CN208765878U - A kind of condenser type pliable pressure sensor - Google Patents
A kind of condenser type pliable pressure sensor Download PDFInfo
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- CN208765878U CN208765878U CN201821589532.3U CN201821589532U CN208765878U CN 208765878 U CN208765878 U CN 208765878U CN 201821589532 U CN201821589532 U CN 201821589532U CN 208765878 U CN208765878 U CN 208765878U
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Abstract
A kind of condenser type pliable pressure sensor, which includes polymer elastomer electrode, insulating layer of thin-film and ITO electrode;The polymer elastomer electrode includes conductive film, polymer elastomer and electrode substrate, the polymer elastomer includes the microstructured layers with micro-structure array of protrusions being formed in the electrode substrate, and the conductive film is covered on the surface of the microstructured layers;The insulating layer of thin-film is placed between the polymer elastomer electrode and the ITO electrode, and is contacted by the conductive film with the top of the micro-structure protrusion of the microstructured layers.The utility model provides the good condenser type pliable pressure sensor of a kind of high sensitivity, device stability.
Description
Technical field
The utility model relates to pressure sensor technique field, in particular to a kind of condenser type pliable pressure sensor.
Background technique
Flexible electronic was once chose as " one of big scientific and technological achievement in the world ten " as emerging technology areas.Industry 4.0 with
Under 2025 epoch of made in China, all things on earth interconnection, the expectation of the range, precision, scene, stability and performance parameter of perception information
It is gradually increased, traditional silicon-based electronic devices are difficult to satisfy social needs.Furthermore the mankind and other biological sheet are as flexible body, more
It is suitble to one of the element of flexible device and flexible electronic driving.So-called flexible electronic, i.e., by organic/inorganic thin film electronic
Device fabrication is manufactured in flexible plastic substrate or metallic film/glass substrate electronic technology.In stretching appropriate, extend, certainly
By can still work normally the accurate measurement realized to information under bending even folded state.Flexible electronic technology in numerous areas,
Such as flexible sensing, Flexible Displays and illumination, medical treatment & health, wearable device, human-computer interaction, energy storage field have extensively
Application.
Pressure sensor can be divided into condenser type, pressure resistance type and piezoelectric type etc. according to its working principle.Capacitive pressure sensing
Device structure is simple, high resolution, and speed-adaptive is fast under the rugged environments such as high temperature, radiation.It is not only applicable to displacement, vibration
The measurement of some mechanical-physical amounts such as dynamic, angular speed, acceleration, and be also widely used for pressure, differential pressure, liquid pressure,
The measurement of the hot engineering parameter such as the content of ingredient.But currently, capacitance pressure transducer, remains some problems, tradition pressure
Force snesor can not be bent or in a flexed condition according sensitivity it is lower, it is at high cost etc..
Utility model content
The main purpose of the utility model is to overcome the deficiencies in the prior art, provide it is a kind of with high sensitivity,
The good condenser type pliable pressure sensor of device stability.
To achieve the above object, the utility model uses following technical scheme:
A kind of condenser type pliable pressure sensor, including polymer elastomer electrode, insulating layer of thin-film and ITO electrode;
The polymer elastomer electrode includes conductive film, polymer elastomer and electrode substrate, and the polymer elastomer includes
The microstructured layers with micro-structure array of protrusions being formed in the electrode substrate, the conductive film are covered on micro- knot
The surface of structure layer;The insulating layer of thin-film is placed between the polymer elastomer electrode and the ITO electrode, and by described
Conductive film is contacted with the top of the micro-structure protrusion of the microstructured layers.
Further:
The micro-structure protrusion includes at least one of taper, truncated cone-shaped, truncated cone-shaped and hemispherical.
The taper includes conical or pyramid, described truncated cone-shaped including frustroconical or truncated pyramid shape, institute
Taper or the truncated cone-shaped taper are stated between 30 ° -90 °.
The bed-plate dimension of the micro-structure protrusion is 10-60 μm of diameter or bottom edge side length is 10-60 μm.
The spacing of the micro-structure protrusion is 10-120 μm.
The polymer elastomer material is PDMS, TPU, PET, silicon rubber or polyurethane rubber.
The material of the conductive film is gold, silver, copper, carbon nanotube or silver nanowires.
The film thickness of the conductive film is 60-100nm.
The polymer elastomer electrode with a thickness of 6-100 μm.
The film thickness of the insulating layer of thin-film is 500nm-2 μm.
The beneficial effects of the utility model include:
The condenser type pliable pressure sensor of the utility model has polymer elastomer electrode, and polymer elastomer includes
The microstructured layers with micro-structure array of protrusions being formed in electrode substrate, conductive film are covered on the surface of microstructured layers,
Insulating layer of thin-film is placed between polymer elastomer electrode and ITO electrode, and passes through the micro-structure of conductive film and microstructured layers
The top contact of protrusion, since polymer elastomer electrode includes the microstructured layers with micro-structure array of protrusions, can perceive
Extremely small pressure change increases the sensitivity of pressure sensor.Specifically, by the utility model polymer elastomer
The capacitance pressure transducer, that electrode is formed, when the effect by ambient pressure, the micro-structure of polymer elastomer electrode is sent out
Raw deformation, causes the distance between polymer elastomer electrode and ITO electrode to change, i.e. the electricity of capacitance pressure transducer,
Capacitance changes.After applying voltage to two electrodes, the variation of capacitance is converted into the variation of electric signal, to perceive the external world
The variation of pressure.Ambient pressure signal is converted electric signal by the pressure sensor of the utility model, has sensitivity high, device
The advantages that part stability is good, and flexibility is good, is easy to array, micromation.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the capacitance pressure transducer, of the utility model embodiment;
Fig. 2 is the diagrammatic cross-section of the capacitance pressure transducer, of the utility model embodiment;
Fig. 3 is the microstructured layers schematic diagram of the polymer elastomer electrode in the utility model embodiment;
Fig. 4 is the diagrammatic cross-section of the microstructured layers of the polymer elastomer electrode in the utility model embodiment;
Fig. 5 is the flow diagram of the production method of the capacitance pressure transducer, of the utility model embodiment;
Fig. 6 is the test result figure of the capacitance pressure transducer, of the utility model embodiment.
Specific embodiment
It elaborates below to the embodiments of the present invention.It is emphasized that following the description is only example
Property, rather than in order to limit the scope of the utility model and its application.
Refering to fig. 1 to Fig. 4, in one embodiment, a kind of condenser type pliable pressure sensor, including ITO electrode plate 1,
Insulating layer of thin-film 2 and polymer elastomer electrode 3;The polymer elastomer electrode 3 includes conductive film 31, polymer bullet
Property body 32 and electrode substrate 33, the polymer elastomer 32 includes being formed in the electrode substrate 33 to have micro-structure convex
The microstructured layers of array are played, the conductive film 31 is coated uniformly on the surface of the microstructured layers;The insulating layer of thin-film 2 is set
Between the polymer elastomer electrode 3 and the ITO electrode plate, and pass through the conductive film 31 and the microstructured layers
Micro-structure protrusion top contact.ITO electrode plate 1 may include ITO11 and ITO electrode substrate material 12.
In some preferred embodiments, the micro-structure protrusion includes in taper, truncated cone-shaped, truncated cone-shaped and hemispherical
At least one.
In a further preferred embodiment, the taper include cone or pyramid (such as pyramid), described section
Addendum cone shape includes frustroconical or truncated pyramid shape (such as truncated pyramid shape), the taper or the truncated cone-shaped taper
Between 30 ° -90 °.In various embodiments, insulating layer of thin-film 2 is contacted with the pinnacle of micro-structure protrusion or truncation.
In a preferred embodiment, the bed-plate dimension of the micro-structure protrusion is 10-60 μm of diameter or bottom edge side length is 10-
60μm。
In a preferred embodiment, the spacing of the micro-structure protrusion is 10-120 μm.
In various embodiments, 32 material of polymer elastomer is PDMS, TPU, PET, silicon rubber or polyurethane
Rubber.
In various embodiments, 31 material of conductive film can be gold, silver, copper, carbon nanotube, silver nanowires
Deng.Preferably, the film thickness of the conductive film 31 is 60-100nm.
In a preferred embodiment, the polymer elastomer electrode 3 with a thickness of 6-100 μm.
In a preferred embodiment, the film thickness of the insulating layer of thin-film 2 is 500nm-2 μm.
For example, in a particular embodiment, the shape of micro-structure protrusion can be pyrometric cone, polygon pyramid, circular cone, rib
Platform, rotary table etc., when micro-structure is taper or is truncated cone-shaped, for range of taper between 30 °~90 °, bottom edge side length is 10-60 μ
m.Convex shape in micro structure array can be one kind, be also possible to it is a variety of, certainly, for the ease of facilitate processing, it is preferably micro-
The shape of protrusion in array of structures is a kind of.The cell spacing of micro structure array is 10-120 μm.The conductive film film thickness
For 60-100nm.The polymer elastomer electrode with a thickness of 6-100 μm, more preferably with a thickness of 10-50 μm.The polymerization
Object elastomer is PDMS, TPU, PET, silicon rubber or polyurethane rubber, preferably PDMS.Preferably, the conductive film material
For gold, silver, copper, carbon nanotube, silver nanowires etc., the film thickness of the conductive film is 60-100nm.The polymer elastomer
Electrode with a thickness of 6-100 μm.Preferably, the material of the insulating layer of thin-film is Parylene, silica etc., the insulating layer
The film thickness of film is 500nm-2 μm, specifically, is coated using atomic layer deposition or chemical vapor deposition process, growth
Thickness of insulating layer is consistent.
As depicted in figs. 1 and 2, capacitance pressure transducer, includes ITO electrode plate 1, insulating layer of thin-film 2 and polymer elasticity
Body electrode 3.At least one micro-structure in the micro structure array of polymer elastomer electrode 3 is contacted with insulating layer of thin-film 2, ITO
Electrode plate 1, insulating layer of thin-film 2 and polymer elastomer electrode 3 are mutually bonded.Wherein, ITO electrode plate 1 includes ITO 11 and ITO
Electrode substrate material 12.Insulating layer of thin-film 2 is Parylene C, and Parylene C is coated uniformly on ITO electrode by vacuum vapor deposition
Plate surface.Polymer elastomer electrode 3 includes Ti/Au metallic film, micro structure array and electrode substrate material.ITO electrode lining
The material of bottom and polymer elastomer electrode substrate can choose PET, PMMA etc..
In this example, the film thickness of ITO conductive film is 200nm, and substrate material selects PET material, with a thickness of 50 μm.
Refering to Fig. 5, a kind of production method for the capacitance pressure transducer, making aforementioned any embodiment, including following step
It is rapid:
The polymerization that one side has micro-structure array of protrusions is produced on using the silicon mould with micro-structure array of protrusions template
Object elastomer;
The another side of the electrode substrate and the polymer elastomer is subjected to lamination bonding, by the polymer after bonding
Elastomer is stripped down from silicon mould;
Metal electrode is plated on one side with the micro-structure array of protrusions in the polymer elastomer, forms polymerization
Object elastomer electrode.
Insulating layer of thin-film coating is carried out in ITO electrode and is packaged with the polymer elastomer electrode.
As shown in Figure 5, it is preferable that the manufacturing process of the capacitance pressure transducer, the following steps are included:
S1, standard photolithography process is carried out to silicon wafer using SU-8 glue, this example is using 100 crystal orientation silicon wafers.
S2, it is performed etching using BOE, BOE solution is configured that 80g NH4F, 20mL 49%HF solution, 120mL
H2O, etch rate 1000A/min.
S3, silicon mould is made using the wet etching technique of silicon, process silicon etching solution is configured to be divided into: 70g KOH and 190mL
After the above two are completely dissolved, 40mL IPA, in 80 DEG C of water-baths, etch rate 8000A/min is added in H2O.
S4, this micro-structure silicon mould is carried out silanization treatment surface, to use 1H, 1H, 2H, 2H- perfluoro decyl three in this example
Chlorosilane handles 3h at 120 DEG C and obtains hydrophobic surface.
S5, vacuum spin coating PDMS (polydimethylsiloxane, the polydimethylsiloxanes on the silicon mould made
Alkane), and 3h is toasted under 80 DEG C of environment, the quality proportioning 10:1 of PDMS and curing agent, vacuum degree -0.1MPa, with shape in this example
At a part of polymer elastomer electrode;Fig. 4 be pressure sensitive layer diagrammatic cross-section, array protrusion between spacing a1 with
The thickness a3 of microstructure height a2 and pressure sensitive layer depends on the detection range and testing requirements of pressure sensor, in preference
In, a1 is 30 μm, and a2 is 15 μm, and a3 is 25 μm.
S6, lamination bonding, carry out ozone activation processing (oxygen for the face to be bonded of PET film and polymer elastomer electrode
Surface Treatment with Plasma, 90W, 30s);Polymer elastomer electrode after bonding is stripped down from silicon mould.
S7, evaporation metal electrode use electron beam evaporation plating conductive film on polymer elastomer electrode microstructure surface, first
10nm Ti is deposited as adhesion layer in PDMS micro-structure surface, then 60nm Au is deposited as conductive layer.
S8, in ITO electrode using vacuum vapor deposition technique complete 2 μm of Parylene C coating and be bonded after polymerization
Object elastomer electrode is packaged.
Fig. 6 show the test result of above-mentioned pressure sensor, and in 0-40Pa, transducer sensitivity reaches 24.21kPa-
1, in 40-130Pa, transducer sensitivity reaches 1.72kPa-1.
The above content is specific/preferred embodiment further detailed description of the utility model is combined, no
It can assert that the specific implementation of the utility model is only limited to these instructions.For the common skill of the utility model technical field
For art personnel, without departing from the concept of the premise utility, the embodiment that these have been described can also be made
Some replacements or modifications, and these substitutions or variant all shall be regarded as belonging to the protection scope of the utility model.
Claims (10)
1. a kind of condenser type pliable pressure sensor, which is characterized in that including polymer elastomer electrode, insulating layer of thin-film and
ITO electrode;The polymer elastomer electrode includes conductive film, polymer elastomer and electrode substrate, the polymer bullet
Property body includes the microstructured layers with micro-structure array of protrusions being formed in the electrode substrate, and the conductive film is covered on
The surface of the microstructured layers;The insulating layer of thin-film is placed between the polymer elastomer electrode and the ITO electrode, and
It is contacted by the conductive film with the top of the micro-structure protrusion of the microstructured layers.
2. condenser type pliable pressure sensor as described in claim 1, which is characterized in that the micro-structure protrusion includes cone
At least one of shape, truncated cone-shaped, truncated cone-shaped and hemispherical.
3. condenser type pliable pressure sensor as claimed in claim 2, which is characterized in that the taper includes cone or rib
Taper, described truncated cone-shaped including frustroconical or truncated pyramid shape, the taper or the truncated cone-shaped taper exist
Between 30 ° -90 °.
4. the condenser type pliable pressure sensor as described in claim 2 to 3 is any, which is characterized in that the micro-structure protrusion
Bed-plate dimension be 10-60 μm of diameter or bottom edge side length is 10-60 μm.
5. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the micro-structure protrusion
Spacing be 10-120 μm.
6. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the polymer elasticity
Body material is PDMS, TPU, PET, silicon rubber or polyurethane rubber.
7. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the conductive film
Film thickness is 60-100nm.
8. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the conductive film
Material is gold, silver, copper, carbon nanotube or silver nanowires.
9. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the polymer elasticity
Body electrode with a thickness of 6-100 μm.
10. the condenser type pliable pressure sensor as described in claims 1 to 3 is any, which is characterized in that the insulating layer of thin-film
Film thickness be 500nm-2 μm.
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Cited By (7)
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CN109115376A (en) * | 2018-09-28 | 2019-01-01 | 清华大学深圳研究生院 | A kind of condenser type pliable pressure sensor and preparation method thereof |
CN110487168A (en) * | 2019-08-29 | 2019-11-22 | 清华大学深圳研究生院 | Bend in one direction sensitive sensor and preparation method thereof |
CN110579225A (en) * | 2019-09-11 | 2019-12-17 | 京东方科技集团股份有限公司 | Planar capacitive sensor and manufacturing method thereof |
CN112798156A (en) * | 2019-11-13 | 2021-05-14 | 中国科学院微电子研究所 | Nanowire pressure sensor and sensor array |
CN113125065A (en) * | 2021-03-30 | 2021-07-16 | 苏州大学 | Flexible three-dimensional force sensor and preparation method thereof |
CN113155327A (en) * | 2021-03-30 | 2021-07-23 | 中国科学院深圳先进技术研究院 | Bionic microarray flexible electrode, preparation method thereof and flexible pressure sensor |
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Cited By (9)
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CN109115376A (en) * | 2018-09-28 | 2019-01-01 | 清华大学深圳研究生院 | A kind of condenser type pliable pressure sensor and preparation method thereof |
CN110487168A (en) * | 2019-08-29 | 2019-11-22 | 清华大学深圳研究生院 | Bend in one direction sensitive sensor and preparation method thereof |
CN110487168B (en) * | 2019-08-29 | 2024-03-01 | 清华大学深圳研究生院 | Unidirectional bending sensitive sensor and preparation method thereof |
CN110579225A (en) * | 2019-09-11 | 2019-12-17 | 京东方科技集团股份有限公司 | Planar capacitive sensor and manufacturing method thereof |
CN110579225B (en) * | 2019-09-11 | 2022-02-25 | 京东方科技集团股份有限公司 | Planar capacitive sensor and manufacturing method thereof |
CN112798156A (en) * | 2019-11-13 | 2021-05-14 | 中国科学院微电子研究所 | Nanowire pressure sensor and sensor array |
WO2021253278A1 (en) * | 2020-06-17 | 2021-12-23 | 中国科学院深圳先进技术研究院 | Touch sensor, manufacturing method, and intelligent device comprising touch sensor |
CN113125065A (en) * | 2021-03-30 | 2021-07-16 | 苏州大学 | Flexible three-dimensional force sensor and preparation method thereof |
CN113155327A (en) * | 2021-03-30 | 2021-07-23 | 中国科学院深圳先进技术研究院 | Bionic microarray flexible electrode, preparation method thereof and flexible pressure sensor |
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