CN209602413U - A kind of equipment handling unqualified material DMMn - Google Patents
A kind of equipment handling unqualified material DMMn Download PDFInfo
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- CN209602413U CN209602413U CN201920093350.5U CN201920093350U CN209602413U CN 209602413 U CN209602413 U CN 209602413U CN 201920093350 U CN201920093350 U CN 201920093350U CN 209602413 U CN209602413 U CN 209602413U
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- alkali cleaning
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Abstract
The utility model belongs to chemical process technical field, is related to a kind of device and method for handling unqualified material DMMn.Entire material recycle step includes that unqualified material generated after follow-up system and parking is passed through reaction, alkali cleaning, distillation system again, the a small amount of formaldehyde having in material, formic acid and water are removed, it ensure that the stability of material, it is ensured that follow-up system stable operation.Unqualified DMMn material can pass through caustic washing system, and a small amount of formaldehyde, formic acid and the water in material are removed, and both can guarantee that unqualified items material recycled, while also ensuring the yield of purpose product, while also reducing the loss of material waste and raw material.
Description
Technical field
The utility model belongs to chemical process technical field, is related to a kind of equipment for handling unqualified material DMMn material.
Background technique
The alcohol-ether fuel experimental rig of present utility model application people, mainly for the production of alcohol-ether fuel (DMMn) product, together
When can also produce the byproducts such as dimethoxym ethane, metaformaldehyde, designed capacity is 50,000 tons/year, and operating flexibility is 70~110%.This dress
Set mainly includes formaldehyde preparation unit, dimethoxym ethane preparation unit, metaformaldehyde synthesis unit and alcohol-ether fuel synthesis unit.
Formaldehyde preparation unit, as raw material, produces formaldehyde with methanol.Methanol and oxygen are under silver catalyst and 650 DEG C of high temperature
Dehydrogenation occurs, oxidation reaction generates formaldehyde gaseous mixture and generates the formalin of high concentration using absorption.
Dimethoxym ethane unit, as raw material, under the action of solid acid catalyst, by addition, is dehydrated instead with methanol and formaldehyde
Synthesizing dimethoxym ethane is answered, is then refining to obtain the dimethoxym ethane product of high concentration by processes such as flash distillation, rectifying again.
Metaformaldehyde synthesis unit is using the formaldehyde of formaldehyde unit processed production as raw material, in the effect of ionic-liquid catalyst
Lower progress TOX synthetic reaction generates TOX reaction gas, and since synthetic reaction is balanced reaction, TOX is dense in the TOX reaction gas of generation
Spend it is low, reaction gas need to by concentration, extraction, alkali cleaning, washing, a series of subtractive processes such as separate with extractant, finally obtain height
The metaformaldehyde product of concentration.
Alcohol-ether fuel synthesis unit is using dimethoxym ethane and metaformaldehyde as raw material, using Chinese Academy of Sciences's Lanzhou Chemical Physics
The Novel solid-catalyst of research institute's recent development reacts under certain temperature and pressure, generate alcohol-ether fuel, then using
With reactants separate, the operation such as depickling, light component recycling obtains the alcohol-ether fuel product of high-purity.
Alcohol-ether fuel is the common name of a substance, and skeleton symbol can indicate are as follows: CH3O (CH2O) nCH3(n is more than or equal to 1
Integer), wherein with application value n value range are as follows: 1≤n≤8.There are two the alcohol ether products of alcohol ether Workshop Production, point
It is not DMM2 and DMMn, wherein 20132 tons of DMM2 annual output, 29940 tons of DMMn annual output.In Conventional process and device
It has underproof DMMn material when parking to generate, the rate of recovery is low, causes material waste serious.
Summary of the invention
The utility model proposes a kind of novel unqualified material DMMn object of processing for the problem of traditional mode of production
The device and method of material.
In order to achieve the above object, the utility model is realized using following technical solutions:
Entire material recycle step includes passing through unqualified material generated after follow-up system and parking instead again
It answers, alkali cleaning, distillation system, a small amount of formaldehyde having in material, formic acid and water is removed, ensure that the stability of material, it is ensured that
Follow-up system stable operation.Unqualified DMMn material can pass through caustic washing system, and a small amount of formaldehyde, formic acid and the water in material are removed
It goes, both can guarantee that unqualified items material recycles, while also ensuring the yield of purpose product, while also reducing material waste
And the loss of raw material.
Device includes: caustic washing system, thick DMMn distillation system.
The caustic washing system includes entry mixers and caustic treater, alkali cleaning tank deck by flow container, coalescer, salkali waste flow container, institute
It states entry mixers to be set to before caustic treater, the caustic treater is set to entry mixers and alkali cleaning top by between flow container, institute
It states alkali cleaning tank deck and is set to caustic treater between salkali waste flow container by flow container, the coalescer is set to caustic treater and alkali cleaning top by liquid
Between tank, salkali waste flow container is set to alkali cleaning top after by flow container.
The distillation system includes first rectifying column, and Second distillation column, first rectifying column is in alkali cleaning tank deck by flow container and
Between two rectifying columns.
Preferably, the entry mixers branch mouth and the discharging of caustic treater bottom connect, the entry mixers branch mouth and benefit
The connection of alkali line, the caustic treater bottom discharging are divided into two-way, go entry mixers all the way, go salkali waste flow container, the alkali cleaning all the way
Tank deck discharging is connected with coalescer, and the coalescer is connect with alkali cleaning top by flow container.
Preferably, the first rectifying column charging is connected with alkali cleaning tank deck by flow container discharging, the first rectifying column
Top gas phase is connected with top gaseous phase condenser inlet, and top gaseous phase condensator outlet is connected with first rectifying column top by flow container
It connects, the discharging of first rectifying column bottom is connected with Second distillation column, and first rectifying column top is discharged by flow container to be connected with raw materials recovery；
Second distillation column feed inlet is connected with the discharging of first rectifying column tower reactor, and Second distillation column top gas phase and Second distillation column top condense
Device import is connected, and Second distillation column top condensator outlet is connected with Second distillation column top by flow container, Second distillation column top by
Flow container discharging is connected with raw materials recovery, and tower reactor is connected with product tower feeding pipe.
Preferably, the alkali cleaning tank deck is divided water packet to connect with salkali waste flow container by flow container, the alkali cleaning top by flow container bottom with
Discharging rectifying column is connected.
Utilize the method for above-mentioned DMMn process units process modification technology, comprising:
(1) material of unqualified tank is uniformly mixed with lye by mixer according to a certain percentage in the future, bottom spent lye
It is pumped to salkali waste flow container by machine, top discharge is dehydrated to extremely top through coalescer by flow container；
(2) after settlement by flow container, by dividing water packet that moisture is drained into salkali waste flow container, moisture, finished off water are further removed
The material divided is sent to rectifying column；
(3) passed through first rectifying column rectifying by the material of flow container from alkali cleaning, top DMM1 goes dimethoxym ethane to recycle, and bottom is thick
DMMn removes Second distillation column, and column bottom temperature is controlled at 100 DEG C；
(4) enter Second distillation column from the discharging of first rectifying column tower reactor, top DMM1 goes dimethoxym ethane to recycle, the thick DMMn in bottom
Rear portion product tower is gone to continue separating-purifying, to achieve the purpose that unqualified DMMn recycling, column bottom temperature is controlled at 120 DEG C.
Above-mentioned steps (1)-(4) technological parameter need to meet the following:
(1) caustic treater feeding temperature should not be higher than 50 DEG C；
(2) certain liquid level should be first established before caustic treater charging, opens lye circulation, lye keeps a certain range after charging
Low concentration alkali is discharged in interior concentration of lye in time, supplements concentrated base；
(3) when coalescer filter element pressure difference is greater than 0.1MPa, cut-in stand-by coalescer；
(4) Fen Shuibao circle are not higher than 50%；
(5) guarantee the separating effect of Second distillation column DMM1, to guarantee the qualification of product；
Compared with prior art, it the advantages of the utility model and has the active effect that
Due in normal productive process and when device parking process has unqualified DMMn material and generates, to prevent from not conforming to
Lattice DMMn material waste, unqualified material is recycled again, by reaction, alkali cleaning, distillation system by a small amount of formaldehyde,
Formic acid and water removal, to improve purpose product yield, device and method provided by the utility model obtain entire DMMn material
With recycling, DMMn material zero-emission is realized.
Detailed description of the invention
Fig. 1 is utility model device flow diagram.
Each appended drawing reference are as follows: 100 entry mixers, 101 caustic treaters, 102 spent lyes recycle discharging pump, 103 coalescences
Device, 104 alkali cleaning tank decks are by flow container, 105 salkali waste flow containers, and 106 alkali cleaning tank decks mend alkali lines by flow container discharging pump, 107, and 200 the
One rectifying column, 201 first rectifying column bottom discharging pumps, 202 first rectifying column top condensers, 203 first rectifying column tops are by liquid
Tank, 204 first rectifying column tops are by flow container discharging pump, 301 Second distillation columns, 302 Second distillation column tower reactor discharging pumps, and 303
Second distillation column top condenser, 304 Second distillation column tops are by flow container, 305 Second distillation column reflux pumps, 306 Second distillation columns
Push up discharging pump.
Specific embodiment
In order to be more clearly understood that the above objects, features, and advantages of the utility model, below with reference to specific implementation
Example is described further the utility model.It should be noted that in the absence of conflict, embodiments herein and implementation
Feature in example can be combined with each other.
Many details are explained in the following description in order to fully understand the utility model, still, this is practical
Novel to be implemented using other modes described herein are different from, therefore, the utility model is not limited to be described below
The limitation of the specific embodiment of specification.
Embodiment 1, as shown in Figure 1, the present embodiment provides DMMn process units and specific process steps.Sequentially connected system
Unite 101-107, each equipment of 200-204,301-306.
Caustic washing system includes entry mixers 100 and caustic treater 101, alkali cleaning tank deck by flow container 104, coalescer 103, salkali waste
Flow container 105, the entry mixers 100 are set to before caustic treater 101, and the caustic treater 101 is set to entry mixers 100
With alkali cleaning top by between flow container 104, the alkali cleaning tank deck is set between caustic treater 101 and salkali waste flow container 105 by flow container 104,
The coalescer 103 is set to caustic treater 101 and alkali cleaning tank deck by between flow container 104, and salkali waste flow container 105 is set to alkali cleaning tank deck
After by flow container 104.
Distillation system includes first rectifying column 200, Second distillation column 201.First rectifying column 200 is in alkali cleaning tank deck by flow container
Between 104 and Second distillation column 201.100 mouths of entry mixers and the discharging of 101 bottom of caustic treater connect, the entry mixers
100 mouths are connect with alkali line 107 is mended, and 101 bottom of the caustic treater discharging is divided into two-way, are gone entry mixers 100 all the way, are gone all the way
Salkali waste flow container 105, the caustic treater top discharging pump 106 are connected with coalescer 103, the coalescer 103 and alkali cleaning tank deck
It is connected by flow container 104.The charging of first rectifying column 202 is connected with alkali cleaning tank deck by the discharging of flow container 104, the first rectifying column
200 top gas phases are connected with 202 import of top gaseous phase condenser, top gaseous phase condenser 202 outlet with first rectifying column top by
Flow container 203 is connected, and first rectifying column bottom discharging pump 204 is connected with Second distillation column 301, and first rectifying column top is by flow container
203 dischargings are connected with raw materials recovery；301 feed inlet of Second distillation column is connected with the discharging of 200 tower reactor of first rectifying column, and second
301 top gas phase of rectifying column is connected with 303 import of Second distillation column top condenser, Second distillation column top condenser 303 outlet with
Second distillation column top is connected by flow container 304, and by the discharging of flow container 304, (Second distillation column is returned with raw materials recovery on Second distillation column top
305) stream pump is connected, another way is connected with the pipeline of Second distillation column top discharging pump 306；Second distillation column tower reactor discharging pump
302 are connected with product tower feeding pipe.Alkali cleaning tank deck is divided water packet to connect with salkali waste flow container 105 by flow container 104, the caustic treater
Top is connected by 104 bottom of flow container with discharging rectifying column.
The specific process steps are as follows:
(1) material of unqualified tank is uniformly mixed with lye by mixer according to a certain percentage in the future, bottom spent lye
Be pumped to salkali waste flow container 105 by machine, top discharge through coalescer 103 be dehydrated to alkali cleaning tank deck by flow container 104；
(2) alkali cleaning tank deck by flow container 104 after settlement, by dividing water packet that moisture is drained into salkali waste flow container 105, further take off
The material of moisture removal, finished off water point is sent to rectifying column；
(3) passed through 200 rectifying of first rectifying column by the material of flow container from alkali cleaning, top DMM1 goes dimethoxym ethane to recycle, bottom
The thick DMMn in portion removes Second distillation column 301, and column bottom temperature is controlled at 100 DEG C；
(4) enter Second distillation column 301 from the discharging of 200 tower reactor of first rectifying column, top DMM1 goes dimethoxym ethane to recycle, bottom
Thick DMMn goes rear portion product tower to continue separating-purifying, and to achieve the purpose that unqualified DMMn recycling, column bottom temperature is controlled 120
℃。
Above-mentioned steps (1) to (4) need to meet following technological parameter:
A. 101 feeding temperature of caustic treater should not be higher than 50 DEG C；
B. caustic treater 101 should first establish certain liquid level before feeding, and open spent lye circulating pump 102, and lye is protected after charging
Concentration of lye in a certain range is held, low concentration alkali is discharged in time, supplements concentrated base；
C. when 103 filter core pressure difference of coalescer is greater than 0.1MPa, cut-in stand-by coalescer 103；
D. Fen Shuibao circle are not higher than 50%；
E. guarantee the DMM1 separating effect of Second distillation column 301, to guarantee the qualification of product.
The above descriptions are merely preferred embodiments of the present invention, is not to make other forms to the utility model
Limitation, any person skilled in the art is changed or is modified as possibly also with the technology contents of the disclosure above equivalent
The equivalent embodiment of variation is applied to other fields, but all without departing from the content of the technical scheme of the utility model, according to this reality
With novel technical spirit any simple modification, equivalent variations and remodeling to the above embodiments, it is practical new to still fall within this
The protection scope of type technical solution.
Claims (4)
1. a kind of equipment for handling unqualified material DMMn, including apparatus body, it is characterised in that: the apparatus body includes alkali
System and thick DMMn distillation system are washed,
The caustic washing system includes entry mixers and caustic treater, alkali cleaning tank deck by flow container, coalescer, salkali waste flow container, and charging is mixed
Clutch is set to before caustic treater, and the caustic treater is set to entry mixers and alkali cleaning tank deck by between flow container, the alkali cleaning
Tank deck is set between caustic treater and salkali waste flow container by flow container, and the coalescer includes multiple spare coalescers of parallel connection, is set to
By between flow container, salkali waste flow container is set to alkali cleaning tank deck after by flow container for caustic treater and alkali cleaning tank deck；
The thick DMMn distillation system includes first rectifying column and Second distillation column, and first rectifying column is set to alkali cleaning tank deck by liquid
Between tank and Second distillation column.
2. handling the equipment of unqualified material DMMn according to claim 1, it is characterised in that: the entry mixers branch mouth
It discharging and connects with caustic treater bottom, the entry mixers branch mouth is connect with alkali line is mended, and the caustic treater bottom, which discharges, is divided into two-way, and one
Road goes entry mixers, removes salkali waste flow container all the way, and the caustic treater ejection material is connected with coalescer, the coalescer and alkali
Top is washed to be connected by flow container.
3. handling the equipment of unqualified material DMMn according to claim 1, it is characterised in that: the first rectifying column into
Material is connected with alkali cleaning tank deck by flow container discharging, and the first rectifying column top gas phase is connected with top gaseous phase condenser inlet,
Top gaseous phase condensator outlet is connected with first rectifying column top by flow container, and the discharging of first rectifying column bottom is connected with Second distillation column
It connects, first rectifying column top is discharged by flow container to be connected with raw materials recovery；Second distillation column feed inlet goes out with first rectifying column tower reactor
Material is connected, and Second distillation column top gas phase is connected with Second distillation column top condenser inlet, and Second distillation column top condenser goes out
Mouth is connected with Second distillation column top by flow container, and Second distillation column top is discharged by flow container to be connected with raw materials recovery, tower reactor and production
Product tower feeding pipe is connected.
4. handling the equipment of unqualified material DMMn according to claim 1, it is characterised in that: the alkali cleaning tank deck is by flow container
Water packet is divided to connect with salkali waste flow container, the alkali cleaning top is connected by flow container bottom with discharging rectifying column.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201920093350.5U CN209602413U (en) | 2019-01-21 | 2019-01-21 | A kind of equipment handling unqualified material DMMn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201920093350.5U CN209602413U (en) | 2019-01-21 | 2019-01-21 | A kind of equipment handling unqualified material DMMn |
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| CN209602413U true CN209602413U (en) | 2019-11-08 |
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| CN201920093350.5U Active CN209602413U (en) | 2019-01-21 | 2019-01-21 | A kind of equipment handling unqualified material DMMn |
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