CN209781006U - Integrated automobile exhaust purification device based on dielectric barrier discharge - Google Patents
Integrated automobile exhaust purification device based on dielectric barrier discharge Download PDFInfo
- Publication number
- CN209781006U CN209781006U CN201920503955.7U CN201920503955U CN209781006U CN 209781006 U CN209781006 U CN 209781006U CN 201920503955 U CN201920503955 U CN 201920503955U CN 209781006 U CN209781006 U CN 209781006U
- Authority
- CN
- China
- Prior art keywords
- metal electrode
- automobile exhaust
- insulating sleeve
- dielectric barrier
- central
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000746 purification Methods 0.000 title claims abstract description 23
- 230000004888 barrier function Effects 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 82
- 239000002184 metal Substances 0.000 claims abstract description 82
- 239000000779 smoke Substances 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims description 46
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000003546 flue gas Substances 0.000 claims description 10
- 229910010293 ceramic material Inorganic materials 0.000 claims description 2
- 230000010354 integration Effects 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 6
- 231100000719 pollutant Toxicity 0.000 abstract description 6
- 230000008859 change Effects 0.000 abstract description 4
- 238000011144 upstream manufacturing Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000013461 design Methods 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004323 axial length Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000012629 purifying agent Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 210000003437 trachea Anatomy 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
Landscapes
- Exhaust Gas After Treatment (AREA)
Abstract
Description
技术领域technical field
本实用新型涉及汽车尾气净化技术领域,特别是一种基于介质阻挡放电的一体化汽车尾气净化装置。The utility model relates to the technical field of automobile exhaust purification, in particular to an integrated automobile exhaust purification device based on dielectric barrier discharge.
背景技术Background technique
随着我国汽车产业的飞速发展,汽车保有量激增,汽车尾气对城市空气质量的影响开始凸显,虽然电动汽车的出现有望在一定程度上应对尾气污染问题,但是受制于电池技术和充电问题,电动汽车续航里程不高,充电尤其是非大城市地区的充电问题尤为突出,且锂电池的制造和废弃本身也带来严重的环境污染。因此,解决好常规燃油汽车尾气污染问题仍然是当务之急。With the rapid development of my country's automobile industry, the number of automobiles has increased sharply, and the impact of automobile exhaust on urban air quality has begun to become prominent. Although the emergence of electric vehicles is expected to solve the problem of exhaust pollution to a certain extent, it is limited by battery technology and charging issues. The mileage of automobiles is not high, and the problem of charging, especially in non-big urban areas, is particularly prominent, and the manufacture and disposal of lithium batteries themselves also bring serious environmental pollution. Therefore, it is still a top priority to solve the problem of conventional fuel vehicle exhaust pollution.
汽车尾气主要污染物有NOX、CO、HC等,当前主要的汽车尾气净化方法有如下两种:The main pollutants of automobile exhaust are NO X , CO, HC, etc. Currently, there are two main methods of purifying automobile exhaust as follows:
1、采用三元催化器,通过其中的净化剂促使以上污染物发生氧化-还原化学反应。然而,这种方法需受制于催化剂活性条件,还需要对其进行加热,既耗费了能量,又容易引起汽车自燃,另外催化剂寿命十分有限。1. The three-way catalytic converter is used to promote the oxidation-reduction chemical reaction of the above pollutants through the purifying agent. However, this method is limited by the active conditions of the catalyst, and it needs to be heated, which consumes energy and is easy to cause spontaneous combustion of the car. In addition, the life of the catalyst is very limited.
2、采用水洗方式对汽车尾气进行过滤也是得到广泛研究的方法,但是,这种方法仅对碳粒子有效,且对水箱容积要求更高。2. Using water washing to filter automobile exhaust is also a method that has been extensively studied. However, this method is only effective for carbon particles and has higher requirements for the volume of the water tank.
随着非平衡等离子体辅助燃烧技术的发展,其在提高燃烧效率、缩短点火延迟、稳定火焰方面展现了不俗的能力。等离子体分为平衡态等离子体和非平衡态等离子体,其中电弧放电产生等离子体属于平衡态等离子体,常被用于发动机点火。然而通过放电产生平衡态等离子体过程中对电极腐蚀十分严重,导致通常难以长时间维持。典型的非平衡发生方式主要有介质阻挡放电、纳秒脉冲放电、微波放电等,这些放电方式中纳秒脉冲放电电源系统复杂、体积很大,且伴随强烈的电磁干扰等问题;微波放电产生等离子体则可能对人体带来伤害,不适合车载。With the development of non-equilibrium plasma-assisted combustion technology, it has shown good capabilities in improving combustion efficiency, shortening ignition delay, and stabilizing flame. Plasma is divided into equilibrium plasma and non-equilibrium plasma. The plasma generated by arc discharge belongs to equilibrium plasma and is often used for engine ignition. However, the corrosion of the electrode is very serious during the process of generating equilibrium state plasma through discharge, which makes it difficult to maintain it for a long time. Typical non-equilibrium occurrence methods mainly include dielectric barrier discharge, nanosecond pulse discharge, microwave discharge, etc. Among these discharge methods, the power supply system of nanosecond pulse discharge is complex, large in size, and accompanied by strong electromagnetic interference and other problems; microwave discharge produces plasma Body may cause harm to the human body, not suitable for vehicles.
公开号为CN102230410A 的中国实用新型专利申请,其实用新型名称为“一种基于等离子体实现光催化的汽车尾气净化装置”,其用到了二氧化钛,该物质一旦泄漏,被人体吸入会长期难以排除。The Chinese utility model patent application with the publication number CN102230410A is titled "A Plasma-Based Photocatalytic Automobile Exhaust Gas Purification Device", which uses titanium dioxide. Once the substance leaks, it will be difficult to get rid of it for a long time if it is inhaled by the human body.
公开号为CN103352744的中国实用新型专利申请,其实用新型名称为“一种汽车尾气的等离子体净化器”,结构复杂,有额外的水槽、电源,中间箱体存在不利于在现有汽车上布局,影响了汽车发动机设计。The Chinese utility model patent application with the publication number CN103352744, the name of the utility model is "A Plasma Purifier for Automobile Exhaust Gas". , affecting automotive engine design.
公开号为CN109351140A的中国实用新型专利申请,其实用新型名称为“一种热等离子体废气处理装置”,其中,放电产生的等离子属于热等离子体,电极工作寿命短,且需要耐火材料防护,变径段的加工难度高。The Chinese utility model patent application with the publication number CN109351140A, the name of the utility model is "a thermal plasma waste gas treatment device". The machining of the diameter section is difficult.
实用新型内容Utility model content
本实用新型要解决的技术问题是针对上述现有技术的不足,而提供一种基于介质阻挡放电的一体化汽车尾气净化装置,该基于介质阻挡放电的一体化汽车尾气净化装置在不影响汽车发动机内部本身结构的基础上,以对汽车最小改动为目标,有效去除汽车尾气中的NOX、CO、HC等主要污染物,并且依靠车载电瓶供电。The technical problem to be solved by the utility model is to provide an integrated automobile exhaust purification device based on dielectric barrier discharge for the above-mentioned deficiencies in the prior art. On the basis of the internal structure, aiming at the minimum modification to the car, it effectively removes major pollutants such as NO X , CO, and HC in the car exhaust, and relies on the car battery for power supply.
为解决上述技术问题,本实用新型采用的技术方案是:For solving the problems of the technologies described above, the technical scheme that the utility model adopts is:
一种基于介质阻挡放电的一体化汽车尾气净化装置,包括DBD排气管、管状连接头、变电器、车载电源调节器和烟气浓度测量装置。An integrated vehicle exhaust purification device based on dielectric barrier discharge, comprising a DBD exhaust pipe, a tubular connector, a transformer, a vehicle power regulator and a smoke concentration measuring device.
DBD排气管包括外管状金属电极、中心杆状金属电极、中心绝缘套管和两组“人”字形支撑架。The DBD exhaust pipe includes an outer tubular metal electrode, a central rod-shaped metal electrode, a central insulating sleeve and two sets of "herringbone"-shaped support frames.
管状连接头包括中间段和位于中间段两端的连接端,其中一个连接端与汽车尾气管相连接,另一个连接端与外管状金属电极相连接。The tubular connector includes a middle section and connecting ends located at both ends of the middle section, one of which is connected to the exhaust pipe of the automobile, and the other connecting end is connected to the outer tubular metal electrode.
中心杆状金属电极外周包覆中心绝缘套管,包覆有中心绝缘套管的中心杆状金属电极同轴插设在外管状金属电极中。The outer periphery of the central rod-shaped metal electrode is covered with a central insulating sleeve, and the central rod-shaped metal electrode covered with the central insulating sleeve is coaxially inserted into the outer tubular metal electrode.
中心杆状金属电极通过导线与变压器连接,变压器和车载电源调节器均与车载电瓶相连接。The central rod-shaped metal electrode is connected to the transformer through wires, and both the transformer and the vehicle power regulator are connected to the vehicle battery.
中心绝缘套管的下游尾端为封闭端,该封闭端与外管状金属电极的下游尾端相齐平。The downstream tail end of the central insulating sleeve is a closed end, and the closed end is flush with the downstream tail end of the outer tubular metal electrode.
中心绝缘套管外壁面通过一组“人”字形支撑架与管状连接头的中间段内壁面相连接,通过另一组“人”字形支撑架与外管状金属电极内壁面相连接。The outer wall of the central insulating sleeve is connected to the inner wall of the middle section of the tubular connector through a set of "herringbone"-shaped support frames, and connected to the inner wall of the outer tubular metal electrode through another set of "herringbone"-shaped support frames.
每组“人”字形支撑架均包括沿周向均匀布设的三根圆柱形的支撑杆。Each set of "herringbone"-shaped support frames includes three cylindrical support rods uniformly arranged along the circumferential direction.
中心绝缘套管与外管状金属电极之间的环状通道为汽车尾气处理通道,烟气浓度测量装置用于对汽车尾气处理通道出口烟气进行测量。The annular channel between the central insulating sleeve and the outer tubular metal electrode is the vehicle exhaust gas treatment channel, and the flue gas concentration measuring device is used to measure the flue gas at the outlet of the vehicle exhaust gas treatment channel.
汽车尾气管、管状连接头和外管状金属电极的内径相等。The inner diameters of the automobile exhaust pipe, the tubular connector and the outer tubular metal electrode are equal.
汽车尾气管、管状连接头和外管状金属电极的外径也相等。The outer diameters of the automobile exhaust pipe, the tubular connector and the outer tubular metal electrode are also equal.
管状连接头的两个连接端均为外螺纹连接端,外管状金属电极包括放电段和内螺纹连接段,内螺纹连接段的壁厚小于放电段的壁厚,内螺纹连接段与管状连接头的其中一个外螺纹连接端螺纹连接,另一个外螺纹连接端与汽车尾气管螺纹连接。The two connecting ends of the tubular connector are externally threaded. The outer tubular metal electrode includes a discharge section and an internally threaded section. The wall thickness of the internally threaded section is smaller than that of the discharge section. One of the external thread connection ends is threaded, and the other external thread connection end is threaded with the automobile exhaust pipe.
放电段的长度不超过内螺纹连接段长度的10倍。The length of the discharge section shall not exceed 10 times the length of the internal thread connection section.
放电段的内壁面加工有浅螺纹。The inner wall surface of the discharge section is machined with shallow threads.
中心杆状金属电极与中心绝缘套管螺纹连接。The central rod-shaped metal electrode is threadedly connected with the central insulating sleeve.
与管状连接头相连接的一组“人”字形支撑架中的一个支撑柱中开设有穿线过孔,与穿线过孔位置相对应的管状连接头上开设有外穿线孔,与穿线过孔位置相对应的中心绝缘套管上开设有内穿线孔,导线依次穿过外穿线孔、穿线过孔和内穿线孔后与中心杆状金属电极相连接。One of the support columns in a set of "herringbone"-shaped support frames connected to the tubular connector is provided with a threading hole, and the tubular connector corresponding to the position of the threading hole is provided with an outer threading hole, which is consistent with the position of the threading hole. The corresponding central insulating sleeve is provided with an inner threading hole, and the wire is connected to the central rod-shaped metal electrode after passing through the outer threading hole, the threading via hole and the inner threading hole in sequence.
管状连接头、中心绝缘套管以及支撑柱均为陶瓷材质。Tubular connectors, central insulating sleeves and support columns are all ceramic.
本实用新型具有如下有益效果:The utility model has the following beneficial effects:
1、基于介质阻挡放电方式产生等离子体来控制汽车尾气污染物具有响应速度快、放电反应迅速、参数可调范围大、电极可长时间运行等优点。1. The generation of plasma based on dielectric barrier discharge to control automobile exhaust pollutants has the advantages of fast response speed, rapid discharge response, large adjustable range of parameters, and long-term operation of electrodes.
2、易于加工,采用的构型与汽车尾气管结构兼容性非常好,模块化设计便于拆装,设计的中心杆状金属电极和支撑杆对尾气来流阻塞很小,且支撑杆能形成脱落涡和回流区,又使尾气的放电更充分。2. It is easy to process, and the configuration adopted is very compatible with the automobile exhaust pipe structure. The modular design is easy to disassemble and assemble. The designed central rod-shaped metal electrode and support rod have little obstruction to the exhaust gas flow, and the support rod can form a fall-off The vortex and recirculation zone make the discharge of exhaust gas more fully.
3、能将NOX和CO等主要污染气体净化为无毒、无污染气体,且能对碳黑、碳氧化物颗粒实现吸附,并通过车载电源调节器实现对净化效果的调控,且该放电模式下放电功率通常小于100 W。3. It can purify the main polluting gases such as NO X and CO into non-toxic and non-polluting gases, and can adsorb carbon black and carbon oxide particles, and realize the regulation and control of the purification effect through the on-board power regulator, and the discharge Mode discharge power is usually less than 100 W.
4、与原有汽车尾气管结构一体化,不占额外空间。4. It is integrated with the original automobile exhaust pipe structure and does not occupy additional space.
附图说明Description of drawings
图1显示了本实用新型一种基于介质阻挡放电的一体化汽车尾气净化装置的整体结构图。Fig. 1 shows the overall structure diagram of an integrated vehicle exhaust purification device based on dielectric barrier discharge of the present invention.
图2显示了DBD排气管的立体图。Figure 2 shows a perspective view of the DBD exhaust pipe.
图3显示了DBD排气管的轴向剖面图。Figure 3 shows an axial cross-section of the DBD exhaust pipe.
图4显示了DBD排气管的径向剖面图。Figure 4 shows a radial cross-section of the DBD exhaust pipe.
图5显示了中心杆状金属电极的立体图。Figure 5 shows a perspective view of the central rod-shaped metal electrode.
图6显示了中心绝缘套管的立体图。Figure 6 shows a perspective view of the central insulating sleeve.
图7显示了中心绝缘套管的轴向剖面图。Figure 7 shows an axial sectional view of the central insulating sleeve.
图8显示了管状连接头的立体图。Figure 8 shows a perspective view of the tubular connector.
图9显示了管状连接头的轴向剖面图。Figure 9 shows an axial section of the tubular connector.
图10显示了外管状金属电极的立体图。Figure 10 shows a perspective view of the outer tubular metal electrode.
图11显示了外管状金属电极的轴向剖面图。Figure 11 shows an axial cross-sectional view of the outer tubular metal electrode.
图12显示了支撑杆不含穿线过孔时的结构图。Figure 12 shows a structural diagram of the support rod without a threading hole.
图13显示了支撑杆含有穿线过孔时的结构图。Fig. 13 shows the structural diagram when the support rod contains the threading hole.
图14显示了支撑杆下游形成的回流区示意图。Figure 14 shows a schematic diagram of the recirculation zone formed downstream of the support rod.
图15显示了支撑杆下游形成的低流速区示意图。Figure 15 shows a schematic diagram of the low flow zone formed downstream of the struts.
图16显示了汽车尾气管内径为40mm时DBD排气管的尺寸布设示意图。Figure 16 shows a schematic diagram of the size layout of the DBD exhaust pipe when the inner diameter of the automobile exhaust pipe is 40 mm.
其中有:Including:
10.DBD排气管;10. DBD exhaust pipe;
11.外管状金属电极;111.内螺纹连接段;12.中心杆状金属电极;13.中心绝缘套管;131.内穿线孔;14.支撑杆;141.穿线过孔;11. Outer tubular metal electrode; 111. Internal thread connection section; 12. Center rod-shaped metal electrode; 13. Center insulating sleeve; 131. Inner threading hole; 14. Support rod; 141. Threading hole;
20.管状连接头;21.外螺纹连接端;22.中间段;221.外穿线孔;20. Tubular connector; 21. External thread connection end; 22. Middle section; 221. Outer threading hole;
30.变电器;40.车载电瓶;41.车载电源调节器;30. Transformer; 40. Vehicle battery; 41. Vehicle power regulator;
50.烟气浓度测量装置;51.测量探头;50. Smoke concentration measuring device; 51. Measuring probe;
60.回流区;61.流线;62.低流速区。60. Recirculation zone; 61. Streamline; 62. Low velocity zone.
具体实施方式Detailed ways
下面结合附图和具体较佳实施方式对本实用新型作进一步详细的说明。The utility model will be described in further detail below in conjunction with the accompanying drawings and specific preferred embodiments.
本实用新型的描述中,需要理解的是,术语“左侧”、“右侧”、“上部”、“下部”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本实用新型和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,“第一”、“第二”等并不表示零部件的重要程度,上游、下游是以尾气走向进行区分的,因此不能理解为对本实用新型的限制。本实施例中采用的具体尺寸只是为了举例说明技术方案,并不限制本实用新型的保护范围。In the description of the present utility model, it should be understood that the orientation or positional relationship indicated by the terms "left side", "right side", "upper part" and "lower part" are based on the orientation or positional relationship shown in the accompanying drawings, only It is for the convenience of describing the present utility model and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operate in a specific orientation, and "first", "second" and the like do not mean zero The importance of components, upstream and downstream are distinguished by the direction of exhaust gas, so it cannot be understood as a limitation of the present invention. The specific dimensions used in this embodiment are only for illustrating the technical solution, and do not limit the protection scope of the present utility model.
如图1所示,一种基于介质阻挡放电的一体化汽车尾气净化装置,包括DBD排气管10、管状连接头20、变电器30、车载电源调节器41和烟气浓度测量装置50。As shown in FIG. 1 , an integrated vehicle exhaust purification device based on dielectric barrier discharge includes a DBD exhaust pipe 10 , a tubular connector 20 , a transformer 30 , a vehicle power regulator 41 and a smoke concentration measuring device 50 .
如图8和图9所示,管状连接头包括中间段22和位于中间段两端的连接端,中间段上优选开设有外穿线孔221。As shown in FIG. 8 and FIG. 9 , the tubular connector includes a middle section 22 and connection ends located at both ends of the middle section. The middle section is preferably provided with an outer threading hole 221 .
管状连接头的两个连接端均优选为外螺纹连接端21,位于上游的外螺纹连接端与汽车尾气管螺纹连接,位于下游的外螺纹连接端与外管状金属电极螺纹连接。The two connecting ends of the tubular connector are preferably externally threaded connecting ends 21, the upstream externally threaded connecting end is threadedly connected to the automobile exhaust pipe, and the downstream externally threaded connecting end is threadedly connected to the outer tubular metal electrode.
管状连接头内径优选与汽车尾气管内径相等,中间段的外径优选与汽车尾气管外径相等。The inner diameter of the tubular connector is preferably equal to the inner diameter of the automobile exhaust pipe, and the outer diameter of the middle section is preferably equal to the outer diameter of the automobile exhaust pipe.
管状连接头与汽车尾气管装配前,先在汽车尾气管的出口尾端内壁面开挖一段与上游外螺纹连接端长度相等的环形凹槽,然后在环形凹槽上车出内螺纹,使得管状连接头与汽车尾气管形成良好装配。Before the tubular connector is assembled with the automobile exhaust pipe, an annular groove with the same length as the upstream external thread connection end is excavated on the inner wall of the outlet end of the automobile exhaust pipe, and then the internal thread is formed on the annular groove, so that the tubular The connectors form a good fit with the exhaust pipe of the car.
管状连接头的存在,也能起到确保放电仅发生在管状连接头下游的外管状金属电极与中心杆状金属电极之间的环形通道。由于管状连接头本身为陶瓷,因此管状连接头与内螺纹段的螺纹连接段较下游放电段多了一层陶瓷绝缘介质的阻挡,使得施加电压后放电段会优先发生放电,而此螺纹连接段则不发生放电。The existence of the tubular connector can also ensure that the discharge only occurs in the annular channel between the outer tubular metal electrode and the central rod-shaped metal electrode downstream of the tubular connector. Since the tubular connector itself is made of ceramics, the threaded connection section between the tubular connector and the internal thread section is blocked by a layer of ceramic insulating medium compared with the downstream discharge section, so that the discharge section will preferentially discharge after the voltage is applied, and the threaded section Then no discharge occurs.
如图2至图4所示,DBD排气管包括外管状金属电极11、中心杆状金属电极12、中心绝缘套管13和两组“人”字形支撑架。As shown in Figures 2 to 4, the DBD exhaust pipe includes an outer tubular metal electrode 11, a central rod-shaped metal electrode 12, a central insulating sleeve 13 and two sets of "herringbone"-shaped support frames.
如图11和图12所示,外管状金属电极包括放电段和内螺纹连接段111,内螺纹连接段的壁厚小于放电段的壁厚,具体操作方法为:先在外管状金属电极的上游端内壁面开挖一段与内螺纹连接段长度相等的环形凹槽,然后在环形凹槽上车出内螺纹,从而形成内螺纹连接段,便于使外管状金属电极的内外径与汽车尾气管和管状连接头保持一致,防止从发动机出来的尾气在管道中流动不畅,如果不一致,可能导致下游内径变小而发生气体拥塞等问题。As shown in Figures 11 and 12, the outer tubular metal electrode includes a discharge section and an internal thread connection section 111. The wall thickness of the internal thread connection section is smaller than the wall thickness of the discharge section. Excavate an annular groove with the same length as the internal thread connection section on the inner wall, and then carve the internal thread on the annular groove to form an internal thread connection section, so that the inner and outer diameters of the outer tubular metal electrode can be aligned with the automobile exhaust pipe and tubular The connectors should be consistent to prevent the exhaust gas from the engine from flowing in the pipeline. If they are not consistent, the inner diameter of the downstream may become smaller and gas congestion and other problems may occur.
放电段的内壁面加工有浅螺纹,用于强化放电。放电段的长度不超过内螺纹连接段长度的10倍。The inner wall surface of the discharge section is processed with shallow threads for strengthening the discharge. The length of the discharge section shall not exceed 10 times the length of the internal thread connection section.
中心杆状金属电极,如图5所示,其外周包覆中心绝缘套管,中心杆状金属电极与中心绝缘套管优选螺纹连接。The central rod-shaped metal electrode, as shown in FIG. 5 , has an outer periphery covered with a central insulating sleeve, and the central rod-shaped metal electrode and the central insulating sleeve are preferably threaded.
包覆有中心绝缘套管的中心杆状金属电极同轴插设在外管状金属电极中。The central rod-shaped metal electrode covered with the central insulating sleeve is coaxially inserted in the outer tubular metal electrode.
如图6和图7所示,中心绝缘套管的上游端开口设置,下游尾端为封闭端,该封闭端与外管状金属电极的下游尾端相齐平。中心绝缘套管的设计,可以实现对其内部中心杆状金属电极的包裹与位置固定,且下游尾端封闭后能实现防DBD排气管出口发生边缘放电。As shown in Figures 6 and 7, the upstream end of the central insulating sleeve is open, and the downstream end is a closed end, which is flush with the downstream end of the outer tubular metal electrode. The design of the central insulating sleeve can realize the wrapping and position fixing of the central rod-shaped metal electrode inside, and the downstream tail end can be closed to prevent edge discharge at the outlet of the DBD exhaust pipe.
中心绝缘套管与外管状金属电极之间的环状通道为汽车尾气处理通道,也称空气间隙或放电间隙。The annular channel between the central insulating sleeve and the outer tubular metal electrode is the vehicle exhaust gas treatment channel, also known as the air gap or the discharge gap.
中心绝缘套管外壁面通过一组“人”字形支撑架与管状连接头的中间段内壁面相连接,通过另一组“人”字形支撑架与外管状金属电极内壁面相连接。The outer wall of the central insulating sleeve is connected to the inner wall of the middle section of the tubular connector through a set of "herringbone"-shaped support frames, and connected to the inner wall of the outer tubular metal electrode through another set of "herringbone"-shaped support frames.
“人”字型支撑杆除了起到支撑和固定中心杆状金属电极和中心绝缘套管的作用,还能隔绝高压导线与外管状金属电极,防止高压导线与外管状金属电极之间优先放电。The "herringbone"-shaped support rod not only supports and fixes the central rod-shaped metal electrode and the central insulating sleeve, but also isolates the high-voltage wire from the outer tubular metal electrode to prevent preferential discharge between the high-voltage wire and the outer tubular metal electrode.
每组“人”字形支撑架均包括沿周向均匀布设的三根支撑杆14,如图12所示,每根支撑杆均呈圆柱形。Each group of "herringbone"-shaped support frames includes three support rods 14 uniformly arranged along the circumference, as shown in FIG. 12 , each support rod is cylindrical.
位于上游的“人”字形支撑架中的一个支撑柱中开设有有如图13所示的穿线过孔141,该穿线过孔与外穿线孔位置相对应,与穿线过孔位置相对应的中心绝缘套管上开设有内穿线孔131。A threading hole 141 as shown in Figure 13 is opened in one of the supporting columns of the "herringbone"-shaped support frame located upstream. The threading hole corresponds to the position of the outer threading hole, and the center insulation corresponding to the position of the threading hole An inner threading hole 131 is opened on the casing.
管状连接头、中心绝缘套管以及支撑柱均为陶瓷材质。Tubular connectors, central insulating sleeves and support columns are all ceramic.
上游“人”字形支撑架的位置设置,一方面能使外管状金属电极的内外径与汽车尾气管和管状连接头保持一致;另一方面,由于管状连接头为陶瓷材料,便于开设外穿线孔,便于导线穿过,防止导线与下游DBD排气管中的外管状金属电极之间发生放电。The position setting of the upstream "herringbone"-shaped support frame, on the one hand, can make the inner and outer diameters of the outer tubular metal electrode consistent with the automobile exhaust pipe and the tubular connector; on the other hand, because the tubular connector is made of ceramic material, it is convenient to open the outer threading hole , to facilitate the passage of wires and prevent discharges between the wires and the outer tubular metal electrode in the downstream DBD exhaust pipe.
另外,上游“人”字形支撑架与外管状金属电极上游端(也即内螺纹连接段上游端)之间的轴向距离不小于放电间隙厚度尺寸,从而防止高压导线与外管状金属电极之间优先放电。In addition, the axial distance between the upstream "herringbone"-shaped support frame and the upstream end of the outer tubular metal electrode (that is, the upstream end of the internal thread connection section) is not less than the thickness of the discharge gap, so as to prevent the gap between the high-voltage wire and the outer tubular metal electrode. Priority discharge.
本实用新型中,外管状金属电极接地,形成地电极;中心杆状金属电极通过导线与变压器连接,形成高压电极;其中,导线依次穿过外穿线孔、穿线过孔和内穿线孔后与中心杆状金属电极相连接。In the utility model, the outer tubular metal electrode is grounded to form a ground electrode; the central rod-shaped metal electrode is connected to the transformer through a wire to form a high-voltage electrode; wherein, the wire passes through the outer threading hole, the threading via hole and the inner threading hole in turn and connects with the center The rod-shaped metal electrodes are connected.
变压器和车载电源调节器均与车载电瓶40相连接,放电类型优选为微秒、毫秒脉冲放电或高频交流放电。Both the transformer and the vehicle power regulator are connected to the vehicle battery 40, and the discharge type is preferably microsecond, millisecond pulse discharge or high frequency AC discharge.
烟气浓度测量装置50用于对汽车尾气处理通道出口烟气进行测量。烟气浓度测量装置优选为手持式烟气浓度分析仪,将其测量探头51放置在汽车尾气处理通道的出口,即可对汽车尾气处理通道出口烟气进行测量。The smoke concentration measuring device 50 is used to measure the smoke at the outlet of the vehicle exhaust treatment channel. The flue gas concentration measuring device is preferably a hand-held flue gas concentration analyzer, and its measuring probe 51 is placed at the exit of the vehicle exhaust treatment channel to measure the flue gas at the exit of the vehicle exhaust treatment channel.
下面以具体事例,将汽车尾气管、管状连接头和外管状金属电极的内径相等的布设方法进行详细介绍。Taking specific examples below, the layout method of the exhaust pipe of the automobile, the tubular connector and the inner diameter of the outer tubular metal electrode is introduced in detail.
如图16所示,针对通常小汽车排气管,汽车尾气管内径为40mm,图中尺寸单位为mm。As shown in Figure 16, for the exhaust pipe of a common car, the inner diameter of the exhaust pipe of the automobile is 40mm, and the dimension unit in the figure is mm.
管件连接头的内径为40mm,其外螺纹连接端壁厚3-10mm,中间段壁厚6-15 mm,两段螺纹连接端轴向长度大于20 mm,且在能保证可靠连接的基础上长度尽可能小;外穿线孔、穿线过孔和内穿线孔的直径均为1-3mm。The inner diameter of the pipe fitting connector is 40mm, the wall thickness of the external thread connection end is 3-10mm, the wall thickness of the middle section is 6-15mm, the axial length of the two thread connection ends is greater than 20mm, and the length is as long as possible on the basis of ensuring reliable connection Small; the diameters of the outer threading hole, the threading via hole and the inner threading hole are all 1-3mm.
支撑杆直径6-15mm,其中,位于上游的“人”字形支撑架其进口端轴向位置距离中心绝缘套管开口端大于5 mm,以保证中心绝缘套管和电极受力平衡。The diameter of the support rod is 6-15mm. Among them, the axial position of the inlet end of the upstream "herringbone" support frame is more than 5 mm from the opening end of the central insulating sleeve to ensure the balance of the central insulating sleeve and the electrode.
另外,位于上游的“人”字形支撑架中支撑杆的中心与上游外螺纹连接端开口之间的距离不少于8 mm。这样的好处是防止导线与最近的外电极之间直接发生放电,而在下游该放电区域未发生放电。In addition, the distance between the center of the support rod in the upstream "chevron" support frame and the opening of the upstream external threaded connection end is not less than 8 mm. The advantage of this is to prevent the direct discharge between the wire and the nearest external electrode, while the discharge does not occur in the downstream discharge area.
外管状金属电极中放电段壁厚6-15 mm,保持与管状连接头装配后内外表面平齐;中心杆状金属电极直径8-15 mm,中心绝缘套管壁厚3-5 mm,且两者螺纹连接后出口断面平齐,中心绝缘套管封闭端壁厚3-6 mm。The wall thickness of the discharge section in the outer tubular metal electrode is 6-15 mm, which is kept flush with the inner and outer surfaces of the tubular connector after assembly; the diameter of the central rod-shaped metal electrode is 8-15 mm, and the wall thickness of the central insulating sleeve is 3-5 mm. After connection, the outlet section is flush, and the wall thickness of the closed end of the central insulating sleeve is 3-6 mm.
具体装配方式为:管状连接头的一端与汽车排气管通过螺纹进行连接,另一端与DBD排气管外管状金属电极通过螺纹进行连接,以上螺纹采用密封型螺纹或者添加密封胶/带;将中心杆状电极旋入中心绝缘套管,即中心绝缘套管对中心杆状金属电极呈包裹态,封闭端的作用是轴向固定中心电极,两者采用螺纹连接;采用两组呈“人”字形支撑架支撑中心杆状金属电极和中心绝缘套管,单组“人”字形支撑架中相邻支撑杆之间呈120°布置,其中距离进气端的“人”字形支撑架中一个支撑杆中心开有1 mm穿线过孔,该穿线过孔与内穿线孔以及外穿线孔均对齐,以保证导线穿过并接触至中心杆状金属电极。The specific assembly method is: one end of the tubular connector is threaded to the automobile exhaust pipe, and the other end is threaded to the outer tubular metal electrode of the DBD exhaust pipe. The above thread adopts a sealed thread or adds a sealant/tape; The central rod-shaped electrode is screwed into the central insulating sleeve, that is, the central insulating sleeve wraps the central rod-shaped metal electrode, and the function of the closed end is to axially fix the central electrode, and the two are connected by threads; The support frame supports the central rod-shaped metal electrode and the central insulating sleeve. The adjacent support rods in a single set of "herringbone"-shaped support frames are arranged at 120°, and the distance from the center of a support rod in the "herringbone"-shaped support frame at the intake end There is a 1 mm threading hole, which is aligned with the inner threading hole and the outer threading hole to ensure that the wire passes through and contacts the central rod-shaped metal electrode.
管状连接头、中心绝缘套管以及所有支撑杆均为陶瓷材质,中心杆状金属电极和外管状金属电极材质则可以是钢、铜等常见电极类金属。支撑杆和外管状金属电极、管状连接头、中心绝缘套管三者之间均采用螺纹连接。The tubular connector, the central insulating sleeve and all the support rods are made of ceramics, and the material of the central rod-shaped metal electrode and the outer tubular metal electrode can be common electrode metals such as steel and copper. The support rod, the outer tubular metal electrode, the tubular connector and the central insulating sleeve are all threaded.
支撑杆布局能保证气流受到的阻挡均匀,根据空气动力学原理,如图14所示,对尾气来流来说各个支撑杆下游会形成回流区60,从而还有利于延长尾气在DBD排气管的驻留时间,强化放电反应。The layout of the support rods can ensure that the airflow is blocked evenly. According to the principle of aerodynamics, as shown in Figure 14, for the exhaust gas to flow, the downstream of each support rod will form a recirculation zone 60, which is also conducive to extending the exhaust gas flow in the DBD exhaust pipe. The residence time, strengthen the discharge reaction.
由于支撑杆为圆柱体,并垂直于排气管来流方向,所以形成了经典的圆柱绕流流场,该流场流线图如图14所示,可以看到由于圆柱体的存在,在圆柱体下游靠近圆柱体位置形成了一对回流区60,根据流体力学知识,回流区内流体质点甚至会向上游运动;图15则给出了圆柱体绕流流场速度分布云图,相对于来流而言是回流区明显是一个低流速区62,并且能影响到圆柱体下游较远位置,因此汽车尾气在经过每一个支撑杆后都会形成相应的回流区和下游的低流速区,使得尾气在其中驻留时间显著增加,而放电开始于管状连接头的支撑杆下游,即放电对每一个流体质点的作用时间变长,电离、分解、氧化等放电相关的反应进行得更彻底了,因而对尾气的净化效果更好。另外,由于采用了上游和下游两组、共计6个支撑杆的方案,在最大限度节省材料的同时,起到了良好的支撑和固定中心杆状金属电极与中心绝缘套管的作用,而利用圆柱绕流减速作用,使得DBD排气管对尾气的净化更彻底,并且对称形式的支撑架设计方案能最大限度保持排气管内气流流场结构的对称,使得对整个尾气的放电作用更均匀。Since the support rod is a cylinder and is perpendicular to the flow direction of the exhaust pipe, a classic flow field around the cylinder is formed. The streamline diagram of the flow field is shown in Figure 14. It can be seen that due to the existence of the cylinder, A pair of recirculation zones 60 are formed downstream of the cylinder close to the cylinder. According to the knowledge of fluid mechanics, the fluid particles in the recirculation zone may even move upstream; Fig. 15 shows the cloud diagram of the flow field velocity distribution around the cylinder. As far as flow is concerned, the recirculation zone is obviously a low flow velocity zone 62, and can affect the far downstream position of the cylinder, so the automobile exhaust will form a corresponding recirculation zone and a downstream low flow velocity zone after passing through each support rod, so that the exhaust gas In it, the residence time is significantly increased, and the discharge starts downstream of the support rod of the tubular joint, that is, the discharge time on each fluid particle becomes longer, and the discharge-related reactions such as ionization, decomposition, and oxidation are carried out more thoroughly, so The purification effect on exhaust gas is better. In addition, due to the adoption of two sets of upstream and downstream support rods, a total of 6 support rods, while saving materials to the greatest extent, it plays a good role in supporting and fixing the central rod-shaped metal electrode and the central insulating sleeve. The deceleration effect of the circumvention makes the exhaust gas purification by the DBD exhaust pipe more thorough, and the symmetrical support frame design scheme can maintain the symmetry of the air flow field structure in the exhaust pipe to the greatest extent, so that the discharge effect on the entire exhaust gas is more uniform.
本实用新型中,对支撑杆数量和直径的选择,也是经过长期反复试验后设计出来的,经过上述分析可知,支撑杆直径越大,在尾气来流条件不变时,下游回流区和低流速区体积越大,使得尾气在其中驻留时间显著增加,尾气处理效果更好。然而,支撑杆直径太大,则会严重影响DBD排气管有效通过面积,可能导致尾气拥塞,且尾气温度较高,因为如果排气管通过面积过小,热量散不出去,会引发爆炸危险。In the utility model, the selection of the number and diameter of the support rods is also designed after long-term repeated tests. Through the above analysis, it can be seen that the larger the diameter of the support rods, the lower the flow rate of the downstream recirculation zone and the lower flow rate when the tail gas flow conditions remain unchanged. The larger the volume of the zone, the longer the residence time of the exhaust gas in it, and the better the exhaust gas treatment effect. However, if the diameter of the support rod is too large, it will seriously affect the effective passing area of the DBD exhaust pipe, which may cause exhaust gas congestion and high exhaust temperature, because if the passing area of the exhaust pipe is too small, the heat will not be dissipated, which will cause explosion hazards .
故而,本实用新型中,每组“人”字形支撑架均选择三根支撑杆,这样对通过面积影响最小并能节省材料,且直径设计上要保证具有一定的强度和刚度以有效支撑中心杆状金属电极。而且,三个支撑杆下游都会形成对称的回流区和低流速区,从而延长尾气驻留时间,使得对尾气电离处理更充分。Therefore, in this utility model, three support rods are selected for each group of "herringbone"-shaped support frames, which has the least impact on the passing area and can save materials, and the diameter design must ensure a certain strength and rigidity to effectively support the central rod-shaped metal electrodes. Moreover, symmetrical recirculation zones and low-velocity zones will be formed downstream of the three support rods, thereby prolonging the residence time of the exhaust gas and making the ionization treatment of the exhaust gas more sufficient.
DBD排气管工作时,利用汽车自带的车载电瓶供电,通过变电器将车载电瓶的连续直流电压转变为微秒、毫秒脉冲电压或高频交流电压中的一种,并通过导线施加于DBD排气管电极上,将在中心绝缘套管和外管状金属电极之间形成介质阻挡放电,汽车发动机排放的气体通过一段管路(管状接头)后进入DBD排气管,在流经放电区域时被电离而形成典型的非平衡等离子体,其中发生一系列放电反应和传统化学反应,减少或消除有害气体和固体颗粒,从而形成清洁的尾气并排入大气。由于汽车起步、熄火以及不同档位等不同工况下尾气状态不同,为此可以在尾气车口利用手持式烟气分析仪对经过处理的尾气进行检测,将烟气分析仪的测量探头深入排气管末端管内即可测量产物中CO、NO、NO2、SO、SO2等物质浓度;再通过车载电源调节器条件施加于DBD排气管上的放电参数,并利用烟气分析仪监测尾气成分浓度变化,从而实现最优的电源控制。When the DBD exhaust pipe is working, it is powered by the vehicle’s own battery, and the continuous DC voltage of the vehicle battery is converted into one of microsecond, millisecond pulse voltage or high-frequency AC voltage through a transformer, and applied to the DBD through a wire. On the exhaust pipe electrode, a dielectric barrier discharge will be formed between the central insulating sleeve and the outer tubular metal electrode. The gas discharged from the automobile engine will enter the DBD exhaust pipe after passing through a section of pipeline (tubular joint). When flowing through the discharge area It is ionized to form a typical non-equilibrium plasma, in which a series of discharge reactions and traditional chemical reactions occur, reducing or eliminating harmful gases and solid particles, thereby forming a clean tail gas and discharging it into the atmosphere. Since the state of the exhaust gas is different under different working conditions such as starting, turning off the engine, and different gears, a handheld flue gas analyzer can be used to detect the processed exhaust gas at the exhaust port. The concentration of CO, NO, NO 2 , SO, SO 2 and other substances in the product can be measured in the end pipe of the trachea; then the discharge parameters applied to the DBD exhaust pipe are applied to the discharge parameters of the DBD exhaust pipe through the on-board power regulator, and the exhaust gas is monitored by the flue gas analyzer Component concentrations vary, allowing for optimal power control.
实施过程Implementation process
以某汽油车为例,当汽车发动机工作时燃料与空气发生反应,正常燃烧时生成CO2和H2O和过量的氧等物质,但是由于燃料中含有杂质,且燃料燃烧常常不完全,使得会排放出一些有害物质,主要是CO、NO、NO2以及一些碳颗粒。当发动机气动后通过车载电源调节器打开一体化汽车尾气净化装置,尾气离开发动机后不久立即进入一体化汽车尾气净化装置发生放电反应,其中电子碰撞反应速率常常远高于传统燃烧化学反应,非常有利于快速形成O、N、OH等活性基团并继续发生氧化反应等,例如:放电电离反应e+O2⟶e+O+O、e+N2⟶e+N+N,电离产生的活性粒子发生一系列氧化反应、还原反应O+CO⟶CO2、N + NO ⟶ O + N2、N + NO2=> O + O + N2、N + NO2 => N2 + O2、O + NO => N + O2、O + N2O => N2 + O2,从而达到净化尾气中的主要污染物CO、NO、NO2的目的。另外,尾气中的碳颗粒主要是碳黑以及一些金属氧化物等颗粒,碳黑和金属氧化物具有一定的导电性,施加放电后这些颗粒会按照各自带电状态分别定向运动并吸附在外管状金属电极和中心绝缘套管表面,由于一体化汽车尾气净化装置采用了模块化设计,当两者表面沉积杂质较多后可以拆除外管状金属电极后对两者内外表面进行清洗,再安装后继续使用。在尾气处理过程中可以利用手持式烟气分析仪在线监测尾气有害物CO、NO等物质浓度,当发现其浓度较高时,操作车载电源调节器,改变放电电压、脉冲频率、脉冲宽度等参数,从而改变放电特性,进而达到改变尾气有害物浓度效果,当调节放电参数后发现监测的尾气有害物浓度已经达标,即可保持该调节参数不变,否则继续改变调节参数直至尾气有害物浓度达标。Taking a gasoline car as an example, when the car engine is working, the fuel reacts with the air, and produces CO 2 and H 2 O and excess oxygen during normal combustion. However, because the fuel contains impurities and the fuel is often incompletely burned, the Some harmful substances will be emitted, mainly CO, NO, NO 2 and some carbon particles. When the engine is aerodynamically activated, the integrated vehicle exhaust gas purification device is turned on through the on-board power regulator, and the exhaust gas enters the integrated vehicle exhaust gas purification device shortly after leaving the engine to undergo a discharge reaction. The electron collision reaction rate is often much higher than the traditional combustion chemical reaction, which is very effective. It is conducive to the rapid formation of active groups such as O, N, OH and continued oxidation reactions, such as: discharge ionization reaction e+O 2 ⟶e+O+O, e+N 2 ⟶e+N+N, the activity generated by ionization Particles undergo a series of oxidation reactions and reduction reactions O+CO⟶CO 2 , N + NO ⟶ O + N 2 , N + NO 2 => O + O + N 2 , N + NO 2 => N 2 + O 2 , O + NO => N + O 2 , O + N 2 O => N 2 + O 2 , so as to achieve the purpose of purifying the main pollutants CO, NO, and NO 2 in the tail gas. In addition, the carbon particles in the exhaust gas are mainly carbon black and some metal oxides. Carbon black and metal oxides have certain conductivity. After the discharge is applied, these particles will move directionally according to their respective charged states and be adsorbed on the outer tubular metal electrode. And the surface of the central insulating sleeve, because the integrated automobile exhaust purification device adopts a modular design, when there are many impurities deposited on the two surfaces, the outer tubular metal electrode can be removed and the inner and outer surfaces of the two can be cleaned, and then continue to be used after installation. During the exhaust gas treatment process, the handheld flue gas analyzer can be used to monitor the concentration of harmful substances such as CO and NO in the exhaust gas online. When the concentration is found to be high, the on-board power regulator can be operated to change the discharge voltage, pulse frequency, pulse width and other parameters. , so as to change the discharge characteristics, and then achieve the effect of changing the concentration of harmful substances in the exhaust gas. When the discharge parameters are adjusted, it is found that the concentration of harmful substances in the exhaust gas has reached the standard, and the adjustment parameters can be kept unchanged. Otherwise, continue to change the adjustment parameters until the concentration of harmful substances in the exhaust gas reaches the standard .
以上详细描述了本实用新型的优选实施方式,但是,本实用新型并不限于上述实施方式中的具体细节,在本实用新型的技术构思范围内,可以对本实用新型的技术方案进行多种等同变换,这些等同变换均属于本实用新型的保护范围。The preferred embodiment of the utility model has been described in detail above, but the utility model is not limited to the specific details in the above-mentioned embodiment, and within the scope of the technical concept of the utility model, various equivalent transformations can be carried out to the technical solution of the utility model , these equivalent transformations all belong to the protection scope of the present utility model.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201920503955.7U CN209781006U (en) | 2019-04-15 | 2019-04-15 | Integrated automobile exhaust purification device based on dielectric barrier discharge |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201920503955.7U CN209781006U (en) | 2019-04-15 | 2019-04-15 | Integrated automobile exhaust purification device based on dielectric barrier discharge |
Publications (1)
Publication Number | Publication Date |
---|---|
CN209781006U true CN209781006U (en) | 2019-12-13 |
Family
ID=68802560
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201920503955.7U Active CN209781006U (en) | 2019-04-15 | 2019-04-15 | Integrated automobile exhaust purification device based on dielectric barrier discharge |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN209781006U (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109854342A (en) * | 2019-04-15 | 2019-06-07 | 中国人民解放军战略支援部队航天工程大学 | All-in-one car exhaust gas cleaner based on dielectric barrier discharge |
-
2019
- 2019-04-15 CN CN201920503955.7U patent/CN209781006U/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109854342A (en) * | 2019-04-15 | 2019-06-07 | 中国人民解放军战略支援部队航天工程大学 | All-in-one car exhaust gas cleaner based on dielectric barrier discharge |
CN109854342B (en) * | 2019-04-15 | 2023-11-21 | 中国人民解放军战略支援部队航天工程大学 | Integrated automobile exhaust purification device based on dielectric barrier discharge |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Okubo et al. | NO/sub x/reduction after treatment system using nitrogen nonthermal plasma desorption | |
CN100503017C (en) | Integrated vehicle exhaust purification device with photocatalysis and plasma action | |
CN105927316B (en) | A kind of vehicle exhaust double purification device and its course of work | |
CN101835336A (en) | A Double Dielectric Barrier Discharge Low Temperature Plasma Generator | |
WO1992019361A1 (en) | Exhaust treatment system and method | |
CN101415292A (en) | Honeycomb medium countercheck discharging low-temperature plasma generator | |
CN201588711U (en) | A plasma generator for improving combustion efficiency of internal combustion engine | |
CN101462021A (en) | Harmful gas conversion device with non-thermal plasma induced by dielectric barrier discharge | |
CN101344026A (en) | System for low temperature plasma pre-oxidizing NOx of auxiliary NH3-SCR fine purification diesel engine | |
CN109854342B (en) | Integrated automobile exhaust purification device based on dielectric barrier discharge | |
CN101391171B (en) | Low-temperature plasma purifier | |
CN204168579U (en) | A kind of two medium low-temperature plasma generator | |
CN209781006U (en) | Integrated automobile exhaust purification device based on dielectric barrier discharge | |
US20230332564A1 (en) | Intake plasma generator systems and methods | |
CN101219338A (en) | A low-temperature plasma automobile exhaust purification device | |
CN104219863A (en) | Double-medium low-temperature plasma generator | |
CN110385020A (en) | Spininess coaxial-type electric discharge removal methods and reactor for removal of nitrogen oxide | |
CN102166474A (en) | Low-temperature plasma cooperating two-phase catalyzing device and harmful exhaust gas processing method | |
CN216171267U (en) | Wall Flow Dielectric Barrier Discharge Purification Diesel Engine Exhaust Treatment Device | |
CN104062154B (en) | Sampling device of collaborative particulates of low-temperature plasma generator and sampling method | |
RU123463U1 (en) | EXHAUST GAS CLEANING DEVICE | |
NL2033965B1 (en) | Low-temperature plasma device for treating dioxin | |
RU154119U1 (en) | DEVICE FOR CLEANING AND RECYCLING EXHAUST GASES | |
CN217410313U (en) | A low temperature plasma device for dioxin treatment | |
CN203108410U (en) | Processing device and processing system for nonuniform field intensity plasma waste gas |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GR01 | Patent grant | ||
GR01 | Patent grant |