Disclosure of Invention
An object of the embodiment of the application is to provide a test electrode, which has the advantages of simple structure, small sample size, low cost, long service life, simple and reversible assembly process, high yield and the like.
In order to achieve the purpose, the technical scheme adopted by the application is as follows: providing a test electrode, wherein the electrode comprises an electrode cover and an electrode core clamped on the electrode cover;
the electrode cover is provided with a liquid inlet channel to be detected, a liquid outlet channel to be detected and a testing semi-cavity structure connected between the liquid inlet channel to be detected and the liquid outlet channel to be detected, and the liquid inlet channel to be detected and the liquid outlet channel to be detected are oppositely arranged;
and the electrode testing position of the electrode core covers and seals the cavity opening of the testing semi-cavity structure to form a testing cavity for testing the liquid to be tested.
In one embodiment, the electrode cover comprises an upper electrode cover and a lower electrode cover, the lower electrode cover is detachably clamped on the upper electrode cover, and the electrode core is detachably clamped between the upper electrode cover and the lower electrode cover.
In one embodiment, the electrode upper cover has an inner rim and an outer rim both extending circumferentially thereof and being radially spaced apart, the electrode lower cover having a mounting opening extending through a thickness thereof;
one side end of the electrode core is clamped on the inner side edge, the other side end of the electrode core is clamped on the mounting port, and the lower electrode cover is clamped on the outer side edge;
the testing half-cavity structure is positioned on the inner side of the inner side edge, and the inlet end of the liquid inlet channel to be tested and the outlet end of the liquid outlet channel to be tested are positioned between the inner side edge and the outer side edge.
In one embodiment, the electrode core includes a core portion and a circuit portion connected to the core portion, and an electrode film;
the chip part comprises a chip body which is detachably arranged on the electrode cover, and a positive electrode and a negative electrode which are packaged in the chip body and exposed from the surface of the chip body, the positive electrode and the negative electrode are mutually insulated, the electrode cover covers the exposed parts of the positive electrode and the negative electrode, and the electrode test site comprises the positive electrode, the negative electrode and the electrode film;
the circuit part comprises a first contact and a second contact, the positive electrode is electrically connected with the first contact, and the negative electrode is electrically connected with the second contact.
In one embodiment, the positive electrode is cylindrical, the negative electrode is annular, and the positive electrode is arranged in the ring of the negative electrode at intervals.
In one embodiment, the test half-cavity structure is bowl-mouth shaped.
In one embodiment, the electrode upper cover and the electrode lower cover are both plastic injection-molded parts.
In one embodiment, the electrode core further comprises an intelligent chip, and the intelligent chip is used for storing factory information and use information of the electrode core;
the circuit part comprises a third contact, and the intelligent chip is electrically connected to the third contact.
Compared with the prior art, the test electrode provided by the application has the advantages that the electrode cover is provided with the liquid inlet runner to be tested, the liquid outlet runner to be tested and the test semi-cavity structure connected between the liquid inlet runner to be tested and the liquid outlet runner to be tested, and the electrode test position of the electrode core covers and seals the cavity opening of the test semi-cavity structure to form the test cavity for testing the liquid to be tested. After the assembly is completed, the structure of the electrode is provided with the straight-through micro flow channel, the structure is simple, the required sample amount is small, a quantifying device is not needed for accurately quantifying the sample, the manufacturing cost is low, the service life is long, each part can be molded by a mold, the assembly process is simple and reversible, and the obtained product has high yield.
Another object of the present application is to provide an electrode module, the electrode module at least includes an electrode holder, and the test electrode as described above, the test electrode is detachably mounted on the electrode holder.
The electrode module that this application provided compares in prior art's beneficial effect, compares in prior art's beneficial effect in the test electrode that this application provided, and this is no longer repeated here.
It is also an object of the present application to provide a detection system comprising a test electrode as described above, or an electrode module as described above.
Compared with the beneficial effects of the prior art, the detection system provided by the application has the beneficial effects that the test electrode or the electrode module provided by the application has the beneficial effects of being compared with the prior art, and the description is omitted here.
Detailed Description
In order to make the technical problems, technical solutions and advantageous effects to be solved by the present application clearer, the present application is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the present application and are not intended to limit the present application.
It will be understood that when an element is referred to as being "secured to" or "disposed on" another element, it can be directly on the other element or be indirectly on the other element. When an element is referred to as being "connected to" another element, it can be directly connected to the other element or be indirectly connected to the other element.
It will be understood that the terms "length," "width," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like, as used herein, refer to an orientation or positional relationship indicated in the drawings that is solely for the purpose of facilitating the description and simplifying the description, and do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be considered as limiting the present application.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present application, "a plurality" means two or more unless specifically limited otherwise.
The test electrode 100, the electrode module 200, and the detection system 300 provided in the embodiments of the present application will now be described.
Referring to fig. 1 to 8, a test electrode 100 according to an embodiment of the present disclosure includes an electrode cover and an electrode core 102 detachably mounted on the electrode cover; the electrode cover is provided with a liquid inlet channel 103 to be tested, a liquid outlet channel 104 to be tested and a testing semi-cavity structure 105 connected between the liquid inlet channel 103 to be tested and the liquid outlet channel 104 to be tested; the electrode test site of the electrode core 102 covers and closes the orifice of the test half-cavity structure 105 to form a test cavity for testing the liquid to be tested.
Compared with the prior art, in the test electrode 100 provided in the embodiment of the present application, the electrode cover has the liquid inlet channel 103 to be tested, the liquid outlet channel 104 to be tested, and the test half-cavity structure 105 connected between the liquid inlet channel 103 to be tested and the liquid outlet channel 104 to be tested, and the electrode test site of the electrode core 102 covers and seals the cavity opening of the test half-cavity structure 105, so as to form a test cavity for testing the liquid to be tested. After the assembly is completed, the structure of the electrode is provided with the straight-through micro flow channel, the structure is simple, the required sample amount is small, a quantifying device is not needed for accurately quantifying the sample, the manufacturing cost is low, the service life is long, each part can be molded by a mold, the assembly process is simple and reversible, and the obtained product has high yield.
In one embodiment, the electrode cover comprises an upper cover 1011 and a lower cover 1012, the lower cover 1012 is detachably clamped on the upper cover 1011, and the electrode core 102 is detachably clamped between the upper cover 1011 and the lower cover 1012.
In one embodiment, the electrode upper cover 1011 has an inner edge 1011b and an outer edge 1011a both extending circumferentially thereof and being radially spaced apart, and the electrode lower cover 1012 has a mounting opening 1012a extending through the thickness thereof; one side end of the electrode core 102 is clamped to the inner side edge 1011b, the other side end of the electrode core 102 is clamped to the mounting port 1012a, and the electrode lower cover 1012 is clamped to the outer side edge 1011 a; the test half-cavity structure 105 is located at the inner side of the inner edge 1011b, and the inlet end of the liquid inlet channel 103 to be tested and the outlet end of the liquid outlet channel 104 to be tested are located between the inner edge 1011b and the outer edge 1011 a.
As shown in fig. 4, the electrode top cover 1011, the electrode bottom cover 1012 and the electrode core 102 are all rectangular, but in other embodiments, the three may be other structures, such as other polygonal, circular, elliptical or irregular shapes.
The outer edge 1011a of the electrode upper cover 1011 is higher than the inner edge 1011b, the outer edge 1011a is provided with a plurality of foolproof openings 1011c which are sequentially spaced along the circumferential direction, and the inner wall of the outer edge 1011a is provided with a plurality of clamping openings 1011d which are sequentially spaced along the circumferential direction. Correspondingly, a plurality of protrusions 1012b are arranged on the peripheral wall of the electrode lower cover 1012 at intervals along the circumferential direction, and the plurality of protrusions 1012b and the plurality of clamping openings 1011d can be clamped correspondingly one by one.
An inlet end of the liquid inlet channel 103 to be measured and an outlet end of the liquid outlet channel 104 to be measured are respectively arranged at two opposite middle positions along the length direction of the electrode upper cover 1011 in the area between the outer edge 1011a and the inner edge 1011 b. The inlet end of the liquid inlet channel 103 to be measured and the outlet end of the liquid outlet channel 104 to be measured are both opened on a convex column structure 1011e, an annular part 1011f is arranged on the periphery of the two convex column structures 1011e at intervals, and a sealing ring 106 is clamped in the interval between the convex column structure 1011e and the annular part 1011 f. Correspondingly, a first matching port 1012c and a second matching port 1012d are respectively arranged at two opposite middle positions along the length direction of the electrode lower cover 1012 in the region between the outer wall of the electrode lower cover 1012 and the edge of the mounting port 1012a, the inlet end of the liquid inlet channel 103 to be measured and the outlet end of the liquid outlet channel 104 to be measured are respectively and correspondingly communicated with the first matching port 1012c and the second matching port 1012d, and the two sealing rings 106 seal the first matching port 1012c and the second matching port 1012 d. The usage of the liquid inlet channel 103 and the liquid outlet channel 104 is explained in the electrode module 200.
Two fool-proof through holes 12 are oppositely provided in the area between the outer edge 1011a and the inner edge 1011b in the diagonal direction of the electrode upper cover 1011. Correspondingly, two fool-proof through holes 12 are oppositely provided in the region between the outer wall of the electrode lower cover 1012 and the mouth edge of the mounting opening 1012a in the diagonal direction of the electrode lower cover 1012. The two fool-proof through holes 12 on the electrode upper cover 1011 and the two fool-proof through holes 12 on the electrode lower cover 1012 are in one-to-one correspondence and are coaxially communicated.
In the embodiment of the present application, as shown in fig. 1 and 4, two testing half-cavity structures 105 are disposed on the inner side of the inner edge 1011b of the electrode upper cover 1011, and the two testing half-cavity structures 105 are sequentially disposed and communicated along the length direction of the electrode upper cover 1011.
Preferably, the testing half-cavity structure 105 is in a bowl-mouth shape (oblate shape), the inlet and outlet of the testing half-cavity structure 105 are arranged at symmetrical positions opposite to each other along the radial direction of the testing half-cavity structure, the to-be-tested liquid inlet flow passage 103 and the to-be-tested liquid outlet flow passage 104 are respectively communicated with the inlet and outlet of the testing half-cavity structure 105, and the to-be-tested liquid inlet flow passage 103 and the to-be-tested liquid outlet flow passage 104 are in a line-cut connection state with the testing half-cavity structure 105, so that the entering liquid can be ensured to be filled in the testing cavity in a rotating mode, bubbles in the liquid can be effectively removed, and the purpose of preventing the bubbles from influencing the testing result is further achieved.
Of course, in other embodiments, one or three or even more test half-cavity structures 105 may be provided according to the requirements of the instrument test project.
In this embodiment, the liquid inlet channel and the liquid outlet channel are symmetrically arranged along the same straight line. In other embodiments, the liquid inlet channel and the liquid outlet channel may be arranged at any angle.
In one embodiment, the electrode core 102 includes a core 1021a portion 1021 and a circuit portion 1022 connected to the core 1021a portion 1021, and an electrode film 1023; the chip 1021a part 1021 comprises a chip 1021a detachably mounted on the electrode cover, and a positive electrode 1021b and a negative electrode 1021c which are packaged in the chip 1021a and exposed from the surface of the chip 1021a, the positive electrode 1021b and the negative electrode 1021c are insulated from each other, the electrode film 1023 covers the exposed parts of the positive electrode 1021b and the negative electrode 1021c, and the electrode test site comprises the positive electrode 1021b, the negative electrode 1021c and the electrode film 1023; the circuit part 1022 includes a first contact and a second contact, the positive electrode 1021b is electrically connected to the first contact, and the negative electrode 1021c is electrically connected to the second contact.
Preferably, the positive electrode 1021b is cylindrical, the negative electrode 1021c is annular, and the positive electrode 1021b is positioned in the ring of the negative electrode 1021c at intervals.
Referring to fig. 5 to 7, in the embodiment of the present application, the positive electrode 1021b is made of platinum Pt (or gold Au), and is cylindrical, and is sealed and encapsulated on the core 1021a of the electrode core 102 by using glue. One end of the positive electrode 1021b is flush with the end face of the chip 1021a and is exposed from the end face of the chip 1021a, the diameter of the exposed circular end face of the positive electrode 1021b is about 0.8mm, and the other end is electrically connected to the first contact of the circuit part 1022.
The negative electrode 1021c is made of silver Ag (or silver chloride AgCl), is in a ring sheet shape, has an outer diameter of about 6mm and an inner diameter of about 2.5mm, and is hermetically sealed on the core 1021a of the electrode core 102 by using glue. One end of the negative electrode 1021c is flush with the end surface of the core 1021a and is exposed from the end surface of the core 1021a, and the other end is electrically connected to the second contact of the circuit part 1022. The exposed circular end face of the positive electrode 1021b is surrounded in a ring shape by the exposed ring-shaped end face of the negative electrode 1021c, and the two are not communicated.
As shown in fig. 4, the electrode core 102 is housed in the electrode upper cover 1011, and a seal flow path is formed by the seal ring 107, the seal ring 106, and the electrode lower cover 1012. At the two electrode test sites on the electrode core 102, a thin specific electrode film 1023 is covered, and the electrode film 1023 covers both the positive electrode 1021b and the negative electrode 1021 c. After the electrode core 102 is coated with the film, if the electrode core 102 is found to be unsuccessful, the surface of the electrode core 102 is polished smoothly by fine sand paper and cleaned up, and then the film can be coated again.
The electrode test site according to the embodiment of the present application is a structure in which a portion exposed in a flow path is a plane, a thin electrode film 1023 is covered on the electrode film 1023, the electrode film 1023 covers a positive electrode 1021b and a negative electrode 1021c, and after a liquid to be tested enters the test site, a small amount of liquid can permeate the electrode film 1023 to reach between planes formed by the electrode film 1023 and the positive and negative electrodes 1021c, which is equivalent to the electrode filling liquid. Also, since the exposed area of the positive and negative electrodes is relatively large, the electrode film 1023 is more reliably in contact with the positive and negative electrodes.
In one embodiment, the electrode upper cover 1011 and the electrode lower cover 1012 are both plastic injection-molded parts, which can reduce the manufacturing cost of the electrode.
In one embodiment, the electrode core 102 further includes an intelligent chip 108, and the intelligent chip 108 is configured to store factory information and usage information of the electrode core 102; the circuit part 1022 includes a third contact point, and the smart chip 108 is electrically connected to the third contact point.
In addition, the connection mode of the parts of the electrode according to the embodiment of the present application is a snap connection, and an alternative may be a screw connection.
The electrode assembly method related to the embodiment of the application is that a plastic part and a sealing part form a sealed flow path, and the alternative scheme can be that glue is sealed to form the sealed flow path.
The electrode related to the embodiment of the application does not need to be added with internal filling liquid, and a solid internal filling liquid can be used instead.
In the electrode according to the embodiment of the present application, the material of the positive electrode 1021b is platinum Pt (or gold Au), and other inert metal materials may be used instead. The negative electrode 1021c is made of silver Ag (or silver chloride AgCl), and alternatively may be made of other metal materials or carbon. The dimensions of both include, but are not limited to, the dimensions mentioned in the examples of the present application.
The test cavity inside the electrode involved in the application is oblate, and the alternative scheme can be oval or long-strip-shaped structures.
The electrode core 102 related to the embodiment of the application has a built-in chip, so that the unexpected use is controllable, and the alternative scheme can be that the chip is protected and protected on other parts of the electrode, or other one-way reading and writing methods are adopted to realize the controllable part of the unexpected use.
Another objective of the present application is to provide an electrode module 200, wherein the electrode module 200 at least includes an electrode holder 201, and the test electrode 100 as described above, and the test electrode 100 is detachably mounted on the electrode holder 201.
As shown in fig. 9, in one embodiment, the electrode module 200 includes an electrode holder 201 and the test electrode 100 as described above, as well as an ejector holder 202, an ejector plate 203, and a signal plate 204 connected to the ejector plate 203.
The electrode holder 201 is provided with a mounting position for the test electrode 100, the mounting position has a through hole 2012 penetrating through the electrode holder 201, the test electrode 100 is mounted in the mounting position, and a part of a contact of the circuit part 1022 of the electrode core 102 is exposed through the through hole 2012. The electrode holder 201 is provided with a first stud 2013, and the first stud 2013 can pass through the fool-proof through hole 12 of the electrode cover of the test electrode 100. The electrode holder 201 is provided with a second column 2014, a to-be-detected liquid flow channel is formed in the center of the second column 2014, and the two to-be-detected liquid flow channels of the two second columns 2014 are respectively communicated with the to-be-detected liquid inlet flow channel 103 and the to-be-detected liquid outlet flow channel 104.
The ejector plate 203 is provided with a plurality of ejectors, the ejector base 202 is provided with a plurality of ejector pin through holes, and the plurality of ejectors electrically contact with the contacts of the circuit part 1022 located in the through holes 2012 after passing through the ejector pin through holes one by one.
It is another object of the present application to provide a detection system 300, wherein the detection system 300 includes the test electrode 100 as described above, or the electrode module 200 as described above.
As shown in fig. 10, in one embodiment, the detection system 300 includes the electrode module 200 as described above, and a liquid inflow pipe 301, a liquid outflow pipe 302 and a peristaltic pump. The liquid inflow pipeline 301 is connected to the liquid inlet channel 103, the liquid outflow pipeline 302 is connected to the liquid outlet channel 104, and the peristaltic pump is disposed on the liquid outflow pipeline 302.
Compared with the prior art, the test electrode 100, the electrode module 200 and the test system provided by the embodiment of the application have the following technical effects:
first, the structure of the electrode that this application embodiment is related to is ingenious, and all structural component all design into the plastic part of wall thickness homogeneous, and these parts all can be through the mould shaping, compare in that all parts of cubic electrode can only machine tooling form, have reduced the material cost of electrode by a wide margin.
Secondly, the electrode related to this application embodiment, after the assembly is accomplished, from taking the closed straight-through miniflow path, the supporting requirement to the flow path is low, and the rod-shaped electrode needs to support the high accuracy proportioning device that the cost is expensive to match to and complicated flow path system, has reduced the cost of equipment by a wide margin.
Thirdly, the electrode related to the embodiment of the application has a simple and reversible assembling process, and compared with the traditional rod-shaped electrode, the block-shaped electrode and the card electrode, the manufacturing difficulty is greatly reduced.
Fourth, in the electrode according to the embodiment of the present application, in the lamination stage, if a defect occurs, the electrode core 102 may be removed and simply processed, and then the lamination may be repeated.
Fifth, the electrode according to the embodiment of the present application does not require an internal filling liquid during production, and the electrode film 1023 inside the electrode does not contact the liquid during the storage period, so that the storage life of the electrode can be as long as 2 years in a cold storage environment, and the storage life of the electrode is greatly prolonged as compared with that of a conventional bulk electrode.
Sixthly, the electrode according to the embodiment of the present application, with the structure, on the premise of realizing a micro flow path, ensures that the contact area between the positive and negative electrodes 1021c and the electrode film 1023 is large enough, so that the electrode film 1023 and the electrode are in more reliable contact, the anti-interference force is stronger, and the service life can be as long as one month; compared with the traditional block-shaped electrode, the service life of the electrode is only about 15 days, and the card electrode can be used only once, so that the service life of the electrode is greatly prolonged.
Seventh, the smart chip 108 in the electrode according to the embodiment of the present application realizes bidirectional reading and writing between the electrode and an instrument. After the electrode is operated, the instrument can read the test item type, the remaining days of life, and the customer code of the instrument of the electrode from the smart chip 108. And when the electrode is operated, the chip can record the operation time of the electrode, calculate the service life and lock the client code of the instrument, so that the unexpected use of the electrode is controllable in a real sense, and the intelligent control of a manufacturer on the electrode consumable is realized.
The above description is only exemplary of the present application and should not be taken as limiting the present application, as any modification, equivalent replacement, or improvement made within the spirit and principle of the present application should be included in the protection scope of the present application.