CN215365616U - Fluidized bed steam reforming furnace for treating radioactive organic waste - Google Patents

Fluidized bed steam reforming furnace for treating radioactive organic waste Download PDF

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CN215365616U
CN215365616U CN202120667216.9U CN202120667216U CN215365616U CN 215365616 U CN215365616 U CN 215365616U CN 202120667216 U CN202120667216 U CN 202120667216U CN 215365616 U CN215365616 U CN 215365616U
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reforming furnace
furnace body
reformer
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fluidized bed
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贾昀澎
顾潮冰
赵博鸿
叶晓明
曹虎子
张灿军
王鹏
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Shanghai Nuclear Energy Environmental Protection Technology Co Ltd
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Shanghai Nuclear Energy Environmental Protection Technology Co Ltd
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Abstract

The present invention provides a fluidized bed steam reformer for treating radioactive organic waste. The fluidized bed steam reforming furnace comprises a reforming furnace body, wherein the reforming furnace body is provided with a standby oxygen/air feed port, a charcoal/fluidized medium feed port, a resin feed port and a gasifying agent feed port from top to bottom; the reforming furnace body is also provided with a dry mixed waste feeding hole, and the dry mixed waste feeding hole is positioned between the standby oxygen/air feeding hole and the gasifying agent feeding hole; the position of each feed inlet is calculated by the intersection point of the axis of the feed inlet and the side wall of the reforming furnace body. The fluidized bed steam reforming furnace can realize reaction subareas, and can not form local hot spots or produce viscous substances and can not cause agglomeration of fluidized particles.

Description

Fluidized bed steam reforming furnace for treating radioactive organic waste
Technical Field
The present invention relates to a fluidized bed steam reformer for treating radioactive organic waste.
Background
The nuclear industry generates a large amount of waste each year during its development, which can be classified as radioactive contaminated ion exchange media, sludge, organic waste liquids, dry miscellaneous organic waste, etc. This waste will be disposed of in various ways before it is disposed of in the bedrock room or by shallow land. These wastes are large in volume, complex in composition and difficult to handle, and in the treatment of radioactive organic wastes, they result in an increase in volume and consequently in storage costs.
The radioactive waste treatment technology adopted in China at present mainly comprises cement solidification, pyrolysis incineration, thermal state super compaction, drying and cement fixation, HIC (high density polyethylene high integral container) loading and dehydration and the like. Besides pyrolysis incineration, the treatment processes of other technologies are all mechanical and physical processes, the volume reduction effect is common, while pyrolysis incineration is only used for treating low-level combustible waste, and the treatment objects are limited. Therefore, there is a need for an apparatus which can reduce the volume and chemical activity of the waste to be treated, i.e. realize the effects of volume reduction and effective waste treatment.
The steam reforming technology can completely convert organic resin into inorganic matters, radioactive elements are enriched in mineralized matters, the generated mineralized matters have good durability and stability, the nuclide leaching resistance is high, and the purpose of safe volume reduction can be achieved. The method has a remarkable volume reduction effect, the volume of the waste can be reduced to 1/10-1/5 before treatment, secondary pollution is avoided in the treatment process, and the synthetic gas generated after cracking can be converted into N after treatment2、CO2And water, basically no waste liquid is generated, and the method is safe and pollution-free. In the fluidized bed steam reforming reaction furnace, radioactive organic wastes are cracked, and simultaneously, various reactions of different types such as a water-gas shift reaction, an oxidation reaction, a reduction reaction, a mineralization reaction under the action of an additive and the like also occur. These reaction processes are coupled with each other, and once the fluidized bed reactor is not well controlled, local hot spots or sticky substances are easily formed to cause agglomeration of fluidized particles, the fluidization quality and the reaction effect are slightly influenced, and the shutdown is caused if the fluidized bed reactor is not well controlled. Therefore, it is required to develop a novel fluidized-bed reactor so that radioactive organic wastes can be stably and effectively treated in the fluidized-bed reactor.
SUMMERY OF THE UTILITY MODEL
The utility model aims to solve the technical problem of providing a fluidized bed steam reforming furnace for treating radioactive organic waste in order to overcome the defects that fluidized particles of a fluidized bed reactor in the prior art are agglomerated, the fluidization quality and the reaction effect are influenced, and even the fluidized bed reactor is stopped. The fluidized bed steam reformer of the present invention achieves reaction zoning without forming localized hot spots or producing sticky materials and without causing agglomeration of fluidized particles, and has a volume reduction ratio for spent ion exchange resin of about 1:8.5 and a volume reduction ratio for dry miscellaneous waste of about 1: 50.
The utility model solves the technical problems through the following technical scheme.
The utility model provides a fluidized bed steam reforming furnace for treating radioactive organic waste, which comprises a reforming furnace body, wherein the reforming furnace body is provided with a standby oxygen/air feed inlet, a charcoal/fluidized medium feed inlet, a resin feed inlet and a gasifying agent feed inlet from top to bottom;
the reforming furnace body is also provided with a dry mixed waste feeding hole, and the dry mixed waste feeding hole is positioned between the standby oxygen/air feeding hole and the gasifying agent feeding hole; the position of each feed inlet is calculated by the intersection point of the axis of the feed inlet and the side wall of the reforming furnace body.
In the utility model, preferably, the ratio of the distance between the standby oxygen/air feed port and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.3-0.4): 1.
preferably, the number of the spare oxygen/air feed openings is two, and more preferably, the included angle between the axes of the two spare oxygen/air feed openings is 45-60 degrees.
Preferably, the backup oxygen/air feed port is perpendicular to the axis of the reformer body.
Preferably, the furnace wall near the spare oxygen/air feed inlet is provided with a sight glass for observing the conditions inside the furnace.
In use of the apparatus of the utility model, the charcoal/fluidising medium feed inlet delivers the carbonaceous particles and the fluidising medium into the bed via the nitrogen. The charcoal particles act as fuel and the fluidizing medium acts as mineralizer and bed fluidization. Wherein, the fluidizing medium is preferably mineralizer kaolin.
Preferably, the ratio of the distance between the charcoal/fluidized medium feed inlet and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.25-0.3): 1.
preferably, the charcoal/fluidizing agent inlet is inclined downwardly, and the axis of the charcoal/fluidizing agent inlet is at an angle of 50 ° to 60 °, for example 55 °, to the horizontal.
Preferably, the furnace wall near the charcoal/fluidized medium inlet is provided with a manhole for maintenance.
When the equipment is used, the waste resin and an additive (for example, aluminum hydroxide powder is used as the additive to play a role of anticoagulation) are mixed, then the waste resin is conveyed into a bed layer through a resin feeding hole by a resin feeding and conveying variable frequency pump and a resin atomizing nozzle, and the feeding rate can be controlled by adjusting the resin feeding and conveying variable frequency pump.
Preferably, the ratio of the distance between the resin feed port and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.23-0.25): 1.
preferably, the resin feed port is inclined downwards, and the included angle between the axis of the resin feed port and the horizontal plane is 45-60 degrees.
Preferably, a cooling air inlet is formed in the periphery of the resin feed port, and cooling air is used for promoting atomization of waste resin and preventing the resin from being melted and blocking the resin feed port before atomization under the high-temperature working condition.
In the utility model, the gasification agent feed inlet is generally used for feeding the gasification agent, the gasification agent can ensure the fluidization of materials and can also provide energy required by the material reaction in the fluidized bed steam reforming furnace; wherein, the gasifying agent is generally superheated steam.
Preferably, the ratio of the distance between the gasification agent feed inlet and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.08-0.1): 1.
preferably, the number of the gasification agent feed inlets is four, and more preferably, the four gasification agent feed inlets are inserted into the reforming furnace body along the tangential direction of the reforming furnace body, and the axes of every two adjacent gasification agent feed inlets are perpendicular to each other.
Preferably, the gasification agent feed port inclines upwards, and the included angle between the axis of the gasification agent feed port and the horizontal plane is 10-15 degrees.
Preferably, a pressure gauge opening and a thermocouple opening are further arranged on the side wall of the furnace body at the gasification agent feeding port.
In use of the apparatus of the utility model, the dry miscellaneous waste is typically passed through a dry miscellaneous waste pusher, through which dry miscellaneous waste is fed into the bed, the rate of feed being controllable by adjustment of the dry miscellaneous waste pusher.
Preferably, the ratio of the distance between the dry impurity waste feed inlet and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.25-0.3): 1.
preferably, the dry miscellaneous waste feed inlet is inclined downwards, and the included angle between the axis of the dry miscellaneous waste feed inlet and the horizontal plane is 50-60 degrees, such as 55 degrees.
In the present invention, the reformer body is preferably further provided with a syngas outlet for discharging a mixed gas with particles generated during the operation of the fluidized bed steam reformer.
Preferably, the syngas outlet is located at the top of the reformer vessel.
Preferably, the syngas outlet is connected to a cyclone.
Preferably, the inner diameter of the synthesis gas outlet accounts for 2% -3% of the total height of the reforming furnace body. More preferably, the syngas outlet has an internal diameter of 200 mm.
In the present invention, the reformer body is preferably further provided with a spray cooling port for cooling the gas before the gas is discharged from the fluidized bed steam reformer. And introducing steam into the spray cooling port, so that the temperature of the mixed gas with particles generated in the operation process of the fluidized bed steam reforming furnace is reduced from 750 ℃ to 900 ℃ to 600 ℃ to 650 ℃ before the mixed gas is discharged from the synthesis gas outlet, and the temperature of the synthesis gas outlet meets the requirements of a downstream cyclone filter and a high-temperature filter.
Preferably, the ratio of the distance between the spray cooling port and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.92-0.95): 1.
preferably, the number of the spray cooling ports is two, and more preferably, the two spray cooling ports are arranged at the opposite positions of the reformer body.
Preferably, the spray cooling port is inclined downwards, and an included angle between the axis of the spray cooling port and the horizontal plane is 45-75 degrees, for example 60 degrees.
Preferably, a pressure gauge opening and a thermocouple opening are arranged below the spray cooling port.
Preferably, a lifting lug is arranged below the spray cooling port, and the fluidized bed steam reforming furnace is convenient to lift when being mounted or dismounted.
In the present invention, the reformer body is preferably further provided with a kiln burner for preheating the reformer body before the fluidized bed steam reformer is operated. Preheating the body of the fluidized bed steam reforming furnace before starting the steam reforming furnace, wherein natural gas and air can be sprayed from a baking furnace burner in the preheating method, and the body of the reforming furnace is preheated by combustion temperature rise; in the preheating process, the air flow sprayed by the baking furnace burner can be 300Nm3H; heating from 500 ℃ to 900 ℃ and the rate of rise can be 50 ℃/h. And after the preheating is finished, stopping running the baking furnace burner.
Preferably, the ratio of the distance between the baking furnace burner and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.2-0.3): 1.
preferably, the baker nozzle inclines downwards, and the included angle between the axis of the baker nozzle and the horizontal plane is 45-60 degrees.
In the present invention, the body of the reformer is further provided with a bed material outlet for discharging bed material particles or ash material when the fluidized bed steam reformer is shut down, as is conventional in the art.
Preferably, the bed material outlet is located at the bottom of the reformer body.
Preferably, the inner diameter of the bed material outlet accounts for 2% -3% of the total height of the reforming furnace body. More preferably, the inner diameter of the bed material outlet is 203 mm.
In the utility model, preferably, a plurality of pressure gauge openings and thermocouple openings are further arranged on the side wall of the reforming furnace body at the middle part of the reforming furnace body.
In the utility model, the filler adopted by the fluidized bed steam reforming furnace is a refractory filler, such as low-silicon corundum castable; the lining used is a refractory lining made of, for example, alumina and silica.
According to the utility model, through the arrangement of the positions of the feed inlet and the discharge outlet, the fluidized bed steam reforming furnace is divided into an upper reaction zone and a lower feeding zone, and the upper reaction zone is further divided into an upper reaction zone and a lower reaction zone. The upper reaction zone carries out the cracking inversion, the reduction reaction and the mineralization reaction of the resin, and the lower reaction zone carries out the water-gas shift reaction and the oxidation reaction of the steam. The upper and lower reaction zones are matched with the control of the addition of carbon particles, oxidant and gasifying agent to control the temperature of the bed layer through the arrangement of the positions of each feeding hole and each discharging hole. In the starting stage, a proper amount of superheated steam is uniformly introduced through a gasification agent feeding port to heat the bed layer, the oxidation reaction generated in the lower reaction zone can provide heat for the lower reaction zone after the operation is stable, at the moment, the supply of the gasification agent can be properly reduced, and the temperature of the bed layer is kept stable.
Preferably, the furnace chamber defined by the reforming furnace body comprises a first cylindrical furnace chamber and a second cylindrical furnace chamber from top to bottom, the inner diameter of the first cylindrical furnace chamber is larger than that of the second cylindrical furnace chamber, and the standby oxygen/air feed port, the charcoal/fluidized medium feed port, the resin feed port and the dry mixed waste feed port are all arranged on the side wall of the second cylindrical furnace chamber.
More preferably, the ratio of the inner diameter of the first cylindrical furnace chamber to the inner diameter of the second cylindrical furnace chamber is 1: (0.5 to 0.7). More preferably, the ratio of the height of the first cylindrical furnace chamber to the height of the second cylindrical furnace chamber is (1.3-1.5): 1.
preferably, the furnace chamber surrounded by the reforming furnace body comprises a third cylindrical furnace chamber, a gradually expanding furnace chamber, a first cylindrical furnace chamber, a first gradually reducing furnace chamber, a second cylindrical furnace chamber and a second gradually reducing furnace chamber from top to bottom, the spray cooling port is arranged on the side wall of the gradually expanding furnace chamber, and the gasification agent feed port is arranged on the side wall of the second gradually reducing furnace chamber.
Further preferably, the ratio of the inner diameter of the third cylindrical furnace chamber to the inner diameter of the first cylindrical furnace chamber is 1: (5-10), for example, 1: 6.
The positive progress effects of the utility model are as follows:
1. the fluidized bed steam reforming furnace can realize reaction subareas, and the lower reaction zone generates steam water-gas shift reaction and oxidation reaction to provide reducing gas and heat required by the reaction for the upper reaction zone; the upper reaction zone is subjected to cracking inversion, reduction reaction, mineralization reaction and the like of the resin. The reaction subarea operation reduces the mutual influence among the reactions and improves the controllability of the reaction process. Meanwhile, the height and temperature of the bed layer can be controlled within a proper range by matching with the addition of oxygen/air, carbon powder and superheated steam, so that the particles are prevented from agglomerating and agglomerating.
2. After the fluidized bed steam reformer of the present invention is used to treat organic waste, the volume and mass of the waste are greatly reduced compared to the initial volume and mass of the waste to be treated, and the decomposition efficiency can be significantly improved. In addition, the components of the treated waste, gases and water vapor, which are to be discharged into the environment, are converted into harmless states before being discharged.
3. In a preferred embodiment, a spraying cooling port is arranged at the upper part of the upper reaction zone, so that the outlet of the synthesis gas is cooled to avoid volatilization of the radioactive nuclide.
Drawings
FIG. 1 is a schematic cross-sectional view of a fluidized bed steam reformer of example 1.
FIG. 2 is a schematic view of a fluidized bed steam reformer in a sectional configuration in accordance with example 1.
FIG. 3 is a schematic top view of the fluidized bed steam reformer of example 1.
FIG. 4 is a schematic view of the distribution of gasification agent feed inlets of the fluidized bed steam reformer of example 1.
Description of the reference numerals
Syngas outlet 1
Spray cooling port 2
Spare oxygen/air feed 3
Resin feed port 4
Gasifying agent feed port 5
Bed material outlet 6
Baker burner 7
Dry miscellaneous waste feed inlet 8
Charcoal/fluidizing agent feed 9
Manhole 10
First pressure gauge opening 11
Second pressure gauge opening 12
Third pressure gauge opening 13
Fourth pressure gauge opening 14
Fifth manometer opening 15
Sixth pressure gauge opening 16
Seventh manometer orifice 17
First thermocouple opening 18
Second thermocouple opening 19
Third thermocouple opening 20
Fourth thermocouple opening 21
Fifth thermocouple opening 22
Sixth thermocouple opening 23
Seventh thermocouple opening 24
Eighth thermocouple opening 25
Third cylindrical furnace chamber 26
Gradually expanding furnace chamber 27
First cylindrical furnace chamber 28
First tapered oven cavity 29
Second cylindrical furnace chamber 30
Second tapered oven cavity 31
Detailed Description
The present invention will be more clearly and completely described in the following description of preferred embodiments, taken in conjunction with the accompanying drawings.
Example 1
The fluidized bed steam reformer is described in detail below with reference to FIGS. 1-4.
Embodiment 1 provides a fluidized bed steam reformer for treating radioactive organic waste, which comprises a reformer body provided with a standby oxygen/air feed port 3, a charcoal/fluidizing medium feed port 9, a resin feed port 4 and a gasifying agent feed port 5 from top to bottom;
the reforming furnace body is also provided with a dry impurity waste feed port 8, and the dry impurity waste feed port 8 is positioned between the standby oxygen/air feed port 3 and the gasifying agent feed port 5; the position of each feed inlet is calculated by the intersection point of the axis of the feed inlet and the side wall of the reforming furnace body.
The height of the reforming furnace body is 8171.5 mm.
The distance between the spare oxygen/air feed port 3 and the bottom of the reforming furnace body is 2625 mm. The number of the spare oxygen/air feed ports 3 is two, and the included angle between the axes of the two spare oxygen/air feed ports 3 is 60 °. The spare oxygen/air feed port 3 is perpendicular to the axis of the reformer body. The furnace wall near the spare oxygen/air inlet 3 is provided with a sight glass for observing the condition in the furnace.
The distance between the charcoal/fluidizing medium inlet 9 and the bottom of the reformer body was 2135 mm. The charcoal/fluidizing agent feed port 9 was inclined downward, and the axis of the charcoal/fluidizing agent feed port 9 was inclined at an angle of 55 ° to the horizontal plane. The furnace wall near the charcoal/fluidizing agent inlet 9 is provided with a manhole 10 for maintenance.
The distance between the resin feed port 4 and the bottom of the reforming furnace body is 2025 mm. The resin feed port 4 is inclined downward, and the angle between the axis of the resin feed port 4 and the horizontal plane is 45. A cooling air inlet is arranged around the resin feed port 4.
The gasification agent feed inlet 5 is used for feeding a gasification agent. The distance between the gasification agent feed port 5 and the bottom of the reforming furnace body is 673.5 mm. The number of the gasification agent feed inlets 5 is four, the four gasification agent feed inlets 5 are inserted into the reforming furnace body along the tangential direction of the reforming furnace body, and the axes of every two adjacent gasification agent feed inlets 5 are mutually vertical. The gasification agent feed port 5 inclines upwards, and the included angle between the axis of the gasification agent feed port 5 and the horizontal plane is 10 degrees. The side wall of the furnace body at the gasification agent feed port 5 is also provided with a first pressure gauge opening 11, a second pressure gauge opening 12, a first thermocouple opening 18 and a second thermocouple opening 19.
The distance between the dry impurity waste feed inlet 8 and the bottom of the reforming furnace body is 2135 mm. The dry miscellaneous waste feed inlet 8 inclines downwards, and the included angle between the axis of the dry miscellaneous waste feed inlet 8 and the horizontal plane is 55 degrees.
The reforming furnace body is also provided with a synthesis gas outlet 1. The syngas outlet 1 is located at the top of the reformer body. The syngas outlet 1 is connected to a cyclone. The inner diameter of the synthesis gas outlet 1 is 200 mm.
The reforming furnace body is also provided with a spray cooling port 2. The distance between the spray cooling port 2 and the bottom of the reforming furnace body and the ratio of the distance to the total height of the reforming furnace body are 7671.5 mm. The number of the spray cooling ports 2 is two, and the two spray cooling ports 2 are arranged at the opposite positions of the reformer body. The spray cooling port 2 is inclined downwards, and the included angle between the axis of the spray cooling port 2 and the horizontal plane is 60 degrees. A seventh pressure gauge opening 17 and an eighth thermocouple opening 25 are arranged below the spray cooling port 2. A lifting lug is arranged below the spray cooling port 2.
The reformer body is also provided with a kiln burner 7 for preheating the reformer body prior to operation of the fluidized bed steam reformer. The distance between the baking furnace burner 7 and the bottom of the reforming furnace body is 1685 mm. The baker burner 7 inclines downwards, and the included angle between the axis of the baker burner 7 and the horizontal plane is 45 degrees.
The reforming furnace body is also provided with a bed material outlet 6. The bed material outlet 6 is positioned at the bottom of the body of the reforming furnace. The internal diameter of the bed material outlet 6 was 203 mm.
The side wall of the furnace body in the middle of the reforming furnace body is also provided with a plurality of pressure gauge openings and thermocouple openings, such as a third pressure gauge opening 13, a fourth pressure gauge opening 14, a fifth pressure gauge opening 15, a sixth pressure gauge opening 16, a third thermocouple opening 20, a fourth thermocouple opening 21, a fifth thermocouple opening 22, a sixth thermocouple opening 23 and a seventh thermocouple opening 24.
The furnace chamber enclosed by the reforming furnace body comprises a first cylindrical furnace chamber 28 and a second cylindrical furnace chamber 30 from top to bottom, the inner diameter of the first cylindrical furnace chamber 28 is larger than that of the second cylindrical furnace chamber 30, and the standby oxygen/air feed port 3, the charcoal/fluidized medium feed port 9, the resin feed port 4 and the dry mixed waste feed port 8 are all arranged on the side wall of the second cylindrical furnace chamber 30.
The first cylindrical furnace chamber 28 has an inner diameter of 1200mm and the second cylindrical furnace chamber 30 has an inner diameter of 760 mm. The first cylindrical furnace chamber 28 has a height of 3100mm and the second cylindrical furnace chamber 30 has a height of 2200 mm.
The furnace chamber enclosed by the reforming furnace body comprises a third cylindrical furnace chamber 26, a gradually expanding furnace chamber 27, a first cylindrical furnace chamber 28, a first gradually reducing furnace chamber 29, a second cylindrical furnace chamber 30 and a second gradually reducing furnace chamber 31 from top to bottom, the spray cooling port 2 is arranged on the side wall of the gradually expanding furnace chamber 27, and the gasifying agent feed port 5 is arranged on the side wall of the second gradually reducing furnace chamber 31. The third cylindrical furnace chamber 26 has an inner diameter of 200 mm.
The above fluidized bed steam reformer was used to treat the waste resin, the parameters of the waste resin before treatment are shown in table 1.
TABLE 1 parameters of waste resin before treatment
Figure BDA0003001078530000101
Figure BDA0003001078530000111
The content of main radionuclides in the mixed waste resin is as follows: cs: 0.2g/m3;Co:0.01g/m3;Sr:2.5μg/m3(the content is extremely low). The content of the non-radioactive elements is considered as follows (mass ratio, calculated by the water content of the combined substance): li: 0.05 percent to 0.85 percent; b: 0.7 to 2.8 percent (by BO)3 -Calculating); na: 3-330 ppm; k: 0.5 to 130 ppm; ca: 2.5-130 ppm; cl: 10 ppm.
The results for the solid waste treated in the fluidized bed steam reformer were as follows:
for waste resin containing alkali metal (such as sodium, potassium and cesium), a mineralizer is added to form a new mineralized phase in a reforming furnace, so that nuclides can be well contained in mineralized products, and the reaction and obtained products are as follows:
Na+Al2O3-2SiO2(Clay) ═ Na2O-Al2O3-2SiO2(nepheline)
Na+K+Al2O3-2SiO2=NaKO-Al2O3-2SiO2(nepheline)
Na+SO4+Al2O3-2SiO2=Na2SO4-(Na2O-Al2O3-2SiO2) (tetrahedrite)
Na+Cl+Al2O3-2SiO2=2NaCl-(Na2O-Al2O3-2SiO2)6(sodalite)
Na+F+Al2O3-2SiO2=2NaF-(Na2O-Al2O3-2SiO2)6(sodalite)
After the mineralization reaction in the furnace body, 99.99 percent of radionuclide captured by the mineralizer is stable, mineralized, nonflammable and leaching-resistant granular/fine sand-shaped solid which can be directly disposed.
The volume reduction rate is: 5:1 to 10: 1.
It should be noted that the terms "vertical", "upper", "lower", "horizontal", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience in describing the present application and simplifying the description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and thus should not be construed as limiting the present invention.

Claims (10)

1. A fluidized bed steam reforming furnace for treating radioactive organic waste is characterized by comprising a reforming furnace body, wherein the reforming furnace body is provided with a standby oxygen/air feed inlet, a charcoal/fluidized medium feed inlet, a resin feed inlet and a gasifying agent feed inlet from top to bottom;
the reforming furnace body is also provided with a dry mixed waste feeding hole, and the dry mixed waste feeding hole is positioned between the standby oxygen/air feeding hole and the gasifying agent feeding hole; the position of each feed inlet is calculated by the intersection point of the axis of the feed inlet and the side wall of the reforming furnace body.
2. The fluidized bed steam reformer for processing radioactive organic waste of claim 1, wherein the distance between said alternate oxygen/air feed opening and the bottom of said reformer body is in a ratio of (0.3-0.4) to the total height of said reformer body: 1;
the number of the standby oxygen/air feed inlets is two, and the included angle between the axes of the two standby oxygen/air feed inlets is 45-60 degrees;
the spare oxygen/air feed port is vertical to the axis of the reforming furnace body;
the furnace wall at the spare oxygen/air feed inlet is provided with a sight glass for observing the condition in the furnace.
3. The fluidized bed steam reformer for processing radioactive organic waste of claim 1, wherein the ratio of the distance between said charcoal/fluidizing agent feed inlet and the bottom of said reformer body to the total height of said reformer body is (0.25-0.3): 1;
the charcoal/fluidized medium feed port is inclined downwards, and the included angle between the axis of the charcoal/fluidized medium feed port and the horizontal plane is 50-60 degrees;
a manhole for maintenance is arranged on the furnace wall at the charcoal/fluidized medium feeding port;
the resin feed inlet is spaced from the bottom of the reforming furnace body, and the ratio of the distance to the total height of the reforming furnace body is (0.23-0.25): 1;
the resin feed port is inclined downwards, and the included angle between the axis of the resin feed port and the horizontal plane is 45-60 degrees;
and a cooling air inlet is arranged around the resin feed port.
4. The fluidized bed steam reformer for processing radioactive organic waste of claim 1, wherein the ratio of the distance between said gasifying agent feed inlet and the bottom of said reformer body to the total height of said reformer body is (0.08-0.1): 1;
the number of the gasification agent feed inlets is four, the four gasification agent feed inlets are inserted into the reforming furnace body along the tangential direction of the reforming furnace body, and the axes of every two adjacent gasification agent feed inlets are mutually vertical;
the gasification agent feed port is inclined upwards, and the included angle between the axis of the gasification agent feed port and the horizontal plane is 10-15 degrees;
the ratio of the distance between the dry impurity waste feed inlet and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.25-0.3): 1;
the dry miscellaneous waste feed inlet is inclined downwards, and the included angle between the axis of the dry miscellaneous waste feed inlet and the horizontal plane is 50-60 degrees.
5. The fluidized bed steam reformer for processing radioactive organic waste of claim 1, wherein said reformer body is provided with a syngas outlet;
the reforming furnace body is provided with a spray cooling port;
the reforming furnace body is provided with a baking furnace burner;
the reforming furnace body is provided with a bed material outlet.
6. The fluidized bed steam reformer of processing radioactive organic waste of claim 5,
the synthesis gas outlet is positioned at the top of the reforming furnace body;
the synthesis gas outlet is connected with the cyclone separator;
the inner diameter of the synthetic gas outlet accounts for 2% -3% of the total height of the reforming furnace body;
the ratio of the distance between the spray cooling port and the bottom of the reforming furnace body to the total height of the reforming furnace body is (0.92-0.95): 1;
the number of the spray cooling ports is two, and the two spray cooling ports are arranged at opposite positions of the reformer body;
the spray cooling port is inclined downwards, and the included angle between the axis of the spray cooling port and the horizontal plane is 45-75 degrees;
a pressure gauge opening and a thermocouple opening are arranged below the spray cooling port;
and a lifting lug is arranged below the spray cooling port.
7. The fluidized bed steam reformer for processing radioactive organic waste of claim 5, wherein the ratio of the distance between said reformer burner and the bottom of said reformer body to the total height of said reformer body is (0.2-0.3): 1;
the baking furnace burner is inclined downwards, and the included angle between the axis of the baking furnace burner and the horizontal plane is 45-60 degrees;
the bed material outlet is positioned at the bottom of the reforming furnace body;
the inner diameter of the bed material outlet accounts for 2% -3% of the total height of the reforming furnace body;
and a plurality of pressure gauge openings and thermocouple openings are also arranged on the side wall of the furnace body in the middle of the reforming furnace body.
8. The fluidized bed steam reformer for processing radioactive organic waste of claim 5, wherein said reformer body defines a chamber comprising, from top to bottom, a first cylindrical chamber and a second cylindrical chamber, said first cylindrical chamber having an inside diameter greater than an inside diameter of said second cylindrical chamber, said backup oxygen/air feed port, said charcoal/fluidizing agent feed port, said resin feed port, and said dry waste feed port being disposed in a sidewall of said second cylindrical chamber;
the inner diameter ratio of the first cylindrical furnace chamber to the second cylindrical furnace chamber is 1: (0.5 to 0.7);
the height ratio of the first cylindrical furnace chamber to the second cylindrical furnace chamber is (1.3-1.5): 1.
9. the fluidized bed steam reformer for processing radioactive organic waste of claim 8, wherein the furnace chamber defined by the reformer body comprises a third cylindrical furnace chamber, a gradually expanding furnace chamber, a first cylindrical furnace chamber, a first gradually reducing furnace chamber, a second cylindrical furnace chamber and a second gradually reducing furnace chamber from top to bottom, the spray cooling port is formed in a side wall of the gradually expanding furnace chamber, and the gasifying agent feed port is formed in a side wall of the second gradually reducing furnace chamber.
10. The fluidized bed steam reformer for processing radioactive organic waste of claim 9, wherein the ratio of the inner diameter of said third cylindrical furnace chamber to the inner diameter of said first cylindrical furnace chamber is from 1: (5-10).
CN202120667216.9U 2021-03-31 2021-03-31 Fluidized bed steam reforming furnace for treating radioactive organic waste Active CN215365616U (en)

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