CN210193783U - Device for preparing desulfurizer from chemical sludge of papermaking wastewater plant - Google Patents
Device for preparing desulfurizer from chemical sludge of papermaking wastewater plant Download PDFInfo
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- CN210193783U CN210193783U CN201822205303.3U CN201822205303U CN210193783U CN 210193783 U CN210193783 U CN 210193783U CN 201822205303 U CN201822205303 U CN 201822205303U CN 210193783 U CN210193783 U CN 210193783U
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- spiral propeller
- chemical sludge
- desulfurizer
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Abstract
The utility model discloses a device for preparing desulfurizer from chemical sludge of a paper-making wastewater plant, which comprises an incinerator, wherein a spiral propeller penetrating through a hearth is arranged above the hearth of the incinerator; the discharge port of the spiral propeller is positioned at the other side of the hearth and is directly connected with the discharge bin through a discharge bin pipeline; the device with the structure can convert iron elements in chemical sludge of a paper mill wastewater plant into ferric oxide, so that the ferric oxide becomes a high-quality raw material for preparing the biogas dry-method desulfurizer, secondary pollution of sludge is eliminated, and waste resources are recycled.
Description
Technical Field
The utility model belongs to the technical field of solid waste cyclic utilization, concretely relates to device of papermaking wastewater plant chemical sludge preparation desulfurizer.
Background
In newsprint factories, waste water produced after waste paper deinking is mainly treated by processes such as a sedimentation tank, anaerobic treatment, aerobic treatment, Fenton advanced oxidation treatment and the like. The sludge after the aerobic treatment process is called biological sludge, and can be directly combusted in an incinerator because the fiber content is high and the heat value can reach more than 3000 calories; the sludge after Fenton advanced oxidation treatment is called chemical sludge, most of various organic substances in the sewage are oxidized by the Fenton reagent after the process, the organic matter content in the residual sludge is low, the residual sludge is low in heat value and cannot be combusted, and landfill causes pollution to the environment. Through analysis, the dryness of the chemical sludge is 45-50%, the content of organic matters is 30-40%, and the content of the rest inorganic matters is about 60-70%. The analysis and test of the inorganic substance by a scanning electron microscope-energy spectrometer show that the main elements are three elements of Si, Fe and Al, and the element with the largest content is the Fe element. (the source of Fe element is mainly that FeSO is added in the Fenton advanced oxidation process4The source of Si element is sodium silicate Na added in the process of deinking waste paper2O▪nSiO2The source of Al element is polymerized AlCl added in the process of papermaking3)。
At present, the method for treating chemical sludge in a paper mill comprises the steps of mixing the chemical sludge with precipitated sludge and secondary biological treatment excess sludge, adding an inorganic conditioner and a polymeric flocculant, pumping the mixed sludge to a sludge dewatering machine for dewatering, and burning or burying the dewatered sludge for subsequent treatment. However, the method adds a large amount of inorganic conditioner and polymeric flocculant, which not only increases the chemical dosing cost of sludge treatment, but also increases the quality of sludge dehydration, increases the dehydration load, and simultaneously has low recovery rate of iron element in the sludge, can not realize the concept of recycling waste resources, generates more waste gas which is difficult to treat when being combusted with biological sludge, and is extremely unfavorable for tail gas treatment.
Disclosure of Invention
The utility model provides a device for preparing desulfurizer by utilizing chemical sludge of paper-making wastewater plant aiming at the defects, which comprises an incinerator, wherein a spiral propeller penetrating through the hearth is arranged above the hearth of the incinerator; the discharge port of the spiral propeller is positioned at the other side of the hearth and is directly connected with the discharge bin through a discharge bin pipeline; the device with the structure can convert iron elements in chemical sludge of a paper mill wastewater plant into ferric oxide, so that the ferric oxide becomes a high-quality raw material for preparing the biogas dry-method desulfurizer, secondary pollution of sludge is eliminated, and waste resources are recycled.
The utility model discloses a concrete technical scheme is:
a device for preparing desulfurizer from chemical sludge of a paper-making wastewater plant comprises an incinerator, wherein a spiral propeller penetrating through a hearth is arranged above the hearth of the incinerator, and a feed inlet and a propulsion motor of the spiral propeller are both positioned outside the hearth; the discharge port of the spiral propeller is positioned at the other side of the hearth and is directly connected with the discharge bin through a discharge bin pipeline; an air outlet is also arranged above the discharge hole of the spiral propeller and is connected with a tail gas treatment device through an air guide pipeline;
the device adopting the structure can firstly separate the biological sludge and the chemical sludge by utilizing the prior art, and the biological sludge is matched with coal powder according to the mass percentage of 10-20 percent in an incinerator to burn the biological sludge, and the temperature can reach more than 800 ℃; feeding chemical sludge from a feed inlet of the spiral propeller, driving the chemical sludge to enter the part of the spiral propeller, which is positioned in the hearth of the incinerator, of the spiral propeller, and adjusting the speed of the spiral propeller to ensure that the retention time of the sludge in the spiral propeller in the hearth is 10-20 minutes; under the action of high temperature, organic matters in the chemical sludge are completely oxidized and decomposed, and ferric hydrate ions are oxidized into active iron oxide, enter a discharging bin through a discharging port under the action of a spiral propeller, and become a main active raw material for preparing the desulfurizer after cooling; the waste gas generated by the chemical sludge in the heating process is separately discharged through an air outlet of the spiral propeller and enters a corresponding tail gas treatment device for treatment; because the chemical sludge is not subjected to the combustion process, but is subjected to the high-temperature reaction process, waste gas generated by combustion cannot be generated, the subsequent treatment is facilitated, and meanwhile, because the chemical sludge is not treated together with the biological sludge, the generation of more waste products caused by secondary reaction of the chemical sludge and the biological sludge is avoided, and a series of problems of difficult gas treatment and the like caused by mixed treatment of the waste gas generated by the treatment of the chemical sludge and the biological sludge are also avoided.
Utilize above-mentioned technology, obtain in the play feed bin and be the solid raw materials who mainly uses active iron oxide, on the basis of this raw materials, the cooperation is added active zinc oxide auxiliary agent, calcium oxide and ammonium bicarbonate, and the stirring misce bene that adds water, presses into columnar iron oxide desulfurizer through screw rod plodder can, follow-up technical scheme belongs to the technology category, in the utility model discloses the inventor no longer gives unnecessary details.
By adopting the device with the structure, the iron element in the chemical sludge of the paper-making wastewater plant can be converted into ferric oxide, so that the ferric oxide becomes a high-quality raw material for preparing the biogas dry-process desulfurizer, the secondary pollution of the sludge is eliminated, and the recycling of waste resources is realized; the desulfurizer prepared from the active iron oxide can be used for desulfurization treatment of biogas, and has a remarkable effect.
Drawings
FIG. 1 is a schematic structural view of a device for preparing a desulfurizer from chemical sludge in a paper mill wastewater treatment plant;
in the figure: 1 is propulsion motor, 2 is screw propeller, 3 is the propulsion spiral, 4 is burning furnace, 5 is ejection of compact storehouse, 6 is ejection of compact storehouse pipeline, 7 is tail gas processing apparatus, 8 is the air guide pipeline, 9 is the gas outlet, 10 is the feed inlet.
Detailed Description
A special device for preparing desulfurizer from chemical sludge of a paper-making wastewater plant comprises an incinerator 4, wherein a spiral propeller 2 penetrating through a hearth is arranged above the hearth of the incinerator 4; the discharge hole of the spiral propeller 2 is positioned at the other side of the hearth and is directly connected with a discharge bin 5 through a discharge bin pipeline 6; an air outlet 9 is also arranged above the discharge hole of the spiral propeller 2, and the air outlet 9 is connected with a tail gas treatment device 7 through an air guide pipeline 8; the feed inlet 10 of the spiral propeller 2 and the propulsion motor 1 are both positioned outside the hearth.
The device adopting the structure can firstly separate the biological sludge and the chemical sludge by utilizing the prior art, and the biological sludge is matched with coal powder according to the mass percentage of 10-20 percent in an incinerator to burn the biological sludge, and the temperature can reach more than 800 ℃; feeding chemical sludge from a feed inlet of the spiral propeller, driving the chemical sludge to enter the part of the spiral propeller, which is positioned in the hearth of the incinerator, of the spiral propeller, and adjusting the speed of the spiral propeller to ensure that the retention time of the sludge in the spiral propeller in the hearth is 10-20 minutes; under the action of high temperature, organic matters in the chemical sludge are completely oxidized and decomposed, and ferric hydrate ions are oxidized into active iron oxide, enter a discharging bin through a discharging port under the action of a spiral propeller, and become a main active raw material for preparing the desulfurizer after cooling; the waste gas generated by the chemical sludge in the heating process is separately discharged through an air outlet of the spiral propeller and enters a corresponding tail gas treatment device for treatment; because the chemical sludge is not subjected to the combustion process, but is subjected to the high-temperature reaction process, waste gas generated by combustion cannot be generated, the subsequent treatment is facilitated, and meanwhile, because the chemical sludge is not treated together with the biological sludge, the generation of more waste products caused by secondary reaction of the chemical sludge and the biological sludge is avoided, and a series of problems of difficult gas treatment and the like caused by mixed treatment of the waste gas generated by the treatment of the chemical sludge and the biological sludge are also avoided.
Claims (2)
1. The utility model provides a device of papermaking waste water factory chemical sludge preparation desulfurizer, includes incinerator (4), its characterized in that: a spiral propeller (2) penetrating through the hearth is arranged above the hearth of the incinerator (4); the discharge hole of the spiral propeller (2) is positioned at the other side of the hearth and is directly connected with the discharge bin (5) through a discharge bin pipeline (6); a gas outlet (9) is also arranged above the discharge hole of the spiral propeller (2), and the gas outlet (9) is connected with a tail gas treatment device (7) through a gas guide pipeline (8).
2. The apparatus for preparing desulfurizer from chemical sludge of paper mill wastewater treatment plant according to claim 1, wherein: the feed inlet (10) of the spiral propeller (2) and the propulsion motor (1) are both positioned outside the hearth.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201822205303.3U CN210193783U (en) | 2018-12-25 | 2018-12-25 | Device for preparing desulfurizer from chemical sludge of papermaking wastewater plant |
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CN201822205303.3U CN210193783U (en) | 2018-12-25 | 2018-12-25 | Device for preparing desulfurizer from chemical sludge of papermaking wastewater plant |
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CN210193783U true CN210193783U (en) | 2020-03-27 |
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CN201822205303.3U Expired - Fee Related CN210193783U (en) | 2018-12-25 | 2018-12-25 | Device for preparing desulfurizer from chemical sludge of papermaking wastewater plant |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109486542A (en) * | 2018-12-25 | 2019-03-19 | 山东华泰纸业股份有限公司 | A method of desulfurizing agent is prepared using paper waste factory chemical sludge |
-
2018
- 2018-12-25 CN CN201822205303.3U patent/CN210193783U/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109486542A (en) * | 2018-12-25 | 2019-03-19 | 山东华泰纸业股份有限公司 | A method of desulfurizing agent is prepared using paper waste factory chemical sludge |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200327 Termination date: 20211225 |
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CF01 | Termination of patent right due to non-payment of annual fee |