CN207968347U - Friction generator with composite film electrode and power-generating shoe - Google Patents
Friction generator with composite film electrode and power-generating shoe Download PDFInfo
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- CN207968347U CN207968347U CN201820302575.2U CN201820302575U CN207968347U CN 207968347 U CN207968347 U CN 207968347U CN 201820302575 U CN201820302575 U CN 201820302575U CN 207968347 U CN207968347 U CN 207968347U
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Abstract
The utility model discloses a kind of friction generator and power-generating shoe with composite film electrode, wherein include with the friction generator of composite film electrode：The first friction component and the second friction component being cascading；First friction component is made of the first composite film electrode and the first high molecular polymer film, and the first composite film electrode is embedded in the first high molecular polymer film, and is wrapped up by the first high molecular polymer film；Wherein, the first composite film electrode includes：Second high molecular polymer film and the first electrode being arranged on the second high molecular polymer film side surface；Second friction component includes at least second electrode；First electrode and the signal output end that second electrode is the friction generator with composite film electrode.Friction generator generating efficiency provided by the utility model with composite film electrode is high, and stable work in work, service life is long, and manufacture craft is simple, of low cost.
Description
Technical field
The utility model is related to triboelectricity technical fields, and in particular to a kind of triboelectricity with composite film electrode
Machine and power-generating shoe.
Background technology
Friction generator has been widely used in multiple fields.Wherein, friction component is the key that group in friction generator
The nature of part, friction component is very big on influences such as the generating efficiency of friction generator, working performance, service lifes.Existing
Have in technology, friction component is polymer film layer by being stacked and metal layer mostly and is formed, this friction component
Manufacture craft is more complicated, and cost of manufacture is higher, and yields is relatively low, it is difficult to ensure that the polymer in prepared friction component
Film layer and metal layer can be smooth and be tightly bonded together, and then cause the generating efficiency of friction generator relatively low, work
It is unstable to make performance；And in the case where stress is bigger, the metal layer on polymer film layer is easy to fall off or damage,
Cause the service life of friction generator shorter.Therefore, lack in the prior art a kind of manufacture craft it is simple, it is of low cost, hair
Electrical efficiency height, stable work in work and friction generator with long service life.
Utility model content
The goal of the invention of the utility model is in view of the drawbacks of the prior art, to provide a kind of with composite film electrode
Friction generator and power-generating shoe, for solution, friction generator is complicated in the prior art, complex manufacturing technology, manufacturing cost
The problem high, generating efficiency is low, working performance is unstable and service life is short.
The utility model provides a kind of friction generator with composite film electrode, including：It is cascading
First friction component and the second friction component；
First friction component is made of the first composite film electrode and the first high molecular polymer film, the first laminated film
Electrode is embedded in the first high molecular polymer film, and is wrapped up by the first high molecular polymer film；Wherein, the first THIN COMPOSITE
Membrane electrode includes：Second high molecular polymer film and be arranged on the second high molecular polymer film side surface first
Electrode；
Second friction component includes at least second electrode；First electrode and second electrode are rubbing with composite film electrode
Wipe the signal output end of generator.
Further, at least one first through hole is provided on the first composite film electrode, the first high molecular polymer is thin
Film is also partially fill in first through hole.
Further, first electrode is arranged in the second high molecular polymer film closer or far from the one of the second friction component
On side surface.
Further, is provided on the first high molecular polymer film side surface opposite with the second friction component
One concave-convex array structure.
Further, the second friction component further includes third high molecular polymer film, third high molecular polymer film
It is arranged on a second electrode side surface opposite with the first friction component.
Further, the second friction component is made of the second composite film electrode and third high molecular polymer film, the
Two composite film electrodes are embedded in third high molecular polymer film, and are wrapped up by third high molecular polymer film；Wherein,
Second composite film electrode includes：4th high molecular polymer film and setting are in the 4th high molecular polymer film side table
Second electrode on face.
Further, at least one second through-hole is provided on the second composite film electrode, third high molecular polymer is thin
Film is also partially fill in the second through-hole.
Further, multiple first through hole array arrangement and/or multiple second through-holes on the first composite film electrode exists
Array arrangement on second composite film electrode.
Further, second electrode is arranged in the 4th high molecular polymer film closer or far from the one of the first friction component
On side surface.
Further, is provided on a third high molecular polymer film side surface opposite with the first friction component
Two concave-convex array structures.
Further, the friction generator with composite film electrode further includes：Interlayer；Interlayer setting rubs first
Between brush assembly and the second friction component.
The utility model additionally provides a kind of power-generating shoe, including：Such as the above-mentioned triboelectricity with composite film electrode
Machine.
Friction generator provided by the utility model with composite film electrode, using same high molecular polymer material
Material the first composite film electrode of package obtains the first friction component, improves the job stability of the first friction component, and make whole
A friction component is more with consistency, helps to improve the generating efficiency of friction generator, and extend friction generator uses the longevity
Life；Also, energy between the second high molecular polymer film in the first high molecular polymer film and the first composite film electrode
Transition zone is enough formed, the presence of transition zone can reduce the neutralization of positive and negative charge, to further improve friction generator
Generating efficiency.Optionally, the first through hole on the first composite film electrode can also be passed through so that the first high molecular polymer film
It is embedded in through-hole and can closely be entrenched togather with the first composite film electrode, bond strength is high, effectively enhances first
The firmness of friction component.The effect in addition, friction generator provided by the utility model with composite film electrode not only generates electricity
Rate height, stable work in work, service life is long, while also having simple, of low cost, the suitable large-scale industry life of manufacture craft
The advantages of production.
Description of the drawings
Fig. 1 is that the cross section structure of the friction generator embodiment one provided by the utility model with composite film electrode shows
It is intended to；
Fig. 2 a are a setting schematic diagram of first through hole provided by the utility model；
Fig. 2 b are another setting schematic diagram of first through hole provided by the utility model；
Fig. 3 is that the cross section structure of the friction generator embodiment two provided by the utility model with composite film electrode shows
It is intended to；
Fig. 4 is that the cross section structure of the friction generator embodiment three provided by the utility model with composite film electrode shows
It is intended to；
Fig. 5 is the flow signal of the preparation method of the friction generator provided by the utility model with composite film electrode
Figure.
Specific implementation mode
To fully understand the purpose, feature and effect of the utility model, by following specific embodiments, to this practicality
It is novel to elaborate, but the utility model is not restricted to this.
The utility model provides a kind of friction generator with composite film electrode, including：It is cascading
First friction component and the second friction component；First friction component is thin by the first composite film electrode and the first high molecular polymer
Film forms, and the first composite film electrode is embedded in the first high molecular polymer film, and by the first high molecular polymer film
Package；Wherein, the first composite film electrode includes：Second high molecular polymer film and setting are in the second high molecular polymer
First electrode on film side surface；Second friction component includes at least second electrode；First electrode and second electrode are tool
There is the signal output end of the friction generator of composite film electrode.
Fig. 1 is that the cross section structure of the friction generator embodiment one provided by the utility model with composite film electrode shows
It is intended to, as shown in Figure 1, the friction generator with composite film electrode includes：The first friction component 110 being cascading
With the second friction component 120.
Wherein, the first friction component 110 is by 112 groups of the first composite film electrode 111 and the first high molecular polymer film
At the first composite film electrode 111 is embedded in the first high molecular polymer film 112, and thin by the first high molecular polymer
Film 112 wraps up.Fig. 1 shows that the first composite film electrode 111 has fully embedded into the feelings in the first high molecular polymer film 112
Condition is equivalent to and wraps up the first composite film electrode 111 using same macromolecule polymer material.Alternatively, it is also possible to being first
Composite film electrode 111 is partially submerged into the first high molecular polymer film 112, and those skilled in the art can be according to practical need
Specific embedded mode is selected, is not limited herein.
Those skilled in the art can according to actual needs be configured the material of the first high molecular polymer film 112,
It does not limit herein.For example, the first high molecular polymer film 112 can be thermosettings, the thermoplastic polymer such as silica gel, rubber
Material.Compared with wrapping up the first composite film electrode 111 using two different macromolecule polymer materials, using same height
First friction component, 110 structure is more secured obtained from Molecularly Imprinted Polymer material wraps up the first composite film electrode 111, can
More stable working performance is obtained, the generating efficiency of friction generator is helped to improve.
Wherein, the first composite film electrode 111 includes：Second high molecular polymer film 1111 and setting are high second
First electrode 1112 on 1,111 1 side surface of Molecularly Imprinted Polymer film.First electrode 1112 may be provided at the second high molecular polymerization
For object film 1111 closer or far from a side surface of the second friction component 120, those skilled in the art can be according to actual needs
Determine the installation position of first electrode 1112.Specifically, Fig. 1 shows that first electrode 1112 is arranged in the second high molecular polymer
Situation on a side surface of the film 1111 far from the second friction component 120.Those skilled in the art can refer to Fig. 1 by the first electricity
Pole 1112 is arranged in the second high molecular polymer film 1111 on a side surface of the second friction component 120, is equivalent to tune
The position of first electrode 1112 and the second high molecular polymer film 1111 in Fig. 1 is changed.
In the present invention, it is thin to be different from the first high molecular polymer for the material of the second high molecular polymer film 1111
The material of film 112 therefore can between the second high molecular polymer film 1111 and the first high molecular polymer film 112
Transition zone is formed, the presence of transition zone can reduce the neutralization of positive and negative charge, to further improve the hair of friction generator
Electrical efficiency.Those skilled in the art can be according to actual needs to the second high molecular polymer in the first composite film electrode 111
Film 1111 and the material of first electrode 1112 are configured, and are not limited herein.For example, the first composite film electrode 111 can
Think that plating is formed with the polyethylene terephthalate (PET) of aluminium, plating is formed with the PET of ITO, plating is formed with the PET of silver-colored grid, is coated with
Have that the polyvinyl chloride (PVC) of aluminium, plating are formed with the PVC of silver or plating is formed with the PVC etc. of nickel.
In addition, as shown in Fig. 2 a or Fig. 2 b, at least one first through hole may be provided on the first composite film electrode 111
113, the first high molecular polymer film 112 is also partially fill in first through hole 113.Specifically, due to first through hole 113
In the presence of, during preparing the first friction component 110, the first high score for making the first high molecular polymer film 112
Sub- polymer material can be filled in first through hole 113, to make the first high molecular polymer film 112 and the first laminated film
Electrode 111 can closely be entrenched togather, and bond strength is high, effectively enhances the firmness of the first friction component 110, makes
Entire first friction component 110 is more with consistency, and performance is more stable.
Specifically, can by punching, laser cutting or other techniques according to pre-set dimension in the first composite film electrode 111
It is upper to make at least one first through hole 113.The shape of first through hole 113 can be round, rectangular, triangle, striped, wave
The preset shapes such as line, broken string, ellipse and irregular shape.Multiple first through hole 113 can be on the first composite film electrode 111
Array arrangement, specifically, multiple first through hole 113 can be arranged according to shapes such as rectangle or diamond shapes.Those skilled in the art
The shape of first through hole 113, size and arrangement mode can be configured according to actual needs, not limited herein.With first
For the shape of through-hole 113 is round, the diameter of first through hole 113 is preferably 0.1mm~10mm.As shown in Figure 2 a, first is multiple
The shape for closing the first through hole 113 on membrane electrode 111 is circle, and multiple first through hole 113 are arranged according to rectangle；
As shown in Figure 2 b, the shape of the first through hole 113 on the first composite film electrode 111 is vertical bar line, and multiple first through hole
113 are arranged according to predetermined interval.
Second friction component 120 include second electrode, the first high molecular polymer film 112 it is opposite with second electrode two
A surface constitutes frictional interface, first electrode 1112 and the signal that second electrode is the friction generator with composite film electrode
Output end.It wherein, can since the first composite film electrode 111 is embedded in the first high molecular polymer film 112
The electric signal that the output of first electrode 1112 is drawn by contact conductor specifically can be in the first high molecular polymer film 112
Contact conductor is pre-set, and one end of contact conductor is connected with first electrode 1112, the other end is arranged in the first high score
Outside sub- thin polymer film 112, to easily draw the electric signal that first electrode 1112 exports.
As shown in Figure 1, on the first high molecular polymer film 112 side surface opposite with the second friction component 120
It is provided with the first concave-convex array structure 114, the presence of the first concave-convex array structure 114 increases minute projections, helps
In the raising of friction generator generating efficiency.Wherein, the first concave-convex array structure 114 is that multiple protrusions are arranged according to rectangle or diamond shape
Row are constituted, or for multiple banded structures according to geometry be arranged in the both sides at least one surface, quadrangle, edge or
In whole surface.Optionally, raised shape can be hemispherical, cylinder, prismatic or pyramid etc., not do herein specific
It limits；Banded structure can be arranged according to the array of shapes of well word, fork word, zebra line style, cross or mouth word, not done herein specific
It limits.
Fig. 3 is that the cross section structure of the friction generator embodiment two provided by the utility model with composite film electrode shows
Be intended to, as shown in figure 3, friction generator embodiment two and friction generator embodiment one difference lies in：Second friction component
220 include not only second electrode 221, further includes third high molecular polymer film 222, third high molecular polymer film 222
It is arranged on the side surface opposite with the first friction component 110 of second electrode 221.First high molecular polymer film 112 with
Two opposite surfaces of third high molecular polymer film 222 constitute frictional interface, and first electrode 1112 and second electrode 221 are
The signal output end of friction generator with composite film electrode.Those skilled in the art can be according to actual needs to third height
The material of Molecularly Imprinted Polymer film 222 is configured, and is not limited herein.Preferably, third high molecular polymer film 222
Material is different from the material of the first high molecular polymer film 112, should have certain polarity difference between them, to obtain
Preferable triboelectricity effect.
Fig. 4 is that the cross section structure of the friction generator embodiment three provided by the utility model with composite film electrode shows
Be intended to, as shown in figure 4, friction generator embodiment three and friction generator embodiment two difference lies in：Second friction component
320 are made of the second composite film electrode 321 and third high molecular polymer film 322, the insertion of the second composite film electrode 321
322 are wrapped up into third high molecular polymer film 322, and by third high molecular polymer film.Fig. 4 shows that second is compound
Membrane electrode 321 has fully embedded into the situation in third high molecular polymer film 322, is equivalent to using same polyphosphazene polymer
It is more secured to close 320 structure of the second friction component obtained from object material wraps up the second composite film electrode 321, this set side
Formula improves the job stability of the second friction component 320, contributes to the generating efficiency for further increasing friction generator.Separately
Outside, or the second composite film electrode 321 is partially submerged into third high molecular polymer film 322, art technology
Personnel can select specific embedded mode according to actual needs, not limit herein.
Wherein, the second composite film electrode 321 includes：4th high molecular polymer film 3211 and setting are high the 4th
Second electrode 3212 on 3,211 1 side surface of Molecularly Imprinted Polymer film.Second electrode 3212 may be provided at the 4th high molecular polymerization
For object film 3211 closer or far from a side surface of the first friction component 110, those skilled in the art can be according to actual needs
Determine the installation position of second electrode 3212.Specifically, Fig. 4 shows that second electrode 3212 is arranged in the 4th high molecular polymer
Situation on a side surface of the film 3211 far from the first friction component 110.Those skilled in the art can refer to Fig. 4 by the second electricity
Pole 3212 is arranged in the 4th high molecular polymer film 3211 on a side surface of the first friction component 110, is equivalent to tune
The position of second electrode 3212 and the 4th high molecular polymer film 3211 in Fig. 4 is changed.
In the present invention, it is thin to be different from third high molecular polymer for the material of the 4th high molecular polymer film 3211
The material of film 322 therefore can between the 4th high molecular polymer film 3211 and third high molecular polymer film 322
Transition zone is formed, the presence of transition zone can reduce the neutralization of positive and negative charge, to further improve the hair of friction generator
Electrical efficiency.Those skilled in the art can be according to actual needs to the 4th high molecular polymer in the second composite film electrode 321
Film 3211 and the material of second electrode 3212 are configured, and are not limited herein.Wherein, the second composite film electrode 321 can
Think that plating is formed with the PET of aluminium, plating is formed with the PET of ITO, plating is formed with the PET of silver-colored grid, plating is formed with the PVC of aluminium, plating is formed with silver
PVC or plating are formed with the PVC etc. of nickel.Specifically, the second composite film electrode 321 can be with 111 phase of the first composite film electrode
Together, can also be different from the first composite film electrode 111, it does not limit herein.
First high molecular polymer film 112, two surfaces opposite with third high molecular polymer film 322, which are constituted, rubs
Wipe interface, first electrode 1112 and the signal output end that second electrode 3212 is the friction generator with composite film electrode.
Wherein, since the first composite film electrode 111 is embedded in the first high molecular polymer film 112, and the second THIN COMPOSITE
Membrane electrode 321 is embedded in third high molecular polymer film 322, therefore can draw the first electricity by two contact conductors respectively
The electric signal that pole 1112 and second electrode 3212 export can specifically be pre-set in the first high molecular polymer film 112
Contact conductor 1, and one end of contact conductor 1 is connected with first electrode 1112, the other end of contact conductor 1 is arranged first
Outside high molecular polymer film 112, and contact conductor 2 is pre-set in third high molecular polymer film 322, and make
One end of contact conductor 2 is connected with second electrode 3212, and the other end of contact conductor 2 is arranged in third high molecular polymer film
Outside 322, to easily draw the electric signal that first electrode 1112 and second electrode 3212 export.
In addition, may be provided at least one second through-hole (not shown) on the second composite film electrode 321, third is high
Molecularly Imprinted Polymer film 322 is also partially fill at least one second through-hole.Specifically, due to the presence of the second through-hole,
During preparing the second friction component 320, the third high molecular polymer for making third high molecular polymer film 322
Material can be filled in the second through-hole, to enable third high molecular polymer film 322 and the second composite film electrode 321
It is closely entrenched togather, bond strength is high, effectively enhances the firmness of the second friction component 320, makes entire second to rub
Brush assembly 320 is more with consistency, and performance is more stablized.
Specifically, can by punching, laser cutting or other techniques according to pre-set dimension in the second composite film electrode 321
It is upper to make at least one second through-hole.The shape of second through-hole can be round, rectangular, triangle, striped, wave, broken string,
The preset shapes such as oval and irregular shape.Multiple second through-holes can on the second composite film electrode 321 array arrangement, tool
Body, multiple second through-holes can be arranged according to shapes such as rectangle or diamond shapes.Those skilled in the art can be according to actual needs
Shape, the size and arrangement mode of second through-hole are configured, do not limited herein.The setting schematic diagram of second through-hole can join
According to the setting schematic diagram of first through hole shown in Fig. 2 a or Fig. 2 b.
As shown in figure 4, in order to further make friction generator induce more charge inducings, to improve friction generator
Generating efficiency, is provided on the side surface opposite with the first friction component 110 of third high molecular polymer film 322
Two concave-convex array structures 324.Wherein, the second concave-convex array structure 324 is constituted for multiple protrusions according to rectangle or diamond array, or
Person is both sides, quadrangle, edge or the whole surface that multiple banded structures are arranged at least one surface according to geometry
On.Optionally, raised shape can be hemispherical, cylinder, prismatic or pyramid etc., be not specifically limited herein；Band
Shape structure can be arranged according to the array of shapes of well word, fork word, zebra line style, cross or mouth word, be not specifically limited herein, when
So bumps array can also be only arranged on the friction surface of a friction component of friction generator in addition to set-up mode in Fig. 4,
Such as it is provided only on the friction surface of the first friction component 110 or is provided only on the friction surface of the second friction component 320.
In a kind of optional embodiment, the friction generator with composite film electrode is in addition to including such as Fig. 3 or Fig. 4
Shown in except the first friction component and the second friction component, may also include interlayer.Interlayer is arranged in the first friction group
Between part and the second friction component.Specifically, interlayer can be film or intervening electrode between two parties.When interlayer is film between two parties
When, the first high molecular polymer film two surfaces opposite with film between two parties and/or between two parties film and third high molecular polymerization
Two opposite surfaces of object film constitute frictional interface, and first electrode and second electrode are signal output end.When interlayer is to occupy
Between electrode when, the first high molecular polymer film two surfaces opposite with intervening electrode and/or intervening electrode and third high score
Opposite two surfaces of sub- thin polymer film constitute frictional interface, and intervening electrode is a signal output end, first electrode and the
Two electrodes are connected to another signal output end.
Friction generator provided by the utility model with composite film electrode, using same high molecular polymer material
Material the first composite film electrode of package obtains the first friction component, improves the job stability of the first friction component, contributes to
Improve the generating efficiency of friction generator；Also, second in the first high molecular polymer film and the first composite film electrode
Transition zone can be formed between high molecular polymer film, the presence of transition zone can reduce the neutralization of positive and negative charge, thus into
One step improves the generating efficiency of friction generator.Optionally, can also be made by the first through hole on the first composite film electrode
Obtaining the first high molecular polymer film and the first composite film electrode can closely be entrenched togather, and bond strength is high, effectively
Ground enhances the firmness of the first friction component, keeps entire first friction component more with consistency, and performance is more stablized.In addition,
Not only generating efficiency is high for friction generator provided by the utility model with composite film electrode, stable work in work, entirely
Friction generator is more with consistency, also have while extending entire friction generator service life manufacture craft it is simple, at
The advantages of this cheap, suitable large-scale industrial production.
The utility model additionally provides a kind of power-generating shoe, which includes such as above-mentioned rubbing with composite film electrode
Wipe generator.Friction generator with composite film electrode is arranged in the inside of shoes body, due in the first friction component
First composite film electrode uses the second high molecular polymer film for being provided with first electrode, and the first composite film electrode
It is embedded in the first high molecular polymer film, and is wrapped up by the first high molecular polymer film, which combines
Intensity is high, fastness is good, solves the problems, such as that existing power-generating shoe friction component in the case where stress is larger is flimsy, to
It is effectively improved the quality of power-generating shoe, extends the service life of power-generating shoe.
It is understood that the friction generator provided by the utility model with composite film electrode acts not only as
Generator is applied in power-generating shoe, is alternatively arranged as in sensor application to other equipment, such as is used for for pulse monitoring device
It senses and receives electric signal.Those skilled in the art can according to actual needs answer the friction generator with composite film electrode
It uses in other equipment, does not limit herein.
The utility model additionally provides the system of the friction generator with composite film electrode for the various embodiments described above
Preparation Method.Fig. 5 is the flow signal of the preparation method of the friction generator provided by the utility model with composite film electrode
Figure, as shown in figure 5, this method comprises the following steps：
Step S501 makes the first composite film electrode.
Wherein, the first composite film electrode includes：Second high molecular polymer film and setting are in the second polyphosphazene polymer
Close the first electrode on object film side surface.When making the first composite film electrode, the second high molecular polymerization can be first made
Then object film makes first electrode on a side surface of the second high molecular polymer film；Also first electrode can be first made,
Then the second high molecular polymer film is made on a side surface of first electrode.Specifically, spin coating proceeding, curtain coating can be passed through
Technique, coating process, Shooting Technique, heat pressing process, spraying process, silk-screen printing technique, InkJet printing processes, magnetron sputtering work
Skill or evaporation process realize the making to the second high molecular polymer film, and those skilled in the art can be according to polymer material
Nature selects specific manufacture craft, does not limit herein.For example, that Shooting Technique making material is PET can be used
Two high molecular polymer films.Spin coating proceeding, silk-screen printing technique, InkJet printing processes, magnetron sputtering technique or steaming can be passed through
Depositing process realizes that the making to first electrode, those skilled in the art can select specific manufacture craft to make according to actual needs
First electrode does not limit herein.In addition, during making the second high molecular polymer film, may be selected to utilize polymerization
Object film is made.During making first electrode, also it may be selected thin using conductive metal film or radio frequency
Film is made.
Optionally, in order to enable the first composite film electrode closely with the first high molecular polymer film carry out
It is chimeric, after making obtains the first composite film electrode, it is logical that at least one first can be made on the first composite film electrode
Hole.Specifically, can be made on the first composite film electrode according to pre-set dimension by punching, laser cutting or other techniques to
A few first through hole.Multiple first through hole can on the first composite film electrode array arrangement.
Step S502 is coated with the first macromolecule polymer material in the first template, and it is thin to obtain the first high molecular polymer
Film intermediate.
One side surface of the first template can be previously provided with the first concave-convex array structure.First template can be acrylic,
The materials such as stainless steel, aluminium alloy, quartz or glass.By spin coating proceeding in table of first template far from the first concave-convex array structure
The first macromolecule polymer material is coated on face, to obtain the first high molecular polymer film intermediate.Wherein, the first high score
Sub- thin polymer film intermediate refers to uncured film, that is, after forming film, the also uncured processing of film, is still glue.
By taking heat cured PDMS as an example, it can be configured according to the ratio that PDMS and curing agent are 10 to 1, stir evenly rear vacuum degassing
5min~30min obtains the first macromolecule polymer material, then by spin coating proceeding in the first template far from the first concave-convex battle array
The first macromolecule polymer material is coated on the surface of array structure, to obtain the first high molecular polymer film intermediate.
The part surface in the first high molecular polymer film intermediate is arranged in first composite film electrode by step S503
On, and it is coated with the first high molecular polymer again on the first composite film electrode and the first high molecular polymer film intermediate
Material obtains the first friction component.
First composite film electrode is arranged on the part surface of the first high molecular polymer film intermediate refer to by
First composite film electrode and the first high molecular polymer film intermediate carry out stacking placement.It wherein, can be by the first THIN COMPOSITE
Membrane electrode is arranged on the part surface that the first concave-convex array structure is not arranged for the first high molecular polymer film intermediate.First
The surface area of composite film electrode is less than the surface area of the first high molecular polymer film intermediate.Obtaining the first macromolecule
After thin polymer film intermediate, the first composite film electrode is arranged in the part of the first high molecular polymer film intermediate
On surface, for the ease of making the first friction component, the first composite film electrode can be entirely arranged in the first polyphosphazene polymer
It is then thin in the first composite film electrode and the first high molecular polymer on the surface for closing the middle position of object film intermediate
It is coated with the first macromolecule polymer material on film intermediate, then the template for completing coating process is put into vacuum drying chamber,
To the first macromolecule polymer material carry out vacuum degassing, be heating and curing and cutting processing, to obtain the first friction component.Its
In, the first electrode in the first composite film electrode is placed closer or far from the first template, and those skilled in the art can root
It is selected according to actual needs, is not limited herein.
In the case where being provided with first through hole on the first composite film electrode, exist when by the setting of the first composite film electrode
When on the part surface of the first high molecular polymer film intermediate, since the first high molecular polymer film intermediate is still glue
Shape, so the first macromolecule polymer material can be filled into the first through hole of the first composite film electrode, in addition, multiple first
It closes during being coated with the first macromolecule polymer material again on membrane electrode, the first macromolecule polymer material can also fill
Into the first through hole of the first composite film electrode, then after the processing that is heating and curing, the first high molecular polymer film
It is also partially fill in first through hole, realizes the close embedding of the first composite film electrode and the first high molecular polymer film
It closes.The utility model wraps up the first composite film electrode using the first high molecular polymer film, and is improved by first through hole
Tight ness rating and conjugation between first composite film electrode and the first high molecular polymer film, obtained first friction
Component can obtain more stable working performance and keep entire friction component more with consistency, help to improve friction generator
Generating efficiency.
Step S504 makes second electrode, obtains the second friction component.
In one embodiment, the second friction component only includes second electrode, then can pass through spin coating proceeding, curtain coating work
Skill, coating process, Shooting Technique, heat pressing process, spraying process, silk-screen printing technique, InkJet printing processes, magnetron sputtering technique
Or evaporation process makes second electrode, to obtain the second friction component.
In another embodiment, the second friction component includes the second electrode being stacked and third high molecular polymerization
Object film, then third high molecular polymer film can first be made, then in a side surface of third high molecular polymer film
Upper making second electrode；Also second electrode can be first made, third polyphosphazene polymer is then made on a side surface of second electrode
Close object film.Specifically, can by spin coating proceeding, casting technique, coating process, Shooting Technique, heat pressing process, spraying process,
Silk-screen printing technique, InkJet printing processes, magnetron sputtering technique or evaporation process are realized to third high molecular polymer film
It makes, those skilled in the art can select specific manufacture craft according to the nature of polymer material, not limit herein.
It can be realized to second electrode by spin coating proceeding, silk-screen printing technique, InkJet printing processes, magnetron sputtering technique or evaporation process
Making, those skilled in the art can select specific manufacture craft to make second electrode, not limit herein according to actual needs
It is fixed.In addition, during making third high molecular polymer film, may be selected to be made using thin polymer film.It is making
During making second electrode, it also may be selected to be made using conductive metal film or radio frequency film.
In another embodiment, the second friction component is thin by the second composite film electrode and third high molecular polymer
Film forms, then realizing the making to the second friction component in the way of similar to step S501 to step S503.
Specifically, (1) makes the second composite film electrode, wherein the second composite film electrode includes：4th polyphosphazene polymer
The second electrode closed object film and be arranged on the 4th high molecular polymer film side surface.In addition, can also be multiple second
It closes and makes at least one second through-hole on membrane electrode.Multiple second through-holes can on the second composite film electrode array arrangement.
It is identical as the process of the first composite film electrode is made to make the second composite film electrode, makes the second through-hole and leads to making first
The process in hole is identical, and details are not described herein again.
(2) it is coated with third macromolecule polymer material in the second template, obtains among third high molecular polymer film
Body a, wherein side surface of the second template can be previously provided with the second concave-convex array structure, then in the second template far from second
It is coated with third macromolecule polymer material on the surface of concave-convex array structure, obtains third high molecular polymer film intermediate.
Second high molecular polymer film intermediate refers to uncured film, is still glue.
(3) the second composite film electrode is arranged on the part surface of third high molecular polymer film intermediate, and
It is coated with third macromolecule polymer material again on the second composite film electrode and third high molecular polymer film intermediate,
Obtain the second friction component.
Second composite film electrode is arranged on the part surface of third high molecular polymer film intermediate refer to by
Second composite film electrode and third high molecular polymer film intermediate carry out stacking placement.Wherein, by the second laminated film
Electrode is arranged on the part surface that the second concave-convex array structure is not arranged for third high molecular polymer film intermediate.Second is multiple
The surface area for closing membrane electrode is less than the surface area of third high molecular polymer film intermediate.Obtaining third polyphosphazene polymer
After closing object film intermediate, the part table in third high molecular polymer film intermediate is arranged in the second composite film electrode
On face, for the ease of making the second friction component, the second composite film electrode can be entirely arranged in third high molecular polymerization
On the surface of the middle position of object film intermediate, then in the second composite film electrode and third high molecular polymer film
It is coated with third macromolecule polymer material on intermediate, then the template for completing coating process is put into vacuum drying chamber, it is right
Third macromolecule polymer material carry out vacuum degassing, be heating and curing and cutting processing, to obtain the second friction component.Its
In, the second electrode in the second composite film electrode is placed closer or far from the second template, and those skilled in the art can root
It is selected according to actual needs, is not limited herein.
In the case where being provided with the second through-hole on the second composite film electrode, exist when by the setting of the second composite film electrode
When on the part surface of third high molecular polymer film intermediate, since third high molecular polymer film intermediate is still glue
Shape, so third macromolecule polymer material can be filled into the second through-hole of the second composite film electrode, in addition, multiple second
It closes during being coated with third macromolecule polymer material again on membrane electrode, third macromolecule polymer material can also fill
Into the second through-hole of the second composite film electrode, then after the processing that is heating and curing, third high molecular polymer film
It is also partially fill in the second through-hole, realizes the close embedding of the second composite film electrode and third high molecular polymer film
It closes.The utility model wraps up the second composite film electrode using third high molecular polymer film, and is improved by the second through-hole
Tight ness rating and conjugation between second composite film electrode and third high molecular polymer film, obtained second friction
Component can obtain more stable working performance and keep entire friction component more with consistency, help to improve friction generator
Generating efficiency.
First friction component and the second friction component are stacked together, obtain with laminated film by step S505
The friction generator of electrode.
After the making for completing the first friction component and the second friction component, the first friction component and second are rubbed
Component stacking is set together, and obtains the friction generator with composite film electrode.If the second friction component only includes second
First friction component and the second friction component are then stacked together by electrode so that the first high molecular polymer film with
Two opposite surfaces of second electrode constitute frictional interface.If the second friction component includes the second electrode and third being stacked
First friction component and the second friction component are then stacked together by high molecular polymer film so that the first macromolecule
Thin polymer film two surfaces opposite with third high molecular polymer film constitute frictional interface.If the second friction component is by
Two composite film electrodes and third high molecular polymer film composition, then set the first friction component and the stacking of the second friction component
It sets together so that the first high molecular polymer film two surfaces opposite with third high molecular polymer film constitute friction
Interface.
Optionally, the preparation method may also include make interlayer the step of, wherein interlayer can be between two parties film or
Intervening electrode.Together with being stacked with the second friction component the first friction component, interlayer so in step S505, obtain
To the friction generator with composite film electrode.In this case, the first high molecular polymer film is opposite with interlayer
Two surfaces and/or interlayer two surfaces opposite with third high molecular polymer film constitute frictional interface.
Above-mentioned preparation method provided by the utility model, by spin coating proceeding, silk-screen printing technique, InkJet printing processes,
The techniques such as magnetron sputtering technique or evaporation process can prepare the friction generator with composite film electrode.The utility model
Generating efficiency height, stable work in work can easily be obtained by using suitable preparation method, consistency is strong and uses the longevity
Long friction generator is ordered, has that manufacture craft is simple, stability is high, easy to process, low-cost advantage.
It should be appreciated by those skilled in the art that apparatus structure shown in attached drawing or embodiment is only schematical, table
Show logical construction.The module wherein shown as separating component may be or may not be to be physically separated, as module
The component of display may be or may not be physical module.
Finally it should be noted that be：Listed above is only specific embodiment of the utility model, certain this field
Technical staff can be modified to the utility model and modification, if these modifications and variations belong to the utility model right and want
Ask and its equivalent technologies within the scope of, be considered as the scope of protection of the utility model.
Claims (15)
1. a kind of friction generator with composite film electrode, which is characterized in that including：The first friction being cascading
Component and the second friction component；
First friction component is made of the first composite film electrode and the first high molecular polymer film, and described first is compound
Membrane electrode is embedded in the first high molecular polymer film, and is wrapped up by the first high molecular polymer film；Its
In, first composite film electrode includes：Second high molecular polymer film and setting are in second high molecular polymerization
First electrode on object film side surface；
Second friction component includes at least second electrode；The first electrode and the second electrode are described with compound
The signal output end of the friction generator of membrane electrode.
2. the friction generator according to claim 1 with composite film electrode, which is characterized in that described first is compound
At least one first through hole is provided on membrane electrode, the first high molecular polymer film is also partially fill in described first
In through-hole.
3. the friction generator according to claim 1 with composite film electrode, which is characterized in that the first electrode
It is arranged on a side surface of the second high molecular polymer film closer or far from second friction component.
4. the friction generator according to claim 2 with composite film electrode, which is characterized in that the first electrode
It is arranged on a side surface of the second high molecular polymer film closer or far from second friction component.
5. the friction generator according to claim 1 with composite film electrode, which is characterized in that high described first
The first concave-convex array structure is provided on a Molecularly Imprinted Polymer film side surface opposite with second friction component.
6. having the friction generator of composite film electrode according to claim 1-5 any one of them, which is characterized in that described
Second friction component further includes third high molecular polymer film, and the third high molecular polymer film is arranged described second
On an electrode side surface opposite with first friction component.
7. having the friction generator of composite film electrode according to claim 1-5 any one of them, which is characterized in that described
Second friction component is made of the second composite film electrode and third high molecular polymer film, second composite film electrode
It is embedded in the third high molecular polymer film, and is wrapped up by the third high molecular polymer film；Wherein, described
Two composite film electrodes include：4th high molecular polymer film and setting are in the 4th high molecular polymer film side
Second electrode on surface.
8. the friction generator according to claim 7 with composite film electrode, which is characterized in that described second is compound
At least one second through-hole is provided on membrane electrode, the third high molecular polymer film is also partially fill in described second
In through-hole.
9. the friction generator according to claim 2 with composite film electrode, which is characterized in that multiple first through hole
The array arrangement on first composite film electrode.
10. the friction generator according to claim 8 with composite film electrode, which is characterized in that multiple first is logical
Hole array arrangement and/or multiple second through-holes on first composite film electrode are gone into battle in second composite film electrode
Row arrangement.
11. the friction generator according to claim 7 with composite film electrode, which is characterized in that second electricity
Pole is arranged on the side surface in the 4th high molecular polymer film closer or far from first friction component.
12. the friction generator according to claim 7 with composite film electrode, which is characterized in that in the third
The second concave-convex array structure is provided on a high molecular polymer film side surface opposite with first friction component.
13. the friction generator according to claim 6 with composite film electrode, which is characterized in that described to have again
Close membrane electrode friction generator further include：Interlayer；Interlayer setting is in first friction component and described the
Between two friction components.
14. the friction generator according to claim 7 with composite film electrode, which is characterized in that described to have again
Close membrane electrode friction generator further include：Interlayer；Interlayer setting is in first friction component and described the
Between two friction components.
15. a kind of power-generating shoe, which is characterized in that including：As claim 1-14 any one of them has composite film electrode
Friction generator.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108696173A (en) * | 2018-03-05 | 2018-10-23 | 纳智源科技（唐山）有限责任公司 | Friction generator, preparation method with composite film electrode and power-generating shoe |
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2018
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108696173A (en) * | 2018-03-05 | 2018-10-23 | 纳智源科技（唐山）有限责任公司 | Friction generator, preparation method with composite film electrode and power-generating shoe |
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