CN111069264A - In-situ thermal desorption repair system and repair method for polluted site - Google Patents
In-situ thermal desorption repair system and repair method for polluted site Download PDFInfo
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- CN111069264A CN111069264A CN201911417991.2A CN201911417991A CN111069264A CN 111069264 A CN111069264 A CN 111069264A CN 201911417991 A CN201911417991 A CN 201911417991A CN 111069264 A CN111069264 A CN 111069264A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/06—Reclamation of contaminated soil thermally
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/002—Reclamation of contaminated soil involving in-situ ground water treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/005—Extraction of vapours or gases using vacuum or venting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
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- Engineering & Computer Science (AREA)
- Soil Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
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- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to the technical field of soil remediation, and discloses an in-situ thermal desorption remediation system and a remediation method for a contaminated site. The repairing system comprises a heating system, an injection system and a temperature monitoring system, wherein the heating system comprises a heating well arranged in soil and a solar heat collector arranged on the ground, a spiral pipeline is arranged in the heating well, and heat conduction liquid heated by the solar heat collector enters the spiral pipeline from a lower part to a higher part through an inflow pipeline and then enters a liquid storage tank through an outflow pipeline. Compared with the traditional in-situ thermal desorption technology, the restoration system has the advantages that the solar heat collector is used for heating the heat conduction liquid, and then the heat conduction liquid is used for carrying out in-situ thermal strengthening restoration on the polluted site in a heat conduction mode, so that the energy consumption is greatly reduced, and the in-situ thermal desorption restoration cost is reduced.
Description
Technical Field
The invention relates to the technical field of soil remediation, in particular to an in-situ thermal desorption remediation system and a remediation method for a contaminated site.
Background
Soil is a basic environmental element constituting a natural ecosystem and is also a material base on which human beings live and develop. With the aggravation of the influence of human activities on the natural environment, such as the influence of petrochemical production activities, large-area soil in China is polluted by petrochemical organic matters such as petroleum, pomegranate oil, coal tar, chlorine-containing solvents and the like, wherein the difficulty in removing pollution formed by non-water-soluble liquids (NAPLs) with organic pollutants gathered in porous media is relatively high, and the damage of the pollution to the environment cannot be recovered to the original state through self-cleaning in a short time. With the prolonged exposure time of NAPLs in soil and groundwater, volatile components in NAPLs, such as chlorine-containing solvents and light petroleum hydrocarbons, will gradually volatilize to form soil vapor which invades the ground and causes great harm to the environment and human health; meanwhile, easily soluble substances in NAPLs can be gradually dissolved into underground water to form a pollution plume so as to pollute the underground water in a large area.
At present, the technology for remedying the soil polluted by organic matters is divided into an ex-situ remediation technology and an in-situ remediation technology. The ectopic remediation technology is a soil remediation technology that polluted soil is excavated or extracted from an original place where the site is polluted, and is transported or transferred to other places or positions for treatment and remediation. The ex-situ remediation technology is short in remediation period, original land development is not influenced, conditions in the treatment process are easy to control and the ex-situ remediation technology is widely popular in China, but the ex-situ remediation technology is involved in soil excavation and soil transportation, the problem of peculiar smell is difficult to solve, and the deep polluted area is difficult to control, so that the in-situ remediation technology is more and more vigorous in vitality in recent years.
In-situ thermal desorption (ISTD) is an important technology In-situ remediation of contaminated sites, and the remediation principle is that a contaminated medium and contaminants contained In soil or groundwater are heated to boiling temperature by direct or indirect heat exchange so as to be volatilized, separated or cracked, and a gaseous product is collected and captured and then purified. According to different heating modes, the in-situ thermal desorption technology mainly comprises the following steps: electric Resistance Heating (ERH), Thermal Conduction Heating (TCH), and Steam heating (SEE) 3 types. At present, in the remediation of organic polluted industrial sites, the application of in-situ thermal desorption technology is gradually increased, but the technologies available in the market have the defects of high energy consumption, high remediation cost and easy secondary pollution caused by the fact that a large amount of extracted pollutants need to be condensed and fully treated by sewage and waste gas.
Disclosure of Invention
Therefore, the technical problem to be solved by the invention is to overcome the defects of high energy consumption, high repair cost and easy secondary pollution of the existing in-situ thermal desorption technology, thereby providing an in-situ thermal desorption repair system for a polluted site; meanwhile, the invention also provides a method for repairing the polluted site by using the system.
In order to solve the technical problem, the invention provides an in-situ thermal desorption repair system for a polluted site, which comprises a heating system, an injection system and a temperature monitoring system, wherein the heating system comprises a heating well arranged in soil and a solar heat collector arranged on the ground, a spiral pipeline is arranged in the heating well, and heat conduction liquid heated by the solar heat collector enters the spiral pipeline through a flow inlet pipeline, exchanges heat from bottom to top and then enters a liquid storage tank through a flow outlet pipeline.
Further, the heat transfer fluid is at least one of distilled water, ethylene glycol and heat transfer oil.
Furthermore, the heating well is provided with a plurality of heating wells which are arranged in a triangular, square or hexagonal mode.
Further, the installation interval between two adjacent heating wells is 2-4 m.
Furthermore, the temperature monitoring system comprises a plurality of temperature monitors arranged in the soil of the in-situ heating polluted site.
Still further, the temperature monitoring system further comprises a temperature monitor disposed in an inflow line at the heater well inlet.
Further, the injection system comprises an injection well, the injection well is connected with a power device arranged on the ground, and chemical agents are injected into the injection well through the power device.
Further, the chemical agent is at least one of an oxidizing agent, a reducing agent, a microbial nutrient medium, and a microbial carbon source.
The system comprises an extraction well, wherein the extraction well is connected with an extraction device arranged on the ground, pollutants are extracted out of an original polluted site through the extraction well by the extraction device, and enter the sewage and/or waste gas treatment system arranged on the ground.
The invention also provides an in-situ thermal desorption restoration method for the polluted site, which comprises the following steps:
(1) heating heat transfer liquid through a solar heat collector, and allowing the heated heat transfer liquid to enter a heating well and perform thermal desorption on a polluted site in a heat transfer mode;
(2) injecting a chemical agent into the injection well.
Further, the method also comprises the following steps:
extracting the pollutants dissolved in the underground water or in the soil gas of the area to be repaired from the original polluted site by a multiphase or gas phase extraction method, and treating the sewage and the waste gas on the ground.
Further, the method also comprises the following steps:
and when the pollution concentration of liquid in the sewage treatment system or gas in the waste gas treatment system is detected to be reduced to the set proportion of the maximum possible pollution concentration and is continuously set, sampling the soil of the polluted site, and stopping repairing if the soil reaches a repairing target value.
The technical scheme of the invention has the following advantages:
1. the in-situ thermal desorption remediation system for the polluted site comprises a heating system, an injection system and a temperature monitoring system, wherein the heating system comprises a heating well arranged in soil and a solar heat collector arranged on the ground, a spiral pipeline is arranged in the heating well, and a heat transfer liquid heated by the solar heat collector enters the spiral pipeline through a flow inlet pipeline, exchanges heat from bottom to top and then enters a liquid storage tank through a flow outlet pipeline. Compared with the traditional in-situ thermal desorption technology, the invention utilizes the solar heat collector to heat the heat transfer liquid, and then the heat transfer liquid carries out in-situ thermal enhanced restoration on the polluted site in a heat conduction mode, so that the restoration system greatly reduces the energy consumption and the in-situ thermal desorption restoration cost. In addition, the heat transfer liquid is used as a heat transfer medium and only circulates in the heating system without entering the surrounding environment, so that the phenomenon that the pollutant migration range is expanded due to the direct contact of the heat transfer liquid with soil and underground water is avoided, the negative influence on the surrounding environment is further caused, the cyclic utilization of the heat transfer liquid can be realized, and the repair cost is further reduced. In addition, compared with the traditional in-situ thermal desorption technology adopting a hot water injection mode, the repair system disclosed by the invention does not need to treat the operations of subsequent extraction treatment and extraction water purification caused by balanced destruction of an aquifer due to injection of a large amount of hot water, so that the operation steps are greatly simplified, and the secondary pollution is effectively reduced.
2. According to the in-situ thermal desorption remediation system for the polluted site, the plurality of heating wells are arranged in a triangular, square or hexagonal mode, and soil and underground water in the polluted area can be uniformly heated.
3. According to the in-situ thermal desorption remediation system for the polluted site, the plurality of temperature monitors are arranged in the polluted site soil, the temperature change of the soil at different depths can be monitored, and the number of the heating wells can be determined according to the requirements of the actual process and the influence of site conditions.
4. According to the in-situ thermal desorption remediation system for the polluted site, the temperature monitor is arranged in the inflow pipeline positioned at the inlet of the heating well, so that the temperature is continuously monitored, and the flow rate of the heat transfer liquid can be automatically adjusted by controlling the power of the liquid power circulating device and then the automatic control system.
5. The in-situ thermal desorption remediation system for the polluted site further comprises an injection well, and the pollutants are subjected to in-situ treatment in a mode of strengthening chemical oxidation/reduction or promoting biodegradation through in-situ thermal effect by injecting chemical agents into the injection well, so that the extraction treatment capacity and treatment concentration are reduced, the secondary pollution risk is reduced, and the treatment cost is reduced.
6. According to the in-situ thermal desorption remediation method for the polluted site, sustainable solar energy is utilized to carry out in-situ heating, and meanwhile, an in-situ injection method is coupled, so that the in-situ thermal effect is cooperatively used with chemical and biological remediation technologies, the pollutant degradation effect of the biochemical remediation technology is enhanced, the treatment capacity of extracted water and extracted gas is reduced, the treatment pressure of secondary pollution is reduced, and the one-time investment and material consumption cost of tail water and tail gas treatment equipment are further reduced.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are some embodiments of the present invention, and other drawings can be obtained by those skilled in the art without creative efforts.
Fig. 1 is a schematic structural diagram of an in-situ thermal desorption remediation system for a contaminated site in embodiment 1 of the present invention;
FIG. 2 is a schematic diagram of the heating well of FIG. 1;
FIG. 3 is a schematic view of the heat radiation range of the heating well of FIG. 1.
Description of reference numerals:
1-a solar heat collector; 2-a circulating pump; 3-heating the well; 4-an inflow pipeline; 5-an outflow pipeline; 6-an extraction well; 7-an injection well; 8-a liquid storage tank; 9-a temperature monitor; 10-a processing system; 11-helical piping.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings, and it should be understood that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
In addition, the technical features involved in the different embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Examples
As shown in fig. 1, the present embodiment provides an in-situ thermal desorption repair system for a contaminated site, which includes a heating system, an injection system and a temperature monitoring system, wherein the heating system is a circulation system composed of a solar heat collector 1, a heater well 3, a circulation pump 2 and a liquid storage tank 8. After the heat transfer fluid (such as distilled water, ethylene glycol, heat transfer oil and the like) in the circulating system is heated to a set temperature in the solar thermal collector 1, the heat transfer fluid flows out of the solar thermal collector 1 and is conveyed to each heating well 3 through the inflow pipeline 4, the structure of each heating well 3 is shown in fig. 2, a spiral pipeline 11 is arranged in each heating well 3, the heated heat transfer fluid flows through the spiral pipeline 11 in each heating well 3 from bottom to top for heat exchange, and heat is conveyed to soil in a heat transfer mode to achieve in-situ soil heating. The heat transfer liquid after heat exchange passes through the outflow pipeline 5 and enters the liquid storage tank 8 under the action of the circulating pump 2 or flows back to the solar heat collector 1 for reheating.
In this embodiment, the number of the heating wells 3 is a plurality of, and the plurality of heating wells 3 are arranged in a triangular, square or hexagonal manner, as shown in fig. 3, so that the purpose of uniformly heating the soil and the groundwater in the polluted area can be realized. The installation distance between two adjacent heating wells 3 is 2-4 m, and the specific installation distance is determined according to factors such as process requirements and designed target temperature. For example, the target temperature is designed to be high, and the installation distance between two adjacent heating wells 3 is relatively small, otherwise, the installation distance can be enlarged appropriately.
In order to realize the continuous monitoring of the temperature of the heat transfer fluid, the flow rate of the heat transfer fluid is convenient to adjust by controlling the power of the circulating pump. In addition, a plurality of temperature monitors 9 are arranged in the soil of the polluted site, are arranged in the vertical direction of the site by relying on the heating wells 3, detect the temperature change of the soil at different depths in real time, and further determine the setting number of the heating wells according to the requirements of the actual process and the influence of site conditions.
In the embodiment, the injection system comprises an injection well 7 arranged in the soil, the injection well 7 is connected with a high-pressure pump arranged on the ground, chemical agents are injected into the injection well 7 through the high-pressure pump, and the chemical agents enter the soil or underground water of the polluted site through gaps of a well screen in the injection well 7. The chemical agent may be an oxidizing agent, such as hydrogen peroxide, persulfate; reducing agents, such as sulfates, microbial nutrients or microbial carbon sources, treat the contaminants in situ by enhanced chemical oxidation/reduction or biodegradation promotion while performing in situ thermal desorption. The specific type of chemical agent is selected according to the prior site pollutant investigation condition, and the specific additive amount needs to be determined according to the pollutant concentration and range.
After the in-situ enhanced chemical oxidation and biodegradation processes, for the pollutants which still need to be extracted to the ground for treatment, as shown in fig. 1, the remediation system of this embodiment further includes an extraction system, and a sewage and/or waste gas treatment system 10. The extraction system comprises an extraction well 6, the extraction well 6 is connected with an extraction device arranged on the ground, such as an extraction pump or a compressor, pollutants are extracted from an original polluted site through the extraction well 6 through the extraction device, and then enter a sewage and/or waste gas treatment system 10 arranged on the ground for subsequent treatment. The extraction well 6 and the sewage and/or waste treatment system 10 are the apparatus and processes used for conventional in situ heating processes.
A method for restoring polluted soil by adopting the in-situ thermal desorption restoration system for the polluted site comprises the following steps:
(1) heating the heat transfer fluid to a set temperature by using a solar heat collector, allowing the heated heat transfer fluid to enter a spiral pipeline in a heating well for heat exchange from bottom to top, and heating the polluted site by heat in a heat transfer mode; the heat transfer liquid after heat exchange enters a liquid storage tank under the action of a circulating pump or flows back to a solar heat collector to be heated again so as to realize internal circulation of the heating system;
(2) injecting a chemical agent into the injection well to utilize the heating effect of the step (1) to enhance chemical oxidation/reduction or promote biodegradation to treat pollutants;
if the pollutants are subjected to in-situ enhanced chemical oxidation and biodegradation, the pollutants which are still required to be extracted to the ground are extracted out of the original polluted site by a multiphase or vapor phase extraction method, and sewage and/or waste gas treatment is carried out on the ground;
(3) and when the pollution concentration of liquid in the sewage treatment system or gas in the waste gas treatment system is detected to be reduced to the set proportion of the maximum possible pollution concentration and is continuously set, sampling the soil of the polluted site, and stopping repairing if the soil reaches a repairing target value.
It should be understood that the above examples are only for clarity of illustration and are not intended to limit the embodiments. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And obvious variations or modifications therefrom are within the scope of the invention.
Claims (10)
1. The utility model provides a contaminated site normal position thermal desorption repair system, includes heating system, injection system and temperature monitoring system, its characterized in that, heating system is including establishing heater well (3) in soil and establishing solar collector (1) on the ground, heater well (3) inside is equipped with helical tube (11), warp heat conduction liquid behind solar collector (1) heating gets into through influent stream pipeline (4) helical tube (11) get into liquid storage pot (8) through outflow pipeline (5) after supreme heat transfer down.
2. The in-situ thermal desorption remediation system for the contaminated site according to claim 1, wherein a plurality of heating wells (3) are provided, and the plurality of heating wells (3) are arranged in a triangular, square or hexagonal manner.
3. The in-situ thermal desorption remediation system for the contaminated site according to claim 2, wherein the installation interval between two adjacent heating wells (3) is 2-4 m.
4. The in-situ thermal desorption remediation system for a contaminated site according to any one of claims 1-3, wherein the temperature monitoring system comprises a plurality of temperature monitors (9) disposed in the in-situ heated contaminated site soil.
5. The in-situ thermal desorption remediation system for a contaminated site according to claim 4, wherein the temperature monitoring system further comprises a temperature monitor disposed in an inflow pipeline (4) at an inlet of the heater well (3).
6. The in-situ thermal desorption remediation system for a contaminated site according to any one of claims 1-5, wherein the injection system comprises an injection well (7) disposed in the soil, the injection well (7) is connected with a power device disposed on the ground, and a chemical agent is injected into the injection well (7) through the power device.
7. The in-situ thermal desorption remediation system for the contaminated site as claimed in any one of claims 1 to 6, further comprising an extraction system and a sewage and/or waste gas treatment system (10), wherein the extraction system comprises an extraction well (6), the extraction well (6) is connected with an extraction device arranged on the ground, and the contaminants are extracted from the original contaminated site through the extraction well (6) by the extraction device and enter the sewage and/or waste gas treatment system arranged on the ground.
8. An in-situ thermal desorption remediation method for a polluted site is characterized by comprising the following steps:
(1) heating heat transfer liquid through a solar heat collector, and allowing the heated heat transfer liquid to enter a heating well and perform thermal desorption on a polluted site in a heat transfer mode;
(2) injecting a chemical agent into the injection well.
9. The repair method according to claim 8, further comprising the steps of:
extracting the pollutants dissolved in the underground water or in the soil gas of the area to be repaired from the original polluted site by a multiphase or vapor extraction method, and treating sewage and/or waste gas on the ground.
10. Repair method according to claim 8 or 9, characterized in that it further comprises the following steps:
and when the pollution concentration of liquid in the sewage treatment system or gas in the waste gas treatment system is detected to be reduced to the set proportion of the maximum possible pollution concentration and is continuously set, sampling the soil of the polluted site, and stopping repairing if the soil reaches a repairing target value.
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