CN214348608U - Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site - Google Patents

Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site Download PDF

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CN214348608U
CN214348608U CN202023194431.6U CN202023194431U CN214348608U CN 214348608 U CN214348608 U CN 214348608U CN 202023194431 U CN202023194431 U CN 202023194431U CN 214348608 U CN214348608 U CN 214348608U
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unit
injection
heating
extraction
chemical oxidation
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黄海
赵雪瑞
姜鸿喆
田立斌
高旺
李振宇
赵晓园
孙博成
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Suzhou Elite Environmental Protection Co Ltd
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Suzhou Elite Environmental Protection Co Ltd
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Abstract

The utility model discloses an in situ chemical oxidation prosthetic devices is reinforceed to electric heat for organic contaminated site, include: the injection heating unit, the electric strengthening unit, the extraction unit and the monitoring unit are respectively connected with the heating unit, the electric strengthening unit and the extraction unit for real-time monitoring and control. In this way, the utility model relates to an in situ chemical oxidation prosthetic devices is reinforceed to electric heat for organic contaminated site, with in situ chemical oxidation technique and electronic repair technique looks coupling, apply the electric field in polluting soil, can reach the effect that promotes material migration in the soil, have and be used to low permeability soil, the advantage that is showing that no secondary pollution produced, still increase hot function simultaneously in the syringe, it has improved medicament utilization ratio and repairing effect to show, and it is more extensive to make the technical application scene, the cost waste has effectively been avoided, compensate in order to the not enough that exist in the in situ chemical oxidation technique.

Description

Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site
Technical Field
The utility model relates to a soil restoration technical field especially relates to an in situ chemical oxidation prosthetic devices is reinforceed to electric heat for organic contaminated site.
Background
In recent years, with the continuous development of industrial industry in China, the problem of the polluted site brought by the pollution is gradually solved, and a polluted site repairing technology with good repairing effect and small secondary pollution is imperative to seek. In the in-situ chemical oxidation technology, chemical agents are injected into a polluted site to perform oxidation reaction with organic pollutants, and macromolecular organic pollutants are converted into small molecules or directly mineralized, so that the repairing effect is achieved.
The in-situ chemical oxidation technology has the characteristics of simple construction, short repair period and the like, and is mostly applied to the repair of actual polluted sites. However, the technology mainly depends on the soil diffusion action for mass transfer, and the application of the technology in some polluted sites with poor permeability is limited to a certain extent.
SUMMERY OF THE UTILITY MODEL
The utility model discloses an overcome prior art's is not enough, provides an electric heat strengthening normal position chemical oxidation prosthetic devices for organic pollution place, with normal position chemical oxidation technique and electronic restoration technique coupled, increases the heat function simultaneously in the syringe, realizes multiple restoration technique combined action, improves oxidant utilization ratio and medicament migration efficiency, strengthens whole restoration effect to it is more extensive to make the technical application scene.
In order to solve the technical problem, the utility model discloses a technical scheme be:
the utility model provides an electric heat strengthens normal position chemical oxidation prosthetic devices for organic contaminated site, includes: an injection heating unit, an electric strengthening unit, an extraction unit and a monitoring unit, wherein the monitoring unit is respectively connected with the heating unit, the electric strengthening unit and the extraction unit for real-time monitoring and control,
an injection heating unit: comprises an injection heating rod and a heating medicine injection device connected with the injection heating rod, wherein the heating medicine injection device comprises a medicine storage stirring tank, a medicine injection pump and a heating device, the injection heating rod comprises an outer tube, an injection hole and a medicine injection pipeline,
the medicament storage stirring tank is connected with the upper end of the medicament injection pipeline through the medicament injection pump, the medicament injection pipeline is arranged in the outer pipe, a plurality of injection holes communicated with the medicament injection pipeline are arranged on the outer pipe in an array manner, the outer pipe is connected with the heating device,
an electric strengthening unit: comprises an electrode plate and a direct current weak power supply, wherein the direct current weak power supply is connected with the electrode plate through a lead,
an extraction unit: comprises an extraction well, an extraction pump and a gas-liquid separation treatment device, wherein the gas-liquid separation treatment device is connected with an extraction pipeline through the extraction pump, the extraction pipeline extends into the extraction well,
a monitoring unit: including monitoring well and be used for acquireing and detect the sample monitoring devices of monitoring well in the sample.
In a preferred embodiment of the present invention, the outer tube is made of a heat conductive material.
In a preferred embodiment of the present invention, the electrode plate has a split structure.
In a preferred embodiment of the present invention, the gas-liquid separation processing device includes a water-gas separation device, a waste gas collection device, and a waste liquid collection device.
The utility model has the advantages that: the method has the advantages of simple equipment, high restoration efficiency and wide application range, can be applied to restoration of low-permeability soil compared with the traditional in-situ chemical oxidation technology, obviously improves the medicament utilization rate and the restoration effect, effectively avoids cost waste, and makes up for the defects existing in the traditional in-situ chemical oxidation technology.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments are briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained without inventive work, wherein:
FIG. 1 is a schematic structural diagram of a preferred embodiment of an electro-thermal enhanced in-situ chemical oxidation remediation device for an organic contaminated site according to the present invention;
fig. 2 is a schematic partial structural view of a preferred embodiment of an electric heating enhanced in-situ chemical oxidation remediation device for an organic contaminated site according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it should be apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.
Referring to fig. 1-2, an embodiment of the present invention includes:
an electric heating strengthening in-situ chemical oxidation restoration device for an organic polluted site is characterized in that a chemical oxidant is injected during restoration, the oxidant is activated by heating, the generation of oxidizing free radicals is promoted, the utilization rate of a medicament is improved, and the medicament is more actively diffused in soil; meanwhile, a direct-current weak electric field is applied to the soil, the migration of the medicament in the soil is enhanced by the action of the electric field, the remediation of the hypotonic soil is realized, and the overall efficiency of the equipment is improved.
An electric heating strengthening in-situ chemical oxidation restoration device for an organic polluted site, which structurally comprises: the injection heating unit, the electric strengthening unit, the extraction unit and the monitoring unit are respectively connected with the heating unit, the electric strengthening unit and the extraction unit for real-time monitoring and control.
An injection heating unit: comprises an injection heating rod 1 and a heating medicine injection device 2 connected with the injection heating rod.
The heating medicine injection device comprises a medicine storage stirring tank 21, a medicine injection pump 22 and a heating device 23.
The injection heating rod comprises an outer tube 11, injection holes 12 and a medicament injection pipeline 13, the medicament storage stirring tank is connected with the upper end of the medicament injection pipeline through a medicament injection pump, the medicament injection pipeline is arranged in the outer tube, a plurality of injection holes communicated with the medicament injection pipeline are arranged on the outer tube in an array mode, the outer tube is connected with the heating device, and when the injection heating rod is used, medicament heating and medicament injection are conducted simultaneously, and the repair effect is strengthened.
Wherein, the outer tube is heat conduction material.
An electric strengthening unit: the device comprises an electrode plate 3, a direct current weak power supply 4 and a plurality of leads, wherein the direct current weak power supply is connected with the electrode plate through the leads.
The electrode plates are of an assembled structure, can be spliced into different sizes and shapes according to the actual situation of a polluted site, and are provided with proper number of the electrode plates in the site. During restoration, an electric field is formed by implementing direct current weak current, so that migration of the agent in soil is enhanced, and restoration effect is improved.
An extraction unit: the device comprises an extraction well 5, an extraction pump 6 and a gas-liquid separation treatment device 7, wherein the gas-liquid separation treatment device is connected with an extraction pipeline through the extraction pump, and the extraction pipeline extends into the extraction well.
The gas-liquid separation treatment device comprises a water-gas separation device, a waste gas collection device and a waste liquid collection device.
During repair, water vapor in the extraction well is extracted through the extraction pump and the extraction pipeline, the extracted water vapor is firstly separated from the gas liquid through the water vapor separation device, and then the extracted water vapor enters the waste gas and waste liquid collection device respectively so as to be convenient for subsequent centralized disposal.
A monitoring unit: including monitoring well 8 and sampling monitoring device 9, sampling monitoring device acquires and detects the sample in the monitoring well for monitor repair effect.
An electric heating strengthening in-situ chemical oxidation restoration device for an organic polluted site comprises the following working steps:
(1) firstly, according to the range limit and the pollution condition of a polluted site, the ratio of medicaments and the number and arrangement of repair facilities are determined.
(2) When the remediation is started, firstly, uniformly stirring the oxidizing agents (such as persulfate and the like) in the agent storage stirring tank, pressurizing the oxidizing agents by an agent injection pump, and then conveying the oxidizing agents to the injection hole through the agent injection pipeline, so that the oxidizing agents are injected into the soil and react with organic pollutants in the soil; meanwhile, the heating device is started, the outer pipe heats the medicament in the medicament injection pipeline, and soil can be heated through heat conduction. On one hand, the utilization efficiency of the oxidant can be improved by heating, and the oxidant is activated by heat energy to generate free radicals with strong oxidizing property so as to oxidize and degrade organic pollutants in soil; on the other hand, the temperature rise of the soil increases the migration rate of molecules in a polluted site, and the contact of the medicament and organic pollutants is increased, so that the reaction is quicker.
(3) When the medicine is injected and heated, the electric strengthening unit is started, direct-current weak current is introduced into the field, the diffusion of the medicine in the soil is promoted by the action of the electric field, particularly, the diffusion of the medicine in a low-permeability soil region is realized, and the repair dead angle is reduced. Meanwhile, the current further catalyzes the oxidant to decompose the free radicals, so that the medicament utilization rate is obviously improved, and the cost waste is avoided.
(4) During repair, extraction is carried out in an extraction well through an extraction pump, gas and liquid are separated through a water-gas separation device after extraction, and waste gas and waste liquid respectively enter a collection device for subsequent centralized treatment; and the monitoring unit monitors the repairing effect in real time.
The utility model relates to an in situ chemical oxidation prosthetic devices is reinforceed to electric heat for organic contaminated site's beneficial effect is:
1. the invention couples the in-situ chemical oxidation technology with the electric repair technology, combines the heating function in the injection unit, and has the combined action of multiple repair technologies, thereby improving the utilization rate of the oxidant and the migration efficiency of the medicament and enhancing the overall repair effect.
2. The method has the advantages of simple equipment, short restoration period and wide application range, can realize restoration of low-permeability soil, effectively improves the medicament utilization rate and restoration effect and makes up for the defects in the conventional in-situ chemical oxidation technology compared with the conventional in-situ chemical oxidation technology.
The above only is the embodiment of the present invention, not limiting the patent scope of the present invention, all of which utilize the equivalent structure or equivalent flow transformation made by the content of the specification of the present invention, or directly or indirectly applied to other related technical fields, all included in the same way in the patent protection scope of the present invention.

Claims (4)

1. An electric heating strengthening in-situ chemical oxidation repair device for an organic polluted site is characterized by comprising: an injection heating unit, an electric strengthening unit, an extraction unit and a monitoring unit, wherein the monitoring unit is respectively connected with the heating unit, the electric strengthening unit and the extraction unit for real-time monitoring and control,
an injection heating unit: comprises an injection heating rod and a heating medicine injection device connected with the injection heating rod, wherein the heating medicine injection device comprises a medicine storage stirring tank, a medicine injection pump and a heating device, the injection heating rod comprises an outer tube, an injection hole and a medicine injection pipeline,
the medicament storage stirring tank is connected with the upper end of the medicament injection pipeline through the medicament injection pump, the medicament injection pipeline is arranged in the outer pipe, a plurality of injection holes communicated with the medicament injection pipeline are arranged on the outer pipe in an array manner, the outer pipe is connected with the heating device,
an electric strengthening unit: comprises an electrode plate and a direct current weak power supply, wherein the direct current weak power supply is connected with the electrode plate through a lead,
an extraction unit: comprises an extraction well, an extraction pump and a gas-liquid separation treatment device, wherein the gas-liquid separation treatment device is connected with an extraction pipeline through the extraction pump, the extraction pipeline extends into the extraction well,
a monitoring unit: including monitoring well and be used for acquireing and detect the sample monitoring devices of monitoring well in the sample.
2. The device of claim 1, wherein the outer tube is made of a heat conducting material.
3. The device for repairing an organic polluted site by electrothermal strengthening in-situ chemical oxidation as claimed in claim 1, wherein the electrode plate has a built-up structure.
4. The device for repairing organic contaminated sites by electrothermal strengthening in-situ chemical oxidation as claimed in claim 1, wherein the gas-liquid separation treatment device comprises a water-gas separation device, an exhaust gas collection device and a waste liquid collection device.
CN202023194431.6U 2020-12-28 2020-12-28 Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site Active CN214348608U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112474768A (en) * 2020-12-28 2021-03-12 苏州精英环保有限公司 Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site
CN114535284A (en) * 2022-02-24 2022-05-27 生态环境部南京环境科学研究所 In-situ heat-enhanced chemical redox coupling repair method for composite organic polluted site
WO2023123426A1 (en) * 2021-12-31 2023-07-06 北京建工环境修复股份有限公司 Soil remediation system and soil remediation method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112474768A (en) * 2020-12-28 2021-03-12 苏州精英环保有限公司 Electric heating reinforced in-situ chemical oxidation repairing device for organic polluted site
WO2023123426A1 (en) * 2021-12-31 2023-07-06 北京建工环境修复股份有限公司 Soil remediation system and soil remediation method
CN114535284A (en) * 2022-02-24 2022-05-27 生态环境部南京环境科学研究所 In-situ heat-enhanced chemical redox coupling repair method for composite organic polluted site
CN114535284B (en) * 2022-02-24 2023-04-07 生态环境部南京环境科学研究所 In-situ heat-enhanced chemical oxidation-reduction coupling repair method for composite organic polluted site

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