CN212800564U - Novel chloride ion-proof electrolytic zinc rod anode - Google Patents
Novel chloride ion-proof electrolytic zinc rod anode Download PDFInfo
- Publication number
- CN212800564U CN212800564U CN202021124898.0U CN202021124898U CN212800564U CN 212800564 U CN212800564 U CN 212800564U CN 202021124898 U CN202021124898 U CN 202021124898U CN 212800564 U CN212800564 U CN 212800564U
- Authority
- CN
- China
- Prior art keywords
- anode
- rod
- lead alloy
- shaped curved
- chloride ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title claims abstract description 20
- 229910000978 Pb alloy Inorganic materials 0.000 claims abstract description 48
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052802 copper Inorganic materials 0.000 claims abstract description 27
- 239000010949 copper Substances 0.000 claims abstract description 27
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 16
- 230000001681 protective effect Effects 0.000 claims abstract description 11
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 11
- 239000011701 zinc Substances 0.000 claims abstract description 11
- 238000005266 casting Methods 0.000 claims description 12
- 239000000956 alloy Substances 0.000 claims description 10
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 238000003466 welding Methods 0.000 claims description 7
- 239000011241 protective layer Substances 0.000 claims description 5
- 230000002265 prevention Effects 0.000 claims 1
- 239000011819 refractory material Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000003792 electrolyte Substances 0.000 abstract description 4
- 239000003779 heat-resistant material Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000005452 bending Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 238000005034 decoration Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000005501 phase interface Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
The utility model provides a novel prevent chlorine ion electrolytic zinc stick form positive pole, include: the lead alloy rod-shaped curved anode is characterized by comprising a lead alloy rod, the lead alloy rod-shaped curved anode is formed by bending a lead alloy rod into a plurality of sections on a plane to form a square, the lead alloy rod-shaped curved anode is connected with a cross beam, a plurality of insulating strips are arranged on the lead alloy rod-shaped curved anode to fix the formed square plane, the insulating strips are cast by PPR heat-resistant materials, and the cross beam comprises: crossbeam main part, vertical connecting pipe, transverse connection stick, copper bar connect, the crossbeam main part includes: t2 copper bar, titanium alloy protective sheath, the bar-shaped curved type positive pole of lead alloy is buckled by a lead alloy and is formed, has both practiced thrift the consumption of raw and other materials, has reduced manufacturing cost, and the positive plate face that forms simultaneously has the space, the concentration phenomenon of electrically conductive and reduction electrolyte that can be better, the structural design of crossbeam has avoided the phenomenon of triphase field by the corruption to take place.
Description
Technical Field
The utility model relates to an electrolytic zinc anode plate and a manufacturing method thereof, which belongs to the technical field of wet metallurgy, in particular to a novel chloride ion-proof electrolytic zinc rod anode.
Background
In the production process of electrolytic metal zinc, the anode plate is a main consumable part and is mainly prepared by mixing silver, lead and the like according to a certain proportion, dissolving, mixing, casting, cold pressing, shearing, stamping and welding. The quality of the anode plate is an important influence factor of the production cost of electrolytic zinc, so that a large number of researches on the alloy formula and the process of the anode plate are carried out at home and abroad, which mainly embody that silver, tin, antimony, calcium, strontium and the like are added into alloy materials, so as to find out the formula and the process of the anode plate, improve the strength, the hardness and the corrosion resistance of the anode plate and prolong the service life of the anode plate. But the problem that the service life of the anode plate is short because the electrolyte level is corroded too fast in the electrolysis process cannot be solved all the time.
A conventional electrolytic zinc metal anode is shown in figure 1 and comprises: lead alloy mainboard 01, crossbeam 02, weld zone 03, copper bar joint 04 have following problem in the high chloride ion ore deposit source electrolysis process, and lead alloy mainboard 01 face weight is big, and manufacturing cost is high, and solution is difficult for flowing and causes concentration polarization in the electrolysis process, and weld zone 03 exposes in air and liquid looks interface department, very easily produces the corruption and breaks.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing a novel prevent chlorine ion electrolysis zinc bar form positive pole, the utility model discloses increased liquid level alloy protective sheath on traditional anode plate, overturned the plate anode who inherits for a century and solved the problem that the anode plate life is too short among the electrolysis process effectively, make the life 6-10 months of traditional anode plate improve to more than 15 months.
The novel chloride ion-proof electrolytic zinc rod anode comprises: the lead alloy rod-shaped curved anode is characterized in that a lead alloy rod is bent into a plurality of sections on a plane to form a square, the lead alloy rod-shaped curved anode is connected with a cross beam, and a plurality of insulating strips are arranged on the lead alloy rod-shaped curved anode to fix the formed square plane.
Furthermore, the insulating strip is formed by casting a PPR heat-resistant material.
Further, the lead alloy rod-shaped curved anode is bent into 16 sections, and the head end and the tail end of the lead alloy rod are bent inwards to form a square.
Furthermore, the lead alloy rod-shaped curved anode is connected with the cross beam in a welding mode.
Further, the cross member includes: crossbeam main part, vertical connecting pipe, transverse connection stick, copper bar connect, the crossbeam main part includes: t2 copper bar, titanium alloy protective sheath, T2 copper bar is wrapped up by the titanium alloy protective sheath, the inside lead alloy casting stick that is of vertical connecting pipe, outside casting cover titanium alloy protective layer, the copper bar articulate circular telegram that one end stretches out on T2 copper bar and the crossbeam main part, vertical connecting pipe sets up crossbeam main part below, transverse connection stick is connected in vertical connecting pipe below, transverse connection stick is the lead alloy stick, the crossbeam links into a whole through welding and casting titanium alloy protective layer, the bar-shaped curved type positive pole of lead alloy is connected with transverse connection stick.
Furthermore, the vertical connecting pipes are round rod-shaped, the diameter of each vertical connecting pipe is 16mm, the number of the vertical connecting pipes is 13, the distance between the vertical connecting pipes is 30-40 mm, and the height of each vertical connecting pipe is 70 mm.
Further, the width of a square plane formed by the lead alloy rod-shaped curved anode is 630mm, the diameter of a lead alloy rod of the lead alloy rod-shaped curved anode is 13mm, and the transverse connecting rod is in a round rod shape and has the diameter of 13 mm.
Further, the total length of the crossbeam is 1000mm, and the overall height is 125mm, T2 copper bar cross-section 40mm 12mm, crossbeam main part cross-sectional dimension is 55mm 22 mm.
Further, the copper bar connector is conical, the size of the front face is 50mm x 45mm, the width of the bottom of the cone is 12mm, and the width of the top of the cone is 6 mm.
The beneficial effects of the utility model are that, the bar-shaped curved type positive pole of lead alloy is buckled by a lead alloy and is formed, has both practiced thrift the consumption of raw and other materials, has reduced manufacturing cost, and the positive plate face that forms simultaneously has the clearance, and the concentration phenomenon of electrically conductive and reduction electrolyte that can be better, being connected between crossbeam and the bar-shaped curved type positive pole of lead alloy realizes through vertical connecting pipe, transverse connection stick, and vertical connecting pipe exposes in air and liquid phase interface department during the electrolysis, but vertical connecting pipe is complete pipe stick, and the outside has covered the titanium alloy protective layer again to the phenomenon of having avoided being corroded takes place.
Drawings
FIG. 1 is a schematic structural diagram of a plate-shaped anode for electrolytic zinc in the prior art;
FIG. 2 is a schematic diagram of the front structure of a novel chloride ion-proof electrolytic zinc rod-shaped anode;
FIG. 3 is a schematic side view of a novel chloride ion-resistant electrolytic zinc rod-shaped anode;
the reference numbers in the figures illustrate: the lead alloy bar-shaped curved anode comprises a lead alloy bar-shaped curved anode 1, a beam 2, a beam main body 21, a T2 copper bar 211, a titanium alloy protective sleeve 212, a vertical connecting pipe 22, a transverse connecting rod 23, a copper bar joint 24 and an insulating strip 3.
Detailed Description
The present invention will be further described with reference to the accompanying drawings so as to facilitate the understanding of the present invention by those skilled in the art.
In the embodiment of the present invention, all the directional indicators (such as upper, lower, left, right, front, and rear … …) are only used to explain the relative position relationship between the components, the motion situation, etc. in a specific posture (as shown in the drawings), and if the specific posture changes, the directional indicator changes accordingly; the technical solution described is to achieve the object of the invention, and the parts not described in detail are implemented by using the prior art.
Example 1: as shown in attached figures 2 and 3, the utility model relates to a novel chloride ion-proof electrolytic zinc rod anode, which comprises: the lead alloy rod-shaped curved anode 1 is characterized in that a lead alloy rod is bent into a plurality of sections on a plane to form a square, the lead alloy rod is bent into 16 sections in the attached drawing 2, the head end and the tail end of the lead alloy rod are bent towards the inside of the formed square, the lead alloy rod-shaped curved anode 1 is connected with a cross beam 2 in a welding mode, and the cross beam 2 comprises: crossbeam main part 21, vertical connecting pipe 22, transverse connection stick 23, copper bar connect 24, crossbeam main part 21 includes: t2 copper bar 211, titanium alloy protective sheath 212, T2 copper bar 211 is wrapped up by titanium alloy protective sheath 212, vertical connecting pipe 22 is inside to be plumbous alloy casting stick, and the outside casting covers the titanium alloy protective sheath, the copper bar joint 24 that one end stretches out on T2 copper bar 211 and the crossbeam main part 21 is connected the circular telegram, vertical connecting pipe 22 sets up crossbeam main part 21 below, transverse connection stick 23 is connected in vertical connecting pipe 22 below, transverse connection stick 23 is plumbous alloy stick, crossbeam 2 links into an entirety through welding and casting titanium alloy protective sheath, plumbous alloy bar-shaped curved type positive pole 1 is connected with transverse connection stick 23, and the connected method is the welding, set up the square plane that fixed formation of a plurality of insulator strips 3 on the bar-shaped curved type positive pole 1 of plumbous alloy, insulator strip 3 adopts the casting of PPR heat-resistant material to form.
Further, the vertical connecting pipe 22 is in a round bar shape, the diameter of the vertical connecting pipe is 16mm, 13 sections are arranged, the distance is about 35mm, the height of the vertical connecting pipe is 70mm, the transverse connecting rod 23 is in a round bar shape, the diameter of the transverse connecting rod is 13mm, the width of a square plane formed by the lead alloy bar-shaped curved anode 1 is 630mm, the total length of the cross beam 2 is 1000mm, the total height of the cross beam is 125mm, the cross section of the T2 copper bar 211 is 40mm 12mm, the cross section size of the cross beam main body 21 is 55mm 22mm, the diameter of the lead alloy bar-shaped curved anode 1 is 13mm, the copper bar joint 24 is in a conical shape, the front size of the copper bar is 50mm 45mm, the width of the bottom of the conical shape is.
The utility model discloses a principle is, the bar-shaped curved type positive pole of lead alloy 1 is buckled by a lead alloy and is formed, has both practiced thrift the consumption of raw and other materials, has reduced manufacturing cost, and the positive plate face that forms simultaneously has the clearance, and the concentration phenomenon of electrically conductive and reduction electrolyte that can be better, being connected between crossbeam 2 and the bar-shaped curved type positive pole of lead alloy 1 realizes through vertical connecting pipe 22, transverse connection stick 23, and vertical connecting pipe 22 exposes in air and liquid phase interface department during the electrolysis, but vertical connecting pipe 22 is complete tube stick, and the outside has covered the titanium alloy protective layer again to the phenomenon of having avoided being corroded takes place.
The above embodiments are only used for illustrating the specific embodiments of the present invention, and are not used for limiting the present invention, and a plurality of improvements and decorations can be made without departing from the principle of the present invention, and these improvements and decorations should be regarded as the protection scope of the present invention.
Claims (10)
1. Novel chloride ion prevention electrolytic zinc rod anode is characterized by comprising: the lead alloy rod-shaped curved anode is characterized in that a lead alloy rod is bent into a plurality of sections on a plane to form a square, the lead alloy rod-shaped curved anode is connected with a cross beam, and a plurality of insulating strips are arranged on the lead alloy rod-shaped curved anode to fix the formed square plane.
2. The new type of chloride ion resistant electrolytic zinc rod anode of claim 1 wherein said insulating strips are cast from PPR refractory material.
3. The novel chloride ion resistant electrolytic zinc rod anode of claim 1, wherein the lead alloy rod-shaped curved anode is bent into 16 sections, and the head end and the tail end of the lead alloy rod are both bent inwards to form a square.
4. The novel chloride ion resistant electrolytic zinc rod anode of claim 1, wherein the lead alloy rod anode is welded to the beam.
5. The novel chloride ion resistant electrolytic zinc rod anode of any one of claims 1 to 4, wherein the beam comprises: crossbeam main part, vertical connecting pipe, transverse connection stick, copper bar connect, the crossbeam main part includes: t2 copper bar, titanium alloy protective sheath, T2 copper bar is wrapped up by the titanium alloy protective sheath, the inside plumbous alloy casting stick that is of vertical connecting pipe, outside casting cover titanium alloy protection, the copper bar articulate circular telegram that one end stretches out on T2 copper bar and the crossbeam main part, vertical connecting pipe sets up crossbeam main part below, transverse connection stick is connected in vertical connecting pipe below, transverse connection stick is the plumbous alloy stick, the crossbeam links into a whole through welding and casting titanium alloy protective layer, the bar-shaped curved type positive pole of plumbous alloy is connected with transverse connection stick.
6. The novel chloride ion-resistant electrolytic zinc rod-shaped anode according to claim 5, wherein the vertical connecting pipes are round rods with a diameter of 16mm, 13 vertical connecting pipes are arranged at intervals of 30-40 mm, and the height of each vertical connecting pipe is 70 mm.
7. The novel chloride ion-resistant electrolytic zinc rod-shaped anode as claimed in claim 5, wherein the lead alloy rod-shaped curved anode is formed with a width of 630mm in a square plane, the lead alloy rod of the lead alloy rod-shaped curved anode has a diameter of 13mm, and the transverse connecting rod is formed with a round rod shape and a diameter of 13 mm.
8. The new type of chloride ion resistant electrolytic zinc rod anode of claim 5 wherein the total length of said beam is 1000mm and the total height is 125 mm.
9. The novel chloride ion resistant electrolytic zinc rod anode of claim 5, wherein said T2 copper bar cross section is 40mm by 12mm, and said beam body cross section dimension is 55mm by 22 mm.
10. The novel chloride ion resistant electrolytic zinc rod anode of claim 5, wherein the copper bar connection is tapered with a face dimension of 50mm x 45mm, a taper with a 12mm width at the bottom and a 6mm width at the top.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202021124898.0U CN212800564U (en) | 2020-06-17 | 2020-06-17 | Novel chloride ion-proof electrolytic zinc rod anode |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202021124898.0U CN212800564U (en) | 2020-06-17 | 2020-06-17 | Novel chloride ion-proof electrolytic zinc rod anode |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN212800564U true CN212800564U (en) | 2021-03-26 |
Family
ID=75096962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202021124898.0U Expired - Fee Related CN212800564U (en) | 2020-06-17 | 2020-06-17 | Novel chloride ion-proof electrolytic zinc rod anode |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN212800564U (en) |
-
2020
- 2020-06-17 CN CN202021124898.0U patent/CN212800564U/en not_active Expired - Fee Related
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107604388B (en) | Composite anode material and preparation method thereof, anode plate and preparation method thereof | |
| CN204779871U (en) | Non ferrous metal is fence type anode plate for electrodeposition | |
| CN212800564U (en) | Novel chloride ion-proof electrolytic zinc rod anode | |
| CN207276744U (en) | Composite anode materials and positive plate | |
| CN102433581B (en) | Method for preparing novel anode material for electro-deposition of nonferrous metals | |
| US4313811A (en) | Arrangement of busbars for electrolytic cells | |
| CN103572331A (en) | Fence type titanium-based PbO2 anode for electrodeposition of non-ferrous metals and manufacturing method of anode | |
| CN106435263B (en) | A kind of production method of the Pb-Ag-La alloy anode plates of energy-saving corrosion-resisting erosion | |
| CN105401175A (en) | Anode Apparatus | |
| CN107779910A (en) | Structure and method for reducing steel-carbon pressure drop of aluminum electrolysis anode | |
| JP6616187B2 (en) | Cathode and hollow conductive rod for cathode | |
| CN205077172U (en) | Special hanger of ball pivot class rubber component zinc -plating | |
| CN206570418U (en) | The frock electroplated simultaneously for hydraulic jack surfaces externally and internally | |
| CN205035474U (en) | Anode device | |
| CN213977900U (en) | Electrolytic tank for preparing tungsten carbide | |
| CN211829227U (en) | Carbon crystal composite grounding module | |
| CN205152353U (en) | Double -barrelled meshed anode | |
| CN209652451U (en) | A kind of enclosed type electrolytic tank permanent cathode | |
| CN208748211U (en) | A kind of copper electrodeposition palisading type composite anode plate | |
| CN209010620U (en) | Cupric electrolysis cathode collector bar | |
| CN209619478U (en) | The rodlike overlay film electrolytic zinc anode plate of NEW TYPE OF COMPOSITE | |
| CN219315112U (en) | Titanium-based composite lead dioxide reticular electrode plate | |
| CN202519346U (en) | Anode scrap-free series-wound electrolyzer with anode material storage tank | |
| CN219689899U (en) | Fence type titanium-based lead dioxide electrode plate | |
| CN201354386Y (en) | Aluminum electrolysis bath energy-saving cathode block structure |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210326 |