CN208814849U - A kind of sewage decomposition apparatus of ortho-aminobenzoic acid - Google Patents

A kind of sewage decomposition apparatus of ortho-aminobenzoic acid Download PDF

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Publication number
CN208814849U
CN208814849U CN201821390166.9U CN201821390166U CN208814849U CN 208814849 U CN208814849 U CN 208814849U CN 201821390166 U CN201821390166 U CN 201821390166U CN 208814849 U CN208814849 U CN 208814849U
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China
Prior art keywords
tank
pipeline
contact
ortho
oxidation pool
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Expired - Fee Related
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CN201821390166.9U
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Chinese (zh)
Inventor
李波
王瑞琛
李卓
张起瞳
胡敏
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Linyi Huayi Chemical Technology Co Ltd
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Linyi Huayi Chemical Technology Co Ltd
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Priority to CN201821390166.9U priority Critical patent/CN208814849U/en
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  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The utility model provides a kind of sewage decomposition apparatus of ortho-aminobenzoic acid, wherein covering at the top of the acidification conditioning tank has shading tent, acidification conditioning tank side is equipped with air-introduced machine, is acidified inside conditioning tank and is equipped with aeration tube;Acidification conditioning tank is connect by pipeline with Fenton's reaction pond, and Fenton's reaction pond is connected with flocculation sedimentation tank through pipeline, and flocculation sedimentation tank is connect by pipeline with acidizing hydrolyzation tank;Acidizing hydrolyzation tank is connected with contact-oxidation pool through pipeline, filler is set in contact-oxidation pool, and catalytic oxidation bottom of pond portion is equipped with aeration tube;The contact-oxidation pool is connect by pipeline with line settling tank;Advantage are as follows: the utility model covers shading tent at the top of acidification conditioning tank, sunlight irradiation is avoided to occur rotten, waste water is handled through Fenton oxidation, make organic macromolecule flocculating setting in waste water by flocculation sedimentation tank, after acidified hydrolytic tank, contact-oxidation pool processing, ortho-aminobenzoic acid decomposition therein is transformed into small molecule nonhazardous substance, and waste water C0D removal rate reaches national emission standard.

Description

A kind of sewage decomposition apparatus of ortho-aminobenzoic acid
Technical field
The utility model relates to sewage device fields, more particularly, to a kind of sewage decomposition apparatus of ortho-aminobenzoic acid.
Background technique
A large amount of discharges of ortho-aminobenzoic acid waste water cause large-scale rivers water pollution.Ortho-aminobenzoic acid is dye The important intermediate and raw material of the fine chemical products such as material, medicine, fragrance and desinsection microbial inoculum, both at home and abroad in relation to o-amino benzoyl The processing method of sour waste water is similar to waste water containing phenolic acid class, such as oxidation, biochemical, extraction and absorption mostly.But because of adjacent aminobenzene The complicated component of formic acid wastewater, through traditional handicraft, treated that water cannot be removed effectively organic pollutant therein, in addition waste water It can change colour by sunlight irradiation, be unable to reach national emission standard.In addition the waste water in acid conditioning tank also has certain Peculiar smell influences the work in waste water station worker.
Summary of the invention
The purpose of this utility model is that solve the deficiencies in the prior art, and a kind of sewage of ortho-aminobenzoic acid is provided Decomposition apparatus.
The new technical solution of the utility model is: a kind of sewage decomposition apparatus of ortho-aminobenzoic acid, including acidification is adjusted Pond, flocculation sedimentation tank, Fenton's reaction pond, acidizing hydrolyzation tank, line settling tank and contact-oxidation pool, the acidification conditioning tank top Portion, which covers, shading tent, and acidification conditioning tank side is equipped with air-introduced machine, is equipped with aeration tube inside the acidification conditioning tank, and Aeration tube is connect by gas pipeline with air blower;The acidification conditioning tank is connect by pipeline with Fenton's reaction pond, described Fenton's reaction pond in dosed hydrogen peroxide and ferrous sulfate;The Fenton's reaction pond is connected with flocculation sedimentation tank through pipeline, And coagulant and flocculation aid are added in flocculation sedimentation tank;The flocculation sedimentation tank is connect by pipeline with acidizing hydrolyzation tank, Contain a large amount of anaerobic bacteria in the acidizing hydrolyzation tank;The acidizing hydrolyzation tank is connected with contact-oxidation pool through pipeline, connects Filler is set in touching oxidation pond, and contains a large amount of aerobic bacteria in contact-oxidation pool, and the catalytic oxidation bottom of pond portion is equipped with exposure Tracheae;The contact-oxidation pool is connect by pipeline with line settling tank.
The aeration tube is type micro-pore aerator.
The hydrogen peroxide is 3%.
The ferrous sulfate is 10%.
The coagulant is aluminium polychloride.
The flocculation aid is polyacrylamide.
The utility model has the following beneficial effects: the utility model covers shading tent at the top of acidification conditioning tank, sunlight is avoided Irradiation occurs to go bad, and waste water is handled through Fenton oxidation, makes organic macromolecule flocculating setting in waste water by flocculation sedimentation tank, through acid After changing hydrolytic tank, contact-oxidation pool processing, ortho-aminobenzoic acid decomposition therein is transformed into small molecule nonhazardous substance, waste water C0D removal rate reaches national emission standard.
Detailed description of the invention
Fig. 1 is the attachment structure schematic diagram of the utility model.
Wherein: 1 being acidification conditioning tank, 2 be air-introduced machine, 3 be flocculation sedimentation tank, 4 be Fenton's reaction pond, 5 be acidification hydrolization Pond, 6 be line settling tank, 7 be contact-oxidation pool.
Specific embodiment
The utility model will be further described below with reference to the accompanying drawings.
A kind of sewage decomposition apparatus of ortho-aminobenzoic acid, including acidification conditioning tank 1, flocculation sedimentation tank 3, Fenton's reaction pond 4, acidizing hydrolyzation tank 5, line settling tank 6 and contact-oxidation pool 7, covering at the top of the acidification conditioning tank 1 has shading tent, is acidified 1 side of conditioning tank is equipped with air-introduced machine 2, is equipped with aeration tube inside the acidification conditioning tank 1, and aeration tube passes through appendix Road is connect with air blower;The acidification conditioning tank 1 is connect by pipeline with Fenton's reaction pond 4, in the Fenton's reaction pond 4 Hydrogen peroxide and ferrous sulfate are dosed;The Fenton's reaction pond 4 is connected with flocculation sedimentation tank 3, and flocculation sedimentation tank 3 through pipeline In added coagulant and flocculation aid;The flocculation sedimentation tank 3 is connect by pipeline with acidizing hydrolyzation tank 5, the acidification Contain a large amount of anaerobic bacteria in hydrolytic tank 5;The acidizing hydrolyzation tank 5 is connected with contact-oxidation pool 7, contact-oxidation pool through pipeline Filler is set in 7, and contains a large amount of aerobic bacteria in contact-oxidation pool 7, and 7 bottom of contact-oxidation pool is equipped with aeration tube; The contact-oxidation pool 7 is connect by pipeline with line settling tank 6.
The aeration tube is type micro-pore aerator.
The hydrogen peroxide is 3%.
The ferrous sulfate is 10%.
The coagulant is aluminium polychloride.
The flocculation aid is polyacrylamide.
Conditioning tank 1 is acidified for regulating pondage, balanced water quality, acidification conditioning tank 1 can at least accommodate production cycle Waste water sets aeration tube in pond, prevents sludge from depositing and for being sufficiently stirred.Shading tent is covered on acidification conditioning tank 1 to avoid giving up Water is irradiated through sunlight, in addition air-introduced machine 2 passes the gas through pipeline height row,
It is that catalyst carries out chemical oxidation with hydrogen peroxide (H202) that Fenton's reaction, which is with ferrous ion (Fe2+), by ferrous iron Ion and hydrogen peroxide composition reagent be Fenton reagent, it can generate the hydroxyl radical free radical of strong oxidizing property, in aqueous solution with Hardly degraded organic substance generates organic free radical and is allowed to structure destruction, final oxygenolysis.It is useless by treated in Fenton's reaction pond 4 CODcr can be greatly lowered in water, significantly increase BOD5.
Dosing coagulant and flocculation aid in the waste water of flocculation sedimentation tank 3, enable the particle for being difficult to precipitate to be aggregated with one another and shape At colloid, bigger floccule body is then formed in conjunction with the impurity in water body.Floccule body has powerful adsorption capacity, can not only adsorb Suspended matter, moreover it is possible to which absorbed portion bacterium and dissolved matter, floccule body are increased and sunk by absorption, volume, the SS in waste water It substantially reduces.
Hydrolysis acidification technique be a large amount of anaerobic bacterias effect under by insoluble hydrolysis of organic matter be dissolved organic matter, will be difficult Biodegradable macromolecular substances are converted into the process of the small-molecule substance of easily biological-degradable, so as to improve the biochemical of waste water Property, it creates conditions for subsequent biochemical.
Filler is set in contact-oxidation pool 7, bottom of pond aeration is oxygenated sewage, and sewage in pond is made to be in flow regime, Waste water comes into full contact with filler in pond, and pollutant is by the aerobic bacteria adsorption-decomposition function on filler.It is aerated supply oxygen by air blower, When biofilm development is to certain thickness, the aerobic bacteria of filler wall can carry out anaerobic metabolism, the gas of generation and exposure because of anoxic Gas plays certain souring, causes the new biomembrane that regrows after biofilm detachment, and promote the growth of neoformation film. Biomembrane is at stereochemical structure, strong shock resistance, adaptable to intermittent duty in contact-oxidation pool 7
Line settling tank 6 is based on precipitating, remove the sludge generated in biological treatment process, obtain clear processing water Syllabus, line settling tank 6 is different from other settling tanks, and effect is first is that cement separates, second is that sludge condensation, and because of water, water The variation of matter will also temporarily store activated sludge.
Process flow:
Waste water carries out PH adjusting after entering acidification conditioning tank 1 by pipeline, enters back into Fenton's reaction pond 4 and carries out Fenton's reaction, In Fenton's reaction pond 4 added with 3% hydrogen peroxide and and 10% ferrous sulfate, it is difficult to the organic matter of degradation is oxidized decomposition, later Into flocculation sedimentation tank 3, organic macromolecule material can be adsorbed added with aluminium polychloride and polyacrylamide in settling tank, in addition Enter acidizing hydrolyzation tank 5 and contact-oxidation pool 7 afterwards, last waste water enters line settling tank 6 through pipeline, and waste water at this time has reached National emission standard.

Claims (6)

1. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid, including acidification conditioning tank (1), flocculation sedimentation tank (3), Fenton's reaction Pond (4), acidizing hydrolyzation tank (5), line settling tank (6) and contact-oxidation pool (7), it is characterised in that: the acidification conditioning tank (1) top, which covers, shading tent, and acidification conditioning tank (1) side is equipped with air-introduced machine (2), and the acidification conditioning tank (1) is internal Aeration tube is installed, and aeration tube is connect by gas pipeline with air blower;The acidification conditioning tank (1) passes through pipeline and sweet smell Reaction tank (4) connection has dosed hydrogen peroxide and ferrous sulfate in the Fenton's reaction pond (4);The Fenton's reaction pond (4) it is connected with flocculation sedimentation tank (3) through pipeline, and has added coagulant and flocculation aid in flocculation sedimentation tank (3);The flocculation Settling tank (3) is connect by pipeline with acidizing hydrolyzation tank (5), and a large amount of anaerobic bacteria is contained in the acidizing hydrolyzation tank (5);Institute The acidizing hydrolyzation tank (5) stated is connected with contact-oxidation pool (7) through pipeline, sets filler, and contact-oxidation pool in contact-oxidation pool (7) (7) contain a large amount of aerobic bacteria in, the contact-oxidation pool (7) bottom is equipped with aeration tube;The contact-oxidation pool (7) It is connect by pipeline with line settling tank (6).
2. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid according to claim 1, it is characterised in that: the aeration Pipe is type micro-pore aerator.
3. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid according to claim 1, it is characterised in that: the dioxygen Water is 3%.
4. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid according to claim 1, it is characterised in that: the sulfuric acid Ferrous iron is 10%.
5. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid according to claim 1, it is characterised in that: the coagulation Agent is aluminium polychloride.
6. a kind of sewage decomposition apparatus of ortho-aminobenzoic acid according to claim 1, it is characterised in that: described helping is solidifying Agent is polyacrylamide.
CN201821390166.9U 2018-08-28 2018-08-28 A kind of sewage decomposition apparatus of ortho-aminobenzoic acid Expired - Fee Related CN208814849U (en)

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CN201821390166.9U CN208814849U (en) 2018-08-28 2018-08-28 A kind of sewage decomposition apparatus of ortho-aminobenzoic acid

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Application Number Priority Date Filing Date Title
CN201821390166.9U CN208814849U (en) 2018-08-28 2018-08-28 A kind of sewage decomposition apparatus of ortho-aminobenzoic acid

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110330189A (en) * 2019-07-25 2019-10-15 四川恒泰环境技术有限责任公司 A kind of wastewater treatment method containing benzoic acid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110330189A (en) * 2019-07-25 2019-10-15 四川恒泰环境技术有限责任公司 A kind of wastewater treatment method containing benzoic acid

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Granted publication date: 20190503

Termination date: 20200828