Summary of the invention
For disadvantage mentioned above, there is big mode field area the purpose of this utility model is to provide one kind and can be selected by bending
The large mode field that modulus method obtains high light beam quality mixes ytterbium Active Optical Fiber.
The technology contents of the utility model are, a kind of large mode field mixes ytterbium Active Optical Fiber, it is characterized in that it is from inside to outside successively
It is made of the first sandwich layer, the second sandwich layer, the first inner cladding, the second inner cladding, surrounding layer and protective layer, wherein
Main component is silica in first sandwich layer, and adulterates the element of following molar percentage: wherein aluminium: 1~6,
Ytterbium: 0.1~0.6, phosphorus: 1~4, cerium: 0~1, fluorine: 0.1~0.5;
Main component is silica in second sandwich layer, and adulterates the element of following molar percentage: wherein aluminium: 1~6,
Ytterbium: 0.1~0.6, phosphorus: 1~4, cerium: 0~1;
First inner cladding main component be silica, and doped with molar percentage be 0.1~0.5 fluorine element;
Second inner cladding main component is silica;
The outside of second inner cladding is octagon,
The radius r of first sandwich layer1It is 1~10 μm, the radius r of the second sandwich layer2It is 5~50 μm, wherein the first core radius
r1With the second core radius r2The ratio between be 0.1~0.3;First inner cladding diameter r3With the second core radius r2Difference be 0.2~1
μm;The inscribed circle radius r of any two opposite side of second inner cladding octagon4It is 60~400 μm;
The refringence △ n of first sandwich layer and the second inner cladding1It is 0.07~0.15%;Second sandwich layer and the second inner cladding
Refringence △ n2It is 0.08~0.16%, and △ n2≥△n1;The refringence △ n of first inner cladding and the second inner cladding3
It is -0.02~-0.01%.
It is mixed in ytterbium Active Optical Fiber in above-mentioned large mode field:
The radius of first sandwich layer is r1, refractive index n1;
The radius of second sandwich layer is r2, refractive index n2;
The radius of first inner cladding is r3, refractive index n3;
The outside of second inner cladding is octagon, and edge-to-edge's inscribed circle radius is r4, refractive index n4;
The radius of surrounding layer is r5, refractive index n5;
The radius of protective layer is r6, refractive index n6;
△n1: for the refringence of the first sandwich layer and the second inner cladding, definition are as follows: △ n1=(n1-n4)/n4;
△n2: the refringence of the second sandwich layer and the second inner cladding, definition are as follows: △ n2=(n2-n4)/n4;
△n3: the refringence of the first inner cladding and the second inner cladding, definition are as follows: △ n3=(n3-n4)/n4。
It is mixed in ytterbium Active Optical Fiber in above-mentioned large mode field, compared with the first sandwich layer, undope in the second sandwich layer has the second sandwich layer
Fluorine element;
Doped with fluorine element compared with the second inner cladding, the second inner cladding undopes and has fluorine element first inner cladding.
The numerical aperture that the large mode field of the utility model mixes the second inner cladding in ytterbium Active Optical Fiber is greater than or equal to 0.46;Make
With the refractive index that wavelength is the second covering of 670nm laser testing 1.4570~1.4573.
Above-mentioned large mode field involved in the utility model mixes the preparation method of ytterbium Active Optical Fiber and is, a kind of large mode field, which mixes ytterbium, to be had
The preparation method of source optical fiber comprising following steps:
(1), base tube pre-processes, and base tube is preheated to and effectively eliminated the impurity and bubble of base tube inner wall;
(2), will be processed that base tube deposit mixed with the first inner cladding of fluorine, the flow of fluorine is 0.1~5sccm, is sunk
Lamination number is 2~5 layers;
(3), the post-depositional base tube of the first inner cladding in step (2) is passed through SiCl at 1500~1650 DEG C4Gas carries out
Silica loosening body deposition, SiCl4The volume flow being passed through is 100~300sccm, cuts the tail pipe of base tube after deposition
It is disconnected, it is then immersed in impregnate and be impregnated 0.2~1 hour in aqueous solution, be passed through N after immersion in base tube2Silica is dried up to dredge
Moisture in loose body layer impregnates in aqueous solution and contains AlCl3、YbCl3、CeCl3And H3PO4, AlCl3Molar concentration be 0.01~
0.5 %, YbCl3Molar concentration be 0.01~0.5 %, CeCl3Molar concentration be 0.01~0.5 %, H3PO4It is mole dense
Degree is 0.01~0.5 %;
(4), the base tube after step (3) drying is connected into tail pipe again again, is then first passed through O at 850~950 DEG C2To base
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body in pipe are aoxidized, O2The time being passed through is 30~60 minutes, O2The body being passed through
Product flow is 150~180sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2It is passed through
Time is 30~60 minutes, Cl2The volume flow being passed through is 100~150sccm;Silica is dredged at 1600~2000 DEG C again
Loose body layer sinters sandwich layer into;
(5), the second sandwich layer is obtained after repeating step (3) and step (4) 2~5 times;
(6), the post-depositional base tube of the second sandwich layer in step (5) is passed through SiCl at 1500~1650 DEG C4Gas carries out two
Silica loosening body deposition, SiCl4The volume flow being passed through is 100~300sccm, cuts the tail pipe of base tube after deposition
It is disconnected, it is then immersed in and is impregnated 0.2~1 hour with identical immersion aqueous solution in step (3), is passed through in base tube after immersion
N2Dry up the moisture in silica loosening body layer;
(7), the base tube after step (6) drying is connected into tail pipe again again, is then first passed through O at 850~950 DEG C2To base
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body in pipe are aoxidized, O2The time being passed through is 30~60 minutes, O2The body being passed through
Product flow is 150~180sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2It is passed through
Time is 30~60 minutes, Cl2The volume flow being passed through is 100~150sccm;Silica is dredged at 1600~2000 DEG C again
Loose body layer sinters the first sandwich layer into, is passed through sulfur hexafluoride gas, the volume flow that sulfur hexafluoride gas is passed through while sintering
For 0.1~5sccm;
(8), the base tube of the first sandwich layer collapses in 2100~2200 DEG C of progress forward directions and reversely sintering in step (7),
Obtained large mode field mixes ytterbium Active Optical Fiber prefabricated rods;
(9), polish simultaneously casing to preform, octagon will be worn into outside casing;Then by the predispersed fiber
Stick processed draws and attenuates into silica fibre;
(10), one layer of low-refraction coating is first coated outside silica fibre obtained in step (9), at ultra-violet curing
Reason forms surrounding layer, is then coated with one layer of acrylic resin optical fiber coatings, forms protective layer by ultra-violet curing processing, thus
Large mode field is made and mixes ytterbium Active Optical Fiber finished product.
Surrounding layer and protective layer all use common process in the preparation method that above-mentioned large mode field mixes ytterbium Active Optical Fiber.
The utility model compared with prior art possessed by advantage are as follows: improve optical fiber mode field diameter while make light
Fibre has higher numerical aperture;To which optical fiber has big mode field area and can obtain high beam matter by bending modeling method
Amount.
Specific embodiment
Example 1, a kind of large mode field mix the preparation method of ytterbium Active Optical Fiber comprising following steps:
(1), base tube pre-processes, and base tube is preheated to and effectively eliminated the impurity and bubble of base tube inner wall;
Wherein the diameter of base tube is 32mm, and wall thickness 2.5mm, the cross-sectional area of base tube is 231.5mm2 ;
(2), will be processed that base tube deposit mixed with the first inner cladding of fluorine, the flow of fluorine is 1sccm, deposits the number of plies
It is 2 layers;
(3), the post-depositional base tube of the first inner cladding in step (2) is passed through SiCl at 1550 DEG C4Gas carries out titanium dioxide
Silicon loosening body deposition, SiCl4The volume flow being passed through is 200sccm, cuts off the tail pipe of base tube after deposition, is then immersed in
It impregnates and is impregnated 0.3 hour in aqueous solution, be passed through N after immersion in base tube2The moisture in silica loosening body layer is dried up,
It impregnates in aqueous solution and contains AlCl3、YbCl3、CeCl3And H3PO4, AlCl3Molar concentration be 0.25 %, YbCl3It is mole dense
Degree is 0.05%, CeCl3Molar concentration be 0.05 %, H3PO4Molar concentration be 0.2 %;
(4), the base tube after step (3) drying is connected into tail pipe again again, is then first passed through O at 860 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 35 minutes, O2The volume flow being passed through is
150sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 35 minutes,
Cl2The volume flow being passed through is 110sccm;Silica loosening body layer is sintered into sandwich layer at 1700 DEG C again;
(5), the second sandwich layer is obtained after repeating step (3) and step (4) 3 times;
(6), the post-depositional base tube of the second sandwich layer in step (5) is passed through SiCl at 1600 DEG C4Gas carries out silica
Loosening body deposition, SiCl4The volume flow being passed through is 150sccm, is cut off the tail pipe of base tube after deposition, be then immersed in
It is impregnated 0.6 hour in identical immersion aqueous solution in step (3), is passed through N after immersion in base tube2Silica is dried up to dredge
Moisture in loose body layer;
(7), the base tube after step (6) drying is connected into tail pipe again again, is then first passed through O at 900 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 45 minutes, O2The volume flow being passed through is
160sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 40 minutes,
Cl2The volume flow being passed through is 120sccm;Silica loosening body layer is sintered into first sandwich layer at 1800 DEG C again, is being sintered
While be passed through sulfur hexafluoride gas, the volume flow that sulfur hexafluoride gas is passed through is 1sccm;
(8), there is the base tube of the first sandwich layer to collapse in 2150 DEG C of progress forward directions and reversely sintering in step (7), be made big
Mould field mixes ytterbium Active Optical Fiber prefabricated rods;
(9), polish simultaneously casing to preform, octagon will be worn into outside casing;Then by the optical fiber
Prefabricated rods draw and attenuate into silica fibre;
(10), one layer of low-refraction coating is first coated outside silica fibre obtained in step (9), at ultra-violet curing
Reason forms surrounding layer, is then coated with one layer of acrylic resin optical fiber coatings, forms protective layer by ultra-violet curing processing, thus
Large mode field as shown in Figure 1 is made and mixes ytterbium Active Optical Fiber finished product, Fig. 2 is the refractive index profile schematic diagram of the optical fiber, it by interior and
It is successively made of outside the first sandwich layer 1, the second sandwich layer 2, the first inner cladding 3, the second inner cladding 4, surrounding layer 5 and protective layer 6, wherein
Main component is silica in first sandwich layer 1, and adulterates the element of following molar percentage: wherein aluminium: 2.2, ytterbium: and 0.05,
Phosphorus: 2, cerium: 0.05, fluorine: 0.2;First sandwich layer, 1 radius is r1;
Main component is silica in second sandwich layer 2, and adulterates the element of following molar percentage: wherein aluminium: 2.2,
Ytterbium: 0.05, phosphorus: 2, cerium: 0.05;Second sandwich layer, 2 radius is r2;
The fluorine element that first inner cladding 3 is 0.2 doped with molar percentage;
The radius of first inner cladding 3 is r3, the second inner cladding 4 radius be r4, surrounding layer 5 radius be r5With protective layer 6
Radius be r6 。
Example 2, a kind of large mode field mix the preparation method of ytterbium Active Optical Fiber comprising following steps:
(1), base tube pre-processes, and base tube is preheated to and effectively eliminated the impurity and bubble of base tube inner wall;
Wherein the diameter of base tube is 32mm, and wall thickness 2.5mm, the cross-sectional area of base tube is 231.5mm2 ;
(2), will be processed that base tube deposit mixed with the first inner cladding of fluorine, the flow of fluorine is 3sccm, deposits the number of plies
It is 3 layers;
(3), the post-depositional base tube of the first inner cladding in step (2) is passed through SiCl at 1550 DEG C4Gas carries out titanium dioxide
Silicon loosening body deposition, SiCl4The volume flow being passed through is 300sccm, cuts off the tail pipe of base tube after deposition, is then immersed in
It impregnates and is impregnated 0.5 hour in aqueous solution, be passed through N after immersion in base tube2The moisture in silica loosening body layer is dried up,
It impregnates in aqueous solution and contains AlCl3、YbCl3、CeCl3And H3PO4, AlCl3Molar concentration be 0.4 %, YbCl3Molar concentration
For 0.1%, CeCl3Molar concentration be 0.1 %, H3PO4Molar concentration be 0.4 %;
(4), the base tube after step (3) drying is connected into tail pipe again again, is then first passed through O at 870 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 40 minutes, O2The volume flow being passed through is
160sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 40 minutes,
Cl2The volume flow being passed through is 120sccm;Silica loosening body layer is sintered into sandwich layer at 1800 DEG C again;
(5), the second sandwich layer is obtained after repeating step (3) and step (4) 4 times;
(6), the post-depositional base tube of the second sandwich layer in step (5) is passed through SiCl at 1600 DEG C4Gas carries out silica
Loosening body deposition, SiCl4The volume flow being passed through is 200sccm, is cut off the tail pipe of base tube after deposition, be then immersed in
It is impregnated 0.6 hour in identical immersion aqueous solution in step (3), is passed through N after immersion in base tube2Silica is dried up to dredge
Moisture in loose body layer;
(7), the base tube after step (6) drying is connected into tail pipe again again, is then first passed through O at 900 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 45 minutes, O2The volume flow being passed through is
170sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 40 minutes,
Cl2The volume flow being passed through is 120sccm;Silica loosening body layer is sintered into first sandwich layer at 1900 DEG C again, is being sintered
While be passed through sulfur hexafluoride gas, the volume flow that sulfur hexafluoride gas is passed through is 3sccm;
(8), there is the base tube of the first sandwich layer to collapse in 2150 DEG C of progress forward directions and reversely sintering in step (7), be made big
Mould field mixes ytterbium Active Optical Fiber prefabricated rods;
(9), polish simultaneously casing to preform, octagon will be worn into outside casing;Then by the optical fiber
Prefabricated rods draw and attenuate into silica fibre;
(10), one layer of low-refraction coating is first coated outside silica fibre obtained in step (9), at ultra-violet curing
Reason forms surrounding layer, is then coated with one layer of acrylic resin optical fiber coatings, forms protective layer by ultra-violet curing processing, thus
Large mode field as shown in Figure 1 is made and mixes ytterbium Active Optical Fiber finished product, Fig. 2 is the refractive index profile schematic diagram of the optical fiber, it by interior and
It is successively made of outside the first sandwich layer 1, the second sandwich layer 2, the first inner cladding 3, the second inner cladding 4, surrounding layer 5 and protective layer 6, wherein
Main component is silica in first sandwich layer 1, and adulterates the element of following molar percentage: wherein aluminium: 1.2, ytterbium: and 0.18,
Phosphorus: 3.0, cerium: 0.1, fluorine: 0.3;First sandwich layer, 1 radius is r1;
Main component is silica in second sandwich layer 2, and adulterates the element of following molar percentage: wherein aluminium: 1.2,
Ytterbium: 0.18, phosphorus: 3.0, cerium: 0.1;Second sandwich layer, 2 radius is r2;
The fluorine element that first inner cladding 3 is 0.2 doped with molar percentage;
The radius of first inner cladding 3 is r3, the second inner cladding 4 radius be r4, surrounding layer 5 radius be r5With protective layer 6
Radius be r6。
Example 3, a kind of large mode field mix the preparation method of ytterbium Active Optical Fiber comprising following steps:
(1), base tube pre-processes, and base tube is preheated to and effectively eliminated the impurity and bubble of base tube inner wall;
Wherein the diameter of base tube is 32mm, and wall thickness 2.5mm, the cross-sectional area of base tube is 231.5mm2 ;
(2), will be processed that base tube deposit mixed with the first inner cladding of fluorine, the flow of fluorine is 5sccm, deposits the number of plies
It is 4 layers;
(3), the post-depositional base tube of the first inner cladding in step (2) is passed through SiCl at 1550 DEG C4Gas carries out titanium dioxide
Silicon loosening body deposition, SiCl4The volume flow being passed through is 100sccm, cuts off the tail pipe of base tube after deposition, is then immersed in
It impregnates and is impregnated 0.6 hour in aqueous solution, be passed through N after immersion in base tube2The moisture in silica loosening body layer is dried up,
It impregnates in aqueous solution and contains AlCl3、YbCl3、CeCl3And H3PO4, AlCl3Molar concentration be 0.4 %, YbCl3Molar concentration
For 0.3 %, CeCl3Molar concentration be 0.2 %, H3PO4Molar concentration be 0.5 %;
(4), the base tube after step (3) drying is connected into tail pipe again again, is then first passed through O at 900 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 45 minutes, O2The volume flow being passed through is
165sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 45 minutes,
Cl2The volume flow being passed through is 150sccm;Silica loosening body layer is sintered into sandwich layer at 2000 DEG C again;
(5), the second sandwich layer is obtained after repeating step (3) and step (4) 5 times;
(6), the post-depositional base tube of the second sandwich layer in step (5) is passed through SiCl at 1600 DEG C4Gas carries out silica
Loosening body deposition, SiCl4The volume flow being passed through is 250sccm, is cut off the tail pipe of base tube after deposition, be then immersed in
It is impregnated 0.6 hour in identical immersion aqueous solution in step (3), is passed through N after immersion in base tube2Silica is dried up to dredge
Moisture in loose body layer;
(7), the base tube after step (6) drying is connected into tail pipe again again, is then first passed through O at 900 DEG C2To in base tube
Aluminium, ytterbium, cerium and the phosphorus of silica loosening body are aoxidized, O2The time being passed through is 45 minutes, O2The volume flow being passed through is
170sccm;Then it is passed through Cl again2Silica loosening body layer in base tube is dried, Cl2The time being passed through is 50 minutes,
Cl2The volume flow being passed through is 140sccm;Silica loosening body layer is sintered into first sandwich layer at 1900 DEG C again, is being sintered
While be passed through sulfur hexafluoride gas, the volume flow that sulfur hexafluoride gas is passed through is 5sccm;
(8), there is the base tube of the first sandwich layer to collapse in 2150 DEG C of progress forward directions and reversely sintering in step (7), be made big
Mould field mixes ytterbium Active Optical Fiber prefabricated rods;
(9), polish simultaneously casing to preform, octagon will be worn into outside casing;Then by the optical fiber
Prefabricated rods draw and attenuate into silica fibre;
(10), one layer of low-refraction coating is first coated outside silica fibre obtained in step (9), at ultra-violet curing
Reason forms surrounding layer, is then coated with one layer of acrylic resin optical fiber coatings, forms protective layer by ultra-violet curing processing, thus
Large mode field as shown in Figure 1 is made and mixes ytterbium Active Optical Fiber finished product, Fig. 2 is the refractive index profile schematic diagram of the optical fiber, it by interior and
It is successively made of outside the first sandwich layer 1, the second sandwich layer 2, the first inner cladding 3, the second inner cladding 4, surrounding layer 5 and protective layer 6, wherein
Main component is silica in first sandwich layer 1, and adulterates the element of following molar percentage: wherein aluminium: 4, ytterbium: and 0.35, phosphorus:
4, cerium: 0.2, fluorine: 0.3;First sandwich layer, 1 radius is r1;
Main component is silica in second sandwich layer 2, and adulterates the element of following molar percentage: wherein aluminium: 4, ytterbium:
0.35, phosphorus: 4, cerium: 0.2;Second sandwich layer, 2 radius is r2;
The fluorine element that first inner cladding 3 is 0.3 doped with molar percentage;
The radius of first inner cladding 3 is r3, the second inner cladding 4 radius be r4, surrounding layer 5 radius be r5With protective layer 6
Radius be r6。
The large mode field of example 1, example 2 and example 3 is mixed into ytterbium Active Optical Fiber detection parameters and final testing result is as shown in table 1;Its
Test condition is that the LD pump power output of two 915 nm is 100W, raster center wavelength 1060nm.
Table 1