CN209322766U - A kind of extraction system of anthocyanidin - Google Patents
A kind of extraction system of anthocyanidin Download PDFInfo
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- CN209322766U CN209322766U CN201822178210.6U CN201822178210U CN209322766U CN 209322766 U CN209322766 U CN 209322766U CN 201822178210 U CN201822178210 U CN 201822178210U CN 209322766 U CN209322766 U CN 209322766U
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- 238000000605 extraction Methods 0.000 title claims abstract description 87
- 229930014669 anthocyanidin Natural products 0.000 title claims abstract description 73
- 235000008758 anthocyanidins Nutrition 0.000 title claims abstract description 73
- 150000001452 anthocyanidin derivatives Chemical class 0.000 title claims abstract 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 283
- 239000007788 liquid Substances 0.000 claims abstract description 210
- 238000000926 separation method Methods 0.000 claims abstract description 89
- 150000004676 glycans Chemical class 0.000 claims abstract description 42
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 42
- 239000005017 polysaccharide Substances 0.000 claims abstract description 42
- 239000000284 extract Substances 0.000 claims abstract description 31
- 238000010828 elution Methods 0.000 claims abstract description 30
- 239000012141 concentrate Substances 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 25
- 238000000746 purification Methods 0.000 claims abstract description 14
- 239000002699 waste material Substances 0.000 claims abstract description 13
- 238000004587 chromatography analysis Methods 0.000 claims abstract description 5
- 239000012530 fluid Substances 0.000 claims abstract description 4
- 238000004064 recycling Methods 0.000 claims abstract description 4
- 238000003860 storage Methods 0.000 claims description 86
- 239000011347 resin Substances 0.000 claims description 47
- 229920005989 resin Polymers 0.000 claims description 47
- 230000003213 activating effect Effects 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 238000004140 cleaning Methods 0.000 claims description 40
- 230000005484 gravity Effects 0.000 claims description 32
- 238000001125 extrusion Methods 0.000 claims description 25
- 239000002893 slag Substances 0.000 claims description 22
- 230000004913 activation Effects 0.000 claims description 18
- 238000007599 discharging Methods 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000011010 flushing procedure Methods 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 238000004458 analytical method Methods 0.000 claims description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 abstract description 3
- 239000003480 eluent Substances 0.000 abstract description 3
- -1 extract unit Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 150000001453 anthocyanidins Chemical class 0.000 description 54
- 238000010586 diagram Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000003513 alkali Substances 0.000 description 6
- 240000000851 Vaccinium corymbosum Species 0.000 description 4
- 235000003095 Vaccinium corymbosum Nutrition 0.000 description 4
- 235000017537 Vaccinium myrtillus Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 235000021014 blueberries Nutrition 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229930002877 anthocyanin Natural products 0.000 description 3
- 235000010208 anthocyanin Nutrition 0.000 description 3
- 239000004410 anthocyanin Substances 0.000 description 3
- 150000004636 anthocyanins Chemical class 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- VEVZSMAEJFVWIL-UHFFFAOYSA-O cyanidin cation Chemical compound [O+]=1C2=CC(O)=CC(O)=C2C=C(O)C=1C1=CC=C(O)C(O)=C1 VEVZSMAEJFVWIL-UHFFFAOYSA-O 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- KZMACGJDUUWFCH-UHFFFAOYSA-O malvidin Chemical compound COC1=C(O)C(OC)=CC(C=2C(=CC=3C(O)=CC(O)=CC=3[O+]=2)O)=C1 KZMACGJDUUWFCH-UHFFFAOYSA-O 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- GCPYCNBGGPHOBD-UHFFFAOYSA-N Delphinidin Natural products OC1=Cc2c(O)cc(O)cc2OC1=C3C=C(O)C(=O)C(=C3)O GCPYCNBGGPHOBD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000001549 Ipomoea eriocarpa Species 0.000 description 1
- 235000005146 Ipomoea eriocarpa Nutrition 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229940093797 bioflavonoids Drugs 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000007336 cyanidin Nutrition 0.000 description 1
- 235000007242 delphinidin Nutrition 0.000 description 1
- JKHRCGUTYDNCLE-UHFFFAOYSA-O delphinidin Chemical compound [O+]=1C2=CC(O)=CC(O)=C2C=C(O)C=1C1=CC(O)=C(O)C(O)=C1 JKHRCGUTYDNCLE-UHFFFAOYSA-O 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
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- 239000000975 dye Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- NWKFECICNXDNOQ-UHFFFAOYSA-N flavylium Chemical compound C1=CC=CC=C1C1=CC=C(C=CC=C2)C2=[O+]1 NWKFECICNXDNOQ-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000576 food coloring agent Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 125000003563 glycoside group Chemical group 0.000 description 1
- 229940087603 grape seed extract Drugs 0.000 description 1
- 235000002532 grape seed extract Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 235000009584 malvidin Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- HKUHOPQRJKPJCJ-UHFFFAOYSA-N pelargonidin Natural products OC1=Cc2c(O)cc(O)cc2OC1c1ccc(O)cc1 HKUHOPQRJKPJCJ-UHFFFAOYSA-N 0.000 description 1
- 235000006251 pelargonidin Nutrition 0.000 description 1
- XVFMGWDSJLBXDZ-UHFFFAOYSA-O pelargonidin Chemical compound C1=CC(O)=CC=C1C(C(=C1)O)=[O+]C2=C1C(O)=CC(O)=C2 XVFMGWDSJLBXDZ-UHFFFAOYSA-O 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 210000003934 vacuole Anatomy 0.000 description 1
- 239000001717 vitis vinifera seed extract Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Extraction Or Liquid Replacement (AREA)
Abstract
The utility model discloses a kind of extraction systems of anthocyanidin, including extract unit, alcohol mixing system, extracting solution separation concentration unit, chromatographic apparatus, elution alcohol separation concentration unit, polysaccharide liquid separation concentration unit and purification liquid separation concentration unit.Then extraction unit passes through extracting solution separation concentration unit separation of solid and liquid concentration using the anthocyanidin in alcoholic extraction pomace, concentrate is sent to chromatography layering in chromatographic apparatus, respectively high-purity fluid, purify liquid, polysaccharide liquid and alcohol eluent, this in four liquid decibel send and separate concentration into respective separation concentration unit, finally obtain the anthocyanidin of high-purity, the recycling and alcohol then flows back, the extraction system utilizes the anthocyanidin in alcoholic extraction pomace, then it is parsed by chromatographic apparatus, final separation is concentrated to get anthocyanidin, alcohol has been recycled during separating concentration, reduce the waste of alcohol, improve the extraction efficiency of anthocyanidin.
Description
Technical field
The utility model relates to a kind of extraction system of anthocyanidin, which can extract the anthocyanidin in blueberry.
Background technique
Anthocyanidin (anthocyanidins), also known as anthocyanidin, it is water-soluble in plant to be that nature one kind is widely present in
Property natural pigment.Main color-generation substance in water fruits and vegetables, flowers is largely associated therewith.It is different in plant cell vacuole
Under the conditions of pH value, anthocyanidin makes petal that multicoloured color be presented.Known cyanine is known as more than 20 kinds, important in food to have 6
Kind, i.e. pelargonidin, cyanidin, delphinidin, paeonidin, morning glory pigment and malvidin.Nature
Anthocyanidin all exist with glycoside forms, referred to as anthocyanin, few free anthocyanidin exist.Anthocyanidin is mainly used for food
Coloring aspect, it can also be used to dyestuff, medicine, cosmetics etc..And anthocyanidin contained by blueberry is current all Anthocyanins
Middle function is most excellent, and (anthocyanidin being especially made of 16 kinds of bioflavonoids has life more superior than general Anthocyanin
Reason activity), application range is most wide, and side effect is minimum and the kind of price most expensive.Anthocyanidin content is mentioned up to 25% blueberry
Take object, price is content up to 5-6 times of grape seed extract of 95%, it is seen that its value free from worldly cares.And current extraction element
Exactly pomace and alcohol are mixed, the anthocyanidin in pomace is just dissolved by alcohol, to complete to extract.It is so this simple
Extraction element needs prolonged dissolution, and time-consuming, and isolated effect is relatively low, remains unchanged or can retain in pomace
Anthocyanidin, so that anthocyanidin be caused to waste.
In addition current extraction system needs to consume a large amount of alcohol, causes the waste of alcohol, the increased costs of production.
Utility model content
The technical problem to be solved by the utility model is to provide a kind of extraction system of anthocyanidin, extraction system benefits
It with the anthocyanidin in alcoholic extraction pomace, is then parsed by chromatographic apparatus, final separation is concentrated to get anthocyanidin, dense separating
Alcohol has been recycled during contracting, has reduced the waste of alcohol, improves the extraction efficiency of anthocyanidin.
In order to solve the above technical problems, the technical solution of the utility model is: a kind of extraction system of anthocyanidin, including
Unit is extracted, the extraction unit includes extracting cylinder, and one end of the extraction cylinder is provided with pomace feeding device and mentions
Liquid is taken to export, the other end for extracting cylinder, which is provided with, extracts alcohol entrance and device for dragging dregs；It extracts and is provided in cylinder for by pomace
The material-pulling device of push extracts and is provided with ultrasonic generator on cylinder；
Alcohol mixing system, the alcohol mixing system are provided with reflow of alcohol entrance, extract alcohol delivery outlet, parsing wine
Smart delivery outlet extracts alcohol delivery outlet and is connected to the extraction alcohol entrance extracted on cylinder, which will configure
Alcohol afterwards is sent to extraction cylinder；
Extracting solution separation concentration unit, the extracting liquid outlet for extracting cylinder separate the feed inlet of concentration unit with extracting solution
Connection, extracting solution separation concentration unit are used to be concentrated to get concentrate after being separated by solid-liquid separation extracting solution and residue, the extracting solution
The alcohol outlet of separation concentration unit is connected to reflow of alcohol entrance；
Chromatographic apparatus, the concentrated solution outlet that the concentrate entrance of the chromatographic apparatus separates concentration unit with extracting solution connect
Logical, chromatographic apparatus is connected to parsing alcohol delivery outlet, which is used to carry out concentrate to stand chromatography layering from shape
At high-purity liquid layer, low pure liquid layer, polysaccharide liquid layer and elution alcohol layer, high-purity liquid layer, low pure liquid layer, polysaccharide liquid layer and elution alcohol
Layer passes through high-purity liquid storage tank, low pure liquid storage tank, polysaccharide liquid storage tank and elution alcohol storage tank caching respectively；
Alcohol separation concentration unit is eluted, elution alcohol separation concentration unit is washed for that will elute alcohol heating separation
The outlet of dealcoholization storage tank is connected to the entrance that elution alcohol separates concentration unit, the alcohol of elution alcohol separation concentration unit
Outlet is connected to the reflow of alcohol entrance of alcohol mixing system；The final liquid for eluting alcohol separation concentration unit exports and first is dense
The connection of contracting collecting tank
Polysaccharide liquid separation concentration unit, polysaccharide liquid separation concentration unit, which is used to heat polysaccharide liquid, to be separated, polysaccharide liquid storage
The outlet of tank separates the entrance connection of concentration unit, the alcohol outlet of polysaccharide liquid separation concentration unit and alcohol tune with polysaccharide liquid
The reflow of alcohol entrance of match system is connected to, and the final liquid outlet of polysaccharide liquid separation concentration unit is connected to the second concentration collecting tank；
Liquid separation concentration unit is purified, extracting solution separation concentration unit is used for low pure liquid and high-purity fluid heating separation,
The entrance that the outlet of high-purity liquid storage tank and low pure liquid storage tank separates concentration unit with purification liquid is connected to, and purification liquid separates thickener
Group alcohol outlet be connected to the reflow of alcohol entrance of alcohol mixing system, purification liquid separation concentration unit final liquid export and
The connection of anthocyanidin storage tank.
As a preferred solution, the chromatographic apparatus includes
Gravity tank is provided with feed inlet on the gravity tank, and the bottom of gravity tank is provided with discharge port, the gravity tank
Feed inlet is connected with feeding pipe, and anthocyanidin concentrate charge pipe, alcohol charge pipe and pure are connected separately on the feeding pipe
Water supply pipe, anthocyanidin concentrate charge pipe separate the concentrated solution outlet of concentration unit, alcohol charge pipe and alcohol with extracting solution
The parsing alcohol delivery outlet of mixing system is connected to；
Several chromatographic columns, each chromatographic column include the column casing being vertically arranged, the upper and lower part point of the column casing
It is not provided with upper filter and lower filter, the space between upper filter and lower filter is provided with resin, the top setting of the column casing
There are activating solution entrance and feed inlet, the activating solution entrance connects activating solution supply pipe, and the activating solution supply pipe and activating solution supply
System connectivity is answered, the feed inlet of the column casing is connected to the discharge port of gravity tank；The bottom of the column casing is provided with discharging nozzle,
It is provided with discharge header pipe on the discharging nozzle, resin replacement entrance and resin replacement outlet, the tree are additionally provided on the column casing
Rouge replacement entrance and resin replacement outlet are located at the top of the lower section of upper filter, lower filter；
The entrance for eluting alcohol storage tank, polysaccharide liquid storage tank, high-purity liquid storage tank and low pure liquid storage tank passes through correspondence respectively
Discharge pipe be connected to the discharge header pipe of column casing bottom, be provided with valve on each discharge pipe, also set in the discharge header pipe
It is equipped with the activating solution outlet connection with valve and the waste connector with valve, the waste connector and blow-off line connect
It is logical, the observation visor for facilitating observation discharging inner manifold liquid is provided in the discharge header pipe, the activating solution outlet connection is logical
Crossing piping connection has activation liquid storage tank.
As a preferred solution, the resin replacement entrance and resin replacement outlet are also respectively communicated with resin activated tank,
Activating solution entrance, activation alcohol entrance and pure water supply opening, the activating solution entrance and activating solution are provided on the resin activated tank
Supply system connection, the activation alcohol entrance are connected to alcohol mixing system, and pure water supply opening is connected to pure water supply system.
As a preferred solution, the alcohol mixing system includes alcohol recycle tank, alcohol coarse adjustment tank, alcohol accurate adjustment
Tank, extraction alcohol container, parsing alcohol container；
The outlet of the alcohol recycle tank and the outlet of alcohol coarse adjustment tank are connected to the alcohol of alcohol accurate adjustment tank configuration mouth,
Pure water inlet is additionally provided on alcohol accurate adjustment tank, the bottom of the alcohol accurate adjustment tank is provided with alcohol delivery outlet；
It is connected between the alcohol entrance of extraction alcohol container and the alcohol delivery outlet of alcohol accurate adjustment tank, the extraction
It is provided with the bottom of alcohol container and extracts alcohol delivery outlet, the extraction alcohol delivery outlet and the extraction alcohol extracted on cylinder enter
Mouth connection；
It is connected between the alcohol entrance of parsing alcohol container and the alcohol delivery outlet of alcohol accurate adjustment tank, the parsing
The bottom of alcohol container is provided with parsing alcohol delivery outlet, the alcohol charge pipe company of the parsing alcohol delivery outlet and gravity tank
It is logical；
The alcohol outlet of the elution alcohol separation concentration unit is connected to the entrance of alcohol recycle tank；
The alcohol outlet of the separation of polysaccharides concentration unit is connected to the entrance of alcohol recycle tank；
The alcohol outlet of the purification liquid separation concentration unit is connected to the entrance of alcohol recycle tank.
As a preferred solution, extracting solution separation concentration unit include extracting solution buffer tank interconnected,
Centrifuge extracts liquid storage tank, single-effect concentrator and concentration liquid storage tank, the entrance of the extracting solution buffer tank and the extraction for extracting cylinder
The outlet of liquid outlet, the extracting solution buffer tank is connected to the feed inlet of centrifuge, the liquid-phase outlet of centrifuge and extraction
The entrance of liquid storage tank is connected to, and the outlet for extracting liquid storage tank is connected to the entrance of single-effect concentrator, the alcohol outlet of single-effect concentrator
Be connected to alcohol recycle tank, the concentrated solution outlet of single-effect concentrator be connected to concentration liquid storage tank, the outlet of the concentration liquid storage tank and
The anthocyanidin concentrate charge pipe of gravity tank is connected to.
As a preferred solution, it is additionally provided with pomace pressurizing unit on the extraction cylinder, which sets
The downstream for being placed in the direction of propulsion of extraction cylinder is provided between device for dragging dregs, the device for dragging dregs and pomace pressurizing unit
By the pomace conveying device of the pomace pulled out conveying pomace pressurizing unit, the bottom of the pomace pressurizing unit is provided with extrusion liquid and goes out
Mouthful, extrusion liquid outlet is connected to by extrusion liquid return pipe with the extrusion liquid refluxing opening for extracting cylinder, extrusion liquid refluxing opening setting
In the propulsion upstream side of device for dragging dregs.
As a preferred solution, the extraction unit further includes extracting liquid circulating device, the extraction liquid circulating device
Including collecting chamber, which is set to the lower section of device for dragging dregs and is connected to device for dragging dregs bottom, and the bottom of device for dragging dregs is set
It is equipped with filter, circulation liquid outlet is provided on the collecting chamber, which is connected with the circulating line with circulating pump, should
The other end of circulating line is connected to pomace pressurizing unit.
As a preferred solution, the extraction unit further includes flusher, which includes being set to mention
The cleaning water inlet pipe mouth of the propulsion downstream of cylinder is taken, which is connected to pure water supply system, the extraction cylinder
Upstream end is promoted to be provided with cleaning water outlet, which connect with one end of cleaning pipeline, is arranged on the cleaning pipeline
There is cleaning pump, the other end connection of the cleaning pipeline is connected to pomace pressurizing unit, is provided with punching on the cleaning water inlet pipe mouth
It washes and is in charge of, the lower part of pomace pressurizing unit is protruded into the end which is in charge of.
After above-mentioned technical proposal, the effect of the utility model is: by jam from the endfeed for extracting cylinder, and wine
Essence enters to form adverse current from the other end for extracting cylinder, while extracting the ultrasonic generator in cylinder and generating ultrasonic wave, by
Ten hundreds of micro-bubbles, i.e. cavitation bubble are generated in liquid vibration.These bubbles form negative in ultrasonic wave longitudinal propagation
Pressure area growth, and in zone of positive pressure rapid closing, thus compressed and stretched under alternately positive and negative pressure, it is straight by compression in bubble
In a flash to collapse, huge instantaneous pressure can be generated, increases molecular motion of material speed and frequency, increases penetrating for solvent
Power improves recovery rate so that anthocyanidin be accelerated to be dissolved into alcohol in this way, shortens dissolution time, reduces anthocyanidin
Waste；And the extracting solution that extraction obtains enters in extracting solution separation concentration unit and is separated by solid-liquid separation and is concentrated, and is concentrated to get
Concentrate be sent in chromatographic apparatus the alcohol for being chromatographed, and being concentrated to get and then flow back again this utilization, and concentrate is in layer
Four layers of different substance can be obtained after chromatographing in analysis apparatus, unit is then concentrated by corresponding separation and carries out separation concentration, most
Useful alcohol has been recycled eventually while also having concentrated anthocyanidin, has finally obtained the anthocyanidin of composite demand, which can be with
The time of extraction is saved, increases recovery rate, while having recycled alcohol, reduces the waste of alcohol.
Again since the chromatographic apparatus includes gravity tank, feed inlet is provided on the gravity tank, the bottom of gravity tank is set
It is equipped with discharge port, the feed inlet of the gravity tank is connected with feeding pipe, and anthocyanidin concentration is connected separately on the feeding pipe
Liquid charge pipe, alcohol charge pipe and pure water supply pipe, anthocyanidin concentrate charge pipe separate the concentration of concentration unit with extracting solution
Liquid outlet, alcohol charge pipe are connected to the parsing alcohol delivery outlet of alcohol mixing system；
Several chromatographic columns, each chromatographic column include the column casing being vertically arranged, the upper and lower part point of the column casing
It is not provided with upper filter and lower filter, the space between upper filter and lower filter is provided with resin, the top setting of the column casing
There are activating solution entrance and feed inlet, the activating solution entrance connects activating solution supply pipe, and the activating solution supply pipe and activating solution supply
System connectivity is answered, the feed inlet of the column casing is connected to the discharge port of gravity tank；The bottom of the column casing is provided with discharging nozzle,
It is provided with discharge header pipe on the discharging nozzle, resin replacement entrance and resin replacement outlet, the tree are additionally provided on the column casing
Rouge replacement entrance and resin replacement outlet are located at the top of the lower section of upper filter, lower filter；It is the elution alcohol storage tank, more
The entrance of liquid glucose storage tank, high-purity liquid storage tank and low pure liquid storage tank is total by corresponding discharge pipe and the discharging of column casing bottom respectively
Pipe connection, is provided with valve on each discharge pipe, be additionally provided in the discharge header pipe activating solution outlet connection with valve and
Waste connector with valve, the waste connector are connected to blow-off line, are provided in the discharge header pipe and facilitate sight
The observation visor of discharge header pipe internal liquid is examined, which has activation liquid storage tank by piping connection, the chromatography
Anthocyanidin concentrate is sent in gravity tank by device, is flowed into each chromatographic column in gravity tank by the effect of gravity,
The resin of activation, the resin adsorption that anthocyanidin concentrate can be activated are provided in chromatographic column, and other impurity are then first from row
Dirty mouth connector drains into blowoff line, and alcohol then is added as eluent, on such resin from the feed inlet of gravity tank again
Anthocyanidin is just dissolved in alcohol by alcohol elution, and the mixed liquor of alcohol and anthocyanidin is stood in chromatographic column, due to density
It is different and be divided into four layers, and the color of the liquid of now thereof in discharge header pipe can be shown by observing visor, then by opening not
The substance of respective layer is just flow in corresponding storage tank by the valve on same discharge pipe, and this four layers of liquid are respectively polysaccharide
Liquid, alcohol eluent, high-purity anthocyanidin liquid, low pure anthocyanidin liquid just flow to different storage tanks respectively, to realize anthocyanidin
Extraction and separation, when resin use one end time after, can by activating solution entrance be added activating solution, the activating solution be for
Activated resin substance general name, the activating solution include acid, alkali, alcohol and pure water, to it is resin activated when first pass through acid progress pickling, then
It is passed through alkali and carries out alkali cleaning, then add alcohol washes, finally wash, just complete the activation of resin.And after long-time use
Can pass through resin replacement entrance and resin replacement outlet replacement resin, it is ensured that chromatographic column can long-time stable effectively transport
Row.The chromatographic apparatus is able to maintain efficient extraction for a long time and separation effect in the extraction and separation process for carrying out anthocyanidin
Rate.
It include again extracting solution buffer tank interconnected, centrifuge, extracting solution since the extracting solution separates concentration unit
Storage tank, single-effect concentrator and concentration liquid storage tank, the entrance of the extracting solution buffer tank are connected to the extracting liquid outlet for extracting cylinder, institute
The outlet for stating extracting solution buffer tank is connected to the feed inlet of centrifuge, and the liquid-phase outlet of centrifuge and the entrance for extracting liquid storage tank connect
Logical, the outlet for extracting liquid storage tank is connected to the entrance of single-effect concentrator, and alcohol outlet and the alcohol recycle tank of single-effect concentrator connect
Logical, the concentrated solution outlet of single-effect concentrator is connected to concentration liquid storage tank, the outlet of the concentration liquid storage tank and the anthocyanidin of gravity tank
The connection of concentrate charge pipe, extracting solution separation concentration unit is structurally reasonable, can be separated by solid-liquid separation by centrifuge, make extracting solution
It separates with pomace, is then concentrated again by single-effect concentrator, also to isolate alcohol during concentration, and this
A little alcohol have been flowed back into again in alcohol recycle tank, to realize the recycling and reusing of alcohol.
Again due to being additionally provided with pomace pressurizing unit on the extraction cylinder, which, which is set to, extracts pushing away for cylinder
Into the downstream in direction, that pomace that will pull out is provided between device for dragging dregs, the device for dragging dregs and pomace pressurizing unit is defeated
The pomace conveying device of pomace pressurizing unit is sent, the bottom of the pomace pressurizing unit is provided with extrusion liquid outlet, which goes out
Mouth is connected to by extrusion liquid return pipe with the extrusion liquid refluxing opening for extracting cylinder, which is set to pushing away for device for dragging dregs
Into upstream side.The pomace pressurizing unit can further squeeze the pomace after fishing slag, make to remain in pomace in this way
Alcohol and anthocyanidin are extruded, and extrusion liquid can pass through the propulsion upstream side for the device for dragging dregs that extrusion liquid return pipe flows back into
(the namely downstream side of alcohol flowing), in this way it is avoided that extrusion liquid is re-introduced into device for dragging dregs, makes to have dissolved anthocyanidin
Alcohol to extracting solution discharge port flow, improve extraction efficiency as far as possible.
Again since the extraction unit further includes extracting liquid circulating device, which includes collecting chamber, should
Collecting chamber is set to the lower section of device for dragging dregs and is connected to device for dragging dregs bottom, and the bottom of device for dragging dregs is provided with filter, described
Circulation liquid outlet is provided on collecting chamber, which is connected with the circulating line with circulating pump, the circulating line it is another
One end is connected to pomace pressurizing unit.Since more pomace, mistake of the device for dragging dregs in fishing slag can be overstock in device for dragging dregs
Cheng Zhong, extracting solution can be flowed into collecting chamber from bottom, and extracting solution is then transported to pomace by circulating pump again and squeezes dress
In setting, and it is flowed into and is extracted in cylinder by the outlet of the extrusion liquid of pomace pressurizing unit, it in this way can be in pomace pressurizing unit
Pomace carry out secondary flushing, improve the solute effect of anthocyanidin.
Again since the extraction unit further includes flusher, which includes being set to the propulsion downstream for extracting cylinder
The cleaning water inlet pipe mouth at end, the cleaning water inlet pipe mouth are connected to pure water supply system, the propulsion upstream end setting for extracting cylinder
There is cleaning water outlet, which connect with one end of cleaning pipeline, is provided with cleaning pump on the cleaning pipeline, the cleaning
The other end connection of pipeline is connected to pomace pressurizing unit, is provided with flushing on the cleaning water inlet pipe mouth and is in charge of, the flushing point
The lower part of pomace pressurizing unit is protruded into the end of pipe.The flusher can after production line stop to extraction tube, collecting bin into
Row cleaning, certainly, device for dragging dregs can be also in the pure water of cleaning during entire cleaning, therefore whole system is more whole
It is clean, facilitate next use.
Detailed description of the invention
The present invention will be further described with reference to the accompanying drawings and examples.
Fig. 1 is the schematic diagram of the extraction system of the utility model embodiment；
Fig. 2 is the structural schematic diagram of the extraction unit of the utility model；
Fig. 3 is the structural schematic diagram of device for dragging dregs；
Fig. 4 is the partial enlargement diagram of the propulsion downstream of the extraction unit of the utility model；
Fig. 5 is the partial enlargement diagram of the propulsion upstream end of the extraction unit of the utility model；
Fig. 6 is the structural schematic diagram of chromatographic apparatus；
Fig. 7 is the enlarged drawing in Fig. 6 at A；
Fig. 8 is the enlarged drawing in Fig. 6 at B；
Fig. 9 is the structural schematic diagram of chromatographic column；
Figure 10 is the structural schematic diagram of extracting solution separation concentration unit；
Figure 11 is the structural schematic diagram of alcohol mixing system；
In attached drawing: 1. extract unit；101. extracting cylinder；102. pomace feeding device；103. pushing screw rod；104. pusher is dynamic
Power device；105. device for dragging dregs；1051. fishing slag cavitys；1052. tape loop；1053. fishing out slag plate；1054. belt wheel；1055. guide
Chute；106. pomace pressurizing unit；107. extracting alcohol entrance；108. extracting liquid outlet；109. collecting chamber；110. circulation pipe
Road；111. cleaning water inlet pipe mouth；112. extrusion liquid return pipe；113. cleaning pipeline；114. cleaning pump；115. circulating pump；116.
Ultrasonic generator；117. flushing is in charge of；2. alcohol mixing system；201. alcohol recycle tanks；202. alcohol coarse adjustment tanks；203.
Alcohol accurate adjustment tank；Alcohol container is used in 204. extractions；Alcohol container is used in 205. parsings；3. extracting solution separation concentration unit；301. extracting solution
Buffer tank；302. centrifuge；303. extract liquid storage tank；304. single-effect concentrator；3041. heating heat exchanger；3042. evaporator 2；
3043. condenser；305. concentration liquid storage tanks；4. chromatographic apparatus；401. gravity tank；402. feeding pipe；403. chromatographic column；
4031. upper filter；4032. resin replacement entrance；4033. resin replacement exports；4034. lower filter；4035. discharge header pipe；
4036. observing visor；4037. feed inlet；4038. activating solution entrance；404. activation liquid storage tanks；405. elution alcohol storage tanks；
406. polysaccharide liquid storage tanks；407. high-purity liquid storage tanks；408. anthocyanidin concentrate charge pipes；409. alcohol charge pipes；410. activation
Liquid supply pipe；411. resins add pipeline；412. resin recovery pipes；413. low pure liquid storage tanks；5. eluting alcohol separation concentration
Unit；6. polysaccharide liquid separation concentration unit；7. purifying liquid separation concentration unit；8. anthocyanidin storage tank；9. resin activated tank；10.
Acid storage tank；11. storing up alkali tank；12. the first concentration collecting tank；13. the second concentration collecting tank.
Specific embodiment
The utility model is described in further detail below by specific embodiment.
As shown in Figure 1 to 11, a kind of extraction system of anthocyanidin, including
Unit 1 is extracted, as shown in Figures 2 to 5, the extraction unit 1 includes extracting cylinder 101, one end of the extraction cylinder 101
It is provided with pomace feeding device 102 and extracting liquid outlet 108, the other end for extracting cylinder 101, which is provided with, extracts 107 He of alcohol entrance
Device for dragging dregs 105；The material-pulling device being provided in cylinder 101 for pushing pomace is extracted, extracts and is provided with ultrasonic wave on cylinder 101
Generating device 116；The material-pulling device include be rotatablely installed in extract cylinder 101 in pushing screw rod 103, the pushing screw rod 103 by
The driving rotation of pusher power device 104；The ultrasonic generator 116 is set in qually spaced in the outside for extracting cylinder 101, is extracting
When generate ultrasonic waveform at air bubble, accelerate the extraction of anthocyanidin.The pomace can be blueberry, is also possible to other anthocyanidin and contains
Measure pomace abundant, such as grape etc..
As shown in Figure 3 and Figure 4, it is additionally provided with pomace pressurizing unit 106 on the extraction cylinder 101, the pomace pressurizing unit
106 are set to the downstream for extracting the direction of propulsion of cylinder 101 close to device for dragging dregs 105, the device for dragging dregs 105 and pomace extruding
It is provided between device 106 by the pomace conveying device (not shown) of the pomace pulled out conveying pomace pressurizing unit 106, it should
Pomace conveying device is using current conventional structure, such as screw rod transmission or Belt Conveying, the pomace pressurizing unit 106
Bottom be provided with extrusion liquid outlet, the extrusion liquid outlet by extrusion liquid return pipe 112 and extract cylinder 101 extrusion liquid flow back
Mouth connection, the extrusion liquid refluxing opening are set to the propulsion upstream side of device for dragging dregs 105, which then includes receiving
Ji Cang, the collecting bin is interior to be provided with pressing mechanism, which can be using conventional fashion of extrusion, such as screw extruding institute
Stating and extracting unit 1 further includes extracting liquid circulating device, which includes collecting chamber 109, the collecting chamber 109 setting
In device for dragging dregs 105 lower section and be connected to 105 bottom of device for dragging dregs, the bottom of device for dragging dregs 105 is provided with filter, the receipts
It is provided with circulation liquid outlet on collection chamber 109, which is connected with the circulating line 110 with circulating pump 115, the circulation pipe
The other end in road 110 is connected to the collecting bin of pomace pressurizing unit 106.
The device for dragging dregs 105 includes fishing slag cavity 1051, the side of the fishing slag cavity 1051 and the propulsion for extracting cylinder 101
The fixed connection in downstream, the bottom of fishing slag cavity 1051 is provided with the filter and liquid outlet and is connected to collecting chamber 109, described
Belt wheel 1054 there are two installing in slag cavity 1051 is fished out, is provided with the tape loop 1052 being vertically arranged between belt wheel 1054, this is followed
For annulus 1052 by promotion motor driven, the outside of the tape loop 1052 is uniformly fixed with fishing slag plate 1053, the fishing slag cavity
It is provided with slag notch on 1051, inclined guide chute 1055 is provided at the slag notch, the guide chute 1055 and fishing slag plate
1053 material casting side linking.Slag plate 1053 is fished out during fishing out slag, liquid can be flowed into collecting chamber 109 and pass through circulation pipe
Road 110 is delivered to collecting bin, is back to eventually by extrusion liquid return pipe 112 and extracts cylinder 101, thus is avoided that fishing slag cavity 1051
Interior extracting solution carries a large amount of extracting solution when excessively fishing out slag.And extracting alcohol entrance 107 is also setting on fishing slag cavity 1051,
The pomace of fishing 1053 row of slag plate can be rinsed, be back to so that the anthocyanidin being attached on pomace be rinsed herein in this way
It extracts in cylinder 101.
As shown in Figures 2 to 5, the extraction unit 1 further includes flusher, which includes being set to extraction cylinder
The cleaning water inlet pipe mouth 111 of 101 propulsion downstream, the cleaning water inlet pipe mouth 111 are connected to pure water supply system, the extraction
The propulsion upstream end of cylinder 101 is provided with cleaning water outlet, which connect with one end of cleaning pipeline 113, the cleaning
Cleaning pump 114 is provided on pipeline 113, the other end connection of the cleaning pipeline 113 is connected to pomace pressurizing unit 106, described
Flushing is provided on cleaning water inlet pipe mouth 111 and is in charge of 117, and the end which is in charge of 117 is protruded under pomace pressurizing unit 106
Portion, to extraction 101 internal washing of cylinder when which can be convenient shutdown.
As shown in Fig. 1 and Figure 11, alcohol mixing system 2, the alcohol mixing system 2 is provided with reflow of alcohol entrance, extracts
Alcohol delivery outlet, parsing alcohol delivery outlet extract alcohol delivery outlet and extract the extraction alcohol entrance 107 on cylinder 101
Connection, the alcohol mixing system 2 will be sent with the alcohol postponed to extraction cylinder 101；
The alcohol mixing system 2 includes alcohol recycle tank 201, alcohol coarse adjustment tank 202, alcohol accurate adjustment tank 203, extracts and use
Alcohol container 204, parsing alcohol container 205；
The alcohol of the outlet of the alcohol recycle tank 201 and the outlet of alcohol coarse adjustment tank 202 with alcohol accurate adjustment tank 203 is matched
Mouth connection is set, is additionally provided with pure water inlet on alcohol accurate adjustment tank 203, the bottom of the alcohol accurate adjustment tank 203 is provided with alcohol
Delivery outlet；It is provided with on-line densimeter on alcohol accurate adjustment tank 203, the alcohol and newly added alcohol recycled back passes through alcohol
Accurate adjustment tank 203 is issued again after modulating and is used in each subsystem.
It is connected between the alcohol entrance of extraction alcohol container 204 and the alcohol delivery outlet of alcohol accurate adjustment tank 203, institute
State extraction with the bottom of alcohol container 204 be provided with extract alcohol delivery outlet, the extraction alcohol delivery outlet and extract cylinder 101 on
Extraction alcohol entrance 107 be connected to；
It is connected between the alcohol entrance of parsing alcohol container 205 and the alcohol delivery outlet of alcohol accurate adjustment tank 203, institute
It states parsing and the bottom of alcohol container 205 is provided with parsing alcohol delivery outlet, the parsing alcohol delivery outlet and gravity tank 401
Alcohol charge pipe 409 is connected to；
The alcohol outlet of the elution alcohol separation concentration unit 5 is connected to the entrance of alcohol recycle tank 201；
The alcohol outlet of the separation of polysaccharides concentration unit is connected to the entrance of alcohol recycle tank 201；
The alcohol outlet of the purification liquid separation concentration unit 7 is connected to the entrance of alcohol recycle tank 201.
As shown in Figure 10, extracting solution separation concentration unit 3, the extracting liquid outlet 108 for extracting cylinder 101 and extracting solution point
Feed inlet connection from concentration unit 3, extracting solution separation concentration unit 3 are used to after being separated by solid-liquid separation extracting solution and residue be concentrated
Concentrate is obtained, the alcohol outlet of extracting solution separation concentration unit 3 is connected to reflow of alcohol entrance；
The extracting solution separation concentration unit 3 includes extracting solution buffer tank 301 interconnected, centrifuge 302, extracting solution
Storage tank 303, single-effect concentrator 304 and concentration liquid storage tank 305, the entrance of the extracting solution buffer tank 301 and mentioning for extraction cylinder 101
108 connection of liquid outlet is taken, the outlet of the extracting solution buffer tank 301 is connected to the feed inlet of centrifuge 302, centrifuge 302
Liquid-phase outlet is connected to the entrance for extracting liquid storage tank 303, and the entrance of the outlet and single-effect concentrator 304 of extracting liquid storage tank 303 connects
Logical, the alcohol outlet of single-effect concentrator 304 is connected to alcohol recycle tank 201, the concentrated solution outlet of single-effect concentrator 304 and concentration
Liquid storage tank 305 is connected to, and the outlet of the concentration liquid storage tank 305 is connected to the anthocyanidin concentrate charge pipe 408 of gravity tank 401.It is single
Effect inspissator 304 is current conventional structure, and single-effect concentrator 304 includes heating heat exchanger 3041, evaporator 3042 and condensation
Device 3043 is passed through extracting solution in the tube side of heating heat exchanger 3041, and is connected to the inside of evaporator 3042, and heats heat exchange
It is passed through hot water in the shell side of device 3041, takes out negative pressure in entire single-effect concentrator 304, reduces the boiling point of alcohol, in this way, extracting solution
It can be flowed in evaporator 3042 after heat absorption, when temperature reaches the boiling point of alcohol, alcohol will evaporate, and remain liquid and return
It flow in heating heat exchanger 3041, after the circulating and evaporating of certain time, what is finally left is exactly the concentrate of anthocyanidin, and
The alcohol of evaporation is back in alcohol recycle tank 201 after condenser 3043 is condensed into liquid.
If Fig. 6 to Fig. 9 illustrates a kind of chromatographic apparatus 4, the concentrate entrance of the chromatographic apparatus 4 separates dense with extracting solution
The concentrated solution outlet of contracting unit 3 is connected to, and chromatographic apparatus 4 is connected to parsing alcohol delivery outlet, and the chromatographic apparatus 4 will be for that will be concentrated
Liquid stand chromatography layering from forming high-purity liquid layer, low pure liquid layer, polysaccharide liquid layer and elution alcohol layer, high-purity liquid layer, low pure
Liquid layer, polysaccharide liquid layer and elution alcohol layer pass through high-purity liquid storage tank 407, low pure liquid storage tank 413,406 and of polysaccharide liquid storage tank respectively
Alcohol storage tank 405 is eluted to cache；
Specifically, the chromatographic apparatus 4 includes gravity tank 401, feed inlet, gravity tank are provided on the gravity tank 401
401 bottom is provided with discharge port, and the feed inlet of the gravity tank 401 is connected with feeding pipe 402, on the feeding pipe 402
It is connected separately with anthocyanidin concentrate charge pipe 408, alcohol charge pipe 409 and pure water supply pipe, anthocyanidin concentrate charge pipe
408 separate the concentrated solution outlet of concentration unit 3, the parsing alcohol confession of alcohol charge pipe 409 and alcohol mixing system 2 with extracting solution
Answer outlet；
Several chromatographic columns 403, each chromatographic column 403 include a column casing being vertically arranged, the top of the column casing and
Lower part is respectively arranged with upper filter 4031 and lower filter 4034, and the space between upper filter 4031 and lower filter 4034 is provided with tree
Rouge is provided with activating solution entrance 4038 and feed inlet 4037, the connection of activating solution entrance 4038 activation at the top of the column casing
Liquid supply pipe 410, the activating solution supply pipe 410 are connected to activating solution supply system, and wherein activating solution supply system includes storage acid
Tank 10 and storage alkali tank 11, activating solution is a kind of general designation, and the activation of resin is needed by a pickling, an alkali cleaning, a wine
Fine is washed cleans with 1 st pure water, and therefore, activating solution is then the general name of liquid used in the above process, and above-mentioned liquid is all
It is to be added from activating solution entrance 4038.Corresponding, discharge header pipe 4035 is also connected with activation liquid storage tank 404, to the tree in column casing
After rouge activation, activation liquid storage tank 404 collects activating solution.
The feed inlet 4037 of the column casing is connected to the discharge port of gravity tank 401；The bottom of the column casing is provided with discharging
Nozzle is provided with discharge header pipe 4035 on the discharging nozzle, resin replacement entrance 4032 and resin is additionally provided on the column casing
Lower section that replacement outlet 4033, the resin replacement entrance 4032 and resin replacement outlet 4033 are located at upper filter 4031, under
The top of filter 4034.
In the present embodiment, pipeline is also added by resin respectively in the resin replacement entrance 4032 and resin replacement outlet 4033
411 are connected to resin activated tank 9 with resin recovery pipe 412, and activating solution entrance 4038, activation are provided on the resin activated tank 9
Alcohol entrance and pure water supply opening, the activating solution entrance 4038 are connected to activating solution supply system, the activation alcohol entrance and wine
Accurate adjustment match system 2 is connected to, and pure water supply opening is connected to pure water supply system.
The entrance for eluting alcohol storage tank 405, polysaccharide liquid storage tank 406, high-purity liquid storage tank 407 and low pure liquid storage tank 413
It is connected to respectively by corresponding discharge pipe with the discharge header pipe 4035 of column casing bottom, is provided with valve on each discharge pipe,
The activating solution outlet connection with valve and the waste connector with valve are additionally provided in the discharge header pipe 4035, which goes out
Mouth connector is connected to blow-off line, and the sight for facilitating observation 4035 internal liquid of discharge header pipe is provided in the discharge header pipe 4035
Periscope 4036, the activating solution outlet connection have activation liquid storage tank 404 by piping connection.
In the present embodiment, elution alcohol separation concentration unit 5, elution alcohol separation concentration unit 5 will be for that will elute wine
The outlet of finishing thermal release, elution alcohol storage tank 405 is connected to the entrance that elution alcohol separates concentration unit 5, the elution alcohol
The alcohol outlet of separation concentration unit 5 is connected to the reflow of alcohol entrance of alcohol mixing system 2；
Polysaccharide liquid separation concentration unit 6, polysaccharide liquid separation concentration unit 6, which is used to heat polysaccharide liquid, to be separated, polysaccharide liquid
The outlet of storage tank 406 separates the entrance connection of concentration unit 6, the alcohol outlet of polysaccharide liquid separation concentration unit 6 with polysaccharide liquid
It is connected to the reflow of alcohol entrance of alcohol mixing system 2；
Liquid separation concentration unit 7 is purified, extracting solution separation concentration unit 3 is used for low pure liquid and high-purity fluid heating point
From the entrance that the outlet of high-purity liquid storage tank 407 and low pure liquid storage tank 413 separates concentration unit 7 with purification liquid is connected to, and purifies liquid
The alcohol outlet of separation concentration unit 7 is connected to the reflow of alcohol entrance of alcohol mixing system 2, purification liquid separation concentration unit 7
Final liquid outlet be connected to anthocyanidin storage tank 8.
In the present embodiment, elution alcohol separation concentration unit 5, polysaccharide liquid separation concentration unit 6 and purification liquid separation concentration
The structure of unit 7 is identical, includes a storage tank and a single-effect concentrator 304, to realize the separation and target of alcohol
The concentration of liquid.Wherein, elution alcohol separation concentration unit 5 and polysaccharide liquid separation concentration unit 6 be mainly used for recycling wine
Essence, therefore the liquid of obtained concentration separately flows into the first concentration collecting tank 12 and the second concentration collecting tank by the outlet of final liquid
In 13；And the purification liquid after the concentration that liquid separation concentration unit 7 then obtains is purified, that is, final anthocyanidin.
Embodiment described above is only the description to preferred embodiments of the present invention, not as to the utility model
The restriction of range is made technical solutions of the utility model various on the basis of not departing from the spirit of the design of the utility model
Deformation and transformation should all be fallen into the protection scope of claims determination of the utility model.
Claims (8)
1. a kind of extraction system of anthocyanidin, it is characterised in that: including
Unit is extracted, the extraction unit includes extracting cylinder, and one end of the extraction cylinder is provided with pomace feeding device and extracting solution
Outlet, the other end for extracting cylinder, which is provided with, extracts alcohol entrance and device for dragging dregs；It extracts and is provided in cylinder for pushing pomace
Material-pulling device, extract cylinder on be provided with ultrasonic generator；
Alcohol mixing system, the alcohol mixing system are provided with reflow of alcohol entrance, extract alcohol delivery outlet, parsing alcohol confession
It should export, the extraction alcohol entrance for extracting alcohol delivery outlet and extracting on cylinder is connected to, which, which will match, postpones
Alcohol is sent to extraction cylinder；
Extracting solution separation concentration unit, the feed inlet that the extracting liquid outlet for extracting cylinder separates concentration unit with extracting solution connect
Logical, extracting solution separation concentration unit is used to be concentrated to get concentrate after being separated by solid-liquid separation extracting solution and residue, the extracting solution point
Alcohol from concentration unit is exported to be connected to reflow of alcohol entrance；
Chromatographic apparatus, the concentrate entrance of the chromatographic apparatus separate the concentrated solution outlet connection of concentration unit, layer with extracting solution
Analysis apparatus is connected to parsing alcohol delivery outlet, which is used to that concentrate to be carried out to standing chromatography layering high-purity from being formed
Liquid layer, low pure liquid layer, polysaccharide liquid layer and elution alcohol layer, high-purity liquid layer, low pure liquid layer, polysaccharide liquid layer and elution alcohol layer difference
Pass through high-purity liquid storage tank, low pure liquid storage tank, polysaccharide liquid storage tank and elution alcohol storage tank caching；
Alcohol separation concentration unit is eluted, elution alcohol separation concentration unit elutes wine for that will elute alcohol heating separation
The outlet of smart storage tank is connected to the entrance that elution alcohol separates concentration unit, the alcohol outlet of elution alcohol separation concentration unit
It is connected to the reflow of alcohol entrance of alcohol mixing system, the final liquid outlet of elution alcohol separation concentration unit is received with the first concentration
Collect tank connection；
Polysaccharide liquid separation concentration unit, polysaccharide liquid separation concentration unit, which is used to heat polysaccharide liquid, to be separated, polysaccharide liquid storage tank
Outlet separates the entrance connection of concentration unit with polysaccharide liquid, and the alcohol outlet of polysaccharide liquid separation concentration unit is with alcohol allotment
The reflow of alcohol entrance of system is connected to, and the final liquid outlet of polysaccharide liquid separation concentration unit is connected to the second concentration collecting tank；
It purifies liquid separation and unit is concentrated, extracting solution separation concentration unit is used to separate low pure liquid and high-purity fluid heating, high-purity
The entrance that the outlet of liquid storage tank and low pure liquid storage tank separates concentration unit with purification liquid is connected to, purification liquid separation concentration unit
Alcohol outlet is connected to the reflow of alcohol entrance of alcohol mixing system, the final liquid outlet of purification liquid separation concentration unit and cyanine
Plain storage tank connection.
2. a kind of extraction system of anthocyanidin as described in claim 1, it is characterised in that: the chromatographic apparatus includes
Gravity tank is provided with feed inlet on the gravity tank, and the bottom of gravity tank is provided with discharge port, the charging of the gravity tank
Mouth is connected with feeding pipe, and anthocyanidin concentrate charge pipe, alcohol charge pipe and pure water are connected separately on the feeding pipe and is supplied
Ying Guan, anthocyanidin concentrate charge pipe separate the concentrated solution outlet of concentration unit with extracting solution, and alcohol charge pipe and alcohol are deployed
The parsing alcohol delivery outlet of system is connected to；
Several chromatographic columns, each chromatographic column include the column casing being vertically arranged, and the upper and lower part of the column casing is set respectively
It is equipped with upper filter and lower filter, the space between upper filter and lower filter is provided with resin, is provided with work at the top of the column casing
Change liquid entrance and feed inlet, the activating solution entrance connects activating solution supply pipe, and the activating solution supply pipe and activating solution supply are
System connection, the feed inlet of the column casing are connected to the discharge port of gravity tank；The bottom of the column casing is provided with discharging nozzle, should go out
It is provided with discharge header pipe on expects pipe mouth, resin replacement entrance and resin replacement outlet are additionally provided on the column casing, the resin is more
Change mouth and resin replacement outlet are located at the top of the lower section of upper filter, lower filter；
The elution alcohol storage tank, polysaccharide liquid storage tank, high-purity liquid storage tank and low pure liquid storage tank entrance pass through respectively it is corresponding go out
Pipe material is connected to the discharge header pipe of column casing bottom, is provided with valve on each discharge pipe, is additionally provided in the discharge header pipe
Activating solution outlet connection with valve and the waste connector with valve, the waste connector are connected to blow-off line, institute
The observation visor for being provided in discharge header pipe and facilitating observation discharging inner manifold liquid is stated, which passes through pipeline
It is connected with activation liquid storage tank.
3. a kind of extraction system of anthocyanidin as claimed in claim 2, it is characterised in that: the resin replacement entrance and resin are more
The mouth that swaps out also is respectively communicated with resin activated tank, and activating solution entrance, activation alcohol entrance and pure water are provided on the resin activated tank
Supply opening, the activating solution entrance are connected to activating solution supply system, which is connected to alcohol mixing system, pure water
Supply opening is connected to pure water supply system.
4. a kind of extraction system of anthocyanidin as claimed in claim 3, it is characterised in that: the alcohol mixing system includes wine
Smart recycling can, alcohol coarse adjustment tank, alcohol accurate adjustment tank, extraction alcohol container, parsing alcohol container；
The outlet of the alcohol recycle tank and the outlet of alcohol coarse adjustment tank are connected to the alcohol of alcohol accurate adjustment tank configuration mouth, alcohol
Pure water inlet is additionally provided on accurate adjustment tank, the bottom of the alcohol accurate adjustment tank is provided with alcohol delivery outlet；
It is connected between the alcohol entrance of extraction alcohol container and the alcohol delivery outlet of alcohol accurate adjustment tank, wine is used in the extraction
The bottom of smart tank, which is provided with, extracts alcohol delivery outlet, and the extraction alcohol delivery outlet and the extraction alcohol entrance extracted on cylinder connect
It is logical；
It is connected between the alcohol entrance of parsing alcohol container and the alcohol delivery outlet of alcohol accurate adjustment tank, wine is used in the parsing
The bottom of smart tank is provided with parsing alcohol delivery outlet, which is connected to the alcohol charge pipe of gravity tank；
The alcohol outlet of the elution alcohol separation concentration unit is connected to the entrance of alcohol recycle tank；
The alcohol outlet of the separation of polysaccharides concentration unit is connected to the entrance of alcohol recycle tank；
The alcohol outlet of the purification liquid separation concentration unit is connected to the entrance of alcohol recycle tank.
5. a kind of extraction system of anthocyanidin as claimed in claim 4, it is characterised in that: the extracting solution separation concentration unit
Including extracting solution buffer tank interconnected, centrifuge, extract liquid storage tank, single-effect concentrator and concentration liquid storage tank, the extraction
The entrance of liquid buffer tank is connected to the extracting liquid outlet for extracting cylinder, the outlet of the extracting solution buffer tank and the feed inlet of centrifuge
Connection, the liquid-phase outlet of centrifuge are connected to the entrance for extracting liquid storage tank, extract the outlet of liquid storage tank and entering for single-effect concentrator
The alcohol outlet of mouth connection, single-effect concentrator is connected to alcohol recycle tank, and the concentrated solution outlet and concentrate of single-effect concentrator store up
Tank connection, the outlet of the concentration liquid storage tank is connected to the anthocyanidin concentrate charge pipe of gravity tank.
6. a kind of extraction system of anthocyanidin as claimed in claim 5, it is characterised in that: be additionally provided with fruit on the extraction cylinder
Slag pressurizing unit, the pomace pressurizing unit are set to the downstream for extracting the direction of propulsion of cylinder close to device for dragging dregs, the fishing slag
It is provided between device and pomace pressurizing unit by the pomace conveying device of the pomace pulled out conveying pomace pressurizing unit, the pomace
The bottom of pressurizing unit is provided with extrusion liquid outlet, and extrusion liquid outlet is returned by the extrusion liquid of extrusion liquid return pipe and extraction cylinder
Head piece connection, the extrusion liquid refluxing opening are set to the propulsion upstream side of device for dragging dregs.
7. a kind of extraction system of anthocyanidin as claimed in claim 6, it is characterised in that: the extraction unit further includes extracting
Liquid circulating device, which includes collecting chamber, which is set to the lower section of device for dragging dregs and fills with fishing slag
The connection of bottom set portion, the bottom of device for dragging dregs are provided with filter, circulation liquid outlet are provided on the collecting chamber, the circulation liquid outlet
It is connected with the circulating line with circulating pump, the other end of the circulating line is connected to pomace pressurizing unit.
8. a kind of extraction system of anthocyanidin as claimed in claim 7, it is characterised in that: the extraction unit further includes rinsing
Device, the flusher include be set to extract cylinder propulsion downstream cleaning water inlet pipe mouth, the cleaning water inlet pipe mouth with it is pure
Water supply system connection, the propulsion upstream end for extracting cylinder are provided with cleaning water outlet, the cleaning water outlet and cleaning pipeline
One end connection, be provided with cleaning pump on the cleaning pipeline, the other end connection of the cleaning pipeline is connected to pomace pressurizing unit,
It is provided with flushing on the cleaning water inlet pipe mouth to be in charge of, the lower part of pomace pressurizing unit is protruded into the end which is in charge of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201822178210.6U CN209322766U (en) | 2018-12-25 | 2018-12-25 | A kind of extraction system of anthocyanidin |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201822178210.6U CN209322766U (en) | 2018-12-25 | 2018-12-25 | A kind of extraction system of anthocyanidin |
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| CN209322766U true CN209322766U (en) | 2019-08-30 |
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| CN201822178210.6U Withdrawn - After Issue CN209322766U (en) | 2018-12-25 | 2018-12-25 | A kind of extraction system of anthocyanidin |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109400570A (en) * | 2018-12-25 | 2019-03-01 | 江苏哈工药机科技股份有限公司 | A kind of extraction system of anthocyanidin |
-
2018
- 2018-12-25 CN CN201822178210.6U patent/CN209322766U/en not_active Withdrawn - After Issue
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109400570A (en) * | 2018-12-25 | 2019-03-01 | 江苏哈工药机科技股份有限公司 | A kind of extraction system of anthocyanidin |
| CN109400570B (en) * | 2018-12-25 | 2023-12-22 | 江苏哈工药机科技股份有限公司 | Anthocyanin extraction system |
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