CN208545143U - Integrated waste water treatment system - Google Patents

Integrated waste water treatment system Download PDF

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Publication number
CN208545143U
CN208545143U CN201820892820.XU CN201820892820U CN208545143U CN 208545143 U CN208545143 U CN 208545143U CN 201820892820 U CN201820892820 U CN 201820892820U CN 208545143 U CN208545143 U CN 208545143U
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China
Prior art keywords
condensing crystallizing
crystallizing device
liquid
solid
waste water
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CN201820892820.XU
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叶昌宏
易毅
向光富
叶大旺
褚川川
陈林杰
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Guangdong Fenlan Environmental Technology Co., Ltd.
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Guangdong Environmental Protection Technology Co Ltd Hereby Cervantes
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Abstract

The utility model discloses a kind of integrated waste water treatment systems, including heat pump of high-temp water source unit, condensing crystallizing device, solid-liquid separator, vacuum pump and condenser, heat pump of high-temp water source unit is equipped with hot water delivery pipe, hot water input pipe, cold water efferent duct and cold water inlet pipe, hot water delivery pipe is connected to the first inlet of condensing crystallizing device, hot water input pipe is connected to the second liquid outlet that the first liquid outlet of condensing crystallizing device is connected to condensing crystallizing device with the inlet of solid-liquid separator, the liquid outlet of solid-liquid separator is connected to the second inlet of condensing crystallizing device, cold water efferent duct and cold water inlet pipe are connected to condenser respectively, vacuum pump is connected to condensing crystallizing device and condenser respectively.Cooling capacity needed for heat needed for the utility model uses heat pump of high-temp water source unit to provide evaporation simultaneously for waste water treatment system and condensation, it is energy-efficient;The utility model can realize the useless zero-emission of solid waste liquid, energy conservation and environmental protection.

Description

Integrated waste water treatment system
Technical field
The utility model relates to technical field of waste water processing, the integrated treatment system of especially a kind of heavy metal-containing waste water System.
Background technique
Wastewater flow rate caused by heavy metal-containing waste water, especially PCB industry, electroplating industry is quite big, main succession Based on COD and heavy metal.Heavy metal chemical coagulation-sedimentation method is generallyd use in the past, forms metal ion in waste water with alkaline agent It after hydroxide wadding body, then is removed in a manner of precipitation and separation, waste water is again into biochemical treatment after heavy-metal ion removal.But this place Reason method, consumption of chemicals is big, and processing cost is high, and heavy workload, treatment effect is unstable, is unable to qualified discharge.
At present the treatment process technology of relatively conventional high concentration heavy metal-containing waste water have chemical reduction method, electrolysis method, from Sub- exchange process and membrane separation method.
Chemical reduction method: it is chemically reacted by putting into relevant medicament in heavy metal-containing waste water, each metal ion It is reacted with medicament and generates synthetic progress precipitation and separation removal, this method is uncontrollable etc. by influent concentration and Adding medicine control variation Factor can not accomplish that stably reaching standard discharges, and treated, and waste water also cannot achieve reuse to procedure for producing.
Electrolysis method: the method for electrolysis is to be moved by electric field, charge potential to the metal ion in heavy metal-containing waste water Move the processing technique of attachment.This processing technique is generally only applicable to that water is less, without the highly concentrated of other foreign metal ions Waste water is spent, the ion in waste water is finally recycled with sheet metal.But to general low concentration, concentration only have tens or Several hundred ppm, water is big, and low concentration and concentration change greatly heavy metal-containing waste water, and the method for electrolysis is difficult to realize in waste water Metal ion carries out effective mobility.Moreover, waste water its salinity after electrolysis has biggish increase, be difficult to accomplish stable emissions and Reuse.
Ion-exchange: ion-exchange inhales the metal ion in waste water generally by ion exchange resin It is attached.Metal ion in waste water is by resin adsorption, and resin saturation failure after a period of time, needs to expend a large amount of acid or alkali carries out Elution and regeneration.Regenerative process needs a large amount of tap water to be eluted and cleaned, this large amount of ejected wash water also contains residue gold Belong to ion, it is also desirable to could discharge after being handled.Ion exchange resin will fail for a period of time after Reusability, Whole all replacements are needed after failure, cause high processing cost.
And film process is used, waste water can be handled well, and film produces water also can stably reaching standard discharge.But the concentration of film has centainly The limit, i.e., when Waste water concentrating to a certain extent after, with the raising of concentration, conductivity rises, concentration of metal ions rises, The solutes such as COD accordingly rise, so that film permeant flux declines, cycles of concentration is obstructed.Pass through membranous system treated concentrate It is difficult to handle, Crystallization Separation effect has not only been not achieved but also reuse concentration is not achieved;In addition some heavy metal wastewater therebies are not suitable for into membrane system System, has damage to film, influences membrane lifetime;And some conductivity of waste water are excessively high, are also not suitable for into membranous system, will lead to membranous system without Produce water.
Processing is seen through using counter, to low concentration, in the waste water of≤500mg/L, processing water outlet can continue metal ion content It is used in plating piece rinsing, does not influence wash effect, but for the higher dope of metal ion 500mg/L concentrations above containing a huge sum of money Belong to waste water, water is produced after processing and is unable to stably reaching standard, is more than discharge standard value range.Coating bath cannot be directly returned simultaneously, will affect Plating quality.
Utility model content
Based on the above issues, the purpose of the utility model is to overcome provide one kind in place of above-mentioned the deficiencies in the prior art The integrated processing system of heavy metal-containing waste water, the system medicament consumption is small, processing cost is low, treatment effect is stable, meets Wastewater discharge standard.
To achieve the above object, the technical solution that the utility model is taken are as follows: integrated waste water treatment system, including high temperature Water source heat pump units, condensing crystallizing device, solid-liquid separator, vacuum pump and condenser, the heat pump of high-temp water source unit are equipped with Hot water delivery pipe, hot water input pipe, cold water efferent duct and cold water inlet pipe, the hot water delivery pipe and the condensing crystallizing device The connection of first inlet, the hot water input pipe are connected to the first liquid outlet of the condensing crystallizing device, the condensing crystallizing device The second liquid outlet be connected to the inlet of the solid-liquid separator, the liquid outlet of the solid-liquid separator and the condensing crystallizing Second inlet of device is connected to, and the cold water efferent duct and cold water inlet pipe are connected to the condenser respectively, the vacuum pump It is connected to respectively with the condensing crystallizing device and condenser.
Wherein, the main function of condensing crystallizing device is constantly to be added the material (heavy metal-containing waste water) of required evaporation Heat, and gas-liquid separation is constantly carried out, evaporative crystallization is done step-by-step;The main function of condenser is that will flash steam is condensed into Water;The main function of solid-liquid separator is for the material after crystallization to be separated by solid-liquid separation;The main function of vacuum pump is to tie up Whole system negative-pressure vacuum is held, realizes negative pressure low-temperature evaporation.
Preferably, crystal discharge outlet is additionally provided on the solid-liquid separator.The resulting crystal of solid-liquid separator obtains as a result, It collects and recycles.
Preferably, distillate discharge outlet is additionally provided on the condenser.The saturated water entered outside condenser shell side as a result, steams Air cooling is discharged after congealing into water by distillate discharge outlet, is collected, stored or recycled by water collect tank.
Preferably, liquid level detector is equipped in the condensing crystallizing device.Thus, it is possible to monitor material in condensing crystallizing device Liquid level when system just starts, can open quick feeding mode, can when liquid level detector monitors that material reaches a certain amount of To change into normal feed mode, to save feed time.
Preferably, material concentration detector is equipped in the condensing crystallizing device.Thus, it is possible to which real-time monitoring is dense through pervaporation The concentration of material after contracting may be selected discharge and be concentrated by evaporation to certain density material according to demand, also can choose discharge concentration Material crystal after crystallization, realizes the discharge method of zero-emission.
In conclusion the utility model has the following beneficial effects:
1, needed for heat needed for the utility model uses heat pump to provide evaporation simultaneously for waste water treatment system and condensation Cooling capacity is not necessarily to mating pre-heating system, and system is simple, and system support is few, cold and heat combined supply, and Energy Efficiency Ratio is high;Add compared to former boiler or electricity The modes such as heat, energy consumption significantly reduce, and take full advantage of the energy that the cold and hot both ends of heat pump generate, energy-efficient;
2, the utility model can realize the final evaporative crystallization of waste water, and the solid crystals of formation can carry out packaging outward transport, It can be utilized again, the mother liquor after separation of solid and liquid can reenter condensing crystallizing device and carry out continuous evaporating, concentrating and crystallizing, It realizes the useless zero-emission of solid waste liquid, realizes the abundant recycling of the energy, energy conservation and environmental protection.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of integrated processing system;
Wherein, 1, heat pump of high-temp water source unit, 2, condensing crystallizing device, 3, solid-liquid separator, 4, vacuum pump, 5, condenser, 6, hot water delivery pipe, 7, hot water input pipe, 8, cold water efferent duct, 9, cold water inlet pipe, the 10, first inlet, 11, first goes out liquid Mouthful, the 12, second liquid outlet, the 13, second inlet, 14, crystal discharge outlet, 15, distillate discharge outlet.
Specific embodiment
The utility model is suitable for PCB (plating, circuit board, wiring board) industry, food-processing industry, chemical industry, doctor The concentration of evaporation decrement and zero-emission of the industries waste water such as medicine industry, machining manufacturing and waste liquid;The utility model passes through It is cold needed for heat needed for providing high-concentration heavy metal waste water evaporative crystallization using heat pump of high-temp water source unit and gas-liquid separation Amount is realized to separation and recovery processing solid, air-liquid in high-concentration heavy metal waste water.
To better illustrate the purpose of this utility model, technical solution and advantage, below in conjunction with attached drawing and specific implementation The utility model is described in further detail for example.
Embodiment 1
As shown in Figure 1, a kind of embodiment of the integrated waste water treatment system of the utility model, including heat pump of high-temp water source Unit 1, condensing crystallizing device 2, solid-liquid separator 3, vacuum pump 4 and condenser 5, it is defeated that heat pump of high-temp water source unit 1 is equipped with hot water Outlet pipe 6, hot water input pipe 7, cold water efferent duct 8 and cold water inlet pipe 9, the first feed liquor of hot water delivery pipe 6 and condensing crystallizing device 2 Mouth 10 is connected to, and hot water input pipe 7 is connected to the first liquid outlet 11 of condensing crystallizing device 2, the second liquid outlet 12 of condensing crystallizing device 2 It being connected to the inlet of solid-liquid separator 3, the liquid outlet of solid-liquid separator 3 is connected to the second inlet 13 of condensing crystallizing device 2, Cold water efferent duct 8 and cold water inlet pipe 9 are connected to condenser 5 respectively, and vacuum pump 4 connects with condensing crystallizing device 2 and condenser 5 respectively It is logical;
Wherein, crystal discharge outlet 14 is additionally provided on solid-liquid separator 3;Distillate discharge outlet 15 is additionally provided on condenser 5;It is dense Liquid level detector (not shown) and material concentration detector (not shown) are equipped in contracting crystallizer 2.
The integrated waste water treatment system of the utility model has the following characteristics that in application
1) hot water that heat pump of high-temp water source unit generates T1~T2 DEG C of high temperature enters condensing crystallizing device, with required heating evaporation Material carry out indirect heat exchange, so that material (heavy metal-containing waste water) is reached evaporating temperature, be then refluxed for heat pump unit, realize High-temperature-hot-water sustainable supply;
2) material after heat exchange heating realizes its gas-liquid separation by stirring in condensing crystallizing device bottom, the saturation after separation Vapor enters condenser;
3) T3~T4 DEG C of the cooling water that heat pump of high-temp water source unit generates simultaneously enters the tube side of condenser, will be outside shell side Saturated vapor be condensed into water, condensed water can pass through water collect tank and collect discharge (distillate);
4) material after gas-liquid separation constantly carries out heating evaporation and gas-liquid separation by the stirring of condensing crystallizing device bottom, Crystal is formed after material evaporation to a certain concentration, the material after crystallization is discharged by the discharge port of condensing crystallizing device bottom, is entered Solid-liquid separator;
5) material after crystallization is separated by solid-liquid separation by solid-liquid separator, forms crystal and mother liquor, crystal are discharged to storage tank, Realize its recycling, mother liquor returns to mother liquor pond, and condensing crystallizing device can be again introduced into material and is evaporated condensing crystallizing processing;
6) vacuum pump connection condenser, condensing crystallizing device, solid-liquid separator realize stable negative pressure for entire vapo(u)rization system Vacuum, it is ensured that material maintains explosive evaporation at low temperature;
7) unpowered charging: vacuum pump has realized that the stable negative-pressure vacuum of entire vapo(u)rization system, material are not necessarily to feed pump, lead to It crosses vacuum and can realize and be inhaled into condensing crystallizing device;When system just starts charging, system starts quick feeding mode, opens quick Inlet valve, material are directly entered condensing crystallizing device middle and lower part by quick feeding valve, the liquid level detector in condensing crystallizing device When (not shown) detects that material reaches a certain amount of, system starts normal feed mode, and machine automatization inlet valve is (in figure not Show) it opens, inlet amount is automatically controlled by machine automatization inlet valve and flash evaporation control valve (not shown);
8) condensing crystallizing device bottom is equipped with material concentration detector (not shown), and real-time detection is by being concentrated by evaporation knot The concentration of material after crystalline substance can control discharge method according to demand, and discharge may be selected and be concentrated by evaporation to certain density material, Material crystal after discharge condensing crystallizing may be selected, realizes the discharge method of zero-emission;
9) pipeline and each device of waste water treatment system can according to demand and region is different, using stainless steel, dual phase steel, The anti-corrosion resistant material such as titanium, modified graphite.
Finally, it should be noted that above embodiments are only to illustrate the technical solution of the utility model rather than to this realities With the limitation of novel protected range, although being explained in detail referring to preferred embodiment to the utility model, this field it is common It will be appreciated by the skilled person that can be with the technical solution of the present invention is modified or equivalently replaced, without departing from this reality With the spirit and scope of new technique scheme.

Claims (5)

1. integrated waste water treatment system, which is characterized in that including heat pump of high-temp water source unit, condensing crystallizing device, be separated by solid-liquid separation Device, vacuum pump and condenser, the heat pump of high-temp water source unit are equipped with hot water delivery pipe, hot water input pipe, cold water efferent duct And cold water inlet pipe, the hot water delivery pipe are connected to the first inlet of the condensing crystallizing device, the hot water input pipe with First liquid outlet of the condensing crystallizing device is connected to, the second liquid outlet of the condensing crystallizing device and the solid-liquid separator into The connection of liquid mouth, the liquid outlet of the solid-liquid separator are connected to the second inlet of the condensing crystallizing device, the cold water output Pipe and cold water inlet pipe are connected to the condenser respectively, and the vacuum pump connects with the condensing crystallizing device and condenser respectively It is logical.
2. integration waste water treatment system according to claim 1, which is characterized in that be additionally provided on the solid-liquid separator Crystal discharge outlet.
3. integration waste water treatment system according to claim 1, which is characterized in that be additionally provided with and distillate on the condenser Liquid discharge outlet.
4. integration waste water treatment system according to claim 1, which is characterized in that be equipped with liquid in the condensing crystallizing device Bit detector.
5. integration waste water treatment system according to claim 1, which is characterized in that be equipped with object in the condensing crystallizing device Expect concentration detector.
CN201820892820.XU 2018-06-06 2018-06-06 Integrated waste water treatment system Active CN208545143U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114057341A (en) * 2021-12-02 2022-02-18 无锡星亿智能环保装备股份有限公司 Electroplating production line evaporation device with collection function

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114057341A (en) * 2021-12-02 2022-02-18 无锡星亿智能环保装备股份有限公司 Electroplating production line evaporation device with collection function

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Effective date of registration: 20200107

Address after: 528000 Building 8, Xinyue Road, Wusha community residents committee, Daliang sub district office, Shunde District, Foshan City, Guangdong Province

Patentee after: Guangdong Fenlan Environmental Technology Co., Ltd.

Address before: 510000 3 Tianyuan Road, Dagang Town, Nansha District, Guangzhou, Guangdong

Patentee before: Guangdong Environmental Protection Technology Co. Ltd. hereby Cervantes