CN208829331U - A kind of nanofiltration removal organic matter system - Google Patents

A kind of nanofiltration removal organic matter system Download PDF

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Publication number
CN208829331U
CN208829331U CN201821100008.5U CN201821100008U CN208829331U CN 208829331 U CN208829331 U CN 208829331U CN 201821100008 U CN201821100008 U CN 201821100008U CN 208829331 U CN208829331 U CN 208829331U
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China
Prior art keywords
nanofiltration
organic matter
sections
booster pumps
water
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Expired - Fee Related
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CN201821100008.5U
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Chinese (zh)
Inventor
戴尚莉
袁萍
徐晴
张彩霞
李毓亮
刘晓敏
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HANGZHOU BEISITE ENERGY-SAVING AND ENVIRONMENT PROTECTION TECHNOLOGY Co Ltd
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HANGZHOU BEISITE ENERGY-SAVING AND ENVIRONMENT PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201821100008.5U priority Critical patent/CN208829331U/en
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Abstract

The utility model relates to a kind of nanofiltrations to remove organic matter system, belong to water prevention and cure of pollution field.The system includes that reservoir, nanofiltration system and nanofiltration produce pond;The nanofiltration system generates nanofiltration water to remove the organic matter in waste water;The nanofiltration produces pond to store nanofiltration water;The reservoir and nanofiltration system are interconnected, and the nanofiltration system and nanofiltration produce pond and be interconnected.The utility model retains the organic matter in waste water by nanofiltration system, realizes and removes to the separation of organic matter, protects the normal operation of the subsequent systems such as reverse osmosis in wastewater treatment.

Description

A kind of nanofiltration removal organic matter system
Technical field
The utility model relates to a kind of nanofiltrations to remove organic matter system, belong to water prevention and cure of pollution field.
Background technique
Coal-burning power plant recycles the organic matter containing higher concentration in effluent and desulfurization wastewater, since power plant effluent belongs to height Salt waste water, therefore organic matter can not be removed by biochemical mode.It is subsequent in the treatment of waste water but if not removing organic matter Reverse osmosis concentration unit can retain organic matter, and organic matter will be constantly enriched with after being trapped, so that membranous system generation is dirty stifled and broken It is bad.
In order to solve this problem, organic matter is removed using the mode of catalytic ozonation in the prior art, but it is this Method is poor to the removal effect of organic matter, and invests huge, and operating cost is high, consumes a large amount of liquid oxygen and electric energy.It is smelly Oxygen can the low substance of preferential selective redox current potential aoxidized, this moieties is mostly inorganic matter, itself will not be to film System impacts, although therefore ozonation system can remove a part of substance, be mostly not constitute a threat to membranous system Material part, the organic matters such as macromolecular, biomass are not still removed but.
Utility model content
The utility model in order to solve the above technical problems, provide it is a kind of it is reasonable in design, effectively remove receiving for organic matter It filters off and removes organic matter system.
The utility model solves technical solution used by above-mentioned technical problem:
A kind of nanofiltration removal organic matter system, including reservoir, nanofiltration system and nanofiltration produce pond;The nanofiltration system is used To remove the organic matter in waste water, and generate nanofiltration water;The nanofiltration produces pond to store nanofiltration water;The reservoir with receive Filter system is interconnected, and the nanofiltration system and nanofiltration produce pond and be interconnected.
The utility model retains the organic matter in waste water by nanofiltration system, realizes that the separation to organic matter removes, protection The normal operation of the subsequent systems such as reverse osmosis in wastewater treatment.
Further, the nanofiltration system includes nanofiltration membrane, for removing the organic matter in waste water.
Further, the nanofiltration system includes high-pressure pump, two sections of booster pumps and three sections of booster pumps, the high-pressure pump, two Section booster pump and three sections of booster pumps are sequentially communicated according to waste water flow direction;One is provided between the high-pressure pump and two sections of booster pumps Section nanofiltration membrane, is provided with two sections of nanofiltration membranes between two sections of booster pumps and three sections of booster pumps, sets after three sections of booster pumps It is equipped with three sections of nanofiltration membranes.
Further, nanofiltration removal organic matter system further includes the nanofiltration concentration after three sections of nanofiltration membranes are arranged in Pond, to store nanofiltration condensed water.
Further, nanofiltration elevator pump is additionally provided between the reservoir and nanofiltration system, the liquid to lifting waste water Position height.
Further, it is additionally provided with cartridge filter between the nanofiltration elevator pump and nanofiltration system, to filter.
The utility model compared with the existing technology has the following advantages that and effect:
1, the utility model realizes that the retention to organic matter removes, organic matter is individually disposed by using nanofiltration system, Nanofiltration protects subsequent reverse osmosis equal concentration systems, increases the stability of system, reduce to rejection >=90% of organic matter Cost of investment, while nanofiltration does not need very high energy consumption, compared to ozonation system, greatly reduce operating cost;
2, the utility model has operating cost compared to biological decomposition organic matter, catalytic ozonation decomposing organic matter Cheap advantage, while the utility model device is simple, investment is low, occupied area is small, is suitble to power plant's operation habit;
3, the utility model is unattended using nanofiltration system removal organic matter, and continuous operation does not need any medicament and throws Add, object without secondary pollution generates.
Detailed description of the invention
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is some embodiments of the utility model, for those of ordinary skill in the art, before not making the creative labor property It puts, is also possible to obtain other drawings based on these drawings.
Fig. 1 is the structural schematic diagram of the utility model.
Label declaration:
1, reservoir, 2, nanofiltration elevator pump, 3, cartridge filter, 4, high-pressure pump, 5, two sections of booster pumps, 6, three sections of pressurizations Pump, 7, nanofiltration production pond, 8, nanofiltration concentration pond.
Specific embodiment
The utility model belongs to water prevention and cure of pollution field, can be used for thermal power plant and discharges the manufacture of similar water pollutant, food Product, weaving, power plant, printing and dyeing, municipal administration, automobile, petrochemical industry, electronic semi-conductor's wastewater zero discharge, biofermentation wastewater zero discharge Deng.
Nanofiltration is also known as low pressure reverse osmosis, is a kind of emerging field of membrane separation technique, separating property is between reverse osmosis Between ultrafiltration, allow some inorganic salts and certain solvents through film, to achieve the effect that separation.
The utility model is done below with reference to the embodiment of power plant cycle sewerage and power plant desulfurization wastewater further detailed Describe in detail bright, following embodiment is the explanation to the utility model and the utility model is not limited to following embodiment.
Embodiment 1:
As shown in Figure 1, a kind of nanofiltration removes organic matter system, including reservoir 1, nanofiltration system and nanofiltration produce pond 7, press According to the processing sequence of waste water, reservoir 1, nanofiltration system and nanofiltration produce pond 7 and are sequentially communicated;Connection in the present embodiment both may be used It, can also be in such a way that other can connect and communicate by pipeline.
To remove waste water, (waste water in the present embodiment includes but are not limited to power plant cycle sewerage and electricity to nanofiltration system Factory's desulfurization wastewater) in organic matter, and generate nanofiltration water.
Nanofiltration produces pond 7 to store nanofiltration water, and nanofiltration produces pond 7 and nanofiltration system is interconnected.
Reservoir 1 is interconnected temporarily to store waste water, reservoir 1 and nanofiltration system.
The utility model retains the organic matter in waste water by nanofiltration system, realizes that the separation to organic matter removes, protection The normal operation of the subsequent systems such as reverse osmosis in wastewater treatment.
For power plant cycle sewerage, embodiment are as follows: Step 1: sodium hydroxide is added in reservoir 1 (and in blowdown The addition sodium carbonate of selectivity is added in water when basicity deficiency) soften, waste water carries out flocculation sedimentation in reservoir 1;Step 2: Waste water after precipitation process enters carry out hyperfiltration treatment, is then included in nanofiltration system and nanofiltration UF membrane generates nanofiltration water and receives Filter concentrated water;Step 3: nanofiltration water, which enters nanofiltration, produces pond 7, then nanofiltration water can enter the reverse osmosis concentration of subsequent wastewater treatment System, the desulfurization wastewater treatment system that nanofiltration concentrated water enters subsequent wastewater treatment are further processed.In the present embodiment, by 4 × 100m3The design of/h processing capacity, the nanofiltration rate of recovery are set as 95%, the retention of organic matter may be implemented by nanofiltration system, real Border operating parameter shows that nanofiltration system is higher than 90% to the removal efficiency of organic matter.
For the nanofiltration concentrated water generated in power plant desulfurization wastewater and above-mentioned power plant cycle sewerage, embodiment are as follows: step One, dosing softens in reservoir 1, and waste water carries out flocculation sedimentation in reservoir 1;Step 2: waste water after precipitation process into Enter nanofiltration system and carry out tubular type micro-filtration filtration treatment, nanofiltration UF membrane generates nanofiltration and produces water and nanofiltration concentrated water;Step 3: nanofiltration water Is produced from pond 7 into nanofiltration, then nanofiltration water can enter the reverse osmosis concentrated compression system of subsequent wastewater treatment, contain height in nanofiltration concentrated water Concentration organic, high concentration divalent salts, nanofiltration concentrated water water is smaller, is individually disposed using scheme in the prior art, Such as coal yard sprinkling, advanced oxidation, flue evaporation.In the present embodiment, by 3 × 25m3The design of/h processing capacity, nanofiltration recycling Rate is set as 65%, and the retention of organic matter may be implemented by nano-filtration unit, and actual operation parameters show nanofiltration system to organic The removal efficiency of object is higher than 90%.
Reverse osmosis concentrated compression system and desulfurization wastewater treatment system are common in existing wastewater treatment in the present embodiment System belongs to the prior art, and carrying out dosing softening also is means common in the art, not reinflated description herein.
Embodiment 2:
As described in Example 1, difference is only that nanofiltration system includes nanofiltration membrane, for removing the organic matter in waste water.
The aperture of nanofiltration membrane is to allow solvent molecule or certain low molecular weight solutes or low in 1nm or more, general 1-2nm A kind of functional semi-permeable membrane that valence ion penetrates, the molecular weight for retaining organic matter is about 150-500 or so, retains dissolubility The ability of salt is lower than high-valence anion salting liquid between 2-98%, to the desalination of monovalent anion salting liquid.
The form of the membrane module of nanofiltration membrane has doughnut, rolling, plate and frame and tubular type etc..Nanofiltration in the present invention The membrane module of film is tubular type.
In the processing of power plant cycle sewerage and in the processing of power plant desulfurization wastewater, used nanofiltration membrane is the same , but pressure environment locating for nanofiltration membrane is had any different, the pressure ratio power plant cycle blowdown of nanofiltration membrane in power plant desulfurization wastewater processing Wanting in water process is high, mainly has relationship with the concentration of waste water, concentration is higher, and osmotic pressure is bigger, and the external pressure needed is bigger.
Embodiment 3:
As described in Example 2, difference is only that nanofiltration system includes 4, two sections of booster pumps 5 of high-pressure pump and three sections of booster pumps 6,4, two sections of booster pumps 5 of high-pressure pump and three sections of booster pumps 6 are sequentially communicated according to waste water flow direction, i.e., high-pressure pump 4 is arranged in reservoir 1 Between two sections of booster pumps 5, two sections of booster pumps 5 are arranged between high-pressure pump 4 and three sections of booster pumps 6;Increase in high-pressure pump 4 and two sections It is provided with one section of nanofiltration membrane between press pump 5, is provided with two sections of nanofiltration membranes between two sections of booster pumps 5 and three sections of booster pumps 6, Three sections of nanofiltration membranes are provided with after three sections of booster pumps 6.4, two sections of booster pumps 5 of high-pressure pump and three sections of booster pumps 6 are nanofiltration system Pressure is provided.
In the present embodiment, the membrane module of one section of nanofiltration membrane, two sections of nanofiltration membranes and three sections of nanofiltration membranes is tubular type, and is existing There is technology, herein not reinflated description.
Embodiment 4:
As described in Example 3, difference be only that nanofiltration removal organic matter system further include setting three sections of nanofiltration membranes it Pond 8 is concentrated in nanofiltration afterwards, to store nanofiltration condensed water.
Embodiment 5:
As described in Example 1, difference, which is only that between reservoir 1 and nanofiltration system, is additionally provided with nanofiltration elevator pump 2, To facilitate waste water to enter nanofiltration system for waste water lifting liquid level.
Embodiment 6:
As described in Example 5, difference is only that is additionally provided with security personnel's filtering between nanofiltration elevator pump 2 and nanofiltration system Device 3 belongs to the prior art, is no longer developed in details herein to filter.
In addition, it should be noted that, the specific embodiments described in this specification, the shape of parts and components are named Title etc. can be different.All equivalent or simple changes done according to structure, feature and principle described in the concept of the patent of the utility model, It is included in the protection scope of the utility model patent.Those skilled in the art of the present invention can be to being retouched The specific embodiment stated does various modifications or additions or is substituted in a similar manner, without departing from the utility model Structure or beyond the scope defined by this claim, all should belong to the protection range of the utility model.

Claims (6)

1. a kind of nanofiltration removes organic matter system, it is characterised in that: produce pond including reservoir (1), nanofiltration system and nanofiltration (7);The nanofiltration system generates nanofiltration water to remove the organic matter in waste water;The nanofiltration produces pond (7) to store Nanofiltration water;The reservoir (1) and nanofiltration system are interconnected, and the nanofiltration system and nanofiltration produce pond (7) and be interconnected.
2. a kind of nanofiltration according to claim 1 removes organic matter system, it is characterised in that: the nanofiltration system includes receiving Filter membrane, for removing the organic matter in waste water.
3. a kind of nanofiltration according to claim 2 removes organic matter system, it is characterised in that: the nanofiltration system includes height Press pump (4), two sections of booster pumps (5) and three sections of booster pumps (6), the high-pressure pump (4), two sections of booster pumps (5) and three sections of booster pumps (6) it is sequentially communicated according to waste water flow direction;It is provided with one section of nanofiltration membrane between the high-pressure pump (4) and two sections of booster pumps (5), Two sections of nanofiltration membranes are provided between two sections of booster pumps (5) and three sections of booster pumps (6), are arranged after three sections of booster pumps (6) There are three sections of nanofiltration membranes.
4. a kind of nanofiltration according to claim 3 removes organic matter system, it is characterised in that: the nanofiltration removes organic system System further includes nanofiltration concentration pond (8) after three sections of nanofiltration membranes are arranged in, to store nanofiltration condensed water.
5. a kind of nanofiltration according to claim 1 removes organic matter system, it is characterised in that: the reservoir (1) with It is additionally provided between nanofiltration system nanofiltration elevator pump (2), the liquid level to lifting waste water.
6. a kind of nanofiltration according to claim 5 removes organic matter system, it is characterised in that: in the nanofiltration elevator pump (2) cartridge filter (3) are additionally provided between nanofiltration system, to filter.
CN201821100008.5U 2018-07-12 2018-07-12 A kind of nanofiltration removal organic matter system Expired - Fee Related CN208829331U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821100008.5U CN208829331U (en) 2018-07-12 2018-07-12 A kind of nanofiltration removal organic matter system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821100008.5U CN208829331U (en) 2018-07-12 2018-07-12 A kind of nanofiltration removal organic matter system

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112551760A (en) * 2020-12-22 2021-03-26 上海鲲谷环保科技有限公司 Method for removing iodine in wastewater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112551760A (en) * 2020-12-22 2021-03-26 上海鲲谷环保科技有限公司 Method for removing iodine in wastewater

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