CN209605166U - Dangerous waste incineration and smoke processing system - Google Patents

Dangerous waste incineration and smoke processing system Download PDF

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Publication number
CN209605166U
CN209605166U CN201920095466.2U CN201920095466U CN209605166U CN 209605166 U CN209605166 U CN 209605166U CN 201920095466 U CN201920095466 U CN 201920095466U CN 209605166 U CN209605166 U CN 209605166U
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China
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activated coke
flue gas
smoke
tower
desulphurization denitration
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何军凯
熊辉
刘力奇
常晓然
虢德威
鲁文涛
芮海锋
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Beijing Geoenviron Engineering and Technology Inc
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Beijing Geoenviron Engineering and Technology Inc
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/30Technologies for a more efficient combustion or heat usage

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Abstract

The utility model discloses a kind of dangerous waste incineration and smoke processing systems, including sequentially connected rotary kiln, dual firing chamber, waste heat boiler, chilling tower, activated coke combined desulfurization and denitration device, bag filter and blowdown stack;Waste heat boiler is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end, and high-temperature flue gas import end is connected to the smoke outlet of dual firing chamber, and low-temperature flue gas outlet end is connected to the smoke inlet and activated coke combined desulfurization and denitration device of chilling tower;It is equipped with material pit at the feed inlet of rotary kiln, driving system is equipped with above material pit, driving system is grabbed for hanging the waste material in material pit into rotary kiln.Simplify the process flow of hazardous waste more, without using raw materials such as calcium hydroxide, liquid alkaline, urea, reduce resource consumption, do not generate brine waste, reduce treatment pressure of sewage and cost, meets resources circulation use, the requirement of cascaded utilization of energy.

Description

Dangerous waste incineration and smoke processing system
Technical field
The utility model belongs to waste incineration and filed of flue gas purification, more particularly, to a kind of dangerous waste incineration and Smoke processing system.
Background technique
With the exacerbation that earth environment pollutes, country is increasingly stringenter the supervision of environmental protection, makes the row of domestic incineration tail gas Put standard towards minimum discharge trend development.In recent years, as hazardous waste handles putting more effort for disposition, hazardous waste Burning amount increases severely.Current semidry method or dry method adds being applied in combination for wet desulphurization and SNCR/SCR denitration technology, Neng Goushi Existing minimum discharge, but the flue gas " Mao Bai " discharged after wet process depickling, and a large amount of waste water are generated, SNCR/SCR denitration technology needs Consume the raw materials such as urea and ammonium hydroxide, and equipment caused to corrode, process flow there are the shortcomings that it is as follows:
1) dry method adds wet desulphurization or semi-dry desulphurization need to use a variety of desulfurizing agents such as a large amount of calcium hydroxide, liquid alkaline, raw It produces at high cost;And wet desulphurization can generate a large amount of saline sewage, to saline sewage, there are no good processing methods at present, dirty Water process difficulty is big, further increases production cost;
2) denitration technologies such as SNCR/SCR more mature at present are needed using raw materials such as a large amount of urea or ammonium hydroxide, and Reaction condition is harsher, control it is bad will cause the escaping of ammonia, secondary pollution is formed, along with making for urea liquid or ammonium hydroxide With will increase pipeline blockage, equipment corrosion risk;
3) process flow is longer, increases smoke flow resistance, the control of index is seriously lagged.
Therefore, it is necessary to develop a kind of dangerous waste incineration and smoke processing systems to keep away while simplifying process flow Exempt from because generating exhaust gas and waste water, and form secondary pollution, and avoid equipment corrosion, reduces the processing cost of hazardous waste, And it can be realized the recycling of the energy, energy conservation and environmental protection.
Utility model content
The purpose of the utility model is to provide a kind of dangerous waste incineration and smoke processing system, without using calcium hydroxide, Under the premise of the raw materials such as liquid alkaline, urea, simplifies the process flow of hazardous waste more, reduce resource consumption, do not generate saliferous Waste water reduces treatment pressure of sewage and cost, meets resources circulation use, the requirement of cascaded utilization of energy.
To achieve the goals above, the utility model provides a kind of dangerous waste incineration and smoke processing system, including according to Rotary kiln, dual firing chamber, waste heat boiler, chilling tower, activated coke combined desulfurization and denitration device, bag filter and the discharge of secondary connection Chimney;
The waste heat boiler is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end, and the high-temperature flue gas import end connects Be connected to the smoke outlet of the dual firing chamber, the low-temperature flue gas outlet end be connected to the chilling tower smoke inlet and the activated coke Combined desulfurization and denitration device;
It is equipped with material pit at the feed inlet of the rotary kiln, is equipped with driving system, the vehicle-driving above the material pit System is grabbed for hanging the waste material in the material pit into the rotary kiln.
Preferably, the activated coke combined desulfurization and denitration device includes desulphurization denitration tower, active coke regeneration device and by-product Object collection device, the desulphurization denitration tower is equipped with smoke inlet, exhanst gas outlet and activated coke entrance, activated coke exports, described Smoke inlet is connected to the smoke outlet of the chilling tower, and the exhanst gas outlet is connected to the entrance of the bag filter;
The active coke regeneration device includes heating cabinet and the activated coke being set to inside the heating cabinet regenerates storehouse, described Heating cabinet is equipped with hot fume import and cold flue gas exports, and activated coke regeneration storehouse is equipped with exhaust outlet, feed inlet and discharging Mouthful, the hot fume import is connected to the smoke outlet of the waste heat boiler, and the cold flue gas outlet is connected to two combustion Room, the activated coke outlet of the desulphurization denitration tower are connected to the feed inlet in activated coke regeneration storehouse, and the activated coke regenerates storehouse Discharge port be connected to the activated coke entrance of the desulphurization denitration tower, the exhaust outlet is connected to the byproduct collection device.
Preferably, in the activated coke combined desulfurization and denitration device include at least two desulphurization denitration towers, described at least two A desulphurization denitration tower is parallel with one another.
Preferably, the activated coke combined desulfurization and denitration device further includes ammonia spirit injection apparatus, the ammonia spirit Injection apparatus is connected to the desulphurization denitration tower.
Preferably, the activated coke inlet of the desulphurization denitration tower is equipped with activated coke adding set, the activated coke entrance It is connect with the activated coke adding set by carrier bar, the discharge port and the activated coke adding set in activated coke regeneration storehouse It is connected by carrier bar.
Preferably, stop valve is equipped at the smoke inlet of the desulphurization denitration tower, the activated coke of the desulphurization denitration tower goes out Pass through conveyer between mouth and the feed inlet in activated coke regeneration storehouse to connect.
Preferably, it is equipped with flue gas on-line continuous monitoring device between the bag filter and the blowdown stack, is used for Monitor smoke components.
The utility model has the beneficial effects that:
1, desulphurization denitration is carried out using activated coke combined desulfurization and denitration device in this processing system, without in addition setting desulfurization Equipment and denitration device simplify process flow more;Using active coke desulphurizing denitration, calcium hydroxide, liquid alkaline, urea etc. are not needed Raw material reduces resource consumption, does not generate brine waste, reduces treatment pressure of sewage and cost;Waste heat boiler utilizes dual firing chamber High-temperature flue gas as production and life needed for heat source, and using heat exchange after low-temperature flue gas be activated coke combined desulfurization and denitration Device heating, is not required to heating device is arranged in the processing system, and meets that resources circulation uses, cascaded utilization of energy is wanted It asks.
2, the activated coke in desulphurization denitration tower, which can enter in active coke regeneration device, carries out thermal desorption regeneration and is recycled, Processing cost is reduced, while the high-concentration sulfur-containing body containing niter air adsorbed in activated coke can be collected during thermal desorption As industrial chemicals, resource is made full use of;It can return in dual firing chamber and be heated for the flue gas that active coke regeneration device heats, Dioxin is further decomposed, prevents flue gas from getting into the air and pollutes environment.
3, at least two desulphurization denitration towers are arranged in parallel in activated coke combined desulfurization and denitration device, a part uses another Part switches to stand-by still after wherein using tower adsorption saturation and continues to adsorb as spare, and by adsorption saturation Activated coke, which is expelled in active coke regeneration device, carries out regeneration treatment, is back in desulphurization denitration tower after being disposed, multiple de- Sulphur denitrating tower is recycled, and guarantees the continuity for the treatment of process.
4, ammonia spirit injection apparatus is set in desulphurization denitration tower, increases by one section of spray ammonia reaction zone, by activated coke and SCR phase In conjunction with activated coke is mainly physical adsorption and chemical adsorption to the removing of nitrogen oxides, in addition containing a large amount of in activated coke hole Functional group, these functional groups can be catalyzed well ammonia and be reacted with nitrogen oxides, and the combination of two kinds of technique, effect is more excellent, Further decrease discharged nitrous oxides.
Other features and advantages of the utility model will then part of the detailed description can be specified.
Detailed description of the invention
The utility model illustrative embodiments are described in more detail in conjunction with the accompanying drawings, the utility model it is upper It states and other purposes, feature and advantage will be apparent, wherein in the utility model illustrative embodiments, phase Same reference label typically represents same parts.
Fig. 1 shows the signal of the dangerous waste incineration and smoke processing system of one embodiment according to the present utility model Figure.
Fig. 2 shows the schematic diagrames of the activated coke combined desulfurization and denitration device of one embodiment according to the present utility model.
Description of symbols
1, material pit;2, driving system;3, rotary kiln;4, dual firing chamber;5, waste heat boiler;6, chilling tower;7, activated coke joins Close desulfuring and denitrifying apparatus;8, bag filter;9, blowdown stack;10, desulphurization denitration tower;11, activated coke adding set;12, living Property coke regenerating unit;13, byproduct collection device;14, valve;15, smoke inlet;16, exhanst gas outlet.
Specific embodiment
Preferred embodiments of the present invention are described in more detail below.Although the following describe the utility model Preferred embodiment, however, it is to be appreciated that may be realized in various forms the utility model without the implementation that should be illustrated here Mode is limited.On the contrary, thesing embodiments are provided so that the utility model is more thorough and complete, and can be by this The range of utility model is completely communicated to those skilled in the art.
Dangerous waste incineration and smoke processing system according to the present utility model, including sequentially connected rotary kiln, two combustions Room, waste heat boiler, chilling tower, activated coke combined desulfurization and denitration device, bag filter and blowdown stack;
Waste heat boiler is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end, and high-temperature flue gas import end is connected to two combustions The smoke outlet of room, low-temperature flue gas outlet end are connected to the smoke inlet and activated coke combined desulfurization and denitration device of chilling tower;
It is equipped with material pit at the feed inlet of rotary kiln, driving system is equipped with above material pit, driving system is used for storing Waste material in hole, which is hung, grabs into rotary kiln.
In the waste heat boiler of the utility model, in addition to above-mentioned high-temperature flue gas import end and low-temperature flue gas outlet end, also set up There are water inlet end and steam outlet end, for exchanging heat with high-temperature flue gas, to realize the utilization of waste heat.
Specifically, desulphurization denitration is carried out using activated coke combined desulfurization and denitration device in this processing system, without in addition setting Desulphurization plant and denitration device are set, simplifies process flow more;Using active coke desulphurizing denitration, do not need calcium hydroxide, liquid alkaline, The raw materials such as urea reduce resource consumption, do not generate brine waste, reduce treatment pressure of sewage and cost;Waste heat boiler utilizes Heat source of the high-temperature flue gas of dual firing chamber as production and needed for living, and be that activated coke joint is de- using the low-temperature flue gas after heat exchange The heating of sulphur denitrification apparatus, is not required to that heating device is arranged in the processing system, and meets resources circulation use, cascaded utilization of energy Requirement.
Preferably, activated coke combined desulfurization and denitration device includes desulphurization denitration tower, active coke regeneration device and pair Collection of products device, desulphurization denitration tower is equipped with smoke inlet, exhanst gas outlet and activated coke entrance, activated coke exports, and flue gas enters Mouth is connected to the smoke outlet of chilling tower, and exhanst gas outlet is connected to the entrance of bag filter;
Active coke regeneration device includes heating cabinet and the activated coke being set to inside heating cabinet regeneration storehouse, and heating cabinet is equipped with Hot fume import and cold flue gas outlet, activated coke regenerate storehouse and are equipped with exhaust outlet, inlet port and outlet port, hot fume import connection In the low-temperature flue gas outlet end of waste heat boiler, cold flue gas outlet is connected to dual firing chamber, and the activated coke of desulphurization denitration tower exports connection The discharge port of feed inlet in activated coke regeneration storehouse, activated coke regeneration storehouse is connected to the activated coke entrance of desulphurization denitration tower, exhaust Mouth is connected to byproduct collection device.
Specifically, the activated coke in desulphurization denitration tower, which can enter in active coke regeneration device, carries out thermal desorption regeneration and recycles It uses, reduces processing cost, while the high-concentration sulfur-containing body containing niter air adsorbed in activated coke can be received during thermal desorption Collect as industrial chemicals, resource has been made full use of;For active coke regeneration device heating flue gas can return in dual firing chamber into Row heating, further decomposes dioxin, prevents flue gas from getting into the air and pollute environment.
Preferably, in activated coke combined desulfurization and denitration device include at least two desulphurization denitration towers, at least two Desulphurization denitration tower is parallel with one another.
Specifically, at least two desulphurization denitration towers are arranged in parallel in activated coke combined desulfurization and denitration device, a part makes Another part is used to switch to stand-by still after wherein using tower adsorption saturation and continue to adsorb as spare, and will absorption The activated coke of saturation, which is expelled in active coke regeneration device, carries out regeneration treatment, is back in desulphurization denitration tower after being disposed, Multiple desulphurization denitration towers are recycled, and guarantee the continuity for the treatment of process.
Preferably, activated coke combined desulfurization and denitration device further includes ammonia spirit injection apparatus, ammonia spirit spray Injection device is connected to desulphurization denitration tower.
Specifically, ammonia spirit injection apparatus is set in desulphurization denitration tower, increases by one section of spray ammonia reaction zone, by activated coke and SCR is combined, and activated coke is mainly physical adsorption and chemical adsorption to the removing of nitrogen oxides, is in addition contained in activated coke hole A large amount of functional group, these functional groups can be catalyzed well ammonia and be reacted with nitrogen oxides, and the combination of two kinds of technique, effect is more It is excellent, further decrease discharged nitrous oxides.
Preferably, the activated coke inlet of desulphurization denitration tower be equipped with activated coke adding set, activated coke entrance with Activated coke adding set is connected by carrier bar, and the discharge port in activated coke regeneration storehouse is connect with activated coke adding set by carrier bar.
Preferably, stop valve is equipped at the smoke inlet of desulphurization denitration tower, the activated coke of desulphurization denitration tower exports It is connect between the feed inlet in activated coke regeneration storehouse by conveyer.
Preferably, flue gas on-line continuous monitoring device is equipped between bag filter and blowdown stack, for supervising Survey smoke components, feedback control system for desulfuration and denitration, to guarantee flue gas qualified discharge.
The dangerous waste incineration and flue gas processing method packet carried out using above-mentioned dangerous waste incineration and smoke processing system Include following steps:
1) hazardous waste in material pit is hung to grab using driving system and is burned into rotary kiln, hazardous waste is returning Harmful smoke and waste residue containing dioxin are generated through pyrolysis in rotary kiln, waste residue is discharged by rotary kiln bottom, and harmful smoke enters Dual firing chamber;
2) high-temperature flue gas is emitted into waste heat boiler changes later by harmful smoke through pyrolytic in dual firing chamber Heat, obtained low-temperature flue gas are discharged into chilling tower and further cool down;
3) low-temperature flue gas after cooling enters the progress desulphurization denitration processing of activated coke combined desulfurization and denitration device;
4) through desulphurization denitration, treated that flue gas enters purifying and dedusting in bag filter;
5) it after purifying and dedusting to discharge standard, is discharged through blowdown stack.
The step of desulphurization denitration processing is wherein carried out in activated coke combined desulfurization and denitration device are as follows:
3.1) activated coke is added into desulphurization denitration tower by activated coke entrance, is later discharged into flue gas by smoke inlet In desulphurization denitration tower, desulphurization denitration is carried out using the adsorption function of activated coke, the flue gas after the completion of adsorbing is entered by exhanst gas outlet To next processing step;
3.2) it is exported and is discharged by activated coke after activated coke adsorption saturation, enter activated coke regeneration storehouse, waste heat pot through feed inlet The flue gas of the low-temperature flue gas outlet end of furnace enters heating cabinet by hot fume import, adds indirectly to the activated coke in activated coke regeneration storehouse Heat is allowed to regenerate through thermal desorption;
3.3) gas generated in thermal desorption regenerative process enters byproduct collection device through exhaust outlet, and it is former to be used as chemical industry Material;
3.4) after completing heating, the flue gas in heating cabinet is exported by cold flue gas to be discharged, and is returned in dual firing chamber and is carried out at heating Reason, further decomposes dioxin;
3.5) activated coke after thermal desorption regenerates is discharged by discharge port, returns to weight in desulphurization denitration tower through activated coke entrance It is multiple to utilize.
Wherein, the heating temperature in dual firing chamber is at least 1100 DEG C, and the heating temperature in active coke regeneration device is 380 ℃-420℃。
Embodiment 1
Fig. 1 shows the schematic diagram of dangerous waste incineration and smoke processing system according to the present embodiment;Fig. 2 shows roots According to the schematic diagram of the activated coke combined desulfurization and denitration device of the present embodiment.
As shown in Figure 1 to Figure 2, the dangerous waste incineration and smoke processing system, including sequentially connected rotary kiln 3, two Fire room 4, waste heat boiler 5, chilling tower 6, activated coke combined desulfurization and denitration device 7, bag filter 8 and blowdown stack 9;Rotary kiln It is equipped with material pit 1 at 3 feed inlet, driving system 2 is equipped with above material pit 1, driving system 2 is used for will be useless in material pit 1 Material, which is hung, grabs into rotary kiln 3;Waste heat boiler 5 is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end;Wherein, activated coke joins Closing desulfuring and denitrifying apparatus 7 includes two desulphurization denitration towers 10, active coke regeneration device 12 and byproduct collection device 13, and two de- Sulphur denitrating tower 10 is parallel with one another, and each desulphurization denitration tower 10 is equipped with smoke inlet 15, exhanst gas outlet 16 and activated coke entrance, work Property coke outlet, stop valve is equipped at smoke inlet 15, smoke inlet 15 is connected to the smoke outlet of chilling tower 6, and exhanst gas outlet 16 connects It is connected to the entrance of bag filter 8;Active coke regeneration device 12 include heating cabinet and the activated coke that is set to inside heating cabinet again Raw storehouse, heating cabinet is equipped with hot fume import and cold flue gas exports, and activated coke regenerates storehouse and is equipped with exhaust outlet, feed inlet and discharging Mouthful, hot fume import is connected to the low-temperature flue gas outlet end of waste heat boiler 5, and cold flue gas outlet is connected to dual firing chamber 4, desulphurization denitration The activated coke outlet of tower 10 is connected to the feed inlet that activated coke regenerates storehouse by conveyer, and activated coke regenerates the discharge port connection in storehouse In activated coke adding set 11, activated coke adding set 11 is connected to the activated coke entrance on desulphurization denitration tower 10 by pipeline, Pipeline is equipped with valve 14, and exhaust outlet is connected to byproduct collection device 13, and the gas being collected into is used as industrial chemicals;Waste heat pot Furnace 5 be used for UTILIZATION OF VESIDUAL HEAT IN, between bag filter 8 and blowdown stack 9 be equipped with continuous flue gas monitoring device, for monitor flue gas at Point.
Hazardous waste in material pit 1 is hung to grab into rotary kiln 3 using driving system 2 and is burned, hazardous waste exists Harmful smoke and waste residue containing dioxin are generated through pyrolysis in rotary kiln 3, waste residue is discharged by 3 bottom of rotary kiln, harmful smoke Into dual firing chamber 4, in dual firing chamber 4 after pyrolytic, high-temperature flue gas is emitted into waste heat boiler 5 and is exchanged heat, is obtained To low-temperature flue gas be discharged into chilling tower 6 and further cool down;Low-temperature flue gas after cooling enters desulphurization denitration tower 10, utilizes desulfurization Active coke desulphurizing denitration in denitrating tower 10;Two desulphurization denitration towers 10, the using and the reserved are cut after one of tower adsorption saturation It shifts to another tower to continue, while the activated coke of adsorption saturation being exported from the activated coke of desulphurization denitration tower 10 and is discharged, Active coke regeneration device 12 is transported to by conveyer and carries out thermal desorption regeneration treatment, the heat source in activated coke regenerative process are as follows: will Activated coke is regenerated in storehouse and has been inhaled by (about 550 DEG C) introducing heating cabinets of partial fume of the low-temperature flue gas outlet end of waste heat boiler 5 The activated coke indirect heating of attached saturation is to carrying out thermal desorption between 380 DEG C -420 DEG C;Low-temperature flue gas after exchanging heat in heating cabinet It is returned in dual firing chamber 4 from hot fume outlet, it is using 1100 DEG C or more of high temperature of dual firing chamber 4, the dioxin in flue gas is complete It decomposes, avoids pollution environment;Activated coke after being disposed loads sulphur denitrating tower back off by activated coke adding set 11 again In 10, two desulphurization denitration towers 10 are recycled;Desulphurization denitration tower 10 is arranged before bag filter 8, can remove some larger The flue dust of particle, then after bag filter 8 filters dust, can directly be discharged by blowdown stack 9, exhaust temperature is 160 DEG C -170 DEG C, avoid " Mao Baiyan ";Activated coke in activated coke combined desulfurization and denitration device 7 can be recycled, still The treatment effect of flue gas is declined after being recycled for multiple times, needs to re-replace activated coke, with specific reference to practical execution.
Embodiment 2
Fig. 1 shows the schematic diagram of dangerous waste incineration and smoke processing system according to the present embodiment;Fig. 2 shows roots According to the schematic diagram of the activated coke combined desulfurization and denitration device of the present embodiment.
As shown in Figure 1 to Figure 2, the dangerous waste incineration and smoke processing system, including sequentially connected rotary kiln 3, two Fire room 4, waste heat boiler 5, chilling tower 6, activated coke combined desulfurization and denitration device 7, bag filter 8 and blowdown stack 9;Rotary kiln It is equipped with material pit 1 at 3 feed inlet, driving system 2 is equipped with above material pit 1, driving system 2 is used for will be useless in material pit 1 Material, which is hung, grabs into rotary kiln 3;Waste heat boiler 5 is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end;Wherein, activated coke joins Closing desulfuring and denitrifying apparatus 7 includes two desulphurization denitration towers 10, ammonia spirit injection apparatus, active coke regeneration device 11 and by-product Collection device 12, two desulphurization denitration towers 10 are parallel with one another, and each desulphurization denitration tower 10 is equipped with smoke inlet 15, exhanst gas outlet 16 and activated coke entrance, activated coke outlet, stop valve is equipped at smoke inlet 15, smoke inlet 15 is connected to the row of chilling tower 6 Mouth, exhanst gas outlet 16 are connected to the entrance of bag filter 8, and ammonia spirit injection apparatus is connected to desulphurization denitration tower 10;It is living Property coke regenerating unit 12 include heating cabinet and the activated coke being set to inside heating cabinet regeneration storehouse, heating cabinet be equipped with hot fume into Mouth and cold flue gas outlet, activated coke regenerate storehouse and are equipped with exhaust outlet, inlet port and outlet port, and hot fume import is connected to waste heat pot The low-temperature flue gas outlet end of furnace 5, cold flue gas outlet are connected to dual firing chamber 4, and the activated coke outlet of desulphurization denitration tower 10 passes through conveying Machine is connected to the feed inlet in activated coke regeneration storehouse, and the discharge port in activated coke regeneration storehouse is connected to activated coke adding set 11, activity Burnt adding set 11 is connected to the activated coke entrance on desulphurization denitration tower 10 by pipeline, and pipeline is equipped with valve 14, exhaust outlet It is connected to byproduct collection device 13, the gas being collected into is used as industrial chemicals;Waste heat boiler 5 is used for UTILIZATION OF VESIDUAL HEAT IN, and cloth bag removes Continuous flue gas monitoring device is equipped between dirt device 8 and blowdown stack 9, for monitoring smoke components.
Hazardous waste in material pit 1 is hung to grab into rotary kiln 3 using driving system 2 and is burned, hazardous waste exists Harmful smoke and waste residue containing dioxin are generated through pyrolysis in rotary kiln 3, waste residue is discharged by 3 bottom of rotary kiln, harmful smoke Into dual firing chamber 4, in dual firing chamber 4 after pyrolytic, high-temperature flue gas is emitted into waste heat boiler 5 and is exchanged heat, is obtained To low-temperature flue gas be discharged into chilling tower 6 and further cool down;Low-temperature flue gas after cooling enters desulphurization denitration tower 10, utilizes desulfurization Active coke desulphurizing denitration in denitrating tower 10;Two desulphurization denitration towers 10, the using and the reserved are cut after one of tower adsorption saturation It shifts to another tower to continue, while the activated coke of adsorption saturation being exported from the activated coke of desulphurization denitration tower 10 and is discharged, Active coke regeneration device 12 is transported to by conveyer and carries out thermal desorption regeneration treatment, the heat source in activated coke regenerative process are as follows: will Activated coke is regenerated in storehouse and has been inhaled by (about 550 DEG C) introducing heating cabinets of partial fume of the low-temperature flue gas outlet end of waste heat boiler 5 The activated coke indirect heating of attached saturation to being desorbed between 380 DEG C -420 DEG C, the low-temperature flue gas after exchanging heat in heating cabinet from Cold flue gas outlet returns in dual firing chamber 4, and using 1100 DEG C or more of high temperature of dual firing chamber 4, the dioxin in flue gas is divided completely Solution, avoids pollution environment;Using activated coke physical absorption and chemisorption function nitrogen oxides is removed while, Ammonia is sprayed into the flue gas of desulphurization denitration tower using ammonia spirit injection apparatus, utilizes a large amount of function contained in activated coke hole Group, catalysis ammonia are reacted with nitrogen oxides, and the combination of two kinds of technique further realizes nitrogen oxides minimum discharge;It has handled Activated coke after finishing is loaded in sulphur denitrating tower 10 back off again by activated coke adding set 11, and two desulphurization denitration towers 10 recycle It uses;Desulphurization denitration tower 10 is arranged before bag filter 8, can remove the flue dust of some larger particles, then through bag filter 8 It after filtering dust, can directly be discharged by blowdown stack 9, exhaust temperature is 160 DEG C -170 DEG C, avoids " Mao Baiyan "; Activated coke used in activated coke combined desulfurization and denitration device 7 can be recycled, but to flue gas after being recycled for multiple times Treatment effect decline, needs to re-replace activated coke, with specific reference to practical execution.
Each embodiment of the utility model is described above, above description is exemplary, and non-exclusive, and And it is also not necessarily limited to disclosed each embodiment.Without departing from the scope and spirit of illustrated each embodiment, for Many modifications and changes are obvious for those skilled in the art.

Claims (7)

1. a kind of dangerous waste incineration and smoke processing system, which is characterized in that including sequentially connected rotary kiln, dual firing chamber, Waste heat boiler, chilling tower, activated coke combined desulfurization and denitration device, bag filter and blowdown stack;
The waste heat boiler is equipped with high-temperature flue gas import end and low-temperature flue gas outlet end, and the high-temperature flue gas import end is connected to The smoke outlet of the dual firing chamber, the low-temperature flue gas outlet end are connected to the smoke inlet and activated coke joint of the chilling tower Desulfuring and denitrifying apparatus;
It is equipped with material pit at the feed inlet of the rotary kiln, driving system is equipped with above the material pit, the driving system is used It grabs in hanging the waste material in the material pit into the rotary kiln.
2. dangerous waste incineration according to claim 1 and smoke processing system, which is characterized in that the activated coke joint Desulfuring and denitrifying apparatus includes desulphurization denitration tower, active coke regeneration device and byproduct collection device, is set on the desulphurization denitration tower There are smoke inlet, exhanst gas outlet and activated coke entrance, activated coke outlet, the smoke inlet is connected to the smoke evacuation of the chilling tower Mouthful, the exhanst gas outlet is connected to the entrance of the bag filter;
The active coke regeneration device includes heating cabinet and the activated coke being set to inside heating cabinet regeneration storehouse, the heating Storehouse is equipped with hot fume import and cold flue gas exports, and activated coke regeneration storehouse is equipped with exhaust outlet, inlet port and outlet port, institute The smoke outlet that hot fume import is connected to the waste heat boiler is stated, the cold flue gas outlet is connected to the dual firing chamber, institute The activated coke outlet for stating desulphurization denitration tower is connected to the feed inlet in activated coke regeneration storehouse, the discharging in activated coke regeneration storehouse Mouth is connected to the activated coke entrance of the desulphurization denitration tower, and the exhaust outlet is connected to the byproduct collection device.
3. dangerous waste incineration according to claim 2 and smoke processing system, which is characterized in that the activated coke joint It include at least two desulphurization denitration towers in desulfuring and denitrifying apparatus, at least two desulphurization denitrations tower is parallel with one another.
4. dangerous waste incineration according to claim 2 and smoke processing system, which is characterized in that the activated coke joint Desulfuring and denitrifying apparatus further includes ammonia spirit injection apparatus, and the ammonia spirit injection apparatus is connected to the desulphurization denitration tower.
5. dangerous waste incineration according to claim 2 and smoke processing system, which is characterized in that the desulphurization denitration tower Activated coke inlet be equipped with activated coke adding set, it is defeated that the activated coke entrance and the activated coke adding set pass through carrier bar Machine is sent to connect, the discharge port in activated coke regeneration storehouse is connect with the activated coke adding set by chain scraper conveyor.
6. dangerous waste incineration according to claim 5 and smoke processing system, which is characterized in that the desulphurization denitration tower Smoke inlet at be equipped with stop valve, the desulphurization denitration tower activated coke outlet with the activated coke regeneration storehouse feed inlet it Between pass through conveyer connect.
7. dangerous waste incineration according to claim 1 and smoke processing system, which is characterized in that the bag filter Flue gas on-line continuous monitoring device is equipped between the blowdown stack, for monitoring smoke components.
CN201920095466.2U 2019-01-21 2019-01-21 Dangerous waste incineration and smoke processing system Active CN209605166U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109708120A (en) * 2019-01-21 2019-05-03 北京高能时代环境技术股份有限公司 Dangerous waste incineration and smoke processing system and method
CN114452962A (en) * 2022-02-11 2022-05-10 青岛新太平洋节能环保集团有限公司 Active coke regeneration and tail gas treatment system and treatment process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109708120A (en) * 2019-01-21 2019-05-03 北京高能时代环境技术股份有限公司 Dangerous waste incineration and smoke processing system and method
CN114452962A (en) * 2022-02-11 2022-05-10 青岛新太平洋节能环保集团有限公司 Active coke regeneration and tail gas treatment system and treatment process thereof

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