CN208865367U - A kind of purifying exhausting gas of yellow phosphorus device - Google Patents

A kind of purifying exhausting gas of yellow phosphorus device Download PDF

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Publication number
CN208865367U
CN208865367U CN201821324542.4U CN201821324542U CN208865367U CN 208865367 U CN208865367 U CN 208865367U CN 201821324542 U CN201821324542 U CN 201821324542U CN 208865367 U CN208865367 U CN 208865367U
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China
Prior art keywords
tail gas
yellow
gas
phosphoric tail
scrubbing tower
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CN201821324542.4U
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Chinese (zh)
Inventor
向松
赵进
郑斌斌
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Co Ltd Of Yunnan Chemical Designing Institute
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Co Ltd Of Yunnan Chemical Designing Institute
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Abstract

The utility model discloses a kind of purifying exhausting gas of yellow phosphorus device, including yellow phosphoric tail gas inlet pipeline and the scrubbing tower connected with tangential direction, sprayer-washer I is additionally provided on the yellow phosphoric tail gas inlet pipeline, the middle part of the scrubbing tower is equipped with ring baffle, top is equipped with foam removal packing layer, is equipped with sprayer-washer II above foam removal packing layer.In the present invention, by the processed yellow phosphoric tail gas of purifying exhausting gas of yellow phosphorus device, fuel can be directly used as and produce chemical products as industrial chemicals.The utility model simple process, it is easy to use, the purification of the impurity such as dust, phosphorus, arsenic, fluorine, sulphur in phosphorus production in tail gas can be removed partial impurities, as various fuel and industrial chemicals.

Description

A kind of purifying exhausting gas of yellow phosphorus device
Technical field
The utility model belongs to phosphorus production equipment technical field, and in particular to generates during a kind of pair of phosphorus production The device of yellow phosphoric tail gas progress purified treatment.
Background technique
Yellow phosphorus is important the basic material of basic chemical raw materials and phosphorous chemical industry.Enterprise is most both at home and abroad at present All use producing yellow Phosphorus by electric oven.As soon as every production ton yellow phosphorus in its production process generates about 2700Nm simultaneously3Containing carbon monoxide 89~91% or more yellow phosphoric tail gas.
Yellow phosphoric tail gas mainly contains CO, and there are also impurity such as dust, phosphorus, sulphur, arsenic, fluorine, calorific value is up to~10000KJ/Nm3, it is A kind of good industrial chemicals and fuel.But current China's phosphorus production Enterprise Integrated utilizes horizontal lower, most of Yellow Phosphorous Plant The utilization rate of tail gas is only 30% or so, and a large amount of direct burning and exhausting of yellow phosphoric tail gas furnace gas causes greatly to pollute to environment. The Ministry of Industry and Information Technology's bulletin in 2008: implement " Yellow Phosphorus Industry entry criteria " from January 1st, 2009, it is desirable that phosphorus furnace exhaust gas It in line must not burn, it is necessary to realize that energy or resource utilization utilize, newly-built yellow phosphorus unit tail gas comprehensive utilization ratio must reach To 90% or more.But the impurity such as dust, phosphorus as contained in yellow phosphoric tail gas, sulphur, arsenic, fluorine, after being both needed to purification removing partial impurities It can utilize.
Currently, the purifying exhausting gas of yellow phosphorus device that most of phosphorus production enterprise uses, clean-up effect is not significant, largely effects on Purification efficiency can be greatly improved in the comprehensive utilization of yellow phosphoric tail gas, the exhaust gas cleaner of the utility model, reduce purification life Produce cost, it is ensured that the decontamination index of cleaning of off-gas.
Utility model content
To solve the above problems, the utility model provides a kind of purifying exhausting gas of yellow phosphorus device.
The utility model is realized using following technical scheme: a kind of purifying exhausting gas of yellow phosphorus device, including yellow phosphoric tail gas into Mouthful pipeline and the scrubbing tower connected with tangential direction are additionally provided with sprayer-washer I on the yellow phosphoric tail gas inlet pipeline, described The middle part of scrubbing tower is equipped with ring baffle, top is equipped with foam removal packing layer, is equipped with sprayer-washer II above foam removal packing layer.
The yellow phosphoric tail gas inlet pipeline is L-type pipe bucket, and the top of L-type pipe bucket is inlet exhaust gas, and the tail end of L-type pipe bucket is Gas-liquid mixed outlet, gas-liquid mixed outlet enter scrubbing tower using tangential swirl.
The wash tower bottoms are equipped with outlet of sewer.
When installing and using, yellow phosphoric tail gas flows into the utility model from yellow phosphoric tail gas inlet pipeline, through yellow phosphoric tail gas import After I spray washing of sprayer-washer in pipeline, along a tangential direction from scrubbing tower, from bottom to top, yellow phosphoric tail gas is removed as far as possible The solid particle polluter and drop of middle carrying reach gas-solid-liquid separation, and setting ring baffle prevents gas from being formed in the middle part of scrubbing tower Vortex, is uniformly distributed yellow phosphoric tail gas in scrubbing tower.Cleaning solution is entered by the top of scrubbing tower by sprayer-washer II, with Yellow phosphoric tail gas continues through the gap of the foam removal packing layer on scrubbing tower top in adverse current, and in filler surface, gas-liquid two-phase is close Contact carries out mass transfer and achievees the purpose that purification to remove the impurity such as the dust in yellow phosphoric tail gas, phosphorus, arsenic, fluorine, sulphur, final yellow Phosphorus tail gas flows out at the top of scrubbing tower.
In the present invention, the setting of yellow phosphoric tail gas inlet pipeline is in scrubbing tower lower part and along tangential direction air inlet, Sprayer-washer I is arranged in yellow phosphoric tail gas inlet pipeline, can carry out spray washing to yellow phosphoric tail gas, remove most of impurity.It is washing Tower top setting foam removal packing layer is washed, sprayer-washer II is set at the top of scrubbing tower, then carries out secondary washing, to improve Huang The clean-up effect of phosphorus tail gas clean-up.
The advantages of the utility model has and effect: in the present invention, processed by purifying exhausting gas of yellow phosphorus device Yellow phosphoric tail gas, can be directly used as fuel and as industrial chemicals produce chemical products.The utility model simple process, user Just, the purification of the impurity such as dust, phosphorus, arsenic, fluorine, sulphur in phosphorus production in tail gas can be removed partial impurities, as various combustions Material and industrial chemicals.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model;
Fig. 2 is the overlooking structure diagram of the utility model.
Specific embodiment
In order to be easy to understand the technical means, creative features, achievement of purpose, and effectiveness of the utility model, under Face combines and is specifically illustrating, and the utility model is further described.
As shown, purifying exhausting gas of yellow phosphorus device includes yellow phosphoric tail gas inlet pipeline 1 and washing with tangential direction connection Tower 2 is washed, sprayer-washer I 5 is additionally provided on the yellow phosphoric tail gas inlet pipeline 1, the middle part of the scrubbing tower 2 is equipped with ring baffle 3, top is equipped with foam removal packing layer 4, is equipped with sprayer-washer II 6 above foam removal packing layer 4.
The yellow phosphoric tail gas inlet pipeline 1 is L-type pipe bucket, and the top of L-type pipe bucket is inlet exhaust gas, the tail end of L-type pipe bucket For gas-liquid mixed outlet, gas-liquid mixed outlet enters scrubbing tower 2 using tangential swirl.
2 bottom of scrubbing tower is equipped with outlet of sewer.
When installing and using, yellow phosphoric tail gas flows into the utility model from yellow phosphoric tail gas inlet pipeline 1, through yellow phosphoric tail gas import After I 5 spray washing of sprayer-washer in pipeline 1, along a tangential direction from scrubbing tower 2, from bottom to top, yellow phosphorus tail is removed as far as possible The solid particle polluter and drop carried in gas reaches gas-solid-liquid separation, and setting ring baffle 3 prevents gas in the middle part of scrubbing tower 2 Vortex is formed, is uniformly distributed yellow phosphoric tail gas in scrubbing tower 2.Cleaning solution passes through sprayer-washer II 6 by the top of scrubbing tower 2 Into with yellow phosphoric tail gas in the gap for the foam removal packing layer 4 for countercurrently continuing through 2 top of scrubbing tower, in filler surface, gas-liquid Two-phase close contact carries out mass transfer and reaches the mesh of purification to remove the impurity such as the dust in yellow phosphoric tail gas, phosphorus, arsenic, fluorine, sulphur , final yellow phosphoric tail gas flows out at the top of scrubbing tower 2.
In the present invention, the setting of yellow phosphoric tail gas inlet pipeline 1 is in 2 lower part of scrubbing tower and along tangential direction air inlet, Sprayer-washer I 5 is set in yellow phosphoric tail gas inlet pipeline 1, spray washing can be carried out to yellow phosphoric tail gas, remove most of impurity. Foam removal packing layer 4 is set on scrubbing tower top, sprayer-washer II 6 is set at the top of scrubbing tower, then carries out secondary washing, thus Improve the clean-up effect of purifying exhausting gas of yellow phosphorus.
Basic principles, main features, and advantages of the present invention has been shown and described above.Current row The technical staff of industry is described in above embodiments and description it should be appreciated that the present utility model is not limited to the above embodiments Only illustrate the principles of the present invention, on the premise of not departing from the spirit and scope of the utility model, the utility model is also It will have various changes and improvements, these various changes and improvements fall within the scope of the claimed invention.The utility model Claimed range is defined by the appending claims and its equivalent thereof.

Claims (3)

1. a kind of purifying exhausting gas of yellow phosphorus device, it is characterised in that: connected including yellow phosphoric tail gas inlet pipeline and with tangential direction Scrubbing tower, sprayer-washer I is additionally provided on the yellow phosphoric tail gas inlet pipeline, the middle part of the scrubbing tower is equipped with annular gear Plate, top are equipped with foam removal packing layer, are equipped with sprayer-washer II above foam removal packing layer.
2. purifying exhausting gas of yellow phosphorus device according to claim 1, it is characterised in that: the yellow phosphoric tail gas inlet pipeline is L Type pipe bucket, the top of L-type pipe bucket are inlet exhaust gas, and the tail end of L-type pipe bucket is gas-liquid mixed outlet, and gas-liquid mixed outlet, which uses, cuts Enter scrubbing tower to eddy flow.
3. purifying exhausting gas of yellow phosphorus device according to claim 1, it is characterised in that: the wash tower bottoms go out equipped with sewage Mouthful.
CN201821324542.4U 2018-08-16 2018-08-16 A kind of purifying exhausting gas of yellow phosphorus device Active CN208865367U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821324542.4U CN208865367U (en) 2018-08-16 2018-08-16 A kind of purifying exhausting gas of yellow phosphorus device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821324542.4U CN208865367U (en) 2018-08-16 2018-08-16 A kind of purifying exhausting gas of yellow phosphorus device

Publications (1)

Publication Number Publication Date
CN208865367U true CN208865367U (en) 2019-05-17

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CN201821324542.4U Active CN208865367U (en) 2018-08-16 2018-08-16 A kind of purifying exhausting gas of yellow phosphorus device

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CN (1) CN208865367U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112933835A (en) * 2021-02-01 2021-06-11 北京首钢朗泽新能源科技有限公司 Fermentation tail gas washing system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112933835A (en) * 2021-02-01 2021-06-11 北京首钢朗泽新能源科技有限公司 Fermentation tail gas washing system

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