CN208254996U - A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device - Google Patents

A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device Download PDF

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CN208254996U
CN208254996U CN201820967315.7U CN201820967315U CN208254996U CN 208254996 U CN208254996 U CN 208254996U CN 201820967315 U CN201820967315 U CN 201820967315U CN 208254996 U CN208254996 U CN 208254996U
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measuring device
case
measurement
flue gas
cabinet
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宣添星
杨爱勇
张承武
舒喜
张亚伟
王敏
余思远
杨玥
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Guodian Environmental Protection Research Institute Co Ltd
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Guodian Environmental Protection Research Institute Co Ltd
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Abstract

The utility model belongs to machinery equipment field, more particularly to a kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device, the measuring device includes: measurement case, venthole is provided at the top of measurement case, bottom is provided with thick liquid discharge mouth, is equipped on cabinet and protrudes into the intracorporal densitometer of case and pH meter;The sampling line being connected with measurement case, for being connected with the tower bottom of smoke-gas wet desulfurization tower, the other end is extend into the cabinet of measurement case for one end of sampling line;Sampling line extend into the intracorporal one end of case and is provided with spray head.In the present invention, the slurries of smoke-gas wet desulfurization tower tower bottom are entered in the measurement case of measuring device by the sampling line of measuring device, by that will measure the control of the liquid level of slurry in case in the sensor for not crossing densitometer and pH meter, measurement obtains the density and pH value of slurries.Measuring device provided by the utility model can realize that gypsum slurries are accurately measured in the low-maintenance of line density and pH value, consistently online and height.

Description

A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device
Technical field
The utility model belong to machinery equipment field more particularly to a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and PH value combined measurement device.
Background technique
Recent years, with the serious of environmental pollution, country has put into effect a series of policies and thermal power plant is encouraged to implement to surpass Low emission transformation, is transformed after-burning coal smoke power-plant flue gas SO2Concentration of emission requires control in 35mg/Nm3Hereinafter, this is to desulphurization system Safe and economical operation proposes tightened up requirement.Currently, in Limestone-gypsum Wet Flue Gas Desulfurization Process system, gypsum slurries density It is two important parameters of Limestone-gypsum Wet Flue Gas Desulfurization Process with pH value, operation, the control of whole system is played vital Effect.Gypsum slurries pH value is one of the main control parameters of Limestone-gypsum Wet Flue Gas Desulfurization Process technique, to the shadow of desulfuration efficiency Sound is the most significant, and selecting suitable pH value is one of the key factor that guarantee system is well run.Under normal circumstances, absorption tower is starched Liquid pH value should control between 5.0~5.4.In actual operation, it should find and this desulphurization system pH value is suitble to operate control range, While the indexs such as desulfuration efficiency reach requirement, system energy consumption is reduced.Serum density control is mainly by keeping absorption tower Output balance, the slurries delivery flow on absorption tower is controlled to realize.It is absorbed simultaneously by adjusting to return from hydrocyclone The spillway discharge and underflow slurry liquid measure of tower carry out stable slurry density.The stable desulfuration efficiency for improving system of holding serum density, The quality of by-produced gypsum and equipment scaling is prevented to be advantageous.Gypsum slurries density is controlled in operation in a suitable model (1080~1100kg/m in enclosing3), be conducive to the efficient, economic of desulphurization system and safe operation.It controls and joins in view of two above Several importance, it is therefore necessary to configure on-line continuous combined measurement device, realize gypsum slurries pH value that absorption tower be discharged with The accurate measurement of density, to guarantee the safe and stable operation of desulphurization system.
Desulfurizer gypsum slurries pH value is often with measurement method at present: installing on gypsum slurries slurry pump outlet conduit Branch pipe installs plug-in type pH electrode on branch pipe, while introducing flushing water, rinses pH electrode.The disadvantage is that: pH electricity in outlet conduit Slurry flow rate at pole is higher, fluid erosion electrode easy to wear;Rinse mouth face electrode, the interior water flow velocity that rinses of pipeline is larger, meeting Impact failure electrode, causes glass electrode to rupture when serious, is not available;Gypsum particle causes to dismantle in surrounding them fouling Difficulty is not easy to periodic calibrating.When system shutdown for a period of time when, also need a pH electrode to remove and be immersed in the water protection, otherwise Exposure in air, will affect measurement accuracy, will lead to electrode failure when serious and scrap electrode for a long time.This increases operation and maintenance Personnel's maintenance.
Desulfurizer gypsum slurries density often with measurement method is set on the outlet conduit of gypsum slurries discharge pump at present A bit of slurries shunt valve is set, slurries are introduced into shunt valve, density measure is carried out by duct type mass flowmenter.But it bypasses The caliber of pipeline is smaller, and there is strict demand in while measuring serum density to flow velocity, and deposition, blocking measurement are also easy to produce when flow velocity is low Pipe;When flow velocity is high slurries to measurement transducer wall's abrasion it is larger, influence measurement accuracy, when serious can worn out measurement pipe, lead to quality stream Meter is scrapped.The caliber difference of shunt valve and main pipeline can make the slurry flow rate of measurement point generate biggish fluctuation, be difficult to control, Therefore cause mass flowmenter that cannot run steadily in the long term.
Gypsum slurries density and pH value cannot reliable, accurately on-line measurement, desulphurization system just can not timely for slurry and Plasma discharge, pH value is too low also to will cause that system corrosion is serious, reduces the service life of equipment, in addition make desulphurization system be difficult to it is economical, The operation of safety.Therefore, a kind of low-maintenance, consistently online, high accurately gypsum slurries density and pH value combined measurement dress are developed It sets, is those skilled in the art's technical problem urgently to be resolved.
Utility model content
In view of this, the purpose of this utility model is to provide a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and pH Be worth combined measurement device, device provided by the utility model realize gypsum slurries the low-maintenance of line density and pH value, continue Online and height accurately measures.
The utility model provides a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and pH value combined measurement device, packet It includes:
Case is measured, is provided with venthole at the top of the measurement case, bottom is provided with thick liquid discharge mouth, is equipped with and protrudes on cabinet The intracorporal densitometer of case and pH meter;
The sampling line being connected with the measurement case, one end of the sampling line is for the tower with smoke-gas wet desulfurization tower Bottom is connected, and the other end is extend into the cabinet of the measurement case;The sampling line extend into the intracorporal one end setting of the case There is spray head.
Preferably, the sampling line is disposed with sampling electric butterfly valve along slurries flow direction and sampling manually adjusts Diaphragm valve.
Preferably, flushing water water inlet is additionally provided on the sampling line.
Preferably, the measuring device further includes the water flushing pipeline being connected with the flushing water water inlet;The water punching It washes and is provided with electric butterfly valve on pipeline.
Preferably, the measuring device further includes the plasma discharge pipeline being connected with the thick liquid discharge mouth;The discharge pipe road is set It is equipped with plasma discharge electric butterfly valve.
Preferably, the densitometer is mounted on the side wall of the cabinet;
The pH meter is mounted on the top of the cabinet.
Preferably, the density is calculated as tuning-fork type densitometer;
The pH meter is immersion abrasion-resistance glass electrode pH meters.
Preferably, overflow port is provided on the side wall of the measurement case.
Preferably, the cabinet top of the measurement case is cylindrical shape, and lower part is cone.
Compared with prior art, the utility model provides a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and pH value Combined measurement device.Measuring device provided by the utility model includes: measurement case, is provided with ventilation at the top of the measurement case Hole, bottom are provided with thick liquid discharge mouth, are equipped on cabinet and protrude into the intracorporal densitometer of case and pH meter;It is taken with what the measurement case was connected Sample pipeline, for being connected with the tower bottom of smoke-gas wet desulfurization tower, the other end extend into the measurement for one end of the sampling line In the cabinet of case;The sampling line extend into the intracorporal one end of the case and is provided with spray head.In the present invention, flue gas The slurries of wet desulfuration tower tower bottom are entered in the measurement case of the measuring device by the sampling line of the measuring device, are passed through By the liquid level of slurry control in the measurement case in the sensor of the excessively not described densitometer and the sensor of the pH meter, measurement Obtain the density and pH value of slurries.Due to the sampling line and smoke-gas wet desulfurization tower of measuring device provided by the utility model Tower bottom is connected, and can obtain the gypsum slurries of desulfurizing tower tower bottom in real time and measure its density and pH value, to realize to calcium plaster The measurement of the consistently online of liquid density and pH value.Since measuring device provided by the utility model is provided with spray head, measuring device When operation, slurries to be measured, which need to flow through spray head, to be made just enter after its volume dilatation in measurement case, so as to abolish gypsum Bubble in slurries realizes steam-water separation, and then guarantees fluid state required for densimeter measurement, reduces gypsum slurries bubble Influence densimeter measurement accuracy.Due to measuring device provided by the utility model be arranged thick liquid discharge mouth, measuring device at runtime, The thick liquid discharge mouth that bottom portion can be measured by opening excludes measurement case solid, prevents from blocking;When stoppage in transit maintenance, it can pass through to close and survey The thick liquid discharge mouth of measuring tank bottom makes measurement case maintain liquid level, submerges the sensor of pH meter in a liquid, prevents measuring electrode dry Puckery damage.Flushing water water inlet is additionally provided in preferred embodiment provided by the utility model, on sampling line, it can be achieved that survey Amount device is timed flushing, prevents slurries product stream blocking for a long time.As it can be seen that can by measuring device provided by the utility model It realizes that gypsum slurries are accurately measured in the low-maintenance of line density and pH value, consistently online and height, keeps desulfurizer safer, economical Operation.
Detailed description of the invention
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is the embodiments of the present invention, for those of ordinary skill in the art, without creative efforts, also Other attached drawings can be obtained according to the attached drawing of offer.
Fig. 1 is flue gas wet flue gas desulfurization gypsum serum density provided by the embodiment of the utility model and the online combined measurement of pH value Device.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work Every other embodiment obtained, fall within the protection scope of the utility model.
The utility model provides a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and pH value combined measurement device, packet It includes:
Case is measured, is provided with venthole at the top of the measurement case, bottom is provided with thick liquid discharge mouth, is equipped with and protrudes on cabinet The intracorporal densitometer of case and pH meter;
The sampling line being connected with the measurement case, one end of the sampling line is for the tower with smoke-gas wet desulfurization tower Bottom is connected, and the other end is extend into the cabinet of the measurement case;The sampling line extend into the intracorporal one end setting of the case There is spray head.
It is that flue gas wet flue gas desulfurization gypsum serum density provided by the embodiment of the utility model and pH value are online referring to Fig. 1, Fig. 1 Combined measurement device.Wherein, 1 is sampling line, and 2 manually adjust diaphragm valve for sampling electric butterfly valve, 3 for sampling, and 4 be overflow Mouthful, 5 be spray head, and 6 be pH meter, and 7 be densitometer, and 8 be measurement case, and 9 be observation window of liquid level, and 10 be venthole, and 11 be thick liquid discharge mouth, 12 be plasma discharge electric butterfly valve, and 13 be water flushing pipeline, and 14 rinse electric butterfly valve for water.
Measuring device provided by the utility model includes sampling line 1 and measurement case 8.Wherein, one end of sampling line 1 is used It is connected in the tower bottom of smoke-gas wet desulfurization tower, the other end is extend into the cabinet of measurement case 8, is used for smoke-gas wet desulfurization tower Gypsum slurries be delivered to measurement case 8, the mode of conveying is preferably flow automatically.In the present invention, gypsum slurries in order to prevent Corrosive wear pipeline, sampling line 1 preferably use DN80 inner liner rubber carbon steel pipe.
In the present invention, sampling line 1 is preferably disposed with sampling electric butterfly valve 2 along slurries flow direction and takes Sample manually adjusts diaphragm valve 3.Wherein, sampling electric butterfly valve 2 is used to open or closes sampling line 1, by opening the electronic butterfly Valve, smoke-gas wet desulfurization tower gypsum slurries flow to measurement case 8 along sampling line 1, which closes when needing to stop transport or rinse The electric butterfly valve;Sampling manually adjusts diaphragm valve 3 for the height of liquid level according to smoke-gas wet desulfurization tower, manually adjusts probe tube The flow on road 1 achievees the purpose that keep measurement 8 liquid level of case.
In the present invention, be preferably additionally provided with flushing water water inlet on sampling line 1, water rinse can by it is described into The mouth of a river enters in sampling line 1, is timed flushing to sampling line 1 and measurement case 8, to prevent slurries, product stream is stifled for a long time Plug.In the present invention, the flushing water water inlet is preferably provided at sampling electric butterfly valve 2 and sampling manually adjusts diaphragm valve Between 3.In the present invention, it is also preferable to include the water flushing pipelines being connected with the flushing water water inlet for the measuring device 13, it is preferably provided with water in the water flushing pipeline 13 and rinses electric butterfly valve 14, so as to rinse electric butterfly valve by switch water 14 realize the flushing being timed to measuring device.In the present invention, water flushing pipeline 13 preferably uses DN50 carbon steel pipe.
In the present invention, sampling line 1 extend into the intracorporal one end of the case and is provided with spray head 5, and spray head 5 On the design liquid level of measurement case 8.In the present invention, the flow of spray head 5 is preferably 270L/min;Spray head 5 Inlet pressure is preferably 0.5bar;The connection size of spray head 5 is preferably 1-1/2;The spray angle of spray head 5 is preferably 70~ 120 °, more preferably 90 °;Spray head 5 is preferably solid-cone (type) nozzle.In the present invention, slurries can make volume by spray Dilatation realizes steam-water separation, and then guarantee flow-like required for densimeter measurement to abolish the bubble in gypsum slurries State.In the present invention, gypsum slurries corrosive wear spray head, the material of spray head 5 are preferably 316L stainless in order to prevent Steel.
In the present invention, it measures to be equipped on the cabinet of case 8 and protrudes into the intracorporal pH meter 6 of case and densitometer 7, be used to The pH value and density of line measurement slurries.In the present invention, pH meter 6 is preferably immersion abrasion-resistance glass electrode pH meters, pH meter 6 It is preferably mounted at the top of the cabinet, the mode of installation is preferably inserted type of flange installation.In the present invention, densitometer 7 preferably tuning-fork type densitometer, densitometers 7 are preferably mounted on the side wall of the cabinet, and the mode of installation is preferably plug-in type Flange installation.
In the present invention, the top for measuring case 8 is provided with venthole 10, for maintaining the pressure in measurement case 8 flat Weighing apparatus.
In the present invention, the bottom for measuring case 8 is provided with thick liquid discharge mouth 11, and playing exclusion measurement 8 solid of case prevents from blocking up The purpose of plug, it should be noted that both the row of being able to achieve is solid for thick liquid discharge mouth 11, avoids the intracorporal slurry emptying of case again.It is practical at this In novel, the measuring device further includes the plasma discharge pipeline being connected with thick liquid discharge mouth 11, and the plasma discharge pipeline preferably uses in DN80 Line with rubber carbon steel pipe.In the present invention, the discharge pipe road is preferably provided with plasma discharge electric butterfly valve 12, is used to open or closes Discharge pipe is closed, the opening when measuring device puts into operation, for discharging gypsum slurries, the measuring device is closed when stopping transport, made Measurement case 8 maintains liquid level, submerges the sensor of pH meter 6 in a liquid, prevents the dry and astringent damage of the sensor of pH meter.
In the present invention, it measures and is preferably additionally provided with overflow port 4 on the side wall of case 8, maintain to survey using overflow port 4 The liquid level of measuring tank 8.In the present invention, the measuring device is described it is also preferable to include the overflow passage being connected with overflow port 4 The other end of overflow passage is passed through the melt pit of smoke-gas wet desulfurization tower, and the overflow port 4 is preferably DN100 inner liner rubber carbon steel pipe.
In the present invention, it measures and is preferably additionally provided with observation window of liquid level 9 on the side wall of case 8 for observing and measuring case liquid Position.
In the present invention, the material for measuring case 8 is preferably polypropylene (PP);The cabinet top of measurement case 8 is preferably Cylindrical shape, lower part are preferred conical, conical horizontal tilt angle preferably ≮ 60 °.
The utility model additionally provides a kind of flue gas wet flue gas desulfurization gypsum slurries in line density and pH value union measuring method, The following steps are included:
A) slurries of smoke-gas wet desulfurization tower tower bottom through the above technical solution the measuring device sampling line enter In the measurement case of the measuring device;
B) by the liquid level of slurry control in the measurement case excessively not described densitometer sensor and the pH meter Sensor, measurement obtain the density and pH value of slurries.
It, can since the sampling line of measuring device provided by the utility model is connected with the tower bottom of smoke-gas wet desulfurization tower The gypsum slurries for obtaining desulfurizing tower tower bottom in real time simultaneously measure its density and pH value, to realize to gypsum slurries density and pH value Consistently online measurement.Since measuring device provided by the utility model is provided with spray head, when measuring device is run, slurries to be measured Needing to flow through spray head makes just enter after its volume dilatation in measurement case, real so as to abolish the bubble in gypsum slurries Existing steam-water separation, and then guarantee fluid state required for densimeter measurement, reduce gypsum slurries aeration densimeter measurement Accuracy.Since thick liquid discharge mouth is arranged in measuring device provided by the utility model, measuring device at runtime, can be measured by opening The thick liquid discharge mouth in bottom portion excludes measurement case solid, prevents from blocking;When stoppage in transit maintenance, the plasma discharge for closing measurement bottom portion can be passed through Mouthful, so that measurement case is maintained liquid level, submerges the sensor of pH meter in a liquid, prevent the dry and astringent damage of measuring electrode.In this reality Flushing water water inlet is additionally provided in preferred embodiment with novel offer, on sampling line, it can be achieved that determining measuring device Shi Chongxi prevents slurries product stream blocking for a long time.As it can be seen that can realize gypsum slurries by measuring device provided by the utility model It is accurately measured in the low-maintenance of line density and pH value, consistently online and height, makes that desulfurizer is safer, economical operation.
For the sake of becoming apparent from, it is described in detail below by following embodiment.
Embodiment 1
The flue gas wet flue gas desulfurization gypsum serum density and pH value for present embodiments providing a kind of structure as shown in Figure 1 join online Close measuring device, including sampling line 1, sampling electric butterfly valve 2, sampling manually adjust diaphragm valve 3, overflow port 4, spray head 5, pH Meter 6, densitometer 7, measurement case 8, observation window of liquid level 9, venthole 10, thick liquid discharge mouth 11, plasma discharge electric butterfly valve 12, water flushing pipeline 13, water rinses electric butterfly valve 14, flushing water water inlet (Fig. 1 is not marked), overflow passage (Fig. 1 is not marked) and plasma discharge pipeline (Fig. 1 It does not mark).Wherein, the connection relationship of each component, optional material and function hereinbefore by the agency of, details are not described herein.
In the present embodiment, spray head 5 is solid-cone (type) nozzle, inlet pressure 0.5bar, connection size 1-1/2, jet angle Degree is 90 °.
In the present embodiment, the cabinet top for measuring case 8 is cylindrical shape, and size φ 800, height 900mm, lower part is circle Cone, cone height 700mm, conical horizontal tilt angle ≮ 60 degree.The setting of densitometer 7 height is from measurement 8 bottom of cylinder of case The top of measurement case 8 is arranged in from measurement 8 bottom of cylinder 400mm of case, pH meter 6 in 200mm, the setting of overflow port 4 height.
The measuring device carrying out practically operating condition: 8~12wt% of solid content of fed slurry when operation, feed rate 270~ 300L/min, liquid level maintain height from measurement case bottom of cylinder 400mm, and pH meter determination data is 5~5.8, density measurement data In 1050~1100kg/m3, per tour (6~12h) is rinsed primary.Measuring device operation 1 year or more, do not occur blocking and measuring different Often.
The above is only the preferred embodiment of the utility model, it is noted that for the common skill of the art For art personnel, without departing from the principle of this utility model, several improvements and modifications can also be made, these improve and Retouching also should be regarded as the protection scope of the utility model.

Claims (9)

1. a kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device, comprising:
Case is measured, is provided with venthole at the top of the measurement case, bottom is provided with thick liquid discharge mouth, is equipped on cabinet and protrudes into cabinet Interior densitometer and pH meter;
The sampling line being connected with the measurement case, one end of the sampling line is for the tower bottom phase with smoke-gas wet desulfurization tower Even, the other end is extend into the cabinet of the measurement case;The sampling line extend into the intracorporal one end of the case and is provided with spray Drench head.
2. measuring device according to claim 1, which is characterized in that the sampling line is successively set along slurries flow direction It is equipped with sampling electric butterfly valve and sampling manually adjusts diaphragm valve.
3. measuring device according to claim 1, which is characterized in that be additionally provided with flushing water water inlet on the sampling line Mouthful.
4. measuring device according to claim 3, which is characterized in that the measuring device further include with the flushing water into The connected water flushing pipeline in the mouth of a river;Electric butterfly valve is provided in the water flushing pipeline.
5. measuring device according to claim 1, which is characterized in that the measuring device further includes and the thick liquid discharge mouth phase Plasma discharge pipeline even;The discharge pipe road is provided with plasma discharge electric butterfly valve.
6. measuring device according to claim 1, which is characterized in that the densitometer is mounted on the side wall of the cabinet On;
The pH meter is mounted on the top of the cabinet.
7. measuring device according to claim 1, which is characterized in that the density is calculated as tuning-fork type densitometer;
The pH meter is immersion abrasion-resistance glass electrode pH meters.
8. measuring device according to claim 1, which is characterized in that be provided with overflow port on the side wall of the measurement case.
9. measuring device according to claim 1, which is characterized in that the cabinet top of the measurement case is cylindrical shape, under Portion is cone.
CN201820967315.7U 2018-06-21 2018-06-21 A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device Active CN208254996U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108801850A (en) * 2018-06-21 2018-11-13 国电环境保护研究院有限公司 A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device and measurement method
CN112666045A (en) * 2020-12-18 2021-04-16 浙江佳环工程技术有限公司 System device and method for online continuous measurement of pH value and density
CN113049744A (en) * 2021-02-05 2021-06-29 华电电力科学研究院有限公司 Online pH meter for wet desulphurization and working method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108801850A (en) * 2018-06-21 2018-11-13 国电环境保护研究院有限公司 A kind of flue gas wet flue gas desulfurization gypsum slurries are in line density and pH value combined measurement device and measurement method
CN112666045A (en) * 2020-12-18 2021-04-16 浙江佳环工程技术有限公司 System device and method for online continuous measurement of pH value and density
CN113049744A (en) * 2021-02-05 2021-06-29 华电电力科学研究院有限公司 Online pH meter for wet desulphurization and working method thereof

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