CN208205033U - A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system - Google Patents

A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system Download PDF

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Publication number
CN208205033U
CN208205033U CN201820535048.6U CN201820535048U CN208205033U CN 208205033 U CN208205033 U CN 208205033U CN 201820535048 U CN201820535048 U CN 201820535048U CN 208205033 U CN208205033 U CN 208205033U
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China
Prior art keywords
pipe
incinerator
alkali metal
heat recovery
containing organic
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Expired - Fee Related
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CN201820535048.6U
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Chinese (zh)
Inventor
江彦雄
许俊明
林加向
张聪颖
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Xiamen Baipeng Environmental Protection Technology Co Ltd
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Xiamen Baipeng Environmental Protection Technology Co Ltd
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Priority to CN201820535048.6U priority Critical patent/CN208205033U/en
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Abstract

It include burner, incinerator, fuse salt receiving slit the utility model discloses a kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system, hot gas outlet is provided on incinerator, regulation room is provided on hot gas outlet, regulation room is connected with ceramic screen pipe filter, in this approach, melting salt slurry can be collected or be dissolved in water in solid form and collect as salting liquid.The function of regulation room is that thermal incinerator exhaust gas is rapidly cooled to the fusing point of melting salt slurry or less.Enough residence times are also provided in regulation room, make to melt fully charge inside and outside salt slurry particulate contaminant.Ceramic screen pipe filter has self-cleaning effect, maintains continuous operation, and ceramic screen pipe can withstand up to 900 degree of temperature.Because in most applications, the fusing point of eutectic mixture is about 600 to 650 degree in combustion products gas.Therefore ceramic screen pipe filter can be used for this application.

Description

A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system
Technical field
The utility model relates to a kind of alkali metal containing organic liquid waste and waste water incineration heat recovery systems, more particularly to a kind of time Receive high utilization rate, the convenient alkali metal containing organic liquid waste of recycling and waste water incineration heat recovery system.
Background technique
In chemical industry, there are the waste liquid and waste water of one group of special alkali metal containing, such as sodium, potassium.This waste liquid is burnt It burns, such as the waste liquid from caprolactam factory or acrylonitrile factory, is a kind of oddity problem for needing special designing to consider.Cause To there is the carbon dioxide of a large amount in combustion products gas, without other acid ingredients (such as sulfur dioxide and hydrogen chloride), one A little metals, especially all alkali metal can all form carbonate.However, the formation of carbonate depends on combustion products gas The partial pressure of middle carbon dioxide.Fig. 1 show point of carbon dioxide and basic carbonate under typical combustion product gas condition Solve equalized temperature curve.In the typical silicon dioxide concentration of carbon of combustion products gas, basic carbonate can be in about 980 DEG C of temperature It is decomposed under degree and forms basic anhydride steam.During burning, metal in fuel, metallic element, metal oxide and/or The derivative of metal salt can be steam, liquid and solid state.Solid compounds will give off combustion in the form of bottom ash or flying dust Burn equipment.Steam condition compound can maintain vapor state or be condensed into liquid (melting salt slurry) or solid-state (flying dust) and from Combustion apparatus discharge.After-combustion is needed to handle to remove these emissions.
The metallic compound of molten condition is the compound of high viscosity, and equipment coating will be made along burning and downstream On the exposed surface.Good design and operating practice can just be obtained by assessing their melting temperature.In liquid and solid The metallic compound of cocrystalization compound is not formed on interface, is analyzed very simple.Every kind of metallic compound of eutectic mixture can divide Not solidification (or liquefaction) at different temperature, until all phase changes are completed.However, forming eutectic mixture when containing When the solid system of two or more solids, the fusing point of mixture is not explicitly defined then.Eutectic mixture is typically shown as altogether Crystalline substance composition and eutectic temperature, under this eutectic temperature, all components of mixture melt simultaneously or solidification.It is this to melt simultaneously Or solidification is that referred to as eutectic reaction, the temperature to react are eutectic temperatures, the composition and temperature for reacting generation are eutectic points.
Utility model content
The technical problem to be solved by the utility model is to provide a kind of alkali metal containing organic liquid wastes and waste water incineration heat to return Receipts system has the characteristics that recovery utilization rate is high, recycling is convenient.
In order to solve the above technical problems, the technical solution of the utility model are as follows: a kind of alkali metal containing organic liquid waste and waste water Burn heat recovery system, innovative point is: the alkali metal containing organic liquid waste and waste water incineration heat recovery system include burning Device, the incinerator being connected with the burner, the fuse salt receiving slit being connected with the incinerator are provided on the incinerator Hot gas outlet and the fuse salt outlet being connected with the fuse salt receiving slit are provided with for cold on the hot gas outlet But via the regulation room of the exhaust gas of hot gas outlet discharge, the regulation room is connected with ceramic screen pipe filter, the ceramic filtering Pipe filter is connected with boiler, and the boiler is connected with smoke processing system.
Preferably, Burning Room is provided in the incinerator, the temperature of the Burning Room should be maintained at indoor metal salt Between fusion temperature and 980 degree.
Preferably, slewing equipment, the central axis of the slewing equipment and incinerator center are provided in the Burning Room Axis is overlapped, and the slewing equipment includes that the turning motor, the rotating shaft being connected with the turning motor, setting of revolution is driven to exist The flabellum for being used to guide flow of flue gas on the rotating shaft.
Preferably, the heating dress for improving temperature at fuse salt outlet position is provided on the fuse salt outlet It sets.
Preferably, the fuse salt outlet, which passes through, return pipe, and one end of return pipe is located in Burning Room, return pipe The other end is located in regulation room.
Preferably, the fire resisting divider on incinerator inside is provided on the incinerator at hot gas outlet position.
Preferably, the outlet conduit of the hot gas outlet is provided through on the incinerator at fire resisting divider position.
Preferably, the outlet conduit includes first pipe and the second pipe that is connected to the first pipe, and described Two pipe levels arrange and are connected to the regulation room that the first pipe is arranged in obtuse angle with the second pipe, and first Central axis is diagonally downward.
Preferably, between the first pipe and the second pipe angle between 150-170 degree.
Preferably, angle is 160 degree between the first pipe and the second pipe.
Utility model has the advantages that installing one between the hot gas air exit of incinerator and the entrance of boiler Regulation room.The outlet of thermal incinerator exhaust gas is usually located at the side of the incinerator to burn vertically downward, and melts salt slurry, as before It is described, by incinerator bottom discharge.In this approach, melting salt slurry can be collected or be dissolved in water in solid form and make For salting liquid collection.The function of regulation room is that thermal incinerator exhaust gas is rapidly cooled to the fusing point of melting salt slurry or less.It is adjusting Section also provides enough residence times in room, makes to melt fully charge inside and outside salt slurry particulate contaminant.Ceramic screen pipe filter tool There is self-cleaning effect, maintain continuous operation, ceramic screen pipe can withstand up to 900 degree of temperature.Because in most of applications In, the fusing point of eutectic mixture is about 600 to 650 degree in combustion products gas.Therefore ceramic screen pipe filter can be used for this Kind application.
Detailed description of the invention
Utility model will be further described in detail below with reference to the attached drawings and specific embodiments.
Fig. 1 is the structural schematic diagram of a kind of alkali metal containing organic liquid waste of the utility model and waste water incineration heat recovery system.
Fig. 2 is incinerator in a kind of alkali metal containing organic liquid waste of the utility model and waste water incineration heat recovery system, adjusts The partial structure diagram of room.
In figure: 1- burner, 2- incinerator, 3- fuse salt receiving slit, 4- hot gas outlet, 5- fuse salt outlet, 6- Regulation room, 7- ceramic screen pipe filter, 8- boiler, 9- smoke processing system, 10- heating device, 11- return pipe, 12- fire resisting gear Frame, 131- first pipe, 132- second pipe.
Specific embodiment
A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system of the utility model include burner 1, with combustion Burner 1 connected incinerator 2, the fuse salt receiving slit 3 that is connected with incinerator 2, is provided with 4 He of hot gas outlet on incinerator 2 The fuse salt outlet 5 being connected with fuse salt receiving slit 3 is provided on hot gas outlet 4 for cooling via hot gas outlet 4 The regulation room 6 of the exhaust gas of discharge, regulation room 6 are connected with ceramic screen pipe filter 7, and ceramic screen pipe filter 7 is connected with boiler 8, Boiler 8 is connected with smoke processing system 9.One tune is installed between the hot gas air exit of incinerator 2 and the entrance of boiler 8 Save room 6.The outlet of 2 exhaust gas of thermal incinerator is usually located at the side of the incinerator 2 to burn vertically downward, and melts salt slurry, such as Before, by 2 bottom discharge of incinerator.In this approach, melting salt slurry can be collected or be dissolved in water in solid form and make For salting liquid collection.The function of regulation room 6 is that 2 exhaust gas of thermal incinerator is rapidly cooled to the fusing point of melting salt slurry or less.? Enough residence times are also provided in regulation room 6, make to melt fully charge inside and outside salt slurry particulate contaminant.Ceramic screen pipe filter 7 have self-cleaning effect, maintain continuous operation, and ceramic screen pipe can withstand up to 900 degree of temperature.Because being answered most of In, the fusing point of eutectic mixture is about 600 to 650 degree in combustion products gas.Therefore ceramic screen pipe filter 7 can be used for This application.
Be provided with Burning Room in incinerator 2, the temperature of Burning Room should be maintained at indoor metal salt fusion temperature and 980 degree Between.It is provided with slewing equipment in Burning Room, is not shown on slewing equipment figure, in the central axis and incinerator 2 of slewing equipment Mandrel line is overlapped, and slewing equipment includes the turning motor for driving revolution, the rotating shaft being connected with turning motor, is arranged in rotating shaft On for guiding the flabellum of flow of flue gas.The mode of combustion products air-flow provides enough for melting salt slurry particulate contaminant Rotation and offer centrifugal force, make the melting salt slurry to be formed be separated to furnace wall surface from primary air via centrifugation is compulsory.These liquid Body particulate contaminant, which hits furnace wall surface, will increase combination, and flow downwardly into melting salt slurry receiving tank from wall.
Freeze to melt salt slurry at fuse salt outlet 5 in order to prevent, be provided on fuse salt outlet 5 molten for improving Melt the heating device 10 of temperature at 5 position of salt outlet, heating device 10 makes the temperature on the furnace wall exported and surface always high The fusing point of melting salt slurry in combustion products gas.Fuse salt outlet 5, which passes through, return pipe 11, one end of return pipe 11 In Burning Room, the other end of return pipe 11 is located in regulation room 6.The combustion products gas for drawing some heat passes through melting Salt outlet 5, the amount and speed of hot gas can keep temperature and prevent the melting salt slurry for leaving outlet from freezing.
The fire resisting divider 12 on 2 inside of incinerator is provided on incinerator 2 at 4 position of hot gas outlet.Incinerator 2 Opening face on locular wall should be protected, in case melting salt slurry falls from the surface of opening.This can be via around the outer of opening The fire resisting divider 12 of edge setting guides the melting salt slurry of flowing to keep away from a mouthful face.
The outlet conduit of hot gas outlet 4 is provided through on incinerator 2 at 12 position of fire resisting divider, outlet conduit includes First pipe 131 and the second pipe 132 being connected to first pipe 131, second pipe 132 is horizontally disposed and connects with regulation room 6 Logical, first pipe 131 is arranged in obtuse angle with second pipe 132, and 131 central axis of first pipe is diagonally downward.First pipe Angle is between 150-170 degree between 131 and second pipe 132, and angle is 160 between first pipe 131 and second pipe 132 Degree.The size of outlet conduit selected angle and outlet conduit is most important.Leave incinerator 2 hot gas should have it is enough from Mental and physical efforts, to force fuse salt slurry drops to leave primary air and hit the wall of outlet conduit, by the way that outlet conduit is designed as two Bending tube at an angle when exhaust gas passes through outlet conduit, hits the in first pipe 131 and 132 bending part of second pipe One pipeline, 131 inner wall, then the fuse salt in exhaust gas returns to Burning Room without entering regulation room 6.First pipe 131 and the second pipe Angle between road 132 makes the melting salt slurry of accumulation flow back to incinerator Room 2, while angle between the two is related to so that leaving The speed of hot combustion gas answer it is sufficiently fast, with prevent melting particulate contaminant low temperature wall surface is hit before fully charge is but.
Finally, it should be noted that property technical side the above examples are only used to illustrate the technical scheme of the present invention and are not limiting Case, those skilled in the art should understand that, modification or equivalent replacement of the technical solution of the present invention are made for those, and The objective and range for not departing from the technical program, are intended to be within the scope of the claims of the invention.

Claims (10)

1. a kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system, it is characterised in that: the alkali metal containing organic waste Liquid and waste water incineration heat recovery system include burner, the incinerator being connected with the burner, are connected with the incinerator Fuse salt receiving slit is provided with hot gas outlet and the fuse salt being connected with fuse salt receiving slit discharge on the incinerator Mouthful, the regulation room for the cooling exhaust gas being discharged via hot gas outlet, the regulation room are provided on the hot gas outlet It is connected with ceramic screen pipe filter, the ceramic screen pipe filter is connected with boiler, and the boiler is connected with smoke processing system.
2. a kind of alkali metal containing organic liquid waste as described in claim 1 and waste water incineration heat recovery system, it is characterised in that: institute State and be provided with Burning Room in incinerator, the temperature of the Burning Room should be maintained at indoor metal salt fusion temperature and 980 degree it Between.
3. a kind of alkali metal containing organic liquid waste as claimed in claim 2 and waste water incineration heat recovery system, it is characterised in that: institute It states and is provided with slewing equipment in Burning Room, the central axis of the slewing equipment is overlapped with incinerator central axis, the revolution Device includes the turning motor, the rotating shaft being connected with the turning motor, the use being arranged on the rotating shaft for driving revolution In the flabellum of guidance flow of flue gas.
4. a kind of alkali metal containing organic liquid waste as described in claim 1 and waste water incineration heat recovery system, it is characterised in that: institute State the heating device being provided on fuse salt outlet for improving temperature at fuse salt outlet position.
5. a kind of alkali metal containing organic liquid waste as described in claim 1 and waste water incineration heat recovery system, it is characterised in that: institute Stating fuse salt outlet and passing through has return pipe, and one end of return pipe is located in Burning Room, and the other end of return pipe is located at regulation room It is interior.
6. a kind of alkali metal containing organic liquid waste as described in claim 1 and waste water incineration heat recovery system, it is characterised in that: institute It states and is provided with the fire resisting divider on incinerator inside on incinerator at hot gas outlet position.
7. a kind of alkali metal containing organic liquid waste as claimed in claim 6 and waste water incineration heat recovery system, it is characterised in that: institute State the outlet conduit for being provided through the hot gas outlet on incinerator at fire resisting divider position.
8. a kind of alkali metal containing organic liquid waste as claimed in claim 7 and waste water incineration heat recovery system, it is characterised in that: institute State the second pipe that outlet conduit includes first pipe and is connected to the first pipe, the second pipe it is horizontally disposed and with The regulation room connection, the first pipe is arranged in obtuse angle with the second pipe, and first pipe central axis is tilted towards Under.
9. a kind of alkali metal containing organic liquid waste as claimed in claim 8 and waste water incineration heat recovery system, it is characterised in that: institute Angle is stated between first pipe and the second pipe between 150-170 degree.
10. a kind of alkali metal containing organic liquid waste as claimed in claim 9 and waste water incineration heat recovery system, it is characterised in that: Angle is 160 degree between the first pipe and the second pipe.
CN201820535048.6U 2018-04-16 2018-04-16 A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system Expired - Fee Related CN208205033U (en)

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Application Number Priority Date Filing Date Title
CN201820535048.6U CN208205033U (en) 2018-04-16 2018-04-16 A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system

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Application Number Priority Date Filing Date Title
CN201820535048.6U CN208205033U (en) 2018-04-16 2018-04-16 A kind of alkali metal containing organic liquid waste and waste water incineration heat recovery system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111780128A (en) * 2019-04-03 2020-10-16 四川轻化工大学 Alkali metal slag removing device
CN115574344A (en) * 2022-11-30 2023-01-06 江苏大格环境科技有限公司 High-salt-content wastewater incineration, melting and cleaning process and system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111780128A (en) * 2019-04-03 2020-10-16 四川轻化工大学 Alkali metal slag removing device
CN111780128B (en) * 2019-04-03 2022-10-28 四川轻化工大学 Alkali metal slag removing device
CN115574344A (en) * 2022-11-30 2023-01-06 江苏大格环境科技有限公司 High-salt-content wastewater incineration, melting and cleaning process and system
CN115574344B (en) * 2022-11-30 2023-04-18 江苏大格环境科技有限公司 High-salt-content wastewater incineration melting cleaning process and system

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Granted publication date: 20181207