CN210245685U - Empty and empty battery hybrid system of hydrogen of aluminium - Google Patents

Empty and empty battery hybrid system of hydrogen of aluminium Download PDF

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Publication number
CN210245685U
CN210245685U CN201920033726.3U CN201920033726U CN210245685U CN 210245685 U CN210245685 U CN 210245685U CN 201920033726 U CN201920033726 U CN 201920033726U CN 210245685 U CN210245685 U CN 210245685U
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hydrogen
liquid
air
liquid feeding
battery
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CN201920033726.3U
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Inventor
Zhiyuan Wu
吴智远
Yibing Xin
辛亦兵
Shuofeng Li
李硕峰
Cheng Li
李成
Pengpeng Guo
郭鹏鹏
Yangyang Wu
武洋洋
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Chuzhou Maite New Energy Co ltd
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Chuzhou Maite New Energy Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The utility model discloses an aluminium air and hydrogen air battery hybrid system, including the aluminium air battery, the aluminium air battery includes liquid feeding box, liquid box, water pump, radiator, support frame, circulation liquid feeding pipeline, liquid feeding liquid separating pipe, hydrogen pipeline, battery monomer, load negative pole, load positive pole and total fluid-discharge outlet, the bottom fixed mounting of liquid feeding box has the liquid box, the right side wall of liquid box has the water pump through bolt fixed mounting, the bottom fixed mounting of liquid box has the support frame, the inside of support frame has the radiator through bolt fixed mounting, the welding of radiator's top has the liquid feeding pipeline of circulation, the liquid feeding pipeline of circulation runs through the bottom of liquid feeding box, the fixed welding of circulation liquid feeding pipeline's top has liquid feeding liquid separating pipe, the top of liquid feeding liquid separating pipe with battery monomer looks fixed connection, this utility model improves discharge stability and good absorption hydrogen, and the byproduct is green clean water without any comprehensive effect of harmful substances.

Description

Empty and empty battery hybrid system of hydrogen of aluminium
Technical Field
The utility model relates to the technical field of batteries, specifically be an empty and empty battery hybrid system of hydrogen of aluminium.
Background
The chemical reaction of the aluminum-air battery is similar to that of the zinc-air battery, the aluminum-air battery takes high-purity aluminum Al (containing 99.99 percent of aluminum) as a negative electrode, oxygen as a positive electrode and potassium hydroxide (KOH) or sodium hydroxide (NaOH) aqueous solution as electrolyte. The aluminum absorbs oxygen in the air, a chemical reaction is generated when the battery is discharged, the aluminum and the oxygen are reacted and converted into aluminum oxide, and the process of generating hydrogen in the aluminum-air battery is a continuous process in the using process. As the cell ages, hydrogen gas slowly accumulates in the local space and environment. When the accumulation amount of hydrogen reaches the lower explosion limit, the explosion danger can be generated when the open fire is met. It is currently a major problem to solve the problem of hydrogen accumulation during use.
Most of aluminum-air batteries in the prior art adopt a blowing and diluting method to solve the problem of hydrogen accumulation, however, the method cannot fundamentally solve the harm of hydrogen generation, and meanwhile, the hydrogen generated in the use of the aluminum-air batteries cannot be reused, so that waste is turned into wealth, and the discharging stability of the aluminum-air batteries is poor, so that the development of an aluminum-air and hydrogen-air battery hybrid system is urgently needed.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide an empty and empty battery hybrid system of hydrogen of aluminium to the safety in utilization of the empty and empty battery hybrid system battery of hydrogen of aluminium that proposes in solving above-mentioned background art has caused very big influence, can not realize the problem of characteristic such as the follow new use of resource.
In order to achieve the above object, the utility model provides a following technical scheme: an aluminum-air and hydrogen-air battery hybrid system comprises an aluminum-air battery, wherein the aluminum-air battery comprises an upper liquid tank, a water pump, a radiator, a support frame, a circulating upper liquid pipeline, an upper liquid separating pipe, a hydrogen pipeline, a battery monomer, a load negative electrode, a load positive electrode, a total liquid inlet and a total liquid outlet, the bottom of the upper liquid tank is fixedly provided with the liquid tank, the right side wall of the liquid tank is fixedly provided with the water pump through a bolt, the bottom of the liquid tank is fixedly provided with the support frame, the inside of the support frame is fixedly provided with the radiator through a bolt, the top of the radiator is welded with the circulating upper liquid pipeline, the circulating upper liquid pipeline penetrates through the bottom of the upper liquid tank, the top of the circulating upper liquid pipeline is fixedly welded with the upper liquid separating pipe, the top of the upper liquid separating pipe is fixedly connected with the battery monomer, and the top of the battery, the right side wall of the aluminum air battery is fixedly connected with a hydrogen air battery, the hydrogen pipeline is fixedly connected with the hydrogen air battery, the left end of the battery monomer is fixedly provided with a load cathode, the right end of the battery monomer is fixedly provided with a load anode, the hydrogen-air battery comprises an exhaust port, a negative electrode, a positive electrode, a hydrogen cavity, a hydrogen electrode, an air electrode and an electrolyte cavity, the bottom of the front side wall of the hydrogen-air battery is provided with an exhaust port, the outer wall of the hydrogen cavity is fixedly provided with a hydrogen electrode, an air electrode is fixedly arranged outside the hydrogen electrode, an electrolyte cavity is formed between the air electrode and the hydrogen electrode, the top of the hydrogen cavity is fixedly provided with a cathode, the bottom of the hydrogen cavity is fixedly provided with an anode, the top of the left side wall of the liquid tank is provided with a total liquid inlet, and the bottom of the left side wall of the liquid tank is provided with a total liquid outlet.
Preferably, the loaded negative electrode is a metal aluminum plate.
Preferably, the aluminum-air battery is composed of 22 groups of battery cells.
Preferably, the single battery is an air electrode with the front and back surfaces of 150mm multiplied by 150mm, the single batteries are connected in series, and the rated power is 1000W.
Preferably, the electrolyte filled in the electrolyte cavity is alkali liquor.
Compared with the prior art, the beneficial effects of the utility model are that: the utility model discloses a provide an empty and empty battery hybrid system of hydrogen of aluminium, the hydrogen that produces when using the empty battery of aluminium is recycled, changing waste into valuables, with the process of hydrogen consumption regeneration, and can find out the required area of best absorption battery electrode and group battery quantity through actual experiment and calculation, reach abundant efficient absorption effect, the battery stability of discharging that improves simultaneously, this system can be repeated and continuous use, and the accessory substance is green clear water, there is not any harmful substance's production.
Drawings
FIG. 1 is a schematic structural view of the present invention;
fig. 2 is a schematic structural diagram of an aluminum-air battery of the structure of the present invention;
fig. 3 is a left side view of the liquid tank of the present invention.
In the figure: the device comprises a liquid feeding tank 1, a liquid feeding tank 2, a water pump 3, a radiator 4, a support frame 5, a circulating liquid feeding pipeline 6, a liquid feeding liquid separating pipe 7, a hydrogen pipeline 8, a single battery 9, an exhaust port 10, a hydrogen air power supply 11, an aluminum air power supply 12, a load negative electrode 13, a load positive electrode 14, a negative electrode 15, a positive electrode 16, a hydrogen cavity 17, a hydrogen electrode 18, an air electrode 19, an electrolyte cavity 20, a total liquid inlet 21 and a total liquid outlet 22.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative work belong to the protection scope of the present invention.
The utility model provides a technical scheme: an aluminum-air and hydrogen-air battery hybrid system is used for improving discharge stability and absorbing hydrogen well, please refer to fig. 1, an aluminum-air battery 12 comprises a liquid feeding tank 1, a liquid feeding tank 2, a water pump 3, a radiator 4, a support frame 5, a circulating liquid feeding pipeline 6, a liquid feeding and distributing pipe 7, a hydrogen pipeline 8, a battery monomer 9, a load cathode 13, a load anode 14, a total liquid inlet 21 and a total liquid outlet 22, the bottom of the liquid feeding tank 1 is fixedly provided with the liquid feeding tank 2, the right side wall of the liquid feeding tank 2 is fixedly provided with the water pump 3 through a bolt, the bottom of the liquid feeding tank 2 is fixedly provided with the support frame 5, the inside of the support frame 5 is fixedly provided with the radiator 4 through a bolt, the top of the radiator 4 is welded with the circulating liquid feeding pipeline 6, the circulating liquid feeding pipeline 6 penetrates through the bottom of the liquid feeding tank 1, the top of the circulating liquid feeding pipeline 6 is fixedly welded with the liquid feeding and distributing pipe 7, the top, the top of the battery monomer 9 is fixedly provided with a hydrogen pipeline 8, the raw materials of the load anode 14 and the load anode 16 are oxygen in the air, the load cathode 13 is a metal aluminum plate, the cathode 15 is harmful byproduct hydrogen generated in the discharging process of the aluminum-air battery 12, the battery monomer 9 is an air electrode with the front and back surfaces of 150mm multiplied by 150mm, the monomers of the battery monomer 9 are connected in series, the rated power is 1000W, please refer to fig. 2, the aluminum-air battery 12 is composed of 22 groups of battery monomers 9, sufficient hydrogen can be generated, the dosage requirement of the hydrogen-air battery 11 is ensured, the right side wall of the aluminum-air battery 12 is fixedly connected with the hydrogen-air battery 11, the left side end of the battery monomer 9 is fixedly provided with the load cathode 13, the right side end of the battery monomer 9 is fixedly provided with the load anode 14, the hydrogen-air battery 11 comprises an exhaust port 10, a cathode 15, an anode 16, a, The hydrogen-air battery comprises a hydrogen electrode 18, an air electrode 19 and an electrolyte cavity 20, wherein the bottom of the front side wall of the hydrogen-air battery 11 is provided with an exhaust port 10, the continuously accumulated redundant hydrogen of the hydrogen is exhausted from the exhaust port 10 below, the combustion and explosion risks caused by the accumulation of a large amount of hydrogen are prevented, the electrolyte filled in the electrolyte cavity 20 is alkali liquor, after the alkali liquor enters the aluminum-air battery 12, the hydrogen generated by self-corrosion enters the hydrogen cavity 17 of the hydrogen-air battery 11 through a hydrogen pipeline 8, the outer wall of the hydrogen cavity 17 is fixedly provided with the hydrogen electrode 18, the outside of the hydrogen electrode 18 is fixedly provided with the air electrode 19, the electrolyte cavity 20 is formed between the air electrode 19 and the hydrogen electrode 18, the hydrogen generated from the aluminum-air battery 12 is introduced between the hydrogen electrodes 18, the top of the hydrogen cavity 17 is fixedly provided with a negative electrode 15, and the, referring to fig. 3, a total liquid inlet 21 is formed at the top of the left side wall of the liquid tank 2, and a total liquid outlet 22 is formed at the bottom of the left side wall of the liquid tank 2.
In specific use, as needs the utility model discloses at first the inside of liquid pipe 6 in the circulation is carried via radiator 4 to the inside electrolyte of liquid case 2 by water pump 3 after the aluminium air cell 12 begins to discharge at the in-process that uses, then recycle circulation upper liquid pipe 6 inputs to the inner chamber of liquid case 1, then divide liquid pipe 7 to the upper liquid through upper liquid case 1 and carry into every battery monomer 9 respectively, alkali lye gets into behind the aluminium air cell 12 part, the hydrogen that produces from the corruption passes through hydrogen pipeline 8 and gets into the hydrogen cavity 17 of hydrogen air cell 11, discharge by below gas vent 10 along with the unnecessary hydrogen of the accumulation of hydrogen, the inside packing of electrolyte cavity 20 has electrolyte, utilize hydrogen electrode 18 and air electrode 19 to connect and produce chemical reaction, thereby produce the electric energy.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (5)

1. The utility model provides an empty and empty battery hybrid system of hydrogen of aluminium which characterized in that: the aluminum air battery comprises an aluminum air battery (12), wherein the aluminum air battery (12) comprises a liquid feeding box (1), a liquid feeding box (2), a water pump (3), a radiator (4), a support frame (5), a circulating liquid feeding pipeline (6), a liquid feeding liquid separating pipe (7), a hydrogen pipeline (8), a battery monomer (9), a load negative electrode (13), a load positive electrode (14), a total liquid inlet (21) and a total liquid outlet (22), the liquid feeding box (2) is fixedly arranged at the bottom of the liquid feeding box (1), the water pump (3) is fixedly arranged on the right side wall of the liquid feeding box (2) through bolts, the support frame (5) is fixedly arranged at the bottom of the liquid feeding box (2), the radiator (4) is fixedly arranged in the support frame (5) through bolts, the circulating liquid feeding pipeline (6) is welded at the top of the radiator (4), and the circulating liquid feeding pipeline (6) penetrates through the bottom of the liquid feeding box (, the top fixed welding of liquid pipeline (6) in the circulation has the liquid of going up to divide liquid pipe (7), go up the liquid divide the top of liquid pipe (7) with battery monomer (9) looks fixed connection, the top fixed mounting of battery monomer (9) has hydrogen pipeline (8), the right side wall fixed connection of aluminium air cell (12) has hydrogen air cell (11), hydrogen pipeline (8) with hydrogen air cell (11) looks fixed connection, the left side fixed mounting of battery monomer (9) has load negative pole (13), the right side end fixed mounting of battery monomer (9) has load positive pole (14), hydrogen air cell (11) include gas vent (10), negative pole (15), anodal (16), hydrogen cavity (17), hydrogen electrode (18), air electrode (19) and electrolyte cavity (20), the preceding lateral wall bottom of hydrogen air cell (11) is opened there is gas vent (10), the outer wall fixed mounting of hydrogen cavity (17) has hydrogen electrode (18), the outside fixed mounting of hydrogen electrode (18) has air electrode (19), form electrolyte cavity (20) between air electrode (19) and hydrogen electrode (18), the top fixed mounting of hydrogen cavity (17) has negative pole (15), the bottom fixed mounting of hydrogen cavity (17) has positive pole (16), open the left side wall top of liquid case (2) has total inlet (21), open the left side wall bottom of liquid case (2) has total leakage fluid dram (22).
2. The hybrid aluminum air and hydrogen air battery system according to claim 1, wherein: the load negative electrode (13) is a metal aluminum plate.
3. The hybrid aluminum air and hydrogen air battery system according to claim 1, wherein: the aluminum-air battery (12) is composed of 22 groups of battery monomers (9).
4. The hybrid aluminum air and hydrogen air battery system according to claim 1, wherein: the battery monomer (9) is an air electrode with the front surface and the back surface of 150mm multiplied by 150mm, the monomers of the battery monomer (9) are connected in series, and the rated power is 1000W.
5. The hybrid aluminum air and hydrogen air battery system according to claim 1, wherein: the electrolyte filled in the electrolyte cavity (20) is alkali liquor.
CN201920033726.3U 2019-01-09 2019-01-09 Empty and empty battery hybrid system of hydrogen of aluminium Active CN210245685U (en)

Priority Applications (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109904568A (en) * 2019-01-09 2019-06-18 滁州迈特新能源有限公司 A kind of aluminium sky and hydrogen sky cell hybrid systems

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109904568A (en) * 2019-01-09 2019-06-18 滁州迈特新能源有限公司 A kind of aluminium sky and hydrogen sky cell hybrid systems

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