CN209317434U - A kind of circulating treating system of wet desulphurization slurry - Google Patents

A kind of circulating treating system of wet desulphurization slurry Download PDF

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CN209317434U
CN209317434U CN201821177736.6U CN201821177736U CN209317434U CN 209317434 U CN209317434 U CN 209317434U CN 201821177736 U CN201821177736 U CN 201821177736U CN 209317434 U CN209317434 U CN 209317434U
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slurry
delivery pump
dilute
pool
heat exchanger
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王正阳
谢庆亮
黄举福
廖增安
罗昌河
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Fujian Longking Co Ltd.
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Fujian Longking Co Ltd.
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Abstract

The utility model discloses a kind of circulating treating system of wet desulphurization slurry, it include: desulfuration absorbing tower, higher level's demister, junior's demister, Multi-layer sprinkling tube layer, pallet and slurry pool are set gradually in tower from top to bottom, slurry pool is connected to by delivery pump with one or more layers of spray tube layer;Separation equipment is connected to slurry pool, for isolating dilute slurry from fraction slurries;Dilute slurry heat exchanger, is connected to separation equipment, for reducing the temperature of dilute slurry, and is connected to desulfuration absorbing tower, and the dilute slurry after making cooling is passed through desulfuration absorbing tower.Due to particle concentration is lower in dilute slurry and grain diameter compared with thread to move followability preferable, the drawbacks of having evaded the easy fouling of dilute slurry heat exchanger, attrition and attack;Clarifying equipment leads to the problem of water level transfinites in desulfuration absorbing tower for isolating clear water from fraction slurries or part dilute slurry and the daily water consumption for use as other units outside the process water and system of desulfuration absorbing tower being discharged in clear water to evade flue gas cooling.

Description

A kind of circulating treating system of wet desulphurization slurry
Technical field
The utility model relates to Wet Flue Gas Desulfurization Technique fields, more particularly to a kind of circular treatment system of wet desulphurization slurry System.
Background technique
Wet desulphurization becomes the most of coal burning machines in China because of the advantages that its desulfuration efficiency is high, adaptable to unit load Group, steel sintering technique and coking industry carry out the mainstream configuration of ultra-clean discharge.
But wet desulphurization can make outlet drain flue gas be in saturation or nearly saturation state containing a large amount of water vapour. Also, since flue-gas temperature is relatively high, contacted from after chimney discharge with the lower surrounding air of temperature, flue-gas temperature can continue Decline, causes the water recovery Cheng Shui in flue gas.Condensing water droplet generates refraction, scattering to light, keeps plume white or grey The condensed water that color causes visual pollution, and largely generates will cause precipitation, snowfall in being discharged into Atmospheric processes, influence part Regional climate.
Currently, in wet desulfurizing process, in order to mitigate above-mentioned visual pollution and the influence to local regional climate, usually Flue gas can be cooled down, to reduce the vapour content in flue gas.A kind of common type of cooling is in the prior art: setting Then slurries after cooling are passed through desulfuration absorbing tower that is, by cooling down to the slurries of wet desulphurization by slurry heat exchanger Spray tube layer in sprayed, with this achieve the purpose that reduce flue-gas temperature.
But found in practical application, when using the above-mentioned type of cooling, there are following two aspects drawbacks:
On the one hand be that slurry heat exchanger fouling, attrition and attack are serious, cause operation stability it is poor, safeguard operation cost It is high;
It on the other hand is that water level frequently transfinites in desulfuration absorbing tower, the water balance of desulphurization system is destroyed, and it is de- to influence wet process The operation stability and safety in operation of sulphur system.
In view of this, how to develop a kind of circulating treating system of wet desulphurization slurry, it is made to realize reduction flue gas temperature While spending purpose, above-mentioned two aspects drawback can be evaded, be those skilled in the art's technical issues that need to address.
Utility model content
In order to solve the above technical problems, the utility model provides a kind of circulating treating system of wet desulphurization slurry, it is described Circulating treating system includes:
Desulfuration absorbing tower sets gradually higher level's demister, junior's demister, Multi-layer sprinkling tube layer, support in tower from top to bottom Disk and slurry pool, the slurry pool are connected to by delivery pump with the one or more layers of spray tube layer;
Separation equipment is connected to, for isolating dilute slurry from fraction slurries with the slurry pool;
Dilute slurry heat exchanger is connected to the separation equipment, for reducing the temperature of dilute slurry, and is absorbed with the desulfurization Tower connection, the dilute slurry after making cooling are passed through the desulfuration absorbing tower;
Clarifying equipment, for isolating clear water from fraction slurries or part dilute slurry and clear water being discharged for use as described The daily water consumption of other outer units of the process water and system of desulfuration absorbing tower.
Circulating treating system provided by the utility model by isolating dilute slurry from fraction slurries, and makes dilute slurry The cooling that exchanges heat is passed through in dilute slurry heat exchanger.Since particle concentration is lower in dilute slurry, and grain diameter moves followability compared with thread Preferably, it is not easy deposition or fouling in dilute slurry heat exchanger under reasonable flow conditions, has thus evaded dilute slurry heat exchanger The drawbacks of easy fouling, attrition and attack.
Also, the circulating treating system is passed through dilute slurry after cooling in desulfuration absorbing tower, effectively reduces desulfurization absorption The mean temperature of slurries in tower, and flue gas is sprayed using the slurries of these lower temperatures, flue gas temperature is reduced so as to reach The purpose of degree, and the low temperature slurries droplet sprayed out is conducive to improve desulfurization absorbent CaCO3Solubility and strengthen to cigarette SO in gas2Absorption, thus be conducive to desulphurization reaction progress.
Also, the circulating treating system by isolating clear water from fraction slurries, and part clear water is expelled at circulation Except reason system, evade the problem of water level transfinites in desulfuration absorbing tower, is maintained the water balance of wet desulfurization system.
Optionally, the outlet of the dilute slurry heat exchanger is connected to by the 4th delivery pump with a spray tube layer;It is described Separation equipment includes slurry distribution box and the first cyclone separator;
The slurry distribution box, import are connected to the slurry pool, and top passes through the first delivery pump and first eddy flow The inlet communication of separator, lower part are connected to by the second delivery pump with the clarifying equipment, and bottom passes through third delivery pump and institute State slurry pool connection;
First cyclone separator, the inlet communication on top and the dilute slurry heat exchanger, lower part and the dilute slurry The outlet of heat exchanger.
Optionally, the outlet of the dilute slurry heat exchanger is connected to by the 4th delivery pump with a spray tube layer;It is described Separation equipment includes slurry distribution box and the first cyclone separator;
The slurry distribution box, import are connected to the slurry pool, and top passes through the first delivery pump and first eddy flow The inlet communication of separator, lower part are connected to by the second delivery pump with the clarifying equipment, and bottom passes through third delivery pump and institute State slurry pool connection;
First cyclone separator, the inlet communication on top and the dilute slurry heat exchanger, lower part pass through the 5th conveying Pump is connected to another spray tube layer.
Optionally, the outlet of the dilute slurry heat exchanger is connected to by the 4th delivery pump with a spray tube layer;It is described Separation equipment includes the slurry distribution box with cyclonic separation function;
The slurry distribution box, have cylindricality tank wall, import it is tangent with cylindricality tank wall and pass through the first delivery pump with it is described Slurry pool connection, the inlet communication on top and the dilute slurry heat exchanger, lower part pass through the second delivery pump and the clarifying equipment Connection, bottom are connected to by third delivery pump with the slurry pool.
Optionally, the outlet of the dilute slurry heat exchanger is connected by third delivery pump and the 4th delivery pump and the slurry pool It is logical, and be connected to by the 4th delivery pump with the clarifying equipment;The separation equipment includes having cyclonic separation function Slurry distribution box;
The slurry distribution box, have cylindricality tank wall, import it is tangent with cylindricality tank wall and pass through the first delivery pump with it is described Slurry pool connection, the inlet communication on top and the dilute slurry heat exchanger, bottom passes through the third delivery pump and the slurries Pond connection.
Optionally, the spray tube layer of the outlet with the top of the dilute slurry heat exchanger is connected to.
Optionally, the clarifying equipment includes the second cyclone separator, clarifying basin, filter and deckered stock chest;
Second cyclone separator, import be connected to the lower part of the slurry distribution box or with the dilute slurry heat exchanger Outlet, top is connected to the clarifying basin, and bottom is connected to the deckered stock chest;
The clarifying basin, bottom are connected to the deckered stock chest;
The filter, import are connected to the top of the clarifying basin, and outlet is in communication with the outside, bottom and the deckered stock chest Connection;
The deckered stock chest is connected to by the third delivery pump with the slurry pool.
Optionally, the outlet of the filter also passes through delivery pump and is connected to junior's demister, uses part clear water Make the process water of the desulfuration absorbing tower.
Detailed description of the invention
Fig. 1 is the signal of the first specific embodiment of circulating treating system of wet desulphurization slurry provided by the utility model Figure;
Fig. 2 is the signal of the second specific embodiment of circulating treating system of wet desulphurization slurry provided by the utility model Figure;
Fig. 3 is the signal of the circulating treating system third specific embodiment of wet desulphurization slurry provided by the utility model Figure;
Fig. 4 is the signal of the 4th specific embodiment of circulating treating system of wet desulphurization slurry provided by the utility model Figure;
Fig. 5 is the cross section signal of slurry distribution box entrance location in third specific embodiment and the 4th specific embodiment Figure.
The reference numerals are as follows into Fig. 5 by Fig. 1:
1 desulfuration absorbing tower, 11 higher level's demisters, 12 junior's demisters, 13 spray tube layer, 14 pallets, 15 slurry pools, 16 again Hot device;
21a/21b/21c/21d slurry distribution box, the first cyclone separator of 22a/22b;
3 dilute slurry heat exchangers;
41 second cyclone separators, 42 clarifying basins, 43 filters, 44 deckered stock chests;
The first delivery pump of 51a/51b/51c/51d, the second delivery pump of 52a/52b/52c, 53a/53b/53c/53d third are defeated Send pump, the 4th delivery pump of 54a/54b/54c/54d, the 5th delivery pump of 55b.
Specific embodiment
In order to make those skilled in the art more fully understand the technical solution of the utility model, with reference to the accompanying drawing and have Body embodiment is described in further detail the technical solution of the utility model.
Referring to FIG. 1, the circulating treating system first that Fig. 1 is wet desulphurization slurry provided by the utility model is embodied The schematic diagram of example.
As shown in Figure 1, the circulating treating system of wet desulphurization slurry provided by the utility model include desulfuration absorbing tower 1, Separation equipment, dilute slurry heat exchanger 3 and clarifying equipment.
Specifically, higher level's demister 11, junior's demister 12, multilayer spray are set gradually in desulfuration absorbing tower 1 from top to bottom Shower pipe layer 13 (four layers are shown in figure), the porous slurries pallet 14 for flowing and strengthening absorption, slurry pool 15.The desulfurization absorbs Tower can both use limestone-gypsum method, can also be using ammonia process, sodium alkali or Dual alkali etc..
Specifically, separation equipment includes slurry distribution box 21a and the first cyclone separator 22a.
Specifically, clarifying equipment includes two the second cyclone separators 41, clarifying basin 42, two filters 43 and deckered stock chests 44.The second cyclone separator 41 for being located at upstream is hereafter known as the second cyclone separator of upstream 41, the second of downstream will be located at Cyclone separator 41 is known as the second cyclone separator of downstream 41, and the filter 43 for being located at upstream is known as upstream filter 43, will Filter 43 positioned at downstream is known as downstream filter 43.It should be noted that the second cyclone separator 41 and filter 43 Quantity can reasonable disposition according to actual needs, for example, second cyclone separator 41 and a filter 43 is only arranged It is possible.
Wherein, the inlet communication of slurry pool 15 and slurry distribution box 21a makes fraction slurries enter slurry distribution box 21a.And And slurry pool 15 is also connected to (slurry pool in the specific embodiment by delivery pump with one or more layers of spray tube layer 13 15 are connected to by three delivery pumps with three layers of spray tube layer 13 respectively), enter fraction slurries in corresponding spray tube layer 13.
Wherein, the top of slurry distribution box 21a is connected by the import of the first delivery pump 51a and the first cyclone separator 22a It is logical, enter diluter slurries after settlement positioned at the top slurry distribution box 21a in the first cyclone separator 22a, the Cyclonic separation is carried out in one cyclone.Also, the lower part of slurry distribution box 21a is revolved by the second delivery pump 52a and upstream second The inlet communication of stream separator 41 makes the denseer slurries positioned at the lower part slurry distribution box 21a enter the second cyclonic separation of upstream In device 41.Also, the bottom of slurry distribution box 21a is connected to by third delivery pump 53a with slurry pool 15, makes to be located at distribution of slurry The denseer slurries of the bottom case 21a return in slurry pool 15.
Wherein, the inlet communication on the top of the first cyclone separator 22a and dilute slurry heat exchanger 3, makes the thin pulp isolated Liquid enters in dilute slurry heat exchanger 3, exchanges heat and cools down with the recirculated water for flowing through dilute slurry heat exchanger 3, due to the particle in dilute slurry Concentration is lower, and compared with thread to move followability preferable for grain diameter, is not easy in dilute slurry heat exchanger 3 under reasonable flow conditions Deposition or fouling, the drawbacks of thus having evaded the easy fouling of dilute slurry heat exchanger 3, attrition and attack.Also, the first cyclone separator The bottom of 22a and the outlet of dilute slurry heat exchanger 3, mix the denseer slurries isolated with the dilute slurry after cooling.
Wherein, the outlet of dilute slurry heat exchanger 3 is connected to by the 4th delivery pump 54a with a spray tube layer 13, makes mixing Dilute slurry and denseer slurries enter together in corresponding spray tube layer 13, since the temperature of mixed slurries is lower, use it Flue gas is sprayed, can achieve the purpose for reducing flue-gas temperature, and the low temperature slurries droplet sprayed out is conducive to improve desulfurization suction Receive agent CaCO3Solubility and strengthen to SO in flue gas2Absorption, thus be conducive to desulphurization reaction progress.Preferably, thin pulp The outlet of liquid heat exchanger 3 is connected to the spray tube layer 13 of the top.
Wherein, the inlet communication of the upper outlet of the second cyclone separator of upstream 41 and the second cyclone separator of downstream 41, The upper outlet of the second cyclone separator of downstream 41 is connected to clarifying basin 42, and the import of clarifying basin 42 and upstream filter 43 connects Logical, the outlet of upstream filter 43 and the inlet communication of downstream filter 43 make fraction slurries by two-stage cyclonic separation, clear Clearly, clear water is isolated after double-filtration.Also, the bottom of two second cyclone separators 41, the bottom of clarifying basin 42 and two mistakes The bottom of filter 43 is connected to deckered stock chest 44, and deckered stock chest 44 is connected to by third delivery pump 53a with slurry pool 15, makes to isolate Remaining denseer slurries return in slurry pool 15 after clear water.
Wherein, the outlet of downstream filter 43 is in communication with the outside, and makes the part clear water isolated that the circular treatment system be discharged Except system, thus evade the problem of water level transfinites in desulfuration absorbing tower 1, is maintained the water balance of wet desulfurization system. Specifically, it is cold this part clear water being discharged except circulating treating system can be used for desulfurized limestone slurrying, unit dragveyer But, grey field damping etc..Also, the outlet of downstream filter 43 also passes through delivery pump and is connected to junior demister 12, makes to isolate Part clear water be used for junior's demister 12 flushing.So used by the way that the clear water isolated to be used as to the technique of desulfuration absorbing tower The daily water consumption of water and other units can save water resource, and can save the operating cost of system.
Referring to FIG. 2, the circulating treating system second that Fig. 2 is wet desulphurization slurry provided by the utility model is embodied The schematic diagram of example.
As shown in Fig. 2, the difference of the second specific embodiment and the first specific embodiment is: dilute slurry heat exchanger 3 goes out Mouth is connected to by the 4th delivery pump 54b with a spray tube layer 13, and the spray tube layer 13 is made only to spray dilute slurry.First cyclonic separation The bottom of device 22b is connected to by the 5th delivery pump 55b with another spray tube layer 13, and the spray tube layer 13 is made only to spray denseer slurry Liquid.
Fig. 3-Fig. 4 is please referred to, Fig. 3 is that the circulating treating system third of wet desulphurization slurry provided by the utility model is specific The schematic diagram of embodiment;Fig. 4 is the 4th specific embodiment of circulating treating system of wet desulphurization slurry provided by the utility model Schematic diagram;Fig. 5 is the cross section signal of slurry distribution box entrance location in third specific embodiment and the 4th specific embodiment Figure.
As shown in figure 3, third specific embodiment and the difference of the first specific embodiment and the second specific embodiment are:
Slurry distribution box 21c itself has the function of cyclonic separation, thus the first cyclone separator is no longer separately provided.Specifically , as shown in figure 3, the slurry distribution box 21c with cyclonic separation function has cylindrical portion, as shown in figure 5, the cylindrical portion has Cylindricality tank wall, the import of slurry distribution box 21c and cylindricality tank wall are tangent, make slurries tangentially into slurry distribution box 21c, by This generates cyclonic separation effect, so as to which slurries are separated into dilute slurry and denseer slurries.Also, as shown in figure 3, cylindricality The lower section in portion is up big and down small tapered portion, and the precipitating for being conducive to particulate matter is arranged such, so as to further enhance separation effect Fruit.
Also, slurry pool 15 is by the inlet communication of the first delivery pump 51c and slurry distribution box 21c, make fraction slurries into Enter slurry distribution box 21c.Also, the inlet communication on the top of slurry distribution box 21c and dilute slurry heat exchanger 3 makes to be located at slurries The dilute slurry on the top distributor box 21c enters in dilute slurry heat exchanger 3;Lower part passes through the second delivery pump 52c and the second eddy flow of upstream Separator 41 is connected to, and enters the denseer slurries positioned at the lower part slurry distribution box 21c in the second cyclone separator of upstream 41;Bottom Portion is connected to by third delivery pump 53c with slurry pool 15, and the denseer slurries positioned at the bottom slurry distribution box 21c is made to return to slurries In pond 15.
As shown in figure 4, the difference of the 4th specific embodiment and third specific embodiment is: dilute slurry heat exchanger 3 goes out Mouthful be connected to slurry pool 15 by the 4th delivery pump 54d and third delivery pump 53d, and passes through the 4th delivery pump 54d and upstream the The connection of two cyclone separators 41, a part of dilute slurry after making cooling enter the second cyclone separator 41 and carry out separating clarifying, Remaining dilute slurry returns in slurry pool 15.
In the above embodiments, the exhanst gas outlet position of desulfuration absorbing tower 1 is respectively provided with reheater 16, the flue gas after cooling Chimney is discharged into after the heating of reheater 16 from after the exhanst gas outlet discharge of desulfuration absorbing tower 1.
The circulating treating system of wet desulphurization slurry provided by the utility model is described in detail above.Herein In apply specific case the principles of the present invention and embodiment be expounded, the explanation of above embodiments is only used The method and its core concept of the utility model are understood in help.It should be pointed out that for those skilled in the art For, without departing from the principle of this utility model, several improvements and modifications can be made to this utility model, these Improvement and modification are also fallen into the protection scope of the utility model claims.

Claims (8)

1. a kind of circulating treating system of wet desulphurization slurry, which is characterized in that the circulating treating system includes:
Desulfuration absorbing tower (1) sets gradually higher level's demister (11), junior's demister (12), Multi-layer sprinkling in tower from top to bottom Tube layer (13), pallet (14) and slurry pool (15), the slurry pool (15) by delivery pump with it is one or more layers of described Spray tube layer (13) connection;
Separation equipment is connected to, for isolating dilute slurry from fraction slurries with the slurry pool (15);
Dilute slurry heat exchanger (3), is connected to the separation equipment, for reducing the temperature of dilute slurry, and absorbs with the desulfurization Tower (1) connection, the dilute slurry after making cooling are passed through the desulfuration absorbing tower (1);
Clarifying equipment, for isolating clear water from fraction slurries or part dilute slurry and clear water being discharged for use as the desulfurization The daily water consumption of the outer unit of the process water and system on absorption tower.
2. the circulating treating system of wet desulphurization slurry according to claim 1, which is characterized in that the dilute slurry heat exchange The outlet of device (3) is connected to by the 4th delivery pump with a spray tube layer (13);The separation equipment includes slurry distribution box With the first cyclone separator;
The slurry distribution box, import are connected to the slurry pool (15), and top passes through the first delivery pump and first eddy flow The inlet communication of separator, lower part are connected to by the second delivery pump with the clarifying equipment, and bottom passes through third delivery pump and institute State slurry pool (15) connection;
First cyclone separator, the inlet communication on top and the dilute slurry heat exchanger (3), lower part is changed with the dilute slurry The outlet of hot device (3).
3. the circulating treating system of wet desulphurization slurry according to claim 1, which is characterized in that the dilute slurry heat exchange The outlet of device (3) is connected to by the 4th delivery pump with a spray tube layer (13);The separation equipment includes slurry distribution box With the first cyclone separator;
The slurry distribution box, import are connected to the slurry pool (15), and top passes through the first delivery pump and first eddy flow The inlet communication of separator, lower part are connected to by the second delivery pump with the clarifying equipment, and bottom passes through third delivery pump and institute State slurry pool (15) connection;
First cyclone separator, the inlet communication on top and the dilute slurry heat exchanger (3), lower part pass through the 5th delivery pump It is connected to another spray tube layer.
4. the circulating treating system of wet desulphurization slurry according to claim 1, which is characterized in that the dilute slurry heat exchange The outlet of device (3) is connected to by the 4th delivery pump with a spray tube layer (13);The separation equipment includes with eddy flow point Slurry distribution box from function;
The slurry distribution box has cylindricality tank wall, and import is tangent with cylindricality tank wall and passes through the first delivery pump and the slurries Pond (15) connection, the inlet communication on top and the dilute slurry heat exchanger (3), lower part are set by the second delivery pump and the clarification Standby connection, bottom are connected to by third delivery pump with the slurry pool (15).
5. the circulating treating system of wet desulphurization slurry according to claim 1, which is characterized in that the dilute slurry heat exchange The outlet of device (3) is connected to by third delivery pump and the 4th delivery pump with the slurry pool (15), and passes through the 4th conveying Pump is connected to the clarifying equipment;The separation equipment includes the slurry distribution box with cyclonic separation function;
The slurry distribution box has cylindricality tank wall, and import is tangent with cylindricality tank wall and passes through the first delivery pump and the slurries Pond (15) connection, the inlet communication on top and the dilute slurry heat exchanger (3), bottom passes through the third delivery pump and the slurry Liquid pool (15) connection.
6. according to the circulating treating system of the described in any item wet desulphurization slurries of claim 2-4, which is characterized in that described dilute The outlet of slurry heat exchanger (3) is connected to the spray tube layer (13) of the top.
7. according to the circulating treating system of the described in any item wet desulphurization slurries of claim 2-4, which is characterized in that described clear Clear equipment includes the second cyclone separator (41), clarifying basin (42), filter (43) and deckered stock chest (44);
Second cyclone separator (41), import be connected to the lower part of the slurry distribution box or with the dilute slurry heat exchanger (3) outlet, top are connected to the clarifying basin (42), and bottom is connected to the deckered stock chest (44);
The clarifying basin (42), bottom is connected to the deckered stock chest (44);
The filter (43), import are connected to the top of the clarifying basin (42), and outlet is in communication with the outside, bottom with it is described dense Stock tank (44) connection;
The deckered stock chest (44) is connected to by the third delivery pump with the slurry pool (15).
8. the circulating treating system of wet desulphurization slurry according to claim 7, which is characterized in that the filter (43) Outlet also pass through delivery pump and be connected to junior's demister (12).
CN201821177736.6U 2018-07-24 2018-07-24 A kind of circulating treating system of wet desulphurization slurry Active CN209317434U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112675675A (en) * 2020-12-11 2021-04-20 杭州蕴泽环境科技有限公司 Desulfurization slurry waste heat recovery system and method
CN112755750A (en) * 2020-12-21 2021-05-07 通化金山银山环保设备制造有限公司 Method for reducing sodium sulfate generation in boiler dual-alkali desulfurization process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112675675A (en) * 2020-12-11 2021-04-20 杭州蕴泽环境科技有限公司 Desulfurization slurry waste heat recovery system and method
CN112755750A (en) * 2020-12-21 2021-05-07 通化金山银山环保设备制造有限公司 Method for reducing sodium sulfate generation in boiler dual-alkali desulfurization process

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