CN208949172U - A kind of carbon black modified system - Google Patents

A kind of carbon black modified system Download PDF

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Publication number
CN208949172U
CN208949172U CN201820946113.4U CN201820946113U CN208949172U CN 208949172 U CN208949172 U CN 208949172U CN 201820946113 U CN201820946113 U CN 201820946113U CN 208949172 U CN208949172 U CN 208949172U
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carbon black
ozone
black modified
staving
modified system
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CN201820946113.4U
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樊载
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Zaiwei New Materials Technology Gansu Co ltd
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Sichuan Michael Air Bubble Technology Co Ltd
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Abstract

The utility model discloses a kind of carbon black modified systems, for carrying out dispersion grinding to carbon black color paste, and provide ozone micro-nano bubble for carbon black color paste, including sequentially connected ozone generating-device, micro-nano bubble generator, carbon black modified device and Ozone Absorption device;Its structure of the system is simple and convenient to operate, oxidation modification is carried out using the micro-nano bubble of ozone, oxidation efficiency is high, reaction condition is mild, environmentally protective and cost is relatively low, bigger and economic benefit can be generated, it is various to solve traditional carbon black modified required equipment, modified technique route is longer, it is cumbersome, the technical issues of being readily incorporated other by-products and impurity, carbon black granularity is inhomogenous when solving traditional carbon black modified simultaneously, the not high technical problem of the stability of the dispersion in water-based system.

Description

A kind of carbon black modified system
Technical field
The utility model relates to carbon black modified technical fields, and in particular to a kind of carbon black modified system.
Background technique
It is easy to form between carbon black ion the features such as large specific surface area, surface free energy is high since carbon black particle itself is small Extremely strong aggregation force, makes it show hydrophobic property, it is difficult to disperse in water-based system.
There are many work carbon black oxidation modification techniques at present, for improving dispersion performance of the carbon black in water-based system.Than Such as, carbon black is modified using the various dispersing agents with many hydrophilic radicals and the group that absorbs water;For another example, nitric acid, double is used It is modified that the oxidants such as oxygen water, hypochlorite carry out chemical oxidation to carbon black.
Although these methods are more obvious to the oxidation of carbon black, since the granularity of carbon black feed stock is inhomogenous, carbon black The stability of dispersion in water-based system is not high;When traditional modified technique is modified carbon black simultaneously, need using very much Equipment, and other by-products and impurity are readily incorporated in modifying process;In addition, conventional carbon black modified technique route is longer, place There are many difficulties in actual quantization production, be unfavorable for large-scale production in reason process very complicated.
Utility model content
The utility model provides a kind of carbon black modified system, and the carbon black modified required equipment to solve traditional is various, changes The technical issues of property process route is longer, cumbersome, is readily incorporated other by-products and impurity, while solving traditional carbon black Carbon black granularity is inhomogenous when modified, the not high technical problem of the stability of the dispersion in water-based system.
To solve the above problems, the technical solution adopted in the utility model is as follows:
A kind of carbon black modified system for carrying out dispersion grinding to carbon black color paste, and provides the micro-nano bubble of ozone to charcoal Black slurry carries out oxidation modification, including sequentially connected ozone generating-device, micro-nano bubble generator and carbon black modified device; The ozone generating-device includes ozone generator;The micro-nano bubble generator is micro-nano including forming ozone for distribution The porous ceramic plate of bubble;The carbon black modified device includes being provided with the staving that layer is sanded on inner wall and being arranged at the top of staving Bung;The staving upper end is provided with deionized water water inlet and ozone outlet, and bottom end is provided with carbon black color paste outlet And PH sensor;It is provided on the cover and is ground with the feed hopper being connected to inside staving and the dispersion extended to inside staving Grinding machine structure;Bottom is arranged in staving in the porous ceramic plate, and is connected to by gas-guide tube with ozone generator.Described in this programme Carbon black modified system structure be simple and convenient to operate, oxidation modification is carried out using the micro-nano bubble of ozone, oxidation efficiency is high, anti- It answers that mild condition, environmentally protective and cost is relatively low, bigger and economic benefit can be generated, solve traditional carbon black modified institute Need equipment various, modified technique route is longer, cumbersome, the technical issues of being readily incorporated other by-products and impurity;Meanwhile It is provided with disperse mill structure to grind carbon black, carbon black granularity is inhomogenous when solving traditional carbon black modified, aqueous The not high technical problem of the stability of dispersion in system.
Further, the disperse mill structure includes being arranged on bung and agitating shaft extends to stirring inside staving Motor, two mixing rolls for being symmetricly set in staving and being in close contact with sand milling layer;Described two mixing rolls pass through two cross It is connected on agitating shaft to connecting rod, and mixing roll can be freely rotated in connecting rod;Agitating shaft between two connecting rods On be provided with multiple stirring blades.Mixing roll grinds the larger particle of carbon black, improves dispersion of the carbon black in water-based system Stability and granularity uniformity;Stirring blade plays the role of being dispersed with stirring, and carbon black and deionized water is quickly made to be sufficiently mixed profit It is wet.
Further, described two grinding roller surfaces are provided with the grinding layer to match with the sand milling layer, enhancing grinding Effect.
Further, it is provided with polytetrafluoroethylsheath sheath on the agitating shaft, prevents agitating shaft from getting rusty in water-based system Or impurity and by-product are introduced to carbon black color paste by ozone oxidation.
Further, the ozone generating-device further includes high pure oxygen steel cylinder;The high pure oxygen steel cylinder by appendix with Ozone generator connection;Explosion-proof solenoid valve and pressure gauge are provided on the appendix.
Further, the porous ceramic plate is internally provided with cushion space, and top part cloth is provided with several empty with buffering Between the micron-sized gas distribution holes that are connected to, bottom is provided with the connecting hole being connected to cushion space;The gas-guide tube is connected to On the connecting hole.The ozone that ozone generator generates is delivered to cushion space through gas-guide tube, and sets through gas distribution holes distribution The micro-nano bubble of ozone is formed in carbon black color paste.
Further, it is provided with gas flowmeter on the gas-guide tube, for monitoring ozone flow velocity, in order to control ozone The flow velocity of micro-nano bubble;The gas-guide tube is silica gel flexible conduit, will not be by ozone oxidation, and the service life is longer.
Residence time of the bubble in carbon black color paste is long, every to rise 1 centimetre of needs 3 minutes, simultaneously as between aqueous vapor Surface tension be greater than bubble inner pressure, bubble can in contract be inclined to, once shrink bubble inner pressure lost with surface tension it is flat Weighing apparatus, bubbles burst, ozone gas is dissolved completely in aqueous, high-efficient to the oxidation modification of carbon black.
Further, it is provided with the Ozone Absorption device for filling potassium iodide absorbing liquid on the ozone outlet, to residue Ozone carries out absorption processing, to prevent generating harm to human body.
In conclusion by adopting the above-described technical solution, the beneficial effects of the utility model are:
1. carbon black modified system, structure described in this programme are simple and convenient to operate, carried out using the micro-nano bubble of ozone Oxidation modification, oxidation efficiency is high, reaction condition is mild, environmentally protective and cost is relatively low, can generate bigger and economic benefit, Solve it is traditional it is carbon black modified needed for equipment it is various, modified technique route is longer, cumbersome, is readily incorporated other by-products And the technical issues of impurity.
2. carbon black modified system described in this programme is provided with disperse mill structure and grinds to carbon black, quickly makes charcoal It is black to be sufficiently mixed wetting with deionized water, and the larger particle of carbon black is ground, improve dispersion of the carbon black in water-based system Stability and granularity uniformity, carbon black granularity is inhomogenous when solving traditional carbon black modified, the dispersion in water-based system The not high technical problem of stability.
3. carbon black modified device described in this programme, the micro-nano bubble of the ozone that the ozone of transmitting is formed in carbon black color paste Diameter is 30~45 microns, and residence time of the bubble in carbon black color paste is long, every to rise 1 centimetre of needs 3 minutes, meanwhile, by Surface tension between aqueous vapor is greater than bubble inner pressure, and bubble can be inclined in contract, once the bubble inner pressure and table that shrink Face tension disequilibrium, bubbles burst, ozone gas is dissolved completely in aqueous, high-efficient to the oxidation modification of carbon black.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the carbon black modified system of the utility model;
Fig. 2 is the structural schematic diagram of the carbon black modified device of the utility model;
Fig. 3 is the structural schematic diagram that layer is sanded in the utility model.
In the figure, it is marked as 1- staving, 2- bung, 3- deionized water water inlet, 4- ozone outlet, the discharge of 5- carbon black color paste Mouthful, 6-PH sensor, 7- stirring motor, 8- feed hopper, 9- agitating shaft, 10- stirring blade, 11- connecting rod, 12- polytetrafluoroethyl-ne Alkene sheath, 13- mixing roll, 14- porous ceramic plate, 15- silica gel flexible conduit, 16- gas distribution holes, 17- gas flowmeter, 18- Layer is sanded in ozone generator, 19- high pure oxygen steel cylinder, 20- explosion-proof solenoid valve, 21- pressure gauge, 22- Ozone Absorption device, 23-.
Specific embodiment
All features disclosed in this specification can be with any other than mutually exclusive feature and/or step Mode combines.
Embodiment 1
It please refers to shown in Fig. 1~3, the present embodiment provides a kind of carbon black modified systems, send out for continuing into carbon black color paste The micro-nano bubble of ozone is penetrated, and dispersion grinding is carried out to carbon black color paste, to improve the dispersion stabilization and uniform particle diameter of carbon black.
In particular, a kind of carbon black modified system provided in this embodiment, including it is sequentially connected ozone generating-device, micro- Nano-bubble generator, carbon black modified device and Ozone Absorption device 22.
The ozone generating-device includes high pure oxygen steel cylinder 19 and ozone generator 18.The bottleneck of the high pure oxygen steel cylinder 19 On be provided with appendix, explosion-proof solenoid valve 20 and pressure gauge 21 are provided on the appendix, for controlling the conveying of high pure oxygen, And monitor the pressure size of the high pure oxygen of output.The air inlet of the ozone generator 18 is connect with the appendix.
The micro-nano bubble generator includes porous ceramic plate 14, silica gel flexible conduit 15 and gas flowmeter 17.Institute The exhaust outlet connection that 15 one end of silica gel flexible conduit is connected to ozone generator 18 is stated, the other end and the porous ceramic plate 14 connect It connects, the gas flowmeter 17 is arranged on silica gel flexible conduit 15.
Specifically by the porous ceramic plate 14 is internally provided with cushion space, and top part cloth is provided with several and buffering The micron-sized gas distribution holes 16 of space connection, bottom is provided with the connecting hole being connected to cushion space;The silica gel is soft to lead Pipe 15 is connected on the connecting hole and is connected to porous ceramic plate 14, and the ozone that ozone generator 18 generates is through silica gel flexible conduit 15 are delivered to cushion space, and are discharged through gas distribution holes 16.
The carbon black modified device includes the staving 1 that one layer of sand milling layer is provided on inner wall;The cylinder, which is surveyed on wall, to be arranged There are deionized water water inlet 3, ozone outlet 4 and carbon black color paste outlet 5.The partial size that layer is sanded and is made up of polypropylene For 15 ± 5 microns of frosting powders and 1 integrated molding of staving.
The porous ceramic plate 14 is arranged in staving 1 bottom, the silica gel flexible conduit 15 through 1 bottom of staving with it is porous The connecting hole of 14 bottom of ceramic wafer connects.
Cover is provided at the top of the staving 1;Feed hopper 8 is provided on the bung 2 and is extended to inside staving 1 Disperse mill structure.
The disperse mill structure includes 10, two mixing rolls 13 of multiple stirring blades and stirring on bung 2 is arranged in Mix motor 7;The agitating shaft 9 of the stirring motor 7 extends in staving 1 at the top of bung 2,9 surface of the agitating shaft setting There is one layer of polytetrafluoroethylsheath sheath 12, prevents agitating shaft 9 from getting rusty in water-based system or being drawn by ozone oxidation to carbon black color paste Enter impurity and by-product.
The mixing roll 13 is in close contact with the sand milling layer on 1 inner wall of staving, and 13 surface of mixing roll is provided with one layer The grinding layer to match with the sand milling layer.
Two mixing rolls 13 are symmetrical arranged, and are connected on agitating shaft 9 by two transverse connecting rods 11 and can be It is freely rotated in connecting rod 11.The multiple stirring blade 10 is arranged on the agitating shaft 9 between two connecting rods 11.
The mixing roll 13, stirring blade 10, transverse connecting rod 11 are made of polytetrafluoroethylene material.
The Ozone Absorption device 22 is the container for filling KI solution, is connected on ozone outlet 4 by pipeline.
In order to detect the pH value of carbon black color paste, in the staving 1 bottom and be located at porous ceramic plate 14 periphery be provided with PH sensor 6.When the pH value of carbon black color paste is reduced to 3.2~3.4, carbon black modified end.
The working principle of carbon black modified system described in this programme are as follows: proportionally, be added respectively from feed hopper 8 and water inlet Then carbon black feed stock and deionized water start stirring motor 7, carbon black and deionized water are mixed well profit using compared with low-rotate speed It is wet;After carbon black mixes wetting by deionized water completely, start ozone generator 18, high pure oxygen generates after ozone generator 18 Ozone be evenly distributed in carbon black color paste by the gas distribution holes 16 on porous ceramic plate 14, and formed in carbon black color paste The micro-nano bubble of 34~45 microns of ozone carries out oxidation modification to carbon black;The revolving speed of stirring motor 7 is improved simultaneously, it is synchronous Dispersion grinding is carried out to carbon black, improves dispersion stabilization and uniform particle diameter of the carbon black in water-based system;To be dissolved in carbon black Ozone in mill base discharges after the absorption of Ozone Absorption device 22.Carbon black modified system described in this programme uses gas phase The mode of oxidation, is modified carbon black, with tradition using dispersing agent and chemical oxidation reagent carry out it is carbon black modified compare, will not Impurity and by-product are introduced, while also simplifying modified technique, so that operating process becomes simple, it is easy to accomplish industry Change.
The personnel of technical field should be appreciated that the ozone generator 18 and stirring motor 7 is the prior art, can According to demand, buying obtains the product of dimension or model on the market.For example, the ozone generator 18 that this programme uses is The SK-CFG-600E type ozone generator of Jinan San Kang Environmental Protection Technology Co., Ltd production.
Although above-mentioned be described specific embodiment of the present utility model, model not is protected to the utility model The limitation enclosed, based on the technical solution of the present invention, those skilled in the art do not need to make the creative labor i.e. Various modifications, replacement or the deformation that can be made are still within the scope of the present invention.
In scheme, it is also necessary to which explanation is unless specifically defined or limited otherwise, term " setting ", " installation ", " connected ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, be also possible to dismantling connection, or be integrally connected; It can be mechanical connection, be also possible to be electrically connected;It can be directly connected, can also be connected by intermediate media's brief introduction, it can be with It is the connection inside two elements.For the ordinary skill in the art, above-mentioned art can be understood as the case may be The concrete meaning of language in the present invention.

Claims (8)

1. a kind of carbon black modified system, it is characterised in that: including sequentially connected ozone generating-device, micro-nano bubble generator With carbon black modified device;The ozone generating-device includes ozone generator (18);The micro-nano bubble generator includes using The porous ceramic plate (14) of the micro-nano bubble of ozone is formed in distribution;The carbon black modified device includes that sand milling is provided on inner wall The staving (1) of layer and the bung (2) being arranged at the top of staving (1);Staving (1) upper end is provided with deionized water water inlet (3) and ozone outlet (4), bottom end are provided with carbon black color paste outlet (5) and PH sensor (6);It is provided on the bung With the feed hopper (8) that be connected to inside staving (1) and extend to disperse mill structure inside staving (1);The porous ceramics Plate (14) is arranged in staving (1) interior bottom, and is connected to by gas-guide tube with ozone generator (18).
2. a kind of carbon black modified system according to claim 1, it is characterised in that: the disperse mill structure includes setting On bung (2) and agitating shaft (9) extend to the internal stirring motor (7) of staving (1), two be symmetricly set in staving (1) And the mixing roll (13) being in close contact with sand milling layer;Described two mixing rolls (13) are connected to by two transverse connecting rods (11) On agitating shaft (9), and mixing roll (13) connecting rod (11) is rotatablely connected;It is set on agitating shaft (9) between two connecting rods (11) It is equipped with multiple stirring blades (10).
3. a kind of carbon black modified system according to claim 2, it is characterised in that: described two mixing roll (13) surfaces are set It is equipped with the grinding layer to match with the sand milling layer.
4. a kind of carbon black modified system according to claim 2, it is characterised in that: be provided on the agitating shaft (9) poly- Tetrafluoroethene sheath (12).
5. a kind of carbon black modified system according to claim 1, it is characterised in that: the ozone generating-device further includes height Pure oxygen steel cylinder (19);The high pure oxygen steel cylinder (19) is connect by appendix with ozone generator (18);It is set on the appendix It is equipped with explosion-proof solenoid valve (20) and pressure gauge (21).
6. a kind of carbon black modified system according to claim 1, it is characterised in that: set inside the porous ceramic plate (14) It is equipped with cushion space, top part cloth is provided with several micron-sized gas distribution holes (16) being connected to cushion space, and bottom is set It is equipped with the connecting hole being connected to cushion space;The gas-guide tube is connected on the connecting hole.
7. a kind of carbon black modified system according to claim 1 or 5, it is characterised in that: be provided with gas on the gas-guide tube Flowmeter body (17);The gas-guide tube is silica gel flexible conduit (15).
8. a kind of carbon black modified system according to claim 1, it is characterised in that: be arranged on the ozone outlet (4) There is the Ozone Absorption device (22) for filling potassium iodide absorbing liquid.
CN201820946113.4U 2018-06-20 2018-06-20 A kind of carbon black modified system Active CN208949172U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110316716A (en) * 2019-07-10 2019-10-11 青岛黑猫炭黑科技有限责任公司 A kind of preparation method and reaction unit of gas-phase modification carbon-based material
JP2023031231A (en) * 2021-08-23 2023-03-08 南華大学 Device and method for leaching sandstone uranium ore through micro-nano bubble oxidation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110316716A (en) * 2019-07-10 2019-10-11 青岛黑猫炭黑科技有限责任公司 A kind of preparation method and reaction unit of gas-phase modification carbon-based material
JP2023031231A (en) * 2021-08-23 2023-03-08 南華大学 Device and method for leaching sandstone uranium ore through micro-nano bubble oxidation

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Effective date of registration: 20231010

Address after: Room 223, 2nd Floor, Unit 1, Building 19, Wanke Haiyue Huicheng, No. 169 Haichang Road, Huayang Street, Tianfu New Area, Chengdu, Sichuan, 610200

Patentee after: Sichuan Keda Tengfei New Material Technology Co.,Ltd.

Address before: No. 1, 16th Floor, Building 11, No. 1388, Middle Section of Tianfu Avenue, Chengdu High tech Zone, China (Sichuan) Pilot Free Trade Zone, Chengdu City, Sichuan Province, 610000

Patentee before: SICHUAN MAIKE LANNUO BUBBLE TECHNOLOGY Co.,Ltd.

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Effective date of registration: 20240401

Address after: 735000, No. 5 Zhenxing Road, Building Materials and Chemical Industry Park, Dongzhen, Laoshi District, Yumen City, Jiuquan City, Gansu Province

Patentee after: Zaiwei New Materials Technology (Gansu) Co.,Ltd.

Country or region after: China

Address before: Room 223, 2nd Floor, Unit 1, Building 19, Wanke Haiyue Huicheng, No. 169 Haichang Road, Huayang Street, Tianfu New Area, Chengdu, Sichuan, 610200

Patentee before: Sichuan Keda Tengfei New Material Technology Co.,Ltd.

Country or region before: China