CN211921327U - Three-silver temperable three-property gray Low-E glass - Google Patents

Three-silver temperable three-property gray Low-E glass Download PDF

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CN211921327U
CN211921327U CN202020374728.1U CN202020374728U CN211921327U CN 211921327 U CN211921327 U CN 211921327U CN 202020374728 U CN202020374728 U CN 202020374728U CN 211921327 U CN211921327 U CN 211921327U
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layer
rete
film layer
glass
thickness
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史胜全
王印
冉东
李可润
邝良琼
苗晓荣
马满江
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Zhongshan Grandglass Industrial Co ltd
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Zhongshan Grandglass Industrial Co ltd
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Abstract

The application discloses three-silver temperable three-property gray Low-E glass is through compounding first rete ZrO in proper order adjacently from inside to outside on glass substrate2Layer, second film layer Nb2O5Layer, third rete AZO layer, fourth rete Ag layer, fifth rete NiCr layer, sixth rete AZO layer, seventh rete Ag layer, eighth rete NiCr layer, ninth rete AZO layer, tenth rete Ag layer, eleventh rete NiCr layer, twelfth rete AZO layer, thirteenth rete Si3N4Layer, fourteenth film layer ZrO2And the thicknesses of the fourth, fifth, seventh, eighth, tenth and eleventh film layers are respectively set to be 9-12 nm, 1-3 nm, 15-17 nm, 2.5-3.5 nm, 3.5-5.5 nm and 2-4 nm, and the thickness is reasonably setThe design thickness of fourth, fifth, seventh, eighth, tenth, eleventh rete makes the utility model discloses a Low-E glass product outward appearance wholly presents the third nature grey, has increased Low-E glass's artistic effect to guaranteed Low-E glass's no colour difference, improved user's use and experienced.

Description

Three-silver temperable three-property gray Low-E glass
Technical Field
The utility model belongs to the technical field of the glass is made, especially, relate to a three-silver temperable three-property grey Low-E glass.
Background
Glass is an important building material, glass curtain walls are mostly adopted in modern high-rise buildings, along with the continuous development of glass deep processing, the building glass is slowly replaced by original single glass sheet Low-radiation Low-E glass which is energy-saving and environment-friendly, but the existing three-silver Low-E glass cannot reach three-property gray, and the front side and the side surface of the Low-E glass have large color difference, so that the color is inconsistent, the appearance of the glass is influenced, and the use experience of a user is poor.
SUMMERY OF THE UTILITY MODEL
Objects of the invention
In order to overcome the defects, the utility model aims to provide a three-silver temperable three-property gray Low-E glass to solve the technical problems that the prior Low-E glass can not reach three-property gray and has great chromatic aberration in the front and the side, and the appearance of the glass is influenced.
(II) technical scheme
In order to achieve the purpose, the technical scheme provided by the application is as follows:
a three-silver temperable three-property gray Low-E glass, comprising: the glass substrate is compounded with fourteen film layers from inside to outside in sequence, wherein the first film layer, namely the innermost film layer, is ZrO2Layer, the second film layer is Nb2O5The third film layer is an AZO layer, the fourth film layer is an Ag layer, the fifth film layer is a NiCr layer, the sixth film layer is an AZO layer, the seventh film layer is an Ag layer, the eighth film layer is a NiCr layer, the ninth film layer is an AZO layer,the tenth film layer is an Ag layer, the eleventh film layer is a NiCr layer, the twelfth film layer is an AZO layer, and the thirteenth film layer is Si3N4Layer, fourteenth film layer ZrO2The thickness of the fourth film layer Ag layer is 9-12 nm, the thickness of the fifth film layer NiCr layer is 1-3 nm, the thickness of the seventh film layer Ag layer is 15-17 nm, the thickness of the eighth film layer NiCr layer is 2.5-3.5 nm, the thickness of the tenth film layer Ag layer is 3.5-5.5 nm, and the thickness of the eleventh film layer NiCr layer is 2-4 nm.
Further, the first film layer, i.e. the innermost film layer ZrO2The thickness of the layer is 35-50 nm, and the fourteenth film layer is ZrO2The thickness of the layer is 45-35 nm.
Further, a second film Nb2O5The thickness of the layer is 11 to 13 nm.
Furthermore, the thickness of the AZO layer of the third film layer is 5-7 nm.
Furthermore, the thickness of the AZO layer of the sixth film layer is 110-115 nm.
Furthermore, the thickness of the AZO layer of the ninth film layer is 40-43 nm.
Furthermore, the thickness of the AZO layer of the twelfth film layer is 68-73 nm.
Further, a thirteenth film layer Si3N4The thickness of the layer is 75 to 80 nm.
Further, a fourteenth film layer Si3N4The thickness of the layer is 35 to 40 nm.
Borrow by above technical scheme, the beneficial effect of this application lies in: the three-silver temperable three-property gray Low-E glass is formed by sequentially compounding a first film layer ZrO of adjacent layers on a glass substrate from inside to outside2Layer, the second film layer is Nb2O5The layer, the third rete is the AZO layer, the fourth rete is the Ag layer, the fifth rete is the NiCr layer, the sixth rete is the AZO layer, the seventh rete is the Ag layer, the eighth rete is the NiCr layer, the ninth rete is the AZO layer, the tenth rete is the Ag layer, the eleventh rete is the NiCr layer, the twelfth rete is the AZO layer, the thirteenth rete is the Si layer3N4Layer, fourteenth film layer ZrO2And the thickness of the Ag layer of the fourth film layer is 9-12 nm, the thickness of the NiCr layer of the fifth film layer is 1-3 nm, and the thickness of the Ag layer of the seventh film layerThe thickness of the NiCr layer of the eighth film layer is set to be 15-17 nm, the thickness of the NiCr layer of the tenth film layer is set to be 2.5-3.5 nm, the thickness of the tenth film layer is set to be 3.5-5.5 nm, the thickness of the eleventh film layer is set to be 2-4 nm, and the thicknesses of the fourth film layer, the fifth film layer, the seventh film layer, the eighth film layer, the tenth film layer and the eleventh film layer are reasonably designed, so that the overall appearance of the Low-E glass product of the utility model is made to be three-gray, and the Nb2O5 layer is arranged, so that the Nb2O5 has the characteristics of high color fastness, high refractive index and high stability, the zero color difference of the Low-E glass is ensured, the color is consistent whether the glass is watched from the front side face or the glass, the artistic effect of the Low-E glass is increased, the aesthetic requirement of high-grade buildings is met, the use experience of users is improved, and the competitiveness of the product on, this application can shield the infrared ray that solar radiation came out in a large number through the Ag layer and the AZO layer that set up for the Low-E glass of this application has isolated solar energy, through setting up TiO2 layer, ZrO2 layer, Si3N4 layer and NiCr layer, can form the protective layer of high rigidity, make Low-E glass hardness high and anti corrosion resisting property strong, make glass mechanical properties better, Low-E glass is difficult by fish tail or wearing and tearing.
Drawings
Fig. 1 is a schematic structural diagram of three-silver temperable three-gray Low-E glass of the present invention.
Reference numerals:
1: a glass substrate; 21: a first film layer; 22: a second film layer; 23: a third film layer; 24: a fourth film layer; 25: a fifth film layer; 26: a sixth film layer; 27: a seventh film layer; 28: an eighth membrane layer; 29: a ninth film layer; 210: a tenth film layer; 211: an eleventh film layer; 212: a twelfth film layer; 213: a thirteenth film layer; 214: a fourteenth film layer.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in detail with reference to the accompanying drawings. It should be understood that the description is intended to be illustrative only and is not intended to limit the scope of the present invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention.
The utility model provides a pair of three silver can three nature grey Low-E glass of tempering, include: the glass substrate 1, fourteen film layers are adjacently compounded on the glass substrate 1 from inside to outside in sequence, wherein the first film layer 21, namely the innermost film layer is ZrO2Layer, the second film layer 22 is Nb2O5The layer, third rete 23 is the AZO layer, fourth rete 24 is the Ag layer, fifth rete 25 is the NiCr layer, sixth rete 26 is the AZO layer, seventh rete 27 is the Ag layer, eighth rete 28 is the NiCr layer, ninth rete 29 is the AZO layer, tenth rete 210 is the Ag layer, eleventh rete 211 is the NiCr layer, twelfth rete 212 is the AZO layer, thirteenth rete 213 is Si3N4Layer, fourteenth film layer 214 is ZrO2The thickness of the fourth film layer 24(Ag layer) is 9-12 nm, the thickness of the fifth film layer 25(NiCr layer) is 1-3 nm, the thickness of the seventh film layer 27(Ag layer) is 15-17 nm, the thickness of the eighth film layer 28(NiCr layer) is 2.5-3.5 nm, the thickness of the tenth film layer 210(Ag layer) is 3.5-5.5 nm, and the thickness of the eleventh film layer 211(NiCr layer) is 2-4 nm.
The three-silver temperable three-property gray Low-E glass sequentially compounds ZrO from inside to outside on the glass substrate 12Layer, Nb2O5Layer, AZO layer, Ag layer, NiCr layer, AZO layer, Si layer3N4Layer and ZrO2A fourth film layer 24(Ag layer) of 9 to 12nm, a fifth film layer 25(NiCr layer) of 1 to 3nm, a seventh film layer 27(Ag layer) of 15 to 17nm, an eighth film layer 28(NiCr layer) of 2.5 to 3.5nm, a tenth film layer 210(Ag layer) of 3.5 to 5.5nm, and an eleventh film layer 211 of 2 to 4nm, by reasonably designing the thickness ratios of the fourth film layer 24, the fifth film layer 25, the seventh film layer 27, the eighth film layer 28, the tenth film layer 210(Ag layer) and the eleventh film layer 211(NiCr layer), make the utility model discloses a Low-E glass product outward appearance wholly presents the grey colour of tribasic, has increased Low-E glass's artistic effect, accords with high-grade building's aesthetic requirement, has improved user's use and has experienced, has improved the product on market.Competitiveness, and, by providing the second film layer 22 (Nb)2O5Layer), Nb2O5Have high resistance to discoloration, high refracting index and high stability's characteristics, guaranteed Low-E glass's no colour difference, it is unanimous to watch the colour to glass no matter from glass front or side, and, Ag and AZO of this application can shield the infrared ray that solar radiation comes out in a large number, make the Low-E glass of this application isolated solar energy, avoid the indoor outer environment to see through the heat exchange that glass goes on, play good thermal-insulated effect, improve indoor comfort level, when the air conditioner refrigerates or heats, after indoor temperature has reached the settlement temperature, the air conditioner can be longer be in standby state, thereby save power consumption, and, TiO, the glass is transparent, the2、ZrO2、Si3N4And NiCr is a high-hardness material, a high-hardness protective layer can be formed, so that the Low-E glass is high in hardness and strong in corrosion resistance, the mechanical property of the glass is better, the Low-E glass is not easy to scratch or wear, and further, the Low-E glass can also increase the transmittance of visible light, so that the indoor lighting effect is better, the reflectivity of the visible light can be reduced, and the light pollution is reduced.
The application discloses but three silver tempering each rete concrete action of Low-E glass and the concrete thickness setting of each rete as follows:
first film layer 21 (ZrO)2Layer), i.e. a zirconium dioxide layer, as a first dielectric layer and a first protective layer, ZrO2Is a high-hardness high-compactness oxidation resistance material, can improve the physical property and the oxidation resistance of the film layer, can enhance the strength of the Low-E glass, avoid the glass from being worn and scratched, and can prevent oxygen from entering an Ag oxide layer, namely a first film layer 21(ZrO 2)2Layer) is set to a thickness of 35 to 50nm, preferably 38 nm.
Second film layer 22 (Nb)2O5Layer), i.e. niobium pentoxide layer, Nb2O5As second dielectric layer and first barrier layer, Nb2O5Besides reducing the color change of the Low-E glass at different angles and reducing the color deviation of the three-silver Low-E glass, the glass substrate can prevent Na < + > on the surface of the glass substrate 1 from enteringThe first functional Ag layer destroys the Ag layer and the second 22 (Nb)2O5Layer) also reduces the visible light reflectivity, avoiding light pollution due to a large amount of visible light reflection, and a second film layer 22 (Nb)2O5Layer) is set to a thickness of 11 to 13nm, preferably 12 nm.
The third film layer 23(AZO layer), namely the aluminum-doped zinc oxide layer, is used as a third dielectric layer and a second barrier layer, AZO is a material with high thermal stability and low emissivity on infrared rays, can prevent outdoor high temperature from being transmitted to the indoor space through radiation, and has a good heat insulation effect, the third film layer 23(AZO layer) can also prevent the high temperature from damaging the fourth film layer 24(Ag layer), and the thickness of the third film layer 23(AZO layer) is 5-7 nm, preferably 6 nm.
The fourth film layer 24(Ag layer), namely the metal silver layer, is used as the first functional layer, silver is used as a coating film layer, the infrared reflectivity of the film layer can be improved, the radiation rate of the metal silver to infrared rays is low, the film has a good heat insulation effect, the environment-friendly and energy-saving effects are achieved, and the preferable thickness of the fourth film layer 24(Ag layer) is 10 nm.
The fifth film layer 25(NiCr layer) is used as a protective layer and a leveling layer of the Ag layer, NiCr is a high-strength and corrosion-resistant alloy material, has good chemical stability and thermal properties, can protect the Ag layer from being damaged and prevent the Ag layer from being oxidized, can improve the mechanical strength and corrosion resistance of the Low-E glass of the present application, and the preferable thickness of the fifth film layer 25(NiCr layer) is 2 nm.
The sixth film layer 26(AZO layer), namely the aluminum-doped zinc oxide layer, is used as a fourth dielectric layer and a third barrier layer, has low infrared radiation rate and a good heat insulation effect, the sixth film layer 26(AZO layer) and the third film layer 23(AZO layer) are complementary, the fourth film layer 24(Ag layer) can be subjected to heat insulation protection from two sides, the fourth film layer 24(Ag layer) is prevented from being damaged by high temperature, and the thickness of the sixth film layer 26(AZO layer) is 110-115 nm, preferably 113 nm.
The seventh film layer 27(Ag layer), namely the metal silver layer, is used as a second functional layer, silver is used as a coating film layer, the infrared reflectivity of the film layer can be improved, the radiance of the metal silver is Low, a good heat insulation effect is achieved, the seventh film layer 27(Ag layer) and the fourth film layer 24(Ag layer) interact with each other, the radiance of the Low-E glass is further reduced, the environment-friendly and energy-saving effects are achieved, and the optimal thickness of the seventh film layer 27(Ag layer) is 16 nm.
The eighth film layer 28(NiCr layer), i.e., the nickel alloy layer, serves as a fourth barrier layer, NiCr is a high-strength and corrosion-resistant alloy material, has good chemical stability and thermal properties, can protect the Ag layer from being damaged and prevent the Ag layer from being oxidized, and can improve the strength and corrosion resistance of the Low-E glass of the present application, the eighth film layer 28(NiCr layer) interacts with the fifth film layer 25(NiCr layer) to protect the seventh film layer 27(Ag layer) from corrosion in two directions, and the thickness of the eighth film layer 28(NiCr layer) is preferably 1.55 nm. The eighth layer 28(NiCr layer) may improve the thermal insulation properties of the Low-E glass.
The ninth film layer 29(AZO layer), namely, the aluminum-doped zinc oxide layer, serves as a fifth dielectric layer and a fifth barrier layer, has low infrared radiation rate and a good heat insulation effect, the ninth film layer 29(AZO layer) and the sixth film layer 26(AZO layer) supplement each other, the seventh film layer 27(Ag layer) is protected from heat from both sides, and the thickness of the ninth film layer 29(AZO layer) is 40-43 nm.
The tenth film layer 210(Ag layer), namely the metal silver layer, utilizes silver as a coating film layer to improve the infrared reflectivity of the film layer, the tenth film layer 210(Ag layer), the seventh film layer 27(Ag layer) and the fourth film layer 24(Ag layer) have multiple functions, the emissivity of the Low-E glass is greatly reduced, the environment-friendly and energy-saving effects are achieved, and the preferable thickness of the tenth film layer 210(Ag layer) is 5.5 nm.
The eleventh film layer 211(NiCr layer), i.e. the nickel alloy layer, is used as the sixth barrier layer, NiCr is an alloy material with high strength and corrosion resistance, has good stability and thermal properties, can improve the strength and corrosion resistance of Low-E glass, and improves the heat insulation effect of Low-E glass, the eleventh film layer 211(NiCr layer) interacts with the eighth film layer 28(NiCr layer), so as to perform heat insulation and corrosion resistance protection on the tenth film layer 210(Ag layer) from two sides, and the preferable thickness of the eleventh film layer 211(NiCr layer) is 3 nm.
The twelfth film layer 212(AZO layer), namely, the aluminum-doped zinc oxide layer, is used as a sixth dielectric layer and a seventh barrier layer, has low infrared radiation rate and a good heat insulation effect, is complementary with the ninth film layer 29(AZO layer), and performs heat insulation protection on the tenth film layer 210(Ag layer) from two sides, and the thickness of the twelfth film layer 212(AZO layer) is 68-73 nm, preferably 70 nm.
Thirteenth film layer 213 (Si)3N4Layer), i.e. a silicon nitride layer, as a second protective layer, Si3N4The material has high hardness and good oxidation resistance, and the physical property and the oxidation resistance of the film layer are improved to enhance the strength of the Low-E glass, so that the Low-E glass is not easy to abrade and scratch. Si3N4Layer 29 is disposed on the outermost layer as a barrier protecting the entire film layer, thirteenth film layer 213 (Si)3N4Layer) has a thickness of 75 to 80nm, preferably 78 nm.
Fourteenth film layer 214 (ZrO)2Layer), i.e. a zirconium dioxide layer, as a seven-dielectric layer, ZrO2Is a high-hardness high-compactness oxidation resistance material, can improve the physical property and oxidation resistance of the film layer, thereby enhancing the strength of the Low-E glass, leading the glass not to be easily worn and scratched, and a fourteenth film layer 214 (ZrO) is formed2Layer) and thirteenth film layer 213 (Si)3N4Layer) to provide overlap protection, fourteenth film layer 214 (ZrO)2Layer) has a thickness of 35 to 40nm, preferably 38 nm.
The three-silver temperable three-property gray Low-E glass of the present application is tested, and the obtained color performance of the glass is shown in table 1:
colour properties Parameter(s)
Visible light transmittance T of glassvis 65
Visible light glass surface reflectivity Rout 10
Color coordinates a of glass surface -0.5
Color coordinates b of glass surface -1.5
Color coordinate of film surface a -2.5
Color coordinate b of film surface -3.0
Table 1
From table 1, it can be seen that the glass surface color coordinate a of the present application is-0.5, the glass surface color coordinate b is-1.5, the film surface color coordinate a is-2.5, the film surface color coordinate b is-3.0, the Low-E glass is entirely in a three-gray color, the artistic effect of the Low-E glass is increased, the aesthetic requirements of high-grade buildings are met, the use experience of users is improved, and the competitiveness of products in the market is improved.
In order to test the shielding and heat-insulating effect of the three-silver temperable three-gray Low-E glass, the three-silver temperable three-gray Low-E glass is placed on a UV-3600 ultraviolet spectrophotometer to be tested, the following data is obtained, and the optical and thermal properties of the 6mm three-silver temperable Low-E +12A +6mm white glass are calculated according to the JGJ/T151-doped 2008 standard, and are specifically shown in table 2:
performance index Parameter(s)
Transmittance of visible light Tvis 66
Visible light glass surface reflectivity Rout 14
Solar energy transmittance T sol 29
Solar reflectance Rout 30
Coefficient of heat transfer U 1.60
Shading coefficient Sc 0.38
Table 2
As can be seen from Table 2, the three-silver temperable grey Low-E glass of the present application has a visible light transmittance TvisA glass face reflectance R of 66 visible lightoutAt 14, solar energy transmittance TsolAt 29, solar reflectance RoutThe heat transfer coefficient U is 30, the heat transfer coefficient U is 1.60, the sun shading coefficient Sc is 0.38, and analysis in the table 2 shows that visible light can penetrate through a large amount of Low-E glass to enter the room, so that the indoor lighting effect is improved, solar energy can be blocked outdoors to avoid too much energy from entering the room to cause the indoor temperature to rise.
Specifically, the visible light transmittance TvisI.e. the intensity of visible light transmitting through the glass, the surface reflectivity R of the visible light glassoutIs visible lightIntensity reflected out of the glass, solar energy transmittance TsolIs the intensity of the solar energy transmitted through the glass, the solar reflectance RoutThe solar energy is reflected to the outside of the glass, the heat transfer coefficient U represents the heat transfer strength of the glass, and the shading coefficient Sc represents the ratio of the heat of the solar radiation transmitted through the glass to the heat of the solar radiation transmitted on the glass, and represents the weakening degree of the glass for transmitting the solar radiation to the heat without other shading measures.
It is to be understood that the above-described embodiments of the present invention are merely illustrative of or explaining the principles of the invention and are not to be construed as limiting the invention. Therefore, any modification, equivalent replacement, improvement and the like made without departing from the spirit and scope of the present invention should be included in the protection scope of the present invention. Further, it is intended that the appended claims cover all such variations and modifications as fall within the scope and boundaries of the appended claims or the equivalents of such scope and boundaries.

Claims (9)

1. The utility model provides a three-silver can tempering three nature grey Low-E glass which characterized in that includes: the glass substrate is compounded with fourteen film layers which are adjacent from inside to outside in sequence, wherein the first film layer, namely the innermost film layer, is ZrO2Layer, the second film layer is Nb2O5The layer, the third rete is the AZO layer, the fourth rete is the Ag layer, the fifth rete is the NiCr layer, the sixth rete is the AZO layer, the seventh rete is the Ag layer, the eighth rete is the NiCr layer, the ninth rete is the AZO layer, the tenth rete is the Ag layer, the eleventh rete is the NiCr layer, the twelfth rete is the AZO layer, the thirteenth rete is the Si layer3N4Layer, fourteenth film layer ZrO2The thickness of the fourth film layer Ag layer is 9-12 nm, the thickness of the fifth film layer NiCr layer is 1-3 nm, the thickness of the seventh film layer Ag layer is 15-17 nm, the thickness of the eighth film layer NiCr layer is 2.5-3.5 nm, the thickness of the tenth film layer Ag layer is 3.5-5.5 nm, and the thickness of the eleventh film layer NiCr layer is 2-4 nm.
2. According to claim 1The three-silver temperable three-property gray Low-E glass is characterized in that the first film layer is the innermost film layer ZrO2The thickness of the layer is 35-50 nm, and the fourteenth film layer is ZrO2The thickness of the layer is 35-45 nm.
3. The tri-silver temperable tri-grey Low-E glass according to claim 1, wherein the second film layer Nb is2O5The thickness of the layer is 11 to 13 nm.
4. The three-silver temperable three-gray Low-E glass according to claim 1, wherein the thickness of the AZO layer of the third film layer is 5 to 7 nm.
5. The three-silver temperable three-gray Low-E glass according to claim 1, wherein the thickness of the AZO layer of the sixth film layer is 110 to 115 nm.
6. The three-silver temperable three-gray Low-E glass according to claim 1, wherein the thickness of the ninth film layer AZO layer is 40-43 nm.
7. The three-silver temperable three-gray Low-E glass according to claim 1, wherein the thickness of the twelfth film layer AZO layer is 68-73 nm.
8. The tri-silver temperable tri-grey Low-E glass according to claim 1, wherein the thirteenth film layer is Si3N4The thickness of the layer is 75 to 80 nm.
9. The tri-silver temperable tri-grey Low-E glass according to claim 1, wherein the fourteenth film layer Si is Si3N4The thickness of the layer is 35 to 40 nm.
CN202020374728.1U 2020-03-23 2020-03-23 Three-silver temperable three-property gray Low-E glass Active CN211921327U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111196683A (en) * 2020-03-23 2020-05-26 中山市格兰特实业有限公司 Three-silver temperable three-property gray Low-E glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111196683A (en) * 2020-03-23 2020-05-26 中山市格兰特实业有限公司 Three-silver temperable three-property gray Low-E glass

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