CN207954920U - A kind of antireflection protective film - Google Patents
A kind of antireflection protective film Download PDFInfo
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- CN207954920U CN207954920U CN201820204278.4U CN201820204278U CN207954920U CN 207954920 U CN207954920 U CN 207954920U CN 201820204278 U CN201820204278 U CN 201820204278U CN 207954920 U CN207954920 U CN 207954920U
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- Prior art keywords
- magnesium fluoride
- layer
- protective film
- antireflection
- antireflection protective
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Abstract
The utility model provides a kind of antireflection protective film, and the antireflection protective film includes:Transparent substrates (101), setting the transparent substrates (101) one side hardened layer (102) and setting the hardened layer (102) surface magnesium fluoride layer (103);The magnesium fluoride layer (103) is made of nano magnesium fluoride particle.The refractive index for the magnesium fluoride layer that the utility model selects is 1.45 or so, it is smaller with the refractive index difference of air, when ambient is incident on magnesium fluoride layer surface, the reflection of generation is less, and the thickness by controlling magnesium fluoride layer, the light rays encounter interference cancellation that two interfaces of magnesium fluoride layer can be made to reflect, to reduce light reflection.Antireflection protective film provided by the utility model is simple in structure, relatively low to the reflectivity of visible light, and the clarity of screen picture under ambient light irradiation can be improved.
Description
Technical field
The utility model belongs to screen protection technical field of membrane, and in particular to a kind of antireflection protective film.
Background technology
The display picture of liquid crystal display will produce mirror when by the light of ambient enviroment such as sunlight or extraneous light-illuminating
Face is reflected and generates the phenomenon that mirroring, the picture that display screen should be shown will with the overlappings such as the light and landscape mirrored by the external world,
So that display image clearly declines, the appreciation effect for showing picture is influenced.The better method for solving this phenomenon is to display screen
It carries out antireflection process or uses antireflection film on the outside of screen.
Anti- (subtracting) reflectance coating is also known as anti-reflection film (AR films), and main function is to reduce electronics screen, video screen etc. in environment
What is generated under light source is reflective, increases light transmittance, screen-picture is made to be more clear.Liquid crystal display with antireflection film is suitable for
The occasion of aircraft cabin, terminating mobile phone, colour screen handset, laptop and large-scale monitor grade height performance requirement.
Antireflection film mainly reduces the reflection of light in terms of two.On the one hand, reflectivity of the light on interface and interface two
The refractive index of side medium is related, and refringence is smaller, then reflectivity is also smaller;On the other hand, made by adjusting the thickness of film layer
Reflected light on two interfaces of film layer forms certain phase difference, to interfere cancellation, can also reduce the reflection of light.Due to certain
The antireflection film layer of one thickness can only have preferable anti-reflection effect to the light of wavelength in a certain range, therefore, general anti-
Reflectance coating is required for the film layer for the different refractivity for having more to obtain lower light reflectivity.
《The research and application of film surface hardening coat》(" research and application of film surface hardening coat ", Du Yanfei,
Information-recording material, the 6th phase volume 13 in 2012) structure of antireflection film is disclosed, there is touch layer, the low folding stacked gradually
Penetrate rate layer, high refractive index layer, hard conating, PET base material layer, adhesive phase and isolation film.Wherein high refractive index layer, which generally requires, mixes
Miscellaneous inorganic nanometer oxide, such as titanium oxide, zirconium oxide, antimony oxide, tin indium oxide, refractive index is generally in 1.9-2.4.It is this
Antireflection film it is complicated, and the refractive index of high refractive index layer is larger, and the reflectivity of light can be caused higher.
Therefore, it is expected to obtain in this field a kind of simple in structure, and there is the antireflection compared with antiradar reflectivity to protect visible light
Cuticula.
Utility model content
In view of the deficienciess of the prior art, the purpose of this utility model is to provide a kind of antireflection protective film, this is anti-
Reflection protection film is relatively low to the reflectivity of visible light, has good anti-reflection effect, and screen can be improved and irradiated in ambient light
The clarity of lower picture.
For this purpose, the utility model uses following technical scheme:
The utility model provides a kind of antireflection protective film, including:Transparent substrates are arranged in the transparent substrates one side
Hardened layer and be arranged it is described hardening layer surface magnesium fluoride layer;
The magnesium fluoride layer is made of nano magnesium fluoride particle.
Magnesium fluoride layer described in the utility model is prepared by the method for magnetron sputtering.
The refractive index for the magnesium fluoride layer that the utility model selects is 1.45 or so, smaller with the refractive index difference of air, outside
When boundary's light is incident on magnesium fluoride layer surface, the reflection of generation is less;Magnesium fluoride layer is by nano magnesium fluoride grain in the utility model
Son is accumulated, and the magnesium fluoride layer for thus accumulating formation is more uniform, can guarantee that the anti-reflection effect of entire protective film is uniform.
Preferably, the grain size of the nano magnesium fluoride particle be 5-40nm, such as can be 5nm, 8nm, 10nm, 12nm,
15nm, 18nm, 20nm, 25nm, 30nm, 35nm or 40nm etc..
Preferably, the thickness of the magnesium fluoride layer be 20-180nm, such as can be 20nm, 30nm, 40nm, 50nm,
60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, 140nm, 150nm, 160nm, 170nm or 180nm etc.;
More preferably 137.5nm.
Antireflection film is the reflection for the light that specific wavelength is reduced using the principle of reflected light cancellation.The thickness e of antireflecting coating
=(n/2+1/4) λ, wherein λ are wavelength, n natural numbers.
Provided by the utility model is a kind of single layer anti reflective coating, i.e., the light of some specific λ wavelength can only be made to reduce to the greatest extent instead
It penetrates, also has different degrees of decrease for other reflected lights of close-spaced wavelength.For general visual transparent optical instrument, Chang Xuan
The light that the most sensitive wavelength of human eye is 550nm carries out anti-reflection, at this time the minimum 137.5nm of the thickness of magnesium fluoride layer.Under white light
The reflected light of this film is watched, yellow-green light is most weak, and feux rouges blue light is more relatively strong.
Preferably, the thickness of the hardened layer is 2-15 μm, such as can be 2 μm, 3 μm, 4 μm, 5 μm, 6 μm, 7 μm, 8 μ
M, 9 μm, 10 μm, 11 μm, 12 μm, 13 μm, 14 μm or 15 μm etc..
Preferably, the thickness of the transparent substrates is 25-250 μm, for example, can be 25 μm, 50 μm, 75 μm, 100 μm,
125 μm, 150 μm, 175 μm, 200 μm, 225 μm or 250 μm etc..
Preferably, the transparent substrates are polyethylene terephthalate (PET) film.
Preferably, the antireflection protective film further includes the first adhesive linkage being arranged on the magnesium fluoride layer surface, and
Protective layer in the first bonding layer surface is set.
Preferably, the thickness of the protective layer is 25-150 μm, for example, can be 25 μm, 30 μm, 40 μm, 50 μm, 60 μm,
70 μm, 80 μm, 90 μm, 100 μm, 110 μm, 120 μm, 130 μm, 140 μm or 150 μm etc..
Preferably, the antireflection protective film further includes the second adhesive linkage being arranged in the transparent substrates another side, with
And the release film in the second bonding layer surface is set.
Compared with prior art, the utility model has the advantages that:
The magnesium fluoride layer of the utility model selection and the refractive index difference of air are smaller, have magnesium fluoride build-up of particles to be formed
Magnesium fluoride layer is more uniform, so that antireflection protective film provided by the utility model is had uniform anti-reflection effect, for wavelength
Total reflectivity≤2.5% of 400-700nm visible lights, and its case hardness >=3H, can be subjected to No. 0000 under the pressure of 2000g
Steel wool rubs 600 times and not damaged repeatedly.
Description of the drawings
Fig. 1 is the structural schematic diagram for the antireflection protective film that the utility model embodiment 1 provides;
Wherein, 101 be transparent substrates, and 102 be hardened layer, and 103 be magnesium fluoride layer.
Fig. 2 is the structural schematic diagram for the antireflection protective film that the utility model embodiment 2 provides;
Wherein, 201 be transparent substrates, and 202 be hardened layer, and 203 be magnesium fluoride layer, and 204 be the first adhesive linkage, and 205 be guarantor
Sheath, 206 be the second adhesive linkage, and 207 be release film.
Specific implementation mode
Further illustrate the technical solution of the utility model below in conjunction with the accompanying drawings and by specific embodiment.This field skill
Art personnel are not construed as to the specific of the utility model it will be clearly understood that the embodiment is only to aid in and understands the utility model
Limitation.
Embodiment 1
A kind of antireflection protective film, as shown in Figure 1, including transparent substrates 101, being arranged in the hard of 101 one side of transparent substrates
Change layer 102 and the magnesium fluoride layer 103 on 102 surface of hardened layer is set;
Wherein, transparent substrates 101 are PET film, and thickness is;The thickness of hardened layer 102 is;Magnesium fluoride layer 103 is by grain size
The fluorination magnesium particle of nm is constituted, and thickness is.
Antireflection protective film provided in this embodiment is for the total reflectivity for the visible light that wavelength is 400-700nm
2.3%, case hardness 3H can be subjected to No. 0000 steel wool under the pressure of 2000g and rub repeatedly 600 times and not damaged.
Embodiment 2
A kind of antireflection protective film, as shown in Fig. 2, including from top to bottom protective layer 205, the first adhesive linkage 204, fluorine successively
Change magnesium layer 203, hardened layer 202, transparent substrates 201, the second adhesive linkage 206 and release film 207;
Wherein, transparent substrates 201 are PET film, and thickness is;The thickness of hardened layer 202 is;Magnesium fluoride layer 203 is by grain size
The fluorination magnesium particle of nm is constituted, and thickness is;The thickness of protective layer is.
Antireflection protective film provided in this embodiment is for the total reflectivity for the visible light that wavelength is 400-700nm
1.9%, case hardness 3H can be subjected to No. 0000 steel wool under the pressure of 2000g and rub repeatedly 600 times and not damaged.
Embodiment 3
A kind of antireflection protective film, including the protective layer, the first adhesive linkage, magnesium fluoride layer, hardened layer, transparent that stacks gradually
Substrate, the second adhesive linkage and release film;
Wherein, transparent substrates are PET film, and thickness is;The thickness of hardened layer is;Magnesium fluoride layer is by the magnesium fluoride that grain size is nm
Particle is constituted, and thickness is;The thickness of protective layer is.
Antireflection protective film provided in this embodiment is for the total reflectivity for the visible light that wavelength is 400-700nm
2.1%, case hardness 3H can be subjected to No. 0000 steel wool under the pressure of 2000g and rub repeatedly 600 times and not damaged.
Embodiment 4
A kind of antireflection protective film, including the protective layer, the first adhesive linkage, magnesium fluoride layer, hardened layer, transparent that stacks gradually
Substrate, the second adhesive linkage and release film;
Wherein, transparent substrates are PET film, and thickness is;The thickness of hardened layer is;Magnesium fluoride layer is by the magnesium fluoride that grain size is nm
Particle is constituted, and thickness is;The thickness of protective layer is.
Antireflection protective film provided in this embodiment is for the total reflectivity for the visible light that wavelength is 400-700nm
1.7%, case hardness 3H can be subjected to No. 0000 steel wool under the pressure of 2000g and rub repeatedly 600 times and not damaged.
Applicant states, the foregoing is merely specific embodiment of the present utility model, but the protection model of the utility model
It encloses and is not limited thereto, person of ordinary skill in the field is it will be clearly understood that any belong to those skilled in the art and exist
In the technical scope that the utility model discloses, the change or replacement that can be readily occurred in all fall within the scope of protection of the utility model
Within the open scope.
Claims (10)
1. a kind of antireflection protective film, which is characterized in that the antireflection protective film includes:Transparent substrates are arranged described
The hardened layer of bright substrate one side and be arranged it is described hardening layer surface magnesium fluoride layer;
The magnesium fluoride layer is made of nano magnesium fluoride particle.
2. antireflection protective film according to claim 1, which is characterized in that the grain size of the nano magnesium fluoride particle is 5-
40nm。
3. antireflection protective film according to claim 1 or 2, which is characterized in that the thickness of the magnesium fluoride layer is 20-
180nm。
4. antireflection protective film according to claim 1 or 2, which is characterized in that the thickness of the magnesium fluoride layer is
137.5nm。
5. antireflection protective film according to claim 1 or 2, which is characterized in that the thickness of the hardened layer is 2-15 μm.
6. antireflection protective film according to claim 1 or 2, which is characterized in that the thickness of the transparent substrates is 25-
250μm。
7. antireflection protective film according to claim 1 or 2, which is characterized in that the transparent substrates are PET film.
8. antireflection protective film according to claim 1 or 2, which is characterized in that the antireflection protective film further includes setting
The first adhesive linkage on the magnesium fluoride layer surface is set, and the protective layer in the first bonding layer surface is set.
9. antireflection protective film according to claim 8, which is characterized in that the thickness of the protective layer is 25-150 μm.
10. antireflection protective film according to claim 1 or 2, which is characterized in that the antireflection protective film further includes setting
The second adhesive linkage in the transparent substrates another side is set, and the release film in the second bonding layer surface is set.
Priority Applications (1)
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CN201820204278.4U CN207954920U (en) | 2018-02-06 | 2018-02-06 | A kind of antireflection protective film |
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CN201820204278.4U CN207954920U (en) | 2018-02-06 | 2018-02-06 | A kind of antireflection protective film |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113302035A (en) * | 2019-01-10 | 2021-08-24 | 三菱瓦斯化学株式会社 | Antireflection film and multilayer film having antireflection film |
-
2018
- 2018-02-06 CN CN201820204278.4U patent/CN207954920U/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113302035A (en) * | 2019-01-10 | 2021-08-24 | 三菱瓦斯化学株式会社 | Antireflection film and multilayer film having antireflection film |
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Granted publication date: 20181012 Termination date: 20190206 |
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