CN212833440U - Tin bath device for molding high borosilicate 4.0 glass - Google Patents

Tin bath device for molding high borosilicate 4.0 glass Download PDF

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Publication number
CN212833440U
CN212833440U CN202021613241.0U CN202021613241U CN212833440U CN 212833440 U CN212833440 U CN 212833440U CN 202021613241 U CN202021613241 U CN 202021613241U CN 212833440 U CN212833440 U CN 212833440U
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tin bath
glass
bath body
borosilicate
molten
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CN202021613241.0U
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宋文凯
曹彦科
张红涛
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Hebei Fujing Technology Co ltd
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Hebei Fujiang Special Glass New Material Technology Co ltd
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Abstract

The utility model belongs to the technical field of glass production, and discloses a molten tin bath device for molding high borosilicate 4.0 glass, which comprises a molten tin bath body, wherein a plurality of baffle ridges are fixedly arranged at the bottom of the molten tin bath body, and a plurality of partition walls are hung at the top of the molten tin bath body; the baffle ridge and the partition wall are vertically corresponding and spaced at a certain distance, and the internal space of the tin bath body is divided into a plurality of temperature areas; a plurality of groups of heating assemblies are detachably arranged at the top end and the bottom end of the tin bath body; the utility model discloses a tin bath, including the tin bath body, the interior temperature zone of tin bath body all sets firmly the exhaust emission pipe of outer odd test, still is equipped with the gas row entry that is used for carrying protective gas to the tin bath inner space on the tin bath body. The utility model discloses can satisfy the fashioned demand of borosilicate 4.0 glass high temperature, reduce the influence of boron volatilization factor to glass shaping quality to produce even, stable and the high borosilicate 4.0 glass of roughness. The utility model discloses use when production borosilicate 4.0 glass for the high temperature shaping of glass liquid.

Description

Tin bath device for molding high borosilicate 4.0 glass
Technical Field
The utility model belongs to the technical field of the glass production, a be used for fashioned molten tin bath of glass, specifically speaking are a be used for fashioned molten tin bath device of borosilicate 4.0 glass.
Background
Borosilicate 4.0 glass has the characteristics of low expansion, high temperature resistance, corrosion resistance, high mechanical strength and light weight, and has extremely wide application. The borosilicate 4.0 glass has excellent thermal shock resistance, high softening point temperature, can generate enough preheating stress, and has the density lower than that of the traditional soda-lime glass by more than 8 percent, so the borosilicate 4.0 glass is also an ideal material for replacing the traditional float glass in the field of building fire prevention.
Borosilicate 4.0 flat glass was introduced by Schott, Germany in the early 90 s, and the technology of oxy-fuel combustion, electric-boosting melting and micro-floating molding was adopted. The Chinese dazzling glass group performs trial production of borosilicate 4.0 glass in 2009, but cannot be put on the market; the Shanghai Yao Pi group perennial specialty glass company has also developed borosilicate 4.0 plate glass in 2015, but it has not succeeded. Borosilicate 4.0 glass is so difficult to produce due to three major causes, including high melt forming temperatures, boron volatilization, and liquid glass delamination. The method comprises the following specific steps:
firstly, the melting temperature of common float glass is 1460 ℃, the melting temperature of borosilicate 4.0 glass reaches more than 1680 ℃, and the forming temperature of the borosilicate 4.0 glass is higher than 240 ℃ of the common float glass. The existing tin bath for forming borosilicate glass is generally small, the input flow of glass liquid is small, and the brought heat is small, so that the temperature of the glass liquid is rapidly reduced after the glass liquid enters the tin bath, and the requirement of high-temperature forming of the borosilicate 4.0 glass is difficult to meet.
Secondly, boron is a small atomic substance, has strong activity and is easy to volatilize at high temperature, so that boron volatilization is very easy to occur in the borosilicate 4.0 glass liquid in the tin bath during the high-temperature forming process to cause glass liquid layering, namely Al in the lower glass liquid2O3High content of B2O3The content is low, so that the stability and uniformity of the finished glass are reduced. And the boron oxide is in a viscous liquid state at 600 ℃, and when the borosilicate 4.0 glass liquid is formed at high temperature, if the volatilized boron oxide is re-condensed into a solid, the quality of finished glass can be seriously influenced.
If the conveying channel with the existing structure is adopted to convey and cool the borosilicate 4.0 glass liquid, the surface layer of the glass liquid is easy to generate temperature difference with the center, so that the flow rate of the glass liquid is uneven (namely, the temperature of the central area is high, and the flow rate of the glass liquid is high), and the produced borosilicate 4.0 glass cannot meet the requirement of flatness.
Disclosure of Invention
For solving exist among the prior art more than not enough, the utility model aims at providing a be used for fashioned molten tin bath device of borosilicate 4.0 glass to satisfy the fashioned demand of borosilicate 4.0 glass high temperature, reduce the influence of boron volatilization factor to glass shaping quality, thereby produce even, stable and the high borosilicate 4.0 glass of roughness.
In order to achieve the above object, the utility model adopts the following technical scheme: a molten tin bath device for molding high borosilicate 4.0 glass comprises a molten tin bath body, wherein a plurality of baffle ridges are fixedly arranged at the bottom of the molten tin bath body, and a plurality of partition walls are hung at the top of the molten tin bath body; the baffle ridge and the partition wall are vertically corresponding and spaced at a certain distance, and the internal space of the tin bath body is divided into a plurality of temperature areas; a plurality of groups of heating assemblies are detachably arranged at the top end and the bottom end of the tin bath body; the utility model discloses a tin bath, including the tin bath body, the interior temperature zone of tin bath body all sets firmly the exhaust emission pipe of outer odd test, still is equipped with the gas row entry that is used for carrying protective gas to the tin bath inner space on the tin bath body.
As the utility model discloses a inject, heating element includes that a plurality of even interlude fix the elema on molten tin bath body top and bottom.
As another limitation of the utility model, the utility model also comprises a material conveying channel communicated with the inlet of the tin bath body; the conveying channel is in a fully-sealed state, and a plurality of vertical stirrers are fixedly arranged at the top of the conveying channel.
As a further limitation of the present invention, the vertical agitator includes an agitating shaft vertically fixed inside the conveying material channel and a plurality of groups of agitating blades evenly distributed on the agitating shaft; wherein, the stirring shaft and the stirring blades are made of molybdenum.
As the utility model discloses a further inject again, (mixing) shaft and conveyer say top hookup location department coating has glass powder for guarantee to carry the material to say good leakproofness.
Since the technical scheme is adopted, compared with the prior art, the utility model, the beneficial effect who gains is:
(1) the baffle ridge fixedly arranged at the bottom of the tin bath body can prevent the glass liquid flowing by means of inertia from flowing back, realize temperature division of the glass liquid, and lead the glass liquid to be cooled in the tin bath body in stages, thereby avoiding mutual influence among the glass liquid in each temperature stage; and hang the divider wall at molten tin bath body top and then can cut off the inner space of molten tin bath body for a plurality of little spaces, can effectively prevent thermal loss, avoid getting into the molten tin bath glass liquid temperature suddenly and reduce (from about 1000 ℃ to about 200 ℃), make the molten tin bath can tentatively satisfy borosilicate 4.0 glass high temperature forming's requirement.
(2) The utility model discloses well molten tin bath body top and bottom alternate fixed silicon carbide rod can carry out the heat to the glass liquid in the molten tin bath and supply, and the effective control to each stage temperature of glass liquid can be realized to fender bank and the divider wall that sets up in the cooperation molten tin bath body to make the molten tin bath can satisfy borosilicate 4.0 glass high temperature forming's requirement completely. In addition, the silicon carbide rod is detachably fixed on the tin bath body in an inserting mode, and is easy to detach and replace, so that the normal operation of high-temperature forming of glass liquid is prevented from being influenced due to the damage of the silicon carbide rod.
(3) The utility model can adjust the distribution total amount of the tin bath protective gas (nitrogen) through the gas exhaust port, so that the gas environment in the tin bath is always in a micro-positive pressure state, and the phenomenon of boron volatilization can be reduced to a certain extent; and the waste gas discharge pipe arranged in each temperature area can discharge the volatilized boron oxide in time so as to prevent the boron oxide from being condensed again when the borosilicate 4.0 glass liquid is formed at high temperature and seriously affect the quality of finished glass.
(4) The conveying channel in the utility model is in a fully sealed state, and the vertical stirrer is arranged in the conveying channel, so that the temperature difference between the surface layer and the center of the glass liquid in the conveying process can be avoided, the uniform flow velocity of the glass liquid is ensured, and the generation of bubbles is reduced, thereby ensuring that the produced glass has better flatness; and the arrangement of the vertical stirrer can also prevent the phenomenon of glass liquid delamination caused by boron volatilization.
(5) The utility model discloses (mixing) shaft and stirring vane among the vertical agitator are the molybdenum material to the molybdenum material replaces platinum and platinum alloy, has not only improved vertical agitator's high temperature resistance ability, and has still reduced vertical agitator's manufacturing cost to a certain extent, has improved economic benefits.
(6) The utility model is coated with glass powder at the connecting position of the stirring shaft and the top end of the material conveying channel, which can ensure the good sealing property of the material conveying channel under the ultra-high temperature state, and the material conveying channel in the totally closed state can properly reduce the volatilization of boron in the glass liquid; on the other hand, the stirring shaft and the stirring blades made of molybdenum can be prevented from being oxidized (molybdenum is more active and is easy to be oxidized), so that the service life of the vertical stirrer is prolonged.
To sum up, the utility model discloses compact structure, relevance are strong, and the work of cooperating each other can satisfy the fashioned requirement of borosilicate 4.0 glass liquid high temperature to the influence of limit reduction boron volatilization to the finished product glass quality to produce stable, even and the high borosilicate 4.0 glass of roughness, realized the quantitative production to borosilicate 4.0 glass.
The utility model discloses use when production borosilicate 4.0 glass for the high temperature shaping of glass liquid.
Drawings
The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments.
FIG. 1 is a schematic structural view of a tin bath according to an embodiment of the present invention;
FIG. 2 is a schematic structural view of a conveying channel according to an embodiment of the present invention;
in the figure: 1. a tin bath body; 2. blocking the ridge; 3. a dividing wall; 4. a silicon carbide rod; 5. a gas exhaust port; 6. an exhaust gas discharge pipe; 7. a stirring shaft; 8. a stirring blade.
Detailed Description
The preferred embodiments of the present invention will be described below with reference to the accompanying drawings. It is to be understood that the preferred embodiments described herein are for purposes of illustration and understanding only and are not intended to limit the invention.
Embodiment is used for fashioned molten tin bath device of borosilicate 4.0 glass
As shown in fig. 1 to 2, the present embodiment includes a material conveying channel and a tin bath body 1 which are communicated with each other, wherein an inner space of the tin bath body 1 is divided into a plurality of temperature regions by a baffle 2 and a partition wall 3, and the tin bath body 1 is further provided with a plurality of groups of heating assemblies. This device can avoid getting into the glass liquid temperature shock dip in the molten tin bath to can carry out effective control to the temperature of molten glass in the molten tin bath, thereby reach the fashioned requirement of borosilicate 4.0 glass high temperature, realize the quantitative production to borosilicate 4.0 glass.
A tin bath body 1
In the production process of float glass, a tin bath is used for molding molten glass: the molten glass continuously flows out of the tank furnace and floats on the surface of the molten tin with higher relative density, and the molten glass is spread and flattened on the surface of the molten tin under the action of gravity and surface tension to form glass with flat upper and lower surfaces. It should be noted that the tin bath body 1 according to the present embodiment is an improvement on the original structure, and the basic structure thereof is the same as that of the tin bath in the prior art, so only the structure of the improved portion will be described.
As shown in fig. 1, a plurality of baffles 2 are fixedly arranged at the bottom of a tin bath body 1, a plurality of partition walls 3 are hung at the top of the tin bath body, the baffles 2 and the partition walls 3 correspond to each other up and down and are spaced at a certain distance, when the internal space of the tin bath body 1 is divided into a plurality of temperature areas, glass liquid can flow through gaps between the baffles 2 and the partition walls 3, and therefore sudden temperature drop after the glass liquid enters the tin bath body 1 is prevented, and the situation that the glass liquid cannot meet the high-temperature forming requirement is avoided. In this embodiment, four baffle ridges 2 and four partition walls 3 are provided, and the inner space of the tin bath body 1 is divided into three temperature regions: a high temperature region, a medium temperature region, and a low temperature region.
The equal detachable in top and the bottom of molten tin bath body 1 is equipped with multiunit heating element, and heating element includes that a plurality of interlude fix the silicon carbide rod 4 in 1 top of molten tin bath body and bottom. Wherein, a plurality of silicon carbide rods 4 evenly distributed can carry out corresponding heat supply to the glass liquid in the molten tin bath to make the temperature satisfy glass liquid high temperature shaping's needs. The silicon carbide rods 4 in the embodiment are communicated with a power supply through aluminum stranded wires.
Every temperature zone of molten tin bath body 1 all sets firmly the exhaust emission pipe 6 of outer pump type to volatilize to the boron oxide in the air smoothly to the molten tin bath outside, avoid boron oxide recondensation to influence glass's shaping quality. As shown in FIG. 1, the exhaust gas discharge pipe 6 is fixedly arranged at the top of the tin bath body 1, and three exhaust gas discharge pipes 6 of an outward drawing type are correspondingly arranged in each temperature area. The gas inlet 5 that is arranged in carrying protective gas to the tin bath inner space is still offered to one side of tin bath body 1, can adjust protective gas's distribution total amount in the tin bath through gas inlet 5, makes the tin bath inner space be in the pressure-fired state all the time to guarantee the smooth shaping of glass liquid.
Second, conveying material channel
The material conveying channel is used for conveying molten glass into the tin bath, and the molten glass can be properly cooled in the conveying process. In actual construction, the inlet of the conveying material channel is communicated with the outlet of the electric melting furnace, the outlet of the conveying material channel is communicated with the inlet of the tin bath body 1, and the conveying material channel body is in a cylindrical sealing structure, so that the whole conveying material channel can form a so-called full-sealing state. As shown in fig. 2, a plurality of vertical stirrers are fixedly arranged inside the conveying channel, the vertical stirrers are fixedly arranged at the top of the conveying channel and extend downwards, so that the temperature difference between the surface layer and the center of the molten glass in the conveying channel can be avoided, the flow rate of the molten glass is uniform, and the formed glass can have high flatness.
Each vertical stirrer comprises a stirring shaft 7 vertically fixed inside the material conveying channel and a plurality of groups of stirring blades 8 uniformly distributed on the stirring shaft 7. Wherein, (mixing) shaft 7 and stirring vane 8 all adopt the molybdenum material, carry the material way totally enclosed state can avoid the (mixing) shaft 7 and the stirring vane 8 of molybdenum material to be oxidized, make vertical agitator high temperature resistance better, life is longer. In this embodiment, the top junction department is still scribbled with glass powder to (mixing) shaft 7 and conveyer material for improve the sealed effect that the conveyer material was said, further prevent that molybdenum (mixing) shaft 7 and stirring vane 8 are oxidized.
The working process of this embodiment is as follows:
firstly, continuously or periodically discharging molten glass liquid to a conveying material channel from the bottom of an electric melting furnace, wherein the temperature of the glass liquid is gradually reduced in the conveying process, and a vertical stirrer in the conveying material channel is used for stirring the glass liquid all the time, so that the glass liquid is prevented from being layered or generating bubbles; then, after the glass liquid enters the tin bath body 1, the glass liquid gradually flows through each temperature area through a gap between the baffle ridge 2 and the partition wall 3, the heating assembly performs corresponding heat supplement on the glass liquid in each temperature area in the process, and sudden drop of the temperature of the glass liquid is avoided, so that the glass liquid is formed at high temperature inside the tin bath body 1 and above the tin liquid. Of course, in glass liquid high temperature forming process, continuously carry protective gas (nitrogen gas) to tin bath body 1 in through gas row entry 5 to simultaneously through exhaust emission pipe 6 with the waste gas (generally be boron oxide) of production take out from tin bath body 1, make tin bath body 1 be in the pressure-fired state always, guarantee the borosilicate 4.0 glass's of production stability and homogeneity.
It should be noted that the above-mentioned embodiments are only preferred embodiments of the present invention, and the present invention is not limited thereto, and although the present invention has been described in detail with reference to the above-mentioned embodiments, it will be apparent to those skilled in the art that modifications can be made to the technical solutions described in the above-mentioned embodiments, or some technical features can be replaced with equivalents. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (5)

1. The utility model provides a be used for fashioned molten tin bath device of borosilicate 4.0 glass, includes the molten tin bath body, its characterized in that: the bottom of the tin bath body is fixedly provided with a plurality of blocking ridges, and the top of the tin bath body is hung with a plurality of partition walls; the baffle ridge and the partition wall are vertically corresponding and spaced at a certain distance, and the internal space of the tin bath body is divided into a plurality of temperature areas; a plurality of groups of heating assemblies are detachably arranged at the top end and the bottom end of the tin bath body; the utility model discloses a tin bath, including the tin bath body, the interior temperature zone of tin bath body all sets firmly the exhaust emission pipe of outer odd test, still is equipped with the gas row entry that is used for carrying protective gas to the tin bath inner space on the tin bath body.
2. The tin bath device for high borosilicate 4.0 glass forming according to claim 1, wherein: the heating assembly comprises a plurality of silicon-carbon rods which are uniformly inserted and fixed at the top end and the bottom end of the tin bath body.
3. A molten tin bath apparatus for forming high borosilicate 4.0 glass according to claim 1 or 2, wherein: the tin bath device also comprises a material conveying channel communicated with the inlet of the tin bath body; the conveying channel is in a fully-sealed state, and a plurality of vertical stirrers are fixedly arranged at the top of the conveying channel.
4. A molten tin bath apparatus for forming high borosilicate 4.0 glass according to claim 3, wherein: the vertical stirrer comprises a stirring shaft vertically fixed in the conveying channel and a plurality of groups of stirring blades uniformly distributed on the stirring shaft; wherein, the stirring shaft and the stirring blades are made of molybdenum.
5. A tin bath device for molding high borosilicate 4.0 glass according to claim 4, wherein: the glass powder is coated at the connecting position of the stirring shaft and the top end of the material conveying channel, and is used for ensuring the good sealing property of the material conveying channel.
CN202021613241.0U 2020-08-06 2020-08-06 Tin bath device for molding high borosilicate 4.0 glass Active CN212833440U (en)

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CN202021613241.0U CN212833440U (en) 2020-08-06 2020-08-06 Tin bath device for molding high borosilicate 4.0 glass

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Application Number Priority Date Filing Date Title
CN202021613241.0U CN212833440U (en) 2020-08-06 2020-08-06 Tin bath device for molding high borosilicate 4.0 glass

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115180805A (en) * 2022-07-12 2022-10-14 蚌埠中光电科技有限公司 Tin bath top cover of float glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115180805A (en) * 2022-07-12 2022-10-14 蚌埠中光电科技有限公司 Tin bath top cover of float glass

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Address after: No. 2888, Zhenxing Road, Beiwu Community, Wangkuai Town, Economic Development Zone, Xingtai City, Hebei Province, 054001

Patentee after: Hebei Fujing Technology Co.,Ltd.

Address before: No. 2888, Zhenxing Road, Xingtai Economic Development Zone, Hebei Province 054001

Patentee before: HEBEI FUJIANG SPECIAL GLASS NEW MATERIAL TECHNOLOGY CO.,LTD.

CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: No. 2888, Zhenxing Road, Beiwu Community, Wangkuai Town, Economic Development Zone, Xingtai City, Hebei Province, 054001

Patentee after: Hebei Fujing Technology Co.,Ltd.

Country or region after: China

Address before: No. 2888, Zhenxing Road, Beiwu Community, Wangkuai Town, Economic Development Zone, Xingtai City, Hebei Province, 054001

Patentee before: Hebei Fujing Technology Co.,Ltd.

Country or region before: China