CN212741199U - Carbon fiber reinforced resin matrix composite recovery unit - Google Patents

Carbon fiber reinforced resin matrix composite recovery unit Download PDF

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Publication number
CN212741199U
CN212741199U CN202021361261.3U CN202021361261U CN212741199U CN 212741199 U CN212741199 U CN 212741199U CN 202021361261 U CN202021361261 U CN 202021361261U CN 212741199 U CN212741199 U CN 212741199U
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gas
pipe
pyrolysis
control valve
microwave
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许磊
任义尧
沈志刚
郭胜惠
韩朝辉
刘建华
夏仡
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Abstract

The utility model discloses a carbon fiber reinforced resin matrix composite recovery unit relates to carbon fiber recovery plant technical field. The device includes atmosphere regulation and control system, microwave pyrolysis system, pyrolysis oil collecting system, cracked gas recovery system, microwave pyrolysis system includes the microwave heating box, microwave generator, control system, flourishing material quartz capsule, be provided with the thermocouple in the flourishing material quartz capsule, flourishing material quartz capsule top is provided with infrared temperature measuring device, atmosphere regulation and control system makes and keeps vacuum, anaerobic or aerobic environment in the flourishing material quartz capsule, gaseous condenser pipe that gets into the slope and set up after the schizolysis, pyrolysis oil after the condensation gets into the pyrolysis oil collecting bottle, residual gas gets into the pyrolysis gas collecting bottle through filtering purification pipe. The temperature of the reaction materials is accurately obtained through a thermocouple and an infrared temperature measuring device, so that the heating temperature of the microwave is more reasonably controlled; through the condenser pipe that the slope set up, utilize pyrolysis oil self gravity, carry out abundant recovery to pyrolysis oil.

Description

Carbon fiber reinforced resin matrix composite recovery unit
Technical Field
The utility model relates to a carbon fiber recovery plant technical field, concretely relates to carbon fiber reinforced resin matrix combined material recovery unit.
Background
The carbon fiber reinforced resin matrix composite material attracts people's attention due to its excellent mechanical properties and light weight. With the development of industries such as aerospace, automobiles, wind power and the like, the demand of the carbon fiber cloth is increased year by year. The usage amount of the carbon fiber reinforced resin matrix composite material in 2018 is about 12.8 ten thousand tons, and the annual demand of the carbon fiber reinforced resin matrix composite material in 2022 is estimated to reach 19.9 ten thousand tons; in addition, the cumulative amount of carbon fiber composite used worldwide was about 705 ten thousand tons in the past decade. During the production of carbon fiber composite products, about 30% of the raw material becomes waste. This finding means that in the last decade we have produced at least 21.1 million tons of carbon fibre reinforced plastic waste, whereas in the future 70.5 million tons of waste must be disposed of. Therefore, the disposal of carbon fiber reinforced resin matrix composite waste is becoming a more urgent issue.
Among chemical methods for effectively recovering carbon fibers, the pyrolysis method is the most developed and applied recovery technology and is the only carbon fiber composite material recovery method for realizing commercial operation in the world at present. The pyrolysis method is based on the basic principle that a carbon fiber reinforced resin matrix composite material is filled into pyrolysis equipment for pyrolysis, the pyrolysis process is accurately controlled, the carbon fiber reinforced resin matrix composite material is heated, the heating temperature is kept between 400 and 500 ℃, clean carbon fibers produced under the condition can keep 90 to 95 percent of original performance, resin is cracked to generate gas in the process, the gas is condensed to obtain fuel oil and a part of non-condensable gas, and the main component of the part of gas is a mixture of combustible gases such as methane, ethane and the like. Therefore, in the process of recycling the carbon fiber by the pyrolysis method, two key steps are provided, namely, accurate temperature control is performed, the temperature of reactants is kept within a certain temperature range, and the pyrolysis reaction rate can be greatly improved; and secondly, gas generated by cracking is condensed and recovered, and part of fuel oil and combustible gas can be used as energy for secondary utilization.
Patent CN110000189A discloses a fiber reinforced organic composite waste high-efficiency resource recovery device, which measures the temperature of a reactant through a thermocouple and condenses and recovers gas through a condensation pipe. However, one thermocouple has one-sidedness in temperature measurement, so that the whole temperature condition of reactants is difficult to accurately master, and once the temperature condition is failed, the temperature condition is difficult to detect. In addition, the condensing pipes are arranged in parallel and are vertically placed, so that the fuel oil is gathered at the bottom of the condensing pipes and cannot be completely recycled.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a carbon fiber reinforced resin matrix combined material recovery unit solves the incomplete problem of the inaccurate, condensation back fuel oil recovery of current device temperature measurement.
In order to solve the technical problem, the utility model adopts the following technical scheme: the utility model provides a carbon fiber reinforced resin matrix composite recovery unit which characterized in that: the system comprises an atmosphere regulating system, a microwave pyrolysis system, a pyrolysis oil collecting system and a pyrolysis gas recovery system, wherein the microwave pyrolysis system comprises a microwave heating box body, a microwave generator, a control system and a material containing quartz tube, the material containing quartz tube transversely penetrates through the middle part of the microwave heating box body, the microwave generator heats reaction materials in the material containing quartz tube through a waveguide tube, a thermocouple is arranged in the material containing quartz tube, an infrared temperature measuring device is arranged at the top of the material containing quartz tube, and the thermocouple, the infrared temperature measuring device and the microwave generator are respectively in signal connection with the control system; the atmosphere regulation and control system comprises a protective gas cylinder, and the protective gas cylinder is connected with a gas inlet pipe of the material containing quartz tube; the pyrolysis oil collecting system comprises a pyrolysis oil collecting bottle, a condensing tube and a cooling water generating device, wherein an air inlet of the pyrolysis oil collecting bottle is connected with an exhaust pipe of a material containing quartz tube, an exhaust port of the pyrolysis oil collecting bottle is connected with an oil return port of the condensing tube, the condensing tube is arranged in an inclined mode, a water inlet of the condensing tube is connected with a water outlet of the cooling water generating device, a water return port of the condensing tube is connected with a water return port of the cooling water generating device, a pyrolysis gas recovery system comprises a filtering and purifying tube and a pyrolysis gas collecting bottle which are connected in sequence, and an exhaust port of the condensing tube is connected with an air.
The gas cylinder of oxidizing gas is connected with the first control valve and the gas inlet pipe in sequence through a pipeline, the gas cylinder of protective gas is connected with the gas inlet pipe through the second control valve, a gas pressure meter is arranged on the side, close to the microwave heating box, of the gas inlet pipe, and the gas inlet pipe is connected with the vacuum generating device through a third control valve.
The further technical scheme is that a fourth control valve is arranged on the exhaust pipe and is connected with an air inlet of the pyrolysis oil collecting bottle through a pipeline.
The exhaust port of the filtering and purifying pipe is connected with a cracked gas collecting bottle through a fifth control valve, is connected with a gas detection device through a sixth control valve, and is directly connected with an emptying pipe through a seventh control valve.
The further technical proposal is that the condensation pipe is a coil-shaped condensation pipe.
The working principle is as follows:
when the device is used, the carbon fiber reinforced resin matrix composite material is placed in the crucible, the crucible is placed in the material containing quartz tube, the thermocouple is placed on the reaction material, and the third control valve is opened to vacuumize the material containing quartz tube. And closing the third control valve, opening the second control valve, introducing protective gas, opening the microwave generator, heating the reaction materials, simultaneously opening the fourth control valve and the fifth control valve, allowing the pyrolysis gas to enter the condensation pipe through the pyrolysis oil collecting bottle, allowing the pyrolysis oil to flow downwards along the coiled pipe under the action of gravity under the cooling of cooling water, allowing the pyrolysis oil to flow into the pyrolysis oil collecting bottle, and allowing uncondensed gas to enter the pyrolysis gas collecting bottle after being purified by the filtering and purifying pipe. When gas is required to be detected, the sixth control valve is opened, the sixth control valve is closed after the gas enters the sampling port of the gas detection device, and real-time online detection can be performed on the cracked gas through the gas detection device.
And after no gas is generated after cracking is finished, closing the microwave generator, simultaneously closing the fifth control valve and the second control valve, opening the first control valve and the seventh control valve, oxidizing the reaction material carbon residue by oxidizing gas, absorbing the generated carbon dioxide gas by a filtering and purifying pipe, and then discharging the carbon dioxide gas into the atmosphere from an emptying pipe.
Compared with the prior art, the beneficial effects of the utility model are that: the thermocouple and the infrared temperature measuring device are used for measuring the temperature of the reaction materials respectively, whether the element fails or not can be judged according to the temperature difference between the thermocouple and the infrared temperature measuring device, the temperature of the reaction materials can be obtained more accurately, and the heating temperature of microwaves can be controlled more reasonably; the cracked oil is fully recovered by the aid of the gravity of the cracked oil through the obliquely arranged condensing pipe; greatly improves the cracking efficiency of reaction materials and improves the recovery completeness of the cracking oil.
Drawings
Fig. 1 is a schematic structural diagram of the present invention.
Fig. 2 is a schematic structural view of an angle of the middle microwave heating box of the present invention.
Fig. 3 is a schematic structural view of another angle of the middle microwave heating box of the present invention.
In the figure: 1-a microwave heating box body, 2-a microwave generator, 3-a material-containing quartz tube, 301-an air inlet tube, 302-an exhaust tube, 4-a waveguide tube, 5-a thermocouple, 6-an infrared temperature measuring device, 7-a protective gas cylinder, 8-a pyrolysis oil collecting bottle, 9-a condensing tube, 10-a cooling water generating device, 11-a filtering and purifying tube, 12-a pyrolysis gas collecting bottle, 13-an oxidizing gas cylinder, 14-a first control valve, 15-a second control valve, 16-a gas pressure gauge, 17-a third control valve, 18-a fourth control valve, 19-a fifth control valve, 20-a gas detecting device, 21-a sixth control valve, 22-a seventh control valve, 23-an emptying tube, 24-a crucible and 25-a reaction material.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more clearly understood, the present invention is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Examples
Fig. 1 shows a carbon fiber reinforced resin matrix composite recovery device, which is characterized in that: comprises an atmosphere control system, a microwave pyrolysis system, a pyrolysis oil collecting system and a pyrolysis gas recovery system.
As shown in fig. 2 and 3, the microwave pyrolysis system comprises a microwave heating box body 1, a microwave generator 2, a control system and a material-containing quartz tube 3. The material containing quartz tube 3 transversely penetrates through the middle part of the microwave heating box body 1, the microwave generator 2 heats reaction materials in the material containing quartz tube 3 through the waveguide tube 4, the thermocouple 5 is arranged in the material containing quartz tube 3, the infrared temperature measuring device 6 is arranged at the top of the material containing quartz tube 3, and the thermocouple 5, the infrared temperature measuring device 6 and the microwave generator 2 are respectively in signal connection with the control system. One end of the material-containing quartz tube 3 is an air inlet tube 301, the air inlet tube 301 is provided with a barometer 16, and the air inlet tube 301 is sequentially connected with a third control valve 17 and a vacuum generating device through branch tubes. The exhaust pipe 302 is provided with a fourth control valve 18.
The atmosphere control system comprises a protective gas cylinder 7 and an oxidizing gas cylinder 13, wherein the protective gas cylinder 7 is connected with the gas inlet pipe 301 through a first control valve 14, and the oxidizing gas cylinder 13 is connected with the gas inlet pipe 301 through a second control valve 15.
Pyrolysis oil collecting system includes pyrolysis oil receiving flask 8, condenser pipe 9, cooling water generating device 10, and 8 air inlets of pyrolysis oil receiving flask are connected with fourth control valve 8 on the blast pipe 302 of flourishing material quartz capsule 3, and 8 gas vents of pyrolysis oil receiving flask are connected with 9 oil return mouths of condenser pipe, and 9 slopes of condenser pipe set up, and 9 water inlets of condenser pipe are connected with 10 delivery ports of cooling water generating device, and 9 delivery ports of condenser pipe are connected with 10 return water mouths of cooling water generating device. In this embodiment, the protective gas cylinder 7 is a nitrogen cylinder, and the oxidizing gas cylinder 13 is an oxygen cylinder.
Cracked gas recovery system includes filtration purification pipe 11, cracked gas receiving flask 12 and gas detection device 20, and 9 gas vents of condenser pipe are connected with filtration purification pipe 11 air inlets, and filtration purification pipe 1 gas vent is connected with cracked gas receiving flask 12 through fifth control valve 19, is connected with gas detection device 20 through sixth control valve 21, directly is connected with evacuation pipe 23 through seventh control valve 22. In order to improve the condensation effect, the condensation pipe 9 is a coil-shaped condensation pipe.
When the device is used, the reaction material 25, the carbon fiber reinforced resin matrix composite material, is placed in the crucible 24, the crucible 24 is placed in the material containing quartz tube 3, the thermocouple 5 is placed on the reaction material 25, and the third control valve 17 is opened to vacuumize the material containing quartz tube 3. Closing the third control valve 17, opening the second control valve 15, introducing protective gas nitrogen, opening the microwave generator 2, heating the reaction materials 25 through the waveguide tube 4, simultaneously opening the fourth control valve 18 and the fifth control valve 19, allowing the pyrolysis gas to enter the condensation tube 9 through the pyrolysis oil collection bottle 8, allowing the pyrolysis oil to flow downwards along the serpentine tube under the action of gravity under the cooling of cooling water, allowing the pyrolysis oil to flow into the pyrolysis oil collection bottle 8, and allowing uncondensed gas to enter the pyrolysis gas collection bottle 12 after being purified through the filtering and purifying tube 11. When gas needs to be detected, the sixth control valve 21 is opened, the sixth control valve 21 is closed after the gas enters the sampling port of the gas detection device 20, and real-time online detection can be performed on the cracked gas through the gas detection device 20. The gas detection device 20 may be a gas chromatograph.
After cracking is finished and no new gas is generated, the microwave generator 2 is closed, the fifth control valve 19 and the second control valve 15 are closed, the first control valve 14 and the seventh control valve 22 are opened, carbon residue in the reaction material 25 is oxidized by oxygen, and the generated carbon dioxide gas is absorbed by the filtering and purifying pipe 11 and then discharged into the atmosphere from the emptying pipe 23.
This device passes through thermocouple 5 and infrared temperature measuring device 6 respectively to the temperature measurement of reaction material 25, can judge whether the component is inefficacy through temperature difference between them, also can be more accurate acquire reaction material 25 temperature for the heating temperature of control system more reasonable control microwave promotes the schizolysis efficiency greatly, shortens reaction time. Through the condenser pipe 9 that the slope set up, utilize pyrolysis oil self gravity, carry out abundant recovery to pyrolysis oil, improve pyrolysis oil's recovery effect. Combustible gas generated by cracking is recycled through the cracking gas collecting bottle 12, and cracked gas components are detected on line through the gas detection device 20, so that the proceeding degree of cracking reaction can be conveniently known.
Although the invention has been described herein with reference to a number of illustrative embodiments thereof, it should be understood that numerous other modifications and embodiments can be devised by those skilled in the art that will fall within the spirit and scope of the principles of this invention. More particularly, various variations and modifications are possible in the component parts and/or arrangements within the scope of the disclosure, the drawings and the appended claims. In addition to variations and modifications in the component parts and/or arrangements, other uses will also be apparent to those skilled in the art.

Claims (5)

1. The utility model provides a carbon fiber reinforced resin matrix composite recovery unit which characterized in that: the system comprises an atmosphere regulation and control system, a microwave pyrolysis system, a pyrolysis oil collection system and a pyrolysis gas recovery system, wherein the microwave pyrolysis system comprises a microwave heating box body (1), a microwave generator (2), a control system and a material containing quartz tube (3), the material containing quartz tube (3) transversely penetrates through the middle part of the microwave heating box body (1), the microwave generator (2) heats reaction materials in the material containing quartz tube (3) through a waveguide tube (4), a thermocouple (5) is arranged in the material containing quartz tube (3), an infrared temperature measuring device (6) is arranged at the top of the material containing quartz tube (3), and the thermocouple (5), the infrared temperature measuring device (6) and the microwave generator (2) are respectively in signal connection with the control system; the atmosphere control system comprises a protective gas cylinder (7), and the protective gas cylinder (7) is connected with a gas inlet pipe (301) of the material containing quartz tube (3); pyrolysis oil collecting system includes pyrolysis oil receiving flask (8), condenser pipe (9), cooling water generating device (10), pyrolysis oil receiving flask (8) air inlet is connected with blast pipe (302) of flourishing material quartz capsule (3), pyrolysis oil receiving flask (8) gas vent is connected with condenser pipe (9) oil return opening, condenser pipe (9) slope sets up, condenser pipe (9) water inlet is connected with cooling water generating device (10) delivery port, condenser pipe (9) delivery port is connected with cooling water generating device (10) return water mouth, pyrolysis gas recovery system is including the filtration purification pipe (11) and pyrolysis gas receiving flask (12) that connect gradually, condenser pipe (9) gas vent is connected with filtration purification pipe (11) air inlet.
2. The recovery device for carbon fiber reinforced resin-based composite material as claimed in claim 1, wherein: the atmosphere control system further comprises an oxidizing gas cylinder (13), the oxidizing gas cylinder (13) is sequentially connected with the first control valve (14) and the gas inlet pipe (301) through a pipeline, the protective gas cylinder (7) is connected with the gas inlet pipe (301) through the second control valve (15), a gas pressure gauge (16) is arranged on the side, close to the microwave heating box body (1), of the gas inlet pipe (301), and the gas inlet pipe (301) is connected with the vacuum generating device through a third control valve (17).
3. The recovery device for carbon fiber reinforced resin-based composite material as claimed in claim 1, wherein: and a fourth control valve (18) is arranged on the exhaust pipe (302), and the fourth control valve (18) is connected with an air inlet of the pyrolysis oil collecting bottle (8) through a pipeline.
4. The recovery device for carbon fiber reinforced resin-based composite material as claimed in claim 1, wherein: the exhaust port of the filtering and purifying pipe (11) is connected with a pyrolysis gas collecting bottle (12) through a fifth control valve (19), is connected with a gas detection device (20) through a sixth control valve (21), and is directly connected with an emptying pipe (23) through a seventh control valve (22).
5. The recovery device for carbon fiber reinforced resin-based composite material as claimed in claim 1, wherein: the condensation pipe (9) is a snake-shaped condensation pipe.
CN202021361261.3U 2020-07-13 2020-07-13 Carbon fiber reinforced resin matrix composite recovery unit Active CN212741199U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114295676A (en) * 2021-12-27 2022-04-08 华东理工大学 Resin-based ablation heat-proof material rapid thermal cracking device and thermal cracking method
CN114769294A (en) * 2022-04-20 2022-07-22 昆明理工大学 Efficient recovery system and method for resin-based composite material waste

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114295676A (en) * 2021-12-27 2022-04-08 华东理工大学 Resin-based ablation heat-proof material rapid thermal cracking device and thermal cracking method
CN114769294A (en) * 2022-04-20 2022-07-22 昆明理工大学 Efficient recovery system and method for resin-based composite material waste

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Inventor after: Xu Lei

Inventor after: Ren Yiyao

Inventor after: Guo Shenghui

Inventor after: Han Chaohui

Inventor after: Liu Jianhua

Inventor before: Xu Lei

Inventor before: Ren Yiyao

Inventor before: Shen Zhigang

Inventor before: Guo Shenghui

Inventor before: Han Chaohui

Inventor before: Liu Jianhua

Inventor before: Xia Ge