CN108421342A - Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower - Google Patents

Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower Download PDF

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Publication number
CN108421342A
CN108421342A CN201810312716.3A CN201810312716A CN108421342A CN 108421342 A CN108421342 A CN 108421342A CN 201810312716 A CN201810312716 A CN 201810312716A CN 108421342 A CN108421342 A CN 108421342A
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CN
China
Prior art keywords
desulfuration absorbing
absorbing tower
spraying
cooling
white cigarette
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810312716.3A
Other languages
Chinese (zh)
Inventor
王海刚
曹蕃
金绪良
郭婷婷
袁斌
张志刚
许希
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thermal Power Generation Technology Research Institute of China Datang Corporation Science and Technology Research Institute Co Ltd
Original Assignee
Thermal Power Generation Technology Research Institute of China Datang Corporation Science and Technology Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thermal Power Generation Technology Research Institute of China Datang Corporation Science and Technology Research Institute Co Ltd filed Critical Thermal Power Generation Technology Research Institute of China Datang Corporation Science and Technology Research Institute Co Ltd
Priority to CN201810312716.3A priority Critical patent/CN108421342A/en
Publication of CN108421342A publication Critical patent/CN108421342A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456Removing acid components
    • B01D53/1481Removing sulfur dioxide or sulfur trioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • B01D53/185Liquid distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to the devices that spraying cooling in a kind of desulfuration absorbing tower eliminates white cigarette, it is characterized in that, including desulfuration absorbing tower, the desulfuration absorbing tower is internally provided with demister, the spraying ventilating device for cooling down to flue gas by cooling water is equipped with above the demister, and the water collector for collecting the cooling water after spraying, the water collector connect the first buffering pond outside desulfuration absorbing tower.The present invention can remove condensable particulate matter in flue gas and eliminate white cigarette, have running resistance small, floor space is small, and transformation difficulty is small, the low technique effect of cost of investment.

Description

Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower
Technical field
The invention belongs to spraying coolings in flue gases purification field more particularly to a kind of desulfuration absorbing tower to eliminate white cigarette Device.
Background technology
Wet desulfurizing process is that China applies most common flue gas scrubbing CO_2 technique.Wet desulphurization exiting flue gas one As in saturation or close to saturation state wet flue gas.Wet flue gas is lower with temperature after in smoke stack emission to air When surrounding air contacts, in flue gas diffusion process, saturation or nearly saturation wet flue gas generate condensation and condensation since temperature reduces, The a large amount of condensing water droplets formed in flue gas generate refraction to light, scattering is called " cigarette to show white or grey Plumage " (" the big white cigarette " that is commonly called as, " white haze ", " white plume " etc.).
Influence of the white cigarette to environment is mainly reflected in two aspects.On the one hand it is higher using wet flue gas relative humidity, contains There are a large amount of sulfate, nitrate, sulfate, nitrate particle to enter " core " for becoming in air and adsorbing other pollutants, be Cause a key factor of haze.On the other hand it is that spreading for plume also causes " vision dirt to the resident on power plant periphery Dye " generates certain influence to the life of resident.
Currently, the major technique that white cigarette is administered includes flue gas, flue gas cool-down reheating and flue gas cool-down technology.Wherein, Flue gas technology can eliminate white cigarette when environment temperature is higher, and it is not notable that white cigarette effect is eliminated when environment temperature is relatively low.Separately Outside, flue gas technology cannot remove the condensable particulate matter in flue gas.
Invention content
The object of the present invention is to provide the devices that spraying cooling in a kind of desulfuration absorbing tower eliminates white cigarette, to remove in flue gas Condensable particulate matter and elimination white cigarette.
The present invention provides the devices that spraying cooling in a kind of desulfuration absorbing tower eliminates white cigarette, including desulfuration absorbing tower, take off Sulphur absorption tower is internally provided with demister, is equipped with above demister for being filled to the spraying cooling that flue gas cools down by cooling water It sets, and the water collector for collecting the cooling water after spraying, water collector connects the first buffering outside desulfuration absorbing tower Pond.
Further, water collector is pallet, and tray bottom trepanning is simultaneously connect with the first buffering pond by pipeline, can be made Cooling water after spray flows automatically to the first buffering pond and exchanges heat.
Further, the desulfuration absorbing tower inner wall above pallet is surrounded by for preventing spraying cooling water around under pallet The baffle of stream.
Further, current equalizer is additionally provided with inside desulfuration absorbing tower, current equalizer is located at the top of pallet, spraying cooling The lower section of device.
Further, current equalizer is packing layer, turbosphere, one kind in bubble level or combination.
Further, demister is tubular type or bundled tube, board-like, in ridge type demister one kind or combination.
Further, the liquid-gas ratio of spraying ventilating device flue gas spray is 0.5-3.
Further, spraying ventilating device includes nozzle, and nozzle uses pressure type or rotarytype injector.
Further, spraying ventilating device is connect by the second buffering pond with cooling tower.
Further, the first buffering pond is connect with cooling tower, is buffered in pond by the recirculated water pair first of cooling tower Cooling water carry out direct cooling.
According to the above aspect of the present invention, eliminating the device of white cigarette by spraying cooling in desulfuration absorbing tower, can remove can in flue gas It condenses particulate matter and eliminates white cigarette, have running resistance small, floor space is small, and transformation difficulty is small, the low technology effect of cost of investment Fruit.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technical means of the present invention, And can be implemented in accordance with the contents of the specification, below with presently preferred embodiments of the present invention and after coordinating attached drawing to be described in detail such as.
Description of the drawings
Fig. 1 is the structural schematic diagram for the device that spraying cooling eliminates white cigarette in a kind of desulfuration absorbing tower of the present invention.
Figure label:
1- desulfuration absorbing towers;The first demisters of 11-;12- spraying ventilating devices;13- pallets;14- baffles;15- spraying layers; 16- desulfuration recycle pumps;The second demisters of 17-;
2- chimneys;3- first buffers pond;The first centrifugal pumps of 4-;5- cooling towers;The second centrifugal pumps of 6-;The second buffered waters of 7- Pond.
Specific implementation mode
With reference to the accompanying drawings and examples, the specific implementation mode of the present invention is described in further detail.Implement below Example is not limited to the scope of the present invention for illustrating the present invention.
The device that spraying cooling in a kind of desulfuration absorbing tower eliminates white cigarette, including desulfuration absorbing tower 1 are present embodiments provided, Desulfuration absorbing tower 1 is internally provided with the first demister 11, and 11 top of the first demister is equipped with for being carried out to flue gas by cooling water The spraying ventilating device 12 of cooling, and the water collector for collecting the cooling water after spraying, water collector connect desulfurization and inhale Receive the first buffering pond 3 outside tower 1.
In the present embodiment, water collector is pallet 13, and 13 bottom opening of pallet simultaneously passes through pipeline and the first buffering pond 3 Connection, can make the cooling water after spray flow automatically to the first buffering pond 3 and exchange heat.
In the present embodiment, the desulfuration absorbing tower inner wall of 13 top of pallet is surrounded by for preventing spraying cooling water from bypassing Pallet influences the baffle 14 of desulphurization system water balance downstream to desulfuration absorbing tower slurry pool.
In the present embodiment, current equalizer (not shown) is additionally provided with inside desulfuration absorbing tower 1, current equalizer is located at pallet 13 Top, the lower section of spraying ventilating device 12.
In the present embodiment, one kind in packing layer, turbosphere, bubble level or combination can be used in current equalizer.
In the present embodiment, 12 top of spraying ventilating device is equipped with for removing the second demister of droplet carried in flue gas 17。
In the present embodiment, tubular type or bundled tube, board-like, ridge type can be used in the first demister 11, the second demister 17 One kind in demister or combination are arranged in the top of spraying layer 15.
In the present embodiment, the liquid-gas ratio of 12 flue gas of spraying ventilating device spray is 0.5-3, and one layer to three layers spray can be arranged Drenching layer.
In the present embodiment, spraying ventilating device 12 includes nozzle, and nozzle uses pressure type or rotarytype injector.
In the present embodiment, spraying ventilating device 12 buffers pond 7 by the second centrifugal pump 6, second and connects with cooling tower 5 It connects.
In the present embodiment, the first buffering pond 3 is connect by the first centrifugal pump 4 with cooling tower 5, passes through cooling tower 5 Recirculated water pair first buffers the cooling water in pond 3 and carries out direct cooling, closed cycle can also be used to cool down, needed between setting It connects aerial cooler or mechanical draft tower cools down to cooling water, recycled after cooling water agent-feeding treatment.The present embodiment carries The device of spraying cooling elimination white cigarette is being pulled out by lifting desulfuration absorbing tower above demister in the desulfuration absorbing tower of confession Direct spraying ventilating device is set in high region, is cooled down to flue gas using cool water shower.Cooling water after spray or Flue gas condensing water is got up by the collection tray of lower part, to prevent from influencing the water balance in desulfuration absorbing tower, is then flowed automatically to outside tower Buffering pond.It can realize that non-heating season reduces 3-5 DEG C of wet-method desulfurized fume temperature, the condensed water 20- in recovered flue gas 30%, realize that Heating Season reduces 5-10 DEG C of wet-method desulfurized fume temperature, the condensed water 30-50% in recovered flue gas.Recycle cigarette In gas while condensed water, with the condensable particulate matter in cooperation-removal flue gas and there can be good elimination white cigarette, Have running resistance small simultaneously, the advantages such as floor space is small, and cost of investment is low.(pH value is the condensed water being precipitated by flue gas cool-down 2-3 or so) it is sufficiently mixed with weakly alkaline recirculated water, it can also avoid inside desulfuration absorbing tower and the corrosion of pipeline, reduction are anti- Rotten difficulty of construction.
The smoke temperature reducer of the present embodiment takes up an area minimum, is particularly suitable for the old of desulfuration absorbing tower nearby not no sufficient space Factory is transformed.Such as a 350MW unit is transformed, desulfuration absorbing tower is lifted to 10 meters above demister, in the area lifted Domain sets gradually pallet, baffle, spraying layer (spraying ventilating device) and efficient bundled tube demister.Cooling water is using cooling tower Recirculated water, water are 2400 cubes ms/h.The recirculated water in pond of cooling tower is extracted into buffering pond with high-pressure pump, then Spraying layer is transported under the action of another high-pressure pump to be sprayed.The recirculated water sprayed from top to bottom carries out reverse with flue gas Heat exchange.Flue gas is after efficient bundled tube demister through smoke stack emission.It recycles water spray later and the condensed water of flue gas precipitation is mixed It is combined in the pallet for falling into lower section, water outlet is arranged in pallet lower part, and water is allowed to flow automatically to what desulfuration absorbing tower was nearby arranged In buffer pool.The water of buffer pool returns to cooling tower under the action of centrifugal pump and cools down.In the whole process, flue gas cool-down 3 DEG C, about 22 cubes ms/h of condensation water quantity is precipitated.
The above is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is noted that for this skill For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and Modification, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (10)

1. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower, which is characterized in that described de- including desulfuration absorbing tower Sulphur absorption tower is internally provided with demister, is equipped with above the demister for being dropped to the spray that flue gas cools down by cooling water Warm device, and the water collector for collecting the cooling water after spraying, the water collector connect outside desulfuration absorbing tower First buffering pond.
2. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 1, which is characterized in that institute It is pallet to state water collector, and the tray bottom trepanning is simultaneously connect by pipeline with first buffering pond, after can making spray Cooling water flow automatically to it is described first buffering pond exchange heat.
3. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 2, which is characterized in that institute The desulfuration absorbing tower inner wall above pallet is stated to be surrounded by for preventing spraying cooling water from bypassing the baffle that the pallet flows down.
4. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 3, which is characterized in that institute It states and is additionally provided with current equalizer inside desulfuration absorbing tower, the current equalizer is located at the top of the pallet, the spraying cooling dress The lower section set.
5. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 4, which is characterized in that institute It is packing layer, turbosphere, one kind in bubble level or combination to state current equalizer.
6. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 1, which is characterized in that institute It is tubular type or bundled tube, board-like, in ridge type demister one kind or combination to state demister.
7. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 1, which is characterized in that institute The liquid-gas ratio for stating spraying ventilating device flue gas spray is 0.5-3.
8. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 7, which is characterized in that institute It includes nozzle to state spraying ventilating device, and the nozzle uses pressure type or rotarytype injector.
9. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 8, which is characterized in that institute Spraying ventilating device is stated to connect with cooling tower by the second buffering pond.
10. spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower according to claim 2, which is characterized in that First buffering pond is connect with cooling tower, and buffering the cooling water in pond by the recirculated water pair first of cooling tower carries out directly Stream cooling.
CN201810312716.3A 2018-04-09 2018-04-09 Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower Pending CN108421342A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108970368A (en) * 2018-10-09 2018-12-11 杭州蕴泽环境科技有限公司 Zero water consume wet desulphurization device of one kind and its sulfur removal technology
CN109482021A (en) * 2018-12-05 2019-03-19 南通醋酸纤维有限公司 Single-tower three-zone desulfurization and whitening integrated device and method
CN109772106A (en) * 2019-01-21 2019-05-21 浙江菲达环保科技股份有限公司 A kind of flue gas takes off white water saving fixtures
CN111330305A (en) * 2020-04-13 2020-06-26 华能国际电力股份有限公司 Spray condensing and water recovering device in desulfurization absorption tower
CN111420524A (en) * 2020-04-27 2020-07-17 大唐环境产业集团股份有限公司 Demisting water receiver and wet desulphurization tower
CN112892167A (en) * 2021-01-27 2021-06-04 山东保蓝环保工程有限公司 A tail gas purification takes off white system for bonderizing industry degree of depth desorption acid mist

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107185329A (en) * 2017-07-24 2017-09-22 北京国电龙源环保工程有限公司 A kind of high-effective dust-removing and device for reclaiming moisture
CN208512140U (en) * 2018-04-09 2019-02-19 中国大唐集团科学技术研究院有限公司火力发电技术研究院 Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107185329A (en) * 2017-07-24 2017-09-22 北京国电龙源环保工程有限公司 A kind of high-effective dust-removing and device for reclaiming moisture
CN208512140U (en) * 2018-04-09 2019-02-19 中国大唐集团科学技术研究院有限公司火力发电技术研究院 Spraying cooling eliminates the device of white cigarette in a kind of desulfuration absorbing tower

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108970368A (en) * 2018-10-09 2018-12-11 杭州蕴泽环境科技有限公司 Zero water consume wet desulphurization device of one kind and its sulfur removal technology
CN109482021A (en) * 2018-12-05 2019-03-19 南通醋酸纤维有限公司 Single-tower three-zone desulfurization and whitening integrated device and method
CN109772106A (en) * 2019-01-21 2019-05-21 浙江菲达环保科技股份有限公司 A kind of flue gas takes off white water saving fixtures
CN111330305A (en) * 2020-04-13 2020-06-26 华能国际电力股份有限公司 Spray condensing and water recovering device in desulfurization absorption tower
CN111420524A (en) * 2020-04-27 2020-07-17 大唐环境产业集团股份有限公司 Demisting water receiver and wet desulphurization tower
CN112892167A (en) * 2021-01-27 2021-06-04 山东保蓝环保工程有限公司 A tail gas purification takes off white system for bonderizing industry degree of depth desorption acid mist
CN112892167B (en) * 2021-01-27 2022-09-27 山东保蓝环保工程有限公司 A tail gas purification takes off white system for bonderizing industry degree of depth desorption acid mist

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Application publication date: 20180821

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