CN209182540U - A kind of anti-oxidant erosion-resisting eyeglass - Google Patents
A kind of anti-oxidant erosion-resisting eyeglass Download PDFInfo
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- CN209182540U CN209182540U CN201822229905.2U CN201822229905U CN209182540U CN 209182540 U CN209182540 U CN 209182540U CN 201822229905 U CN201822229905 U CN 201822229905U CN 209182540 U CN209182540 U CN 209182540U
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Abstract
The utility model relates to a kind of anti-oxidant erosion-resisting eyeglasses; the anti-oxidant erosion-resisting eyeglass includes substrate and the film layer that the substrate outer surface is arranged in; the film layer includes the prime coat stacked gradually from inside to outside, anti-oxidant etch resistant layer, photochromic layer and protective layer, and the prime coat is made of the first silicon-aluminum mixture layer and the second metal oxide layer；The anti-oxidant etch resistant layer is made of the 4th selenium layer and fifth metal oxide skin(coating), and the photochromic layer is alternately made of the metal oxide layer and low refractive index film layer of layer 1-7.Anti-oxidant erosion-resisting eyeglass described in the utility model has preferable anti-oxidant, anti-corrosion effects, and when having pattern, and pattern and eyeglass are presented colourful different colours, colour-fast, do not influence wearer's sight, has preferable market prospects.
Description
Technical field
The utility model relates to color-changing lens technology of preparing, especially a kind of anti-oxidant erosion-resisting eyeglass.
Background technique
Sunglasses uses extensively, wherein colored sunglasses uses special chemical substance, so that eyeglass has specific face
Color.In order to develop diversified eyeglass, loading pattern on colour lens becomes a kind of faddish trend.In general, sunglasses is whole
Embody a kind of color, pattern also with the solid colour of Integrated lens, it is difficult to realize the diversification of pattern color.And pattern loads
Afterwards, it is easy to leave the decomposition line of generation Chong Die with upper and lower layer in pattern edge, influences visual effect.Whether pattern is stabilized,
It is not susceptible to oxidation stain, it is important that and.Patterned sunglasses color is single in the prior art, pattern and eyeglass
Binding force it is poor, easy oxidation discoloration, exist simultaneously to a certain degree influence wearer's sight the problem of.
Utility model content
The purpose of this utility model is to overcome the problems of the difference of binding force present in existing sunglasses, provide one kind
Anti-oxidant erosion-resisting eyeglass can be without pattern on the basis of the lens structure, can also be with layout, when with figure
When case, cooperated by photochromic layer and pattern layer, realize an eyeglass, two kinds of colors: pattern is in a kind of color, and eyeglass is integrally in another
A kind of color, and pattern does not influence the sight of wearer.
Concrete scheme is as follows:
A kind of anti-oxidant erosion-resisting eyeglass, including substrate and the film layer that the substrate outer surface is arranged in, the film layer
Including prime coat, anti-oxidant etch resistant layer, photochromic layer and the protective layer stacked gradually from inside to outside, the prime coat is by the first silicon
Aluminium mixture layer and the second metal oxide layer composition；The anti-oxidant etch resistant layer is by the 4th selenium layer and fifth metal oxide
Layer composition, the photochromic layer are alternately made of the metal oxide layer and low refractive index film layer of layer 1-7；
Wherein, second metal oxide layer, fifth metal oxide skin(coating) are ZrO2、Ti3O5Or Ta2O5In it is any one
The coating that kind is formed；And the metal oxide layer is ZrO2、Ti3O5Or Ta2O5In any one formed coating, it is described low
Index film layer is SiO2, vacuum coating material L5 or MgF2In any one formed coating.
Further, the substrate is acrylic substrate, polycarbonate substrate, nylon substrates, CR-39 substrate or glass base
Any one of piece；The first silicon-aluminum mixture layer is the coating that vacuum coating material L5 is formed, and the protective layer is waterproof
The coating that material is formed.
Further, the first silicon-aluminum mixture layer described in the prime coat with a thickness of 50-150 Ethylmercurichlorendimide；Described second
Metal oxide layer with a thickness of 100-200 Ethylmercurichlorendimide；The 4th selenium layer in the anti-oxidant etch resistant layer is with a thickness of 200-400 angstroms
Rice, fifth metal oxide layer thicknesses are 100-1900 Ethylmercurichlorendimide；The photochromic layer with a thickness of 1000-4000 Ethylmercurichlorendimide；The guarantor
Sheath with a thickness of 10-280 Ethylmercurichlorendimide.
Further, be additionally provided with pattern layer between the prime coat and the anti-oxidant etch resistant layer, the pattern layer by
Pattern and third silicon-aluminum mixture layer composition, wherein the pattern in the pattern layer is ink print, copper mold plate fitting figure
Case or electrostatic paster are bonded any one in pattern；The third silicon-aluminum mixture layer is the plating that vacuum coating material L5 is formed
Layer.
Further, the anti-oxidant erosion-resisting eyeglass include the substrate stacked gradually, the first silicon-aluminum mixture layer,
Second metal oxide layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low-refraction
Film layer and waterproof layer, wherein the 6th low refractive index film layer is SiO2, vacuum coating material L5 or MgF2In any one shape
At coating.
Further, in the prime coat the first silicon-aluminum mixture layer with a thickness of 80 Ethylmercurichlorendimides, the second metal oxide thickness
Degree is 120 Ethylmercurichlorendimides, third silicon-aluminum mixture layer with a thickness of 100 Ethylmercurichlorendimides, the 4th selenium layer with a thickness of 200 Ethylmercurichlorendimides, fifth metal oxygen
Compound layer is with a thickness of 950 Ethylmercurichlorendimides, and for the 6th low refractive index film layer with a thickness of 1000 Ethylmercurichlorendimides, waterproofing layer thickness is 150 Ethylmercurichlorendimides.
Further, the anti-oxidant erosion-resisting eyeglass include the substrate stacked gradually, the first silicon-aluminum mixture layer,
Second metal oxide layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low-refraction
Film layer, the 7th metal oxide layer, the 8th low-index layer and waterproof layer, wherein the 7th metal oxide layer is ZrO2、
Ti3O5Or Ta2O5In any one formed coating.
Further, in the prime coat the first silicon-aluminum mixture layer with a thickness of 100 Ethylmercurichlorendimides, the second metal oxide layer
With a thickness of 150 Ethylmercurichlorendimides；Third silicon-aluminum mixture layer with a thickness of 150 Ethylmercurichlorendimides in the pattern layer；It is described anti-oxidant anticorrosive
For the 4th selenium layer in layer with a thickness of 300 Ethylmercurichlorendimides, fifth metal oxide layer thicknesses are 300 Ethylmercurichlorendimides；The 6th is low in the photochromic layer
Index film layer with a thickness of 1500 Ethylmercurichlorendimides, the 7th metal oxide layer with a thickness of 200 Ethylmercurichlorendimides, the 8th low-index layer with a thickness of
900 Ethylmercurichlorendimides；The protective layer with a thickness of 200 Ethylmercurichlorendimides.
Further, the anti-oxidant erosion-resisting eyeglass include the substrate stacked gradually, the first silicon-aluminum mixture layer,
Second metal oxide layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low-refraction
Film layer, the 7th metal oxide layer, the 8th low refractive index film layer, the 9th metal oxide layer, the tenth low refractive index film
Layer and waterproof layer.
Further, the first silicon-aluminum mixture layer is L5, and with a thickness of 130 Ethylmercurichlorendimides, the second metal oxide layer is Ti3O5, thick
Degree is 180 Ethylmercurichlorendimides, and third silicon-aluminum mixture layer is L5, with a thickness of 1100 Ethylmercurichlorendimides, the 4th selenium layer with a thickness of 350 Ethylmercurichlorendimides, the 5th
Metal oxide layer is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the 6th low refractive index film layer is L5, with a thickness of 1400 Ethylmercurichlorendimides, the 7th
Metal oxide layer is Ti3O5, with a thickness of 150 Ethylmercurichlorendimides, the 8th low refractive index film layer is L5, with a thickness of 140 Ethylmercurichlorendimides, the 9th gold medal
Category oxide skin(coating) is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the tenth low refractive index film layer is L5, with a thickness of 600 Ethylmercurichlorendimides, waterproof thickness
Degree is 260 Ethylmercurichlorendimides.
The utility model has the advantages that anti-oxidant erosion-resisting eyeglass described in the utility model is deposited on substrate table using selenium under a high vacuum
Face has preferable anti-oxidant, anti-corrosion effects so that being formed has higher and stable resistivity.
Moreover matched in the utility model using photochromic layer and pattern layer, so that pattern and eyeglass presentation are rich and varied
Different colours, meet different guest's demands, and clear patterns are true to nature, it is colour-fast, do not influence wearer's sight, have preferable
Market prospects.
Further, prime coat uses the first silicon-aluminum mixture layer and the second metal oxide layer group in the utility model
At film layer adhesion strength is high, and enriches the color of eyeglass and pattern, improves the quality of eyeglass.
Detailed description of the invention
In order to illustrate more clearly of the technical solution of the utility model, attached drawing will be briefly described below, it is aobvious and easy
Insight, the accompanying drawings in the following description merely relate to some embodiments of the utility model, rather than limitations of the present invention.
Fig. 1 is the lens structure schematic diagram that the utility model one embodiment 1 provides；
Fig. 2 is the lens structure schematic diagram that the utility model one embodiment 2 provides.
Specific embodiment
The definition of part term used in the utility model is given below, other terms that do not address have this field institute
Well known definition and meaning:
Substrate: substrate can be planar optics, be also possible to the eyeglass with certain radian.
Outer surface: outer surface refers to eyeglass in a state of use in the utility model, for wearer, is located at outer
The one side of side.
Angstrom meter per second forms the speed of film growth for characterizing particle deposition.
In the utility model, prime coat is combined using the first silicon-aluminum mixture layer and the second metal oxide layer, is compared
Individual silicon-aluminum mixture bottoming, can be enhanced the adhesive force of film layer, and the second metal oxide layer and the first silicon-aluminum mixture
Layer constitutes " high-low " refractive index and interlocks, so that the color variation range of eyeglass is more abundant and easy to accomplish.
In the utility model, when eyeglass has pattern, the pattern in pattern layer is ink print, copper mold plate fitting figure
Case or electrostatic paster are bonded any one in pattern.When production, pattern is printed or is fitted on prime coat, is increased using prime coat
The binding force of strong pattern and film layer, prime coat are made of the first silicon-aluminum mixture layer and the second metal oxide layer, and preferably second
Metal oxide layer and pattern layer close to.After mimeograph or fitting pattern, third low refractive index film layer plated film is carried out, is utilized
Contrast effect between white space and coating film area forms pattern form；At the same time, pattern is located at the second metal oxide
Between layer (high refractive index layer) and third low refractive index film layer, the intensity of light can be effectively reduced, weaken pattern intensity, reach
Special visual effect, it may be assumed that wearer itself is almost not felt by the presence of pattern when observing, ensure that the sight of eyeglass is complete
It is whole, and onlooker can see that clearly pattern, promote the aesthetic feeling and fashion statement of eyeglass.
Photochromic layer is the key that colour of lens design in the utility model, different photochromic layer designs, the whole face of eyeglass
The color of color and pattern is different.The photochromic layer is formed by low refractive index film layer and metal oxide layer are alternately laminated, is amounted to
Layer 1-7, preferably layer 2-4.Such as: photochromic layer is the 6th low refractive index film layer.Or preferably 3 layers, i.e., by the 6th low folding
Penetrate rate film layer, the 7th metal oxide layer and the 8th low refractive index film layer composition, such as: thickness be respectively 1500 Ethylmercurichlorendimides,
800 Ethylmercurichlorendimides, 800 Ethylmercurichlorendimides, so that eyeglass is red, pattern is hyacinthine.The thickness of film layer is combined with material, may be implemented most
Good color coordination effect.
In the utility model, the second metal oxide layer, fifth metal oxide skin(coating), the 7th metal oxide layer or the 9th
Metal oxide layer, membrane material ZrO2、Ti3O5Or Ta2O5In any one.
In the utility model, the 6th low refractive index film layer or the 8th low refractive index film layer or the tenth low refractive index film
Layer, membrane material SiO2, vacuum coating material L5 or MgF2In any one, preferably vacuum coating material L5.First sial is mixed
The membrane material silicon-aluminum mixture of nitride layer or third silicon-aluminum mixture layer is closed, silicon-aluminum mixture can be SiO2With Al2O3Mixture,
Such as Al2O3Account for the 2-6% of silicon-aluminum mixture gross weight, more preferably Al2O3Account for the 3-3.5% of silicon-aluminum mixture gross weight.The material
It can make by oneself, commercial product, preferably vacuum coating material L5 can also be used.Wherein vacuum coating material L5, China are general
Title " silicon-aluminum mixture ", " L5 " are its German adopted names, which can be new by Merck Optical Co., Ltd, Nanyang happy Rett optics
Materials Co., Ltd or Suzhou Putin's vacuum technique Co., Ltd provide, and regular size is 1-3mm shot, white.
In the preparation method of anti-oxidant erosion-resisting eyeglass described in the utility model, it is normal that plated film, which uses vacuum coating equipment,
Advise equipment, such as the true coating machine that Long Pian vacuum technology limited liability company provides, the KRI that cooperation U.S.'s koff Mann provides
Ion source apparatus.The key of plated film is the temperature of vacuum chamber and the speed of particle deposition.It is to be promoted using 40-60 DEG C of advantage
The attachment degree of film, it should be noted that it is succinct in order to describe, it is referred in the introduction of preparation method with substrate and completes upper one
The substrate of operating procedure, rather than bare substrate.
Preferred embodiments of the present invention are described in more detail below.Although the following describe the utility model
Preferred embodiment, however, it is to be appreciated that may be realized in various forms the utility model without the implementation that should be illustrated here
Mode is limited.In the examples where no specific technique or condition is specified, described technology or item according to the literature in the art
Part is carried out according to product description.Reagents or instruments used without specified manufacturer, being can be by commercially available acquisition
Conventional products.In the following embodiments, illustrate as being not known, " % " refers both to weight percent.
Test method used below includes:
Corrosion-resistant test: eyeglass is impregnated using the salt water that mass concentration is 4.5%, record lens surface film color starts
There is the time faded.
Anti-oxidant test: QUV tester, UV irradiation: intensity 0.67W/m are used2, temperature 60 C, irradiation 4 hours；Condensation:
Temperature 50 C time 4H.UV irradiation is tested with condensation cycle, and recording sheet color starts the time for occurring fading.
Main agents used below include:
Vacuum coating material L5, commercial product, by Merck, Optical Co., Ltd is provided；Vacuum coating material selenium, commercial product, by
Changsha Sheng Te new material Co., Ltd provides；Waterproof material, commercial product are mentioned by Kodak Coating Materials Co., Ltd, Danyang City
For.
Embodiment 1
With reference to Fig. 1, a kind of anti-oxidant erosion-resisting eyeglass, including stack gradually substrate 1, the first silicon-aluminum mixture layer 2,
Second metal oxide layer 3, the 4th selenium layer 4, fifth metal oxide skin(coating) 5, the 6th low refractive index film layer 6 and waterproof layer 7.Its
In, the first silicon-aluminum mixture layer 2 and the second metal oxide layer 3 form prime coat, the 4th selenium layer 4 and fifth metal oxide skin(coating)
5 groups become anti-oxidant etch resistant layer, and the 6th low refractive index film layer 6 is photochromic layer, and waterproof layer 7 is used as protective layer.
Specifically, eyeglass substrate 1 is acrylic substrate, the first silicon-aluminum mixture layer 2 is L5, with a thickness of 80 Ethylmercurichlorendimides, second
Metal oxide layer 3 is Ti3O5, with a thickness of 120 Ethylmercurichlorendimides, the 4th selenium layer 4 with a thickness of 200 Ethylmercurichlorendimides, fifth metal oxide skin(coating) 5
For Ti3O5, with a thickness of 950 Ethylmercurichlorendimides, the 6th low refractive index film layer 6 is L5, and with a thickness of 1000 Ethylmercurichlorendimides, waterproof layer 7 is with a thickness of 150
Ethylmercurichlorendimide.
Prepared eyeglass is brilliant white eyeglass, has anti-oxidation, anticorrosion ability, and film adhesion is high.
Embodiment 2
With reference to Fig. 2, a kind of anti-oxidant erosion-resisting eyeglass, including stack gradually substrate 1, the first silicon-aluminum mixture layer 2,
Second metal oxide layer 3, pattern 80, third silicon-aluminum mixture layer 81, the 4th selenium layer 4, fifth metal oxide skin(coating) the 5, the 6th
Low refractive index film layer 6 and waterproof layer 7.Wherein, the first silicon-aluminum mixture layer 2 and the second metal oxide layer 3 form prime coat,
Pattern 80 and third silicon-aluminum mixture layer 81 are one layer, and pattern is ink print, copper mold plate is bonded pattern or electrostatic paster pastes
Any one in pattern is closed, the 4th selenium layer 4 and 5 groups of fifth metal oxide skin(coating) become anti-oxidant etch resistant layer, the 6th low folding
Penetrating rate film layer 6 is photochromic layer, and waterproof layer 7 is used as protective layer.
Specifically, eyeglass substrate 1 is acrylic substrate, the first silicon-aluminum mixture layer 2 is L5, with a thickness of 80 Ethylmercurichlorendimides, second
Metal oxide layer 3 is Ti3O5, with a thickness of 120 Ethylmercurichlorendimides, third silicon-aluminum mixture layer 81 is L5, with a thickness of 100 Ethylmercurichlorendimides, the 4th selenium
Layer 4 with a thickness of 200 Ethylmercurichlorendimides, fifth metal oxide skin(coating) 5 is Ti3O5, with a thickness of 950 Ethylmercurichlorendimides, the 6th low refractive index film layer 6
For L5, with a thickness of 1000 Ethylmercurichlorendimides, waterproof layer 7 is with a thickness of 150 Ethylmercurichlorendimides.
Prepared eyeglass is brilliant white eyeglass, and blue is presented in the pattern in eyeglass.There is eyeglass anti-oxidation, anticorrosion to imitate
Fruit, and film adhesion is high.
Embodiment 3
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer,
Seven metal oxide layers, the 8th low refractive index film layer and waterproof layer.Wherein, the first silicon-aluminum mixture layer and the oxidation of the second metal
Nitride layer forms prime coat, and pattern and third silicon-aluminum mixture layer are one layer, and pattern is ink print, copper mold plate fitting pattern
Or any one in electrostatic paster fitting pattern, the 4th selenium layer and fifth metal oxide skin(coating) group become anti-oxidant etch resistant layer,
6th low refractive index film layer, the 7th metal oxide layer and the 8th low refractive index film layer are photochromic layer, and waterproof layer is as guarantor
Sheath.
Specifically, eyeglass substrate is nylon substrates, the first silicon-aluminum mixture layer is L5, with a thickness of 100 Ethylmercurichlorendimides, the second metal
Oxide skin(coating) is ZrO2, with a thickness of 150 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is L5, with a thickness of 150 Ethylmercurichlorendimides, the thickness of the 4th selenium layer
Degree is 300 Ethylmercurichlorendimides, and fifth metal oxide skin(coating) is ZrO2, with a thickness of 300 Ethylmercurichlorendimides, the 6th low refractive index film layer is L5, thickness
For 1500 Ethylmercurichlorendimides, the 7th metal oxide layer is ZrO2, with a thickness of 200 Ethylmercurichlorendimides, the 8th low refractive index film layer is L5, with a thickness of
900 Ethylmercurichlorendimides, the 9th film layer with a thickness of 200 Ethylmercurichlorendimides.Prepared eyeglass is golden yellow eyeglass, and the pattern in eyeglass presents purple
It is red.
The step of preparing above-mentioned eyeglass is as follows:
(1) substrate cleaned, dried, 40-65 DEG C of baking temperature, time 1-2 hour；
(2) prime coat vacuum coating successively is carried out to the outer surface of substrate；
A, the substrate of drying is placed on jig, is sent into vacuum chamber and vacuumizes；
B, when vacuum chamber vacuum degree is less than or is equal to 5*10-5When Torr, ion source is opened, gas is argon gas, function
Rate is voltage 150V electric current 8A, carries out surface to substrate and cleans for 2 minutes；
C, prime coat is plated to substrate outer surface
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled in 40-
60 DEG C, base is deposited in the form of angstrom nanoscale molecule after membrane material L5, the L5 evaporation of the first silicon-aluminum mixture layer is bombarded using electron gun
The outer surface of piece, while controlling the first silicon-aluminum mixture layer evaporation rate and beingFirst silicon-aluminum mixture layer ultimately forms
Afterwards with a thickness of 100 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, using electron gun bombard the second metal oxide layer membrane material metal oxide, metal oxide evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling the second metal oxide layer evaporation rate and beingSecond gold medal
Belong to after oxide skin(coating) ultimately forms with a thickness of 150 Ethylmercurichlorendimides, form prime coat；
(3) after the completion of prime coat plated film, atmosphere is poured to vacuum chamber, then takes out substrate, then in substrate prime coat
Upper printing or fitting plating film figure；
(4) substrate is emitted on jig, is put into vacuum chamber and vacuumizes, and carry out pattern layer plated film；
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled in 40-
60 DEG C, base is deposited in the form of angstrom nanoscale molecule after evaporating using the membrane material L5, L5 of electron gun bombardment third silicon-aluminum mixture layer
The outer surface of piece, while controlling third silicon-aluminum mixture layer evaporation rate and beingThird silicon-aluminum mixture layer ultimately forms
Afterwards with a thickness of 150 Ethylmercurichlorendimides；
(5) after the completion of pattern layer plated film, atmosphere is poured to vacuum chamber, substrate is then taken out, then substrate is gone
Except ink or removal copper mold plate or removal electrostatic paster；
(6) substrate cleaned, dried, 40-60 DEG C of baking temperature, time 20-40 minute；
(7) anti-oxidant etch resistant layer, photochromic layer and protective layer vacuum coating successively are carried out to the outer surface of substrate；
A, the substrate of drying is placed on jig, is sent into vacuum chamber and vacuumizes；
B, when vacuum chamber vacuum degree is less than or is equal to 5*10-5When Torr, ion source is opened, surface is carried out to substrate
Cleaning
C, anti-oxidant etch resistant layer plated film is carried out to substrate outer surface
When vacuum chamber vacuum degree is less than or is equal to 2.0*10-5When Torr, and the temperature of vacuum chamber is controlled in 40-
60 DEG C, the 4th layer of membrane material selenium is bombarded using electron gun, is deposited on the outer surface of substrate after selenium evaporation in the form of angstrom nanoscale molecule,
Controlling the 4th selenium layer evaporation rate simultaneously is4th selenium layer ultimately form after with a thickness of 300 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, using electron gun bombardment fifth metal oxide skin(coating) membrane material metal oxide, metal oxide evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling fifth metal oxide skin(coating) evaporation rate and beingWith a thickness of
Then 300 Ethylmercurichlorendimides form anti-oxidant etch resistant layer；
D, photochromic layer plated film is carried out to substrate outer surface
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, the membrane material of the 6th low refractive index film layer is bombarded using electron gun, is sunk in the form of angstrom nanoscale molecule after membrane material evaporation
Product controls the 6th low refractive index film layer evaporation rate and is in the outer surface of substrateWith a thickness of 1500 Ethylmercurichlorendimides；
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, using electron gun bombard the 7th metal oxide layer membrane material metal oxide, metal oxide evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling the 7th metal oxide layer evaporation rate and beingWith a thickness of
200 Ethylmercurichlorendimides；
It holds vacuum chamber vacuum degree and is less than or is equal to 2.0*10-5When Torr, while the temperature of vacuum chamber being kept to exist
40-60 DEG C, the membrane material of the 8th low refractive index film layer is bombarded using electron gun, is deposited in the form of angstrom nanoscale molecule after membrane material evaporation
In the outer surface of substrate, while controlling the 8th low refractive index film layer evaporation rate and beingWith a thickness of 900 Ethylmercurichlorendimides, then
Form photochromic layer；
E, plating plated film is carried out to substrate outer surface
Vacuum chamber vacuum degree is kept to be less than or be equal to 2.0*10-5When Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, the membrane material waterproof material of the 9th film layer is heated using tungsten boat, with an angstrom nanoscale molecule shape after the evaporation of the 9th film layer
Formula is deposited on the outer surface of substrate, while controlling the 9th film layer evaporation rate and beingAfter 9th film layer ultimately forms
With a thickness of 200 Ethylmercurichlorendimides, as protective layer.
Embodiment 4
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer,
Seven metal oxide layers, the 8th low refractive index film layer, the 9th metal oxide layer, the tenth low refractive index film layer and waterproof
Layer.Wherein, the first silicon-aluminum mixture layer and the second metal oxide layer form prime coat, and pattern and third silicon-aluminum mixture layer are
One layer, pattern is that ink print, copper mold plate are bonded any one that pattern or electrostatic paster are bonded in pattern, the 4th selenium layer and
Fifth metal oxide skin(coating) group becomes anti-oxidant etch resistant layer, the 6th low refractive index film layer, the 7th metal oxide layer, the 8th
Low refractive index film layer, the 9th metal oxide layer, the tenth low refractive index film layer are photochromic layer, and waterproof layer is as protective layer.
Specifically, eyeglass substrate is acrylic substrate, the first silicon-aluminum mixture layer is L5, with a thickness of 130 Ethylmercurichlorendimides, the second gold medal
Category oxide skin(coating) is Ti3O5, with a thickness of 180 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is L5, with a thickness of 1100 Ethylmercurichlorendimides, the 4th selenium layer
With a thickness of 350 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the 6th low refractive index film layer is L5, thick
Degree is 1400 Ethylmercurichlorendimides, and the 7th metal oxide layer is Ti3O5, with a thickness of 150 Ethylmercurichlorendimides, the 8th low refractive index film layer is L5, thickness
For 140 Ethylmercurichlorendimides, the 9th metal oxide layer is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the tenth low refractive index film layer is L5, with a thickness of
600 Ethylmercurichlorendimides, the 11st thin film layer thickness are 260 Ethylmercurichlorendimides.Prepared eyeglass is purplish blue eyeglass, and the pattern in eyeglass presents green
Color.
The preparation method of eyeglass is that, due to the change of lens structure design, plating run is answered with embodiment 3, difference
Make it is corresponding change, evaporation rate when plated film can carry out ± 20% variation on the basis of the above, also the change comprising membrane material,
The variation of thicknesses of layers and number of plies variation etc., wherein the 9th metal oxide layer, the tenth low refractive index film layer, the 11st
The preparation of film layer can be according to following progress:
When keeping vacuum chamber vacuum degree to be less than or being equal to 2.0*10-5Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, using electron gun bombard the 9th metal oxide layer membrane material metal oxide, metal oxide evaporation after with angstrom
Nanoscale molecule form is deposited on the outer surface of substrate, while controlling the 9th metal oxide layer evaporation rate and beingWith a thickness of
1000 Ethylmercurichlorendimides；
When holding vacuum chamber vacuum degree and being less than or be equal to 2.0*10-5Torr, while the temperature of vacuum chamber being kept to exist
40-60 DEG C, the membrane material of the tenth low refractive index film layer is bombarded using electron gun, is deposited in the form of angstrom nanoscale molecule after membrane material evaporation
In the outer surface of substrate, while controlling the tenth low refractive index film layer evaporation rate and beingWith a thickness of 600 Ethylmercurichlorendimides, then
Form photochromic layer；
When keeping vacuum chamber vacuum degree to be less than or being equal to 2.0*10-5Torr, while keeping the temperature of vacuum chamber
At 40-60 DEG C, the membrane material waterproof material of the 11st film layer is heated using tungsten boat, with Ethylmercurichlorendimide fraction after the evaporation of the 11st film layer
Sub- form is deposited on the outer surface of substrate, while controlling the 11st film layer evaporation rate and being11st film layer is most
End form after with a thickness of 260 Ethylmercurichlorendimides, as protective layer.
Embodiment 5
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer gold, fifth metal oxide skin(coating), the 6th low refractive index film layer,
7th metal oxide layer, the 8th low refractive index film layer and waterproof layer.Wherein, the first silicon-aluminum mixture layer and the second metal oxygen
Compound layer forms prime coat, and pattern and third silicon-aluminum mixture layer are one layer, and pattern is ink print, copper mold plate fitting figure
Case or electrostatic paster are bonded any one in pattern, and the 4th selenium layer and fifth metal oxide skin(coating) group become anti-oxidant anticorrosive
Layer, the 6th low refractive index film layer, the 7th metal oxide layer, the 8th low refractive index film layer are photochromic layer, waterproof layer conduct
Protective layer.
Specifically, eyeglass substrate is acrylic substrate, the first silicon-aluminum mixture layer is L5, with a thickness of 100 Ethylmercurichlorendimides, the second gold medal
Category oxide skin(coating) is Ti3O5, with a thickness of 150 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is L5, with a thickness of 900 Ethylmercurichlorendimides, the 4th selenium layer
With a thickness of 300 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is Ti3O5, with a thickness of 1600 Ethylmercurichlorendimides, the 6th low refractive index film layer is L5, thick
Degree is 1900 Ethylmercurichlorendimides, and the 7th metal oxide layer is Ti3O5, with a thickness of 600 Ethylmercurichlorendimides, the 8th low refractive index film layer is L5, thickness
For 600 Ethylmercurichlorendimides, waterproofing layer thickness is 260 Ethylmercurichlorendimides.
Prepared eyeglass is purplish blue eyeglass, and purple powder is presented in the pattern in eyeglass.
Embodiment 6
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer,
Seven metal oxide layers, the 8th low refractive index film layer, the 9th metal oxide layer and waterproof layer.Wherein, the first sial mixes
Nitride layer and the second metal oxide layer form prime coat, and pattern and third silicon-aluminum mixture layer are one layer, and pattern is ink printing
Pattern, copper mold plate fitting pattern or electrostatic paster are bonded any one in pattern, the 4th selenium layer and fifth metal oxide skin(coating) group
As anti-oxidant etch resistant layer, the 6th low refractive index film layer, the 7th metal oxide layer, the 8th low refractive index film layer,
Nine metal oxide layers are photochromic layer, and waterproof layer is as protective layer.
Specifically, eyeglass substrate is acrylic substrate, the first silicon-aluminum mixture layer is L5, with a thickness of 130 Ethylmercurichlorendimides, the second gold medal
Category oxide skin(coating) is Ti3O5, with a thickness of 180 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is L5, with a thickness of 1100 Ethylmercurichlorendimides, the 4th selenium layer
With a thickness of 350 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the 6th low refractive index film layer is L5, thick
Degree is 1600 Ethylmercurichlorendimides, and the 7th metal oxide layer is Ti3O5, with a thickness of 500 Ethylmercurichlorendimides, the 8th low refractive index film layer is L5, thickness
For 500 Ethylmercurichlorendimides, the 9th metal oxide layer is Ti3O5, with a thickness of 1400 Ethylmercurichlorendimides, waterproofing layer thickness is 260 Ethylmercurichlorendimides.
Embodiment 7
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer,
Seven metal oxide layers, the 8th low refractive index film layer and waterproof layer.Wherein, the first silicon-aluminum mixture layer and the oxidation of the second metal
Nitride layer forms prime coat, and pattern and third silicon-aluminum mixture layer are one layer, and pattern is ink print, copper mold plate fitting pattern
Or any one in electrostatic paster fitting pattern, the 4th selenium layer and fifth metal oxide skin(coating) group become anti-oxidant etch resistant layer,
6th low refractive index film layer, the 7th metal oxide layer, the 8th low refractive index film layer are photochromic layer, and waterproof layer is as protection
Layer.
Specifically, eyeglass substrate is CR-39 substrate, the first silicon-aluminum mixture layer is SiO2, with a thickness of 50 Ethylmercurichlorendimides, the second gold medal
Category oxide skin(coating) is ZrO2, with a thickness of 200 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is SiO2, with a thickness of 100 Ethylmercurichlorendimides, the 4th selenium layer
With a thickness of 400 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is ZrO2, with a thickness of 1900 Ethylmercurichlorendimides, the 6th low refractive index film layer is SiO2,
With a thickness of 800 Ethylmercurichlorendimides, the 7th metal oxide layer is ZrO2, with a thickness of 100 Ethylmercurichlorendimides, the 8th low refractive index film layer is SiO2, thick
Degree is 100 Ethylmercurichlorendimides, and waterproofing layer thickness is 280 Ethylmercurichlorendimides.
Embodiment 8
A kind of anti-oxidant erosion-resisting eyeglass, including substrate, the first silicon-aluminum mixture layer, the second metal oxygen stacked gradually
Compound layer, pattern, third silicon-aluminum mixture layer, the 4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer,
Seven metal oxide layers, the 8th low refractive index film layer and waterproof layer.Wherein, the first silicon-aluminum mixture layer and the oxidation of the second metal
Nitride layer forms prime coat, and pattern and third silicon-aluminum mixture layer are one layer, and pattern is ink print, copper mold plate fitting pattern
Or any one in electrostatic paster fitting pattern, the 4th selenium layer and fifth metal oxide skin(coating) group become anti-oxidant etch resistant layer,
6th low refractive index film layer, the 8th low refractive index film layer, is photochromic layer at the 7th metal oxide layer, and waterproof layer is as guarantor
Sheath.
Specifically, eyeglass substrate is glass substrate, the first silicon-aluminum mixture layer is L5, with a thickness of 150 Ethylmercurichlorendimides, the second metal
Oxide skin(coating) is Ta2O5, with a thickness of 100 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is MgF2, with a thickness of 1500 Ethylmercurichlorendimides, the 4th selenium layer
With a thickness of 200 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is Ta2O5, with a thickness of 100 Ethylmercurichlorendimides, the 6th low refractive index film layer is MgF2,
With a thickness of 1700 Ethylmercurichlorendimides, the 7th metal oxide layer is Ta2O5, with a thickness of 300 Ethylmercurichlorendimides, the 8th low refractive index film layer is MgF2,
With a thickness of 300 Ethylmercurichlorendimides, waterproofing layer thickness is 10 Ethylmercurichlorendimides.
Performance detection
Eyeglass in embodiment is tested for the property, corrosion resistance and antioxygenic property are shown in Table 1:
1 performance test table of table
Preferred embodiments of the present invention are described in detail above, still, the utility model is not limited to above-mentioned reality
Apply the detail in mode, in the range of the technology design of the utility model, can to the technical solution of the utility model into
The a variety of simple variants of row, these simple variants belong to the protection scope of the utility model.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case where shield, it can be combined in any appropriate way.In order to avoid unnecessary repetition, the utility model is to each
No further explanation will be given for the possible combination of kind.
In addition, any combination can also be carried out between a variety of different embodiments of the utility model, as long as it is not disobeyed
The thought for carrying on the back the utility model, equally should be considered as content disclosed in the utility model.
Claims (10)
1. a kind of anti-oxidant erosion-resisting eyeglass, including substrate and the film layer that the substrate outer surface is arranged in, it is characterised in that:
The film layer includes the prime coat stacked gradually from inside to outside, anti-oxidant etch resistant layer, photochromic layer and protective layer, the prime coat
It is made of the first silicon-aluminum mixture layer and the second metal oxide layer；The anti-oxidant etch resistant layer is by the 4th selenium layer and hardware
Belong to oxide skin(coating) composition, the photochromic layer is alternately made of the metal oxide layer and low refractive index film layer of layer 1-7；
Wherein, second metal oxide layer, fifth metal oxide skin(coating) are ZrO2、Ti3O5Or Ta2O5In any one shape
At coating；And the metal oxide layer is ZrO2、Ti3O5Or Ta2O5In any one formed coating, the low refraction
Rate film layer is SiO2, vacuum coating material L5 or MgF2In any one formed coating.
2. anti-oxidant erosion-resisting eyeglass according to claim 1, it is characterised in that: the substrate be acrylic substrate,
Any one of polycarbonate substrate, nylon substrates, CR-39 substrate or glass substrate；The first silicon-aluminum mixture layer is true
The coating that empty Coating Materials L5 is formed, the protective layer are the coating that waterproof material is formed.
3. anti-oxidant erosion-resisting eyeglass according to claim 1, it is characterised in that: the first silicon described in the prime coat
Aluminium mixture layer with a thickness of 50-150 Ethylmercurichlorendimide；Second metal oxide layer with a thickness of 100-200 Ethylmercurichlorendimide；The antioxygen
Change the 4th selenium layer in etch resistant layer with a thickness of 200-400 Ethylmercurichlorendimide, fifth metal oxide layer thicknesses are 100-1900 Ethylmercurichlorendimide；Institute
State photochromic layer with a thickness of 1000-4000 Ethylmercurichlorendimide；The protective layer with a thickness of 10-280 Ethylmercurichlorendimide.
4. anti-oxidant erosion-resisting eyeglass according to any one of claim 1-3, it is characterised in that: the prime coat and
Pattern layer is additionally provided between the anti-oxidant etch resistant layer, the pattern layer is made of pattern and third silicon-aluminum mixture layer,
Described in pattern in pattern layer be ink print, copper mold plate be bonded pattern or electrostatic paster be bonded it is any one in pattern
Kind；The third silicon-aluminum mixture layer is the coating that vacuum coating material L5 is formed.
5. anti-oxidant erosion-resisting eyeglass according to claim 4, it is characterised in that: the anti-oxidant erosion-resisting mirror
Piece include the substrate stacked gradually, the first silicon-aluminum mixture layer, the second metal oxide layer, pattern, third silicon-aluminum mixture layer,
4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer and waterproof layer, wherein the 6th low refractive index film layer is
SiO2, vacuum coating material L5 or MgF2In any one formed coating.
6. anti-oxidant erosion-resisting eyeglass according to claim 5, it is characterised in that: the first sial is mixed in the prime coat
Nitride layer is closed with a thickness of 80 Ethylmercurichlorendimides, the second metal oxide layer is with a thickness of 120 Ethylmercurichlorendimides, and third silicon-aluminum mixture layer is with a thickness of 100 angstroms
Rice, the 4th selenium layer with a thickness of 200 Ethylmercurichlorendimides, fifth metal oxide layer thicknesses are 950 Ethylmercurichlorendimides, the 6th low refractive index film thickness
Degree is 1000 Ethylmercurichlorendimides, and waterproofing layer thickness is 150 Ethylmercurichlorendimides.
7. anti-oxidant erosion-resisting eyeglass according to claim 4, it is characterised in that: the anti-oxidant erosion-resisting mirror
Piece include the substrate stacked gradually, the first silicon-aluminum mixture layer, the second metal oxide layer, pattern, third silicon-aluminum mixture layer,
4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer, the 7th metal oxide layer, the 8th low-index layer
And waterproof layer, wherein the 7th metal oxide layer is ZrO2、Ti3O5Or Ta2O5In any one formed coating.
8. anti-oxidant erosion-resisting eyeglass according to claim 7, it is characterised in that: the first sial is mixed in the prime coat
Close nitride layer with a thickness of 100 Ethylmercurichlorendimides, the second metal oxide layer with a thickness of 150 Ethylmercurichlorendimides；Third sial is mixed in the pattern layer
Close nitride layer with a thickness of 150 Ethylmercurichlorendimides；The 4th selenium layer in the anti-oxidant etch resistant layer is with a thickness of 300 Ethylmercurichlorendimides, fifth metal oxygen
Compound layer is with a thickness of 300 Ethylmercurichlorendimides；The 6th low refractive index film layer is in the photochromic layer with a thickness of 1500 Ethylmercurichlorendimides, the oxidation of the 7th metal
Nitride layer is with a thickness of 200 Ethylmercurichlorendimides, and the 8th low-index layer is with a thickness of 900 Ethylmercurichlorendimides；The protective layer with a thickness of 200 Ethylmercurichlorendimides.
9. anti-oxidant erosion-resisting eyeglass according to claim 4, it is characterised in that: the anti-oxidant erosion-resisting mirror
Piece include the substrate stacked gradually, the first silicon-aluminum mixture layer, the second metal oxide layer, pattern, third silicon-aluminum mixture layer,
4th selenium layer, fifth metal oxide skin(coating), the 6th low refractive index film layer, the 7th metal oxide layer, the 8th low-refraction are thin
Film layer, the 9th metal oxide layer, the tenth low refractive index film layer and waterproof layer.
10. anti-oxidant erosion-resisting eyeglass according to claim 9, it is characterised in that: the first silicon-aluminum mixture layer is L5,
With a thickness of 130 Ethylmercurichlorendimides, the second metal oxide layer is Ti3O5, with a thickness of 180 Ethylmercurichlorendimides, third silicon-aluminum mixture layer is L5, thickness
For 1100 Ethylmercurichlorendimides, the 4th selenium layer with a thickness of 350 Ethylmercurichlorendimides, fifth metal oxide skin(coating) is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the 6th
Low refractive index film layer is L5, and with a thickness of 1400 Ethylmercurichlorendimides, the 7th metal oxide layer is Ti3O5, low with a thickness of 150 Ethylmercurichlorendimides, the 8th
Index film layer is L5, and with a thickness of 140 Ethylmercurichlorendimides, the 9th metal oxide layer is Ti3O5, with a thickness of 1000 Ethylmercurichlorendimides, the tenth low folding
Penetrating rate film layer is L5, and with a thickness of 600 Ethylmercurichlorendimides, waterproofing layer thickness is 260 Ethylmercurichlorendimides.
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| CN201822229905.2U CN209182540U (en) | 2018-12-28 | 2018-12-28 | A kind of anti-oxidant erosion-resisting eyeglass |
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