CN214937857U - Jig assembly of micro oxygen generation module - Google Patents

Abstract

The utility model provides a tool subassembly of module takes place for trace oxygen, its shaping that can solve polymer electrolyte membrane's sunken spatial structure, the location of positive pole gas diffusion electrode and the technical problem of encapsulation. The utility model provides a tool subassembly is used in preparation of trace oxygen generation module which characterized in that: the device comprises a forming tool and a hot-pressing die; the forming tool comprises an upper plate and a lower plate, the upper plate is provided with a forming head, the lower plate is provided with a lower plate grid, a through hole of a prefabricated glue layer is formed in the center of the prefabricated glue layer, and the upper plate and the lower plate can be vertically positioned and spliced to enable the forming head and the lower plate grid to be coaxially arranged; the hot-pressing die comprises an anode template and a cathode template, wherein the anode template is provided with an anode grid which is positioned and used for accommodating the anode gas diffusion electrode, the cathode template is provided with a cathode grid which is positioned and used for accommodating at least the prefabricated glue layer and the polymer electrolyte membrane, and the anode template and the cathode template can be vertically positioned and spliced so that the anode grid and the cathode grid are coaxially arranged.

Description

Jig assembly of micro oxygen generation module

Technical Field

The utility model relates to a make the technical field of micro-flow pure oxygen through the electrochemistry method, concretely relates to tool subassembly of micro-oxygen generation module.

Background

The main method for producing micro-flow pure oxygen is an electrochemical method, in which direct current is applied to a membrane electrode assembly, oxygen in the air is subjected to electrocatalytic reaction at a cathode of the membrane electrode assembly to generate water, the water is diffused to an anode of the membrane electrode assembly through a polymer electrolyte membrane and subjected to electrocatalytic oxidation at the anode to generate pure oxygen, and the process is a process for concentrating and purifying the oxygen in the air in macroscopic view.

The micro oxygen generating module as the core part for producing micro flow pure oxygen has the structure as shown in fig. 11d and 11e, and comprises a cathode collector plate 36, a membrane electrode assembly 19, an anode collector plate 25, a sheet semi-permeable layer 39 and a base 28 which are stacked from top to bottom and are bound and fixed at the periphery through an insulating tape 401/an insulating shrinkage tube, wherein the membrane electrode assembly 19 comprises a cathode gas diffusion electrode 8, a polymer electrolyte membrane 6 and an anode gas diffusion electrode 17 which are stacked from top to bottom. Wherein, the middle part of the polymer electrolyte membrane 6 is pressed to form a concave space (for positioning the anode gas diffusion electrode 17) facing to one side of the cathode gas diffusion electrode 8, and a prefabricated glue layer 11 for adhering and packaging the outer edge of the polymer electrolyte membrane 6 (namely the part outside the concave space) and the cathode gas diffusion electrode 8 is arranged between the two; a polar plate frame type sealing element 26 for adhering and packaging the outer edge of the polymer electrolyte membrane 6 and the anode collector plate 25 is arranged between the outer edge of the polymer electrolyte membrane and the anode collector plate, and the polar plate frame type sealing element 26 is also embedded into a gap between the concave space and the anode gas diffusion electrode 17; the base 28 is provided with a base frame type sealing element 32 which is positioned between the sheet semi-permeable layer 29 and the anode collector plate 25 in a circle and used for adhesion and encapsulation of the two. Compared with the traditional structure, the micro oxygen generation module with the structure mainly has the differences of the concave space structure of the polymer electrolyte membrane, the positioning matching of the concave space and the anode gas diffusion electrode 17, and the adjustment of the corresponding packaging structure, such as the prefabricated glue layer 11 and the polar plate frame type sealing element 26. Therefore, it is necessary to develop a corresponding jig assembly for the novel structure to improve the production efficiency of the trace oxygen generation module and the yield of the product.

SUMMERY OF THE UTILITY MODEL

The utility model provides a tool subassembly of module takes place for trace oxygen, its shaping that can solve polymer electrolyte membrane's sunken spatial structure, the location of positive pole gas diffusion electrode and the technical problem of encapsulation.

Its technical scheme is like, a tool subassembly of module takes place for trace oxygen, its characterized in that: the device comprises a forming tool and a hot-pressing die;

the forming tool comprises an upper plate and a lower plate, wherein the upper plate is provided with a forming head matched with the inner profile of the groove of the depression space, the lower plate is provided with a lower plate grid which is positioned and at least contains a prefabricated glue layer and a polymer electrolyte membrane, the center of the prefabricated glue layer is provided with a prefabricated glue layer through hole matched with the outer profile of the groove of the depression space, and the upper plate and the lower plate can be vertically positioned and spliced to enable the forming head and the lower plate grid to be coaxially arranged;

the hot-pressing die comprises an anode template and a cathode template, wherein the anode template is provided with an anode grid which is positioned and used for accommodating the anode gas diffusion electrode, the cathode template is provided with a cathode grid which is positioned and used for accommodating at least the prefabricated glue layer and the polymer electrolyte membrane, and the anode template and the cathode template can be positioned and spliced up and down so that the anode grid and the cathode grid are coaxially arranged.

Further, the lower plate mesh positions and accommodates the cathode gas diffusion electrode, the pre-made glue layer, and the polymer electrolyte membrane, and the cathode mesh accommodates the cathode gas diffusion electrode, the pre-made glue layer, and the polymer electrolyte membrane.

Further, the upper plate and the lower plate are connected through a hinge, and when the upper plate is turned over to the lower plate, the upper plate and the lower plate are positioned and spliced; the anode template and the cathode template are connected through a hinge, and when the anode template is turned over to the cathode template, the anode template is turned over to the cathode template for positioning and splicing.

Furthermore, after the anode template and the cathode template are positioned and spliced up and down, the lower end of the anode gas diffusion electrode is accommodated in the concave space of the polymer electrolyte membrane, and the upper end of the anode gas diffusion electrode is higher than the upper surface of the anode template.

Further, the tool subassembly includes adsorbs bottom plate and absorption head, adsorb a side end face of bottom plate and seted up first absorption hole, first absorption hole intercommunication vacuum pump, the locating rack is installed along the outer of adsorbing the bottom plate, a side end face of absorption head has seted up the second and has adsorbed the hole, and second absorption hole intercommunication vacuum pump, the outer edge of absorption head is installed detachable guide frame, a side end face of absorption head with the size of a side end face of adsorbing the bottom plate is the same.

Furthermore, the jig assembly comprises a collector plate tool, and the collector plate tool is provided with a collector plate grid which is positioned and contains the membrane electrode assembly and the anode collector plate.

Further, the jig assembly comprises a base tool, and the base tool is provided with a base grid which is used for positioning and containing the membrane electrode assembly, the anode collector plate, the sheet semi-transparent layer and the base.

Further, the tool subassembly is including the encapsulation frock, the encapsulation frock includes a pair of chuck, the front side lower part of chuck extends forward and forms the chin, front side upper portion articulates there is the maxilla, the axle that links is connected to the rear side of chuck, the left and right sides lower part symmetry of chuck is equipped with the spout, the spout front side extends to the chin, the locking frame of the shape of falling U is installed to the top of chuck, the both sides lower part of locking frame be formed with spout sliding fit's slider, the upper portion threaded connection of locking frame has the screw, the end connection that the screw passed the locking frame has the pressure head.

The fixture component of the utility model bonds and encapsulates the tiled polymer electrolyte membrane and the prefabricated glue layer with the prefabricated glue layer through holes, and then presses the polymer electrolyte membrane through the forming head, so that the polymer electrolyte membrane extends into each prefabricated glue layer through hole, and a concave space is formed on the polymer electrolyte membrane; after the concave space structure is formed, the anode gas diffusion electrode is positioned and arranged in the middle of the concave space of the polymer electrolyte membrane to form a membrane electrode assembly; the packaging of the cathode gas diffusion electrode and the polymer electrolyte membrane is completed by arranging a prefabricated glue layer through hole on a prefabricated glue layer, then bonding the tiled polymer electrolyte membrane with the prefabricated glue layer and pressing to form a concave space, and the packaging between the membrane electrode assembly and an anode current collecting plate is completed by pressing the anode current collecting plate coated with the polar plate frame-shaped sealing element and the membrane electrode assembly; the preparation process is simple, and the jig assembly which is convenient to use and accurate in positioning is used as an auxiliary tool, so that the production efficiency of the trace oxygen generation module is improved, and the qualification rate of products is ensured.

Drawings

FIG. 1a is a schematic structural diagram of an adsorption base plate.

Fig. 1b is a schematic structural view of the functional layer.

Fig. 1c is a schematic view of the state where the functional layer is adsorbed on the upper surface of the adsorption base plate.

Fig. 2a is a schematic structural view of the suction head connecting guide frame.

Fig. 2b is a schematic structural view of the adsorption head without the guide frame.

FIG. 2c is a schematic diagram of the structure of the bilayer membrane.

Fig. 3a is a schematic view of the positioning and pressing state of the adsorption head, the double-layer film, the functional layer and the adsorption base plate.

Fig. 3b is a schematic structural diagram of the first adherend.

Fig. 4a is a schematic structural view of the first adhesive body with the release layer removed.

Fig. 4b is a schematic structural view of the cathode gas diffusion electrode, the first adhesive body stripped of the release layer, and the adsorption base plate in combination.

Fig. 4c is a schematic structural diagram of the second adherend.

Fig. 5a is a schematic view of a second adherend in a state of being cut to form small adherends.

Fig. 5b is an exploded view of the small adherend.

Fig. 6a is a schematic structural view of the small adherend cooperating with the molding tool in the state where the upper and lower plates are opened.

Fig. 6b is a schematic structural view of the forming tool with the upper plate and the lower plate closed.

FIG. 6c is a schematic diagram of a structure of a recessed adherend.

Fig. 7a is a schematic structural view of the concave bonding body matched with the hot pressing mold with the anode and cathode templates in an open state.

Fig. 7b is a schematic structural view of the anode gas diffusion electrode in cooperation with the hot pressing mold in the closed state of the anode and cathode templates.

Fig. 7c is a schematic structural view of the hot-pressed film in cooperation with a hot-pressed mold for mounting the concave bonding body and the anode gas diffusion electrode.

Fig. 7d is a schematic cross-sectional structure view of the membrane electrode assembly.

Fig. 8a is a schematic view of the structure of the anode collector plate.

Fig. 8b is a schematic structural diagram of the anode collector plate, the collector plate tool, the transfer plate and the workbench.

Fig. 8c is a schematic view of the structure of an anode current collector plate forming a plate frame type sealing member.

Fig. 8d is a schematic structural diagram of the membrane electrode assembly, the anode collector plate, the collector plate tool and the transfer plate.

Fig. 8e is a schematic structural diagram of the first intermediate.

FIG. 8f is a schematic cross-sectional structure of the first intermediate.

Fig. 9a is a schematic structural view of a base.

Fig. 9b is a schematic structural view of the second intermediate, i.e. the sheet-like semi-permeable layer, cooperating with the base.

Fig. 10a is a schematic structural diagram of the second intermediate body, the base tool, the transfer plate and the workbench.

Fig. 10b is a schematic view of a second intermediate body forming a base frame type sealing member.

Fig. 10c is a schematic structural diagram of the first intermediate body, the second intermediate body forming the frame-type sealing member of the base, the base fixture, and the transfer plate.

Fig. 10d is a schematic diagram of the structure of the third intermediate.

FIG. 10e is a schematic sectional view of the third intermediate.

Fig. 11a is a schematic view showing a state where the front cartridge, the rear cartridge, the cathode collector plate, and the third intermediate body are not assembled.

Fig. 11b is a schematic view showing a state where the front cartridge, the rear cartridge, the cathode collector plate and the third intermediate body are assembled.

Fig. 11c is a schematic structural view of the front and rear chucks.

Fig. 11d is a schematic structural diagram of the trace oxygen generation module.

Fig. 11e is a schematic cross-sectional structural view of the trace oxygen generation module.

Detailed Description

A jig assembly of a trace oxygen generation module, as shown in FIG. 1a, FIG. 2a, FIGS. 6a to 6b, FIGS. 7a to 7c, FIG. 8b, FIG. 10a, FIG. 10c and FIGS. 11a to 11c, comprises an adsorption tool, a forming tool 14, a hot-pressing mold 16, a current collecting plate tool 24, a base tool 31 and an encapsulation tool.

Adsorb frock includes adsorption bottom plate 2 and adsorption head 4, adsorption bottom plate 2's upper surface 22 has seted up first adsorption hole 23, first adsorption hole 23 intercommunication vacuum pump, adsorption bottom plate 2's outer edge is installed locating rack 21, second adsorption hole 43 has been seted up to adsorption head 4's a side end face, second adsorption hole 43 intercommunication vacuum pump, adsorption head 4's outer edge is installed detachable guide frame 5, four medial surfaces 51 of guide frame 5 and four lateral surfaces of adsorption head 4 slide the laminating, four medial surfaces 51 of guide frame 5 and adsorption head 4's adsorption plane 41 form film accommodation space 541, a lateral surface of adsorption head 4 and the size of a lateral surface of adsorption bottom plate 2 are the same.

The forming tool 14 comprises an upper plate 142 and a lower plate 144, the upper plate 142 is provided with a forming head 143 matched with the inner profile of the groove of the recessed space 611, the lower plate 144 is provided with a lower plate grid 141 which is positioned and at least contains the preformed adhesive layer 11 and the polymer electrolyte membrane 61, the center of the preformed adhesive layer 11 is provided with a preformed adhesive layer through hole 131 matched with the outer profile of the groove of the recessed space 611, and the upper plate 142 and the lower plate can be positioned and spliced up and down so that the forming head 143 and the lower plate grid 141 are coaxially arranged. The upper plate 142 and the lower plate 144 are connected by a hinge, and when the upper plate 142 is turned over onto the lower plate, the upper plate 142 and the lower plate 144 are positioned and spliced.

The hot press mold 16 includes an anode mold plate 162 and a cathode mold plate 164, the anode mold plate 162 is provided with an anode mesh 163 positioned and accommodating the anode gas diffusion electrode 17, the cathode mold plate 164 is provided with a cathode mesh 161 positioned and accommodating at least the prepreg layer 11 and the polymer electrolyte membrane 61, and the anode mold plate 162 and the cathode mold plate 164 can be positioned and spliced up and down such that the anode mesh 163 and the cathode mesh 161 are coaxially disposed. Anode template 162 and cathode template 164 are connected by a hinge, and when anode template 162 is inverted onto the cathode template, anode template 162 and cathode template 164 are positioned in alignment.

The lower plate mesh 141 positions and accommodates the cathode gas diffusion electrode 8, the pre-preg layer 11 and the polymer electrolyte membrane 61, and the cathode mesh 161 accommodates the cathode gas diffusion electrode 8, the pre-preg layer 11 and the polymer electrolyte membrane 61. When the anode template 162 and the cathode template are positioned and joined up and down, the lower end of the anode gas diffusion electrode 17 is accommodated in the concave space 611 of the polymer electrolyte membrane 61 and the upper end thereof is higher than the upper surface of the anode template 162.

The collector plate assembly 24 is provided with a collector plate grid 241 that locates and contains the membrane electrode assembly 19 and the anode collector plate 25.

The base fixture 31 is provided with a base grid 311 that locates and contains the membrane electrode assembly 19, the anode current collector plate 25, the sheet-like semi-permeable layer 29, and the base 28.

The packaging tool comprises a pair of chucks, namely a front chuck 34 and a rear chuck 35, wherein the rear sides of the front chuck 34 and the rear chuck 35 are connected with a connecting shaft 38, the lower parts of the left side and the right side are symmetrically provided with sliding grooves 353/343, an inverted U-shaped locking frame 37 is arranged above the front chuck 34 and the rear chuck 35, the lower parts of the two sides of the locking frame 37 are provided with sliding blocks in sliding fit with the sliding grooves, the upper part of the locking frame 37 is in threaded connection with a screw 371, the end part of the screw penetrating through the locking frame 37 is connected with a pressure head, the locking frame 37, the screw 371 and the pressure head form a locking mechanism, which is used for matching the upper jaw with the lower jaw after the upper jaw is pressed downwards to clamp the third intermediate body 33 and the cathode collector plate 36, the lower part of the front side of the front chuck 34 extends forwards to form a front lower jaw 342, the upper part of the front side is hinged with a front upper jaw 341, and a front inner profile matched with the front parts (including the oxygen connecting pipe 282) of the third intermediate body 33 and the cathode collector plate 36 is formed after the front upper jaw 341 and the front lower jaw 342 are spliced; the rear chuck 35 corresponds to the rear lower jaw 352 and the rear upper jaw 351, and the rear upper jaw 351 and the rear lower jaw 352 are joined together to form an inner contour profile that fits the third intermediate body 33 and the rear portion of the cathode collector plate 36 (including the oxygen tail tube 283, the cathode connecting head 361, and the anode connecting head 251). The runners each extend to a respective front mandible 342 and rear mandible 352.

The preparation method for preparing the trace oxygen generation module by the jig component comprises the following steps,

s1, adhering the tiled polymer electrolyte membrane 61 and the cathode gas diffusion electrode 8 through a prefabricated glue layer 11, forming a prefabricated glue layer through hole 131 in the prefabricated glue layer 11, pressing the middle parts of the polymer and the electrolyte membrane towards one side of the cathode gas diffusion electrode 8 through a forming head 143 to form a concave space 611, and attaching the side part of the groove outer molded surface of the concave space 611 to the inner side surface of the prefabricated glue layer through hole 131 and attaching the top part of the concave space 611 to the cathode gas diffusion electrode 8; positioning and bonding the anode gas diffusion electrode 17 in the middle of the recessed space 611 to form a membrane electrode assembly 19, wherein a ring of sealing member embedding groove is formed between the circumference of the anode gas diffusion electrode 17 and the recessed space 611;

s2, coating a circle of sealant around the outer edge of the end face of one side of the anode collector plate 25 to form an electrode plate frame-shaped sealing element 26, pressing the membrane electrode assembly 19 and the anode collector plate 25 with the electrode plate frame-shaped sealing element 26, attaching the anode collector plate 25 and the anode gas diffusion electrode 17, adhering the electrode plate frame-shaped sealing element 26, packaging the polymer electrolyte membrane 61 and the anode collector plate 25, and embedding and filling the sealing element embedding groove in the inner side of the end part of the electrode plate frame-shaped sealing element 26 to form a first intermediate body 27;

s3, connecting the flaky semi-permeable layer 29 on the boss 281 of the base 28 to form a second intermediate 30;

s4, coating a circle of sealant around the outer side of the boss 281 of the base 28 to form a base frame type sealing element 32, pressing the first intermediate body 27 and the second intermediate body 30, attaching the sheet semi-permeable layer 29 and the anode current collecting plate 25, and adhering and packaging the anode current collecting plate 25 and the base 28 by the base frame type sealing element 32 to form a third intermediate body 33;

and S5, connecting the cathode side of the third intermediate body 33 with the cathode collector plate 36, and binding and fixing the third intermediate body 33 and the cathode collector plate 36 through an insulating tape/an insulating shrink tube to form the micro oxygen generation module.

The following describes the manufacturing method in detail with reference to the jig assembly, the corresponding equipment (press and packaging machine are not shown) and the attached fig. 1a to 11 e.

Step S1 includes the following steps:

firstly, as shown in fig. 1a to 1c, a functional layer 1 is arranged on the upper surface of an adsorption base plate 2 and is positioned by a positioning frame 21, a vacuum pump is started to suck air flow, so that the functional layer 1 is adsorbed and fixed on the adsorption base plate 2, the length and width of the functional layer 1 are consistent with those of an upper surface 22 of the adsorption base plate 2, the functional layer 1 is composed of a prefabricated glue layer 11 and a release layer 12, the functional layer is provided with a prefabricated through hole 13 penetrating through the prefabricated glue layer 11 and the release layer 12, the prefabricated through hole 13 is arranged at a hole position part of the prefabricated glue layer 11, namely a prefabricated glue layer through hole 131, and the release layer 12 is attached to the upper surface 22 of the adsorption base plate 2;

secondly, as shown in fig. 2a to 2c, the double-layer film 6 is placed on the adsorption surface 41 of the adsorption head 4 and is positioned by the guide frame 5, namely, the double-layer film is placed in the film accommodating space 541, the vacuum pump is started to suck air flow, so that the double-layer film 6 is adsorbed and fixed on the adsorption head 4, the size distribution of the length and the width of the double-layer film 6 is consistent with the size distribution of the length and the width of the adsorption surface 41 of the adsorption head 4, the double-layer film 6 is composed of a polymer electrolyte film 61 and a protective layer 62, and the protective layer 62 is adsorbed and attached to the adsorption surface 41 of the adsorption head 4;

thirdly, as shown in fig. 3a and 3b, the guide frame 5 is taken down from the adsorption head 4, the adsorption head 4 adsorbing the double-layer film 6 is positioned and pressed with the adsorption base plate 2 adsorbed with the functional layer 1 under the guiding action of the positioning frame 21, so that the polymer electrolyte film 61 of the double-layer film 6 is adhered with the preformed adhesive layer 11 of the functional layer 1 to form a first adhesive body 7;

closing the vacuum pump communicated with the adsorption base plate 2, closing the vacuum pump communicated with the adsorption head 4, taking the first adhesive body 7 off the upper surface of the adsorption base plate 2, placing the first adhesive body 7 in a press, and applying a certain pressure to the first adhesive body 7 through the press to increase the adhesive force between the polymer electrolyte membrane 61 and the prefabricated adhesive layer 11;

fourthly, as shown in fig. 4a to 4c, placing the release layer 12 of the first adhesive body 7 with the surface facing upward, placing the first adhesive body 7 on the upper surface 22 of the adsorption base plate 2 and positioning the first adhesive body by the positioning frame 21, enabling the protective layer 62 to contact and cover the upper surface 22 of the adsorption base plate 2, starting a vacuum pump to suck air flow so that the first adhesive body 7 is adsorbed and fixed on the adsorption base plate 2, stripping the release layer 12 from the first adhesive body 7 to expose the prefabricated adhesive layer 11, placing the cathode gas diffusion electrode 8 on the prefabricated adhesive layer 11 under the guiding action of the positioning frame 21 and adhering the cathode gas diffusion electrode with the prefabricated adhesive layer 11 to form a second adhesive body 9;

placing the adsorption head 4 on the cathode gas diffusion electrode 8 of the second adhesive body 9, and applying pressure to the adsorption head 4 to preliminarily adhere the cathode gas diffusion electrode 8 and the prefabricated adhesive layer 11;

closing the vacuum pump communicated with the adsorption base plate 2, taking down the second adhesive body 9 from the upper surface of the adsorption base plate 2, placing the second adhesive body 9 in a press, and applying a certain pressure to the second adhesive body 9 through the press to increase the adhesive force between the cathode gas diffusion electrode 8 and the prefabricated adhesive layer 11; drying the second adherend 9 to further increase the adhesive force of the pre-adhesive layer 11;

fifthly, peeling the protective layer 62 from the second adhesive body 9 to expose the polymer electrolyte membrane 61, cutting the second adhesive body 9 from which the protective layer 62 is removed to form a plurality of small adhesive bodies 10, wherein the small adhesive bodies 10 are formed by sequentially adhering a small polymer electrolyte membrane 61, a small adhesive layer 11 provided with a through hole of the adhesive layer 11 and a small cathode gas diffusion electrode 8, and the small polymer electrolyte membrane 61, the small adhesive layer 11 provided with the through hole of the adhesive layer 11 and the small cathode gas diffusion electrode 8 correspond to a single trace oxygen generation module 40;

and a sixth step: placing the small adherends 10 in the lower plate grids 141 of the forming tool 14, covering the upper plate 142 of the forming tool 14, placing the forming tool 14 in a hot press for hot pressing, under the pressing of a forming head 143 at the back of the upper plate 142, extending the polymer electrolyte membrane 61 of each small adherend 10 into the through hole of each prefabricated glue layer 11 to form a concave adherend 15, forming a concave space 611 on the polymer electrolyte membrane 61, and enabling the forming head 143 and the lower plate grids 141 corresponding to the forming head and the built-in small adherends 10 to be on the same axis;

the seventh step: the depressed bond 15 is placed in the cathode mesh 161 of the cathode template 164 of the hot press mold 16, the anode template 162 is covered, the anode gas diffusion electrode 17 is inserted into the anode mesh 163 of the anode template 162 with the head of the anode gas diffusion electrode 17 higher than the anode mesh 163, the hot press film 18 is overlaid on the anode template 162 and the anode gas diffusion electrode 17, and the hot press mold 16 is placed in a hot press machine for hot pressing, thereby forming the membrane electrode assembly 19. The cathode mesh 161 of the hot press mold 16 is slightly larger in size than the recessed bond 15, and the cathode gas diffusion electrode 8 of the recessed bond 15 is in direct contact with the mold cathode face of the cathode template 164 of the hot press mold 16. The length and width of each anode mesh 163 are slightly smaller than those of the corresponding concave spaces 611, and the length and width of each anode gas diffusion electrode 17 are equivalent to those of the corresponding anode mesh 163; each recessed space 611 and the corresponding cathode mesh 161, anode mesh 163, and anode gas diffusion layer four are substantially on the same axis. The anode catalyst layer of the anode gas diffusion electrode 17 is in contact with the polymer electrolyte membrane 61 of the depressed bond 15. The anode gas diffusion electrode 17 is exposed to the anode template 162, i.e. the thickness of the anode gas diffusion electrode 17 is larger than the sum of the thickness of the anode template 162 and the thickness of the recessed space 611.

Step S2 includes the following steps:

the transfer plate 20 is placed on a workbench 23, the collector plate tool 24 is placed on the transfer plate 20, the anode collector plate 25 is placed in a collector plate grid 241 of the collector plate tool 24, a circle of sealant is coated around the outer edge of one side end face of the anode collector plate 25 to form a plate frame type sealing element 26, the collector plate tool 24 and each anode collector plate 25 placed on the anode collector plate tool are moved to a storage area from the workbench 23 by translating the transfer plate 20, and the storage area is temporarily stored for 0.5 minutes to 5 hours, the temperature range of the storage area is room temperature to 100 ℃, and the relative humidity range of the storage area is 0% to 100%. Then, the membrane electrode assembly 19 is placed in the collector plate mesh 241 of the collector plate tool 24 to cover each anode collector plate 25, the anode collector plates 25 covering the membrane electrode assembly 19 are placed in a press machine to be pressed and bonded, the plate frame type sealing member 26 is bonded to encapsulate the polymer electrolyte membrane 61 and the anode collector plates 25, and the inner side of the end portion of the plate frame type sealing member 26 is inserted into and filled in the sealing member insertion groove to form the first intermediate body 27. The first intermediate body 27 is stored for a time ranging from 0.5 hours to 48 hours at a temperature ranging from room temperature to 100 ℃ and at a relative humidity ranging from 0% to 100%, ensuring curing of the plate frame type seal 26.

The contour shape of the long and wide plane of the collector plate mesh 241 is the same as the contour shape of the long and wide plane of the anode collector plate 25, and the contour shape of the long and wide plane of the collector plate mesh 241 includes the contour shape of the long and wide plane of the cathode gas diffusion electrode 8 of the membrane electrode assembly 19. The length and width dimensions of the anode collector plate 25 are slightly smaller than those of the collector plate grid 241, and the sum of the thickness dimension of the anode collector plate 25 plus the thickness dimension of the membrane electrode assembly 19 is less than or equal to the thickness of the collector plate tooling 24. In the first intermediate body 27, the anode gas diffusion electrode 17 of the membrane electrode assembly 19 and the oxygen active surface of the anode current collector 25 are bonded to each other, the plate frame seal 26 is sealed and bonded to the polymer electrolyte membrane 61 and the oxygen active surface, and the plate frame seal 26 surrounds the anode gas diffusion electrode 17. The length and width dimensions of the cathode gas diffusion electrode 8 of the membrane electrode assembly 19 are comparable to the length and width dimensions of the oxygen active surface of the anode current collector plate 25, the sides of the cathode gas diffusion electrode 8 are aligned with the corresponding sides of the oxygen active surface, respectively, and the membrane electrode assembly 19 is substantially on the same axis as the oxygen active surface.

Step S3 includes the following steps:

the sheet-like semipermeable layer 29 is placed on the boss 281 of the base, and the two are bonded together to form the second intermediate 30.

The length and width dimensions of the sheet-shaped semi-permeable layer 29 are equivalent to those of the boss 281 of the base, four sides of the sheet-shaped semi-permeable layer 29 are aligned with four sides of the boss 281, and the sheet-shaped semi-permeable layer 29 and the boss 281 are on the same axis.

Step S4 includes the following steps:

placing the transfer plate 20 on the workbench 23, placing the base fixture 31 on the transfer plate 20, placing the second intermediate body 30 in the base grid 311 of the base fixture 31, coating a ring of sealant on the sealing edge 284 of the base 28 around the outer side of the boss 281 thereof to form the base frame-type sealing member 32, translating the transfer plate 20 to move the base fixture 31 and each second intermediate body 30 placed thereon from the workbench 23 to the storage area, temporarily storing in the storage area for a time period ranging from 0.5 minutes to 5 hours, the storage area having a temperature ranging from room temperature to 100 ℃, the storage area having a relative humidity ranging from 0% to 100%, thereafter placing the first intermediate body 27 in the base grid 311 of the base fixture 31 to cover each second intermediate body 30, placing the second intermediate body 30 covering the first intermediate body 27 in a press to press-bond the second intermediate body 30 to form the third intermediate body 33, storing the third intermediate body 33, the time of storage ranges from 0.5 hours to 48 hours, the temperature of storage ranges from room temperature to 100 ℃, the relative humidity of storage ranges from 0% to 100%, and the curing of the base frame-shaped sealing element is ensured.

The outline shape of the long and wide plane of the base mesh 311 is the same as the outline shape of the long and wide plane of the base, and the outline shape of the long and wide plane of the base mesh 311 includes the outline shape of the long and wide plane of the anode current collecting plate 25. The length and width dimensions of the base are slightly smaller than the length and width dimensions of the base grid 311. The current collector plate 25 of the first intermediate body 27 is bonded to the sheet-like semi-permeable layer of the second intermediate body 30, and the current collector plate 25 and the base 28 are bonded and sealed together by the base frame seal 32. The length and width dimensions of the oxygen active surface of the anode current collector plate 25 are comparable to the length and width dimensions of the outer edge profile of the sealing edge 284 of the base 28, with each edge of the oxygen active surface of the anode current collector plate 25 being aligned with a respective corresponding edge of the outer edge profile of the sealing edge 284 of the base 28. The oxygen active surface of the anode current collector plate 25 is substantially coaxial with the sheet-like semipermeable layer 29.

Step S5 includes the following steps:

opening the front upper jaw 341 of the front chuck 34 and the rear upper jaw 351 of the rear chuck 35 of the packaging machine, placing the cathode collector plate 36 and the third intermediate body 33 on the front lower jaw 342 of the front chuck 34 and the rear lower jaw 352 of the rear chuck 35, closing the front upper jaw 341 and the rear upper jaw 351, rotating the screws 371 of the locking mechanisms on the front chuck 34 and the rear chuck 35, and locking the front chuck 34 and the rear chuck 35, thereby applying a pre-tightening force to the cathode collector plate 36 and the third intermediate body 33; and electrifying the packaging machine, simultaneously rotating the connecting shaft 38 of the front chuck 34 and the connecting shaft 38 of the rear chuck 35 to drive the cathode collector plate 36 and the third intermediate body 33 to rotate, winding the insulating adhesive tape on the outer surfaces of the cathode collector plate 36 and the third intermediate body 33 between the front chuck 34 and the rear chuck 35 to form a trace oxygen generation module, loosening screws 371 of locking mechanisms on the front chuck 34 and the rear chuck 35, opening the front upper jaw 341 of the front chuck 34 and the rear upper jaw 351 of the rear chuck 35, taking out the trace oxygen generation module 40, and completing the whole preparation process.

The cathode gas diffusion electrode 8 of the third intermediate body 33 and the air active surface of the cathode current collecting plate 36 are bonded to each other, the length and width of the cathode gas diffusion electrode 8 are equivalent to those of the air active surface, and the outer edge of the cathode gas diffusion electrode 8 is aligned with that of the air active surface. The cathode connection terminal 361 of the cathode collector plate 36, the anode connection terminal 251 of the anode collector plate 25, and the oxygen tail tube 283 of the base 28 are on the same side of the trace oxygen generation module 40. The inner surface of the rear upper jaw 351 and the inner surface of the rear lower jaw 352 of the rear cartridge 35 are combined to form an inner contour space of the rear cartridge 35 identical to the outer surface of the anode contact tab 251 of the anode collector plate 25, the outer surface of the cathode contact tab 361 of the cathode collector plate 36, the outer surface of the oxygen tail tube 283 and the outer surface of the rear square region of the trace oxygen generation module 40, and the anode contact tab 251, the cathode contact tab 361, the oxygen tail tube 283 and the rear square region are fitted into the inner contour space of the rear cartridge 35. The inner surface of the front upper jaw 341 and the inner surface of the front lower jaw 342 of the front cartridge 34 combine to form the same inner contour space of the front cartridge 34 as the outer surface of the oxygen connector 282 and the outer surface of the front square region of the micro oxygen generation module 40, the oxygen connector 282 and the front square region being embedded in the inner contour space of the front cartridge 34. The axial lead of the front chuck 34 and the axial lead of the rear chuck 35 are coincident.

In other embodiments, step S5 can also be implemented by:

stacking the cathode collector plate 36 and the third intermediate body 33 together, sleeving the insulating shrink tube outside, opening the front upper jaw 341 of the front chuck 34 and the rear upper jaw 351 of the rear chuck 35 of the packaging machine, placing the cathode collector plate 36 and the third intermediate body 33 on the front lower jaw 342 of the front chuck 34 and the rear lower jaw 352 of the rear chuck 35, closing the front upper jaw 341 and the rear upper jaw 351, rotating the screws 371 of the locking mechanisms on the front chuck 34 and the rear chuck 35, and locking the front chuck 34 and the rear chuck 35, thereby applying a pre-tightening force to the cathode collector plate 36 and the third intermediate body 33. Electrifying the packaging machine, enabling the front chuck 34 and the rear chuck 35 to rotate in a shaft-connected manner, driving the cathode collector plate 36 and the third intermediate body 33 to rotate, applying hot air to the insulating shrinkage tube, enabling the insulating shrinkage tube to shrink to be tightly sleeved and attached on the outer surfaces of the cathode collector plate 36 and the third intermediate body 33 between the front chuck 34 and the rear chuck 35 to form the trace oxygen generation module 40, loosening screws 371 of locking mechanisms on the front chuck 34 and the rear chuck 35, opening a front upper jaw 341 of the front chuck 34 and a rear upper jaw 351 of the rear chuck 35, taking out the trace oxygen generation module 40, and completing the whole preparation process.

Claims (8)

1. The utility model provides a tool subassembly of module takes place for trace oxygen which characterized in that: the device comprises a forming tool and a hot-pressing die;

the forming tool comprises an upper plate and a lower plate, wherein the upper plate is provided with a forming head matched with the inner profile of the groove of the depression space, the lower plate is provided with a lower plate grid which is positioned and at least contains a prefabricated glue layer and a polymer electrolyte membrane, the center of the prefabricated glue layer is provided with a prefabricated glue layer through hole matched with the outer profile of the groove of the depression space, and the upper plate and the lower plate can be vertically positioned and spliced to enable the forming head and the lower plate grid to be coaxially arranged;

the hot-pressing die comprises an anode template and a cathode template, wherein the anode template is provided with an anode grid which is positioned and used for accommodating the anode gas diffusion electrode, the cathode template is provided with a cathode grid which is positioned and used for accommodating at least the prefabricated glue layer and the polymer electrolyte membrane, and the anode template and the cathode template can be positioned and spliced up and down so that the anode grid and the cathode grid are coaxially arranged.

2. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the lower plate grid positions and accommodates the cathode gas diffusion electrode, the preformed adhesive layer and the polymer electrolyte membrane, and the cathode grid accommodates the cathode gas diffusion electrode, the preformed adhesive layer and the polymer electrolyte membrane.

3. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the upper plate and the lower plate are connected through a hinge, and when the upper plate is turned over to the lower plate, the upper plate and the lower plate are positioned and spliced; the anode template and the cathode template are connected through a hinge, and when the anode template is turned over to the cathode template, the anode template is turned over to the cathode template for positioning and splicing.

4. The jig assembly of a trace oxygen generation module according to claim 1, wherein: and after the anode template and the cathode template are positioned and spliced up and down, the lower end of the anode gas diffusion electrode is accommodated in the concave space of the polymer electrolyte membrane, and the upper end of the anode gas diffusion electrode is higher than the upper surface of the anode template.

5. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the tool subassembly is including adsorbing bottom plate and absorption head, adsorb a side end face of bottom plate and seted up first absorption hole, first absorption hole intercommunication vacuum pump, adsorb the outer edge of bottom plate and install the locating rack, a side end face of absorption head has seted up the second and has adsorbed the hole, and the second adsorbs hole intercommunication vacuum pump, the outer edge of absorption head is installed detachable guide frame, a side end face of absorption head with a side end face of absorption bottom plate's size is the same.

6. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the jig assembly comprises a collector plate tool, and the collector plate tool is provided with a collector plate grid which is positioned and contains the membrane electrode assembly and the anode collector plate.

7. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the jig assembly comprises a base tool, and the base tool is provided with a base grid which is used for positioning and containing the membrane electrode assembly, the anode collector plate, the sheet semi-transparent layer and the base.

8. The jig assembly of a trace oxygen generation module according to claim 1, wherein: the tool assembly comprises a packaging tool, the packaging tool comprises a pair of chucks, the lower portion of the front side of each chuck extends forwards to form a lower jaw, the upper portion of the front side of each chuck is hinged to an upper jaw, the rear sides of the chucks are connected with connecting shafts, sliding grooves are symmetrically formed in the lower portions of the left side and the right side of each chuck, the front sides of the sliding grooves extend to the lower jaws, inverted U-shaped locking frames are installed above the chucks, sliding blocks are matched with the sliding grooves in a sliding mode, the upper portions of the locking frames are in threaded connection with screws, and the ends, penetrating through the locking frames, of the screws are connected with pressure heads.

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