CN208923201U - A kind of perovskite solar cell encapsulation structure - Google Patents

A kind of perovskite solar cell encapsulation structure Download PDF

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Publication number
CN208923201U
CN208923201U CN201821979458.6U CN201821979458U CN208923201U CN 208923201 U CN208923201 U CN 208923201U CN 201821979458 U CN201821979458 U CN 201821979458U CN 208923201 U CN208923201 U CN 208923201U
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perovskite solar
solar cell
layer
cell device
back plate
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董超
熊继光
秦校军
赵志国
邬俊波
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Huaneng Clean Energy Research Institute
China Huaneng Group Co Ltd
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Huaneng Clean Energy Research Institute
China Huaneng Group Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/50Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • H10K30/88Passivation; Containers; Encapsulations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The utility model provides a kind of perovskite solar cell encapsulation structure, glass substrate, perovskite solar cell device, glass back plate and edge seal glue including being coated with conductive layer;Perovskite solar cell device face down is arranged on the conductive layer of glass substrate;The top of perovskite solar cell device is arranged in glass back plate;Edge seal glue is arranged in glass back plate and perovskite solar cell device edge.The utility model uses primary encapsulation of the glass back plate to perovskite solar battery, on the one hand can isolate moisture and oxygen, on the other hand increases the ability of encapsulating structure antiskid, wiping, avoids scratching during using, operating battery;One layer of fine and close silicon nitride protective layer is deposited using in perovskite solar cell surface, it can play anticorrosive well, the effect that waterproof, oxygen invade, its excellent encapsulation performance of the utility model substantially increase stability of the perovskite solar battery under air environment.

Description

A kind of perovskite solar cell encapsulation structure
Technical field
The utility model belongs to solar cell package technical field, in particular to a kind of perovskite solar cell package Structure.
Background technique
Organic/inorganic perovskite solar battery is since discovery in 2009, and photoelectric conversion efficiency is from 3.8% Promoted by now 22% or more, improved efficiency speed be in the market various solar batteries promoted it is fastest, and Its photoelectric conversion efficiency has been approached or more than conventional crystalline silicon, copper indium gallium selenide and cadmium telluride cells on the market.Perovskite solar energy Another big advantage of battery is exactly that fabrication processing compares and greatly shortens simplification, and cost of manufacture with conventional crystalline silicon battery It is greatly reduced.
Encapsulation technology has a major impact battery life in solar battery use process, existing perovskite solar energy The disadvantages of battery is often poor to the stability of moisture, oxygen, and calcium titanium ore bed is extremely easy in decomposition failure in atmospheric environment.
Utility model content
The purpose of this utility model is to provide a kind of perovskite solar cell encapsulation structures, to solve above-mentioned existing skill The problem of art, the maximized water and oxygen obstructed in air improve the stability of perovskite battery by encapsulation.
To achieve the above object, the technology employed by the present utility model is
A kind of perovskite solar cell encapsulation structure, glass substrate, perovskite solar-electricity including being coated with conductive layer Pond device, glass back plate and edge seal glue;The conduction of glass substrate is arranged in perovskite solar cell device face down On layer;The top of perovskite solar cell device is arranged in glass back plate;Glass back plate and perovskite solar cell device Edge seal glue is arranged in edge.
Further, it is equipped with cavity between glass back plate and perovskite solar cell device, is filled with inertia in cavity Gas.
It further, further include silicon nitride protective layer, perovskite solar cell device is arranged in silicon nitride protective layer The back side.
Further, perovskite solar cell device includes the electron transfer layer set gradually from bottom to top, perovskite Active layer, hole transmission layer and positive electrode.
Further, negative electrode of the conductive layer of glass substrate as perovskite solar cell device, conductive layer ITO Transparency conducting layer.
Further, electron transfer layer is thin layer of tin oxide, with a thickness of 20-50nm.
Further, positive electricity extremely aluminium layer, silver layer or layer gold, with a thickness of 60-100nm.
It further, further include positive electrode exit, negative electrode exit;Positive electrode exit is arranged in the perovskite sun One end of energy battery device, positive electrode exit are connect with positive electrode;Negative electrode exit is arranged in perovskite solar battery The other end of device, negative electrode exit are connect with negative electrode.
Compared with prior art, the beneficial effects of the utility model have:
The utility model provides a kind of perovskite solar cell encapsulation structure, and the utility model is using glass back plate to calcium The primary encapsulation of titanium ore solar battery, on the one hand can isolate moisture and oxygen, and the addition of another aspect glass back plate increases The ability of encapsulating structure antiskid, wiping, avoid use, operation battery during the scratching phenomenon that occurs;
Further, one layer of fine and close silicon nitride protective layer, silicon nitride are deposited using in perovskite rear surface of solar cell Protective layer has excellent chemical stability and higher hardness, can play the work anticorrosive well, waterproof, oxygen invade With;
The utility model provides a kind of perovskite solar cell encapsulation structure, with solar energy in installation, use process Battery it is non-breakable with damage, simple process, low in cost, good seal performance the advantages that;Using pressurization patch in a nitrogen atmosphere Close glass back plate, to perovskite solar battery carry out first layer protection, using on perovskite battery deposited silicon nitride protect Layer carries out second layer protection, and moisture and oxygen in air has effectively been isolated, has improved the stabilization of perovskite solar battery Property, it has broad application prospects.
Detailed description of the invention
Fig. 1 is the cross-sectional view of perovskite solar cell encapsulation structure.
Specific embodiment
When describing the embodiments of the present invention, for the sake of clarity, specific term is used, however, this reality Selected specific term is not intended to be limited to novel.It should be appreciated that each specific original part includes that similar method is run to realize class Like all technically equivalent ones of purpose.
With reference to the accompanying drawing with example in detail the embodiments of the present invention.
As shown in Figure 1, the utility model provides a kind of encapsulating structure of perovskite solar battery, including to be coated with ITO saturating The glass substrate 101 of bright conductive layer, perovskite solar cell device 102, positive electrode exit 104, negative electrode exit 103, silicon nitride protective layer 105, edge seal glue 106 and glass back plate 107.
The top for being coated with the glass substrate 101 of transparent conductive layer, calcium is arranged in perovskite solar cell device 102 102 face down of titanium ore solar cell device is close to the transparent conductive layer setting of glass substrate 101;Silicon nitride protective layer 105 are arranged in the back side of perovskite solar cell device 102, and the first layer as perovskite solar cell device 101 is anti- Shield.
The setting of glass back plate 107 is in 105 top of silicon nitride protective layer, glass back plate 107 and perovskite solar battery device 102 edge of part is sealed using edge seal glue 106, and edge seal glue 106 is arranged in glass substrate 101 and back-panel glass Between 107;Perovskite solar cell device 102 is encapsulated in glass substrate 101, glass back plate 107 and edge seal glue 106 In the sealing space of formation, it is equipped with cavity between glass back plate 107 and silicon nitride protective layer 105, is filled with nitrogen in cavity, makees It is protected for the second layer of perovskite solar cell device 101.
Perovskite solar cell device 101 includes being successively set on glass substrate transparent conductive layer from bottom to top Electron transfer layer, perovskite active layer, hole transmission layer and positive electrode;Transparent conductive layer conduct in glass substrate 101 Extremely, perovskite active layer is AX to the negative electricity of perovskite solar cell device 101nY3-n, wherein R is alkyl, and A is Pb or Sn, X and Y is Cl, Br or I, and n is the real number of 0-3, with a thickness of 350-500nm;Hole transmission layer be and perovskite active layer material energy The matched organic and inorganic material layer of grade, with a thickness of 100nm;Positive electricity extremely aluminium layer, silver layer or layer gold, with a thickness of 60-100nm.
A kind of perovskite solar cell encapsulation structure of the utility model, further includes positive electrode exit 104 and negative electrode Exit 103;One end of perovskite solar cell device 102, positive electrode exit 104 is arranged in positive electrode exit 104 It is connect with the positive electrode of perovskite solar cell device 102;Negative electrode exit 103 is arranged in perovskite solar battery device The other end of part 102, negative electrode exit 103 are connect with the negative electrode of perovskite solar cell device 102.
A kind of packaging method of perovskite solar cell encapsulation structure of the utility model, comprising the following steps:
Step 1: using and be coated with conductive layer glass substrate 101 as substrate, prepare perovskite solar cell device 102;
Wherein:
The making step of perovskite solar cell device is specific as follows in step 1:
Step 11, electron transfer layer is prepared:
It suspends in the tin oxide nanoparticles of the conductive laminated upper spin coating diameter 1-10nm of the transparent of glass substrate 101 Liquid, revolving speed 2000-5000rpm, time 30-50s;Then 180 DEG C at a temperature of anneal 30 minutes, the electron-transport of preparation Thickness degree is in 20-50nm.
Step 12, titanium ore active layer is prepared:
Perovskite active layer can be used spin-coating method, vapour deposition process, magnetron sputtering method or roll-to-roll process and be prepared, and adopt When being prepared with spin-coating method, comprising the following steps:
1) lead iodide is dissolved in DMF solvent with 1.3mol/mL, lead iodide-DMF solution is spin-coated on electron transfer layer On, revolving speed 1500-2000rpm, time 40-50s obtained lead iodide-DMF film with annealing temperature 2 minutes of 75 DEG C;
2) iodine methyl ether, chloromethane amine and bromine methylamine are dissolved in isopropanol solvent with 1.3mol/mL, by iodine methyl ether-chloromethane amine- Bromine methylamine-aqueous isopropanol is spin-coated on lead iodide-DMF film, revolving speed 1500-2000rpm, time 40-50s, environment Humidity be 30% or so, with 150 DEG C annealing temperature 20 minutes, obtain perovskite active layer.Iodine methyl ether, chloromethane amine and bromine methylamine with The mass ratio of 10:1:1 is dissolved in isopropanol solvent, and obtaining iodine methyl ether, chloromethane amine and bromine methylamine total mol concentration is 1.3mol/mL Iodine methyl ether-chloromethane amine-bromine methylamine-aqueous isopropanol.
Step 13, hole transmission layer is prepared
Hole transmission layer is prepared using spin-coating method: the Spiro-OMeTAD solution mixed is spin-coated on perovskite active layer On, revolving speed 1500-2000rpm, time 40-50s obtain the hole transmission layer of preset thickness;
Step 14, positive electrode, negative electrode are prepared:
Positive electrode is prepared using vacuum evaporation, ALD deposition, magnetron sputtering, laser deposition or roll-to-roll process.Using Vacuum evaporation process are as follows:
The glass substrate 101 for being loaded with perovskite solar cell device 102 is fixed on mask plate, vacuum evaporation is utilized Equipment adjusts vacuum degree to preset range and default electrode domain is deposited on perovskite active layer, just to preset evaporation rate Thickness of electrode is controlled in 60-100nm;
Negative electrode uses after the completion of hole transmission layer preparation, and one end of perovskite solar cell device 102 is scraped, Gold is used as negative electrode exit 103, using the transparent conductive layer of glass substrate 101 as negative electrode.
Step 2: silicon nitride protective layer 105 is prepared on perovskite solar cell device 102:
Silicon nitride protective layer 105 is carried out using in PECVD filming equipment at 102 back side of perovskite solar cell device Preparation, technological temperature are 50-80 DEG C, deposition thickness 50-80nm.
Step 3: using in glove box nitrogen atmosphere, applying equal edge in 102 surrounding of perovskite solar cell device and seal Glue 106 is filled, edge seal glue 106 uses epoxide resin AB component glue;Cover glass backboard 107 adds on edge seal glue 106 Overlay conjunction, static 4h.
The principles of the present invention are: using the fabulous thin layer of sin of chemical stability to perovskite solar battery into The protection of row first layer carries out physical barrier to the intrusion of water, oxygen;Using pressurizing attaching glass back plate under nitrogen environment to perovskite Solar battery carries out second layer protection, has further prevented the ability of perovskite solar battery barrier water, oxygen, while glass The addition of backboard increases the ability of encapsulating structure antiskid, wiping.

Claims (8)

1. a kind of perovskite solar cell encapsulation structure, which is characterized in that including be coated with conductive layer glass substrate (101), Perovskite solar cell device (102), glass back plate (107) and edge seal glue (106);Perovskite solar cell device (102) face down is arranged on the conductive layer of glass substrate (101);Glass back plate (107) is arranged in perovskite solar-electricity The top of pond device (102);Glass back plate (107) and perovskite solar cell device (102) edge setting edge seal It fills glue (106).
2. a kind of perovskite solar cell encapsulation structure according to claim 1, which is characterized in that glass back plate (107) it is equipped with cavity between perovskite solar cell device (102), is filled with inert gas in cavity.
3. a kind of perovskite solar cell encapsulation structure according to claim 1, which is characterized in that further include silicon nitride Protective layer (105), silicon nitride protective layer (105) are arranged at the back side of perovskite solar cell device (102).
4. a kind of perovskite solar cell encapsulation structure according to claim 1, which is characterized in that perovskite solar energy Battery device (102) includes the electron transfer layer set gradually from bottom to top, perovskite active layer, hole transmission layer and positive electricity Pole.
5. a kind of perovskite solar cell encapsulation structure according to claim 4, which is characterized in that glass substrate (101) negative electrode of the conductive layer as perovskite solar cell device (102), conductive layer are transparent conductive layer.
6. a kind of perovskite solar cell encapsulation structure according to claim 4, which is characterized in that electron transfer layer is Thin layer of tin oxide, with a thickness of 20-50nm.
7. a kind of perovskite solar cell encapsulation structure according to claim 4, which is characterized in that positive electricity extremely aluminium Layer, silver layer or layer gold, with a thickness of 60-100nm.
8. a kind of perovskite solar cell encapsulation structure according to claim 5, which is characterized in that further include positive electrode Exit (104), negative electrode exit (103);Positive electrode exit (104) is arranged in perovskite solar cell device (102) one end, positive electrode exit (104) are connect with positive electrode;Negative electrode exit (103) is arranged in perovskite solar energy The other end of battery device (102), negative electrode exit (103) are connect with negative electrode.
CN201821979458.6U 2018-11-28 2018-11-28 A kind of perovskite solar cell encapsulation structure Active CN208923201U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109411611A (en) * 2018-11-28 2019-03-01 中国华能集团有限公司 A kind of perovskite solar cell encapsulation structure and packaging method
WO2021205336A1 (en) * 2020-04-06 2021-10-14 Elixens Photovoltaic module and method for manufacturing such a module
EP4243103A4 (en) * 2021-04-13 2024-06-12 Contemporary Amperex Technology Co., Limited Perovskite solar cell and preparation method therefor, and electrical device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109411611A (en) * 2018-11-28 2019-03-01 中国华能集团有限公司 A kind of perovskite solar cell encapsulation structure and packaging method
CN109411611B (en) * 2018-11-28 2024-07-02 中国华能集团有限公司 Perovskite solar cell packaging structure and packaging method
WO2021205336A1 (en) * 2020-04-06 2021-10-14 Elixens Photovoltaic module and method for manufacturing such a module
EP4243103A4 (en) * 2021-04-13 2024-06-12 Contemporary Amperex Technology Co., Limited Perovskite solar cell and preparation method therefor, and electrical device

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