CN214060265U - Crushed coal pressure gasification gas water separation and recycling system - Google Patents
Crushed coal pressure gasification gas water separation and recycling system Download PDFInfo
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Abstract
The utility model provides a separation of crushed coal pressure gasification gas water and recycling system belongs to gas separation and retrieval and utilization field. The utility model discloses separate different categorised gas water respectively and retrieval and utilization, not only make entire system area little, the investment is low, the running cost is low, and the processing flow is short, equipment is few, and the pollutant emission point is few, is difficult for causing environmental pollution. By arranging equipment such as a medium-pressure flash evaporator, a vacuum flash separator and an ammonia still and arranging a settling tank and the top of a gas water tank to be connected with an inert gas pipeline, the whole system and the separation and recycling process are kept in micro-positive pressure operation of more than 0.2kPa, and the concentrated treatment of the VOCs and the odor discharged from the system can be ensured. The coal gas water treated by the deacidification tower is sent to the ammonia still, so that the coal gas water going to the biochemical treatment equipment can be subjected to ammonia still, the ammonia content in the coal gas water going to the biochemical treatment equipment can be reduced, and the problem that a biochemical system is difficult to stably operate due to the change of different raw material coals is solved.
Description
Technical Field
The utility model relates to a coal gas separation and retrieval and utilization technical field especially relate to a garrulous coal pressure gasification gas water separation and recycling system.
Background
The raw gas produced by the pressure gasification of crushed coal contains a large amount of water vapor, dust, and by-products of carbonization, such as tar, light oil, naphthalene, phenol, fatty acids, dissolved gases, and inorganic salts, and the temperature is also high. Therefore, it needs to be cooled and washed to lower the temperature and remove harmful substances from the raw gas. During the washing and cooling process of the crude gas, the impurity components enter water to form gas water with various components existing in gas, liquid and solid states, the components of the gas water are complex, and the contents of the various components are different along with the difference of coal types. The gas water can not be directly treated by conventional biochemical, filtering, reverse osmosis and other methods, and oil, dust, phenol, ammonia and the like in the gas water must be separated and recovered, so that on one hand, valuable substances in the wastewater are recovered, and certain economic benefit can be generated; on the other hand, the wastewater can meet the water inlet requirement of a common wastewater treatment method and is discharged after the wastewater is biochemically treated to reach the national discharge standard.
The most classical gas-water separation and recovery process is briefly described in the modern technical handbook of coal chemical industry, which is also a process commonly used in the conventional crushed coal pressure gasification technology, and specifically, after gasified gas water with the pressure of 3.0-6.0MPa and conversion cooling gas water are respectively sent into a gas-water separation system, the gasified gas water is firstly cooled to 90 ℃, and then enters a gas-water expander to be subjected to flash evaporation expansion to normal pressure, and CO dissolved in the gas water is subjected to flash evaporation expansion to be normal pressure2、NH3And flash separation of gas such as part of water vapor. The coal gas water after flash evaporation enters a tar separator at the lower part to separate the coal gas water from tar by using density difference, and dust-containing tar with the density higher than that of the water is discharged from the bottom and can be used as a product and also can return to a gasification furnace for gasification again; light less dense than waterOil and gas water overflow from the upper part of the tar separator and enter a gas water buffer tank, part of the gas water is pumped back to gasification for recycling by a high-pressure pump, and the redundant gas water enters a light oil separator. The device is characterized in that a coke and TPI plate assembly is arranged in a light oil separator, impurities are filtered, oil drops float on the water surface after being condensed to form an oil layer, light oil is led out through an upper overflow weir and is sent into an oil storage tank, water at the lower part passes through the TPI plate and then enters a water chamber, is led out through the overflow weir, is sent into a double-medium filter through a buffer tank by a pump to be further dedusted and then is sent to a phenol and ammonia recovery device, the aim is to separate dust, oil and dissolved gas in coal gas water, most of water is recycled, and a small part of water is subjected to water quality biochemical treatment which meets biochemical requirements after further deoiling, ammonia distillation and dephenolization.
However, with the development of the coal gas technology, the development gradually proceeds to the direction of large-scale, energy-saving, environmental protection, high efficiency and stability, and the coal gas water separation and recovery process of the conventional crushed coal pressure gasification technology cannot meet the modern requirements, and mainly appears as follows:
1. the existing gas water treatment system collects different types of gas water from different devices to carry out gas-water separation and recovery, and a plurality of separators and buffers are arranged in the device flow, so that the whole gas-water separation and recovery system is large in occupied area, high in investment, high in operation cost, long in flow and multiple in devices, pollutant discharge points are multiple, and serious environmental pollution is easily caused.
2. The existing gas-water separation and recovery system can use a plurality of buffers, separators and the like, and the devices are operated under normal pressure, so that the discharged VOCs (Volatile Organic Compounds), odor and the like can not be collected and then intensively treated, and the field environment is severe.
Disclosure of Invention
In order to solve the technical problem, the utility model provides a separation and recycling system for crushed coal pressurized gasification gas and water.
In order to solve the technical problem, the utility model discloses a technical scheme is:
the utility model provides a garrulous coal pressurization gasification gas water separation and recycling system, its includes middling pressure flash vessel, first vacuum flash vessel, subsider, gas water jar, deacidification tower, first vacuum flash vessel separator, ammonia still, second vacuum flash vessel separator, third vacuum flash vessel separator, flocculating agent jar, pressure filter, filtrate jar, a plurality of water pump and pipeline, wherein: the first water inlet of the medium-pressure flash evaporator is connected with a high-temperature condensate pipeline, the second water inlet of the medium-pressure flash evaporator is connected with a gasified dust-containing gasified water pipeline, the water outlet of the medium-pressure flash evaporator is connected with the first water inlet of the first vacuum flash evaporator through a pipeline, the second water inlet of the first vacuum flash evaporator is connected with a low-pressure gasified gas water pipeline, the third water inlet of the first vacuum flash evaporator is connected with a low-pressure start-up gas water pipeline, the water outlet of the first vacuum flash evaporator is connected with the water inlet of the settling tank through a pipeline and a water pump, the water outlet of the settling tank is connected with the water inlet of a filter press through a pipeline and a water pump, the water outlet of the filter press is connected with the water inlet of a filtrate tank through a pipeline and a water pump, the water inlet of the settling tank is also connected with the discharge port of a flocculant tank through, a gas water outlet of the settling tank is connected with a gas water inlet of a gas water tank through a pipeline, a first gas water outlet of the gas water tank is connected with a gas water recycling device through a pipeline and a water pump, and the settling tank and the top of the gas water tank are hermetically connected with an inert gas pipeline; the gas outlet of the medium-pressure flash evaporator is connected with the gas inlet of a third vacuum flash evaporator through a pipeline, the gas outlet of the first vacuum flash evaporator is connected with the gas inlet of the first vacuum flash evaporator, the water inlet of the second vacuum flash evaporator is connected with a low-temperature condensate conversion pipeline, the water outlet of the second vacuum flash evaporator is connected with the second water inlet of the gas tank through a pipeline and a water pump, the gas outlet of the second vacuum flash evaporator is connected with the gas inlet of the second vacuum flash evaporator through a pipeline, the water outlet of the second vacuum flash evaporator is connected with the second water inlet of the gas tank through a pipeline, and the gas outlet of the first vacuum flash evaporator, the gas outlet of the second vacuum flash evaporator and the gas outlet of the third vacuum flash evaporator are all connected with a waste gas pipeline; the second gas water outlet of the gas water tank is connected with the water inlet of the deacidification tower through a pipeline and a water pump, the water outlet of the deacidification tower is connected with the water inlet of the ammonia still through a pipeline and a water pump, and the water outlet of the ammonia still is connected with the gas water biochemical treatment equipment.
Optionally, the system for separating and recycling crushed coal pressure gasification gas and water further comprises an oil collecting floater and an oil tank, wherein the oil collecting floater is arranged inside the gas water tank, and the bottom of the oil collecting floater is connected with the oil tank through a hose.
Optionally, a cooling water sleeve is arranged outside the breathing gas discharge pipeline at the top of the gas water tank and the settling tank.
The utility model has the advantages that:
1. through will transform high temperature condensate, the gasification dirty gasification water, transform low temperature condensate, the used equipment of whole flow is few with the gas water of several kinds of different classification of gasification start gas water is handled respectively and is realized the separation and the retrieval and utilization of gas water, makes the used equipment of whole flow, not only makes entire system area little, and the investment is low, the running cost is low, and the processing flow is short moreover, equipment is few, makes the pollutant emission point few, is difficult for causing environmental pollution, has energy-concerving and environment-protective, high-efficient stable advantage.
2. Through setting up equipment such as middling pressure flash vessel, vacuum flash separator and ammonia still to set up subsider and gas water tank top and inert gas pipeline sealing connection, make entire system and separation retrieval and utilization process keep being greater than 0.2kPa pressure-fired operation, thereby can guarantee that exhaust VOCs and foul smell can the centralized processing in the system, make site environment friendly.
3. The whole system has simple equipment and safe and stable operation, and can effectively reduce the cost of gas water treatment.
4. Because ammonia content direct influence biochemical system's operating stability, the utility model discloses a send the gas water after deacidifying tower is handled into ammonia still for the gas water to biochemical treatment equipment can be through ammonia still ammonia, thereby can reduce the ammonia content in the gas water to biochemical treatment equipment, has solved because of the different raw materials coal changes the problem that biochemical system is difficult to steady operation.
Practice proves that compared with the current gas-water separation and recycling system, the system investment of the utility model is reduced by 50 percent, and the operating cost is saved by 50 percent.
Drawings
Fig. 1 is a schematic diagram of the system of the present invention.
FIG. 2 is a schematic view of the connection relationship between the present invention and the gasification unit, the scrubbing unit and the shift unit.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and examples.
As shown in fig. 1, the system for separating and recycling crushed coal pressure gasification gas water in this embodiment includes a medium-pressure flash evaporator 1, a first vacuum flash evaporator 2, a settling tank 3, a gas water tank 4, an acid removal tower 5, a first vacuum flash separator 6, an ammonia still 7, a second vacuum flash evaporator 8, a second vacuum flash separator 9, a third vacuum flash separator 10, a flocculant tank 11, a filter press 12, a filtrate tank 13, a plurality of water pumps and pipelines, wherein: the first water inlet of the medium-pressure flash evaporator 1 is connected with a high-temperature condensate pipeline, the second water inlet of the medium-pressure flash evaporator 1 is connected with a gasified dust-containing gasified water pipeline, the water outlet of the medium-pressure flash evaporator 1 is connected with the first water inlet of the first vacuum flash evaporator 2 through a pipeline, the second water inlet of the first vacuum flash evaporator 2 is connected with a low-pressure gasified gas water pipeline, the third water inlet of the first vacuum flash evaporator 2 is connected with a low-pressure start-up gas water pipeline, the water outlet of the first vacuum flash evaporator 2 is connected with the water inlet of the settling tank 3 through a pipeline and a water pump, the water outlet of the settling tank 3 is connected with the water inlet of a filter press 12 through a pipeline and a water pump, the water outlet of the filter press 12 is connected with the water inlet of a filtrate tank 13 through a pipeline and a water pump, the water inlet of the filtrate tank 13 is connected with the first water inlet of a gas tank 4 through a pipeline and a water pump, the water inlet of the settling tank 3 is also connected with the discharge port of a flocculant tank 11 through a pipeline, a gas water outlet of the settling tank 3 is connected with a gas water inlet of a gas water tank 4 through a pipeline, a first gas water outlet of the gas water tank 4 is connected with gas water recycling equipment (coal lock gas washing equipment and start gas washing equipment) through a pipeline and a water pump, and the tops of the settling tank 3 and the gas water tank 4 are hermetically connected with an inert gas pipeline; an air outlet of the medium-pressure flash evaporator 1 is connected with an air inlet of a third vacuum flash evaporator separator 10 through a pipeline, an air outlet of the first vacuum flash evaporator 2 is connected with an air inlet of a first vacuum flash evaporator separator 6, a water inlet of a second vacuum flash evaporator 8 is connected with a low-temperature condensate conversion pipeline, a water outlet of the second vacuum flash evaporator 8 is connected with a second water inlet of the gas tank 4 through a pipeline and a water pump, an air outlet of the second vacuum flash evaporator 8 is connected with an air inlet of a second vacuum flash evaporator 9 through a pipeline, a water outlet of the second vacuum flash evaporator 9 is connected with a second water inlet of the gas tank 4 through a pipeline, and an air outlet of the first vacuum flash evaporator separator 6, an air outlet of the second vacuum flash evaporator 9 and an air outlet of the third vacuum flash evaporator 10 are all connected with a waste gas pipeline; a second gas water outlet of the gas water tank 4 is connected with a water inlet of the deacidification tower 5 through a pipeline and a water pump, a water outlet of the deacidification tower 5 is connected with a water inlet of the ammonia still 7 through a pipeline and a water pump, and a water outlet of the ammonia still 7 is connected with gas water biochemical treatment equipment.
As shown in figure 2, the crushed coal pressure gasification gas-water separation and recycling system provided by the embodiment of the utility model is connected with a gasification unit, a washing unit and a transformation unit in front. Specifically, crushed coal raw materials are added into a crushed coal pressure gasification furnace through a coal adding lock hopper to be subjected to pressure gasification to generate gasified raw gas, the gasified raw gas is dedusted through a cyclone separator and then reaches a waste heat boiler, after heat in the gas is recovered by the waste heat boiler, the gas is continuously subjected to three-stage dedusting through a Venturi washing device and a raw gas washing device and then is sent into a conversion device, a precooler, an intermediate and final cooling device and an ammonia washing tower in a conversion unit. And one part of coal gas in the crushed coal pressure gasification furnace enters coal gas locking washing equipment, and the other part of the coal gas also enters start-up coal gas washing equipment. The crushed coal is any one of anthracite, coke or semicoke. Wherein the precooler produces shift high temperature condensate. The intermediate, final cooling equipment and ammonia scrubber produce shift low temperature condensate. The venturi scrubbing apparatus produces gasified dusty gasified water. The coal lock gas washing equipment generates low-pressure gasified gas water. The start-up gas washing equipment generates low-pressure start-up gas water.
Optionally, the system for separating and recycling crushed coal pressure gasification gas and water further comprises an oil collecting float 14 and an oil tank 15, the oil collecting float 14 is arranged inside the gas water tank 4, the bottom of the oil collecting float 14 is connected with the oil tank 15 through a hose, the height of the oil collecting float 14 can change along with the liquid level inside the gas water tank 4, and light oil floating on the upper portion of the gas water tank 4 can enter the oil collecting float 14 and is collected into the oil tank 15 through the hose, so that the collection of the light oil is realized.
Optionally, a cooling water sleeve 16 is arranged outside the breathing gas discharge pipeline at the top of the gas water tank 4 and the settling tank 3. The cooling water jacket 16 can cool the respiratory air discharged from the respiratory air discharge pipeline at the top of the gas water tank 4 and the settling tank 3, so that the condensed easily condensed odor flows back to the equipment, thereby avoiding the discharge of VOCs or odor from the gas water tank 4 and the settling tank 3.
Garrulous coal pressure gasification gas water separation and recycling system, can realize garrulous coal pressure gasification gas water separation and retrieval and utilization through following step:
and S1, degassing the transformed high-temperature condensate and the gasified dust-containing gasified water through the medium-pressure flash evaporator 1, feeding the degassed high-temperature condensate and the gasified dust-containing gasified water, together with the gasified low-pressure coal gas water and the gasified starting coal gas water into the first vacuum flash evaporator 2, and deeply removing dissolved gas in the first vacuum flash evaporator 2.
Optionally, the flash evaporation temperature of the medium-pressure flash evaporator 1 is 140-160 ℃, and the pressure is 0.4-0.5 MPa. The flash evaporation temperature of the first vacuum flash evaporator 2 is 80-86 ℃, and the vacuum degree is 50-60 kPa.
And S2, mixing the gas water after gas stripping with a flocculating agent from a flocculating agent tank 11, and then sending the mixture into a settling tank 3.
S3, performing pressure filtration and dehydration on the solid material settled at the bottom of the settling tank 3 by using a pressure filter 12 to prepare mud cakes, feeding the filtrate generated by the pressure filtration and dehydration into a filtrate tank 13 and sending the filtrate to a gas water tank 4, and sending the gas water at the upper part of the settling tank 3 into the gas water tank 4.
Optionally, the addition amount of the flocculant is 3-5g of flocculant added into 1 ton of coal gas water.
And S4, converting the low-temperature condensate, removing dissolved gas in the second vacuum flash evaporator 8, and delivering the gas water after removing the dissolved gas into the gas water tank 4.
S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4.
S6, recycling a part of gas water in the gas water tank 4 as washing water of gasified low-pressure gas water for gas water recycling equipment (coal gas locking washing equipment and start-up gas washing equipment), deacidifying the rest gas water in the deacidification tower 5, desulfurizing and recycling the deacidified gas obtained by deacidification in the deacidification tower 5, feeding the gas water deacidified in the deacidification tower 5 into the ammonia still 7 for ammonia distillation, feeding the gas water subjected to ammonia distillation in the ammonia still 7 to gas water biochemical treatment equipment, and recycling ammonia water/liquid ammonia generated in the ammonia still 7.
Wherein the conversion high-temperature condensate is coal gas water with dust content not more than 2000mg/L, temperature of 150-190 ℃ and pressure of 3.0-7.0 MPa; the gasified dust-containing gasified water is coal gas water with dust content not more than 3000mg/L, temperature of 180-200 ℃ and pressure of 3.0-7.0 MPa; the conversion low-temperature condensate is gas water with dust content less than 50mg/L, temperature of 40-80 ℃ and pressure of 3.0-5.0 MPa; the low-pressure gasified gas water is gas water with the dust content of less than 100mg/L, the temperature of 60-80 ℃ and the pressure of 0.5-0.7 MPa; the low-pressure starting gas water is gas water with the dust content of less than 200mg/L, the temperature of 60-80 ℃ and the pressure of 0.5-0.7 MPa.
Optionally, the inert gas is continuously introduced into the top of the settling tank 3 and the top of the gas water tank 4, so that the micro-positive pressure (0.2-0.5kPa) greater than 0.2kPa is always maintained inside the settling tank 3 and the gas water tank 4.
The method provided by the embodiments of the present invention is illustrated by the following examples.
Example 1
The crushed coal in the embodiment is anthracite with water content of 5%, the coal sample is crushed and screened to obtain a coal sample with particle size of 5-50mm, the coal sample is put into a crushed coal pressure gasification furnace for crushed coal pressure gasification, the gasification pressure is 4.0MPa, the gasification temperature is 1250 ℃, crude coal gas generated by gasification is divided into high-temperature coal gas water and low-temperature coal gas water according to the dust content, temperature and pressure in water during washing, the high-temperature coal gas water is divided into high-temperature condensate and gasified dust-containing gasified water according to the dust content, temperature and pressure, and the low-temperature coal gas water is divided into low-temperature condensate, low-pressure gasified coal gas water and low-pressure start coal gas water according to the dust content, temperature and pressure. The gas water of different classifications is separated and recycled respectively, the whole separation and recycling process of the gas water keeps micro-positive pressure operation larger than 0.2kPa and adopts inert gas protection to ensure that VOCs and odor in the system can be treated in a centralized way.
The dust content of the converted high-temperature condensate obtained by processing the coal sample by the gasification unit, the washing unit and the conversion unit is 1900mg/L, the temperature is 150 ℃, the pressure is 4MPa, the dust content of the gasified dust-containing gasified water is 2800mg/L, the temperature is 189 ℃, and the pressure is 4.0 MPa. The dust content of the conversion low-temperature condensate is 45mg/L, the temperature is 67.5 ℃, the pressure is 3.75MPa, the dust content of the low-pressure gasification gas water is 90mg/L, the temperature is 70 ℃, the pressure is 0.5MPa, the dust content of the low-pressure start gas water is 180mg/L, the temperature is 65 ℃, and the pressure is 0.65 MPa.
Wherein, the main pollutant characteristic data of the high-temperature gas water and the low-temperature gas water are respectively shown in the table 1 and the table 2.
TABLE 1
| Item | Unit of | Gasified dust-containing gasified water | Conversion of high temperature condensate |
| Dust content | mg/L | ＜3000 | ＜2000 |
| Oil content | mg/L | ＜5 | ＜0.06 |
| COD | mg/L | ＜800 | ＜2500 |
| Total salt | mg/L | ＜2000 | ＜300 |
TABLE 2
| Item | Unit of | Shift low temperature condensate | Low-pressure gasified gas water | Low pressure gas water for starting |
| Dust content | mg/L | ＜50 | ＜50 | ＜200 |
| Oil content | mg/L | ＜65 | ＜80 | ＜100 |
| COD | mg/L | ＜800 | ＜600 | ＜2500 |
| Total salt | mg/L | ＜10 | ＜500 | ＜700 |
The conversion high-temperature condensate and the gasified dust-containing gasified water are degassed by a medium-pressure flash evaporator 1, enter a first vacuum flash evaporator 2 together with gasified low-pressure coal gas water and gasified starting coal gas water to deeply remove dissolved gas, wherein the flash evaporation temperature of the medium-pressure flash evaporator 1 is 144 ℃, the pressure is 0.4MPa, the flash evaporation temperature of the first vacuum flash evaporator 2 is 84.8 ℃, and the vacuum degree is 50 kPa; adding a flocculating agent into the gas water after gas desolventizing according to the proportion of adding 3g of the flocculating agent into 1 ton of the gas water, mixing, sending the mixture into a settling tank 3, carrying out filter pressing and dehydration on solid materials settled at the bottom of the settling tank 3 by a filter press 12 to prepare mud cakes with the water content of 22%, sending filtrate into a filtrate tank 13, sending the filtrate into a gas water tank 4, and sending the gas water on the upper part of the settling tank 3 into the gas water tank 4. The low-temperature condensate is converted to remove the dissolved gas in the second vacuum flash evaporator 8, and the gas water after removing the dissolved gas is sent to the gas water tank 4. S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4; a part of gas water in the gas water tank 4 is used as washing water of gasified low-pressure gas water to be recycled by gas water recycling equipment, the rest of gas water enters the deacidification tower 5 for deacidification, the deacidification gas obtained by the deacidification tower 5 is used for desulphurization recycling equipment, the gas water after deacidification in the deacidification tower 5 enters the ammonia still 7 for ammonia distillation, the gas water after ammonia distillation in the ammonia still 7 goes to gas water biochemical treatment equipment, and ammonia water/liquid ammonia generated in the ammonia still 7 is recycled.
The operating pressure of the whole gas-water separation and recycling process is micro-positive pressure operation larger than 0.2kPa, inert gas serving as protective gas is continuously introduced into the top of the settling tank 3 and the top of the gas water tank 4, the pressure of the system is ensured to be micro-positive pressure larger than 0.2kPa, and VOCs, odor and the like in the system can be intensively collected to burn or RTO byproduct steam. The effect of continuously introducing inert gas into the settling tank 3 and the gas water tank 4 to seal the tops of the settling tank 3 and the gas water tank 4 is mainly to prevent the settling tank 3 and the gas water tank 4 from generating negative pressure and sucking air from breathing valves of the settling tank 3 and the gas water tank 4 so as to keep micro-positive pressure in the tanks, the normal pressure set value of the sealing valve is preferably 0.2kPa, and the intersection with the set pressure of the breathing valve, a single-breathing valve or a control valve and the like is avoided so as to generate unnecessary inert gas circulation and have high operation cost.
The embodiment of the utility model adopts the pressure gasification of the crushed anthracite coal, which utilizes the characteristics of less oil content, low COD content and low dust content in the coal gas water. In the embodiment, the anthracite is used for pressure gasification, and because the anthracite has low moisture content, the total moisture content is generally below 10%, the volatile matter is less than 10%, the carbon content is high, the melting point of the coal ash is high, and the ash content is high. The true density is generally 1.4-1.8g/cm3High mineral content in anthraciteThe true density reaches 1.8-1.9g/cm3In addition, the anthracite has high thermal stability, is not easy to pulverize when entering the gasification furnace, has small coal dust amount brought out of the gasification furnace and large density difference between coal dust particles and coal gas water, so the coal dust is easier to separate, and the retention time of the dust-containing coal gas water separator can be shortened.
At present, the water quality requirements of biochemical treatment equipment are that COD is less than or equal to 3500mg/L, pH is between 8.0 and 9.0, oil content is less than or equal to 50mg/L, and BOD is not more than 1100 mg/L. The current effluent and reuse indexes of the gas water are shown in a table 3, the oil content of the gas water which is treated by biochemical treatment equipment is high, oxidation treatment is required before the gas water enters the biochemical treatment equipment, and the COD content is reduced.
TABLE 3
After the treatment by the method provided by the embodiment of the utility model, the ammonia content, COD content and the like in the coal gas water going to the biochemical treatment equipment and the coal gas water recycled by the coal gas water are far less than those in the coal gas water obtained by the treatment of the current coal gas water separation and recovery system.
Example 2
The crushed coal in the embodiment is anthracite with 6% of water content, the coal sample is crushed and screened to obtain a coal sample with the particle size of 5-50mm, the coal sample is put into a crushed coal pressure gasification furnace to perform crushed coal pressure gasification, the gasification pressure is 5.0MPa, the gasification temperature is 1250 ℃, crude coal gas generated by gasification is divided into high-temperature coal gas water and low-temperature coal gas water according to the dust content, temperature and pressure in water during washing, the high-temperature coal gas water is divided into high-temperature condensate and gasified dust-containing gasified water according to the dust content, temperature and pressure, and the low-temperature coal gas water is divided into low-temperature condensate, low-pressure gasified coal gas water and low-pressure start coal gas water according to the dust content, temperature and pressure. The gas water of different classifications is separated respectively and is retrieved, and the pressure-fired operation that the separation retrieval and utilization process of whole gas water keeps being greater than 0.2kPa adopts inert gas protection, guarantees that VOCs and foul smell can centralized processing in the system.
The dust content of the transformed high-temperature condensate obtained by processing the coal sample through the gasification unit, the washing unit and the transformation unit is 1800mg/L, the temperature is 158 ℃ and the pressure is 5MPa, and the dust content of the gasified dust-containing gasified water is 1985mg/L, the temperature is 196 ℃ and the pressure is 5.0 MPa. The dust content of the conversion low-temperature condensate is 48mg/L, the temperature is 70.5 ℃, the pressure is 4.75MPa, the dust content of the low-pressure gasification gas water is 98mg/L, the temperature is 72 ℃, the pressure is 0.6MPa, the dust content of the low-pressure start gas water is 180mg/L, the temperature is 75 ℃, and the pressure is 0.55 MPa.
The conversion high-temperature condensate and the gasified dust-containing gasified water are degassed by a medium-pressure flash evaporator 1, and enter a first vacuum flash evaporator 2 together with gasified low-pressure coal gas water and gasified starting coal gas water to deeply remove dissolved gas, wherein the flash evaporation temperature of the medium-pressure flash evaporator 1 is 148 ℃, the pressure is 0.5MPa, the flash evaporation temperature of the first vacuum flash evaporator 2 is 86 ℃, and the vacuum degree is 60 kPa; adding a flocculating agent into the gas water after gas desolventizing according to the proportion of adding 4.5g flocculating agent into 1 ton of gas water, mixing, sending into a settling tank 3, carrying out filter pressing and dehydration on solid materials settled at the bottom of the settling tank 3 by a filter press 12 to prepare mud cakes with the water content of 28%, sending filtrate into a filtrate tank 13 and then into a gas water tank 4, and sending the gas water on the upper part of the settling tank 3 into the gas water tank 4. The low-temperature condensate is converted to remove the dissolved gas in the second vacuum flash evaporator 8, and the gas water after removing the dissolved gas is sent to the gas water tank 4. S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4; a part of gas water in the gas water tank 4 is used as washing water of gasified low-pressure gas water to be recycled by gas water recycling equipment, the rest of gas water enters the deacidification tower 5 for deacidification, the deacidification gas obtained by the deacidification tower 5 is used for desulphurization recycling equipment, the gas water after deacidification in the deacidification tower 5 enters the ammonia still 7 for ammonia distillation, the gas water after ammonia distillation in the ammonia still 7 goes to gas water biochemical treatment equipment, and ammonia water/liquid ammonia generated in the ammonia still 7 is recycled.
The operating pressure of whole gas-water separation retrieval and utilization process is greater than the pressure-fired operation of 0.2kPa, and setting up inert gas as the protective gas is lastingly let in at settling tank 3 and 4 tops of gas water tank, guarantees that system's pressure is greater than the pressure-fired operation of 0.2kPa, and VOCs and foul smell etc. can concentrate in the system and collect and burn or RTO byproduct steam. The effect of continuously introducing inert gas into the settling tank 3 and the gas water tank 4 to seal the tops of the settling tank 3 and the gas water tank 4 is mainly to prevent the settling tank 3 and the gas water tank 4 from generating negative pressure and sucking air from breathing valves of the settling tank 3 and the gas water tank 4 so as to keep micro-positive pressure in the tanks, the normal pressure set value of the sealing valve is preferably 0.2kPa, and the unnecessary inert gas circulation and high operation cost are generated due to the fact that the normal pressure set value is intersected with the set pressure of the breathing valve, a single-breathing valve or a control valve and the like.
Example 3
The crushed coal in the embodiment is Yangquan anthracite with water content of 8%, the coal sample is crushed and screened to obtain a coal sample with particle size of 5-50mm, the coal sample is placed in a crushed coal pressure gasification furnace to be subjected to crushed coal pressure gasification, the gasification pressure is 7.0MPa, the gasification temperature is 1350 ℃, crude gas generated by gasification is divided into high-temperature gas water and low-temperature gas water according to the dust content, temperature and pressure in water during washing, the high-temperature gas water is divided into conversion high-temperature condensate and gasification dust-containing gasification water according to the dust content, temperature and pressure, and the low-temperature gas water is divided into conversion low-temperature condensate, low-pressure gasification gas water and low-pressure start gas water according to the dust content, temperature and pressure. The gas water of different classifications is separated respectively and is retrieved, and the pressure-fired operation that the separation retrieval and utilization process of whole gas water keeps being greater than 0.2kPa adopts inert gas protection, guarantees that VOCs and foul smell can centralized processing in the system.
The dust content of the converted high-temperature condensate obtained by processing the coal sample through the gasification unit, the washing unit and the conversion unit is 1785mg/L, the temperature is 170 ℃, the pressure is 7MPa, the dust content of the gasified dust-containing gasified water is 1650mg/L, the temperature is 197 ℃, and the pressure is 7.0 MPa. The dust content of the conversion low-temperature condensate is 35mg/L, the temperature is 67.5 ℃, the pressure is 3.75MP, the dust content of the low-pressure gasification gas water is 65mg/L, the temperature is 70 ℃, the pressure is 0.5MPa, the dust content of the low-pressure start gas water is 150mg/L, the temperature is 60 ℃, and the pressure is 0.5 MPa.
The conversion high-temperature condensate and the gasified dust-containing gasified water are degassed by a medium-pressure flash evaporator 1, and enter a first vacuum flash evaporator 2 together with gasified low-pressure coal gas water and gasified starting coal gas water to deeply remove dissolved gas, wherein the flash evaporation temperature of the medium-pressure flash evaporator 1 is 144 ℃, the pressure is 0.4MPa, the flash evaporation temperature of the first vacuum flash evaporator 2 is 84.8 ℃, and the vacuum degree is 50 kPa; adding a flocculating agent into the gas water after gas desolventization according to the proportion of adding 4.8g flocculating agent into 1 ton of gas water, mixing, sending into a settling tank 3, carrying out filter pressing and dehydration on solid materials settled at the bottom of the settling tank 3 by a filter press 12 to prepare mud cakes with the water content of 28%, sending filtrate into a filtrate tank 13 and then into a gas water tank 4, and sending the gas water on the upper part of the settling tank 3 into the gas water tank 4. The low-temperature condensate is converted to remove the dissolved gas in the second vacuum flash evaporator 8, and the gas water after removing the dissolved gas is sent to the gas water tank 4. S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4; a part of gas water in the gas water tank 4 is used as washing water of gasified low-pressure gas water to be recycled by gas water recycling equipment, the rest of gas water enters the deacidification tower 5 for deacidification, the deacidification gas obtained by the deacidification tower 5 is used for desulphurization recycling equipment, the gas water after deacidification in the deacidification tower 5 enters the ammonia still 7 for ammonia distillation, the gas water after ammonia distillation in the ammonia still 7 goes to gas water biochemical treatment equipment, and ammonia water/liquid ammonia generated in the ammonia still 7 is recycled.
The operating pressure of whole gas-water separation retrieval and utilization process is greater than the pressure-fired operation of 0.2kPa, and setting up inert gas as the protective gas is lastingly let in at settling tank 3 and 4 tops of gas water tank, guarantees that system's pressure is greater than the pressure-fired operation of 0.2kPa, and VOCs and foul smell etc. can concentrate in the system and collect and burn or RTO byproduct steam. The function of continuously introducing inert gas into the settling tank 3 and the gas water tank 4 to seal the tops of the settling tank 3 and the gas water tank 4 is to prevent the settling tank 3 and the gas water tank 4 from generating negative pressure and sucking air from breathing valves of the settling tank 3 and the gas water tank 4 so as to keep micro-positive pressure in the tanks, the normal pressure set value of the sealing valve is preferably 0.2kPa, and the intersection with the set pressure of the breathing valve, a single breathing valve or a control valve and the like is avoided, so that unnecessary inert gas circulation is generated, and the operation cost is high.
Example 4
The crushed coal in the embodiment is semicoke containing 8% of water, the coal sample is crushed and screened to obtain a coal sample with the particle size of 5-50mm, the coal sample is put into a crushed coal pressure gasification furnace for crushed coal pressure gasification, the gasification pressure is 3MPa, the gasification temperature is 1250 ℃, crude gas generated by gasification is divided into high-temperature coal gas water and low-temperature coal gas water according to the dust content, temperature and pressure in water during washing, the high-temperature coal gas water is divided into conversion high-temperature condensate and gasification dust-containing gasification water according to the dust content, temperature and pressure, and the low-temperature coal gas water is divided into conversion low-temperature condensate, low-pressure gasification coal gas water and low-pressure start coal gas water according to the dust content, temperature and pressure. The gas water of different classifications is separated respectively and is retrieved, and the pressure-fired operation that the separation retrieval and utilization process of whole gas water keeps being greater than 0.2kPa adopts inert gas protection, guarantees that VOCs and foul smell can centralized processing in the system.
The dust content of the converted high-temperature condensate obtained by processing the coal sample through the gasification unit, the washing unit and the conversion unit is 980mg/L, the temperature is 155 ℃, the pressure is 3MPa, the dust content of the gasified dust-containing gasified water is 1250mg/L, the temperature is 185 ℃, and the pressure is 3.0 MPa. The dust content of the conversion low-temperature condensate is 30mg/L, the temperature is 66 ℃, the pressure is 3MPa, the dust content of the low-pressure gasification gas water is 65mg/L, the temperature is 75 ℃, the pressure is 0.5MPa, the dust content of the low-pressure start gas water is 120mg/L, the temperature is 60 ℃, and the pressure is 0.5 MPa.
The conversion high-temperature condensate and the gasified dust-containing gasified water are degassed by a medium-pressure flash evaporator 1, and enter a first vacuum flash evaporator 2 together with gasified low-pressure coal gas water and gasified starting coal gas water to deeply remove dissolved gas, wherein the flash evaporation temperature of the medium-pressure flash evaporator 1 is 142 ℃, the pressure is 0.4MPa, the flash evaporation temperature of the first vacuum flash evaporator 2 is 82 ℃, and the vacuum degree is 50 kPa; adding a flocculating agent into the gas water after gas desolventizing according to the proportion of adding 3g of the flocculating agent into 1 ton of the gas water, mixing, sending the mixture into a settling tank 3, carrying out filter pressing and dehydration on solid materials settled at the bottom of the settling tank 3 by a filter press 12 to prepare mud cakes with the water content of 23%, sending filtrate into a filtrate tank 13, sending the filtrate into a gas water tank 4, and sending the gas water on the upper part of the settling tank 3 into the gas water tank 4. The low-temperature condensate is converted to remove the dissolved gas in the second vacuum flash evaporator 8, and the gas water after removing the dissolved gas is sent to the gas water tank 4. S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4; a part of gas water in the gas water tank 4 is used as washing water of gasified low-pressure gas water to be recycled by gas water recycling equipment, the rest of gas water enters the deacidification tower 5 for deacidification, the deacidification gas obtained by the deacidification tower 5 is used for desulphurization recycling equipment, the gas water after deacidification in the deacidification tower 5 enters the ammonia still 7 for ammonia distillation, the gas water after ammonia distillation in the ammonia still 7 goes to gas water biochemical treatment equipment, and ammonia water/liquid ammonia generated in the ammonia still 7 is recycled.
The operating pressure of whole gas-water separation retrieval and utilization process is greater than the pressure-fired operation of 0.2kPa, and setting up inert gas as the protective gas is lastingly let in at settling tank 3 and 4 tops of gas water tank, guarantees that system's pressure is greater than the pressure-fired operation of 0.2kPa, and VOCs and foul smell etc. can concentrate in the system and collect and burn or RTO byproduct steam. The function of continuously introducing inert gas into the settling tank 3 and the gas water tank 4 to seal the tops of the settling tank 3 and the gas water tank 4 is to prevent the settling tank 3 and the gas water tank 4 from generating negative pressure and sucking air from breathing valves of the settling tank 3 and the gas water tank 4 so as to keep micro-positive pressure in the tanks, and the normal pressure of the sealing valve is set to be 0.4kPa, and the intersection with the set pressure of the breathing valve, a single-breathing valve or a control valve and the like is avoided, so that unnecessary inert gas circulation is generated, and the operation cost is high.
Example 5
The crushed coal in the embodiment is coke with 5% of water content, the coal sample is crushed and screened to obtain a coal sample with the particle size of 5-50mm, the coal sample is put into a crushed coal pressure gasification furnace for crushed coal pressure gasification, the gasification pressure is 3MPa, the gasification temperature is 1250 ℃, crude gas generated by gasification is divided into high-temperature coal gas water and low-temperature coal gas water according to the dust content, temperature and pressure in water during washing, the high-temperature coal gas water is divided into conversion high-temperature condensate and gasification dust-containing gasification water according to the dust content, temperature and pressure, and the low-temperature coal gas water is divided into conversion low-temperature condensate, low-pressure gasification coal gas water and low-pressure start coal gas water according to the dust content, temperature and pressure. The gas water of different classifications is separated respectively and is retrieved, and the pressure-fired operation that the separation retrieval and utilization process of whole gas water keeps being greater than 0.2kPa adopts inert gas protection, guarantees that VOCs and foul smell can centralized processing in the system.
The dust content of the converted high-temperature condensate obtained by processing the coal sample through the gasification unit, the washing unit and the conversion unit is 1200mg/L, the temperature is 165 ℃ and the pressure is 3MPa, and the dust content of the gasified dust-containing gasified water is 1800mg/L, the temperature is 185 ℃ and the pressure is 3.0 MPa. The dust content of the conversion low-temperature condensate is 46mg/L, the temperature is 66 ℃, the pressure is 3.0MPa, the dust content of the low-pressure gasification gas water is 84mg/L, the temperature is 75 ℃, the pressure is 0.5MPa, the dust content of the low-pressure start gas water is 150mg/L, the temperature is 78 ℃, and the pressure is 0.7 MPa.
The conversion high-temperature condensate and the gasified dust-containing gasified water are degassed by a medium-pressure flash evaporator 1, and enter a first vacuum flash evaporator 2 together with gasified low-pressure coal gas water and gasified starting coal gas water to deeply remove dissolved gas, wherein the flash evaporation temperature of the medium-pressure flash evaporator 1 is 142 ℃, the pressure is 0.4MPa, the flash evaporation temperature of the first vacuum flash evaporator 2 is 82 ℃, and the vacuum degree is 50 kPa; adding a flocculating agent into the gas water after gas desolventizing according to the proportion of adding 3g of the flocculating agent into 1 ton of the gas water, mixing, sending the mixture into a settling tank 3, carrying out filter pressing and dehydration on solid materials settled at the bottom of the settling tank 3 by a filter press 12 to prepare mud cakes with the water content of 22%, sending filtrate into a filtrate tank 13, sending the filtrate into a gas water tank 4, and sending the gas water on the upper part of the settling tank 3 into the gas water tank 4. The low-temperature condensate is converted to remove the dissolved gas in the second vacuum flash evaporator 8, and the gas water after removing the dissolved gas is sent to the gas water tank 4. S5, feeding the condensate formed by flash evaporation in the first vacuum flash evaporator 2 and the second vacuum flash evaporator 8 into the first vacuum flash evaporator separator 6 and the second vacuum flash evaporator separator 9 respectively for vacuum flash evaporation separation, feeding the flash evaporation gas flashed by the medium-pressure flash evaporator 1 into the third vacuum flash evaporator separator 10 for vacuum flash evaporation separation, and feeding the condensate condensed by the first vacuum flash evaporator separator 6, the second vacuum flash evaporator separator 9 and the third vacuum flash evaporator separator 10 into the gas water tank 4; a part of gas water in the gas water tank 4 is used as washing water of gasified low-pressure gas water to be recycled by gas water recycling equipment, the rest of gas water enters the deacidification tower 5 for deacidification, the deacidification gas obtained by the deacidification tower 5 is used for desulphurization recycling equipment, the gas water after deacidification in the deacidification tower 5 enters the ammonia still 7 for ammonia distillation, the gas water after ammonia distillation in the ammonia still 7 goes to gas water biochemical treatment equipment, and ammonia water/liquid ammonia generated in the ammonia still 7 is recycled.
The operating pressure of whole gas-water separation retrieval and utilization process is greater than the pressure-fired operation of 0.2kPa, and setting up inert gas as the protective gas is lastingly let in at settling tank 3 and 4 tops of gas water tank, guarantees that system's pressure is greater than the pressure-fired operation of 0.2kPa, and VOCs and foul smell etc. can concentrate in the system and collect and burn or RTO byproduct steam. The function of continuously introducing inert gas into the settling tank 3 and the gas water tank 4 to seal the tops of the settling tank 3 and the gas water tank 4 is to prevent the settling tank 3 and the gas water tank 4 from generating negative pressure and sucking air from breathing valves of the settling tank 3 and the gas water tank 4 so as to keep micro-positive pressure in the tanks, the normal pressure of the sealing valve is set to be 0.5kPa, and the intersection with the set pressure of the breathing valve, a single breathing valve or a control valve and the like is avoided, so that unnecessary inert gas circulation is generated, and the operation cost is high
It is to be understood that the above embodiments are merely exemplary embodiments that have been employed to illustrate the principles of the present invention, and that the present invention is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.
Claims (3)
1. The utility model provides a separation of crushed coal pressurization gasification gas water and recycling system, its characterized in that, including middling pressure flash vessel (1), first vacuum flash vessel (2), subsider (3), gas water pitcher (4), deacidification tower (5), first vacuum flash vessel separator (6), ammonia still (7), second vacuum flash vessel separator (8), second vacuum flash vessel separator (9), third vacuum flash vessel separator (10), flocculating agent jar (11), pressure filter (12), filtrating jar (13), a plurality of water pumps and pipeline, wherein:
a first water inlet of the medium-pressure flash evaporator (1) is connected with a high-temperature condensate pipeline, a second water inlet of the medium-pressure flash evaporator (1) is connected with a gasified dust-containing gasified water pipeline, a water outlet of the medium-pressure flash evaporator (1) is connected with a first water inlet of the first vacuum flash evaporator (2) through a pipeline, a second water inlet of the first vacuum flash evaporator (2) is connected with a low-pressure gasified gas water pipeline, a third water inlet of the first vacuum flash evaporator (2) is connected with a low-pressure start gas water pipeline, a water outlet of the first vacuum flash evaporator (2) is connected with a water inlet of the settling tank (3) through a pipeline and a water pump, a water outlet of the settling tank (3) is connected with a water inlet of a filter press (12) through a pipeline and a water pump, a water outlet of the filter press (12) is connected with a water inlet of the filtrate tank (13) through a pipeline and a water pump, a water outlet of the filtrate tank (13) is connected with a first water inlet of the water tank (4) through a pipeline and a water pump, the water inlet of the settling tank (3) is also connected with the discharge hole of the flocculating agent tank (11) through a pipeline, the gas water outlet of the settling tank (3) is connected with the gas water inlet of the gas water tank (4) through a pipeline, the first gas water outlet of the gas water tank (4) is connected with a gas water recycling device through a pipeline and a water pump, and the tops of the settling tank (3) and the gas water tank (4) are hermetically connected with an inert gas pipeline; the gas outlet of the medium-pressure flash evaporator (1) is connected with the gas inlet of the third vacuum flash evaporator separator (10) through a pipeline, the gas outlet of the first vacuum flash evaporator (2) is connected with the gas inlet of the first vacuum flash evaporator (6), the water inlet of the second vacuum flash evaporator (8) is connected with a transformation low-temperature condensate pipeline, the water outlet of the second vacuum flash evaporator (8) is connected with the second water inlet of the gas tank (4) through a pipeline and a water pump, the gas outlet of the second vacuum flash evaporator (8) is connected with the gas inlet of the second vacuum flash evaporator (9) through a pipeline, the water outlet of the second vacuum flash evaporator (9) is connected with the second water inlet of the gas tank (4) through a pipeline, the gas outlet of the first vacuum flash separator (6), the gas outlet of the second vacuum flash separator (9) and the gas outlet of the third vacuum flash separator (10) are all connected with a waste gas pipeline; a second gas water outlet of the gas water tank (4) is connected with a water inlet of the deacidification tower (5) through a pipeline and a water pump, a water outlet of the deacidification tower (5) is connected with a water inlet of the ammonia still (7) through a pipeline and a water pump, and a water outlet of the ammonia still (7) is connected with gas water biochemical treatment equipment.
2. The system for separating and recycling crushed coal pressure gasification gas water according to claim 1, further comprising an oil collecting float (14) and an oil tank (15), wherein the oil collecting float (14) is arranged inside the gas water tank (4), and the bottom of the oil collecting float (14) is connected with the oil tank (15) through a hose.
3. The system for separating and recycling crushed coal pressure gasification gas and water according to claim 1 or 2, wherein cooling water sleeves (16) are arranged outside the breathing gas discharge pipelines at the tops of the gas water tank (4) and the settling tank (3).
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| CN112299664B (en) * | 2020-11-19 | 2024-04-05 | 赛鼎工程有限公司 | System and method for separating and recycling crushed coal pressurized gasification gas water |
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