CN208372832U - A kind of reducing agent supply system for SCR denitration - Google Patents

A kind of reducing agent supply system for SCR denitration Download PDF

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Publication number
CN208372832U
CN208372832U CN201820612178.5U CN201820612178U CN208372832U CN 208372832 U CN208372832 U CN 208372832U CN 201820612178 U CN201820612178 U CN 201820612178U CN 208372832 U CN208372832 U CN 208372832U
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China
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supply system
spray gun
reducing agent
ammonium hydroxide
agent supply
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CN201820612178.5U
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王丽霞
沈宏伟
郭无双
钱琨
蒋海峰
刘海舰
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Everbright Envirotech China Ltd
Everbright Environmental Protection Research Institute Nanjing Co Ltd
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Everbright Envirotech China Ltd
Everbright Environmental Protection Research Institute Nanjing Co Ltd
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Abstract

The utility model provides a kind of reducing agent supply system for SCR denitration, the reducing agent supply system for SCR denitration includes: spray gun, the spray gun is arranged on the flue of connection house outlet and SCR reactor inlet, the ammonium hydroxide for the jet atomization into the flue;And the ammonium hydroxide feed system and compressed-air supply system of the connection spray gun.Reducing agent supply system provided by the utility model for SCR denitration directly heats the ammonium hydroxide after spray gun atomization using the hot fume of house outlet, traditional two processes of ammonia preparation and injection are combined into one, not only eliminate additional heating equipment, ammonia spraying equipment etc., keep technique simpler, and significantly reduces energy consumption.

Description

A kind of reducing agent supply system for SCR denitration
Technical field
The utility model relates to denitrating flue gas fields, supply system in particular to a kind of reducing agent for SCR denitration System.
Background technique
With the worsening of ecological environment, one of the problem of being treated as extensive concern of rubbish.In waste incineration Cheng Zhonghui, which is generated, contains HCl, SO2、NOxEtc. harmful substances flue gas, need to handle the flue gas, can be arranged after up to standard It puts.
Selective catalytic reduction (Selective Catalytic Reduction, SCR) denitration technology is in catalyst Under the conditions of existing, so that NOxWith reducing agent NH3A kind of technology that can be reacted under low temperature (150-400 DEG C).It is common Reactant include liquefied ammonia, ammonium hydroxide and urea.Since above-mentioned reactant is liquid or solid-state, needed before entering reaction module It is gasified in advance, more rapid and better to be mixed with flue gas, and prevents drop from damaging to reactor and catalyst.
In above-mentioned three kinds of reactants, it is minimum that liquefied ammonia prepares ammonia cost, but liquefied ammonia belongs to the product of being in extreme danger, and safety is difficult To ensure, especially use in metropolitan district;For urea ammonia mode although comparatively safe, preparation cost is excessively high;It is comprehensive and Speech, ammonium hydroxide compare suitable for waste incineration SCR denitration.However, there are system complex, occupied area for currently used ammonia still Greatly, the disadvantages of waste water handling problem;Ammonium hydroxide evaporation tank systems effectively prevent the above problem, but need to provide additional heat Source, it is not energy saving enough, in addition, the technical process for being prepared into injection from ammonia is complex, it is difficult to control.
Therefore, it is necessary to a kind of new reducing agent supply system for SCR denitration be proposed, to solve the above problems.
Utility model content
A series of concept of reduced forms is introduced in utility model content part, this will be in specific embodiment part Middle further description.The utility model content part of the utility model is not meant to attempt to limit claimed Technical solution key feature and essential features, do not mean that the guarantor for attempting to determine technical solution claimed more Protect range.
In order at least be partially solved the above problem, the utility model discloses a kind of reducing agent confessions for SCR denitration To system, the reducing agent supply system for SCR denitration includes: spray gun, and the spray gun setting is in connection house outlet Ammonium hydroxide on the flue of SCR reactor inlet, for from the jet atomization to the flue;And the ammonium hydroxide of the connection spray gun Feed system and compressed-air supply system.
Illustratively, the reducing agent supply system further includes being arranged vertically in the flue in the spray gun downstream Mixed plate, the mixed plate include and the consistent baffle of the number of the spray gun, the nozzle location of the baffle and the spray gun It is corresponding.
Illustratively, the baffle is fixedly connected by support frame.
Illustratively, the shape of the baffle is circle.
Illustratively, the number of the spray gun is no less than three, and the spray gun is uniform on the sustained height of the flue Arrangement.
Illustratively, when the section of the flue is rectangular, the number of the spray gun is four;When cutting for the flue When face is round, the number of the spray gun is three.
Illustratively, ammonium hydroxide of the spray gun relative to atomization described in the hot fume upstream injection in the flue.
Illustratively, the nozzle of the spray gun is 45 ° -60 ° to the spray angle of the ammonium hydroxide of the atomization.
Illustratively, the atomizing particle size of the ammonium hydroxide is 100 μm or less.
Illustratively, the ammonium hydroxide feed system includes sequentially connected tank used for storing ammonia, ammonium hydroxide delivery pump and ammonium hydroxide point With unit, the compressed-air supply system includes sequentially connected compressed air source and compressed air allocation unit.
Reducing agent supply system provided by the utility model for SCR denitration is straight using the hot fume of house outlet Traditional ammonia is prepared and two processes of injection is combined into one, not only eliminated additional by the ammonium hydroxide after connecing heat gun atomization Heating equipment, ammonia spraying equipment etc., keep technique simpler, and significantly reduce energy consumption.
Detailed description of the invention
The following drawings of the utility model is used to understand the utility model in this as a part of the utility model.Attached drawing In show the embodiments of the present invention and its description, for explaining the principles of the present invention.
In attached drawing:
Fig. 1 shows the structure of the reducing agent supply system for SCR denitration according to one embodiment of the utility model Schematic diagram.
Fig. 2 shows according to the spray in the reducing agent supply system for SCR denitration of one embodiment of the utility model Rifle arrangement schematic diagram.
Fig. 3 shows mixed in the reducing agent supply system for SCR denitration according to one embodiment of the utility model The structural schematic diagram of plywood.
Specific embodiment
In the following description, a large amount of concrete details are given more thoroughly to manage in order to provide to the utility model Solution.It is, however, obvious to a person skilled in the art that the utility model may not need it is one or more of these thin It saves and is carried out.In other examples, in order to avoid obscuring with the utility model, for more well known in the art Technical characteristic is not described.
In order to thoroughly understand the utility model, detailed step will be proposed in following description, it is practical to illustrate The reducing agent supply system for SCR denitration of novel proposition.Obviously, the execution of the utility model is not limited to this field The specific details that technical staff is familiar with.The preferred embodiment of the utility model is described in detail as follows, however in detail in addition to these Description is outer, and the utility model can also have other embodiments.
It should be understood that when the term " comprising " and/or " including " is used in this specification, indicating described in presence Feature, entirety, step, operation, element and/or component, but do not preclude the presence or addition of other one or more features, entirety, Step, operation, element, component and/or their combination.
Selective catalytic reduction (Selective Catalytic Reduction, SCR) denitration technology is in catalyst Under the conditions of existing, so that NOxWith reducing agent NH3A kind of technology that can be reacted under low temperature (150-400 DEG C).It is common Reactant include liquefied ammonia, ammonium hydroxide and urea.Since above-mentioned reactant is liquid or solid-state, needed before entering reaction module It is gasified in advance, more rapid and better to be mixed with flue gas, and prevents drop from damaging to reactor and catalyst.
For different types of reducing agent, used by ammonia mode processed it is also different.It is general to use for weak aqua ammonia Ammonia still produces ammonia, using thermophore water vapour as heating agent, the equilibrium vapour pressure for recycling ammonia in water level is made to be greater than heat The partial pressure of ammonia in carrier, gas-liquid two-phase counter current contacting carry out mass-and heat-transfer, so that ammonia be made gradually to release from recirculated water Come, obtains the mixture of ammonia steam and water vapour in tower top, obtain purer recirculated water in tower bottom.In addition, there are also use ammonia Evaporator tank is ammonium hydroxide evaporation equipment, mainly hot-air or hot fume is obtained by steam heating or electric heating, into evaporator tank In with atomizing lance spray into ammonium hydroxide mix, ammonium hydroxide be heated is evaporated to dilution ammonia.For urea, using hydrolysis or pyrolysis side Formula.For liquefied ammonia, ammonia is generally flashed to using heat evaporating device, is used in coal-burning power plant more.Above-mentioned several ammonia processed The ammonia gas mixture that mode generates needs to pass through again in the flue before ammonia-spraying grid is sprayed into SCR reactor.
In above-mentioned three kinds of reactants, it is minimum that liquefied ammonia prepares ammonia cost, but liquefied ammonia belongs to the product of being in extreme danger, and safety is difficult To ensure, especially use in metropolitan district;For urea ammonia mode although comparatively safe, preparation cost is excessively high;It is comprehensive and Speech, ammonium hydroxide compare suitable for waste incineration SCR denitration.However, there are system complex, occupied area for currently used ammonia still Greatly, the disadvantages of waste water handling problem;Ammonium hydroxide evaporation tank systems effectively prevent the above problem, but need to provide additional heat Source, it is not energy saving enough, in addition, the technical process for being prepared into injection from ammonia is complex, it is difficult to control.
For at least one above-mentioned problem, the utility model provides a kind of reducing agent supply system for SCR denitration, The reducing agent supply system includes: spray gun, and the flue of connection house outlet and SCR reactor inlet is arranged in the spray gun On, the ammonium hydroxide for the jet atomization into the flue;And the ammonium hydroxide feed system and compressed air of the connection spray gun supply To system.
Reducing agent supply system provided by the utility model for SCR denitration is straight using the hot fume of house outlet Traditional ammonia is prepared and two processes of injection is combined into one, not only eliminated additional by the ammonium hydroxide after connecing heat gun atomization Heating equipment, ammonia spraying equipment etc., keep technique simpler, and significantly reduce energy consumption.
System is supplied below with reference to the reducing agent for SCR denitration of Fig. 1, Fig. 2 and Fig. 3 to one embodiment of the utility model System is described in detail.
As shown in Figure 1, reducing agent supply system provided by the present embodiment includes spray gun 105, the setting of spray gun 105 exists On the flue 106 for connecting house outlet and 101 entrance of SCR reactor, the ammonia for the jet atomization into the flue 106 Water;The spray gun 105 is connected with ammonium hydroxide feed system and compressed-air supply system.The reducing agent supply system directly passes through Spray gun 105 sprays into the ammonia spirit of atomization in the flue 106 between house outlet and 101 entrance of SCR reactor, utilizes cigarette Traditional ammonia is prepared to generate ammonia and two processes of injection closes two by the heat direct gasification ammonium hydroxide of hot fume in road 106 It is one, not only eliminates additional heating equipment, ammonia spraying equipment etc., keep technique simpler, and significantly reduce energy Consumption.
Wherein, the ammonium hydroxide feed system supplies ammonium hydroxide to the spray gun 105, and the compressed-air supply system is to described Spray gun 105 supplies compressed air, and the ammonium hydroxide into spray gun 105 is atomized the ammonium hydroxide for atomization under the action of compressed air.Example Property, the ammonium hydroxide feed system includes sequentially connected tank used for storing ammonia 102, ammonium hydroxide delivery pump 103 and ammonium hydroxide allocation unit 104, the compressed-air supply system includes sequentially connected compressed air source and compressed air allocation unit 107.The pressure Contracting air-source can be the station-service compressed air from station-service compressed air line.Certain density ammonia spirit is conveyed through ammonium hydroxide Pump 103 is delivered to ammonium hydroxide allocation unit 104 from tank used for storing ammonia 102, passes through the metering control tune in ammonium hydroxide allocation unit 104 Ammonium hydroxide is sent into the ammonium hydroxide interface of spray gun 105, compressed air is delivered to through compressed air allocation unit 107 after amount of restriction and pressure The compressed air interface of spray gun 105, the ammonium hydroxide into spray gun 105 are atomized under the action of compressed air, and with carry out Self-duster The hot fume of outlet sprays into flue 106 in countercurrent direction.The ammonium hydroxide droplet that atomization generates absorbs the heat of flue gas in flue 106 Amount, gasification is ammonia and water vapour rapidly, and is mixed into certain density ammonia/flue gas gaseous mixture with flue gas, and it is anti-to enter back into SCR Device 101 is answered to carry out denitration reaction.
In one embodiment, the ammonium hydroxide that spray gun 105 is atomized relative to hot fume upstream injection, to effectively extend ammonia The incorporation time of water and hot fume has better ammonium hydroxide/hot fume mixed effect.It illustratively, can also be by controlling ammonium hydroxide The preferred equal measures of solution concentration and compressed air pressure and spray gun, make the atomizing particle size of ammonium hydroxide at 100 μm hereinafter, spray gun The jet angle of 105 nozzle is 45 ° -60 °.Reasonable lance ejection angle and atomizing particle size are capable of increasing ammonium hydroxide drop and flue gas Contact area, to guarantee that ammonium hydroxide sprays into Quick-gasifying after flue 106.
The number of the spray gun 105 is no less than three, also, the spray gun 105 is uniform on the sustained height of flue 106 Distribution, equally distributed arrangement keep the ammonium hydroxide ejected distribution more uniform.Illustratively, when the cross section of flue 106 When being rectangular, it is evenly arranged on the sustained height of the flue 106 there are four spray gun 105;The cross section of flue 106 is circle When, it is evenly arranged on the sustained height of the flue 106 there are three spray gun.As an example, in the present embodiment, it is described uniformly to divide Cloth refers to that the central axis for being positioned around flue 106 of the nozzle of each spray gun 105 is equidistantly positioned.Fig. 2 is transversal when flue 106 When face is rectangular, arrangement schematic diagram of the spray gun 105 on flue 106.
After being heated due to atomized drop, ammonia is quickly evaporated than water vapour, and the ammonia on the section of air-flow is caused easily to collect In at the nozzle location, ammonia and flue gas mixing are uneven, therefore in the present embodiment, in 105 downstream of spray gun, one spacing Mixed plate 108 is disposed with perpendicular to flue 106 in flue 106 from place.When the section of flue 106 is rectangular, it is applicable in The structural schematic diagram of mixed plate 108 is as shown in Figure 3.Mixed plate 108 includes mainly circle corresponding with the nozzle location of spray gun 105 Shape baffle 108a (by taking the number of spray gun 105 is four as an example), circular baffle plate 108a is fixedly connected by support frame 108b.Work as gas Stream can stream when flowing near circular baffle plate 108a, mix to play the role of reinforcement ammonia with hot fume.
Reducing agent supply system provided by the utility model for SCR denitration has the advantages that
1, the ammonium hydroxide after spray gun atomization is directly heated using the hot fume of house outlet, traditional ammonia is prepared and sprayed It penetrates two processes to be combined into one, not only eliminates additional heating equipment, ammonia spraying equipment etc., keep technique simpler, and And significantly reduce energy consumption;
2, the flexible arrangement of spray gun, the mode being evenly arranged keep the ammonium hydroxide ejected distribution more uniform;
3, spray gun counter-flow arrangement can effectively extend the incorporation time of ammonium hydroxide and hot fume, have better ammonium hydroxide/hot fume Mixed effect;
4, reasonable lance ejection angle and tiny atomizing particle size increase the contact area of ammonium hydroxide drop and hot fume, from And guarantee the Quick-gasifying of ammonium hydroxide;
5, distinctive mixed plate design structure is simple, ammonia can be made to be more fully mixed with flue gas, is conducive to improve subsequent The efficiency of SCR denitration reaction.
In conclusion reducing agent supply system provided by the present invention is simple and efficient, takes up little area, cost is relatively low, operation peace It is complete reliable, it is suitable for burning power plant.
Unless otherwise defined, the technology of technical and scientific term used herein and the technical field of the utility model The normally understood meaning of personnel is identical.Term used herein is intended merely to describe specifically to implement purpose, it is not intended that limit The utility model processed.Terms such as herein presented " settings " can both indicate that a component was attached directly to another portion Part can also indicate that a component is attached to another component by middleware.The spy described in one embodiment herein Sign can be applied in combination another embodiment individually or with other feature, unless this feature is in another embodiment It is not suitable for or is otherwise noted.
The utility model is illustrated through the foregoing embodiment, but it is to be understood that, above-described embodiment is Purpose for illustrating and illustrating, and be not intended to limit the invention within the scope of described embodiment.Furthermore ability Field technique personnel are it is understood that the utility model is not limited to above-described embodiment, and introduction according to the present utility model is also More kinds of variants and modifications can be made, these variants and modifications all fall within the utility model range claimed with It is interior.The protection scope of the utility model is defined by the appended claims and their equivalents.

Claims (10)

1. a kind of reducing agent supply system for SCR denitration, which is characterized in that the reducing agent supply system includes:
Spray gun, the spray gun are arranged on the flue of connection house outlet and SCR reactor inlet, for into the flue The ammonium hydroxide of jet atomization;And
Connect the ammonium hydroxide feed system and compressed-air supply system of the spray gun.
2. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that further include vertical cloth The mixed plate in the flue in the spray gun downstream is set, the mixed plate includes and the consistent gear of the number of the spray gun Plate, the baffle are corresponding with the nozzle location of the spray gun.
3. the reducing agent supply system according to claim 2 for SCR denitration, which is characterized in that the baffle passes through Support frame is fixedly connected.
4. the reducing agent supply system according to claim 2 for SCR denitration, which is characterized in that the shape of the baffle Shape is circle.
5. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that the number of the spray gun Mesh is no less than three, and the spray gun is evenly arranged on the sustained height of the flue.
6. the reducing agent supply system according to claim 5 for SCR denitration, which is characterized in that when the flue When section is rectangular, the number of the spray gun is four;When the section of the flue is round, the number of the spray gun is three It is a.
7. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that the spray gun is opposite The ammonium hydroxide of atomization described in hot fume upstream injection in the flue.
8. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that the spray of the spray gun Mouth is 45 ° -60 ° to the spray angle of the ammonium hydroxide of the atomization.
9. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that the mist of the ammonium hydroxide Changing partial size is 100 μm or less.
10. the reducing agent supply system according to claim 1 for SCR denitration, which is characterized in that the ammonium hydroxide supply System includes sequentially connected tank used for storing ammonia, ammonium hydroxide delivery pump and ammonium hydroxide allocation unit, the compressed-air supply system packet Include sequentially connected compressed air source and compressed air allocation unit.
CN201820612178.5U 2018-04-25 2018-04-25 A kind of reducing agent supply system for SCR denitration Active CN208372832U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI720730B (en) * 2019-01-30 2021-03-01 日商三菱動力股份有限公司 Reducing agent supply device and denitration device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI720730B (en) * 2019-01-30 2021-03-01 日商三菱動力股份有限公司 Reducing agent supply device and denitration device
US11583803B2 (en) 2019-01-30 2023-02-21 Mitsubishi Heavy Industries, Ltd. Reducing agent supply device and denitration device

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