CN209182599U - A kind of eyeglass of anti-oxidant anti-blue light - Google Patents
A kind of eyeglass of anti-oxidant anti-blue light Download PDFInfo
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- CN209182599U CN209182599U CN201822229904.8U CN201822229904U CN209182599U CN 209182599 U CN209182599 U CN 209182599U CN 201822229904 U CN201822229904 U CN 201822229904U CN 209182599 U CN209182599 U CN 209182599U
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Abstract
The utility model relates to a kind of eyeglasses of anti-oxidant anti-blue light; the eyeglass of the anti-oxidant anti-blue light includes substrate and the film layer that the substrate outer surface is arranged in; the film layer includes the prime coat stacked gradually from inside to outside, anti oxidation layer, anti-blue light layer and protective layer, and the prime coat includes the first low refractive index film layer；The anti oxidation layer is the 4th selenium layer, and the anti-blue light layer is alternately made of total 3-7 layers of high refractive index film layer and low refractive index film layer.The eyeglass of anti-oxidant anti-blue light described in the utility model has preferable anti-oxidant, anti-blue light effect, and when having pattern, pattern is tightly combined with eyeglass, and clear patterns are true to nature, colour-fast, do not influence wearer's sight, with preferable market prospects.
Description
Technical field
The utility model relates to anti-blue light eyeglass technology of preparing, especially a kind of eyeglass of anti-oxidant anti-blue light.
Background technique
Blue light is nature visible light a part therein, and daylight and electronic curtain can all issue blue light, and wavelength is short, energy
Height can be directed through the through eye macular area of crystalline lens, lead to maculopathy.All kinds of LED such as TV, computer, PAD and mobile phone
Light-emitting display apparatus, producer is beautiful to make its image quality effect more become clear, and often promotes the blue light strength of LED backlight, companion
With the every aspect that is universal and penetrating into life of these electronic products, the chance that everyone contacts blue light sharply increases therewith
Add, for the ordinary person, the irradiation for a long time of barrier blue light is to reduce damage most effectual way, therefore anti-blue light eyeglass obtains extensively
General utilization.Currently, anti-blue light eyeglass is generally absorbed by substrate or the effect of barrier blue light is realized in film layer reflection.Film layer reflection
It usually requires compared with multilayer film or the higher film layer of thickness.
In order to develop diversified eyeglass, the eyeglass of specific function is made to become a kind of faddish trend with pattern.Pattern must
There must be preferable syncretizing effect with lens materials, and be stabilized, be not susceptible to oxidation stain, meanwhile and most important one
Point, pattern should not influence the sight of wearer.For anti-blue light eyeglass, since its anti-blue light designs, eyeglass is blocked up, the number of plies
More, pattern layer is difficult to firm attachment, thus is difficult to ensure the combination effect of pattern.
Utility model content
The purpose of this utility model is to overcome existing anti-blue light eyeglass film adhesion is poor, it is difficult to which figure is stablized in load
The problem of case, provides a kind of eyeglass of anti-oxidant anti-blue light.The eyeglass of the anti-oxidant anti-blue light is set by special layer structure
Meter has anti-blue light effect so that light reflecting effect of the eyeglass to wavelength in 400~500nm is preferable；Have inside eyeglass compared with
High and stable resistivity, surface oxidation-resistant performance is good, and stickiness is good；It is true to nature and do not influence wearer that clear patterns may be implemented
The effect of sight.
Concrete scheme is as follows:
A kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer that the substrate outer surface is arranged in, the film layer
Including prime coat, anti oxidation layer, anti-blue light layer and the protective layer stacked gradually from inside to outside, the prime coat includes the first low folding
Penetrate rate film layer；The anti oxidation layer is the 4th selenium layer, and the anti-blue light layer is by total 3-7 layers of high refractive index film layer and low
Index film layer alternately forms；
Wherein, the low refractive index film layer in the first low refractive index film layer or the anti-blue light layer is SiO2, silicon
Aluminium mixture or MgF2In any one formed film layer；And the high refractive index film layer in the anti-blue light layer is ZrO2、
Ti3O5Or Ta2O5In any one formed film layer.
Further, the substrate is acrylic substrate, polycarbonate substrate, nylon substrates, CR-39 substrate or glass base
Any one of piece.
Further, the protective layer is the film layer that waterproof material is formed.
Further, the prime coat with a thickness of 50-300 Ethylmercurichlorendimide；The anti oxidation layer with a thickness of 150-400 angstroms
Rice；The anti-blue light layer with a thickness of 2000-5000 Ethylmercurichlorendimide；The protective layer with a thickness of 10-280 Ethylmercurichlorendimide.
Further, pattern layer is additionally provided between the prime coat and the anti oxidation layer, the pattern layer is by pattern
It is formed with third low refractive index film layer, the prime coat is made of the first low refractive index film layer and the second selenium layer, wherein institute
The second selenium layer and the pattern layer are stated close to the third low refractive index film layer is SiO2, silicon-aluminum mixture or MgF2In appoint
It anticipates the film layer of formation a kind of.
Further, the eyeglass of the anti-oxidant anti-blue light by stack gradually substrate, the first low refractive index film layer,
Second selenium layer, pattern, third low refractive index film layer, the 4th selenium layer, the 5th low refractive index film layer, the 6th high refractive index film
Layer, the 7th low refractive index film layer, the 8th high refractive index film layer, the 9th low-index layer and waterproof layer composition.
Further, the eyeglass of the anti-oxidant anti-blue light by stack gradually substrate, the first low refractive index film layer,
Second selenium layer, pattern, third low refractive index film layer, the 4th selenium layer, the 6th high refractive index film layer, the 5th low refractive index film
Layer, the 8th high refractive index film layer, the 7th low refractive index film layer and waterproof layer composition.
Further, in the prime coat the first low refractive index film layer with a thickness of 50-150 Ethylmercurichlorendimide, the second selenium layer
With a thickness of 50-150 Ethylmercurichlorendimide；Third low refractive index film layer with a thickness of 1000-1500 Ethylmercurichlorendimide in the pattern layer；The antioxygen
Change layer with a thickness of 150-400 Ethylmercurichlorendimide；5th low refractive index film layer in the anti-blue light layer, the 6th high refractive index film layer,
7th low refractive index film layer, the 8th high refractive index film layer, the 9th low-index film thickness be followed successively by 600-800 angstroms
Rice, 400-600 Ethylmercurichlorendimide, 600-800 Ethylmercurichlorendimide, 400-600 Ethylmercurichlorendimide；1000-2000 Ethylmercurichlorendimide；The protective layer with a thickness of 10-280
Ethylmercurichlorendimide.
Further, the eyeglass of the anti-oxidant anti-blue light by stack gradually substrate, the first low refractive index film layer,
Second selenium layer, pattern, third low refractive index film layer, the 4th selenium layer, the 5th low refractive index film layer, the 6th high refractive index film
Layer, the 7th low refractive index film layer, the 8th high refractive index film layer, the 9th low refractive index film layer, the tenth high refractive index layer,
11 low refractive index film layers and waterproof layer composition.
Further, in the prime coat the first low refractive index film layer with a thickness of 80-130 Ethylmercurichlorendimide, the second selenium layer
With a thickness of 80-130 Ethylmercurichlorendimide；Third low refractive index film layer with a thickness of 1200-1400 Ethylmercurichlorendimide in the pattern layer；The antioxygen
Change layer with a thickness of 200-380 Ethylmercurichlorendimide；5th low refractive index film layer in the anti-blue light layer, the 6th high refractive index film layer,
7th low refractive index film layer, the 8th high refractive index film layer, the 9th low refractive index film layer, the tenth high refractive index layer, the tenth
The thickness of one low refractive index film layer be followed successively by 650-750 Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide, 650-750 Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide,
650-750 Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide, 1300-1600 Ethylmercurichlorendimide；The protective layer with a thickness of 50-250 Ethylmercurichlorendimide.
The utility model has the advantages that the eyeglass of anti-oxidant anti-blue light described in the utility model has preferable anti-oxidant, anti-blue light effect,
Can have pattern, can not also layout, when have pattern when, pattern layer is tightly combined with eyeglass, and clear patterns are true to nature,
It is colour-fast, do not influence wearer's sight, have preferable market prospects.
Detailed description of the invention
In order to illustrate more clearly of the technical solution of the utility model, attached drawing will be briefly described below, it is aobvious and easy
Insight, the accompanying drawings in the following description merely relate to some embodiments of the utility model, rather than limitations of the present invention.
Fig. 1 is the lens structure schematic diagram that the utility model one embodiment 1 provides；
Fig. 2 is the lens structure schematic diagram that the utility model one embodiment 2 provides；
Fig. 3 is the lens reflecting rate spectrogram that the utility model one embodiment 2 provides.
Specific embodiment
The definition of part term used in the utility model is given below, other terms that do not address have this field institute
Well known definition and meaning:
Substrate: substrate can be planar optics, be also possible to the eyeglass with certain radian.
Outer surface: outer surface refers to eyeglass in a state of use in the utility model, for wearer, is located at outer
The one side of side.
Angstrom meter per second forms the speed of film growth for characterizing particle deposition.
Anti-blue light layer is preferably that 5 layers of high and low refractive index film layer alternately form in the utility model, specially the 5th low folding
Penetrate rate film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index film layer, the 9th low folding
Rate film layer is penetrated, thickness is followed successively by 600-800 Ethylmercurichlorendimide, 400-600 Ethylmercurichlorendimide, 600-800 Ethylmercurichlorendimide, 400-600 Ethylmercurichlorendimide, 1300-
1700 Ethylmercurichlorendimides, preferably 620-780 Ethylmercurichlorendimide, 420-580 Ethylmercurichlorendimide, 620-780 Ethylmercurichlorendimide, 420-580 Ethylmercurichlorendimide, 1400-1600 Ethylmercurichlorendimide,
More preferably 700 Ethylmercurichlorendimides, 500 Ethylmercurichlorendimides, 700 Ethylmercurichlorendimides, 500 Ethylmercurichlorendimides, 1500 Ethylmercurichlorendimides；The protective layer with a thickness of 150 Ethylmercurichlorendimides.Film
The thickness of layer is combined with material, and optimal anti-blue light effect may be implemented.Wherein, the 5th low refractive index film layer is wanted and antioxygen
Change layer close to because anti oxidation layer uses selenium, as high refractive index layer, the 5th low refractive index film layer and anti oxidation layer are tight for this
Neighbour is arranged alternately with forming high and low refractive index, improves anti-blue light effect.
In the utility model, high refractive index layer, such as the 6th high refractive index film layer or the 8th high refractive index film layer, membrane material
For ZrO2、Ti3O5Or Ta2O5In any one.
In the utility model, low-index layer, such as the first low refractive index film layer, third low refractive index film layer, the 5th
Low refractive index film layer, the 7th low refractive index film layer or the 9th low refractive index film layer, membrane material SiO2, silicon-aluminum mixture or
MgF2In any one, preferably silicon-aluminum mixture, the silicon-aluminum mixture can be SiO2With Al2O3Mixture, such as
Al2O3Account for the 2-6% of silicon-aluminum mixture gross weight, more preferably Al2O3Account for the 3-3.5% of silicon-aluminum mixture gross weight.The material can be with
Self-control can also use commercial product, and such as vacuum coating material L5, Chinese adopted name " silicon-aluminum mixture ", " L5 " is its moral
State's adopted name, the material can be by Merck Optical Co., Ltd, Nanyang happy Rett New Optical Material Co., Ltd or Suzhou Putin's vacuum
Technology Co., Ltd. provides, and regular size is 1-3mm shot, white.
Pattern in the utility model in pattern layer is ink print, copper mold plate is bonded pattern or electrostatic paster fitting is schemed
Any one in case.When production, pattern is printed or is fitted on prime coat, utilizes the knot of prime coat enhancing pattern and film layer
With joint efforts, prime coat is made of the first low refractive index film layer and the second selenium layer, preferably the second selenium layer and pattern layer close to.Mimeograph or
Person is bonded after pattern, carries out third low refractive index film layer plated film, removes ink or removal copper mold plate or removal later
Electrostatic paster forms pattern form using the contrast effect between white space and coating film area, and at the same time, pattern is located at second
Between selenium layer and third low refractive index film layer, the intensity of light can be effectively reduced, weaken pattern intensity, reach special vision
Effect, it may be assumed that wearer itself is almost not felt by the presence of pattern when observing, ensure that the sight of eyeglass is complete, and onlooker
It can see that clearly pattern, promote the aesthetic feeling and fashion statement of eyeglass.
In the preparation method of the eyeglass of anti-oxidant anti-blue light described in the utility model, it is normal that plated film, which uses vacuum coating equipment,
Advise equipment, such as the true coating machine that Long Pian vacuum technology limited liability company provides, the KRI that cooperation U.S.'s koff Mann provides
Ion source apparatus.The key of plated film is the temperature of vacuum chamber and the speed of particle deposition.Using 40-60 DEG C of advantage to be can be with
The miscellaneous gas for further excluding substrate, promotes the attachment degree of film.It should be noted that it is succinct in order to describe, in preparation method
The substrate for completing last action step, rather than bare substrate are referred in introduction with substrate.
Preferred embodiments of the present invention are described in more detail below.Although the following describe the utility model
Preferred embodiment, however, it is to be appreciated that may be realized in various forms the utility model without the implementation that should be illustrated here
Mode is limited.In the examples where no specific technique or condition is specified, described technology or item according to the literature in the art
Part is carried out according to product description.Reagents or instruments used without specified manufacturer, being can be by commercially available acquisition
Conventional products.In the following embodiments, illustrate as being not known, " % " refers both to weight percent.
Test method used below includes:
Reflectance test: 280-780nm reflectivity is tested using spectrophotometer U-3900H.
Corrosion-resistant test: eyeglass is impregnated using the salt water that mass concentration is 4.5%, record lens surface film color starts
There is the time faded.
Anti-oxidant test: QUV tester, UV irradiation: intensity 0.67W/m are used2, temperature 60 C, irradiation 4 hours；Condensation:
Temperature 50 C time 4H.UV irradiation is tested with condensation cycle, and recording sheet color starts the time for occurring fading.
Main agents used below include:
Silicon-aluminum mixture, commercial product, the vacuum coating material L5 provided by Merck Optical Co., Ltd；Selenium, commercial product, by
Changsha Sheng Te new material Co., Ltd provides；Waterproof material, commercial product are mentioned by Kodak Coating Materials Co., Ltd, Danyang City
For.
Embodiment 1
With reference to Fig. 1, a kind of eyeglass of anti-oxidant anti-blue light, including substrate 1 and the film layer for being covered on substrate outer surface, film layer
By stacking gradually the first low refractive index film layer 2, the 4th selenium layer 3, the 5th low refractive index film since the side of connection substrate 1
The 4, the 6th high refractive index film layer 5 of layer, the 7th low refractive index film layer 6, the 8th high refractive index film layer 7 and waterproof layer 8 form.
Wherein, the first low refractive index film layer 2 is used as prime coat, and the 4th selenium layer 3 is anti oxidation layer, the 5th low refractive index film layer 4, the
Six high refractive index film layers 5, the 7th low refractive index film layer 6 form anti-blue light layer, and waterproof layer 8 is used as protective layer.
Specifically, substrate 1 is acrylic substrate, the first low refractive index film layer 2 is L5 in the prime coat, with a thickness of
100 Ethylmercurichlorendimides；The anti oxidation layer 3 is nichrome, with a thickness of 280 Ethylmercurichlorendimides；5th low refractive index film in the anti-blue light layer
Layer 4 is SiO2, with a thickness of 800 Ethylmercurichlorendimides, the 6th high refractive index film layer 5 is ZrO2, with a thickness of 600 Ethylmercurichlorendimides, the 7th low-refraction is thin
Film layer 6 is SiO2, with a thickness of 800 Ethylmercurichlorendimides,；The protective layer 8 with a thickness of 150 Ethylmercurichlorendimides.
Embodiment 2
With reference to Fig. 2, a kind of eyeglass of anti-oxidant anti-blue light, including substrate 1 and the film layer for being covered on 1 outer surface of substrate, film
Layer is low by stacking gradually the first low refractive index film layer 2, the second selenium layer 9, pattern 10, third since the side of connection substrate 1
Index film layer 11, the 4th selenium layer 3, the 5th low refractive index film layer 4, the 6th high refractive index film layer 5, the 7th low-refraction
Film layer 6, the 8th high refractive index film layer 7, the 9th low refractive index film layer 12 and waterproof layer 8 form.Wherein, the first low refraction
Rate film layer 2 and the second selenium layer 9 form prime coat, and pattern 10 is ink print, copper mold plate is bonded pattern or electrostatic paster pastes
Pattern is closed, pattern 10 and third low refractive index film layer 11 are one layer, and the 4th selenium layer 3 is anti oxidation layer, and the 5th low-refraction is thin
Film layer 4, the 6th high refractive index film layer 5, the 7th low refractive index film layer 6, the 8th high refractive index film layer 7 and the 9th low refraction
Rate film layer 12 forms anti-blue light layer, and waterproof layer 8 is used as protective layer.
Specifically, substrate 1 is acrylic substrate, the first low refractive index film layer 2 is L5 in the prime coat, with a thickness of
100 Ethylmercurichlorendimides, the second selenium layer 9 is with a thickness of 100 Ethylmercurichlorendimides；Third low refractive index film layer 11 is SiO in the pattern layer2, with a thickness of
1250 Ethylmercurichlorendimides；The anti oxidation layer 3 is selenium, with a thickness of 275 Ethylmercurichlorendimides；The 5th low refractive index film layer 4 is in the anti-blue light layer
SiO2, with a thickness of 700 Ethylmercurichlorendimides, the 6th high refractive index film layer 5 is ZrO2, with a thickness of 500 Ethylmercurichlorendimides, the 7th low refractive index film layer 6
For SiO2, with a thickness of 700 Ethylmercurichlorendimides, the 8th high refractive index film layer 7 is ZrO2, with a thickness of 500 Ethylmercurichlorendimides, the 9th low refractive index film
Layer 12 is SiO2, with a thickness of 1500 Ethylmercurichlorendimides；The protective layer 8 with a thickness of 150 Ethylmercurichlorendimides.
The reflectance spectrum figure of above-mentioned eyeglass is shown in Fig. 3, from 3 as can be seen that eyeglass is high to the reflectivity of blue light, has preferable
Anti-blue light effect.
Embodiment 3
A kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer for being covered on substrate outer surface, film layer is from linker
Piece is since side by stacking gradually the first low refractive index film layer, the second selenium layer, pattern, third low refractive index film layer,
Four selenium layers, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index
Film layer and waterproof layer composition.Wherein, the first low refractive index film layer, the second selenium layer form prime coat, and pattern is ink printing
Pattern, copper mold plate fitting pattern or electrostatic paster are bonded pattern, and the 4th selenium layer is anti oxidation layer, the 5th low refractive index film layer, the
Six high refractive index film layers, the 7th low refractive index film layer and the 8th high refractive index film layer form anti-blue light layer, and waterproof layer is made
For protective layer.
Specifically, substrate is nylon substrates, the first low refractive index film layer is SiO in the prime coat2, with a thickness of 150
Ethylmercurichlorendimide, the second selenium layer is with a thickness of 150 Ethylmercurichlorendimides；Third low refractive index film layer is SiO in the pattern layer2, with a thickness of 1500 angstroms
Rice；The anti oxidation layer is selenium, with a thickness of 400 Ethylmercurichlorendimides；The 5th low refractive index film layer is SiO in the anti-blue light layer2, thickness
For 800 Ethylmercurichlorendimides, the 6th high refractive index film layer is Ti3O5, with a thickness of 600 Ethylmercurichlorendimides, the 7th low refractive index film layer is SiO2, thick
Degree is 800 Ethylmercurichlorendimides, and the 8th high refractive index film layer is Ti3O5, with a thickness of 600 Ethylmercurichlorendimides；The protective layer with a thickness of 280 Ethylmercurichlorendimides.
Embodiment 4
The present embodiment is substantially the same manner as Example 3, and difference is, the 6th high refractive index film layer and the 5th low-refraction
Sequential thin film layers exchange, the 8th high refractive index film layer and the 7th low refractive index film layer sequence exchange namely anti-blue light layer by
6th high refractive index film layer, the 5th low refractive index film layer, the 8th high refractive index film layer, the 7th low refractive index film layer according to
It is secondary to be laminated, and the 6th high refractive index film layer is connect with the 4th selenium layer.
Embodiment 5
A kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer for being covered on substrate outer surface, film layer is from linker
Piece is since side by stacking gradually the first low refractive index film layer, the second selenium layer, pattern, third low refractive index film layer,
Four selenium layers, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index
Film layer, the 9th low refractive index film layer, the tenth high refractive index layer and waterproof layer composition.Wherein, the first low refractive index film layer
Prime coat is formed with the second selenium layer, pattern is ink print, copper mold plate is bonded pattern or electrostatic paster is bonded pattern, the 4th selenium
Layer is anti oxidation layer, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high
Index film layer, the 9th low refractive index film layer and the tenth high refractive index layer form anti-blue light layer, and waterproof layer is as protective layer.
Specifically, substrate is glass substrate, the first low refractive index film layer is L5 in the prime coat, with a thickness of 50 angstroms
Rice, the second selenium layer is with a thickness of 50 Ethylmercurichlorendimides；Third low refractive index film layer is MgF in the pattern layer2, with a thickness of 1000 Ethylmercurichlorendimides；
The anti oxidation layer is selenium, with a thickness of 150 Ethylmercurichlorendimides；The 5th low refractive index film layer is MgF in the anti-blue light layer2, with a thickness of
600 Ethylmercurichlorendimides, the 6th high refractive index film layer are Ta2O5, with a thickness of 400 Ethylmercurichlorendimides, the 7th low refractive index film layer MgF2, with a thickness of
600 Ethylmercurichlorendimides, the 8th high refractive index film layer are Ta2O5, with a thickness of 400 Ethylmercurichlorendimides, the 9th low refractive index film layer MgF2, with a thickness of
1300 Ethylmercurichlorendimides, the tenth high refractive index layer are Ta2O5, with a thickness of 100 Ethylmercurichlorendimides；The protective layer with a thickness of 190 Ethylmercurichlorendimides.
Embodiment 6
A kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer for being covered on substrate outer surface, film layer is from linker
Piece is since side by stacking gradually the first low refractive index film layer, the second selenium layer, pattern, third low refractive index film layer,
Four selenium layers, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index
Film layer, the 9th low refractive index film layer, the tenth high refractive index layer and waterproof layer composition.Wherein, the first low refractive index film layer
Prime coat is formed with the second selenium layer, pattern is ink print, copper mold plate is bonded pattern or electrostatic paster is bonded pattern, the 4th selenium
Layer is anti oxidation layer, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high
Index film layer, the 9th low refractive index film layer, the tenth high refractive index layer and the 11st low-index layer form anti-blue light layer,
Waterproof layer is as protective layer.
Specifically, substrate is glass substrate, the first low refractive index film layer is L5 in the prime coat, with a thickness of 80 angstroms
Rice, the second selenium layer is with a thickness of 80 Ethylmercurichlorendimides；Third low refractive index film layer is MgF in the pattern layer2, with a thickness of 1400 Ethylmercurichlorendimides；
The anti oxidation layer is selenium, with a thickness of 200 Ethylmercurichlorendimides；The 5th low refractive index film layer is MgF in the anti-blue light layer2, with a thickness of
650 Ethylmercurichlorendimides, the 6th high refractive index film layer are Ta2O5, with a thickness of 550 Ethylmercurichlorendimides, the 7th low refractive index film layer MgF2, with a thickness of
650 Ethylmercurichlorendimides, the 8th high refractive index film layer are Ta2O5, with a thickness of 550 Ethylmercurichlorendimides, the 9th low refractive index film layer MgF2, with a thickness of
650 Ethylmercurichlorendimides, the tenth high refractive index layer are Ta2O5, with a thickness of 550 Ethylmercurichlorendimides, the 11st low-index layer is MgF2, with a thickness of 1300
Ethylmercurichlorendimide；The protective layer with a thickness of 250 Ethylmercurichlorendimides.
Embodiment 7
A kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer for being covered on substrate outer surface, film layer is from linker
Piece is since side by stacking gradually the first low refractive index film layer, the second selenium layer, pattern, third low refractive index film layer,
Four selenium layers, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index
Film layer, the 9th low refractive index film layer, the tenth high refractive index layer and waterproof layer composition.Wherein, the first low refractive index film layer
Prime coat is formed with the second selenium layer, pattern is ink print, copper mold plate is bonded pattern or electrostatic paster is bonded pattern, the 4th selenium
Layer is anti oxidation layer, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high
Index film layer, the 9th low refractive index film layer, the tenth high refractive index layer and the 11st low-index layer form anti-blue light layer,
Waterproof layer is as protective layer.
Specifically, substrate is glass substrate, the first low refractive index film layer is L5 in the prime coat, with a thickness of 130 angstroms
Rice, the second selenium layer is with a thickness of 130 Ethylmercurichlorendimides；Third low refractive index film layer is MgF in the pattern layer2, with a thickness of 1200 Ethylmercurichlorendimides；
The anti oxidation layer is selenium, with a thickness of 380 Ethylmercurichlorendimides；The 5th low refractive index film layer is MgF in the anti-blue light layer2, with a thickness of
750 Ethylmercurichlorendimides, the 6th high refractive index film layer are Ta2O5, with a thickness of 450 Ethylmercurichlorendimides, the 7th low refractive index film layer MgF2, with a thickness of
750 Ethylmercurichlorendimides, the 8th high refractive index film layer are Ta2O5, with a thickness of 450 Ethylmercurichlorendimides, the 9th low refractive index film layer MgF2, with a thickness of
750 Ethylmercurichlorendimides, the tenth high refractive index layer are Ta2O5, with a thickness of 450 Ethylmercurichlorendimides, the 11st low-index layer is MgF2, with a thickness of 1600
Ethylmercurichlorendimide；The protective layer with a thickness of 50 Ethylmercurichlorendimides.
Embodiment 8
The eyeglass of the anti-oxidant anti-blue light in embodiment 2 is prepared, steps are as follows:
(1) substrate cleaned, dried, 50 DEG C of baking temperature, time 1-2 hour；
(2) prime coat vacuum coating successively is carried out to the outer surface of substrate；
A, the substrate of drying is placed on jig, is sent into vacuum chamber and vacuumizes；
B, when vacuum chamber vacuum degree is less than or is equal to 5*10-5When Torr, ion source is opened, gas is argon gas, function
Rate is voltage 150V electric current 8A, carries out surface to substrate and cleans for 2 minutes；
C, prime coat is plated to substrate outer surface
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled 50
DEG C, the first low refractive index film layer material is bombarded using electron gun, is deposited on substrate in the form of angstrom nanoscale molecule after material evaporation
Outer surface, while control the first low refractive index film layer evaporation rate beFirst low refractive index film layer most end form
After with a thickness of 100 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, the membrane material selenium of the second film layer is bombarded using electron gun, is deposited on substrate in the form of angstrom nanoscale molecule after selenium evaporation
Outer surface, while controlling the second selenium layer evaporation rate and beingSecond selenium layer ultimately form after with a thickness of 100 Ethylmercurichlorendimides；
(3) after the completion of prime coat plated film, atmosphere is poured to vacuum chamber, then takes out substrate, then in substrate prime coat
Upper printing or fitting plating film figure；
(4) substrate is emitted on jig, is put into vacuum chamber and vacuumizes, and carry out the plating of third low refractive index film layer
Film；
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled 50
DEG C, third low refractive index film layer material is bombarded using electron gun, is deposited on substrate in the form of angstrom nanoscale molecule after material evaporation
Outer surface, while controlling third low refractive index film layer evaporation rate and beingThird low refractive index film layer most end form
After with a thickness of 1250 Ethylmercurichlorendimides；
(5) after the completion of plated film, atmosphere is poured to vacuum chamber, substrate is then taken out, ink then is removed to substrate
Either remove copper mold plate or removal electrostatic paster；
(6) substrate cleaned, dried, 50 DEG C of baking temperature, the time 30 minutes；
(7) anti oxidation layer plated film is carried out to the outer surface of substrate；
A, the substrate of drying is placed on jig, is sent into vacuum chamber and vacuumizes；
B, when vacuum chamber vacuum degree is less than or is equal to 5*10-5When Torr, ion source is opened, gas is argon gas, function
Rate is voltage 150V electric current 8A, carries out surface to substrate and cleans for 2 minutes；
C, anti oxidation layer plated film is carried out to substrate outer surface
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled 50
DEG C, the membrane material selenium of the 4th film layer is bombarded using electron gun, is deposited in the form of angstrom nanoscale molecule after the evaporation of the 4th film layer selenium
The outer surface of substrate, while controlling the 4th film layer evaporation rate and being4th film layer ultimately form after with a thickness of
275 Ethylmercurichlorendimides；
(8) anti-blue light layer plated film is carried out to substrate outer surface
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, the 5th low refractive index film layer material is bombarded using electron gun, is deposited in the form of angstrom nanoscale molecule after material evaporation
The outer surface of substrate, while controlling the 5th low refractive index film layer evaporation rate and being5th low refractive index film layer is most
End form after with a thickness of 700 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, the 6th high refractive index film layer material is bombarded using electron gun, with Ethylmercurichlorendimide grade after the evaporation of the 6th high refractive index film layer
Molecular forms are deposited on the outer surface of substrate, while controlling the 6th high refractive index film layer evaporation rate and being6th high folding
The rate film layer of penetrating ultimately form after with a thickness of 500 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, using electron gun bombard the 7th low refractive index film layer material, the 7th low refractive index film layer material evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling the 7th low refractive index film layer evaporation rate and beingThe
Seven low refractive index film layers ultimately form after with a thickness of 700 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, the 8th high refractive index film layer material is bombarded using electron gun, with Ethylmercurichlorendimide grade after the evaporation of the 8th high refractive index film layer
Molecular forms are deposited on the outer surface of substrate, while controlling the 8th high refractive index film layer evaporation rate and being8th high folding
The rate film layer of penetrating ultimately form after with a thickness of 500 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, using electron gun bombard the 9th low refractive index film layer material, the 9th low refractive index film layer material evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling the 9th low refractive index film layer material evaporation rate and being9th low refractive index film layer material ultimately form after with a thickness of 1500 Ethylmercurichlorendimides, then form anti-blue light layer；
(9) plating plated film is carried out to substrate outer surface
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 50 DEG C, the membrane material waterproof material of the tenth film layer is heated using tungsten boat, after the evaporation of the tenth film layer in the form of angstrom nanoscale molecule
It is deposited on the outer surface of substrate, while controlling the tenth film layer evaporation rate and beingAfter tenth film layer ultimately forms
With a thickness of 150 Ethylmercurichlorendimides, protective layer is formed.
The present embodiment is merely illustrative, and as known to those skilled in the art, the temperature of substrate baking is at 40-65 DEG C, and the time, 1-2 was small
When can realize the utility model, evaporation rate when plated film can carry out ± 20% variation on the basis of the above；According to
The variation of lens structure, plating run is adjustable in corresponding preparation step, for example, one layer of low refractive index film layer of more platings or
Person changes membrane material etc..
Performance detection
The eyeglass of embodiment is tested, to wavelength in the average reflectance of 400-500nm, corrosion resistance and antioxygen
Change performance and be shown in Table 1:
1 performance test table of table
Preferred embodiments of the present invention are described in detail above, still, the utility model is not limited to above-mentioned reality
Apply the detail in mode, in the range of the technology design of the utility model, can to the technical solution of the utility model into
The a variety of simple variants of row, these simple variants belong to the protection scope of the utility model.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, it can be combined in any appropriate way.In order to avoid unnecessary repetition, the utility model is to each
No further explanation will be given for the possible combination of kind.
In addition, any combination can also be carried out between a variety of different embodiments of the utility model, as long as it is not disobeyed
The thought for carrying on the back the utility model, equally should be considered as content disclosed in the utility model.
Claims (10)
1. a kind of eyeglass of anti-oxidant anti-blue light, including substrate and the film layer that the substrate outer surface is arranged in, it is characterised in that:
The film layer includes the prime coat stacked gradually from inside to outside, anti oxidation layer, anti-blue light layer and protective layer, and the prime coat includes
First low refractive index film layer；The anti oxidation layer is the 4th selenium layer, and the anti-blue light layer is thin by total 3-7 layers of high refractive index
Film layer and low refractive index film layer alternately form；
Wherein, the low refractive index film layer in the first low refractive index film layer or the anti-blue light layer is SiO2, sial it is mixed
Close object or MgF2In any one formed film layer；And the high refractive index film layer in the anti-blue light layer is ZrO2、Ti3O5
Or Ta2O5In any one formed film layer.
2. the eyeglass of anti-oxidant anti-blue light according to claim 1, it is characterised in that: the substrate be acrylic substrate,
Any one of polycarbonate substrate, nylon substrates, CR-39 substrate or glass substrate.
3. the eyeglass of anti-oxidant anti-blue light according to claim 1, it is characterised in that: the protective layer is waterproof material shape
At film layer.
4. the eyeglass of anti-oxidant anti-blue light according to claim 1, it is characterised in that: the prime coat with a thickness of 50-
300 Ethylmercurichlorendimides；The anti oxidation layer with a thickness of 150-400 Ethylmercurichlorendimide；The anti-blue light layer with a thickness of 2000-5000 Ethylmercurichlorendimide；Institute
State protective layer with a thickness of 10-280 Ethylmercurichlorendimide.
5. the eyeglass of anti-oxidant anti-blue light described in any one of -4 according to claim 1, it is characterised in that: in the prime coat
Pattern layer is additionally provided between the anti oxidation layer, the pattern layer is made of pattern and third low refractive index film layer, described
Prime coat is made of the first low refractive index film layer and the second selenium layer, wherein second selenium layer and the pattern layer are close to institute
Stating third low refractive index film layer is SiO2, silicon-aluminum mixture or MgF2In any one formed film layer.
6. the eyeglass of anti-oxidant anti-blue light according to claim 5, it is characterised in that: the mirror of the anti-oxidant anti-blue light
Piece is by the substrate, the first low refractive index film layer, the second selenium layer, pattern, the third low refractive index film layer, the 4th selenium that stack gradually
Layer, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index film
Layer, the 9th low-index layer and waterproof layer composition.
7. the eyeglass of anti-oxidant anti-blue light according to claim 5, it is characterised in that: the mirror of the anti-oxidant anti-blue light
Piece is by the substrate, the first low refractive index film layer, the second selenium layer, pattern, the third low refractive index film layer, the 4th selenium that stack gradually
Layer, the 6th high refractive index film layer, the 5th low refractive index film layer, the 8th high refractive index film layer, the 7th low refractive index film
Layer and waterproof layer composition.
8. the eyeglass of anti-oxidant anti-blue light according to claim 6 or 7, it is characterised in that: first is low in the prime coat
Index film layer with a thickness of 50-150 Ethylmercurichlorendimide, the second selenium layer with a thickness of 50-150 Ethylmercurichlorendimide；Third is low in the pattern layer
Index film layer with a thickness of 1000-1500 Ethylmercurichlorendimide；The anti oxidation layer with a thickness of 150-400 Ethylmercurichlorendimide；The anti-blue light
5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index film in layer
Layer, the 9th low-index film thickness be followed successively by 600-800 Ethylmercurichlorendimide, 400-600 Ethylmercurichlorendimide, 600-800 Ethylmercurichlorendimide, 400-600 angstroms
Rice；1000-2000 Ethylmercurichlorendimide；The protective layer with a thickness of 10-280 Ethylmercurichlorendimide.
9. the eyeglass of anti-oxidant anti-blue light according to claim 5, it is characterised in that: the mirror of the anti-oxidant anti-blue light
Piece is by the substrate, the first low refractive index film layer, the second selenium layer, pattern, the third low refractive index film layer, the 4th selenium that stack gradually
Layer, the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index film
Layer, the 9th low refractive index film layer, the tenth high refractive index layer, the 11st low refractive index film layer and waterproof layer composition.
10. the eyeglass of anti-oxidant anti-blue light according to claim 9, it is characterised in that: the first low folding in the prime coat
Penetrate rate film layer with a thickness of 80-130 Ethylmercurichlorendimide, the second selenium layer with a thickness of 80-130 Ethylmercurichlorendimide；The low folding of third in the pattern layer
Penetrate rate film layer with a thickness of 1200-1400 Ethylmercurichlorendimide；The anti oxidation layer with a thickness of 200-380 Ethylmercurichlorendimide；The anti-blue light layer
In the 5th low refractive index film layer, the 6th high refractive index film layer, the 7th low refractive index film layer, the 8th high refractive index film
Layer, the 9th low refractive index film layer, the tenth high refractive index layer, the 11st low refractive index film layer thickness be followed successively by 650-750
Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide, 650-750 Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide, 650-750 Ethylmercurichlorendimide, 450-550 Ethylmercurichlorendimide, 1300-1600 angstroms
Rice；The protective layer with a thickness of 50-250 Ethylmercurichlorendimide.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201822229904.8U CN209182599U (en) | 2018-12-28 | 2018-12-28 | A kind of eyeglass of anti-oxidant anti-blue light |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201822229904.8U CN209182599U (en) | 2018-12-28 | 2018-12-28 | A kind of eyeglass of anti-oxidant anti-blue light |
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| CN209182599U true CN209182599U (en) | 2019-07-30 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109613716A (en) * | 2018-12-28 | 2019-04-12 | 厦门美澜光电科技有限公司 | A kind of anti-oxidant anti-blue light band pattern eyeglass and preparation method thereof |
| CN110908019A (en) * | 2019-12-03 | 2020-03-24 | 厦门朵彩光学科技有限公司 | Anti-aging TAC (TAC) coated lens and preparation method thereof |
| CN110927989A (en) * | 2019-12-18 | 2020-03-27 | 厦门美澜光电科技有限公司 | Eimei antioxidant anti-infrared band pattern lens and preparation method thereof |
| CN112034538A (en) * | 2020-04-21 | 2020-12-04 | 江苏新唯尊光学眼镜有限公司 | Blue-light-proof anti-ultraviolet lens and production process thereof |
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2018
- 2018-12-28 CN CN201822229904.8U patent/CN209182599U/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109613716A (en) * | 2018-12-28 | 2019-04-12 | 厦门美澜光电科技有限公司 | A kind of anti-oxidant anti-blue light band pattern eyeglass and preparation method thereof |
| CN109613716B (en) * | 2018-12-28 | 2022-03-18 | 厦门美澜光电科技有限公司 | Anti-oxidation blue-light-proof patterned lens and preparation method thereof |
| CN110908019A (en) * | 2019-12-03 | 2020-03-24 | 厦门朵彩光学科技有限公司 | Anti-aging TAC (TAC) coated lens and preparation method thereof |
| CN110908019B (en) * | 2019-12-03 | 2021-10-22 | 厦门朵彩光学科技有限公司 | Anti-aging TAC (TAC) coated lens and preparation method thereof |
| CN110927989A (en) * | 2019-12-18 | 2020-03-27 | 厦门美澜光电科技有限公司 | Eimei antioxidant anti-infrared band pattern lens and preparation method thereof |
| CN112034538A (en) * | 2020-04-21 | 2020-12-04 | 江苏新唯尊光学眼镜有限公司 | Blue-light-proof anti-ultraviolet lens and production process thereof |
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