CN214318886U

CN214318886U - Microorganism disinfection type silver-carrying mask

Info

Publication number: CN214318886U
Application number: CN202020944882.8U
Authority: CN
Inventors: 黄庆玺; 郑洋; 罗章元; 郑丛龙
Original assignee: Anson Biotechnology Co ltd
Current assignee: Anson Biotechnology Co ltd
Priority date: 2020-05-29
Filing date: 2020-05-29
Publication date: 2021-10-01
Anticipated expiration: 2030-05-29

Abstract

The embodiment of the utility model relates to the technical field of medical health gauze mask, specifically discloses a microorganism disappears and kills type silver-carrying gauze mask. Microorganism type silver-carrying gauze mask that kills includes the cover body and connects the frenulum of the cover body, the cover body is by outer to interior include in proper order: the protective layer, the silver-loaded filtering and disinfecting layer with negative charges and the protective layer, wherein the silver-loaded filtering and disinfecting layer carries nano silver particles in the nano silver colloidal solution prepared by the tannic acid green reduction method. The embodiment of the utility model provides a mainstream gauze mask product on can solving the existing market does not possess the microorganism and disappears and kill the efficiency and/or the air can get into the technical problem of nasal cavity all around by pasting in the gauze mask of face.

Description

Microorganism disinfection type silver-carrying mask

Technical Field

The utility model relates to a medical treatment and sanitation gauze mask technical field especially relates to a microorganism disappears and kills type silver-carrying gauze mask.

Background

The current medical and health mask standards in China are mainly divided into two types. YY0469-2011 & lt technical requirements for medical surgical masks & gt stipulates the technical requirements for medical surgical masks in a specification, and is suitable for disposable masks worn by clinical medical staff in invasive operation and other processes; the standard BFE test flow is 28.3L/min, and the filtration efficiency requirement is more than or equal to 95 percent; PFE testing flow is 30L/min, and the filtration efficiency requirement is more than or equal to 30 percent; the testing flow of the respiratory resistance is 8L/min, and the testing area is 5.06cm²The resistance is required to be less than or equal to 49mmH₂O; synthetic blood penetration requirements: 2mL of the synthetic blood was sprayed to the mask under a pressure of 10.7kPa (80mmHg) without causing permeation of the inside of the mask. The GB19083-2010 specification stipulates the technical requirements, test methods, marks and instructions for use of medical protective masks, and packaging, transportation and storage. The self-suction filtering type medical protective mask is suitable for filtering particles in air and blocking spray, blood, body fluid, secretion and the like in a medical working environment; the standard is detected at 85 flow rate, and the inhalation resistance of the mask is no more than 343.2Pa (35 mmH)₂O); synthetic blood penetration requirements: 2mL of the synthetic blood was sprayed to the mask under a pressure of 10.7kPa (80mmHg) without causing permeation of the inside of the mask. The mask is classified according to the filtering efficiency: the filtration efficiency of grade 1 is more than or equal to 95 percent, the filtration efficiency of grade 2 is more than or equal to 99 percent, and the filtration efficiency of grade 3 is more than or equal to 99.97 percent.

American medical hygiene mask Standard ASTM F2100-2004: the Low level index requires BFE not less than 95% and pressure difference less than 4.0mmH₂O，80mmHg of blood penetration; the Moderate grade index requirement is that BFE is more than or equal to 98 percent, and the pressure difference is less than 5.0mmH₂O, PFE is more than or equal to 98 percent, and the blood permeability is 120 mmHg; the index requirement of High level is that BFE is more than or equal to 98%, and the pressure difference is less than 5.0mmH₂O, PFE is more than or equal to 98 percent, and the blood permeability is 160 mmHg.

European union medical mask standard EN 14683-2014: the criteria are ranked in terms of filtration efficiency. The index requirements of TYPE Ia are that BFE is more than or equal to 95 percent, the pressure difference is less than 29.4Pa, and a represents that the material can only be applied to patients and people who are easy to be allergic; the index requirements of TYPE II are that BFE is more than or equal to 98%, differential pressure is less than 29.4Pa, and hemodialysis is 120 mmHg. The standard BFE test flow rate is 28.3L/min; the differential pressure test flow is 8L/min, and the test area is 4.9cm²。

The medical and health mask standards of our country and europe and the united states are mainly focused on physical indexes such as air permeability and filterability and safety of materials. While the main concern of filterability is bacterial filtration efficiency, there is no clear requirement for respiratory virus filtration efficiency. The virus is typically about 1/30 bacterial in size. Thus, bacteria cannot filter 100% of the material and viruses will pass easily. According to the report of researchers of the research institute of health and equipment of military medical science institute, the rejection rate of the N95 filter mask to viruses is 60.02%, the rejection rate of the ultrafine polypropylene fiber mask to the viruses is 49.90, and the rejection rate of the common mask to the viruses is less than 30%. It is known that, during the epidemic of viral infections of the respiratory tract, the activity of the virus is very high and a small amount of virus can infect the virus. Therefore, it is apparently difficult to effectively block the spread of respiratory viral infection by merely physical blocking and filtration with a mask. How to upgrade the physical barrier filtration mask into a microbial sterilizing mask becomes one of the important problems to be solved urgently.

The disposable medical mask mainly has a three-layer structure, wherein the outer layer is a waterproof or non-waterproof protective layer, the middle layer is a melt-blown cloth filter layer, and the inner layer is a water-absorbing protective layer. The intermediate meltblown fabric is typically electret treated to enhance electrostatic attraction. The meltblown web is very fine and the web is very uniform. When the liquid contacts with the film, the liquid is not easy to permeate due to surface tension; since the space formed by the connection between the ultrafine fibers is small, dust and bacteria are blocked. The specific surface area is large, and the non-woven material is arranged irregularly, so that the contradiction between the filtering effect and the air suction resistance of the common filter material is solved.

Due to the ultra-fine fiber composition of the meltblown fabric, numerous voids are formed which are effective in preventing penetration of bacteria, but are difficult to prevent penetration of viruses. At present, the mainstream mask products in the market are mainly physically blocked and filtered, and the microbial killing effect is not fully reflected. In addition, the periphery of the existing mask is open and not sealed, so that air can enter the nasal cavity from the periphery of the mask attached to the face. From the defects of the existing mask, the reason why the virus infection rate is high when people wear the mask during the epidemic period of respiratory virus infection can be explained.

Therefore, there is a need to provide a microbial sterilizing mask to solve the above problems in the prior art.

SUMMERY OF THE UTILITY MODEL

The embodiment of the utility model aims at providing a microorganism type silver-carrying gauze mask that disappears, can solve the mainstream gauze mask product on the existing market and do not possess microorganism and disappear and kill efficiency and/or the air can get into the technical problem of nasal cavity all around by pasting in the gauze mask of face.

On the one hand, the embodiment of the utility model provides a microorganism disappears and kills type silver-carrying gauze mask, including the cover body and connection the frenulum of the cover body, the cover body is by outer to interior including in proper order: the protective layer, the silver-loaded filtering and disinfecting layer with negative charges and the protective layer, wherein the silver-loaded filtering and disinfecting layer carries nano silver particles in the nano silver colloidal solution prepared by the tannic acid green reduction method.

In an embodiment of the present invention, the protective layer is a non-woven protective layer, the silver-loaded filtering and disinfecting layer is a silver-loaded teflon film material filtering and disinfecting layer, and the protective layer is a non-woven protective layer.

In an embodiment of the present invention, the cover further includes: and the high-efficiency filter layer is positioned between the silver-loaded filtering and sterilizing layer and the protective layer.

In an embodiment of the present invention, the high efficiency filter layer is made of a teflon film.

In an embodiment of the present invention, the protection layer is a silver-ion-carrying knitted fabric protection layer, the silver-carrying filtering and disinfecting layer is a silver-carrying knitted fabric filtering and disinfecting layer, and the protection layer is a silver-ion-carrying knitted fabric protection layer.

In an embodiment of the present invention, the face-attaching portion around the protective layer is further provided with an acrylic oil adhesive tape.

In one embodiment of the present invention, the width of the acrylic oil-based adhesive tape is 0.5 cm.

In an embodiment of the present invention, the acrylic oil adhesive tape is correspondingly provided with a cold seal.

In one embodiment of the present invention, the width of the cold seal is equal to the width of the acrylic oil-based adhesive tape.

In an embodiment of the present invention, the microbe-disinfecting silver-loaded mask further comprises: a nose bridge strip disposed at an upper edge of the mask body.

In an embodiment of the present invention, the particle size of the nano silver particles in the nano silver colloidal solution prepared by the tannic acid green reduction method ranges from 30 nm to 50 nm and the zeta potential ranges from-15 mv to-30 mv.

The utility model discloses microorganism type of killing silver-carrying gauze mask that disappears has given the gauze mask skin, intermediate level and inlayer to respiratory track virus, bacterium and fungi have static and repel or have static adsorption and repel and the dual efficiency of killing fast simultaneously, make the gauze mask block the type upgrade from the physics of the simple in the prior art and be effective microorganism type of killing, can not only guarantee healthy person and avoid being infected by the environment, also can effectively prevent the pathogenic microorganism polluted environment of respiratory track infection patient exhalation, infect other people.

Drawings

In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to these drawings without creative efforts.

Fig. 1 is a schematic structural view of the microbe-disinfecting silver-carrying mask of the present invention.

Fig. 2 is a schematic view of a local structure of a main stream type of the mask body of a microbe-disinfecting silver-loaded mask (disposable medical protective mask) of the present invention.

Fig. 3 is a schematic view of the local structure of the mask body of another mainstream style of the present invention, which is a microbe-disinfecting silver-loaded mask (reusable medical protective mask).

Detailed Description

Reference will now be made in detail to embodiments of the present general inventive concept, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to the like elements throughout. The embodiments are described below in order to explain the present general inventive concept by referring to the figures.

Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings.

Advantages and features of the present invention and methods of accomplishing the same may be understood more readily by reference to the following detailed description and the accompanying drawings. The present general inventive concept may, however, be embodied in many different forms and may be practiced or carried out in various ways, and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete and will fully convey the general inventive concept to those skilled in the art, and the present general inventive concept is defined by the appended claims.

Also, the phraseology and terminology used in this document is for the purpose of description and should not be regarded as limiting. The use of the terms "a" and "an" and "the" and similar referents in the context of describing the invention (especially in the context of the following claims) is to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The terms "comprising," "having," "including," and "containing" are to be construed as open-ended terms (i.e., meaning "including, but not limited to,") unless otherwise noted.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In addition, unless otherwise defined, all terms defined in commonly used dictionaries shall have their ordinary meaning. It is noted that the use of any and all examples, or exemplary terms, provided herein is intended merely to better illuminate the general utility concept and does not pose a limitation on the scope of the invention unless otherwise claimed.

The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.

The utility model discloses a microorganism type of killing silver-carrying gauze mask has two kinds of mainstream styles, and a style is the medical protective facial mask style of disposable type, and another style is the medical protective facial mask style of repetitious usage type. As is well known, a mask generally comprises a mask body and a fastening band connected to the mask body, the fastening band is used for fixing the mask body to a proper position by being hung on the ear of a user or being fastened on the head of the user, and the mask can be classified into an ear-hanging type or a bandage type according to the wearing manner. As shown in fig. 1, for the utility model, a schematic structural diagram of a microbe-sterilizing silver-carrying mask, it can be seen that the mask 10 shown in fig. 1 is composed of a mask body 11 and a fastening band 13 connecting the mask body 11, the fastening band 13 in fig. 1 is of an ear-hanging type, the mask 10 further comprises an acrylic oil adhesive tape 15 arranged around the face-attaching part of the mask 10 and a nose bridge strip 17 arranged at the upper edge of the mask body 11 and embedded therein, it can be understood that the mask body 11 is formed with a plurality of folds 19, for example, so as to present a three-dimensional shape to better attach to the face of a user and cover the nose and mouth of the user in a use state, and it can be known from the foregoing description that the utility model does not use the structure of the drawing as a limitation, and fig. 1 shows a microbe-sterilizing silver-carrying mask designed and manufactured on the basis of the style of the existing common disposable medical protective mask. In other embodiments, the mask 10 may not include the folds 19, the straps 13 may be strapping straps, the shape of the mask body 11 may be other shapes, such as the shape of a common N95 mask, the shape of a common sun-proof mask or an anti-haze dust-proof mask, such as a cup shape, a shell shape, or a boat shape, the position of the acrylic oil-based adhesive tape 15 may be set at a distance from the peripheral edge of the mask body 11, the acrylic oil-based adhesive tape 15 may be set at some critical position of the mask body 11 where air is easy to enter or leak, even the mask 10 may not include the nose bridge clip 17, or even the structure of the mask 10 may be set such that a certain layer of the structure of the mask body 11 can be freely removed and replaced, etc.

Specifically, the microbe-disinfecting silver-loaded mask of the disposable medical protective mask style is mainly composed of a three-layer structure, as shown in fig. 2, which is a schematic view of a local structure of the mask body of the microbe-disinfecting silver-loaded mask of the disposable medical protective mask style, the outer layer 1 is a protective layer, the middle layer 2 is a silver-loaded filtering disinfecting layer with negative charges, and the inner layer 3 is a protective layer. The intermediate layer 2 can achieve, for example, the effect of no shedding of the silver carrier. It should be noted that the terms "inner" and "outer" of the present invention refer to the position of the mask relative to the user when the mask is properly used.

The multi-use type medical protective mask is characterized in that the microbial sterilizing type silver-carrying mask mainly comprises four layers, wherein an outer layer 4 is a protective layer, a secondary outer layer 5 is a silver-carrying filtering sterilizing layer with negative charges, a middle layer 6 is a high-efficiency filter layer, and an inner layer 7 is a protective layer. Wherein, the secondary outer layer 5 can achieve the effect of no shedding of silver, and the middle layer 6 is, for example, a high-efficiency filter layer made of Polytetrafluoroethylene (PTFE) film-coated material, and the Polytetrafluoroethylene (PTFE) film-coated material has high-efficiency filtering efficiency which is more than 95%.

The middle layer 2 of the microbe-disinfecting silver-carrying mask in the style of the disposable medical protective mask or the secondary outer layer 5 of the microbe-disinfecting silver-carrying mask in the style of the reusable medical protective mask are both negatively charged silver-carrying filtering and disinfecting layers which bear nano silver colloidal solution decorated by tannic acid, namely nano silver particles in the nano silver colloidal solution prepared by the tannic acid green reduction method, and the nano silver particles decorated by the tannic acid in the nano silver colloidal solution have negative charges. Because viruses, bacteria and fungi are generally negatively charged, the negatively charged viruses, bacteria and fungi are not easily adsorbed or pass through the negatively charged silver-loaded filtering and sterilizing layer due to the repulsion action of static electricity. Even if a small amount of viruses, bacteria and fungi contact the silver-loaded filtering and killing layer with negative charges due to the action of airflow, the nano silver carried by the silver-loaded filtering and killing layer can generate multi-target effects (such as changing protein function, inhibiting enzyme activity, destroying nucleic acid template function and cracking viruses, bacteria and fungi), so that respiratory pathogenic microorganisms such as the viruses, the bacteria and the fungi can be killed quickly and effectively.

The utility model discloses a microorganism disappears and kills type silver-carrying gauze mask is different with the mainstream gauze mask among the prior art, and the mainstream gauze mask that appears in the existing market mainly is to the physics nature of bacterium and fungi filter, does not carry out the efficiency of killing to bacterium and fungi, especially is worse and does not kill the effect completely to the filter action of virus.

The utility model discloses a microorganism disappears and kills type silver-carrying gauze mask not only possesses the physics nature to the microorganism and blocks filterable function, has also had the efficiency of killing to the microorganism simultaneously. It can be said that the utility model discloses a microorganism disappears and kills type silver-carrying gauze mask has added twice insurance again on the basis that medical protective facial mask accords with the N95 standard, and first insurance is the absorption that excludes virus, bacterium and fungi, and second insurance is to contacting the virus, bacterium and the fungi that carry silver filtering and disinfecting layer with the negative charge to a small amount of, and the nanometer silver that carries on silver filtering and disinfecting layer will kill these pathogenic microorganisms fast effectively.

The utility model discloses utilize the nanometer silver colloidal solution ration dip-dyeing Polytetrafluoroethylene (PTFE) tectorial membrane material that tannic acid green reduction method prepared or texture soft, skin-friendly, moisture absorption is ventilative, have the looped fabric of good elasticity and extensibility 1-2 hours, then through 60-80 degrees stoving treatment, thereby it is not firm absorption in Polytetrafluoroethylene (PTFE) tectorial membrane material or texture soft, skin-friendly, moisture absorption is ventilative again to wash through 1-2 kPa's gas makes the nanometer silver granule on the looped fabric of good elasticity and extensibility come off and be close to zero, finally makes the utility model discloses the used material of the silver-carrying filtration killing layer of the area negative charge that includes in the aforesaid microorganism killing type silver-carrying gauze mask. Wherein, the grain diameter of the nano silver particles in the nano silver colloid solution prepared by the tannic acid green reduction method is about 30 to 50 nanometers and has negative charge, and the zeta potential of the nano silver particles is about-15 to-30 millivolts.

Specifically, the nano-silver colloidal solution is, for example, a 400-1000ppm nano-silver colloidal solution prepared by using silver nitrate, 1-2% tannic acid aqueous solution and 1-2% sodium carbonate aqueous solution, that is, by using a tannic acid green reduction method, and the specific preparation method thereof is, for example: preparing 0.063% or 0.126% (w/v) silver nitrate aqueous solution with purified water, taking 95 parts of the prepared silver nitrate aqueous solution under the condition of a magnetic stirrer, slowly adding 4 parts of 1-2% tannic acid aqueous solution, fully and uniformly mixing, then slowly adding 1 part of 1-2% sodium carbonate solution, fully stirring for 15 minutes, filtering the obtained solution through a 0.22 micron filter to finally prepare nano silver colloidal solution, then placing the nano silver colloidal solution into a brown bottle for later use, and performing the whole preparation process under the condition of 4 ℃. The average particle size of the prepared nano silver colloid solution is about 40 nanometers, and the nano silver colloid solution has negative charges (-15 millivolts to-30 millivolts).

The nano silver colloidal solution modified by tannic acid of the utility model also has the functions of broad-spectrum antivirus, antibacterial and antifungal by utilizing the nano silver colloidal solution prepared by the tannic acid green reduction method. The utility model discloses a concrete application of nanometer silver colloidal solution and corresponding experimental data as follows:

1. broad spectrum antibacterial antifungal applications: taking the nano silver colloid solution (400ppm) with negative charge and 10 respectively⁴cfu/ml of escherichia coli, staphylococcus aureus, klebsiella pneumoniae, pseudomonas aeruginosa broth culture, acinetobacter baumannii and candida albicans culture which are equal in volume are mixed, the mixture is acted for different times at room temperature, and then the nano-silver colloid solution is applied to detecting the inhibition effect of the nano-silver colloid solution on different bacteria. The specific data of the experimental results are shown in table 1, and the experimental results show that the nano silver colloidal solution has a very strong killing effect on the bacteria and the fungi.

TABLE 1

2. Broad spectrum antiviral applications: mixing the nano silver colloid solution (400ppm) with the same volume of influenza virus (H1N1), influenza virus (H3N2), parainfluenza virus and Newcastle disease virus solution respectively, acting at room temperature for 1 hour, then diluting the mixture on a 96-hole hemagglutination plate with normal saline at the same time, dripping 0.1 ml of 0.5% chicken erythrocyte into each hole, uniformly mixing, acting at room temperature for 1 hour, and observing the influence of the nano silver colloid solution on the blood coagulation activity of the four virus hemagglutinins. The specific data of the experimental results are shown in table 2, and the experimental results show that the nano silver colloidal solution can obviously inhibit the blood coagulation activity of hemagglutinin of influenza virus (H1N1), influenza virus (H3N2), parainfluenza virus and Newcastle disease virus, so that the nano silver colloidal solution has the effect of broad-spectrum resistance to respiratory virus infection.

TABLE 2

Viral species	Hemagglutination potency of the experimental group	Hemagglutination titers of virus controls
			Influenza virus (H1N1)	Has no hemagglutination activity	1280
Influenza virus (H3N2)	Has no hemagglutination activity	1280
			Parainfluenza virus	Has no hemagglutination activity	1280
Newcastle disease virus	Has no hemagglutination activity	1280

3. Broad-spectrum virucidal applications: mixing the nano silver colloid solution (400ppm) with negative charges with influenza virus (H1N1), influenza virus (H3N2), parainfluenza virus and Newcastle disease virus liquid in equal volumes respectively, acting for 1 hour at room temperature, then inoculating 0.1 ml of the mixed liquid into allantoic cavities of 10-day-old chick embryos respectively, 5 chick embryos in each group, and keeping the chick embryos in a 38-degree incubator for 72 hours, then putting the chick embryos in a 4-degree refrigerator for overnight, taking allantoic cavity liquid the next day, diluting the allantoic cavity liquid with physiological saline on a 96-hole blood coagulation plate in an equal time, dropwise adding 0.1 ml of 0.5% chick red blood cells (the content of the chick red blood cells is 5 mg/ml) into each hole, uniformly mixing, acting for 1 hour at room temperature, and observing the inactivation effect of the nano silver colloid solution on the four viruses. The specific data of the experimental results are shown in table 3, and the experimental results show that the nano silver colloid solution can completely inactivate influenza virus (H1N1), influenza virus (H3N2), parainfluenza virus and Newcastle disease virus, and four viruses do not proliferate in allantoic cavity of 10-day-old chick embryo.

TABLE 3

Viral species	Hemagglutination potency of the experimental group	Hemagglutination titers of virus controls
			Influenza virus (H1N1)	Has no hemagglutination activity	2560
Influenza virus (H3N2)	Has no hemagglutination activity	2560
			Parainfluenza virus	Has no hemagglutination activity	1280
Newcastle disease virus	Has no hemagglutination activity	1280

The following two specific examples are used to describe in detail the specific preparation method of the microbe-disinfecting silver-carrying mask of the present invention:

example 1 (disposable medical protective mask):

the microorganism type silver-carrying gauze mask that disappears in this example is 3 layers of structures, and the outer non-woven fabrics inoxidizing coating (as the name implies, the material is the non-woven fabrics), and the intermediate level is the silver-carrying Polytetrafluoroethylene (PTFE) tectorial membrane material filtration layer that disappears of taking the negative charge, and the inlayer is the non-woven fabrics protective layer (as the name implies, the material is the non-woven fabrics). The face-attaching part around the inner layer of the mask, for example, the periphery of the inner side of the mask is provided with the acrylic acid oily adhesive tape with a certain width (for example, 0.5 cm to 1 cm, preferably 0.5 cm) and the cold seal strip is correspondingly arranged on the acrylic acid oily adhesive tape, the width of the cold seal strip is suitable for completely covering the acrylic acid oily adhesive tape, therefore, the width of the cold seal strip is usually larger than that of the acrylic acid oily adhesive tape, preferably, the widths of the acrylic acid oily adhesive tape and the cold seal strip are equal, the acrylic acid oily adhesive tape can be started by tearing off the cold seal strip when the mask enters an epidemic area, a hospital and a crowd dense place, so that the acrylic acid oily adhesive tape arranged on the periphery of the inner side of the mask can be tightly attached to the face, gas can be prevented from entering and exiting from the periphery of the inner side of the mask, and the protection effect of the mask is remarkably improved. Further, as one skilled in the art can imagine, the mask may be provided with a nose bridge strip located at the upper edge of the mask, for example, embedded in the interior of the mask.

Example 2 (reusable medical protective mask):

the microorganism type of killing silver-carrying gauze mask in this example is 4 layer structures, and the skin is silver ion-carrying looped fabric inoxidizing coating (as the name implies, the material is silver ion-carrying looped fabric), and the secondary skin is fine and close skin, the texture is soft, the ventilative silver-carrying looped fabric filtration of taking the negative charge of moisture absorption disappears and kills the layer, and the intermediate level is Polytetrafluoroethylene (PTFE) tectorial membrane material high efficiency filter layer, and the inlayer is silver ion-carrying looped fabric protective layer (as the name implies, the material is silver ion-carrying looped fabric). The face-attaching part around the inner layer of the mask, for example, the periphery of the inner side of the mask is provided with the acrylic acid oily adhesive tape with a certain width (for example, 0.5 cm to 1 cm, preferably 0.5 cm) and the cold seal strip is correspondingly arranged on the acrylic acid oily adhesive tape, the width of the cold seal strip is suitable for completely covering the acrylic acid oily adhesive tape, therefore, the width of the cold seal strip is usually larger than that of the acrylic acid oily adhesive tape, preferably, the widths of the acrylic acid oily adhesive tape and the cold seal strip are equal, the acrylic acid oily adhesive tape can be started by tearing off the cold seal strip when the mask enters an epidemic area, a hospital and a crowd dense place in a special occasion, so that the acrylic acid oily adhesive tape arranged on the periphery of the inner side of the mask is attached to the face, gas can be prevented from entering and exiting from the periphery of the inner side of the mask, and the protection effect of the mask is remarkably improved. The material of the inner layer and the outer layer of the mask in the example, namely the silver ion-carrying knitted fabric, has positive charges, can be braked on the inner layer and the outer layer through electrostatic adsorption of negatively charged viruses, bacteria and fungi, and the silver ions on the inner layer can effectively kill the viruses, bacteria and fungi adsorbed on the silver ions. Further, as one skilled in the art can imagine, the mask may be provided with a nose bridge strip located at the upper edge of the mask, for example, embedded in the interior of the mask.

Specifically, the utility model discloses a Polytetrafluoroethylene (PTFE) tectorial membrane material that takes negative charge carries filtering and disinfecting layer is that the silver-carrying that takes negative charge that Polytetrafluoroethylene (PTFE) tectorial membrane material prepared as the substrate filters and disinfects the material and makes for, and its specific preparation method is as follows: the Polytetrafluoroethylene (PTFE) film-coated material is selected as a base material, and the fibers of the material are staggered to form a filter with the aperture smaller than 0.1 micron, and the filter has the advantages of water washing resistance and good filtering effect. Selecting 1 volume of a Polytetrafluoroethylene (PTFE) film-coated material, immersing into 2 volumes of nano silver colloid solution prepared by the 400-plus-1000 ppm tannic acid green reduction method, soaking for 1-2 hours at 37 ℃, taking out, drying at 42 ℃, washing away the nano silver particles which are not firmly adsorbed by gas of 1-2kPa to ensure that the nano silver particles fall off to be close to zero (for example, detecting by an atomic absorption spectrometer), and finally preparing the material for the silver-loaded Polytetrafluoroethylene (PTFE) film-coated material filtering and sterilizing layer with negative charges.

The utility model discloses an aforesaid silver-carrying looped fabric filtration of taking negative charge disappears and kills layer is made with the silver-carrying filtration of taking negative charge that the looped fabric prepared as the substrate disappears and kills the material, and its specific preparation method is as follows: soaking 1 volume of dense skin-friendly, soft, moisture-absorbing and breathable knitted fabric into 4 volumes of nano silver colloid solution prepared by the 400-plus-1000 ppm tannic acid green reduction method at 37 ℃ for 1-2 hours, taking out, drying at 42 ℃, washing away the nano silver particles which are not firmly adsorbed by gas of 1-2kPa to ensure that the shedding of the nano silver particles is close to zero (for example, by using an atomic absorption spectrometer), and finally preparing the material for the silver-loaded knitted fabric filtering and sterilizing layer with negative charges. Due to the fact that the nano silver colloid solution modified by the tannic acid is in the solution, numerous tannic acid molecules can be adsorbed on the surfaces of the nano particles. The tannic acid molecule has a dendritic branch structure, the tail end of the tannic acid molecule is provided with a large number of active hydroxyl groups, and the tail end of the tannic acid molecule has extremely strong hydroxyl acidity due to the electron-withdrawing effect of a benzene ring connected with hydroxyl groups, so that the swelling permeability of the tannic acid molecule to knitted fabric cellulose is greatly enhanced. Therefore, when the nano silver colloid solution modified by the tannic acid is used for treating the knitted fabric, the acidic hydroxyl can quickly permeate into the knitted fabric fiber to replace the bound water and form a swelling compound with the hydroxyl in the amorphous region and the crystalline region. In addition, the tannin molecules are in a dendritic branch structure, the number of terminal free hydroxyl groups is large, a strong hydrogen bond effect can be formed with hydroxyl groups on a knitted fabric cellulose macromolecule, the weighted hydrogen bond acting force is far higher than that of a traditional linear polymer (the linear polymer has intermolecular entanglement, and the active groups are mostly combined with self groups and are consumed in a large amount), so that the bonding force between the nanoparticles and the knitted fabric fibers in the tannin-modified nano silver colloidal solution is obviously enhanced, and the tannin-modified nano silver colloidal solution is washable and is not easy to fall off.

As can be seen from the foregoing description, the silver-loaded microbe disinfecting mask of the present invention, for the style of the disposable medical protective mask of example 1, can make bacteria, fungi and viruses with negative charges in the air not easily adsorbed on the silver-loaded Polytetrafluoroethylene (PTFE) film-coated material filtering disinfecting layer with negative charges through electrostatic action. For the style of the multi-use medical protective mask in example 2, the inner layer and the outer layer are made of silver ion-carrying materials, have positive charges, can adsorb and brake negatively charged bacteria, fungi and viruses through electrostatic action, and the silver ions on the inner layer and the outer layer can effectively kill the pathogenic microorganisms; a small number of bacteria, fungi and viruses which are not killed sequentially encounter the filtering and killing of a secondary outer silver-loaded knitted fabric filtering and killing layer with negative charges, a Polytetrafluoroethylene (PTFE) film-coated material high-efficiency filtering layer in the middle layer and a silver ion-loaded knitted fabric protective layer in the inner layer, and the mask has high-efficiency filtering and killing functions on respiratory viruses, bacteria and fungi due to the 4-layer structure.

Specifically, the specific advantages or effects of the microbial sterilizing silver-carrying mask of the present invention can be summarized as follows:

(1) double effect of electrostatic trapping and killing

The utility model discloses a microorganism disappears and kills type silver-carrying gauze mask, it is outer to have given the gauze mask, intermediate level and inlayer are to respiratory track virus, bacterium and fungi have had static to repel (the medical protective facial mask of disposable type), static adsorbs and repels (the medical protective facial mask of repetitious usage type) and the dual efficiency who disappears and kill fast, make the gauze mask block the type upgrading from the physics filtration of the simple in the prior art and be effective microorganism and disappear and kill the type, can not only guarantee healthy person and avoid by environmental infection, also can effectively prevent the pathogenic microorganism polluted environment of respiratory track infection patient exhalation, infect other people.

(2) Broad spectrum antiviral and antibacterial effects

The utility model discloses utilize the nano-silver absorption in the nano-silver colloidal solution of the negative charge of tannic acid decoration to carry silver Polytetrafluoroethylene (PTFE) tectorial membrane material filtering to disappear and kill the layer or carry silver looped fabric filtering to disappear and kill the layer, make the gauze mask have the efficiency of broad-spectrum anti respiratory track virus, bacterium and fungi.

(3) Effectively avoids the potential toxic and side effects of the nano-silver

The utility model discloses utilize the nano-silver colloidal solution of the negative charge of tannic acid decoration, after special production technology handles, can enough ensure the silver-carrying of gauze mask and filter the nano-silver that has born sufficient dose above killing the layer, can guarantee again that the silver-carrying of gauze mask filters the nano-silver granule on killing the layer and is difficult for droing, water-fast washing, has effectively avoidd the potential toxic and side effect that the nano-silver granule got into internal production.

To sum up, the utility model discloses a microorganism disappears and kills type silver-carrying gauze mask can guarantee effectively that bacterium, fungi and virus are effectively detained and are killed in the air to healthy people, makes the organism inhale clean air. For respiratory tract infectors, the exhaled infectious bacteria, fungi or viruses can be prevented from remaining on the silver-carrying filtering and sterilizing layer and can be killed, so that the exhaled air is clean, the air environment is effectively protected, and the transmission path of respiratory tract virus and bacterial infection is cut off.

While the invention has been described with reference to specific embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation to the teachings of the invention without departing from its scope. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed, but that the invention will include all embodiments falling within the scope of the appended claims.

Further, the logic flows depicted in the figures do not require the particular order shown, or sequential order, to achieve desirable results. In addition, other steps may be provided, or steps may be deleted from the described flows, and other components may be added to, or removed from, the described systems. Accordingly, other embodiments are within the scope of the following claims.

Claims

1. The utility model provides a microorganism type silver-carrying gauze mask that disappears, includes the cover body and connects the frenulum of the cover body, its characterized in that, the cover body is by outer to interior include in proper order: the silver-loaded filtering and killing device comprises a protective layer, a silver-loaded filtering and killing layer with negative charges and the protective layer, wherein the silver-loaded filtering and killing layer is loaded with nano silver particles; the protective layer is a non-woven fabric protective layer, the silver-loaded filtering and disinfecting layer is a silver-loaded polytetrafluoroethylene film-coated material filtering and disinfecting layer, and the protective layer is a non-woven fabric protective layer.

2. The microbe-disinfecting silver-carrying mask as claimed in claim 1, wherein an acrylic acid oil adhesive tape is further provided on the face-attached portion around the protective layer.

3. The microbiologically sterile, silver-loaded mask of claim 2, wherein said acrylic oiliness strip has a width of 0.5 cm.

4. The microbe-disinfecting silver-carrying mask as claimed in claim 2, wherein the acrylic oil adhesive tape is correspondingly provided with a cold seal.

5. The microbiologically sterile, silver-loaded mask of claim 4, wherein said cold seal has a width equal to the width of said acrylic oil strip.

6. The microbe-disinfecting silver-loaded mask of claim 1, further comprising: a nose bridge strip disposed at an upper edge of the mask body.

7. The microbe-disinfecting silver-loaded mask as claimed in claim 1, wherein the particle size of the nano silver particles ranges from 30 nm to 50 nm and the zeta potential ranges from-15 mv to-30 mv.