CN208923144U - A kind of silicon germanium tin high electron mobility transistor - Google Patents

A kind of silicon germanium tin high electron mobility transistor Download PDF

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Publication number
CN208923144U
CN208923144U CN201821596246.XU CN201821596246U CN208923144U CN 208923144 U CN208923144 U CN 208923144U CN 201821596246 U CN201821596246 U CN 201821596246U CN 208923144 U CN208923144 U CN 208923144U
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silicon
gesn
electron mobility
germanium tin
layer
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汪巍
方青
涂芝娟
曾友宏
蔡艳
王庆
王书晓
余明斌
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Shanghai Industrial Utechnology Research Institute
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Shanghai New Micro Technology Service Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/16Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
    • H01L29/161Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System including two or more of the elements provided for in group H01L29/16, e.g. alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/778Field effect transistors with two-dimensional charge carrier gas channel, e.g. HEMT ; with two-dimensional charge-carrier layer formed at a heterojunction interface

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Junction Field-Effect Transistors (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The application provides a kind of silicon germanium tin high electron mobility transistor, which includes: silicon-based substrate;Buffer layer in the silicon-based substrate;Channel layer on the buffer layer, the channel layer are germanium tin (GeSn) material;And the wall on the channel layer, barrier layer and cap rock, the wall, barrier layer and cap rock are III-V group semi-conductor material, wherein the interface of the wall and channel layer forms two-dimensional electron gas, and the buffer layer thickness is greater than 500nm.According to the present embodiment, the high speed performance of transistor can be improved, also, GeSn is easy to integrate with Si base ic manufacturing technology.

Description

A kind of silicon germanium tin high electron mobility transistor
Technical field
This application involves technical field of semiconductors more particularly to a kind of silicon germanium tin high electron mobility transistor.
Background technique
High speed that high electron mobility transistor (HEMT, High Electron Mobility Transistor) has, The excellent properties such as high frequency, low noise are the mainstream microwave devices for realizing 5G communication, high frequency satellite communication.
It is high as the iii-v of representative using GaAs, indium phosphide as semiconductor application is constantly to microwave (high frequency) Duan Tuozhan Transport factor material shows huge superiority, is able to satisfy high speed, the high frequency demand of information processing.
It should be noted that the above description of the technical background be intended merely to it is convenient to the technical solution of the application carry out it is clear, Complete explanation, and facilitate the understanding of those skilled in the art and illustrate.Cannot merely because these schemes the application's Background technology part is expounded and thinks that above-mentioned technical proposal is known to those skilled in the art.
Summary of the invention
In the prior art, III-V material manufacturing cost is all very high, and can cause environmental problem, and be difficult to It is integrated with silicon (Si) base ic manufacturing technology.
The embodiment of the present application provides a kind of silicon germanium tin (GeSn) high electron mobility transistor and its manufacturing method, in silicon It is formed on base substrate and high electron mobility transistor is prepared by germanium tin (GeSn) material, thereby, it is possible to improve the high speed of transistor Performance, also, GeSn is easy to integrate with Si base ic manufacturing technology.
According to the one aspect of the embodiment of the present application, a kind of silicon germanium tin (GeSn) high electron mobility transistor is provided, Include:
Silicon-based substrate;
Buffer layer in the silicon-based substrate;
Channel layer on the buffer layer, the channel layer are germanium tin (GeSn) material;And
Wall on the channel layer, barrier layer and cap rock, the wall, barrier layer and cap rock are III-V Race's semiconductor material, wherein the interface of the wall and channel layer forms two-dimensional electron gas, and the buffer layer thickness is greater than 500nm。
According to the other side of the embodiment of the present application, wherein the material of the silicon-based substrate is on silicon or insulator Silicon, the cushioning layer material are germanium or germanium silicon (SiGe).
According to the other side of the embodiment of the present application, wherein the material of the channel layer is Ge(1-x)Snx, wherein 0.06<x<0.3。
According to the other side of the embodiment of the present application, wherein the material of the wall, barrier layer and cap rock is indium aluminium Phosphorus (InAlP), indium aluminium arsenic (InAlAs), indium gallium phosphorus (InGaP) or indium gallium arsenic (InGaAs).
According to the other side of the embodiment of the present application, wherein the wall is undoped, the barrier layer and the lid Layer adulterates, also, the doping concentration of the cap rock is higher than the doping concentration of the barrier layer.
According to the other side of the embodiment of the present application, wherein the barrier layer is connect with gate electrode, the cap rock and source Electrode is connected with drain electrode.
The beneficial effects of the present application are as follows: it is formed in silicon-based substrate and high electron mobility is prepared by germanium tin (GeSn) material Transistor, thereby, it is possible to improve the high speed performance of transistor, also, GeSn is easy to integrate with Si base ic manufacturing technology.
Referring to following description and accompanying drawings, specific implementations of the present application are disclosed in detail, specify the original of the application Reason can be in a manner of adopted.It should be understood that presently filed embodiment is not so limited in range.In appended power In the range of the spirit and terms that benefit requires, presently filed embodiment includes many changes, modifications and is equal.
The feature for describing and/or showing for a kind of embodiment can be in a manner of same or similar one or more It uses in a other embodiment, is combined with the feature in other embodiment, or the feature in substitution other embodiment.
It should be emphasized that term "comprises/comprising" refers to the presence of feature, one integral piece, step or component when using herein, but simultaneously It is not excluded for the presence or additional of one or more other features, one integral piece, step or component.
Detailed description of the invention
Included attached drawing is used to provide that a further understanding of the embodiments of the present application, and which constitute one of specification Point, for illustrating presently filed embodiment, and with verbal description come together to illustrate the principle of the application.Under it should be evident that Attached drawing in the description of face is only some embodiments of the present application, for those of ordinary skill in the art, is not paying wound Under the premise of the property made is worked, it is also possible to obtain other drawings based on these drawings.In the accompanying drawings:
Fig. 1 is a schematic diagram of the silicon germanium tin high electron mobility transistor of the embodiment of the present application 1;
Fig. 2 is a schematic diagram of the manufacturing method of the silicon germanium tin high electron mobility transistor of the embodiment of the present application 2;
Fig. 3 (a)-Fig. 3 (d) is the corresponding device sectional view of each step in the embodiment of the present application 2.
Specific embodiment
Referring to attached drawing, by following specification, the aforementioned and other feature of the application be will be apparent.In specification In attached drawing, specific implementations of the present application are specifically disclosed, which show wherein can be using the portion of the principle of the application Divide embodiment, it will thus be appreciated that the application is not limited to described embodiment, on the contrary, the application includes falling into appended power Whole modifications, modification and equivalent in the range of benefit requirement.
In the explanation of each embodiment of the application, for convenience of description, the direction for being parallel to the main surface of silicon-based substrate is claimed For " transverse direction ", the direction that will be perpendicular to the main surface of silicon-based substrate is known as " longitudinal direction ".
Embodiment 1
The embodiment of the present application provides a kind of silicon germanium tin (GeSn) high electron mobility transistor.
Fig. 1 is a schematic diagram of silicon germanium tin (GeSn) high electron mobility transistor of the present embodiment, such as Fig. 1 institute Show, which includes: silicon-based substrate 11;Buffer layer 12 in silicon-based substrate 11;Position In the channel layer 13 on buffer layer 12, channel layer 13 is the preparation of germanium tin (GeSn) material;Wall 14 on channel layer 13, Barrier layer 15 and cap rock 16, wherein wall 14, barrier layer 15 and cap rock 16 are III-V group semi-conductor material, and buffer layer 12 is thick Degree is greater than 500nm.
In the present embodiment, wall 14 and channel layer 13 form III-V/GeSn hetero-junctions, and in the III-V/GeSn Conduction band band rank is formed in hetero-junctions, and III- is controlled by the Schottky barrier under gate electrode 17 to generate two-dimensional electron gas Two-dimensional electron gas in V/GeSn hetero-junctions, to realize the control of electric current.Since there is GeSn material high electronics to move Shifting rate, and two-dimensional electron gas is spatially separated with the impurity center that is in III-V layers, and not by ionized impurity scattering Influence, it is possible to realize high mobility.
According to the present embodiment, is formed in silicon-based substrate and high electron mobility transistor is prepared by germanium tin (GeSn) material, Thereby, it is possible to improve the high speed performance of transistor, also, GeSn is easy to integrate with Si base ic manufacturing technology.And existing Have in technology, there are no the technical solutions about GeSn high electron mobility transistor, more without silicon substrate GeSn high electron mobility The relevant report of rate transistor.
In the present embodiment, the material of silicon-based substrate 11 is the silicon (SOI) on silicon (Si) or insulator.The silicon-based substrate 11 Surface be, for example, (111) crystal face.
In the present embodiment, the material of buffer layer 12 is germanium (Ge) or germanium silicon (SiGe).The buffer layer 12 can buffer Mismatch between the lattice on the surface of silicon-based substrate 11 and the lattice of channel layer 13, to improve the quality of channel layer 13.
In the present embodiment, germanium tin (GeSn) material of channel layer 13 can be expressed as Ge(1-x)Snx, wherein 0.06 < x < 0.3。
The band structure of germanium tin (GeSn) is adjusted with Sn component, and when Sn component is greater than 6%, GeSn will be realized indirectly Band gap material is to the transformation of direct band gap material, also, when GeSn becomes direct band gap material, electron mobility is much larger than Si and Ge material.
Therefore, in the present embodiment, the component of Sn in germanium tin (GeSn) material of channel layer 13 is controlled and is arrived 6% 30%, germanium tin (GeSn) material of channel layer 13 can be made to become direct band gap material, so that the electronics improved in channel layer moves Shifting rate.
In the present embodiment, the III-V material of wall 14, barrier layer 15 and cap rock 16 can be the germanium with channel layer 13 The Lattice Matching of tin (GeSn) material or the material of approximate match, wherein by adjusting the component of each element in III-V material, It can make III-V material lattice constant and GeSn material lattice is matched or approximate match.The III-V material for example can be with It is indium aluminium phosphorus (InAlP), indium aluminium arsenic (InAlAs), indium gallium phosphorus (InGaP) or indium gallium arsenic (InGaAs).In addition it is also possible to be Other III-V group materials.
In the present embodiment, wall 14 is undoped, to avoid the movement of two-dimensional electron gas by the scattering of impurity It influences.
In the present embodiment, barrier layer 15 is connect with gate electrode 17, and cap rock 16 is connect with source electrode 18 and drain electrode 19.
In the present embodiment, barrier layer 15 and cap rock 16 adulterate, consequently facilitating with gate electrode, source electrode, drain electrode shape At contact.In addition, in the present embodiment, the doping concentration of cap rock 16 can be higher than the doping concentration of barrier layer 15.
According to the present embodiment, is formed in silicon-based substrate and high electron mobility transistor is prepared by germanium tin (GeSn) material, It is easy and Si base IC manufacturing skill thereby, it is possible to improve the high speed performance of transistor, also, as the GeSn of four race's materials Art is integrated.
Embodiment 2
Embodiment 2 provides a kind of manufacturing method of silicon germanium tin high electron mobility transistor, for manufacturing 1 institute of embodiment The silicon germanium tin high electron mobility transistor stated.
Fig. 2 is a schematic diagram of the manufacturing method of the silicon germanium tin high electron mobility transistor of the present embodiment, such as Fig. 2 Shown, in the present embodiment, which may include:
Step 201 forms buffer layer in silicon-based substrate;
Step 202 forms channel layer on the buffer layer, and the channel layer is germanium tin (GeSn) material;And
Step 203 forms wall, barrier layer and cap rock, the wall, barrier layer and cap rock on the channel layer For III-V group semi-conductor material, wherein the interface of the wall and channel layer is formed with two-dimensional electron gas,
Step 204, the etching cap rock, to expose the barrier layer;
Step 205 forms gate electrode on the barrier layer of exposing;
Step 206 is respectively formed source electrode and drain electrode on the cap rock of the gate electrode two sides.
In the present embodiment, the material of the silicon-based substrate is the silicon on silicon or insulator, the cushioning layer material be germanium or Germanium silicon (SiGe).
In the present embodiment, the material of channel layer is Ge (1-x) Snx, wherein 0.06 < x < 0.3.
In the present embodiment, the material of wall, barrier layer and cap rock be indium aluminium phosphorus (InAlP), indium aluminium arsenic (InAlAs), Indium gallium phosphorus (InGaP) or indium gallium arsenic (InGaAs).Wherein, the wall is undoped, and the barrier layer and the cap rock adulterate, and And the doping concentration of the cap rock is higher than the doping concentration of the barrier layer.
In the following, illustrating the manufacture of the silicon germanium tin high electron mobility transistor of the application in conjunction with a specific example Method.
Fig. 3 is the corresponding device sectional view of each step in the example, as shown in figure 3, in this example, silicon germanium tin (GeSn) manufacturing method of high electron mobility transistor includes the following steps:
Step 1: as shown in Fig. 3 (a), 11 surface of Si substrate after cleaning, using two step chemical gaseous phase of low temperature and high temperature Deposition method, successively epitaxial growth Ge buffer layer 12 and GeSn channel layer 13, wherein 12 thickness of Ge buffer layer > 500nm, GeSn Sn group is divided into 10%, GeSn channel layer, 13 thickness > 300nm in channel layer 13, wherein GeSn channel layer 13 undopes.
Step 2: as shown in Fig. 3 (b), epitaxial growth eigen I n1-yAlyAs wall 14, y=0.72, thickness~2nm;Outside Prolong growing n-type In1-yAlyAs barrier layer 15, y=0.72, thickness about 30nm, doping concentration 1*1018cm-3;Epitaxial growth heavy doping N-shaped In1-yAlyAs cap rock 16, y=0.72, thickness about 50nm, doping concentration 1*1019cm-3
Step 3: as shown in Fig. 3 (c), defining source and drain areas in cap rock 16 using photoetching and reactive ion etching technology 16a;In the barrier layer 15 exposed between source and drain areas 16a, area of grid is defined by photoetching and etching;Deposit gate electrode material Material, and gate electrode 17 is prepared by chemical wet etching.
Step 4: as shown in Fig. 3 (d), deposit source-drain electrode electrode material, and by chemical wet etching prepare source-drain electrode electrode 18, 19, complete device preparation.
According to the present embodiment, is formed in silicon-based substrate and high electron mobility transistor is prepared by germanium tin (GeSn) material, It is easy and Si base IC manufacturing skill thereby, it is possible to improve the high speed performance of transistor, also, as the GeSn of four race's materials Art is integrated.
Combine specific embodiment that the application is described above, it will be appreciated by those skilled in the art that this A little descriptions are all exemplary, and are not the limitation to the application protection scope.Those skilled in the art can be according to the application Spirit and principle various variants and modifications are made to the application, these variants and modifications are also within the scope of application.

Claims (6)

1. a kind of silicon germanium tin (GeSn) high electron mobility transistor, which is characterized in that the high electricity of the silicon germanium tin (GeSn) Transport factor transistor includes:
Silicon-based substrate;
Buffer layer in the silicon-based substrate;
Channel layer on the buffer layer, the channel layer are germanium tin (GeSn) material;And
Wall on the channel layer, barrier layer and cap rock, the wall, barrier layer and cap rock are iii-v half Conductor material,
Wherein,
The interface of the wall and channel layer forms two-dimensional electron gas,
The buffer layer thickness is greater than 500nm.
2. silicon germanium tin (GeSn) high electron mobility transistor as described in claim 1, which is characterized in that
The material of the silicon-based substrate is the silicon on silicon or insulator,
The cushioning layer material is germanium or germanium silicon (SiGe).
3. silicon germanium tin (GeSn) high electron mobility transistor as described in claim 1, which is characterized in that
The material of the channel layer is Ge(1-x)Snx, wherein 0.06 < x < 0.3.
4. silicon germanium tin (GeSn) high electron mobility transistor as described in claim 1, which is characterized in that
The material of the wall, barrier layer and cap rock is indium aluminium phosphorus (InAlP), indium aluminium arsenic (InAlAs), indium gallium phosphorus (InGaP) Or indium gallium arsenic (InGaAs).
5. silicon germanium tin (GeSn) high electron mobility transistor as described in claim 1, which is characterized in that
The wall is undoped, and the barrier layer and the cap rock adulterate, also, the doping concentration of the cap rock is higher than institute State the doping concentration of barrier layer.
6. silicon germanium tin (GeSn) high electron mobility transistor as described in claim 1, which is characterized in that the barrier layer It is connect with gate electrode,
The cap rock is connect with source electrode and drain electrode.
CN201821596246.XU 2018-09-27 2018-09-27 A kind of silicon germanium tin high electron mobility transistor Active CN208923144U (en)

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CN201821596246.XU CN208923144U (en) 2018-09-27 2018-09-27 A kind of silicon germanium tin high electron mobility transistor
PCT/CN2019/070518 WO2020062706A1 (en) 2018-09-27 2019-01-05 Silicon-based germanium-tin transistor with high electron mobility

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CN100511706C (en) * 2007-09-29 2009-07-08 西安电子科技大学 GaN device based on component-gradient GaN MISFET and preparing method thereof
KR101890749B1 (en) * 2011-10-27 2018-08-23 삼성전자주식회사 Electrode structure, gallium nitride based semiconductor device including the same and methods of manufacturing the same
CN103594506B (en) * 2012-08-16 2017-03-08 中国科学院微电子研究所 Semiconductor device
CN103311306A (en) * 2013-06-26 2013-09-18 重庆大学 GeSn channel metal-oxide-semiconductor field-effect transistor with InAlP cover layer

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Patentee before: SHANGHAI INTERNATIONAL MICRO-TECH AFFILIATION CENTER