CN212068317U - Integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery and its purification system - Google Patents

Integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery and its purification system Download PDF

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CN212068317U
CN212068317U CN201922295040.4U CN201922295040U CN212068317U CN 212068317 U CN212068317 U CN 212068317U CN 201922295040 U CN201922295040 U CN 201922295040U CN 212068317 U CN212068317 U CN 212068317U
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魏晓东
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Harbin Zhongke Tiande Energy Saving Environmental Protection Technology Co ltd
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Abstract

本实用新型公开了一种脱硫、除尘、脱硝、余热回收一体化装备及其净化系统,该脱硫、除尘、脱硝、余热回收一体化装备包括文丘里雾化装置、本体、至少一个气液补充孔、排烟管、螺旋板、和排污管;该脱硫、除尘、脱硝、余热回收一体化装备的净化系统包括脱硫、除尘、脱硝、余热回收一体化装备,还包括换热除尘装置、气水分离系统、固液分离系统和多物质混合吸收液系统。本实用新型结构简单合理,能更高效的处理烟气并进行回收,最终使烟气排放达到国家现行发布的环保行业标准。

Figure 201922295040

The utility model discloses an integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery and a purification system thereof. The integrated equipment for desulfurization, dust removal, denitration and waste heat recovery comprises a venturi atomization device, a main body and at least one gas-liquid supplementary hole , flue pipe, spiral plate, and sewage pipe; the purification system of the integrated desulfurization, dust removal, denitrification, and waste heat recovery equipment includes desulfurization, dust removal, denitrification, and waste heat recovery integrated equipment, as well as heat exchange and dust removal devices, gas-water separation equipment system, solid-liquid separation system and multi-substance mixed absorption liquid system. The utility model has a simple and reasonable structure, can process and recycle the flue gas more efficiently, and finally make the flue gas discharge reach the current national environmental protection industry standard.

Figure 201922295040

Description

脱硫、除尘、脱硝、余热回收一体化装备及其净化系统Integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery and its purification system

技术领域technical field

本实用新型属于电厂脱硫、脱硝设备领域技术领域,特别涉及一种脱硫、除尘、脱硝、余热回收一体化装备及其净化系统。The utility model belongs to the technical field of desulfurization and denitrification equipment in power plants, in particular to an integrated equipment for desulfurization, dust removal, denitration and waste heat recovery and a purification system thereof.

背景技术Background technique

电厂传统的脱硫、脱硝、除尘设备及与之配套的系统主要包括:除尘设备及系统、脱硫设备及系统、脱硝设备及系统、大烟囱等,具有设备庞大、系统复杂、脱硫、脱硝塔设计不合理、易结垢堵塞;布袋除尘、电除尘、脱硫与脱硝塔风阻大、故障率多、配套设备多、维护工作量大、投资巨大、运行费用高、占地面积大等缺陷;最为关键的是,传统装备及系统没有根本突破解决烟气与吸收液、反应气充分均质混合、碰撞、接触以及化合吸收时间短的瓶颈,致使烟气处理有效率低,最终烟气排放达不到国家现行发布的环保行业标准。The traditional desulfurization, denitration, and dust removal equipment in power plants and their supporting systems mainly include: dust removal equipment and systems, desulfurization equipment and systems, denitration equipment and systems, large chimneys, etc. Reasonable, easy to scale and block; bag dust removal, electrostatic precipitator, desulfurization and denitrification towers have large wind resistance, many failure rates, many supporting equipment, large maintenance workload, huge investment, high operating costs, large floor space and other defects; the most critical Yes, traditional equipment and systems have not fundamentally broken through to solve the bottleneck of fully homogeneous mixing, collision, contact and combined absorption time of flue gas, absorbing liquid and reaction gas, resulting in low efficiency of flue gas treatment, and ultimately flue gas emissions can not reach the national level. The current published environmental protection industry standards.

公开于该背景技术部分的信息仅仅旨在增加对本实用新型的总体背景的理解,而不应当被视为承认或以任何形式暗示该信息构成已为本领域一般技术人员所公知的现有技术。The information disclosed in this Background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art.

发明内容SUMMARY OF THE INVENTION

本实用新型主要目的是为了解决目前设备结构复杂、故障率多、配套设备多、维护工作量大、投资巨大、运行费用高、占地面积大等缺陷,并提高烟气处理效率,提供了一种脱硫、除尘、脱硝、余热回收一体化装备及其净化系统。The main purpose of the utility model is to solve the defects of the current equipment, such as complex structure, high failure rate, many supporting equipment, large maintenance workload, huge investment, high operating cost, large floor space, etc., and to improve the efficiency of flue gas treatment. A desulfurization, dust removal, denitrification, waste heat recovery integrated equipment and its purification system.

为了达到上述目的,本实用新型提供的技术方案是:一种脱硫、除尘、脱硝、余热回收一体化装备,该脱硫、除尘、脱硝、余热回收一体化装备包括:文丘里雾化装置、本体、至少一个气液补充孔、换热介质进管、换热介质出管、排烟管、螺旋板、和排污管;文丘里雾化装置包括进烟管、多物质混合吸收液进口、反应气进口、文丘里雾化器、雾化入口和雾化出口;进烟管、多物质混合吸收液进口和反应气进口置于文丘里雾化装置前端;进烟管的后端、多物质混合吸收液进口的后端和反应气进口的后端分别与雾化入口前端相连;文丘里雾化入口的后端与文丘里雾化器相连;文丘里雾化器的后端与雾化出口相连;雾化出口与本体的上端连通;本体的下端与排污管相连;换热介质进管与本体的下端外壁连通;换热介质出管与本体的上端外壁连通;排烟管置于本体的中部;排烟管的下端与排污管相连;排烟管的上端从本体的上方伸出;螺旋板置于本体的侧壁内与排烟管外壁之间;气液补充孔开在本体的侧面与螺旋板之间构成的螺旋通道连通。In order to achieve the above purpose, the technical solution provided by the present utility model is: an integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery, the integrated equipment for desulfurization, dust removal, denitration and waste heat recovery includes: a venturi atomization device, a body, At least one gas-liquid supplementary hole, heat exchange medium inlet pipe, heat exchange medium outlet pipe, smoke exhaust pipe, spiral plate, and sewage pipe; the venturi atomization device includes a smoke inlet pipe, a multi-substance mixed absorption liquid inlet, and a reaction gas inlet , Venturi atomizer, atomization inlet and atomization outlet; the smoke inlet pipe, the multi-substance mixed absorption liquid inlet and the reaction gas inlet are placed at the front end of the Venturi atomization device; the rear end of the smoke inlet pipe, the multi-substance mixed absorption liquid The rear end of the inlet and the rear end of the reaction gas inlet are respectively connected with the front end of the atomization inlet; the rear end of the venturi atomization inlet is connected with the venturi atomizer; the rear end of the venturi atomizer is connected with the atomization outlet; The chemical outlet is communicated with the upper end of the body; the lower end of the body is connected with the sewage discharge pipe; the heat exchange medium inlet pipe is communicated with the lower end outer wall of the body; the heat exchange medium outlet pipe is communicated with the upper end outer wall of the body; the smoke exhaust pipe is placed in the middle of the body; The lower end of the smoke pipe is connected with the sewage pipe; the upper end of the smoke pipe protrudes from the top of the main body; the spiral plate is placed between the side wall of the main body and the outer wall of the smoke exhaust pipe; the gas-liquid supplementary hole is opened on the side of the main body and the spiral plate The spiral channel formed between them communicates with each other.

多物质混合吸收液进口、反应气进口均为喷嘴。The inlet of the multi-substance mixed absorption liquid and the inlet of the reaction gas are both nozzles.

雾化出口的后端沿切线方向与本体的上端连通并与螺旋通道连通。The rear end of the atomization outlet communicates with the upper end of the body along the tangential direction and communicates with the spiral channel.

排烟管为下返烟式排烟管;排烟管、螺旋板及本体均设置有夹层,夹层之间互通;夹层内装有换热介质。The smoke exhaust pipe is a bottom-return smoke exhaust pipe; the smoke exhaust pipe, the spiral plate and the main body are all provided with interlayers, and the interlayers communicate with each other; the interlayer is provided with a heat exchange medium.

排污管为水封式椎体排污管。The sewage pipe is a water-sealed vertebral sewage pipe.

一种脱硫、除尘、脱硝、余热回收一体化装备的净化系统,包括脱硫、除尘、脱硝、余热回收一体化装备;还包括换热除尘装置、气水分离系统、固液分离系统和多物质混合吸收液系统;换热除尘装置后端与进烟管前端连接;气水分离系统与排烟管的后端相连;固液分离系统与排污管相连;多物质混合吸收液系统的出口端与多物质混合吸收液进口相连。A purification system with integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery, including integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery; also includes heat exchange and dust removal device, gas-water separation system, solid-liquid separation system and multi-substance mixing The absorption liquid system; the rear end of the heat exchange and dust removal device is connected with the front end of the smoke inlet pipe; the gas-water separation system is connected with the rear end of the smoke exhaust pipe; the solid-liquid separation system is connected with the sewage pipe; the outlet end of the multi-substance mixed absorption liquid system is connected with the The substance mixed absorption liquid inlet is connected.

多物质混合吸收液系统包括补水管、吸收液输送管、混合罐和积液池;补水管和吸收液输送管分别与混合罐相连;混合罐的出口与积液池相连;积液池与多物质混合吸收液进口相连。The multi-substance mixed absorption liquid system includes a water replenishing pipe, an absorption liquid conveying pipe, a mixing tank and a liquid accumulation tank; the water replenishing pipe and the absorption liquid conveying pipe are respectively connected with the mixing tank; the outlet of the mixing tank is connected with the liquid accumulation tank; The substance mixed absorption liquid inlet is connected.

积液池通过第一液泵与多物质混合吸收液进口相连。The liquid accumulation pool is connected with the multi-substance mixed absorption liquid inlet through the first liquid pump.

固液分离系统包括固液分离装置、缓存罐、在线全自动过滤装置、污泥固化装置和废渣回收装置;固液分离装置安装于排污管下端;固液分离装置的混合液出口与缓存罐相连;缓存罐的液体出口与在线全自动过滤装置相连;在线全自动过滤装置的出液口与积液池相连;固液分离装置和缓存罐的沉降物出口分别与污泥固化装置相连;污泥固化装置的液体出口与积液池相连;污泥固化装置的固化物出口与废渣回收装置相连。The solid-liquid separation system includes a solid-liquid separation device, a buffer tank, an online automatic filtration device, a sludge solidification device and a waste residue recovery device; the solid-liquid separation device is installed at the lower end of the sewage pipe; the mixed liquid outlet of the solid-liquid separation device is connected to the buffer tank ; The liquid outlet of the buffer tank is connected to the online automatic filtering device; the liquid outlet of the online automatic filtering device is connected to the liquid accumulation tank; the sediment outlet of the solid-liquid separation device and the buffer tank are respectively connected to the sludge solidification device; The liquid outlet of the solidification device is connected with the liquid accumulation pool; the solidified product outlet of the sludge solidification device is connected with the waste residue recovery device.

污泥固化装置的液体出口通过第二液泵与积液池相连;固液分离装置和缓存罐的沉降物出口分别通过污泥输出装置与污泥固化装置相连。The liquid outlet of the sludge solidification device is connected to the liquid accumulation tank through the second liquid pump; the sediment outlets of the solid-liquid separation device and the buffer tank are respectively connected to the sludge solidification device through the sludge output device.

气水分离系统包括气体入口、净化烟气排出口、气水分离装置和液体出口;气体入口与排烟管连通;气体入口与气水分离装置一端相连;气水分离装置的另一端和液体出口相连;气水分离装置的上端与净化烟气排出口连通。The gas-water separation system includes a gas inlet, a purified flue gas outlet, a gas-water separation device and a liquid outlet; the gas inlet is communicated with the exhaust pipe; the gas inlet is connected to one end of the gas-water separation device; the other end of the gas-water separation device and the liquid outlet connected; the upper end of the gas-water separation device is communicated with the exhaust port of the purified flue gas.

气体入口通过引风机与排烟管连通。The gas inlet is communicated with the exhaust pipe through the induced draft fan.

本实用新型的特点:Features of this utility model:

与现有技术相比,本实用新型的脱硫、除尘、脱硝、余热回收一体化装备及其净化系统具有如下有益效果:该脱硫、除尘、脱硝、余热回收一体化装备及其净化系统采用气、液喷嘴、文丘里雾化装置、带夹层的螺旋板与本体形成强制拉长螺旋通道,实现充分换热、均质混合、碰撞、接触、延时的作用,实现了烟气分子团和多物质混合吸收液、反应气分子团均质、充分混合、碰撞与接触并持续一定的化合反应及吸收时间的作用,极大的提高了处理有效率,实现完全消除烟气里的有害气体的目的,尤其突出的实现了消除PM2.5尘埃及以上灰尘的目的;由于采用带夹层的螺旋通道设计,很好的解决了余热回收的问题,夹层内的换热介质可以是水、空气、油类等;采用水封排污管的无障碍设计,彻底解决了装备在线排污和密封问题,彻底消除了装备内部结垢被堵塞的可能性,消除了因设备堵塞而造成停产检修几率;其配套的净化系统充分保障了一体化装备的运行效果;由于一体化装备结构简单合理,规避了漏气、结垢、堵塞等风险,确保一体化装备连续正常运行,为实现一体化装备及系统在线智能化运行提供了保障。进而,实现一体化装备和净化系统与锅炉在线智能自动化控制运行的目的。Compared with the prior art, the integrated equipment for desulfurization, dust removal, denitration, and waste heat recovery and its purification system of the present invention have the following beneficial effects: the integrated equipment for desulfurization, dust removal, denitration, and waste heat recovery and its purification system use gas, Liquid nozzle, Venturi atomization device, spiral plate with interlayer and the body form a forced elongated spiral channel to achieve full heat exchange, homogeneous mixing, collision, contact and delay, and realize the effect of flue gas molecular clusters and multi-substance The mixed absorption liquid and reaction gas molecular groups are homogeneous, fully mixed, collided and contacted, and continue for a certain combination reaction and absorption time, which greatly improves the treatment efficiency and achieves the purpose of completely eliminating harmful gases in the flue gas. In particular, it achieves the purpose of eliminating PM2.5 dust and above dust; due to the spiral channel design with interlayer, the problem of waste heat recovery is well solved, and the heat exchange medium in the interlayer can be water, air, oil, etc. ;The barrier-free design of the water-sealed sewage pipe completely solves the problem of online sewage and sealing of equipment, completely eliminates the possibility of internal fouling and blockage of equipment, and eliminates the probability of shutdown and maintenance due to equipment blockage; its supporting purification system The operation effect of the integrated equipment is fully guaranteed; due to the simple and reasonable structure of the integrated equipment, risks such as air leakage, scaling and blockage are avoided, and the continuous and normal operation of the integrated equipment is ensured, which provides for the realization of the online intelligent operation of the integrated equipment and system. guaranteed. Furthermore, the purpose of integrated equipment and purification system and boiler online intelligent automatic control operation is realized.

附图说明:Description of drawings:

图1:本实用新型的结构示意图。Fig. 1: The structure schematic diagram of the present utility model.

具体实施方式:Detailed ways:

下面结合附图,对本实用新型的具体实施方式进行详细描述,但应当理解本实用新型的保护范围并不受具体实施方式的限制。The specific embodiments of the present invention will be described in detail below with reference to the accompanying drawings, but it should be understood that the protection scope of the present invention is not limited by the specific embodiments.

除非另有其它明确表示,否则在整个说明书和权利要求书中,术语“包括”或其变换如“包含”或“包括有”等等将被理解为包括所陈述的元件或组成部分,而并未排除其它元件或其它组成部分。Unless expressly stated otherwise, throughout the specification and claims, the term "comprising" or its conjugations such as "comprising" or "comprising" and the like will be understood to include the stated elements or components, and Other elements or other components are not excluded.

实施例1:Example 1:

如图1所示:As shown in Figure 1:

一种脱硫、除尘、脱硝、余热回收一体化装备25,包括文丘里雾化装置、本体29、至少一个气液补充孔30、换热介质进管28、换热介质出管27、排烟管5、螺旋板6、和排污管11;文丘里雾化装置包括进烟管31、多物质混合吸收液进口3、反应气进口23、文丘里雾化器4、雾化入口33和雾化出口32;进烟管31、多物质混合吸收液进口3和反应气进口23置于文丘里雾化装置前端;进烟管31的后端、多物质混合吸收液进口3的后端和反应气进口23的后端分别与雾化入口33前端相连;文丘里雾化入口33的后端与文丘里雾化器4相连;文丘里雾化器4的后端与雾化出口32相连;雾化出口32与本体29上端连通;本体29下端与排污管11相连;换热介质进管28与本体29下端外壁连通;所述换热介质出管27与本体29上端外壁连通;排烟管5置于本体29的中部;排烟管5的下端与排污管11相连;排烟管5的上端从本体29的上方伸出;螺旋板6置于本体29侧壁内与排烟管5外壁之间,形成螺旋通道7,气液补充孔30开在本体29的侧面与螺旋板6之间构成的螺旋通道7连通。An integrated equipment 25 for desulfurization, dust removal, denitration and waste heat recovery, including a venturi atomization device, a main body 29, at least one gas-liquid supplementary hole 30, a heat exchange medium inlet pipe 28, a heat exchange medium outlet pipe 27, and a smoke exhaust pipe 5. Spiral plate 6, and sewage pipe 11; Venturi atomization device includes smoke inlet pipe 31, multi-substance mixed absorption liquid inlet 3, reaction gas inlet 23, Venturi atomizer 4, atomization inlet 33 and atomization outlet 32; the smoke inlet pipe 31, the multi-substance mixed absorption liquid inlet 3 and the reaction gas inlet 23 are placed at the front end of the venturi atomization device; the rear end of the smoke inlet pipe 31, the rear end of the multi-substance mixed absorption liquid inlet 3 and the reaction gas inlet The rear end of 23 is connected with the front end of the atomization inlet 33 respectively; the rear end of the venturi atomization inlet 33 is connected with the venturi atomizer 4; the rear end of the venturi atomizer 4 is connected with the atomization outlet 32; the atomization outlet 32 is communicated with the upper end of the body 29; the lower end of the body 29 is connected with the sewage pipe 11; the heat exchange medium inlet pipe 28 is communicated with the outer wall of the lower end of the body 29; the heat exchange medium outlet pipe 27 is communicated with the outer wall of the upper end of the body 29; The middle part of the main body 29; the lower end of the smoke exhaust pipe 5 is connected with the sewage pipe 11; the upper end of the smoke exhaust pipe 5 protrudes from the top of the main body 29; the spiral plate 6 is placed between the side wall of the main body 29 and the outer wall of the smoke exhaust pipe 5, A spiral channel 7 is formed, and the gas-liquid replenishing hole 30 is opened on the side surface of the main body 29 and communicates with the spiral channel 7 formed between the spiral plate 6 .

多物质混合吸收液进口3、反应气进口23均为喷嘴。The multi-substance mixed absorption liquid inlet 3 and the reaction gas inlet 23 are both nozzles.

雾化出口32的后端沿切线方向与本体29的上端连通并与螺旋通道7连通。The rear end of the atomization outlet 32 communicates with the upper end of the main body 29 and communicates with the spiral channel 7 along the tangential direction.

排烟管5为下返烟式排烟管;排烟管5、螺旋板6及本体29均设置有夹层26,且夹层26互通,夹层26内的换热介质可以是水、空气、油类等。The smoke exhaust pipe 5 is a bottom-return type smoke exhaust pipe; the smoke exhaust pipe 5, the spiral plate 6 and the main body 29 are all provided with an interlayer 26, and the interlayer 26 communicates with each other, and the heat exchange medium in the interlayer 26 can be water, air, oil Wait.

排污管11为水封式椎体排污管。The sewage pipe 11 is a water-sealed vertebral sewage pipe.

反应气进口23和储气罐或在线反应气生产系统连通。The reaction gas inlet 23 is communicated with a gas storage tank or an on-line reaction gas production system.

一种脱硫、除尘、脱硝、余热回收一体化装备的净化系统,包括脱硫、除尘、脱硝、余热回收一体化装备25;还包括换热除尘装置2、气水分离系统、固液分离系统和多物质混合吸收液系统;换热除尘装置2后端与进烟管31前端连接;换热除尘装置2前端与锅炉引风机1连通;气水分离系统与排烟管5的后端相连;固液分离系统与排污管11相连;多物质混合吸收液系统的出口端与多物质混合吸收液进口3相连。A purification system with integrated equipment for desulfurization, dust removal, denitration, and waste heat recovery, including desulfurization, dust removal, denitrification, and waste heat recovery integrated equipment 25; it also includes a heat exchange and dust removal device 2, a gas-water separation system, a solid-liquid separation system, and multiple Substance mixed absorption liquid system; the rear end of the heat exchange and dust removal device 2 is connected to the front end of the smoke inlet pipe 31; the front end of the heat exchange dust removal device 2 is connected to the boiler induced draft fan 1; the gas-water separation system is connected to the rear end of the smoke exhaust pipe 5; The separation system is connected with the sewage pipe 11 ; the outlet end of the multi-substance mixed absorption liquid system is connected with the multi-substance mixed absorption liquid inlet 3 .

多物质混合吸收液系统包括补水管21、吸收液输送管22、吸收液混合罐24和积液池20;补水管21和吸收液输送管22分别与吸收液混合罐24相连;吸收液混合罐24的出口与积液池20相连;积液池20与多物质混合吸收液进口3相连。水和硫、氮氧化物吸收剂分别通过补水管21和吸收液输送管22进入吸收液混合罐24,进行混合调整PH值后再进入积液池20形成用于电厂锅炉烟气的脱硫、脱硝的多物质混合吸收液。The multi-substance mixed absorption liquid system includes a water replenishing pipe 21, an absorption liquid conveying pipe 22, an absorption liquid mixing tank 24 and an accumulation pool 20; the water replenishing pipe 21 and the absorption liquid conveying pipe 22 are respectively connected with the absorption liquid mixing tank 24; the absorption liquid mixing tank The outlet of 24 is connected with the liquid accumulation pool 20; the liquid accumulation pool 20 is connected with the multi-substance mixed absorption liquid inlet 3. Water, sulfur and nitrogen oxide absorbents enter the absorption liquid mixing tank 24 through the water replenishing pipe 21 and the absorption liquid conveying pipe 22 respectively, and then enter the liquid accumulation tank 20 after mixing and adjusting the pH value to form the desulfurization and denitration of the power plant boiler flue gas. The multi-substance mixed absorption solution.

积液池20通过第一液泵15与多物质混合吸收液进口3相连,通过第一液泵15将多物质混合吸收液抽入文丘里雾化装置的雾化入口33。The liquid accumulation pool 20 is connected to the multi-substance mixed absorption liquid inlet 3 through the first liquid pump 15 , and the multi-substance mixed absorption liquid is pumped into the atomization inlet 33 of the venturi atomization device through the first liquid pump 15 .

经过文丘里雾化装置雾化混合后的多物质混合吸收液、反应气和锅炉烟气沿切线方向引入本体29内的螺旋通道7内,由螺旋通道7底部切线旋出;由于离心作用,固液气混合体向下沿切线方向进入水封式椎体排污管11,固液气混合体由水封式椎体排污管11排入固液分离装置12,剩余的烟气进入带夹层的下返烟式排烟管5排出;带夹层的下返烟式排烟管5经引风机10将剩余的气体导入气水分离装置9。The multi-substance mixed absorption liquid, reaction gas and boiler flue gas after being atomized and mixed by the venturi atomizing device are introduced into the spiral channel 7 in the main body 29 along the tangential direction, and are tangentially spun out from the bottom of the spiral channel 7; The liquid-gas mixture enters the water-sealed vertebral body sewage pipe 11 downward along the tangential direction, the solid-liquid gas mixture is discharged from the water-sealed vertebral body sewage pipe 11 into the solid-liquid separation device 12, and the remaining flue gas enters the lower part with the interlayer. The smoke return type smoke exhaust pipe 5 is discharged; the lower return smoke type smoke exhaust pipe 5 with the interlayer guides the remaining gas into the gas-water separation device 9 through the induced draft fan 10 .

固液分离系统包括固液分离装置12、缓存罐13、在线全自动过滤装置19、污泥固化装置17和废渣回收装置18。固液分离装置12安装于排污管11下端,排污管11的下端伸入到固液分离装置12内的多物质混合吸收液的液面以下形成水封式排污,利用液体压强原理,实现无障碍排污及封闭装备的目的,该原理的应用,彻底摒弃了阀门开关所导致的多发故障以及相对应的运行费用,减少了相关联的配套设施,在减少了工作难度的同时,也降低了相关投入成本以及运行费用,为实现在线智能化运行提供了保障。The solid-liquid separation system includes a solid-liquid separation device 12 , a buffer tank 13 , an online automatic filter device 19 , a sludge solidification device 17 and a waste residue recovery device 18 . The solid-liquid separation device 12 is installed at the lower end of the sewage pipe 11, and the lower end of the sewage pipe 11 extends below the liquid level of the multi-substance mixed absorption liquid in the solid-liquid separation device 12 to form a water-sealed sewage discharge, using the principle of liquid pressure to achieve barrier-free The purpose of sewage and sealing equipment, the application of this principle, completely abandons the multiple failures caused by valve switches and the corresponding operating costs, reduces the associated supporting facilities, reduces the difficulty of work, and reduces related investment. Costs and operating expenses provide a guarantee for the realization of online intelligent operation.

固液分离装置12的混合液出口与缓存罐13相连;缓存罐13的液体出口与在线全自动过滤装置19相连;在线全自动过滤装置19的出液口与积液池20相连;固液分离装置12和缓存罐13的沉降物出口分别与污泥固化装置17相连;污泥固化装置17的液体出口与积液池20相连;污泥固化装置17的固化物出口与废渣回收装置18相连。The mixed liquid outlet of the solid-liquid separation device 12 is connected to the buffer tank 13; the liquid outlet of the buffer tank 13 is connected to the online automatic filtering device 19; the liquid outlet of the online automatic filtering device 19 is connected to the liquid accumulation tank 20; the solid-liquid separation The sediment outlet of the device 12 and the buffer tank 13 are respectively connected to the sludge solidification device 17 ; the liquid outlet of the sludge solidification device 17 is connected to the sump 20 ;

污泥固化装置17的液体出口通过第二液泵16与积液池20相连,将在线全自动过滤装置19和污泥固化装置17排出的吸收液返回积液池20重复利用,即节约了大量的水资源,又减少了废液的二次污染;经污泥固化装置17脱水后的物质进入废渣回收装置18。The liquid outlet of the sludge solidification device 17 is connected to the liquid accumulation tank 20 through the second liquid pump 16, and the absorption liquid discharged from the online automatic filtering device 19 and the sludge solidification device 17 is returned to the liquid accumulation tank 20 for reuse, which saves a lot of money. It also reduces the secondary pollution of the waste liquid; the dehydrated material through the sludge solidification device 17 enters the waste residue recovery device 18 .

固液分离装置12和缓存罐13的沉降物出口分别通过污泥输出装置14与污泥固化装置17相连。The sediment outlets of the solid-liquid separation device 12 and the buffer tank 13 are respectively connected to the sludge solidification device 17 through the sludge output device 14 .

气水分离系统包括气体入口35、净化烟气排出口8、气水分离装置9和液体出口34;气体入口35与排烟管5连通;气体入口35与气水分离装置9一端相连;气水分离装置9的另一端和液体出口34相连;气水分离装置9的上端与净化烟气排出口8连通。The gas-water separation system includes a gas inlet 35, a purified flue gas outlet 8, a gas-water separation device 9 and a liquid outlet 34; the gas inlet 35 is communicated with the exhaust pipe 5; the gas inlet 35 is connected with one end of the gas-water separation device 9; The other end of the separation device 9 is connected with the liquid outlet 34 ; the upper end of the gas-water separation device 9 is connected with the purified flue gas discharge port 8 .

气体入口35通过引风机10与排烟管5连通,将烟气与多物质混合液混合接触后剩余的气体导入气水分离装置9,净化烟气排出口8用于将气水分离后的气体排出。气水分离装置9分离后的固液混合液通过液体出口34进入缓存罐13。The gas inlet 35 is communicated with the exhaust pipe 5 through the induced draft fan 10, and the remaining gas after the mixed contact between the flue gas and the multi-substance mixed liquid is introduced into the gas-water separation device 9, and the purified flue gas outlet 8 is used to separate the gas from the gas and water. discharge. The solid-liquid mixed liquid separated by the gas-water separation device 9 enters the buffer tank 13 through the liquid outlet 34 .

在脱硫、除尘、脱硝、余热回收一体化装备25里,高速、高压烟气与多物质混合吸收液、反应气经文丘里雾化装置在线雾化后,再由带夹层的螺旋通道7强制螺旋旋风均质混合、碰撞、接触与延时的作用下,增大了烟气的分子团与多物质吸收液、气的分子团均质混合、碰撞、接触、化合、吸收、换热的几率,从而创造出余热进一步回收和完全吸收硫化物、硫氧化物、氮氧化物和灰尘的最佳条件。其化学反应机理如下:In the integrated equipment 25 of desulfurization, dust removal, denitration and waste heat recovery, the high-speed, high-pressure flue gas mixed with multi-substance absorbing liquid and reaction gas is atomized online by the Venturi atomization device, and then forced to spiral by the spiral channel 7 with interlayer. Under the action of cyclone homogeneous mixing, collision, contact and delay, the probability of homogeneous mixing, collision, contact, combination, absorption and heat exchange between the molecular clusters of flue gas and multi-substance absorbing liquid and gas is increased. This creates the best conditions for further recovery of waste heat and complete absorption of sulfides, sulfur oxides, nitrogen oxides and dust. The chemical reaction mechanism is as follows:

烟气里的NO在强氧化气体氧化下生成NO2;烟气中CO2、硫化物以及硫氧化物和除一氧化氮外的氮氧化物等均溶于强碱水溶液,经强碱性的多物质混合吸收液吸收后,在强碱性多物质混合液中生成稳定的碳酸盐、硫酸盐和硝酸盐以及络合物被截留下来,而生成的氮气随剩余的气体排出;其过程如下:NO in flue gas is oxidized by strong oxidizing gas to generate NO2; CO2, sulfide and sulfur oxides and nitrogen oxides except nitric oxide in flue gas are all dissolved in strong alkali aqueous solution, and after strong alkali multi-substance After the mixed absorption liquid is absorbed, stable carbonates, sulfates, nitrates and complexes are generated in the strong alkaline multi-substance mixed liquid and are trapped, and the generated nitrogen gas is discharged with the remaining gas; the process is as follows:

在脱硫、除尘、脱硝、余热回收一体化装备25里,在一氧化氮被强氧化气体生成二氧化氮的前提下,烟气里的CO2、硫化物、硫氧化物和氮氧化物与强碱性多物质吸收液、强氧化气体、灰尘里碱性金属氧化物等化合吸收,便会生成碳酸盐、亚硫酸盐、亚硝酸盐、硫酸盐、硝酸盐以及所衍生出来的络合物等物质;这些物质溶于混合液便形成了多物质混合吸收液,即是强极性多物质吸收液,返回到积液池20循环再利用;在混合液里析出的物质则通过固化成为灰渣进行二次利用。In the integrated equipment 25 of desulfurization, dust removal, denitration, and waste heat recovery, under the premise that nitrogen monoxide is converted into nitrogen dioxide by strong oxidizing gas, CO2, sulfide, sulfur oxides and nitrogen oxides in the flue gas are combined with strong alkali. The combined absorption of multi-substance absorption liquid, strong oxidizing gas, alkaline metal oxides in dust, etc., will generate carbonate, sulfite, nitrite, sulfate, nitrate and derived complexes, etc. These substances are dissolved in the mixed liquid to form a multi-substance mixed absorption liquid, that is, a strong polar multi-substance absorption liquid, which is returned to the effusion pool 20 for recycling; the substances precipitated in the mixed liquid are solidified into ash. for secondary use.

发明本专利的现实意义:脱硫、除尘、脱硝、余热回收一体化装备25,摒弃了传统装备的设备多、反应塔设计不合理、易结垢堵塞、风阻大、造价高、占地多、运行费用高、维护难、反应处理效率低等的弊端,提高了整体的运行效率,为发电锅炉以及企业用大、中、小锅炉以及窑炉在线智能化运行创造了的可靠条件,这一革新,突破了传统配套装备的种种弊病,减少了相关配套设施的投入成本,同时也降低了相关运行成本,从根本上解决了烟气排放不达标的难题,达到了节能降耗目的。The practical significance of the invention patent: desulfurization, dust removal, denitration, waste heat recovery integrated equipment25, abandoning the traditional equipment, the unreasonable design of the reaction tower, easy scaling and clogging, large wind resistance, high cost, large land occupation, operation The disadvantages of high cost, difficult maintenance, and low reaction processing efficiency have improved the overall operating efficiency and created reliable conditions for the online intelligent operation of power generation boilers and large, medium and small boilers and kilns used by enterprises. This innovation, It breaks through the shortcomings of traditional supporting equipment, reduces the input cost of related supporting facilities, and also reduces the related operating costs, fundamentally solves the problem of substandard flue gas emissions, and achieves the purpose of energy saving and consumption reduction.

脱硫、除尘、脱硝、余热回收一体化装备25实现了烟气分子团和多物质混合吸收液分子团以及反应气体分子团充分均质混合、碰撞、接触、化合、吸收、延时,延时是为了确保化合反应及吸收完全完成。脱硫、除尘、脱硝、余热回收一体化装备25具备实现完全消除烟气里有害气体的目的,实现消除PM2.5尘埃及以上灰尘的目的,实现烟气余热进一步回收的目的;由于一体化装备结构简单合理,规避了漏气、结垢、堵塞等风险,确保一体化装备连续正常运行,为实现一体化装备及系统在线智能化运行提供了保障。The integrated equipment of desulfurization, dust removal, denitration, and waste heat recovery 25 realizes the fully homogeneous mixing, collision, contact, combination, absorption, and delay of flue gas molecular clusters, multi-substance mixed absorption liquid molecular clusters, and reaction gas molecular clusters. In order to ensure complete completion of the compounding reaction and absorption. The integrated equipment of desulfurization, dust removal, denitrification and waste heat recovery 25 has the purpose of completely eliminating harmful gases in flue gas, eliminating dust above PM2.5 dust, and further recovering waste heat of flue gas; Simple and reasonable, it avoids the risks of air leakage, scaling and blockage, ensures the continuous and normal operation of the integrated equipment, and provides a guarantee for the online intelligent operation of the integrated equipment and system.

综上,该脱硫、除尘、脱硝、余热回收一体化装备及其净化系统应用并不局限于本实用新型的内容;本实用新型的脱硫、除尘、脱硝、余热回收一体化装备的核心理论是:文丘里雾化混合洗涤原理、带夹层的螺旋通道原理、椎体排污管液体密封原理以及带夹层的下返烟式排烟管相结合的构造;本实用新型的脱硫、除尘、脱硝、余热回收一体化装备可以是带夹层的设计,也可以设计成不带夹层的一体化装备;在脱硫、除尘、脱硝、余热回收一体化装备运用过程中,在本领域可以单一使用带夹层的一体化装备,也可以使用不带夹层的一体化装备,更可以根据工艺要求把两个或以上一体化装备串联使用,分别用于一氧化氮氧化、一氧化碳燃烧、换热、除尘的带夹层的一体化然后再串联不带夹层的一体化装备用于脱硫、脱硝、除尘净化;脱硫、除尘、脱硝、余热回收一体化装备在其他领域应用方面,还可以应用于车间、室内除尘、加湿;在水处理领域可以用于前端的污水与絮凝剂的在线混合工艺等;更可以微型化,用于居室除尘、加湿、除味等。To sum up, the desulfurization, dust removal, denitrification, waste heat recovery integrated equipment and its purification system application are not limited to the content of the present utility model; the core theory of the present utility model desulfurization, dust removal, denitrification, and waste heat recovery integrated equipment is: Venturi atomization mixed washing principle, spiral channel principle with interlayer, liquid sealing principle of vertebral body sewage pipe and lower return smoke exhaust pipe with interlayer combined structure; desulfurization, dust removal, denitration, waste heat recovery of the utility model The integrated equipment can be designed with an interlayer, or can be designed as an integrated equipment without an interlayer; in the application of the integrated equipment for desulfurization, dust removal, denitrification, and waste heat recovery, the integrated equipment with an interlayer can be used alone in this field. , you can also use integrated equipment without interlayer, and you can use two or more integrated equipment in series according to process requirements, which are respectively used for nitric oxide oxidation, carbon monoxide combustion, heat exchange, and dust removal. The integrated equipment without interlayer is connected in series for desulfurization, denitration, dust removal and purification; the integrated equipment of desulfurization, dust removal, denitrification and waste heat recovery can be applied in other fields, and can also be used in workshops, indoor dust removal and humidification; in the field of water treatment It can be used for the online mixing process of sewage and flocculants at the front end, etc.; it can be miniaturized for dust removal, humidification, deodorization, etc.

前述对本实用新型的具体示例性实施方案的描述是为了说明和例证的目的。这些描述并非想将本实用新型限定为所公开的精确形式,并且很显然,根据上述教导,可以进行很多改变和变化。对示例性实施例进行选择和描述的目的在于解释本实用新型的特定原理及其实际应用,从而使得本领域的技术人员能够实现并利用本实用新型的各种不同的示例性实施方案以及各种不同的选择和改变。本实用新型的范围意在由权利要求书及其等同形式所限定。The foregoing descriptions of specific exemplary embodiments of the present invention have been presented for purposes of illustration and description. These descriptions are not intended to limit the invention to the precise form disclosed, and obviously many changes and modifications are possible in light of the above teachings. The exemplary embodiments were chosen and described for the purpose of explaining certain principles of the invention and its practical applications, to thereby enable those skilled in the art to make and utilize various exemplary embodiments of the invention and various Different choices and changes. The scope of the present invention is intended to be defined by the claims and their equivalents.

Claims (9)

1.一种脱硫、除尘、脱硝、余热回收一体化装备,其特征在于:该脱硫、除尘、脱硝、余热回收一体化装备包括文丘里雾化装置、本体、至少一个气液补充孔、换热介质进管、换热介质出管、排烟管、螺旋板和排污管;所述的文丘里雾化装置包括进烟管、多物质混合吸收液进口、反应气进口、文丘里雾化器、雾化入口和雾化出口;所述的进烟管、多物质混合吸收液进口和反应气进口置于所述的文丘里雾化装置前端;所述的进烟管的后端、多物质混合吸收液进口的后端和反应气进口的后端分别与所述的雾化入口前端相连;所述的文丘里雾化入口的后端与所述的文丘里雾化器相连;所述的文丘里雾化器的后端与所述的雾化出口相连;所述的雾化出口与所述的本体的上端连通;所述的本体的下端与所述的排污管相连;所述的换热介质进管与本体的下端外壁连通;所述的换热介质出管与本体的上端外壁连通;所述的排烟管置于所述的本体的中部;所述的排烟管的下端与所述的排污管相连;所述的排烟管的上端从本体的上方伸出;所述的螺旋板置于所述的本体的侧壁内与所述的排烟管外壁之间;所述的气液补充孔开在所述的本体的侧面与所述的螺旋板之间构成的螺旋通道连通。1. a desulfurization, dust removal, denitration, waste heat recovery integrated equipment, it is characterized in that: this desulfurization, dust removal, denitration, waste heat recovery integrated equipment comprises a venturi atomization device, a body, at least one gas-liquid supplementary hole, heat exchange Medium inlet pipe, heat exchange medium outlet pipe, smoke exhaust pipe, spiral plate and sewage pipe; the venturi atomization device includes a smoke inlet pipe, a multi-substance mixed absorption liquid inlet, a reaction gas inlet, a Venturi atomizer, The atomization inlet and the atomization outlet; the smoke inlet pipe, the multi-substance mixed absorption liquid inlet and the reaction gas inlet are placed at the front end of the venturi atomization device; the rear end of the smoke inlet pipe, the multi-substance mixture The rear end of the absorption liquid inlet and the rear end of the reaction gas inlet are respectively connected with the front end of the atomization inlet; the rear end of the venturi atomization inlet is connected with the venturi atomizer; the venturi The rear end of the inner atomizer is connected with the atomization outlet; the atomization outlet is communicated with the upper end of the main body; the lower end of the main body is connected with the sewage pipe; the heat exchange The medium inlet pipe is communicated with the lower end outer wall of the body; the heat exchange medium outlet pipe is communicated with the upper end outer wall of the body; the smoke exhaust pipe is placed in the middle of the body; the lower end of the smoke exhaust pipe is connected to the outer wall of the upper end of the body; the upper end of the smoke exhaust pipe protrudes from the top of the main body; the spiral plate is placed between the side wall of the main body and the outer wall of the smoke exhaust pipe; the The gas-liquid replenishing hole is opened in the spiral channel formed between the side surface of the main body and the spiral plate. 2.根据权利要求1所述的脱硫、除尘、脱硝、余热回收一体化装备,其特征在于:所述的多物质混合吸收液进口、反应气进口均为喷嘴;所述的雾化出口的后端沿切线方向与本体的上端连通。2. The integrated equipment for desulfurization, dust removal, denitration and waste heat recovery according to claim 1, characterized in that: the inlet of the multi-substance mixed absorption liquid and the inlet of the reaction gas are both nozzles; The end communicates with the upper end of the body along the tangential direction. 3.根据权利要求1所述的脱硫、除尘、脱硝、余热回收一体化装备,其特征在于:所述的排烟管为下返烟式排烟管;所述的排烟管、螺旋板及所述的本体均设置有夹层;所述的夹层之间互通;所述的夹层内装有换热介质;所述的排污管为水封式椎体排污管。3. The integrated equipment for desulfurization, dust removal, denitration and waste heat recovery according to claim 1, characterized in that: the smoke exhaust pipe is a bottom-returning smoke exhaust pipe; the smoke exhaust pipe, the spiral plate and the The bodies are all provided with interlayers; the interlayers communicate with each other; the interlayers are provided with a heat exchange medium; the sewage pipes are water-sealed vertebral sewage pipes. 4.一种脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:该净化系统包括权利要求1-3任一所述的脱硫、除尘、脱硝、余热回收一体化装备;还包括换热除尘装置、气水分离系统、固液分离系统和多物质混合吸收液系统;所述的换热除尘装置后端与所述的进烟管前端连接;所述的气水分离系统与排烟管的后端相连;所述的固液分离系统与所述的排污管相连;所述的多物质混合吸收液系统的出口端与所述的多物质混合吸收液进口相连。所述的多物质混合吸收液系统包括补水管、吸收液输送管、混合罐和积液池;所述的补水管和所述的吸收液输送管分别与所述的混合罐相连;所述的混合罐的出口与所述的积液池相连;所述的积液池与所述的多物质混合吸收液进口相连。4. A purification system of desulfurization, dust removal, denitration, and waste heat recovery integrated equipment, characterized in that: the purification system comprises the desulfurization, dust removal, denitration, and waste heat recovery integrated equipment described in any one of claims 1-3; and It includes a heat exchange and dust removal device, a gas-water separation system, a solid-liquid separation system and a multi-substance mixed absorption liquid system; the rear end of the heat exchange and dust removal device is connected to the front end of the smoke inlet pipe; the gas-water separation system is connected to the The rear end of the exhaust pipe is connected; the solid-liquid separation system is connected with the sewage pipe; the outlet end of the multi-substance mixed absorption liquid system is connected with the multi-substance mixed absorption liquid inlet. The multi-substance mixed absorption liquid system includes a water replenishing pipe, an absorption liquid conveying pipe, a mixing tank and a liquid accumulation pool; the water replenishing pipe and the absorption liquid conveying pipe are respectively connected with the mixing tank; the The outlet of the mixing tank is connected with the liquid accumulation pool; the liquid accumulation pool is connected with the inlet of the multi-substance mixed absorption liquid. 5.根据权利要求4所述的脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:所述的积液池通过第一液泵与所述的多物质混合吸收液进口相连。5. The purification system of integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery according to claim 4, characterized in that: the liquid accumulation tank is connected to the inlet of the multi-substance mixed absorption liquid through the first liquid pump . 6.根据权利要求4所述的脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:所述的固液分离系统包括固液分离装置、缓存罐、在线全自动过滤装置、污泥固化装置和废渣回收装置;所述的固液分离装置安装于所述的排污管下端;所述的固液分离装置的混合液出口与所述的缓存罐相连;所述的缓存罐的液体出口与所述的在线全自动过滤装置相连;所述的在线全自动过滤装置的出液口与所述的积液池相连;所述的固液分离装置和所述的缓存罐的沉降物出口分别与所述的污泥固化装置相连;所述的污泥固化装置的液体出口与所述的积液池相连;所述的污泥固化装置的固化物出口与所述的废渣回收装置相连。6. The purification system of integrated equipment for desulfurization, dust removal, denitration and waste heat recovery according to claim 4, characterized in that: the solid-liquid separation system comprises a solid-liquid separation device, a buffer tank, an online automatic filter device, a sludge solidification device and a waste residue recovery device; the solid-liquid separation device is installed at the lower end of the sewage pipe; the mixed liquid outlet of the solid-liquid separation device is connected to the buffer tank; The liquid outlet is connected with the online automatic filtering device; the liquid outlet of the online automatic filtering device is connected with the liquid accumulation pool; the solid-liquid separation device and the sediment in the buffer tank The outlets are respectively connected with the sludge solidification device; the liquid outlet of the sludge solidification device is connected with the liquid accumulation tank; the solidified product outlet of the sludge solidification device is connected with the waste residue recovery device . 7.根据权利要求6所述的脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:所述的所述的污泥固化装置的液体出口通过第二液泵与所述的积液池相连;所述的固液分离装置和所述的缓存罐的沉降物出口分别通过污泥输出装置与所述的污泥固化装置相连。7. The purification system of integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery according to claim 6, characterized in that: the liquid outlet of the sludge solidification device communicates with the sludge solidification device through the second liquid pump. The liquid accumulation tank is connected; the solid-liquid separation device and the sediment outlet of the buffer tank are respectively connected with the sludge solidification device through the sludge output device. 8.根据权利要求4所述的脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:所述的气水分离系统包括气体入口、净化烟气排出口、气水分离装置和液体出口;所述的气体入口与所述的排烟管连通;所述的气体入口与所述的气水分离装置一端相连;所述的气水分离装置的另一端和液体出口相连;所述的气水分离装置的上端与所述的净化烟气排出口连通。8. The purification system of integrated equipment for desulfurization, dust removal, denitration and waste heat recovery according to claim 4, characterized in that: the gas-water separation system comprises a gas inlet, a purified flue gas outlet, a gas-water separation device and a the liquid outlet; the gas inlet is communicated with the smoke exhaust pipe; the gas inlet is connected with one end of the gas-water separation device; the other end of the gas-water separation device is connected with the liquid outlet; the The upper end of the gas-water separation device is communicated with the purified flue gas discharge port. 9.根据权利要求8所述的脱硫、除尘、脱硝、余热回收一体化装备的净化系统,其特征在于:所述的气体入口通过引风机与所述的排烟管连通。9 . The purification system of integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery according to claim 8 , wherein the gas inlet is communicated with the exhaust pipe through an induced draft fan. 10 .
CN201922295040.4U 2019-12-19 2019-12-19 Integrated equipment for desulfurization, dust removal, denitrification and waste heat recovery and its purification system Expired - Fee Related CN212068317U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110772963A (en) * 2019-12-19 2020-02-11 哈尔滨中科天德节能环保科技有限公司 Desulfurization, dust removal, denitration, waste heat recovery integration are equipped and clean system thereof
CN113117459A (en) * 2021-06-17 2021-07-16 中国恩菲工程技术有限公司 Tail gas washing system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110772963A (en) * 2019-12-19 2020-02-11 哈尔滨中科天德节能环保科技有限公司 Desulfurization, dust removal, denitration, waste heat recovery integration are equipped and clean system thereof
CN110772963B (en) * 2019-12-19 2024-08-06 哈尔滨中科天德节能环保科技有限公司 Desulfurization, dust removal, denitration and waste heat recovery integrated equipment and purification system thereof
CN113117459A (en) * 2021-06-17 2021-07-16 中国恩菲工程技术有限公司 Tail gas washing system

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