CN212051190U - Organic solvent purification device - Google Patents
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- CN212051190U CN212051190U CN201921105538.3U CN201921105538U CN212051190U CN 212051190 U CN212051190 U CN 212051190U CN 201921105538 U CN201921105538 U CN 201921105538U CN 212051190 U CN212051190 U CN 212051190U
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Abstract
The utility model relates to an organic solvent purification device, which mainly solves the problems of longer process flow, higher equipment investment and energy consumption in the prior art, and adopts an organic solvent purification device comprising a rectifying tower, a first reboiler, a second reboiler, a first condenser, a second condenser and a third condenser; the method is characterized in that at least a first clapboard, a second clapboard and a third clapboard are arranged in the rectifying tower; a first channel is formed between the first partition plate and the tower wall, a second channel is formed between the first partition plate and the second partition plate, a third channel is formed between the second partition plate and the third partition plate, and a fourth channel is formed between the fourth partition plate and the tower wall; the first partition board enables the first channel to be provided with a single tower top, the fourth partition board enables the fourth channel to be provided with a single tower top, and the first partition board and the fourth partition board enable the second channel and the third channel to be provided with a common tower top.
Description
Technical Field
The utility model relates to an organic solvent purification device, especially a dimethyl sulfoxide purification device.
Technical Field
Solvent recovery is an important production unit within carbon fiber plants. Dimethyl sulfoxide recycled by the industrial device accounts for more than 90% of the total amount of the solvent demand, and directly influences the production cost, so the PAN protofilament device must be matched with a solvent recovery facility.
The solvent recovery usually adopts the vacuum rectification operation, the energy consumption is high, and the consumption of heating steam and circulating cooling water of the unit is far higher than that of other units, so the method is also an important link for saving energy and reducing consumption in the carbon fiber device. According to the production practice of carbon fibers, dimethyl sulfoxide suitable for the polymerization production of carbon fibers has higher requirements on reducing impurities, transmittance and metal ions.
In industrial production, the dimethyl sulfoxide solvent recovery mostly adopts a multi-tower continuous rectification process, and the process is divided into four working procedures of pretreatment, dehydration, refining and post-treatment and is provided with an auxiliary vacuum system. The main purposes of pretreatment are polymer removal and deacidification; the dehydration unit is mainly used for separating water from the dimethyl sulfoxide waste liquid, the dimethyl sulfoxide content in water is required to be far lower than 1%, and the industrial discharge requirement is met; the refining unit is mainly used for obtaining high-concentration dimethyl sulfoxide as a final product, and the requirement of solvent recycling in the carbon fiber production process is met.
Chinese patent CN107459472 proposes to remove the polymer first, the treated raw material is dehydrated by vacuum rectification, and the dehydrated material is subjected to vacuum rectification to obtain a high-concentration dimethyl sulfoxide product. The process has the advantages of long flow, complex operation and high energy consumption, and the dimethyl sulfoxide obtained by the process has purity and metal ion content reaching the dimethyl sulfoxide recycling standard, but light transmittance is not considered, so that the dimethyl sulfoxide suitable for carbon fiber polymerization production has high requirements on reducing impurities and metal ions and strict requirements on light transmittance.
Chinese patent CN102225904 provides a device for recovering and refining dimethyl sulfoxide and a separation method thereof, comprising a first-stage dehydration tower, a wiped film evaporator, a primary distillation intermediate tank, a second-stage dehydration tower and a DMSO refining tower, wherein the first-stage dehydration tower is connected with the primary distillation intermediate tank, the wiped film evaporator is connected with the primary distillation intermediate tank, and then the second-stage dehydration tower and the DMSO refining tower are sequentially connected. The dimethyl sulfoxide raw material is divided into two strands, the low-concentration DMSO raw material does not contain high polymers, the DMSO content is 2.0% -15.0%, the dimethyl sulfoxide raw material directly enters a first-stage dehydration tower, and most of water in the raw material is removed; the high-concentration DMSO raw material contains high polymer, the DMSO content is 22.0-50.0%, the high polymer is removed by a wiped film evaporator, then the high polymer and the dehydrated low-concentration raw material enter a secondary dehydration tower together, and the dehydrated raw material is subjected to reduced pressure rectification and refining again to obtain the high-concentration dimethyl sulfoxide.
Chinese patent 104119256 proposes a method for purifying dimethyl sulfoxide, which comprises the steps of: feeding the raw material containing dimethyl sulfoxide into a first evaporator for heating, carrying out vapor-liquid separation after partial evaporation, and feeding the obtained vapor phase into a rectifying tower; inputting the obtained liquid phase into a second evaporator for heating, performing vapor-liquid separation after partial evaporation, inputting the obtained vapor phase into a rectifying tower, and inputting the obtained liquid phase into a wiped film evaporator; collecting a dimethyl sulfoxide crude product at the tower bottom of the rectifying tower, inputting the dimethyl sulfoxide crude product into a third evaporator for heating, carrying out vapor-liquid separation after partial evaporation, inputting the obtained liquid phase into a wiped film evaporator, and returning the obtained vapor phase to the rectifying tower as a feed; and heating the third evaporator, partially evaporating, separating vapor from liquid, and returning the vapor phase obtained by vapor-liquid separation to the first evaporator as a heating medium, and condensing to obtain purified dimethyl sulfoxide.
Chinese patent CN104891591B proposes a method for recycling dimethyl sulfoxide, which comprises the steps of enabling waste water containing 0.5-1% of acrylonitrile and 1-5% of dimethyl sulfoxide to enter an acrylonitrile removing tower, firstly removing acrylonitrile in the water under reduced pressure for quality separation treatment, removing water from the waste water in the tower bottom through a dimethyl sulfoxide concentrating tower and a crude product tower under reduced pressure to enable the content of the dimethyl sulfoxide to reach 99%, and then performing reduced pressure rectification through a refining tower to obtain the dimethyl sulfoxide with the purity of more than 99.97%.
Chinese patent CN106674066 proposes a dimethyl sulfoxide purification method, which comprises the following steps: 1) deacidifying and dewatering; 2) carrying out reduced pressure distillation; 3) carrying out first melting crystallization; 4) and (4) carrying out second melting crystallization. The purity of the dimethyl sulfoxide obtained by the steps is more than or equal to 99.99 percent, and the yield is higher by about 85 percent.
The above patents have common problems that: the process flow is longer, the energy consumption is higher, and the transmittance of the obtained product is not described.
Chinese patent CN107459472 proposes to obtain chromatographic grade dimethyl sulfoxide by using the following steps: (1) mixing and stirring raw materials of dimethyl sulfoxide and activated alumina, (2) distilling the adsorbed dimethyl sulfoxide and calcium hydride under reduced pressure, wherein the distillation pressure is 12mmHg, and the distillation temperature is about 70-90 ℃, so that the dimethyl sulfoxide is dehydrated and dried; (3) and storing the distillate in a storage tank filled with a 4A molecular sieve to obtain the chromatographic grade dimethyl sulfoxide. Obviously, the technology is used for preparing chromatographic grade dimethyl sulfoxide on the basis of obtaining high-concentration dimethyl sulfoxide, and is not suitable for recovering dimethyl sulfoxide waste liquid in carbon fiber production.
Chinese patent CN 107362568 proposes a solvent recovery method in carbon fiber production, which utilizes a vacuum rectification tower, wherein the upper section in the tower is filled with filler, and the lower section is a tower plate. Obtaining dimethyl sulfoxide products after decompression and rectification. It is clear that it is possible to obtain high concentrations of dimethyl sulfoxide from the bottom of the column obtained by means of a vacuum distillation column, which have the disadvantages of metal ion content and color intensity, and of the fact that heavy-end impurities cannot be removed.
Chinese patent CN1887864 proposes that metal ions in dimethyl sulfoxide are removed by using the principle of ion exchange, iron ions in sulfoxide are removed by using macroporous weakly-basic anion exchange resin, and calcium, magnesium, sodium and potassium ions in dimethyl sulfoxide are removed by using macroporous strongly-acidic cation exchange resin. Although the method can remove metal ions in sulfoxide, the influence of acrylonitrile polymer on the adsorption process is not considered, and the method is limited by the adsorption capacity, so that solid waste is inevitably generated, and the solid waste treatment is easy to cause secondary pollution.
SUMMERY OF THE UTILITY MODEL
The utility model discloses the technical problem who wants to solve is that although prior art has to organic solvent waste liquid, especially dimethyl sulfoxide waste liquid recycle technology, but the process flow is longer, the higher problem of equipment investment and energy consumption, the utility model provides an organic solvent purification device, the device have equipment simple process, and the energy consumption is low, the efficient advantage of desorption.
For solving one of the above technical problems, the utility model discloses a technical scheme be: an organic solvent purification device comprises a rectifying tower 1, a first reboiler 2, a second reboiler 3, a first condenser 6, a second condenser 7 and a third condenser 8; the method is characterized in that at least a first partition board 9, a second partition board 10 and a third partition board 11 are arranged in the rectifying tower 1; a first channel is formed between the first partition plate and the tower wall, a second channel is formed between the first partition plate and the second partition plate, a third channel is formed between the second partition plate and the third partition plate, and a fourth channel is formed between the fourth partition plate and the tower wall; wherein the first partition enables the first channel to have a single overhead, the fourth partition enables the fourth channel to have a single overhead, and the first partition and the fourth partition enable the second channel and the third channel to have a common overhead; the first channel, the second channel, the third channel and the fourth channel are respectively provided with mutually independent common tower kettles by the second partition plate; a first channel and second channel common tower kettle is connected with a first reboiler 2 through a first circulating pump 4, a third channel and fourth channel common tower kettle is connected with a second reboiler 3 through a second circulating pump 5, the top of the first channel is connected with a first condenser 6, the top of the second channel and third channel common tower is connected with a second condenser 7, and the top of the fourth channel common tower is connected with a third condenser 8.
In the technical scheme, the proportion range of the sectional area of each channel in the sectional area of the rectifying tower is independently and preferably 10-90%.
In the above technical solution, a first gas-liquid contacting inner member 12 is disposed in the first passage.
In the above-mentioned solution, the first gas-liquid contacting internals are preferably selected from trays or packing; it is further preferred that the number of plates of the trays is preferably 15 to 35 or the theoretical number of plates of the packing is preferably 15 to 35.
In the above technical solution, a second gas-liquid contact internal member 13 is disposed in the second passage.
In the above-mentioned embodiment, the second gas-liquid contacting internals are preferably selected from trays or packing; it is further preferred that the number of plates of the trays is preferably 15 to 35 or the theoretical number of plates of the packing is preferably 15 to 35.
In the above technical solution, a third gas-liquid contact internal member 14 is disposed in the third passage.
In the above-mentioned embodiment, the third gas-liquid contacting internal member is preferably selected from a tray or a packing; it is further preferred that the number of plates of the trays is preferably 15 to 35 or the theoretical number of plates of the packing is preferably 15 to 35.
In the above technical solution, a fourth gas-liquid contacting inner member 15 is disposed in the fourth channel.
In the above-mentioned embodiment, the fourth gas-liquid contacting internals are preferably selected from trays or packing; it is further preferred that the number of plates of the trays is preferably 15 to 35 or the theoretical number of plates of the packing is preferably 15 to 35.
In the above technical solution, the organic solvent may be an organic solvent in various organic solvent waste liquids, particularly an organic solvent in an organic solvent waste liquid generated in carbon fiber production, for example, but not limited to dimethyl sulfoxide, dimethylformamide, dimethylacetamide, and the like, and dimethyl sulfoxide is preferred.
The utility model discloses a use method of organic solvent purification device can include following step:
1) introducing the organic solvent waste liquid (A) into a first channel of a rectifying tower, obtaining a qualified light component (B) at the top of the first channel tower, and obtaining tower bottom liquid containing the organic solvent with the concentration not lower than 80% at the tower bottom of the first channel tower according to the mass percentage;
2) evaporating the tower bottom liquid obtained in the step 1) through a first reboiler, evaporating part of steam to the top of the tower through a first channel, condensing the steam through a first condenser, extracting one part of steam serving as qualified light component (B), and refluxing one part of steam; the other part of the steam reaches the top of the common tower of the second channel and the third channel through the second channel, is condensed through a second condenser and is redistributed to the second channel and the third channel in a reflux mode;
3) the redistributed organic solvent solution passes through a third channel, and an organic solvent solution with the organic solvent concentration not lower than 99.5 percent is obtained in a tower kettle shared by the third channel and a fourth channel according to the mass percentage;
4) evaporating the organic solvent solution obtained in the step 3) by a second reboiler, allowing part of the organic solvent solution to pass through a third channel, allowing the other part of the organic solvent solution to pass through a fourth channel, condensing the organic solvent solution by a third condenser, allowing part of the organic solvent solution to be used as reflux, and collecting part of the organic solvent solution serving as a final organic solvent product (C).
In the technical scheme, the proportion of the steam evaporated to the first channel and the second channel in the step 2) is preferably in direct proportion to the cross section area of the channels, and the proportion value is 1/10-9/10.
In the above technical solution, the distribution ratio of the organic solvent solution condensed in step 2) redistributed to the second channel and the third channel in a reflux manner is preferably proportional to the channel cross-sectional area, and the ratio is 1/10-9/10.
In the technical scheme, the proportion of the steam evaporated to the third channel and the fourth channel in the step 3) is preferably in direct proportion to the cross section area of the channels, and the proportion value is 1/10-9/10.
In the above technical solution, in the step 2), the evaporation conditions of the distillation column shared by the first channel and the second channel are preferably: the operation pressure is 1KPa to 100KPa, and the operation temperature is 30 ℃ to 160 ℃.
In the above technical solution, in the step 3), the evaporation conditions of the distillation column shared by the third channel and the fourth channel are preferably: the operation pressure is 1KPa to 100KPa, and the operation temperature is 30 ℃ to 160 ℃.
In the above technical scheme, the reflux ratio in the step 1) and the step 4) is independently preferably selected from 0.1-10.
In the above technical solution, the organic solvent may be any one of dimethylformamide, dimethylacetamide and dimethylsulfoxide; further preferably dimethyl sulfoxide, wherein the tower top temperature of the first channel is preferably 10-50 ℃, the tower top temperature of the second channel and the third channel is preferably 20-90 ℃, and the tower top temperature of the fourth channel is preferably 50-100 ℃.
Adopt the technical scheme of the utility model, through the organic solvent purification device that sets up, a tower has replaced three tower process flows of tradition, has saved reboiler and condenser simultaneously except that process flow simplifies greatly to greatly reduced energy consumption has gained better technological effect.
Drawings
FIG. 1 shows the process of the present invention.
In the figure, 1 is a four-channel rectifying column, 2 is a first reboiler, 3 is a second reboiler, 4 is a first circulation pump, 5 is a second circulation pump, 6 is a first condenser, 7 is a second condenser, 8 is a third condenser, 9 is a first partition, 10 is a second partition, 11 is a third partition, 12 is a first gas-liquid contact internal, 13 is a second gas-liquid contact internal, 14 is a third gas-liquid contact internal, and 15 is a fourth gas-liquid contact internal.
A is organic solvent waste liquid, B is qualified light component, C is organic solvent product, D is residual liquid, E is first channel backflow, F is second channel backflow, G is third channel backflow, and H is fourth channel backflow.
FIG. 2 shows a rectifying column used in comparative example 1, in which a partition is provided in the middle.
FIG. 3 shows a rectification column used in comparative example 2, with two baffles in the middle, the gas and liquid in the column contacting the trays of internals.
FIG. 4 shows a rectification column used in comparative example 3, in which three baffles are located in the middle and the gas-liquid contact the trays of the internals.
The following description will further describe the embodiments of the present invention with reference to the drawings.
Detailed Description
The following is a detailed description of embodiments of the invention: the present embodiment is implemented on the premise of the technical solution of the present invention, and detailed embodiments and processes are given, but the scope of the present invention is not limited to the following embodiments, and the process parameters of specific conditions not noted in the following embodiments are generally in accordance with conventional conditions.
[ example 1 ]
According to the apparatus of FIG. 1, the gas-liquid inside the column contacts the trays of the internals, the number of trays is 30, and the specific operating parameters of the column are: the pressure of the tower is controlled at 1KPa, wherein the temperature of the first tower kettle is controlled at 75 ℃, the temperature of the second tower kettle is controlled at 92 ℃, the temperature of the top of the first channel is controlled at 25 ℃, the temperature of the top of the second channel and the third channel which share the same tower is controlled at 39 ℃, the temperature of the top of the fourth channel is controlled at 63 ℃, the reflux ratio of the first channel is 4, and the reflux ratio of the fourth channel is 0.3.
The weight percent composition, light transmittance, process parameters, and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in tables 1.1 and 1.2.
TABLE 1.1
TABLE 1.2
[ example 2 ]
According to the apparatus of FIG. 1, the gas-liquid inside the column contacts the trays of the internals, the number of trays is 25, and the specific operating parameters of the column are: the pressure of the tower is controlled at 6KPa, wherein the temperature of the first tower kettle is controlled at 80 ℃, the temperature of the second tower kettle is controlled at 107 ℃, the temperature of the top of the first channel is controlled at 28 ℃, the common top of the second channel and the third channel is controlled at 43 ℃, the top of the fourth channel is controlled at 68 ℃, the reflux ratio of the first channel is 5, and the reflux ratio of the fourth channel is 1.
The weight percent composition, transmittance, process parameters and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in tables 2.1 and 2.2
TABLE 2.1
TABLE 2.2
[ example 3 ]
According to the apparatus of FIG. 1, the gas-liquid inside the column contacts the trays of the internals, the number of trays is 25, and the specific operating parameters of the column are: the pressure of the tower is controlled at 9KPa, wherein the temperature of the first tower kettle is controlled at 85 ℃, the temperature of the second tower kettle is controlled at 117 ℃, the temperature of the top of the first channel is controlled at 31 ℃, the common top of the second channel and the third channel is controlled at 20 ℃, the top of the fourth channel is controlled at 75 ℃, the reflux ratio of the first channel is 2, and the reflux ratio of the fourth channel is 0.5.
The weight percent composition, transmittance, process parameters, and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in tables 3.1 and 3.2
TABLE 3.1
TABLE 3.2
[ example 4 ]
According to the apparatus of FIG. 1, the gas-liquid inside the column contacts the trays of the internals, the number of trays is 25, and the specific operating parameters of the column are: the pressure of the tower is controlled at 22KPa, wherein the temperature of the first tower kettle is controlled at 124 ℃, the temperature of the second tower kettle is controlled at 142 ℃, the temperature of the first channel tower top is controlled at 48 ℃, the temperature of the second channel tower top and the third channel tower top are controlled at 64 ℃, the temperature of the fourth channel tower top is controlled at 95 ℃, the reflux ratio of the first channel is 5, and the reflux ratio of the fourth channel is 1.5.
The weight percent composition, transmittance, process parameters and dimethylsulfoxide yields of the raw materials and the individual stream components used in this example are shown in tables 4.1 and 4.2
TABLE 4.1
TABLE 4.2
Comparative example 1
The comparative example is the rectifying tower of fig. 2, a baffle is arranged in the tower, the baffle is positioned in the middle, gas and liquid in the tower contact internal member tower plates, the number of the tower plates is 30, and the specific operating parameters of the tower are as follows: the pressure of the tower is controlled at 1KPa, wherein the temperature of the kettle of the tower is controlled at 92 ℃, the temperature of the top of the tower is controlled at 63 ℃, and the reflux ratio is 4.
The weight percent composition, light transmittance, process parameters, and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in table 5.
TABLE 5
Comparative example 2
The comparative example is the rectification column of fig. 3, with two baffles in the middle, gas-liquid contact internals trays in the column, the number of trays being 30, the specific operating parameters of the column being: the pressure of the tower is controlled at 1KPa, wherein the temperature of the kettle of the tower is controlled at 92 ℃, the temperature of the top of the tower is controlled at 63 ℃, and the reflux ratio is 4.
The weight percent composition, light transmittance, process parameters, and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in table 6.
TABLE 6
Comparative example 3
The comparative example is the rectification column of fig. 4, with three baffles in the middle, the gas and liquid in the column contacting the trays of the internals, the number of trays being 30, the specific operating parameters of the column being: the pressure of the tower is controlled at 1KPa, wherein the temperature of the kettle of the tower is controlled at 92 ℃, the temperature of the top of the tower is controlled at 63 ℃, and the reflux ratio is 4.
The weight percent composition, light transmittance, process parameters, and dimethyl sulfoxide yield of the raw materials and components of each stream used in this example are shown in table 7.
TABLE 7
It can be seen from the above comparative example that the position of the partition board has a great influence on the purity of the product of the rectifying tower, and the suspended partition board in the comparative example may cause the mixing of the pure components at the top or bottom of the tower, so that the product is difficult to achieve a high purity (not less than 99.5%).
The analytical results of dimethyl sulfoxide used in the polymerization of carbon fibers and dimethyl sulfoxide obtained by the process were compared, as shown in Table 8
TABLE 8
| Item | Index of commercial DMSO raw Material | Example 1 | Example 2 | Example 3 | Example 4 |
| Water (%) | 0.09 | 0.05 | 0.04 | 0.04 | 0.04 |
| DMSO(％) | 99.88 | 99.95 | 99.96 | 99.96 | 99.96 |
| Polymer (%) | Not detected out | Not detected out | Not detected out | Not detected out | Not detected out |
| Acrylonitrile (%) | Not detected out | Not detected out | Not detected out | Not detected out | Not detected out |
| Na ion (μ g/g) | 0.09 | 0.12 | 0.05 | 0.09 | 0.11 |
| K ion (μ g/g) | 0.03 | 0.02 | 0.01 | 0.01 | 0.04 |
| Ca ion (μ g/g) | 0.21 | 0.07 | 0.03 | 0.09 | 0.03 |
| Mg ion (μ g/g) | 0.06 | 0.01 | 0.01 | 0.01 | 0.02 |
| Fe ion (μ g/g) | 0.06 | 0.03 | 0.01 | 0.02 | 0.01 |
| Transmittance at 400nm (%) | 96 | 99.8 | 99.8 | 99.7 | 99.6 |
In conclusion, can see by the data of table 8, organic solvent recovery unit and method, especially be arranged in dimethyl sulfoxide recovery process, can effectively retrieve the dimethyl sulfoxide waste liquid that produces in the carbon fiber production process (including but not limited to dimethyl sulfoxide solvent for the polymerization, polymeric kettle wash kettle liquid, coagulation bath sulfoxide waste liquid etc.), each item index of dimethyl sulfoxide of recovery is equivalent to or is superior to commodity dimethyl sulfoxide, compare with similar technology, process flow is simple, the dimethyl sulfoxide luminousness after the refining is very high, this is that similar patent does not reach or does not have the report. The utility model discloses effectual recovery dimethyl sulfoxide has reduced manufacturing cost, and simultaneously, the water of retrieving can cyclic utilization, has reduced the pollution to the environment.
Claims (14)
1. An organic solvent purification device comprises a rectifying tower (1), a first reboiler (2), a second reboiler (3), a first condenser (6), a second condenser (7) and a third condenser (8); the device is characterized in that at least a first clapboard (9), a second clapboard (10) and a third clapboard (11) are arranged in the rectifying tower (1); a first channel is formed between the first partition plate and the tower wall, a second channel is formed between the first partition plate and the second partition plate, a third channel is formed between the second partition plate and the third partition plate, and a fourth channel is formed between the fourth partition plate and the tower wall; wherein the first partition enables the first channel to have a single overhead, the fourth partition enables the fourth channel to have a single overhead, and the first partition and the fourth partition enable the second channel and the third channel to have a common overhead; the first channel, the second channel, the third channel and the fourth channel are respectively provided with mutually independent common tower kettles by the second partition plate; a first channel and a second channel common tower kettle are connected with a first reboiler (2) through a first circulating pump (4), a third channel and a fourth channel common tower kettle are connected with a second reboiler (3) through a second circulating pump (5), a first condenser (6) is connected to the top of the first channel, a second condenser (7) is connected to the top of the second channel and the third channel common tower, and a third condenser (8) is connected to the top of the fourth channel common tower.
2. The organic solvent purification apparatus as claimed in claim 1, wherein the ratio of the sectional area of each channel to the sectional area of the distillation column is independently selected from the range of 10% to 70%.
3. An organic solvent purification apparatus according to claim 1, characterized in that a first gas-liquid contacting internal member (12) is provided in the first passage.
4. The organic solvent purification apparatus according to claim 3, wherein the first gas-liquid contacting internals are selected from trays or packing.
5. The organic solvent purification apparatus as claimed in claim 4, wherein the number of the trays is 15 to 35 or the theoretical plate number of the packing is 15 to 35.
6. The organic solvent purification apparatus according to claim 1, wherein a second vapor-liquid contacting inner member (13) is provided in the second passage.
7. The organic solvent purification apparatus according to claim 6, wherein the second vapor-liquid contacting internals are selected from trays or packing.
8. The organic solvent purification apparatus as claimed in claim 7, wherein the number of plates of the plates is 15 to 35 or the number of theoretical plates of the packing is 15 to 35.
9. An organic solvent purification apparatus according to claim 1, wherein a third vapor-liquid contact trim (14) is provided in the third passage.
10. The organic solvent purification apparatus according to claim 9, wherein the third vapor-liquid contacting internals are selected from trays or packing.
11. The organic solvent purification apparatus as recited in claim 10, wherein the number of plates of the plates is 15 to 35 or the number of theoretical plates of the packing is 15 to 35.
12. An organic solvent purification apparatus according to claim 1, characterized in that a fourth gas-liquid contacting internals (15) are arranged in the fourth channel.
13. The organic solvent purification apparatus according to claim 12, wherein the fourth gas-liquid contacting internals are selected from trays or packing.
14. The organic solvent purification apparatus as recited in claim 13, wherein the number of plates of the plates is 15 to 35 or the number of theoretical plates of the packing is 15 to 35.
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| CN201921105538.3U CN212051190U (en) | 2019-07-15 | 2019-07-15 | Organic solvent purification device |
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