CN215574914U - Device for automatically measuring ion content in water samples such as stratum water - Google Patents
Device for automatically measuring ion content in water samples such as stratum water Download PDFInfo
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Abstract
The utility model relates to a device for automatically measuring the ion content in water samples such as formation water and the like, which comprises a measuring pool, a measuring and controlling mechanism connected with the measuring pool, and a standard solution supplying mechanism connected with the measuring pool and the measuring and controlling mechanism, wherein the measuring pool is connected with a sample water supplying pipe to be measured, a deionized water supplying pipe, a standard hydrochloric acid solution supplying pipe and an ORP electrode; the measurement and control mechanism comprises a main board, a signal board and a control board, wherein the signal board and the control board are connected with the main board, and the signal board is connected with the ORP electrode. The method adopts the ORP electrode, identifies the end point through the change of ORP oxidation-reduction potential in the titration process, replaces manual judgment of the color change end point in titration, and replaces a pH titration method for judging the end point through the pH reaching a preset value, so that the measurement accuracy and consistency are good.
Description
Technical Field
The utility model relates to the field of chemical water quality analysis, in particular to a device for automatically measuring the ion content in water samples such as formation water.
Background
Carbonate and bicarbonate are main anions in separated water in mining industries such as crude oil, and the determination of the concentration of carbonate and bicarbonate in formation water in the mining process is helpful for determining the hardness and the type of the formation water and the amount of carbon dioxide in the separated water. At present, phenolphthalein and methyl orange are used as indicators for measuring carbonate/bicarbonate/hydroxyl in water, standard hydrochloric acid with known concentration is used for titration, and due to the fact that the color change pH range of phenolphthalein is 8.2-10.0, and the color change pH range of methyl orange is 3.1-4.4, different people have the problem of different judgment end points in the color change range of the indicators, errors in the use amount of hydrochloric acid are easily caused, and errors exist in the calculation of the content of carbonate/bicarbonate/hydroxyl.
In addition, at present, an ion selection electrode and a carbon dioxide gas-sensitive electrode for measuring the concentration of hydrogen ions are adopted to automatically measure bicarbonate radical and carbonate radical, the measurement range of the ion selection electrode is 1-10mol/L, the measurement range of the carbon dioxide gas-sensitive electrode is 10-5mol/L, and the device can continuously work for a long time, but has strict requirements on the accuracy and the stability of the external environment and the electrodes.
The two schemes can only carry out off-line measurement in a laboratory, cannot carry out on-line and real-time measurement, and have certain limitation.
SUMMERY OF THE UTILITY MODEL
The utility model aims to overcome the defects in the prior art and provide a device for automatically measuring the ion content in water samples such as formation water and the like.
In order to achieve the purpose, the technical scheme adopted by the utility model is as follows:
a device for automatically measuring the ion content in water samples such as formation water comprises a measuring pool, a measuring and controlling mechanism connected with the measuring pool, and a standard solution supplying mechanism connected with the measuring pool and the measuring and controlling mechanism, wherein the measuring pool is connected with a sample water supplying pipe to be measured, a deionized water supplying pipe, a standard hydrochloric acid solution supplying pipe and an ORP electrode;
the measurement and control mechanism comprises a main board, a signal board and a control board, wherein the signal board and the control board are connected with the main board, the signal board is connected with the ORP electrode, and the control board is connected with the first constant delivery pump, the second constant delivery pump and the third constant delivery pump.
Further, the bottom of the measuring pool is provided with a stirrer, and the stirrer is in signal connection with the control panel.
Further, the bottom of the measuring tank is connected with a sewage discharge port through a sewage discharge electromagnetic valve, and an overflow port is arranged on the side face of the measuring tank.
Furthermore, the mainboard is connected with a power supply and a display screen.
The method for automatically measuring the ion content in water samples such as formation water comprises the following steps:
s1, adding 2-50mL of sample water to be detected into the measuring pool through a first quantitative pump, and recording the volume of the sample water to be detected as V;
s2, adding 50mL of boiled deionized water into the measuring cell through a third quantitative pump;
s3, turning on the stirrer, and adding a standard acid solution with known concentration into the measuring pool at a certain speed through a second quantitative pump, wherein the concentration is recorded as c(HCl)；
S4, determining the ORP value of the water sample solution to be measured in the step S3;
s5, whether the current number of titrations is out of limit? If yes, the test is abnormal and the test is finished; if not, the following step S6 is performed;
s6, judging whether the characteristic point of the first end point appears or not, and if the characteristic point of the first end point appears, recording the volume V of the acid standard solution consumed by the characteristic point from the beginning to the first end point1Performing the following step S7; if the characteristic point of the first end point does not appear, the following step S7 is performed;
s7, judging whether the characteristic point of the second end point appears or not, if the characteristic point of the second end point appears, the method comprises the following steps: if the characteristic point of the first end point occurs before, recording the volume V of the acid standard solution consumed from the characteristic point of the first end point to the characteristic point of the second end point2Performing the following step S8;
if the characteristic point of the first end point does not appear before, recording the characteristic points from the beginning to the second end pointVolume V of the standard solution of the acid consumed at the end of the feature point2Performing the following step S8;
if the characteristic point of the second end point does not appear, the steps S3, S4, S5, S6 and S7 are sequentially carried out until the characteristic point of the second end point appears or the current titration frequency exceeds the limit.
Further, the step S8: according to V1、V2And concentration c of standard acid solution(HCl)Calculating the concentration of carbonate, bicarbonate and hydroxyl by using the sampling volume V;
for the water sample to be detected without the characteristic point of the first end point and only with the characteristic point of the second end point:
in this case, the sample water to be tested does not contain carbonate but contains only bicarbonate, the volume of the sample water to be tested in step S1 is denoted as V, the volume of the hydrochloric acid standard solution added in step S7 is denoted as V2, and the concentration thereof is denoted as c (hcl). The calculation formula is as follows:
ρ(HCO3-)＝V2×M3×c(HCl)/V
in the formula (I), the compound is shown in the specification,
ρ(HCO3-)——HCO3-concentration of (3), g/L;
v2 — volume of acid standard solution consumed at feature point from start to second endpoint, mL, in step S7;
M3——HCO3-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Further, for the sample water to be measured having both the characteristic point of the first end point and the characteristic point of the second end point, according to the volume V1 of the hydrochloric acid solution added in step S6 and the volume V2 of the acid standard solution consumed from the characteristic point of the first end point to the characteristic point of the second end point in step S7:
OH in solution when V1 > V2-And CO32-Coexistence of
ρ(OH-)＝(V1-V2)×M1×c(HCl)/V
ρ(CO32-)＝V2×M2×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(OH-)——OH-concentration of (3), g/L;
ρ(CO32-)——CO32-concentration of (3), g/L;
v1 — volume of acid standard solution consumed at feature point from start to first endpoint, mL, in step S6;
v2 — volume V2, mL of acid standard solution consumed from the characteristic point of the first endpoint to the characteristic point of the second endpoint in step S7;
M1——OH-molar mass of (a), g/mol;
M2——CO32-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Further, when V1 < V2, HCO in solution3-And CO32-Coexistence of
ρ(CO32-)＝V1×M2×c(HCl)/V
ρ(HCO3-)＝(V2-V1)×M3×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(CO32-)——CO32-concentration of (3), g/L;
ρ(HCO3-)——HCO3-concentration of (3), g/L;
v1 — volume of acid standard solution consumed at feature point from start to first endpoint, mL, in step S6;
v2 — volume V2, mL of acid standard solution consumed from the characteristic point of the first endpoint to the characteristic point of the second endpoint in step S7;
M2——CO32-molar mass of (a), g/mol;
M3——HCO3-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Further, when V1 ═ V2, only CO3 was present in the solution2-
ρ(CO32-)＝V1×M2×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(CO32-)——CO32-concentration of (3), g/L;
v1 — volume of acid standard solution consumed at feature point from start to first endpoint, mL, in step S6;
M2——CO32-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Further, the characteristic point of the first end point is a point of which the oxidation-reduction potential value is in the range of 180-310mV and the oxidation-reduction potential variation value is maximum in unit time; the characteristic point of the second endpoint is the point with the oxidation-reduction potential value within the range of 310-440mV and the oxidation-reduction potential variation value in unit time is maximum.
The utility model has the beneficial effects that: 1. by adopting the ORP electrode, the endpoint is identified through the change of ORP oxidation-reduction potential in the titration process, the manual judgment of the color change endpoint in the titration is replaced, the endpoint judgment through a pH titration method that the pH value reaches a preset value is replaced, and the measurement accuracy and consistency are good;
2. the limit that the optical titration method is only suitable for colorless and low-turbidity sample water is overcome, the patent technology can measure not only colorless and low-turbidity sample water, but also colored and certain-turbidity sample water, the application range is wide, and online and real-time measurement can be realized.
The utility model can be adapted to the pollution of impurities in separation water in oil fields, mining and the like by designing a special titration cell and an oxidation-reduction electrode to identify titration end points, and can determine 2 titration end points through the change of oxidation-reduction potential by directly titrating hydrochloric acid or sulfuric acid standard solution without adding indicators such as phenolphthalein, methyl orange and the like, thereby being capable of accurately measuring carbonate, bicarbonate and hydroxyl in water quality in real time.
Drawings
FIG. 1 is a schematic structural diagram of a measuring device according to the present invention;
FIG. 2 is a schematic view of a measurement process according to the present invention;
FIG. 3 is a graph showing the standard hydrochloric acid addition amount and the ORP variation per unit time at the time of titration according to example 1 of the present invention;
FIG. 4 is a graph of the standard acid volume at the time of titration and the ORP change value in 1 second for example 1 of the present invention;
FIG. 5 is a graph showing the standard hydrochloric acid addition amount and the ORP variation per unit time at the time of titration according to example 2 of the present invention;
FIG. 6 is a graph of the standard acid volume and the ORP change in 1 second at the time of titration according to example 2 of the present invention.
Detailed Description
Example 1
As shown in fig. 1, an apparatus for automatically measuring the ion content in a water sample such as formation water comprises a measuring cell 1, a measuring and controlling mechanism 2 connected to the measuring cell 1, and a standard solution supplying mechanism 3 connected to the measuring cell 1 and the measuring and controlling mechanism 2, wherein the standard solution supplying mechanism 3 comprises a standard hydrochloric acid solution tank 31 and a deionized water tank 32.
Wherein, the measuring cell 1 is connected with a sample water supply pipe 11 to be measured, a deionized water supply pipe 12, a standard hydrochloric acid solution supply pipe 13 and an ORP electrode 14, the sample water supply pipe 11 to be measured is connected with a sample water tank 4 to be measured through a first quantitative pump 15, the standard hydrochloric acid solution supply pipe 13 is connected with a standard hydrochloric acid solution tank 31 through a second quantitative pump 16, and the deionized water supply pipe 12 is connected with a deionized water tank 32 through a third quantitative pump 17;
the measurement and control mechanism 2 comprises a main board 21, a signal board 22 and a control board 23, wherein the signal board 22 is connected with the ORP electrode 14, the control board 23 is connected with a first quantitative pump 15, a second quantitative pump 16 and a third quantitative pump 17, and the main board 21 is connected with a power supply 24 and a display screen 25.
Further, the bottom of the measuring cell 1 is provided with a stirrer 18, and the stirrer 18 is in signal connection with a control board 23.
Further, the bottom of the measuring tank 1 is connected with a sewage draining outlet 110 through a sewage draining electromagnetic valve 19, and the side surface of the measuring tank 1 is provided with an overflow port 111.
Further, as shown in fig. 2, based on the structure of the device, the utility model provides a method for measuring carbonate, bicarbonate and hydroxyl in geological water, soil leachate and other water, and is suitable for colored and high-turbidity water samples. The principle of the utility model is mainly that the titration end point is comprehensively judged by measuring the change of the oxidation-reduction potential of the solution to be measured in the titration process through an oxidation-reduction electrode. The measurement procedure (shown in FIG. 2) is as follows:
s1, adding 2-50mL of a water sample to be detected into the measuring pool 1 through the first quantitative pump 15, wherein the volume of the water sample to be detected is recorded as V, the sampling volume is related to the concentration of carbonate, bicarbonate and hydroxyl to be detected, the concentration of the sample to be detected is larger, the sampling amount is smaller, the concentration of the sample to be detected is smaller, the sampling amount is larger, and the sampling amount is generally 10 mL;
s2, adding 50mL of boiled deionized water into the measuring cell 1 through the third quantitative pump 17;
s3, turning on the stirrer 18, and adding a standard acid solution (the standard acid solution is hydrochloric acid, sulfuric acid and other acid solutions, preferably hydrochloric acid solution, and the concentration is recorded as c) with known concentration into the water sample to be measured in the S2 measuring cell at a certain speed by using a second quantitative pump 16(HCl))；
S4, determining the ORP value of the water sample solution to be detected in S3;
the ORP electrode 14 does not need to be calibrated before use, and can be directly used, if the quality or the test result of the ORP electrode 14 is questioned, the ORP standard solution can be used for checking whether the potential is between 200 and 275mv, so as to judge whether the ORP electrode or the instrument is good or bad. The method is suitable for measuring carbonate, bicarbonate and hydroxyl with initial pH value within the range of 5-10. If the pH is lower than 5, accurate measurement of carbonate, bicarbonate and hydroxyl cannot be carried out;
s5, is the current number of titrations exceeded (a preferred limit of 5000 times)? If the titration frequency is larger than the specified value, the titration frequency is abnormal, and the experiment is ended (the result cannot be measured); if not (the current titration frequency is less than the specified value), the following step S6 is carried out;
s6, judging whether the characteristic point 1 of the first end point (preferably the characteristic point of the first end point 1 is the point with the oxidation-reduction potential value within the range of 180-310mV and the maximum oxidation-reduction potential change value in unit time) appears, if so, recording the volume V of the consumed acid standard solution of the characteristic point 1 from the beginning to the first end point1Performing the following step S7; if not (feature point 1 of the first end point does not appear), the following step S7 is performed;
s7, judging whether the characteristic point 2 of the second end point appears or not (preferably, the characteristic point 2 of the second end point is a point that the oxidation-reduction potential value is in the range of 310-440mV and the oxidation-reduction potential change value in unit time is maximum), if so, dividing into 2 cases: if the characteristic point 1 of the first end point appears before, recording the volume V of the acid standard solution consumed from the characteristic point 1 of the first end point to the characteristic point 2 of the second end point2If the characteristic point 1 of the first end point does not appear before, recording the volume V of the consumed acid standard solution from the characteristic point 2 from the beginning to the second end point2Performing the following step S8; if not (the characteristic point 2 of the second end point does not appear), sequentially performing the steps S3, S4, S5, S6 and S7 until the characteristic point 2 of the second end point appears or the current titration frequency exceeds the limit;
s8, according to V1、V2And concentration c of standard acid solution(HCl)Calculating carbonate, bicarbonate and hydroxyl by using the sampling volume V, and dividing into two conditions:
(1) for the water sample to be detected with the characteristic point 1 without the first end point and the characteristic point 2 with the second end point
In this case, the sample water to be tested does not contain carbonate but contains only bicarbonate, the volume of the sample water to be tested in step S1 is denoted as V, the volume of the hydrochloric acid standard solution added in step S7 is denoted as V2, and the concentration thereof is denoted as c (hcl). The calculation formula is as follows:
ρ(HCO3-)＝V2×M3×c(HCl)/V
in the formula (I), the compound is shown in the specification,
ρ(HCO3 -)——HCO3 -concentration of (3), g/L;
v2 — feature point 2 from start to second endpoint in step S7 consumes volume of acid standard solution, mL;
M3——HCO3 -molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
(2) For the water sample to be detected with the characteristic point 1 of the first end point and the characteristic point 2 of the second end point
In this case, the volume V1 of the acid standard solution is consumed according to the volume V of the hydrochloric acid solution added in the step S6 and the volume V of the acid standard solution consumed from the characteristic point 1 of the first endpoint to the characteristic point 2 of the second endpoint in the step S72There are the following three cases:
(ii) when V1 > V2, OH in the solution-And CO3 2-Coexistence of
ρ(OH-)＝(V1-V2)×M1×c(HCl)/V
ρ(CO3 2-)＝V2×M2×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(OH-)——OH-concentration of (3), g/L;
ρ(CO3 2-)——CO3 2-concentration of (3), g/L;
v1 — feature point 1 from start to first endpoint in step S6 consumes a volume of acid standard solution, mL;
v2 — volume V2, mL of acid standard solution consumed from feature point of the first endpoint to feature point 2 of the second endpoint in step S7;
M1——OH-molar mass of (a), g/mol;
M2——CO3 2-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
② when V1 is less than V2, HCO in the solution3 -And CO3 2-Coexistence of
ρ(CO3 2-)＝V1×M2×c(HCl)/V
ρ(HCO3 -)＝(V2-V1)×M3×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(CO3 2-)——CO3 2-concentration of (3), g/L;
ρ(HCO3 -)——HCO3 -concentration of (3), g/L;
v1 — feature point 1 from start to first endpoint in step S6 consumes a volume of acid standard solution, mL;
v2 — volume V2, mL of acid standard solution consumed from feature point of the first endpoint to feature point 2 of the second endpoint in step S7;
M2——CO3 2-molar mass of (a), g/mol;
M3——HCO3 -molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
③ when V1 is V2, the solution contains only CO3 2-
ρ(CO3 2-)＝V1×M2×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(CO3 2-)——CO3 2-concentration of (3), g/L;
v1 — feature point 1 from start to first endpoint in step S6 consumes a volume of acid standard solution, mL;
M2——CO3 2-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
The utility model is illustrated below with reference to specific examples:
the water sample in this example has characteristic points of a first endpoint and a second endpoint, and the method for measuring the carbonate, bicarbonate and hydroxyl contents of the water sample comprises the following steps:
s1, closing the blowdown electromagnetic valve 19, adding 10mL of water sample to be detected into the clean measuring pool 1 through the first quantitative pump 15, and recording the volume of the water sample to be detected as V;
s2, adding 50mL of deionized water into the measuring cell through a quantitative pump 3;
s3, turning on the stirrer, turning off the stirrer after 30 seconds, determining the ORP value of the solution of the water sample to be measured in the measuring tank, adding 0.05mol/L standard hydrochloric acid solution into the water sample to be measured at a certain speed through the second quantitative pump 16, and recording the concentration of the standard hydrochloric acid solution as c(HCl)；
S4, determining the ORP value of the water sample solution to be detected after a certain volume of standard hydrochloric acid solution is added in S3;
s5, is the current number of titrations exceeded (a preferred limit of 5000 times)? If the titration frequency is larger than the specified value, the titration frequency is abnormal, and the experiment is ended (the result cannot be measured); this example judges no (the current titration number is smaller than the prescribed value), the following step S6 is performed;
s6, judging whether the characteristic point 1 of the first end point (the preferable characteristic point 1 of the first end point is the point with the oxidation-reduction potential value in the range of 180-310mV and the maximum oxidation-reduction potential change value in unit time) appears, recording the characteristic point of the first end point when 1.695mL of standard hydrochloric acid solution is added, and recording the volume V of the acid standard solution consumed by the characteristic point 1 from the beginning to the first end point11.695mL, the following step S7 was performed;
s7, judging whether the characteristic point 2 of the second end point (the preferable characteristic point 2 of the second end point is the point with the oxidation-reduction potential value within the range of 310-440mV and the maximum oxidation-reduction potential change value in unit time) appears, if the characteristic point of the second end point appears at the point where 2.665mL of standard hydrochloric acid solution is added in total, and if the characteristic point 1 of the first end point appears at S6, recording the characteristic point from the first end pointCharacteristic point 1 of the endpoint to characteristic point 2 of the second endpoint consumed volume V of the acid standard solution2(ii) performing the following step S8, when the total volume of 2.665-1.695mL is 0.97 mL;
s8, according to V1、V2And concentration c of standard acid solution(HCl)Calculating carbonate, bicarbonate and hydroxyl by using the sampling volume V:
v1 > V2 indicates OH in solution-And CO3 2-Coexistence of
ρ(OH-)＝(V1-V2)×M1×c(HCl)/V
ρ(CO3 2-)＝V2×M2×c(HCl)/V
In the formula (I), the compound is shown in the specification,
ρ(OH-)——OH-concentration of (3), g/L;
ρ(CO3 2-)——CO3 2-concentration of (3), g/L;
v1 — feature point 1 from start to first endpoint in step S6 consumes a volume of acid standard solution, mL;
v2 — volume V2, mL of acid standard solution consumed from feature point 1 of the first endpoint to feature point 2 of the second endpoint in step S7;
M1——OH-molar mass of (a), g/mol;
M2——CO3 2-molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Calculating to obtain:
ρ(OH-)＝(1.695-0.97)×17.01×0.05/10≈0.062g/L
ρ(CO3 2-)＝0.97×60.02×0.05/10≈0.291g/L。
the curves of the standard acid volume for titration and the measured ORP value during titration in this example are shown in fig. 3, and the curves of the standard acid volume for titration and the measured ORP value within 1 second during titration in this example are shown in fig. 4.
Example 2:
the water sample in the embodiment only has the characteristic point 2 of the second end point, and has no characteristic point 1 of the first end point, and the method for measuring the carbonate, the bicarbonate and the hydroxyl of the water sample comprises the following steps:
s1, closing the blowdown electromagnetic valve 19, adding 10mL of water sample to be detected into the clean measuring pool 1 through the first quantitative pump 15, and recording the volume of the water sample to be detected as V;
s2, adding 50mL of deionized water into the measuring cell through a third quantitative pump 17;
s3, turning on the stirrer 18, turning off the stirring after 30 seconds, determining the ORP value of the water sample solution to be measured in the measuring cell 1, adding 0.05mol/L standard hydrochloric acid solution into the water sample to be measured at a certain speed through the quantitative pump 2, and recording the concentration of the standard hydrochloric acid solution as c(HCl)；
S4, determining the ORP value of the water sample solution to be detected after a certain volume of standard hydrochloric acid solution is added in S3;
s5, is the current number of titrations exceeded (a preferred limit of 5000 times)? If the titration frequency is larger than the specified value, the titration frequency is abnormal, and the experiment is ended (the result cannot be measured); this example judges no (the current titration number is smaller than the prescribed value), the following step S6 is performed;
s6, judging whether the characteristic point 1 of the first end point (the preferable characteristic point 1 of the first end point is the point with the oxidation-reduction potential value within the range of 180-310mV and the maximum oxidation-reduction potential change value in unit time) appears or not, and carrying out the following step S7 if the characteristic point 1 of the first end point does not appear;
s7, judging whether a characteristic point 2 of a second end point (preferably, the characteristic point 2 of the second end point is a point with the oxidation-reduction potential value within the range of 310-440mV and the maximum oxidation-reduction potential change value in unit time) appears, adding 1.815mL of standard hydrochloric acid solution to form the characteristic point 2 of the second end point, and recording V because the characteristic point 1 of the first end point does not appear in the step S61When the titration period started from step S3 to the characteristic point 2 where the second endpoint appeared, the volume V of the consumed acid standard solution was recorded at 0mL21.815mL, the following step S8 was performed;
s8, according to V1、V2And concentration c of standard acid solution(HCl)Calculating carbonate, bicarbonate and hydroxyl by using the sampling volume V:
when V1 < V2, HCO in solution3 -And CO3 2-Coexistence of
ρ(CO3 2-)＝V1×M2×c(HCl)/V
ρ(HCO3 -)＝(V2-V1)×M3×c(HCl)/V
In the formula, rho (CO)3 2-)——CO3 2-Concentration of (3), g/L;
ρ(HCO3 -)——HCO3 -concentration of (3), g/L;
v1 — feature point 1 from start to first endpoint in step S6 consumes a volume of acid standard solution, mL;
v2 — volume V2, mL of acid standard solution consumed from feature point of the first endpoint to feature point 2 of the second endpoint in step S7;
M2——CO3 2-molar mass of (a), g/mol;
M3——HCO3 -molar mass of (a), g/mol;
(HCl) -the concentration of the hydrochloric acid standard solution added in step S3, mol/L;
v-volume, mL, of water sample to be tested added in step S1.
Calculating to obtain:
ρ(CO3 2-)＝0×60.02×0.05/10＝0g/L
ρ(HCO3 1-)＝1.815×61.02×0.05/10≈0.554g/L
the curves of the standard acid volume for titration and the measured ORP value during titration in this example are shown in fig. 5, and the curves of the standard acid volume for titration and the measured ORP value within 1 second during titration in this example are shown in fig. 6.
In conclusion, the ORP electrode is adopted, the endpoint is identified through the change of the ORP oxidation-reduction potential in the titration process, the manual judgment of the color change endpoint in the titration is replaced, the endpoint judgment through the pH titration method when the pH value reaches the preset value is replaced, and the measurement accuracy and consistency are good;
the limit that the optical titration method is only suitable for colorless and low-turbidity sample water is overcome, the patent technology can measure not only colorless and low-turbidity sample water, but also colored and certain-turbidity sample water, the application range is wide, and online and real-time measurement can be realized.
The utility model can be adapted to the pollution of impurities in separation water in oil fields, mining and the like by designing a special titration cell and an oxidation-reduction electrode to identify titration end points, and can determine 2 titration end points through the change of oxidation-reduction potential by directly titrating hydrochloric acid or sulfuric acid standard solution without adding indicators such as phenolphthalein, methyl orange and the like, thereby being capable of accurately measuring carbonate, bicarbonate and hydroxyl in water quality in real time.
The foregoing shows and describes the general principles, essential features, and advantages of the utility model. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are merely illustrative of the principles of the utility model, but that various changes and modifications may be made without departing from the spirit and scope of the utility model, which fall within the scope of the utility model as claimed. The scope of the utility model is defined by the appended claims and equivalents thereof.
Claims (4)
1. A device for automatically measuring the ion content in water samples such as formation water and the like comprises a measuring pool, a measuring and controlling mechanism connected with the measuring pool, and a standard solution supplying mechanism connected with the measuring pool and the measuring and controlling mechanism, and is characterized in that the measuring pool is connected with a sample water supplying pipe to be measured, a deionized water supplying pipe, a standard hydrochloric acid solution supplying pipe and an ORP electrode, the sample water supplying pipe to be measured is connected with a sample water tank to be measured through a first quantitative pump, the standard hydrochloric acid solution supplying pipe is connected with a standard hydrochloric acid solution tank through a second quantitative pump, and the deionized water supplying pipe is connected with a deionized water tank through a third quantitative pump;
the measurement and control mechanism comprises a main board, a signal board and a control board, wherein the signal board and the control board are connected with the main board, the signal board is connected with the ORP electrode, and the control board is connected with the first constant delivery pump, the second constant delivery pump and the third constant delivery pump.
2. The device for automatically measuring the ion content in a water sample such as formation water according to claim 1, wherein a stirrer is arranged at the bottom of the measuring pool and is in signal connection with the control board.
3. The device for automatically measuring the ion content in the water sample such as the formation water according to the claim 1 or 2, characterized in that the bottom of the measuring tank is connected with a drain port through a drain electromagnetic valve, and the side of the measuring tank is provided with an overflow port.
4. The device for automatically measuring the ion content in a water sample such as formation water according to claim 3, wherein the main board is connected with a power supply and a display screen.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202121504432.8U CN215574914U (en) | 2021-07-01 | 2021-07-01 | Device for automatically measuring ion content in water samples such as stratum water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202121504432.8U CN215574914U (en) | 2021-07-01 | 2021-07-01 | Device for automatically measuring ion content in water samples such as stratum water |
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| CN215574914U true CN215574914U (en) | 2022-01-18 |
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| CN202121504432.8U Active CN215574914U (en) | 2021-07-01 | 2021-07-01 | Device for automatically measuring ion content in water samples such as stratum water |
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