Utility model content
In order to overcome drawbacks described above, the utility model provides a kind of system freezed using steam condensate waste heat,
The system generates refrigerant liquefied ammonia required for refrigeration process using the by-product steam condensate (SC) generated in calcination process, makes
It obtains waste heat to be recycled, has saved cost, reduced energy consumption.
The utility model is to solve technical solution used by its technical problem:
A kind of system freezed using steam condensate waste heat, including generator, evaporative condenser, Outer Cooler,
Ammonia scrubber and exchanger, the generator is equipped with steam condensate import and steam condensate outlet, in the generator
The ammonia for being heated generation enters evaporative condenser by ammonia pipeline, and ammonia is condensed into liquefied ammonia by evaporative condenser
And storage of described liquefied ammonia is entered by liquefied ammonia pipeline, the liquefied ammonia in the storage of described liquefied ammonia enters Outer Cooler by pipeline, and liquefied ammonia is by outer cold
Become low pressure ammonia after device heat absorption and enter ammonia scrubber, the poor ammonia solution in the ammonia scrubber becomes after absorbing low pressure ammonia
Rich ammonia solution, the richness ammonia solution are pumped into exchanger by rich solution force (forcing) pump, enter generator, the generation after absorbing heat in exchanger
Poor ammonia solution in device enters ammonia scrubber after exchanger is cooling.
Preferably, cooler is additionally provided between exchanger and ammonia scrubber, the poor ammonia solution come out from exchanger
Enter ammonia scrubber after the cooler further cools down.
Preferably, the cooler is water cooling exchanger, which is equipped with the inlet and outlet of recirculated water.
Preferably, the ammonia scrubber is also connected with a lean solution circulating pump, and the lean solution circulating pump is for following poor ammonia solution
Spray into ammonia scrubber to ring.
Preferably, the ammonia in the generator passes sequentially through that enter vaporation-type after primary filter and gas-liquid separator cold
Condenser.
Preferably, the primary filter is set to the top of generator, the drop separated in the gas-liquid separator
It is returned in the generator by pipeline.
Preferably, the ammonia scrubber is equipped with fluid level controller, is arranged in steam condensate inlet ductwork automatic
Regulating valve, the automatic regulating valve can be according to the uninterrupteds of the temperature automatic adjustment steam condensate in generator.
The beneficial effects of the utility model are:
1) this system is cooled down using the waste heat of steam condensate to carry out pressure-raising to low-pressure ammonia again, to obtain high-pressure liquid ammonia confession
Freeze to Outer Cooler, thus traditional high-power ammonia refrigerating compressor is substituted, to realize energy-efficient beneficial effect;
2) using 150 DEG C or so of high temperature condensate liquid of calcination process output in this system, by freezing process waste heat benefit
With rear, temperature is down to 100 DEG C hereinafter, therefore avoiding former 150 DEG C of condensate liquids during long distance delivery due to vapor flash
It phenomena such as pipe vibration of generation, noise, excessively high moment pressure, is brought so as to cause rupture and water attack (water hammer) effect of pipe
The safety in production hidden danger such as great destructiveness, the condensate liquid after this cooling first cool down with boiler feedwater heat exchange, then with desalted water
Raw water heat exchange cooling is not needed to be further added by the cooling device with recirculated water, be saved into purification mixed bed as the water supply of boiler
Cost reduces energy consumption;
3) novel polynary refrigeration working medium is used in this system in ammonia solution, this polynary refrigeration working medium includes lithium nitrate, hydrogen
The components such as potassium oxide, amides compound, lithium chromate have when to the solubility of ammonia, big, working medium gasification temperature height evaporates not
It is easily taken out of with gas and the advantages that physical and chemical performance is highly stable, will need to complete by helical-lobe compressor originally using this working medium
Compressible gas by pressure-raising process be changed into incompressible liquid boosting, substantially subtract while efficiently using heat sources
Electric energy loss is lacked;
4) this system is conducive to promoting the use using recycling new technologies of low-grade heat sources such as waste heat and waste heat, reduces
The operation cost of user has good energy-saving and emission-reduction demonstration effect and social benefit in chemical field.
Embodiment: as shown in Figure 1, a kind of system freezed using steam condensate waste heat, including generator 10, steaming
Hairdo condenser 20, Outer Cooler 30, ammonia scrubber 40 and exchanger 50, the generator 10 be equipped with steam condensate into
Mouthful and steam condensate outlet, the ammonia that generation is heated in the generator 10 evaporative condenser is entered by ammonia pipeline
20, ammonia is condensed into liquefied ammonia by evaporative condenser and enters storage of described liquefied ammonia 21 by liquefied ammonia pipeline, the storage of described liquefied ammonia 21
In liquefied ammonia Outer Cooler 30 is entered by pipeline, liquefied ammonia becomes low pressure ammonia after Outer Cooler absorbs heat and enters ammonia scrubber
40, the poor ammonia solution in the ammonia scrubber 40 becomes rich ammonia solution after absorbing low pressure ammonia, which is added by rich solution
Press pump 42 is pumped into exchanger 50, and generator 10 is entered after absorbing heat in exchanger, and the poor ammonia solution in the generator 10 is by handing over
Enter ammonia scrubber 40 after parallel operation 50 is cooling.The remaining of 150 DEG C of saturated vapor condensed waters of calcination process by-product is utilized in this system
Heat cools down again to low-pressure ammonia pressure-raising, obtains high-pressure liquid ammonia and uses for Outer Cooler, thus instead of the ammonia refrigeration of one big function rate
Compressor realizes energy-efficient effect.By taking calcination process generates 120 tons of 150 DEG C of saturated vapor condensed waters per hour as an example, steam
Condensed water is cooled to 90 DEG C from 150 DEG C and produces 8500Kw heat, and energy a part is used to compress 0.4MPa low pressure gas ammonia
To the high pressure gas ammonia of 1.3MPa, numerical value about 1600Kw;Its excess heat is used to the solvent of ammonia solution carrying out heat temperature raising repeatedly.
Novel polynary refrigeration working medium is used in this system in ammonia solution, the compressible gas that will need to complete by helical-lobe compressor originally
Body is changed into incompressible liquid boosting by pressure-raising process, and electric energy damage is greatly reduced while efficiently using heat sources
Consumption.
Further, it is additionally provided with cooler 60 between exchanger 50 and ammonia scrubber 40, is come out from exchanger 50
Poor ammonia solution after the cooler further cools down enter ammonia scrubber 40.The effect of exchanger 50 is to inhale from ammonia
The low temperature richness ammonia solution received in device carries out heat exchange with the poor ammonia solution of high temperature in generator, and rich ammonia solution adds by rich solution
Press pump 42 reaches 1.3MPa after boosting, and generator is entered after exchanger heats up, and the pressure of generator is 1.3MPa, therefore from
The poor ammonia solution come out in generator overcomes resistance to reach ammonia scrubber enough.The cooler 60 is water cooling exchanger, should
Cooler is equipped with the inlet and outlet of recirculated water.Poor ammonia solution is further cooled down in cooler by recirculated cooling water
Afterwards, into ammonia scrubber, to be conducive to absorption of the poor ammonia solution to ammonia.
The ammonia scrubber 40 is also connected with a lean solution circulating pump 41, and the lean solution circulating pump 41 is for following poor ammonia solution
Spray into ammonia scrubber to ring.The lean solution circulating pump 41 effect is to improve sprinkle density, is conducive to suction of the solvent to ammonia
It receives.Ammonia in the generator 10 enters evaporative condenser after passing sequentially through primary filter 11 and gas-liquid separator 12
20.The primary filter 11 is set to the top of generator 10, and the drop separated in the gas-liquid separator 12 passes through pipe
Road returns in the generator 10.The primary filter 11 is to be used to filter out the mist in ammonia, gas-liquid separation except mist device
Device 12 further comes out the drop separation carried in ammonia, the content liquid drop after above-mentioned twice filter in ammonia
To 0.1ppmw hereinafter, to improve subsequent refrigerating efficiency.Gas-liquid separator is limited using quite your filter in the present embodiment
The product of company.
The ammonia scrubber 40 is equipped with fluid level controller, and automatic adjustment is arranged in steam condensate inlet ductwork
Valve, the automatic regulating valve can be according to the uninterrupteds of the temperature automatic adjustment steam condensate in generator 10.It uses herein
Automation control, automatic regulating valve is interior to be equipped with software control system, and the thermometer in this software control system and generator is electrical
Connection, software control system adjust automatic adjustment valve according to this temperature after the temperature obtained in generator in thermometer
Aperture, to ensure that the stability to exchange heat in generator, this automation control is routine techniques, is not done herein further
It is described in detail.For the protection to rich solution force (forcing) pump 42, fluid level controller is loaded on ammonia scrubber, to guarantee force (forcing) pump
There are enough suction heads, prevent the generation of cavitation and the lubricating fluid of bearing is made to have enough pressure;In rich solution force (forcing) pump
It is equipped with load-relay in 42 circuit, temperature relay, load-relay are installed on the outlet conduit of rich solution force (forcing) pump 42
For playing the role of protection to motor and impeller etc.;Temperature relay is used to prevent lubricating oil temperature is excessively high from damage bearing
It is bad;In order to guarantee the safety operation of system, it can also be equipped with a spare rich solution force (forcing) pump.
The refrigerating method of the utility model:
As shown in Fig. 2, a kind of method freezed using steam condensate waste heat, steps are as follows:
Step 1: 150 DEG C of by-product or so of saturated vapor of the calcination process come enters generation by condensate liquid import
Device 10 heats the rich ammonia solution in generator, makes ammonia and poor ammonia solution, and ammonia is entered by ammonia pipeline
The poor ammonia solution of evaporative condenser 20, high temperature enters exchanger 50;
Step 2: ammonia is cooled to saturation liquefied ammonia by evaporative condenser 20, which is flow automatically by liquefied ammonia pipeline
Enter storage of described liquefied ammonia 21, is sent using the pressure of storage of described liquefied ammonia itself into Outer Cooler 30 and freezed;
Step 3: liquefied ammonia absorbs heat in Outer Cooler 30 to be become entering ammonia scrubber 40 after low pressure ammonia, and ammonia is inhaled
Receiving after the poor ammonia solution in device absorbs low pressure ammonia becomes rich ammonia solution;
Step 4: the rich ammonia solution in ammonia scrubber 40 is pumped into exchanger 50 by rich solution force (forcing) pump 42, with high temperature
Poor ammonia solution enters generator 10 after carrying out heat exchange, repeats step 1 richness ammonia solution and is recycled;
Step 5: the poor ammonia solution in generator 10 enters cooler after exchanger 50 is cooling and further cools down, then
Into ammonia scrubber 40, repeats the poor ammonia solution of step 3 and be recycled.150 DEG C or so of high temperature saturated vapor condensate liquid
By heating to rich ammonia solution, 100 DEG C itself are reduced to hereinafter, and the low-boiling ammonia evaporation of major part in rich ammonia solution
Become high pressure ammonia out, rich ammonia solution becomes poor ammonia solution because most ammonia is evaporated, and poor ammonia solution passes through
Enter after exchanger 50 (carrying out heat exchange with rich ammonia solution) and cooler 60 (using cooling water that poor ammonia solution is cooling) cooling
Ammonia scrubber 40, the poor ammonia solution after being cooled down are more conducive to the absorption of ammonia, and high pressure ammonia passes through 20 He of evaporative condenser
After Outer Cooler 30, become low pressure ammonia and enter ammonia scrubber 40 being absorbed by poor ammonia solution, so as to become rich ammonia molten for poor ammonia solution
Liquid, rich ammonia solution enter generator 10 after exchanger 50 absorbs the heat of poor ammonia solution, and in the whole process, saturation is steamed
The waste heat of vapour condensate liquid is utilized, and ammonia solution is recycled.
Wherein, in step 1, the ammonia in generator 10 is removed by being set to the primary filter 11 at the top of generator
After mist, then the micro drop by being carried in the removing ammonia of gas-liquid separator 12, finally enter evaporative condenser 20.In step
In rapid three, the ammonia scrubber 40 is also connected with a lean solution circulating pump 41, and the lean solution circulating pump 41 is for recycling poor ammonia solution
Ground is sprayed into ammonia scrubber 40.
This system economic analysis:
1, the power consumption of this utilizing waste heat for refrigeration project calculates
1. the 2 circulating pump power consumptions of utilizing waste heat for refrigeration unit, unit internal circulation pump general power is 84 kW;
2. needing mating recirculated water 1560m3/ h, recirculated water energy consumption 0.035kWh/m3, circulating water cooling tower fan energy consumption is
1560m3/h×0.035kWh/m3=54.6kW;
3. water circulating pump energy consumption is about twice of blower, i.e. 109.2kW;
The total power consumption of UTILIZATION OF VESIDUAL HEAT IN unit: 84+54.6+109.2=247.8kW;
2, former a set of ammonia refrigerating compressor group power consumption calculates
1. ammonia refrigerating compressor group main motor rated power 1600kW;
2. Oil pump electrical machinery 15Kw in unit, Lubricating-oil Station motor 3Kw, total 18Kw;
3. unit is cooling using evaporative condenser, every set ammonia refrigerating compressor group is equipped with four specified heat exchange amounts and is
The evaporative condenser of 2000kW, every set condenser are equipped with the water pump of a 7.5kW, the blower of two 7.5kW power;
The condenser power consumption of single set unit: 7.5kWx4+7.5kWx8=90kW.
Former a set of total power consumption of ammonia refrigerating compressor: 1600+15+3+90=1708kW.
3, the power cost saved after system operation
Year economic benefit: (1708-247.8) × 8000 × 0.71=8293936 (member)
Wherein, the electricity charge are as follows: 0.71 yuan/degree, calculated by 8000 hours in year;It therefore, 1 year can by using this refrigeration system
To save more than 80 ten thousand power cost.
It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the premise utility,
Various modifications and improvements can be made, and these are all within the protection scope of the present invention.Therefore, the utility model patent
The scope of protection shall be subject to the appended claims.