Invention content
In order to overcome shortcoming and defect existing in the prior art, the purpose of this utility model is to provide a kind of costs
Low, zero-emission, water outlet can reach the heavy metal waste water treatment system of originally water quality standard.
The purpose of this utility model is achieved through the following technical solutions:
A kind of heavy metal waste water treatment system includes the pH regulating reservoirs, coagulating basin, flocculation being sequentially communicated by waste water flow direction
Pond, sedimentation basin, biochemical treatment system, ultrafiltration system, counter-infiltration system and evaporating, concentrating and crystallizing device, the counter-infiltration system are pressed
Waste water flow direction includes the level-one RO devices being sequentially communicated and multistage RO systems, and the level-one RO systems are equipped with the first treated water outlet
It is exported with the first concentrated water, first treated water outlet is communicated with reuse pool, the first concentrated water outlet and the multistage RO
System connectivity.
Wherein, the multistage RO systems include the two level RO devices being sequentially communicated and SRO devices by waste water flow direction, described
Disc tube reverse osmosis (dt-ro) film is equipped in SRO devices.
Wherein, the two level RO devices are equipped with the second treated water outlet and the second concentrated water and export, and the SRO devices are equipped with the
Three treated water outlets and the outlet of third concentrated water, second treated water outlet and third treated water outlet with level-one RO devices
Water inlet is connected to, and the second concentrated water outlet is connected to the water inlet of SRO devices, and the third concentrated water outlet and the evaporation are dense
The water inlet of contracting crystallization apparatus is connected to.
Wherein, the biochemical treatment system by waste water flow direction include be sequentially communicated hydrolysis acidification pool, contact-oxidation pool,
The ponds MBR and MBR produce pond.
Wherein, the ultrafiltration system includes the carbon filter being sequentially communicated and UF filter devices by waste water flow direction.
Wherein, PVDF filter membranes are equipped in the UF filter devices, the molecular cut off of the UF filter devices is
14000-16000 dalton.
Wherein, the evaporating, concentrating and crystallizing device is multi-effect evaporator.
Wherein, it is flowed to by waste water, wastewater equalization pond, the concentrated water evaporating, concentrating and crystallizing is additionally provided with before the pH regulating reservoirs
Device is equipped with condensation-water drain, and the condensation-water drain is connected to the water inlet of wastewater equalization pond.
Wherein, it is flowed to by waste water, readjustment pond is additionally provided between the sedimentation basin and the biochemical treatment system.
The beneficial effects of the utility model are:The heavy metal waste water treatment system and method for the utility model can to run
It leans on, economical rationality is that principle uses " ultrafiltration+multi-stage reverse osmosis " for " double films of core using relevant design standard and specification
Method " water treatment technology, program reasonable design, stable, production water quality are met the requirements, and each device has installation
Convenient, easy to use, easy to operate, easy to maintain advantage and stable, energy-saving and environmental protection, high degree of automation, economy
The features such as practical.
Embodiment 1
By waste water flow direction include the pH regulating reservoirs 2 being sequentially communicated, mixed as shown in Figure 1, a kind of heavy metal waste water treatment system
Solidifying pond 3, flocculation basin 4, sedimentation basin 5, biochemical treatment system, ultrafiltration system, counter-infiltration system and evaporating, concentrating and crystallizing device 17, institute
It includes by the level-one RO devices 13 and multistage RO systems of waste water flow direction setting to state counter-infiltration system, and the level-one RO systems are equipped with the
One treated water outlet and the outlet of the first concentrated water, first treated water outlet are communicated with reuse pool 14, and first concentrated water goes out
Mouth and the multistage RO system connectivities.
Wherein, the multistage RO systems include the two level RO devices 15 being sequentially communicated and SRO devices 16, institute by waste water flow direction
It states and is equipped with disc tube reverse osmosis (dt-ro) film in SRO devices 16.
Wherein, the two level RO devices 15 are equipped with the second treated water outlet and the second concentrated water exports, and the SRO devices 16 are set
There are third treated water outlet and the outlet of third concentrated water, second treated water outlet to be filled with level-one RO with third treated water outlet
13 water inlet connection is set, the second concentrated water outlet is connected to the water inlet of SRO devices 16, the third concentrated water outlet and institute
State the water inlet connection of evaporating, concentrating and crystallizing device 17.
Wherein, the biochemical treatment system by waste water flow direction include be sequentially communicated hydrolysis acidification pool 7, contact-oxidation pool 8,
The ponds MBR 9 and MBR produce pond 10.
Wherein, the ultrafiltration system includes the carbon filter 11 being sequentially communicated and UF filter devices 12 by waste water flow direction.
Wherein, PVDF filter membranes are equipped in the UF filter devices 12, the molecular cut off of the UF filter devices 12 is
14000-16000 dalton.
Wherein, the evaporating, concentrating and crystallizing device 17 is multi-effect evaporator.
Wherein, it is flowed to by waste water, wastewater equalization pond 1 is additionally provided with before the pH regulating reservoirs 2, the concentrated water is concentrated by evaporation knot
Brilliant device 17 is equipped with condensation-water drain, and the condensation-water drain is connected to the water inlet of wastewater equalization pond 1.
Wherein, it is flowed to by waste water, readjustment pond 6 is additionally provided between the sedimentation basin 5 and the biochemical treatment system.
It is now directed to each device effect of the present embodiment and total process flow illustrates:
(a) in pH regulating reservoirs 2, PH adjustings and demulsification are carried out using sodium hydroxide and complexing agent, adjustment pH value control exists
11-12, waste water are transferred in coagulating basin 3 and PAC are added in coagulating basin 3, and mixed water enters flocculation basin 4 and PAM shapes are added
At the floccule body for being more easy to precipitation, reduce part COD, SS, the water after flocculation enter in sedimentation basin 5 and precipitated (heavy metal CU2+,
Ni2+ is precipitated with precipitation form);
(b) in sedimentation basin 5, the body refuse of bulky grain is periodically scraped body refuse the bottom of to using mechanical mud scraper by shallow layer settling
It is deposited in portion's bucket, supernatant enters next link;
(c) supernatant of sedimentation basin 5 is 6-9 through adjusting back pond 6 to adjust pH, subsequently into hydrolysis acidification pool 7.In hydrolysis acid
Change in pond 7, the main hydrolysis acidification using anaerobic reaction acts on, and changes the molecular structure of macromolecular compound, makes water
The small molecule of dissolubility improves the biodegradability of sewage, creates conditions for Aerobic Process for Treatment;
(d) production waste water is flowed into from hydrolysis acidification pool 7 in contact-oxidation pool 8.Under aerobic condition, heterotroph and der Pilz are attached
It the syntrophism on filler and forms biomembrane, the sorrow of no sludge bulking.The oxygen needed for biological growth is provided by aerating system,
By the biomembrane of culture, organic matter of sewage is adsorbed, is absorbed, useless Organic substance in water is made to be eventually converted into H2O、CO2And N2
Equal inorganic molecules, to make sewage achieve the purpose that purification;
(e) it considers that raw water fluctuation is larger, to ensure the water outlet of system energy stably reaching standard, increases after contact-oxidation pool 8
The ponds MBR 9;A kind of new technology being combined using MBR membrane separation techniques and biochemical processing, instead of two in traditional handicraft
Heavy pond.It can be efficiently separated by solid-liquid separation, and stable clear liquid is obtained.Meanwhile and high concentration can be maintained in biological tank
Biomass, excess sludge is few, and the very effective removal ammonia nitrogen of energy goes out aqueous suspension and turbidity close to zero.The present embodiment is adopted simultaneously
It is MBR belt material hollow-fibre membranes, avoids the fracture of wire of conventional film, blocks the short problem of service life, it can be with direct-on-line medicine
It washes, simple operation, a large amount of artificial, the polluter in next further degrading waste water need to be impregnated in medicine pond by reducing;
(f) production waste water enters from the ponds MBR 9 in MBR productions pond 10, plays cushioning effect;
(g) the CODcr contents in MBR productions pond 10 are lower less than 60mg/L, the content of ammonia nitrogen, generally less than 5mg/L, SS
Content is extremely low, is generally less than less than 2mg/L;Such waste water can be used as the influent source of reuse water system.For further purified water
Matter achievees the purpose that zero-emission, MBR produce the production waste water in pond 10 and enter carbon filter 11 through raw water pump pressurization, go in water removal
The impurity such as suspended matter, colloid, it is ensured that enter the water quality of UF filter devices 12.Through treated the concentrated water of UF filter devices 12
Containing higher salinity, unsuitable direct reuse to production, it is necessary to carry out desalting processing.Using reverse osmosis unit desalination, go
Extra heavy metal ion in water removal, organic matter, salinity, achieve the purpose that purification, and to meet workshop water requirement, RO fresh water is sent
It is back to workshop again to plant area's water purification system.It is dense that the backwash water of carbon filter 11/UF devices enters pH regulating reservoirs 2, UF
Pond 10 can be produced into MBR by shrinking.Enter evaporating, concentrating and crystallizing device 17 after the concentrated decrement of RO concentrated waters, crystalline solid is packaged transfer office
It sets.
The targeted wastewater source of the present embodiment is in the etching solution of the processes such as production line etching, development striping, etching solution master
It is sulfuric acid to want ingredient<20%, acetic acid 5-15%, remaining ingredient are water, therefore estimate that etching waste component is copper sulphate, copper acetate.
Pollution factor is mainly PH:2-11;COD:2200mg/L;SS:9mg/L;Cu:123mg/L;T-N:39mg/L.
The running cost (including medicament expense, electricity cost, labour cost and consumptive material expense) of the present embodiment is about 0.39~
10.89 yuan/ton of water, relatively directly evaporation can save the cost of 70%-80%, and handling result reaches national integrated wastewater discharge mark
Accurate (GB8978-1996),《Pollutant emission standard is electroplated》(GB21900-2008);《Electroplating Wastewater Treatment engineering legislation》
(HJ2002-2010)、《Environmental Engineering Design handbook》;《Code for structural design of water supply and sewerage engineering》(GBJ69-84)、《Concrete
Code for structural design》(GBJ10-89)、《Code for design of low voltage power distribution installations and wiring systems》(GBJ54-83)、《Industrial enterprise illuminates
Design standard》(GBJ50034-92)、《General electrical equipment design specification》(GBJ50055-93)、《Rubber lining chemical industry equipment》
(HGJ32-90)、《Water treatment facilities manufacturing technology condition》(JB/T2932-1999)、《Reverse osmosis water treating equipment》(CJ/
T119-2000)、《Code for design of indutrial water softening and demineralization》(GBJ109-87)、《Water and Waste Water Engineering construction inspection rules》
(GB1328-1995) standards such as.
Above-described embodiment is the preferable implementation of the utility model, and in addition to this, the utility model can be with other sides
Formula realizes that any obvious replacement is in the protection model of the utility model without departing from the concept of the premise utility
Within enclosing.