a water inlet at the bottom of said liquid inlet zone.
3. An electrophoresis anolyte circulation system according to claim 1 further comprising:
the conductivity meter is used for detecting the conductivity of the anolyte in the dilution tank;
the first control valve is arranged at the overflow port;
and the PLC is connected with the conductivity meter and the first control valve and controls the first control valve to be opened and closed according to the measurement result of the conductivity meter.
4. An electrophoresis anolyte circulation system according to claim 3 wherein said conductivity meter is disposed in said inlet region.
5. An electrophoresis anolyte circulation system according to claim 1 characterized in that said return tube is provided with a branch for direct discharge of anolyte, said return tube being provided with a second control valve downstream of the junction of said branch, said branch being provided with a third control valve.
6. The electrophoresis anolyte circulation system of claim 1 wherein said water barrier comprises a water barrier extending downwardly from the top of said dilution tank and defining at the bottom a passage opening through which anolyte passes.
7. The electrophoresis anolyte circulation system of claim 1, wherein said circulation pump is disposed in said inlet liquor pipe.
8. An electrophoresis anolyte circulation system according to claim 7 characterized in that said inlet pipe is provided with a filter downstream of said circulation pump.
9. An electrophoresis anolyte circulation system according to claim 1 characterized in that said dilution tank is provided with stirring means in said inlet region.
10. An electrodeposition coating system comprising the electrodeposition anolyte circulation system according to any one of claims 1 to 9.
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CN118028955A (en) * | 2024-04-10 | 2024-05-14 | 苏州智程半导体科技股份有限公司 | Wafer electroplating solution processing device and processing method |
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CN118028955A (en) * | 2024-04-10 | 2024-05-14 | 苏州智程半导体科技股份有限公司 | Wafer electroplating solution processing device and processing method |
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